Module 1 Quiz Practice Questions Sourced from Chem 131 F2017 Exam 1 1. An element has two naturally occurring isotopes. Isotope 1 has a mass of 120.9038 amu and a relative abundance of 57.4%. Isotope 2 has a mass of 122.9042 amu. Calculate the atomic mass of the atom and identify the atom from the periodic table.1 (15pts) 2. b-hydroxybutyrate is a nutritional supplement used by people following a ketogenic diet and is composed of carbon, oxygen, and hydrogen. A sample of 10.00 g of bhydroxybutyrate is burned completely in the presence of excess oxygen and 16.94 g of CO2 and 6.930 g of H2O is isolated. Assume 100 % yield of the combustion reaction. The unbalanced reaction is given below: ! − ℎ$%&'($)*+$&,+- + /! → 1/! + 2! / a. Provide an empirical formula for b-hydroxybutyrate. (10 pts) b. **Note: This information requires use of concentration concepts from Module 2 and would not be asked in this way for a Module 1 quiz.** To a container was added 10 mL of b-hydroxybutyrate (1.041 g/mL). Water was added until the total volume was 100 mL. This solution had a concentration of b-hydroxybutyrate of 1.00 M. What is the molecular weight and molecular formula of b-hydroxybutyrate? (10 pts) 1 Adapted from Tro, Principles of Chemistry, A Molecular Approach, 2nd edition 1 PERI ODI C TABLE OF THE ELEM ENTS 2 7 O 8 F 9 Ne He 6 N 18 20.18 H 5 C 17 19.00 10 4 B 16 16.00 4.00 3 Be 15 14.01 1.008 Li 14 12.01 Ar 13 Cl 10.81 S 12 P 9.01 Si 11 Al 6.94 Mg Kr Na Br 36 Se 39.95 As 35 30 Ge 35.45 29 Ga 34 28 Zn 32.06 27 Cu 33 26 Ni 30.97 25 Co 32 24 Fe 28.09 23 Mn 31 22 Cr 26.98 21 V 20 Ti 24.30 Sc 19 Ca 22.99 K Xe 54 131.29 83.80 I 53 126.91 79.90 Te 52 127.60 78.96 Sb 51 121.75 74.92 Sn 50 118.71 72.59 In 49 114.82 69.72 Cd 48 112.41 65.39 Ag 47 107.87 63.55 Pd 86 46 106.42 Rn 58.69 Rh 85 (222) 45 102.91 At 58.93 Ru 84 (210) 44 101.1 Po 55.85 Tc 83 (209) 43 (98) 82 Bi 54.94 Mo 81 208.98 42 95.94 80 Pb 52.00 Nb 79 207.2 41 92.91 78 Tl 50.94 Zr 77 204.38 40 91.22 76 Hg 47.90 Y 75 200.59 39 88.91 74 Au 44.96 Sr 73 196.97 38 87.62 72 Pt 40.08 Rb 57 195.08 37 85.47 56 Ir 39.10 55 192.2 71 Os Lu 190.2 70 174.97 Re Yb 186.21 69 173.04 W Tm 183.85 68 168.93 103 Ta Er Lr 180.95 67 167.26 102 (262) Hf Ho No 178.49 Rg 66 164.93 101 (259) * La (272) Dy 100 (258) Md 138.91 Ds 65 162.50 Fm Ba (271) Tb 99 (257) 137.33 Mt 64 158.93 Es Cs (268) Gd 98 (252) 132.91 Hs 63 157.25 Cf 111 (277) Eu 97 (251) 110 Bh 62 151.97 Bk 109 (2624 Sm 96 (247) 108 Sg 61 150.4 95 (247) Cm 107 (266) Pm 94 (243) Am 106 Db 60 (145) Pu 105 (262) Nd 93 (244) 104 Rf 59 144.24 Np 89 (261) Pr 92 (237) 88 58 140.91 U 87 227.03 Ce 91 238.03 Ra 140.12 Pa 226.02 90 231.04 Fr Th (223) *Lanthanide Series 232.04 Formulas !" = −log [" ! ] 5 !," = −log [," ] Units and Constants +" = +#!" +$"# ! 5 +" = [" ][," ] [HA] [HA] !," = !+ + log $ [/ 5 ] [/5] 5 [A ] [A5 ] !" = !+# + log !," = !+$ − log ["/] ["/] !" = !+# − log LM = N>O P3,* + P3,*+$ P2 = 2 [2+ ] = [2, /+ ] = 10#-. 3/0 1 1* = 3- S T >O L& = H& L'('&) 1= 2344 6(89 ) = 5 ;< NAvogadro = 6.022 × 1023 1 mL = 1 cm–3; 1000 L = 1 m3 3" = 1.0 • 10#$% 1000 mL = 1 L 1000 g = 1 kg 1000 mg = 1 g 0 °1 = 2733 ,+@ • A @'B • 3 D > = 8.314 @'B • 3 > = 0.0821 1 '() = 760 ./00 = 760 ))12 = 101 34' 1D =1 EF • @! G! −) ± √) ! − 4,K H= 2, 3-U