AN ASSESSMENT OF GROUNDWATER QUALITY AND SANITARY INSPECTION OF BOREHOLES IN THE ADENTAN MUNICIPALITY OF THE GREATER ACCRA REGION NATHANAIEL KAFUI KODJO DUMASHIE BSc. Biological Science, Dip Ed. 1 STATEMENT OF THE PROBLEM • Adentan Municipality never enjoyed constant supply of water. • Location on periphery of Accra puts it in a problematic situation. • Urbanisation, population growth are increasing pressure on cities, resulting in people living without adequate provision of water, sanitation. 2 • Ghana government, some N.G.O.’s have constructed boreholes, hand dug wells countrywide. • These non-treated water sources are being increasingly used as drinking water, yet testing to see whether the water is of good quality or not is non-existent (Obiri-Danso et al., 2009). 3 MAIN OBJECTIVE • To determine the quality of water in nine boreholes in the Adentan Municipality and carry out a sanitary inspection of the boreholes. 4 SPECIFIC OBJECTIVES • To identify the potential risks of contamination of water in the boreholes. • To determine the physico-chemical, ion and heavy metal parameters of water in the boreholes. • To assess the levels of total heterotrophic bacteria, total and faecal coliforms in the water. 5 METHODOLOGY Water was sampled from nine boreholes 6 Fig.1 Map of Adentan Municipality 7 PARAMETERS TESTED PHYSICO-CHEMICAL PARAMETERS Insitu Testing: Temp, pH, TDS and Cond, Turbidity, Salinity In the laboratory: Alkalinity, Total Suspended Solids, Colour IONS Nitrate, Phosphate, Sulphate, Bicarbonate, Chloride and Fluoride HEAVY METAL Mn, Cr, Cu, Zn, Pb, Fe, Ca, Mg 8 PARAMETERS TESTED (cont’d) Bacteriological Testing Total heterotrophic bacteria total coliforms faecal coliforms Sanitary Inspections Systematic inspection of all nine boreholes Risk-to-health analysis Sanitary inspections scores were combined with mean faecal coliform levels to derive a risk-to-health matrix. 9 Physico chemical, ions, heavy metals and bacteria were compared with WHO and GWCL standards. 10 RESULTS & DISCUSSION Physico Chemical Parameters pH fell within W.H.O and G.W.C.L. limits at all the sites except at Station (STN) where the water was found to be acidic (5.80-6.20) below W.H.O and G.W.C.L. range 11 Physico-chemical parameters of borehole water at Station (STN) Table 1. SAMPLING DATE (MONTH & YEAR) Temperature (oC) EC (µS/cm) Dec-2011 28.50±0.05 Jan-2012 PARAMETER pH Turbidity (NTU) TSS (mg/L) 1349.00±0.00 6.20±0.00 0.72±0.00 0.00±0.00 28.70±0.09 1400.00±0.00 5.90±0.00 0.67±0.08 0.00±0.00 Feb-2012 29.00±0.05 1686.00±0.00 5.80±0.00 0.98±0.02 1.00±0.00 Mar-2012 29.20±0.02 1709.00±0.00 5.80±0.00 0.97±0.01 2.00±0.00 Apr-2012 29.00±0.15 1675.00±0.00 5.93±0.00 1.60±0.01 0.00±0.00 May-2012 29.50±0.03 1690.00±0.00 5.92±0.00 0.77±0.05 0.00±0.00 W.H.O. Limit G.W.C.L. Limit 25.00 1500.00 6.50-8.50 5.00 500.00 - - 6.50-8.50 0.00-15.00 0.00 12 • Turbidity satisfied WHO standards except at ACS. and G.W.C.L. 13 Physico-chemical parameters of borehole water at Adenta Community School (ACS) Table 2 PARAMETER SAMPLING DATE (MONTH & YEAR) Temperature (oC) EC (µS/cm) Dec-2011 29.10±0.08 Jan-2012 pH Turbidity (NTU) TSS (mg/L) 1682.00±0.00 7.40 ±0.00 13.80±0.22 9.00±0.00 29.00±0.52 1671.00±0.00 7.40±0.00 4.19±0.07 1.00±0.00 Feb-2012 30.20±0.59 2671.00±0.00 7.30±0.00 13.00±1.92 1.20±0.00 Mar-2012 30.00±0.14 2902.00±0.00 7.20±0.00 16.60±0.25 4.00±0.00 Apr-2012 29.00±0.05 2906.00±0.00 7.35±0.00 4.53±0.19 0.00±0.00 May-2012 29.50±0.13 2968.00±0.00 7.11±0.00 24.90±0.18 0.00±0.00 W.H.O. Limit G.W.C.L. Limit 25.00 1500.00 6.50-8.50 5.00 500.00 - - 6.50-8.50 0.00-15.00 0.00 14 • Values for total dissolved solids at ASH, AdMA, ACS, NL, SRA, ADJ, OGB all exceeded both WHO and GWCL standards. 15 Physico-chemical parameters of borehole water at Ashiyie (ASH) PARAMETER SAMPLING DATE (MONTH & YEAR) TDS (mg/L) Alkalinity (mg/L) Salinity (‰) Colour (Ptco) Total Hardness (mg/L) Dec-2011 876.00±0.00 88.40±0.00 1.00±0.00 8.00±0.73 952.53±0.00 Jan-2012 725.00±0.00 87.60±0.00 2.00±0.00 3.00±0.72 526.65±0.00 Feb-2012 1035.00±0.00 94.60±0.00 3.00±0.00 19.00±0.68 658.34±0.00 Mar-2012 1040.00±0.00 84.60±0.00 3.00±0.00 0.00±0.69 475.78±0.00 1028.00±0.00 92.60±0.00 6.00±0.00 4.00±0.93 502.82±0.00 May-2012 1050.00±0.00 102.10±0.00 5.00±0.00 5.00±0.89 517.27±0.00 W.H.O. Limit G.W.C.L. Limit 1000.00 200.00 - 15.00 500.00 1000.00 - - 0.00-15.00 500.00 Table 3 Apr-2012 16 • Total suspended solids (TSS) and alkalinity at all the nine sites were within safe limits of the W.H.O.. • Temperature, conductivity and total hardness at various times during the study were higher than W.H.O. standards at all nine sites. 17 ION CONCENTRATIONS • Phosphate and nitrate at all the nine sites were within safe limits of the W.H.O. However a value of 11.20mg/L nitrate was recorded at AdMA in March and May, 2012, outside the G.W.C.L. range of 0.00-10.00mg/L 18 Ion Concentrations in borehole at Adenta Municipal Assembly (AdMA) Table 4 SAMPLIN G DATE (MONTH & YEAR) Phosphate Nitrate Dec-2011 0.55±0.00 8.44±0.00 105.10±0.00 112.60±0.00 174.62±0.00 2.40±0.00 Jan-2012 0.48±0.00 7.60±0.00 114.92±0.00 104.50±0.00 71.04±0.00 2.09±0.00 Feb-2012 0.44±0.00 9.20±0.00 124.93±0.00 124.50±0.00 74.60±0.00 2.24±0.00 Mar-2012 0.44±0.00 11.20±0.00 107.80±0.00 152.40±0.00 70.10±0.00 2.19±0.00 Apr-2012 0.38±0.00 7.50±0.00 149.33±0.00 182.00±0.00 75.22±0.00 2.11±0.00 May-2012 W.H.O. Limit G.W.C.L. Limit 0.42±0.00 11.20±0.00 160.06±0.00 246.00±0.00 70.10±0.00 1.99±0.00 8.00 50.00 - - 0.00-10.00 - PARAMETER (mg/L) Bicarbonate Sulphate 400.00 Chloride 250.00 0.00-400.00 0.00-600.00 Fluoride 1.50 0.00-1.50 19 • Sulphate concentrations at SRA, OGB, ADJ and NL were higher at certain times of the study above W.H.O. and G.W.C.L. limits of 400.00mg/L. 20 Ion Concentrations in borehole at Sraha (SRA) Table 5 SAMPLING DATE (MONTH & YEAR) Dec-2011 Jan-2012 Feb-2012 Mar-2012 Apr-2012 May-2012 W.H.O. Limit G.W.C.L. Limit PARAMETER (mg/L) Phosphate Nitrate Bicarbonate Sulphate Chloride Fluoride 0.16±0.00 1.90±0.00 104.20±0.00 204.20±0.00 115.41±0.00 0.25±0.00 0.60±0.00 2.20±0.00 102.72±0.00 264.60±0.00 0.01±0.00 0.17±0.00 0.53±0.00 2.60±0.00 134.44±0.00 270.00±0.00 2.46±0.00 1.27±0.00 0.55±0.00 3.00±0.00 100.70±0.00 276.40±0.00 0.00±0.00 1.28±0.00 0.56±0.00 2.30±0.00 149.82±0.00 450.20±0.00 288.60±0.00 0.19±0.00 0.66±0.00 4.20±0.00 125.17±0.00 364.20±0.00 2.46±0.00 0.26±0.00 8.00 50.00 - 400.00 250.00 1.50 - 0.00-10.00 - 0.00-400.00 0.00-600.00 0.00-1.50 21 • Chloride values at all the sites fell within the G.W.C.L. tolerable range of 0.00-600.00mg/L. Values at ACS, SRA, STN and NL however fell above the W.H.O. safe limit of 250.00mg/L at various times during the study. 22 Ion Concentrations in borehole at Adenta Community School (ACS) Table 6 SAMPLIN G DATE (MONTH & Phosphate YEAR) PARAMETER (mg/L) Nitrate Bicarbonate Sulphate Chloride Fluoride Dec-2011 0.76±0.00 0.90±0.00 103.40±0.00 148.20±0.00 165.88±0.00 1.55±0.00 Jan-2012 0.70±0.00 0.80±0.00 105.16±0.00 166.20±0.00 138.51±0.00 0.17±0.00 Feb-2012 0.35±0.00 2.30±0.00 117.36±0.00 154.20±0.00 122.60±0.00 2.05±0.00 Mar-2012 0.82±0.00 2.60±0.00 114.90±0.00 136.80±0.00 120.60±0.00 2.07±0.00 Apr-2012 0.63±0.00 0.40±0.00 129.56±0.00 228.00±0.00 288.50±0.00 0.66±0.00 May-2012 W.H.O. Limit G.W.C.L. Limit 0.88±0.00 0.70±0.00 121.51±0.00 272.10±0.00 121.40±0.00 1.99±0.00 8.00 50.00 - 400.00 250.00 1.50 - 0.00-10.00 - 0.00-400.00 0.00-600.00 0.00-1.5023 • During the six months study, all the sites except SRA, recorded fluoride concentrations above the W.H.O. limit of 1.50mg/L and G.W.C.L. range of 0.00-1.50mg/L 24 HEAVY METAL CONCENTRATION • Calcium concentrations at ASH, ACS, SRA, OGB, ADJ and NL were above the W.H.O. limit at various times. • Each of the nine sites recorded magnesium concentrations above the W.H.O. limit of 50mg/L at various times. 25 Heavy Metal Concentrations in borehole at Ashiyie (ASH) Table 7 SAMPLING DATE (MONTH & YEAR) Dec 2011 Jan 2012 Feb 2012 Mar 2012 Apr 2012 May 2012 W.H.O. Limit G.W.C.L. Limit PARAMETER (mg/L) Calcium Magnesium Copper Manganese 232.30±0.00 90.45±0.00 ND* 0.29±0.00 164.90±0.00 27.90±0.00 ND* 0.34±0.00 149.00±0.00 69.52±0.00 0.01±0.00 0.39±0.00 140.90±0.00 30.10±0.00 0.01±0.00 0.37±0.00 155.11±0.00 28.05±0.00 0.01±0.00 0.32±0.00 160.80±0.00 28.11±0.00 0.01±0.00 0.37±0.00 200.00 50.00 2.00 0.50 - - 1.00 0.00-0.10 26 • Water in all the nine boreholes recorded copper and zinc concentrations within the W.H.O. limit throughout the study period. 27 • Manganese concentration at ACS, SRA and VPS were outside the W.H.O. limit, at various months during the study 28 Heavy Metal Concentrations in borehole at Adenta Community School (ACS) Table 8 SAMPLING DATE (MONTH & YEAR) Dec 2011 Jan 2012 Feb 2012 Mar 2012 Apr 2012 May 2012 W.H.O. Limit G.W.C.L. Limit PARAMETER (mg/L) Calcium Magnesium Copper Manganese 223.30±0.00 92.47±0.00 ND* 0.93±0.00 186.60±0.00 27.62±0.00 0.06±0.00 0.30±0.00 139.90±0.00 85.94±0.00 0.01±0.00 0.73±0.00 140.20±0.00 30.22±0.00 0.01±0.00 0.80±0.00 180.44±0.00 28.00±0.00 0.01±0.00 0.31±0.00 143.20±0.00 31.01±0.00 0.01±0.00 0.81±0.00 200.00 50.00 2.00 0.50 - - 1.00 0.00-0.10 29 • Iron concentrations at ACS and VPS were above the W.H.O. and G.W.C.L. limits of 0.30mg/L at various times of the study. • Chromium and lead were not detected at any of the borehole sites throughout the study. 30 Heavy Metal Concentrations in borehole at Victory Presby School (VPS) Table 9 SAMPLING DATE (MONTH & YEAR) PARAMETER (mg/L) Iron 0.44±0.00 Zinc 0.01±0.00 0.11±0.00 0.02±0.00 0.34±0.00 0.03±0.00 0.25±0.00 0.02±0.00 0.30±0.00 0.02±0.00 0.24±0.00 0.02±0.00 0.30 0.00-0.30 ND* ND* ND* ND* ND* ND* ND* ND* ND* ND* ND* 3.00 0.05 0.01 5.00 - 0.01 Jan 2012 Feb 2012 Mar 2012 Apr 2012 May 2012 G.W.C.L. Limit Lead ND* Dec 2011 W.H.O. Limit Chromium 31 MICROBIAL INDICATORS • Total heterotrophic bacteria, total coliforms and faecal coliforms were present in the water samples at all the nine sites, with Sraha (SRA) recording the highest of all the microbial indicators in March 2012. 32 Microbial indicator numbers of water in borehole at Sraha (SRA) Table 10 PARAMETERS (CFU/100mL) SAMPLING DATE (MONTH & YEAR) Total Heterotrophic Bacteria Total Coliform Dec-2011 3.00x102±0.43 0.00 Jan-2012 0.00 Feb-2012 0.00 Mar-2012 1.54x104±0.00 Apr-2012 6.70x103±0.02 May-2012 1.05x103±0.07 W.H.O. Limit 0.00 G.W.C.L. Limit 0.00 0.00 0.00 1.33x104±0.02 1.60x103±0.02 0.00 0.00 0.00 Faecal Coliform 0.00 0.00 0.00 9.35x103±0.00 8.50x102±0.08 0.00 0.00 0.00 33 Sanitary Inspections • The boreholes were sited very close to public toilets, refuse dumps, commercial areas like lorry parks and markets and in the vicinity of domestic and grazing animals. 34 Public toilet located near to borehole with hand pump at ADJ. A refuse dump can be seen to the left of the borehole. 35 CONCLUSION AND RECOMMENDATIONS CONCLUSION WHO standards: • no adverse effects from pH (except at STN), total suspended solids (TSS), alkalinity, phosphate, nitrate, copper and zinc. • adverse effects from temperature, conductivity, total dissolved solids (TDS) (except at VPS and STN), total hardness, fluoride (except at SRA), and magnesium 36 CONCLUSION (Cont’d) G.W.C.L. standards: • no adverse effects from pH (except at STN), turbidity (except at ACS), nitrate (except at AdMA), chloride, copper and zinc are concerned. • adverse effects due to total dissolved solids (TDS) (except at VPS and STN), total hardness, fluoride (except at SRA), magnesium and manganese (except at NL and OGB). • Water is contaminated with animal and human waste and unsuitable for drinking purposes. 37 CONCLUSION (Cont’d) • Sanitary inspection generally showed that septic tanks, choked soakage pits, human activities and animal wastes contributed significantly to poor water quality. • Risk analysis shows importance to take urgent action to improve on potability of water from boreholes. 38 RECOMMENDATIONS • boreholes should be sited at least 10m away from latrines. • Creation of rubbish dumps should be discouraged. • Borehole facilities should be fenced. • The drainage systems at the STN, NL and OGB borehole facilities should be properly sloped • Borehole aprons should be well reinforced with steel wire (OGB). • Hand pump at SRA should be firmly tightened onto the base. 39