Sri Chaitanya IIT Academy.,India. A.P T.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI A right Choice for the Real Aspirant ICON Central Office - Madhapur - Hyderabad JEE-ADVANCE-2022_P2 Sec: Sr. Elite(C-120, C-IPL, IPL-IC) RPTA-08 Time: 02.30PM to 05.30PM Date: 08-10-2023 Max. Marks: 180 KEY SHEET MATHEMATICS 1 9 2 6 3 8 4 8 5 2 6 1 7 0 8 4 9 ABD 10 AD 11 ABCD 12 CD 13 ABD 14 BCD 15 A 16 B 17 A 18 C PHYSICS 19 2 20 8 21 2 22 5 23 6 24 8 25 4 26 8 27 AB 28 AC 29 ABCD 30 ABC 31 AD 32 AD 33 A 34 B 35 C 36 D 3 CHEMISTRY 37 9 38 5 39 9 41 5 42 5 43 2 44 3 45 ABCD 46 AB 47 BC 48 ACD 49 CD 50 CD B D 53 A 54 C 51 40 52 Sri Chaitanya IIT Academy 08-10-23_Sr.Elite(C-120, C-IPL, IPL-IC)_Jee Adv(2022-P2)_RPTA-08_Paper 2_Key & Sol's SOLUTIONS MATHEMATICS 1 1 1 9 4 36 . det ad B 1 A1 1 1 2 1 1 B A j 2 2 B A 01. det ad j B 1 A1 02. 3 4 3 4 1 0 BC 2 3 2 3 0 1 1 ABC=A A BC 2 ABC Tr A Tr Tr 4 2 1 A A = Tr A Tr Tr Tr A 2Tr A 2 3 6 1 2 4 1 2 03. A2 2 I 0; 2C A2 32 A2 A3 B 2C A3 B 0 A 3 B A2 2C 0 As A2 2C 0; A3 B 0 [2C A2 is non singular] B A3 A A2 A 2 I 2 A 2 2 B A 2A A A 2 A2 2 I A2 2 I 8 3 2 B A A2 8 Absolute value=8. 04. adj A T adj A T 1 1 adj AT AT A 2 2 1 1 2 A 2 1 adj A A1 Sec : Sr.Elite(C-120, C-IPL, IPL-IC) Page 2 Sri Chaitanya IIT Academy 1 b x 1 c x 1 b x 1 c x 1 b x 1 c x 1 a2 x 05. 08-10-23_Sr.Elite(C-120, C-IPL, IPL-IC)_Jee Adv(2022-P2)_RPTA-08_Paper 2_Key & Sol's f x 1 a 2 x 1 a x 2 2 2 2 2 2 2 R3 R3 R1 1 b x 1 c x 1 a2 x 2 R2 R2 R1 x 1 1 x 0 x 1 1 a2 x 2 0 1 x x 1 2 1 1 1 b x 1 c x 2 2 1 0 0 1 2 x 1 1 a 2 x 1 0 1 b2 x 1 0 1 c 2 x 0 1 2 2 x 1 1 a 2 x x b2 x x c 2 x x 1 1 2 x a 2 b 2 c 2 x But a 2 b 2 c 2 2 . x 1 1 2 x 2 x x 1 2 2 Degree 2. 06. l1 m1 n1 l1 m1 n1 l2 l3 m2 m3 n2 l2 n3 l3 m2 m3 n2 n3 2 l12 m12 n12 l1l2 m1m2 n1n2 l1l3 m1m3 n1n3 l1l2 m1m2 n1n2 l m n 2 2 2 2 2 2 l2l3 m2 m3 n2 n3 l1l3 m1m3 n1n3 1 0 0 l2l3 m2 m3 n2 n3 0 1 0 1 2 1 1 0 0 1 l32 m32 n32 1. 07. Put n=3 But A2 A1 3 B A2 A8 C A2 3 1 A3 I A2 B A6 . A2 I . A2 A2 Hence det B C A2 A2 0 0 . 08. A is 3 x 3 matrix and A 2 Now adjA1 1 09. 1 1 2 A 4 2 1 adjA A 1 A2 4 A 5I 3 0 A A 4 I 3 5I 3 A1 1 A 4 I3 . 5 Sec : Sr.Elite(C-120, C-IPL, IPL-IC) Page 3 Sri Chaitanya IIT Academy 10. 9 2 A9 B 1 22 A . 08-10-23_Sr.Elite(C-120, C-IPL, IPL-IC)_Jee Adv(2022-P2)_RPTA-08_Paper 2_Key & Sol's 1 2 B 9 A 1 3 4 1 1 . 11. 2 2 2 2 2 2 3 1 1 1 0 1 2 x 12. b a a 2 2 b x a b x a b x 1 a b a b c1 c1 c2 c3 a b x x ab x b a a b x 1 x a 1 b x x R2 R2 R1 , R3 R3 R1 1 a b a b x 0 x a a b 0 b a x b 2 a b x x a x b a b a b x x 2 a b x a 2 b 2 ab 13. a,b,c are roots of x 2 x 2 4 0 a b c 1 ab+bc+ca=0, abc=4 a b c A c a b a 3 b3 c 3 3abc a b c a 2 b 2 c 2 ab bc ca b c a 2 2 1 a b c 3 ab bc ca 1 1 0 1 0 AAT I A1 AT . 14. A 2 3 2 2 6 . (i) Unique solution if A 0 2 6 0 (ii) Infinitely many solutions if A 0 3 Equations becames 3x 2 y and 3x 2 y 3 x 2 y 0 . Sec : Sr.Elite(C-120, C-IPL, IPL-IC) Page 4 Sri Chaitanya IIT Academy 15. 08-10-23_Sr.Elite(C-120, C-IPL, IPL-IC)_Jee Adv(2022-P2)_RPTA-08_Paper 2_Key & Sol's By definition A I 2 A2 A 2 A I 2 A 1 2 A. 2 16. i 1 j x 1 i Lt x 0 x j a11 a12 A a21 a22 a31 a32 a13 1 1 / 2 1 / 3 a23 2 1 2 / 3 a33 3 3 / 2 1 A2 3 A . 17. f(x)= 1 x x 1 2x 3x x 1 x x 1 x x 1 x 2 x 1 x x x 1 x 1 x 2 x 1 2 x 1 x 2 x x 1 x 1 2 x 1 x 1 3 x 2 x 1 1 1 2 x 1 1 3 x2 1 C2 C2 C1 x 2 x 1 x 1 2 1 2 x 1 0 3 x 1 f x 0 f 500 0 . 18. 4 as non zero solution A 0 p 1 1 1 q 1 0 1 1 r Put p=2, q=3 2 1 1 1 3 1 0 1 1 r 2 3r 1 1 r 1 1 1 3 0 6r 2 r 1 2 0 5r 3 r 3/5 1 1 1 1 1 1 1 5 1 =-1+2=1 1 p 1 q 1 r 1 2 1 3 1 3 / 5 2 2 Sec : Sr.Elite(C-120, C-IPL, IPL-IC) Page 5 Sri Chaitanya IIT Academy 19. 08-10-23_Sr.Elite(C-120, C-IPL, IPL-IC)_Jee Adv(2022-P2)_RPTA-08_Paper 2_Key & Sol's PHYSICS Shearing stress, F / A 10 N / m 6 2 Length of side, L=10cm=0.1m Shearing displacement, x 0.05cm 0.005 cm The modulus of rigidity is F FL A Ax x 106 0.1 2 108 N / m 2 tan L 0.005 20. Y FL / Ae 21. consider an element as shown in the figure. Stress in the element = Force xA g x g Area A Now, electric potential energy stored in the wire is dx 1 dU (stress) (strain) (volume) 2 x 1 stress . volume 2 Y 2 1 x g 1 2g2 A 2 dU . Adx . x dx 2 Y 2 Y 2 1 2g2 A 2 2 g 2 AL3 12 106 x dx 2 106 J 2 Y 0 6Y 6 Total electric potential energy= . 22. L Here, r1 30cm and r2 4cm . Since a saop bubble has two free surfaces, total surface area of the coalesced bubble= 2 4 r 2 8 r 2 Potential energy of the coalesced bubble, i.e. W 8 r 2T Similarly if W1 and W2 are the potential energies of the two given bubbles, W1 8 r12T and W2 r22T Since the total energy of the system is conserved. 8 r 2T 8 r12T 8 r22T or r 2 r12 r22 3 4 25 2 2 or r 5cm . Sec : Sr.Elite(C-120, C-IPL, IPL-IC) Page 6 Sri Chaitanya IIT Academy 23. 08-10-23_Sr.Elite(C-120, C-IPL, IPL-IC)_Jee Adv(2022-P2)_RPTA-08_Paper 2_Key & Sol's 4 4 R 3 r 3 K (Conservation of volume) 3 3 R=radius of bigger drop r=radius of smaller drop R3 r3 K U i S 4 R 2 U f KS 4 r 2 KS 4 r 2 S 4 R 2 103 4 S Kr 2 R 2 10 3 K 1/3 R 2 R 2 102 10a /3 1 100 10a /3 101 a 6 24. 4 4 R 3 n r 3 or R 3 nr 3 or R n1/3r 3 3 Or R 2n1/3mm v0 r 2 , v01 R 2 Now, v01 R 2 4n 2/3 32 2 or n 2/3 or n 2/3 4 v0 r 4 8 or n 43/2 64 or n=8 25. Mass of air entering in 1s is m b2v Change in momentum in 1s mv 0 b2 v 2 Thus, F b 2 v 2 Pressure due to this force is p F b2 v 2 v2 A b2 When this excess pressure equals to v2 4T , the bubble gets separated R 4T 4T R 2 R v So, 4 . Sec : Sr.Elite(C-120, C-IPL, IPL-IC) Page 7 Sri Chaitanya IIT Academy 08-10-23_Sr.Elite(C-120, C-IPL, IPL-IC)_Jee Adv(2022-P2)_RPTA-08_Paper 2_Key & Sol's 26. r 4 P1 2 r P2 P 1 8 8 I 8 2l P2 27. Conceptual 28. Conceptual 29. Conceptual 30. Conceptual 31. Conceptual 32. Conceptual 33. Taking g constant, work done in both cases is –mg (1000) since the max velocity of the 4 journey is attained at a height of 1km, and the second half journey is travelled by max velocity the time taken for second half journey will be less. 34. F F ' A dv mg sin dz Velocity gradient dv v dz h F mg sin v h F 300 35. m 10 2 3 102 10 10 or m 6 104 kg 6 104 103 g 0.6 g 36. A longer pipe offers a greater resistance to the flow of a viscous fluid than a shorter pipe does. The volume flow rate depends inversely on the length of the pipe. For a given pipe radius and pressure difference between the ends of the pipe, the volume flow rate is less in longer pipes. In this case the longer pipe is twice as long, so its volume flow rate QB is one-half that of QA . Sec : Sr.Elite(C-120, C-IPL, IPL-IC) Page 8 Sri Chaitanya IIT Academy 08-10-23_Sr.Elite(C-120, C-IPL, IPL-IC)_Jee Adv(2022-P2)_RPTA-08_Paper 2_Key & Sol's CHEMISTRY 37. Conceptual 38. From PV=nRT, total moles =0.6. Let C x H 8 be ‘a’ mole therefore moles of C x H12 0.6 a mole Mass of ‘c’ in ‘a’ mole of C x H 8 12axg . Mass of ‘c’ in 0.6 a mole of C x H12 12 0.6 a g . Therefore total mass of c in mixture = 41.4g and x=5. 39. U rms u12 N1 u22 N 2 U 2 N U 22 N 2 2 U rms 1 1 N1 N 2 N1 N 2 25 40. 4 72 422 5.4 u2 3 ms 1 10 6 v,n are constant T Pi Pf 109 Pf f Pi Pi Ti T f Ti 100 P increases P Pf Pi “1” pressure increases 9 Pi 100 Pf Pc 100 9 Pi 100 % X 9 1 100 Pi X=9. 41. mol.wt of aceylated M .wt of organic compound ACompound 42 No.of amino groups= 390 180 5. 42 42. a,d,e,f,g can form stable carbanion. 43. Two different amides give two different amines. 44. HOOC COOH D H CH 3 CH 3 CH 3 HOOC H H D CH 3 CH 3 45. Dehydration products of carboxylic acids. 46. Mechanism of HVZ reaction. Sec : Sr.Elite(C-120, C-IPL, IPL-IC) H H COOH CO2 D CH 3 Page 9 Sri Chaitanya IIT Academy 47. 08-10-23_Sr.Elite(C-120, C-IPL, IPL-IC)_Jee Adv(2022-P2)_RPTA-08_Paper 2_Key & Sol's Decarboxylation is facilitated by the presence of any carbonyl group at the position, including that of carboxyl group (or) ester. The mechanism followed through a cyclic, six members. Transition state involving rearrangement of 3e pairs gives the enol form of a carboxylic acid, which is tautomerised to the carboxylic acid. 3RT PMw 3 d . RT 1mole U rms Mw RT 2 48. KE 49. U mp U av U rms 2 RT M U mp 2 U mp 2 RT M 3 2 3 mv mp RT 4 2 50. r1 v m2 32 44 m2 / m1 1 x 27.3ml r2 v2 m1 x 32 Similarly volume of SO2 will be 22.62 ml . 51. Conceptual. 52. Rate of effusion= PA 2 RTm A=Area of cross section of orifice. 53. Conceptual 54. O O || || C Cl H NaOH OH C O HNO3 / H 2 SO4 HONO C O Sn / HCl NH 2a || O C O NO2 C O || O CaCl N 2 C l || O Sec : Sr.Elite(C-120, C-IPL, IPL-IC) Cl C O || O C Page 10