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材熱 HW5

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10701112859194442
THT ,¥¥HW5
I
,
Ps
=
f- ( FFL
-
A
.
=
f- ( Eph ( CET ( Eth
-
Cp
,
-
Tl
p
)
ves=¥¥¥ vet=¥¥;
.
÷i¥¥¥iE÷
(
=
T (
-
Ethnicity
.
I
=
2
(Ttip
rx
Cp #
.
V
VIT
-
-
.
#
P)
( Ff ) DP
dV=¥HpdTt
,
( Ff )
H
"
Va
up
-
t
v
( Yp )
=
,
-
=
-
,
(IIT )
Yap
-
-
p *
EIGIL 1¥71
-
-
.
,
Eft xtvldfph
=
( Eff Ptv LIFT )
-
.
,
,
H
3
H
Vp
-
VL
,
(a)
5=5
ds =L
Tds
LT
P)
.
Tdp
# Ipd Tt (
=
{ ¥4
Sgp
=
-
I
=
-
p
-
reversible process
Cpd T
=
DT
=
Kdp
at
#
constant
P
(ft
)p=¥
Va
lb )
ds
OS
'
DT
=
=
Cpln IT
,
i reversible
05=0
=
18
-
=
&
-
Vxdp
Val Pa
-
Pi )
adiabatic
cpln
-
VL ( Pz
-
Pi )
(1-100)×105 "ymy
.no/ex#g%aeyxl
n
TI
t
k-18m3m/oTexl
0
-bmI
m
I
x
2xi
o
-%eegx
dg
18
* In
Tf
=
295.54k
=
#
18×10-42×10
"
x
(
-
991×105
V
(IIT )
,
4-
tap )
EH 5- Elp
Yehia:
t
-
i
=
# " ¥4
'
.
#
'
Tds
EY ) p
Epp
c
It's valid for
.
LEAP
5
=
Cpd T for
Vd
=
P
constant
If
=
law
gas
any
other
or
under the condition of
only
'
Sgp
ideal
apply
: I don't
'
=
restrictions
P
constant
substance
.
and do the
S and reversible
.
,
#
la )
i
l ll
free expansion
i
'
{
A
V
=
'
.
.
TS
-
o
G
=
H
-
A
=
=
OH
=
A
=
OG
=
OU
=
OH
=
OG
o
o
=
OH
G
=
=
-
0
o
#
Tos
=
-
S
Rtn
=
O
-
#
OS
=
2
Rlm 2 t Rlnz
=
Rtn 8
#
RT In 8 #
(3)
o
A
O
=
=
OS
#
O
=
O #
#
(4)
OU
OA
=
=
OH
OG
=
=
O
-
#
05=2 Rlm
RT In
#
2 t
3
2 t
R Thr 4 #
TS
(2)
OU
U
o
Rlm 5-
=
Rlm
Rlm 2
=
Rtn
4
#
proof
(b)
free expansion
n'
'
OS
Rlm
-
(c)
-
Tos
oU=q/°W
Cv ( Tz
=
C
-
,
Rbnz #
=
oA=oG=
00=01-1--0 #
'
c
=
RTln2
#
adiabatic )
'
'
-
.
05=0
OA
Ti )
#
-
-
=
OH
Cp ( Tz
=
-
Ti )
#
OG
=
=
(d)
OU
OH
G W
-
Cpt
-
i' A. G
'
,
paths
"
-
×
desire
)
OU
ou
OH
-
-
cut
opt
Ti )
.
.
-
Til
,
6
Ti )
#
OH SOT
OH
-
S ( Ta
T1 )
-
#
oS=fEfIdT=¥dT=Cpln¥
into
#
state
the
2
Ti
,
→
Ta
isothermal
:
"
off
OU
=
-
-
OH
III ! ! !!:L:'m 't
'
n
#
( Tz
-
-
Ita
OA
OG
#
oS=fs8÷dT=fI¥dT
=aln¥
-
entropy )
dH=S8p=CpdT
#
adiabatic
i
path
-
S ( Tz
-
constant
,
( e)
-
50T (
-
-
OG
-
'
.
path l
y
Ti
functions of
are
we
-
Ti ) #
divide the process
'
c
( Tz
Cv
=
-
-
OU
l : adiabatic ) #
-
-
=
Ti ) Si
-
-
Tiki
ou
OH
-
-
Taos #
-
Taos
-
it
-
.
( Tz
-
Tiki
Ti ) Si
#
-
-
.
Ta
#
,
ills
DS
-_
SIT V)
,
=
Tds
( f.
=
-
f- ( ¥4
( ¥ )vdTt ( Itv) , DV
-
=Sqr=CvdT
{ ⇐h=l
u=
-
a,
Tds
=
f- ( IF )p
Credit
reversible process
Fie
,
)
at
constant
DV
V
#
(ft )
If
Taos
Taos
#
#
(2)
LT
5=5
.
P)
dS=l¥tpdT -11¥ dp
-
,
Tds
Sgp
=
{ ¥4
Tds
-
-
-
-
(
=
(3)
5- SIP V
.
-
p
Cpd T
-
-
reversible process
Cpd T
at
P
constant
(ft
)p=¥
Va
TVLDP #
)
(F) udptlftulpdv
Eph I # HIFI Exeat
dS=
Tds
cuffed Pt
=
DV #
-
{ (Fulp
7
-
-_
-
pl Ef )p=¥x¥
(
Tds
.
Tds
=
DV
Cud Tt
↳g=cuezdPtvdV
Tds
-
-
=
Cpd T
We
Tva dp
-
want
to
know the
T
A
Bi
→
B→
C
'
a
constant
T
constant
P
,
,
Vt
St
TT
ST
is: : : ::::i: : :
8
(
Tc
it .
TB )
>
..
.
.
Ps
=
-
Il # Is
.
A
=
-
f- ( Ft
,
ves=¥¥¥ verify
.
¥¥¥¥iE¥÷
=
=
h÷=
( Flux (Ttip
E
Cp
-
r#
-
Tl # he
# CITY
.
I
relationship of
Ty
T S
-
"
#
-
s
#
Ehs
IET
'
=
LET)
d
tf
v
-
I
-
¥1
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-
Ehs
=
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