DE ZG 631 Materials Technology and Testing Lecture 01(Introduction). BITS Pilani Pilani Campus Prof.P.Srinivasan. Mechanical Engineering Department Details of Presentation Introduction to Materials Science and Engineering. Types of Engineering materials, properties and Applications. Advanced Materials. DE ZG 631 Materials Technology and 9/22/2023 Testing 2 BITS Pilani, Pilani Campus Materials Science and Engineering Materials Science -The discipline of investigating the relationships that exist between the structures and properties of materials. Materials Engineering – The discipline of designing or engineering the structure of a material to produce a predetermined set of properties based on established structure-property correlation. BITS Pilani, Pilani Campus Historical Evolution of Materials Ages of “Man” we survive based on the materials we control – Stone Age – naturally occurring materials • Special rocks, skins, wood – Bronze Age • Casting and forging – Iron Age • High Temperature furnaces – Steel Age • High Strength Alloys – Non-Ferrous and Polymer Age • Aluminum, Titanium and Nickel (superalloys) – aerospace • Silicon – Information • Plastics and Composites – food preservation, housing, aerospace and higher speeds – Exotic Materials Age? • Nano-Material and bio-Materials – they are coming and then … BITS Pilani, Pilani Campus Basic Engineering Materials Metals: – Strong, ductile – high thermal & electrical conductivity – opaque, reflective. Polymers/plastics: Covalent bonding sharing of e’s – Soft, ductile, low strength, low density – thermal & electrical insulators – Optically translucent or transparent. Ceramics: ionic bonding (refractory) – compounds of metallic & nonmetallic elements (oxides, carbides, nitrides, sulfides) – Brittle, glassy, elastic – non-conducting (insulators) BITS Pilani, Pilani Campus BITS Pilani, Pilani Campus BITS Pilani, Pilani Campus BITS Pilani, Pilani Campus Examples of Metallic Materials. BITS Pilani, Pilani Campus Examples of Ceramic Materials. BITS Pilani, Pilani Campus Examples of Polymeric Materials. BITS Pilani, Pilani Campus 9/22/2023 DE ZG 631 Materials Technology and Testing 12 f03_01_pg6 BITS Pilani, Pilani Campus f04_01_pg6 BITS Pilani, Pilani Campus f05_01_pg7 BITS Pilani, Pilani Campus f06_01_pg7 BITS Pilani, Pilani Campus f07_01_pg8 BITS Pilani, Pilani Campus About structure of materials It relates to the arrangement of its internal components. Subatomic Structure Atomic Structure Crystal structure Microscopic Structure Macroscopic Structure BITS Pilani, Pilani Campus Structure of materials and influence BITS Pilani, Pilani Campus Four Major Components of Material Science and Engineering: – Structure of Materials – Properties of Materials – Processing of Materials – Performance of Materials BITS Pilani, Pilani Campus Structure, Processing, & Properties • Properties depend on structure ex: hardness vs structure of steel Hardness (BHN) (d) 600 500 400 (a) (b) 4m 300 200 30m (c) 30m 100 0.01 0.1 30m Data obtained from Figs. 10.21(a) and 10.23 with 4wt%C composition, and from Fig. 11.13 and associated discussion, Callister 6e. Micrographs adapted from (a) Fig. 10.10; (b) Fig. 9.27;(c) Fig. 10.24; and (d) Fig. 10.12, Callister 6e. 1 10 100 1000 Cooling Rate (C/s) • Processing can change structure ex: structure vs cooling rate of steel DE ZG 631 Materials Technology and 9/22/2023 Testing 2 21 BITS Pilani, Pilani Campus Materials of the Future Smart Materials – Able to sense the changes in their environment and respond to these changes in predetermined manner. Following materials used for actuators. – Shape Memory Alloy – Piezoelectric Ceramics – Magnetostrictive Materials – Electro-rheological/ Magnetorheological Fluids DE ZG 631 Materials Technology and 9/22/2023 Testing 22 BITS Pilani, Pilani Campus Continued.. Nanotechnology Top down approach Bottom up approach The study of properties of materials using bottom up approach is called Nanotechnology. “Nano” refers to the dimensions of the structural entities are on order of a nanometer (10-9m) as a rule less than 100 nanometers. DE ZG 631 Materials Technology and 9/22/2023 Testing 23 BITS Pilani, Pilani Campus Transportation Reducing the weight of the transportation vehicle. Increasing the Engine operation Condition. New High strength, low density material remain to be developed. Materials that have high temperature capabilities, for use in engine components. DE ZG 631 Materials Technology and 9/22/2023 Testing 24 BITS Pilani, Pilani Campus Continued.. To find new and economical source of energy and to use present resource more efficiently. Materials play significant role in these developments e.g.: Solar Cells. DE ZG 631 Materials Technology and 9/22/2023 Testing 25 BITS Pilani, Pilani Campus Maintaining the Environmental Quality Depends upon our ability to control air and water pollution. Need to improve the material processing and refinements so that they produce less environmental degradation. In some materials manufacturing process, toxic substances are produced and ecological impact of their disposal must be considered. DE ZG 631 Materials Technology and 9/22/2023 Testing 26 BITS Pilani, Pilani Campus Continued.. Materials derived from Nonrenewable resources. Includes Polymers (made from oil and some metals) These nonrenewable resources are gradually depleting which necessitates Discovery of additional reservoirs. Development of new and comparable material Increased recycling efforts and development of new recycling technology. DE ZG 631 Materials Technology and 9/22/2023 Testing 27 BITS Pilani, Pilani Campus The Materials Selection Process 1. Pick Application Determine required Properties Properties: mechanical, electrical, thermal, magnetic, optical, deteriorative. 2. Properties Identify candidate Material(s) Material: structure, composition. 3. Material Identify required Processing Processing: changes structure and overall shape ex: casting, sintering, vapor deposition, doping forming, joining, annealing. DE ZG 631 Materials Technology and 9/22/2023 Testing 3 28 BITS Pilani, Pilani Campus Six Important Properties Mechanical Electrical Thermal Magnetic Optical Deteriorative. BITS Pilani, Pilani Campus ELECTRICAL • Electrical Resistivity of Copper: 6 From Fig. 17.8 Callister’s Materials Science and Engineering Adapted Version. (Fig. 17.8 adapted from: J.O. Linde, Ann Physik 5, 219 (1932); and C.A. Wert and R.M. Thomson, Physics of Solids, 2nd edition, McGraw-Hill Company, New York, 1970.) (10-8 Ohm-m) Resistivity, r 5 4 3 2 1 0 -200 -100 0 T (°C) • Adding “impurity” atoms to Cu increases resistivity. • Deforming Cu increases resistivity. BITS Pilani, Pilani Campus THERMAL --Silica fiber insulation offers low heat conduction. From chapter-opening photograph, Chapter 19, Callister’s Materials Science and Engineering, Adapted Version. (Courtesy of Lockheed Missiles and Space Company, Inc.) • Thermal Conductivity of Copper: --It decreases when you add zinc! Thermal Conductivity (W/m-K) • Space Shuttle Tiles: Adapted from Fig. 19.4W, Callister 6e. (Courtesy of Lockheed Aerospace Ceramics Systems, Sunnyvale, CA) (Note: "W" denotes fig. is on CD-ROM.) 400 300 200 100 0 0 10 20 30 40 Composition (wt% Zinc) From Fig. 19.4 Callister’s Materials Science and Engineering, Adapted Version. (Fig. 19.4 is adapted from Metals Handbook: Properties and Selection: Nonferrous alloys and Pure Metals, Vol. 2, 9th ed., H. Baker, (Managing Editor), American Society for Metals, 1979, p. 315.) 100m BITS Pilani, Pilani Campus MAGNETIC • Magnetic Storage: Magnetic Permeability vs. Composition: --Adding 3 atomic % Si makes Fe a better recording medium! Magnetization --Recording medium is magnetized by recording head. • Fe+3%Si Fe Magnetic Field Fig. 18.23 Callister’s Materials Science and Engineering, Adapted Version. (Fig. 18.23 is from J.U. Lemke, MRS Bulletin, Vol. XV, No. 3, p. 31, 1990.) Adapted from C.R. Barrett, W.D. Nix, and A.S. Tetelman, The Principles of Engineering Materials, Fig. 1-7(a), p. 9, 1973. Electronically reproduced by permission of Pearson Education, Inc., Upper Saddle River, New Jersey. BITS Pilani, Pilani Campus OPTICAL • Transmittance: --Aluminum oxide may be transparent, translucent, or opaque depending on the material structure. single crystal polycrystal: low porosity polycrystal: high porosity Adapted from Fig. 1.2, Callister’s Materials Science and Engineering, Adapted Version. (Specimen preparation, P.A. Lessing; photo by S. Tanner.) BITS Pilani, Pilani Campus f02_01_pg4 BITS Pilani, Pilani Campus DETERIORATIVE • Stress & Saltwater... crack speed (m/s) --causes cracks! slows crack speed in salt water! • Heat treatment: 10 -8 “as-is” “held at 160ºC for 1 hr before testing” 10 -10 From chapter-opening photograph, Chapter 16 Callister’s Materials Science and Engineering, Adapted Version. (from Marine Corrosion, Causes, and Prevention, John Wiley and Sons, Inc., 1975.) Alloy 7178 tested in saturated aqueous NaCl solution at 23ºC increasing load Adapted from Fig. 11.20(b), R.W. Hertzberg, "Deformation and Fracture Mechanics of Engineering Materials" (4th ed.), p. 505, John Wiley and Sons, 1996. (Original source: Markus O. Speidel, Brown Boveri Co.) --material: 4 m 7150-T651 Al "alloy" (Zn,Cu,Mg,Zr) From Fig. 10.31, Callister’s Materials Science and Engineering, Adapted Version. (Fig. 10.31 provided courtesy of G.H. Narayanan and A.G. Miller, Boeing Commercial Airplane Company.) BITS Pilani, Pilani Campus The Materials Selection Process 1. Pick Application Determine required Properties Properties: mechanical, electrical, thermal, magnetic, optical, deteriorative. 2. Properties Identify candidate Material(s) Material: structure, composition. 3. Material Identify required Processing Processing: changes structure and overall shape ex: casting, sintering, vapor deposition, doping forming, joining, annealing. BITS Pilani, Pilani Campus SUMMARY Course Goals: • Use the right material for the job. • Understand the relation between properties, structure, and processing. • Recognize new design opportunities offered by materials selection. BITS Pilani, Pilani Campus