MATERIAL SCIENCE GROUP PROJECT Material Selection Lecturer: Mr. V. Buchanan Group Members: • Shannon Thompson ID#: 1905339 • Emorni White ID#: 2005398 • Kah-J Moss-Solomon ID#: 1901006 • Jaden Green ID#: 1802371 • Dominique Dawkins ID#: 1800693 Material Selection Material Science Group Assignment Table of Contents Objective ........................................................................................................................................ 4 Team Contribution ....................................................................................................................... 4 Format............................................................................................................................................ 4 Laptop Touch Screen .................................................................................................................... 5 Definition .................................................................................................................................... 5 History ........................................................................................................................................ 5 Uses of touchscreen laptops ...................................................................................................... 6 Materials .................................................................................................................................... 7 Manufacturing process ............................................................................................................. 7 Property- Control Methods ...................................................................................................... 9 Performance Criteria .............................................................................................................. 10 Razor Blades ................................................................................................................................ 11 Definition .................................................................................................................................. 11 History of The Razor Blade .................................................................................................... 11 Uses of Razor Blades ............................................................................................................... 12 Materials .................................................................................................................................. 12 Manufacturing Process ........................................................................................................... 13 Property-Control Methods ..................................................................................................... 14 Performance Criteria .............................................................................................................. 15 Air Bags........................................................................................................................................ 16 Description ............................................................................................................................... 16 Properties ................................................................................................................................. 16 Working principle of the air bag ........................................................................................... 17 Components ............................................................................................................................. 17 Manufacturing Process ........................................................................................................... 18 Contact Lens ................................................................................................................................ 19 Description ............................................................................................................................... 19 Materials .................................................................................................................................. 19 Manufacturing process ........................................................................................................... 19 Properties ................................................................................................................................. 20 Chemical Structure of Contact lenses ................................................................................... 20 1 Material Selection Material Science Group Assignment Flywheel ....................................................................................................................................... 21 Description and Use ................................................................................................................ 21 Material Selection and Properties ......................................................................................... 21 Manufacturing Process ........................................................................................................... 22 Performance Criteria .............................................................................................................. 22 Property Control Methods ..................................................................................................... 23 Golf Club Head ........................................................................................................................... 24 Overview .................................................................................................................................. 24 What is a golf club head?........................................................................................................ 24 Purpose of each part. .............................................................................................................. 25 The performance criteria and control. .................................................................................. 25 Why should these performance criteria be noted when creating a golf club head? ...... 25 The materials use to make the golf club head. ...................................................................... 25 The manufacturing processes ................................................................................................. 28 Step to step process to manufacture a golf club head. ..................................................... 28 Golf ball........................................................................................................................................ 33 Overview .................................................................................................................................. 33 What is a golf ball? .................................................................................................................. 33 Types of golf balls. ................................................................................................................... 34 The performance criteria and control. .................................................................................. 34 Why should these performance criteria be noted when creating a golf ball? ................ 34 The materials use to make the golf ball. ................................................................................ 35 The manufacturing processes. ................................................................................................ 35 Drying and Packaging............................................................................................................. 36 $1 Coin ......................................................................................................................................... 38 Application of Coins ................................................................................................................ 38 Performance Criteria .............................................................................................................. 38 Types of materials used........................................................................................................... 39 Manufacturing Processes: ...................................................................................................... 41 Property Control Method ....................................................................................................... 43 Airplane Wings............................................................................................................................ 44 Definition .................................................................................................................................. 45 2 Material Selection Material Science Group Assignment Description ............................................................................................................................... 45 Application of wings ................................................................................................................ 46 Performance Criteria .............................................................................................................. 46 Mechanical Properties ............................................................................................................ 46 Chemical Properties ................................................................................................................ 47 The type of materials used to make airplane wings: ............................................................ 48 Manufacturing Properties ...................................................................................................... 49 Property-control methods: ..................................................................................................... 50 Bulletproof Vest .......................................................................................................................... 51 Description and application ................................................................................................... 51 Materials .................................................................................................................................. 52 Manufacturing process ........................................................................................................... 53 Performance Criteria .............................................................................................................. 54 Property Control Method ....................................................................................................... 54 Cutlery Parts ............................................................................................................................... 55 Description and application ................................................................................................... 55 Materials .................................................................................................................................. 55 Manufacturing Process ........................................................................................................... 56 Performance Criteria .............................................................................................................. 57 Property control method ........................................................................................................ 58 References .................................................................................................................................... 59 3 Material Selection Material Science Group Assignment Objective This project has been a colossal amount of researching which resulted in an expansion of knowledge. The sole objective of this project was to apply what was taught in Material Science class to select 11 products (5 of these products were completely new to the researchers) and expound on several different areas. Team Contribution As a group, our individual contributions to the making of this assignment is as follows: • • • • • Shannon Thompson: Razor blades flywheel (partial) and laptop touch screen. Proofread, edit, and format Emorni White: Golf club head and golf balls Jaden: $1 coin and Airplane wings Kah-J Moss- Solomon: cutlery parts and bulletproof vest Dominique Dawkins: Contact lens, airbags, and flywheel (partial) Format This assignment has 6 known objects and 5 unknowns. Please see the below table which illustrates which item falls under which heading: KNOWN Razor Blade Golf Club $1 Coins Cutlery Parts Contact Lens Flywheel UNKNOWN Laptop touch Screen Golf Balls Airplane Wings Bulletproof Vests Airbags - 4 Material Selection Material Science Group Assignment Laptop Touch Screen Source: (Woodford, 2019) Definition It is hard to believe that just a few decades ago, touchscreen technology could only be found in science fiction books and film. These days, it is almost unfathomable how we once got through our daily tasks without a trusty tablet or smartphone nearby (Ion, 2013). A touchscreen in is just an ordinary LCD device that has an additional human-interface device (HID) that allows users to touch the screen to further interact with the RasPi in accordance with an underlying control/display program (Norris, 2016). Essentially, a laptop with touchscreen can be described as a regular laptop with the keyboard attached but the screen is enabled for touch (DelCor Staff, 2016). History The first touchscreen was invented in 1965 by Eric A. Johnson who worked at the Royal Radar Establishment in Malvern, England. His first article, "Touch display—a novel input/output device for computers" describes his work and features a diagram of the design. The invention is known as a capacitive touchscreen, which uses an insulator, in this case glass, coated with a transparent conductor, like indium tin oxide. The user's finger also acts as a conductor and disrupts the capacitance of the conducting layer. In more simple terms, touching the screen causes a change in the electric charge that the computer detects. Johnson patented his design in 1966, improved it in 1968, and wrote another article in the same year. At some point, it was adopted by British air traffic controllers and was used into the 1990s (Displays2Go, 2018). Although capacitive touchscreens were designed first, they were eclipsed in the early years of touch by resistive touchscreens. American inventor Dr. G. Samuel Hurst developed resistive touchscreens almost accidentally. Hurst and the research team had been working at the University of Kentucky. The university tried to file a patent on his behalf to protect this 5 Material Selection Material Science Group Assignment accidental invention from duplication, but its scientific origins made it seem like it was not that applicable outside the laboratory. Hurst, however, had other ideas. "I thought it might be useful for other things," he said in the article. In 1970, after he returned to work at the Oak Ridge National Laboratory (ORNL), Hurst began an after-hours experiment. In his basement, Hurst and nine friends from various other areas of expertise set out to refine what had been accidentally invented. The group called its fledgling venture "Elographics," and the team discovered that a touchscreen on a computer monitor made for an excellent method of interaction. All the screen needed was a conductive cover sheet to make contact with the sheet that contained the X- and Yaxis. Pressure on the cover sheet allowed voltage to flow between the X wires and the Y wires, which could be measured to indicate coordinates. This discovery helped found what we today refer to as resistive touch technology (because it responds purely to pressure rather than electrical conductivity, working with both a stylus and a finger). As a class of technology, resistive touchscreens tend to be very affordable to produce. Most devices and machines using this touch technology can be found in restaurants, factories, and hospitals because they are durable enough for these environments. Smartphone manufacturers have also used resistive touchscreens in the past, though their presence in the mobile space today tends to be confined to lower-end phones (Ion, 2013). Tech companies were starting to take notice of this new way to control computers. HewlettPackard was the first to release a product that put touchscreens in the hands of everyday users. HP made a name for itself in the 1960s and 70s for creating smaller and smaller computers to the point where it had made one of the first machines to be called a "personal computer", the 9100A. In 1983, Hewlett-Packard released the HP-150, also known as the HP Touchscreen. The included device used a new system for touch input, featuring a grid of infrared emitters and detectors in the monitor's bezel. When the infrared beams were interrupted, the HP-150 could locate where the user was touching the screen. However, the system had its faults: dust would get into the infrared holes and require vacuuming. The design was not ergonomic either, users would complain of muscle fatigue, or "Gorilla Arm" from keeping their arm outstretched and unsupported for long periods of time. This first foray into a consumer touchscreen device was not incredibly popular. When the HP Touchscreen II released in 1984, the touch screen was optional, and rarely added. Meanwhile, other touch technologies were being developed. Myron Krueger, an American computer artist developed the Video Place, a screen that could track a user's silhouette and movements. Multi-touch was also proven in 1982 at the University of Toronto by Nimish Mehta. This design also used a camera to identify where the user was touching the screen. The first multi-touch overlay was developed in 1984 by Bob Boie of Bell Labs, creating a true capacitive screen that could detect multiple points of contact (Displays2Go, 2018). Uses of touchscreen laptops Touchscreens really are everywhere. Homes, cars, restaurants, stores, planes, wherever—they fill our lives in spaces public and private (Ion, 2013). For people who use laptops with touchscreen displays, they mention that the touchscreen feature makes them more productive since it helps them accomplish tasks faster. Touchscreen models are very feasible for specific tasks, like taking notes and doing creative work from sketching to drawing. Navigating the display is made faster 6 Material Selection Material Science Group Assignment and more convenient just by using one finger or more. In addition, touchscreen models are aesthetically pleasing and have excellent colour accuracy and brightness, too. It is recommended for people who often work with colour. If you are a student or a creative, maybe touchscreen models are more your speed since it makes note-taking and arty activities faster to accomplish (Haden, 2020). Materials Laptop touchscreens can be made of glass or plastic. Acting like a keyboard, they use 2 layers of material. The first layer interacts with the second when pressed to form a circuit and send a command. Some touchscreens can only interact with point at a time. One example is a resistive touchscreen often made of polyester and bound to conductive glass separated by an insulated membrane. The circuit is connected when the polyester is pressed down on the glass. In another example a capacity screen has both layers of the screen conduct electricity. By touching the screen, the electrical field is altered. On advantage of these screens is that they can be pressed in more than one place and function. Infrared touch screens utilize a grid pattern of LED lights and a light detector photocell arranged on opposite sides of the screen. When touching the screen these lights are interrupted and a microchip calculates where this interruption is and creates the command based on the lights connected to that section of the screen. Surface acoustic wave using ultrasonic sounds that are generated at the edges of the screen which reflect across the screen back and forth. When touched the sound beam is interrupted and absorbed. The microchip in the screen figures out where on the screen is touched and initiates the command (Woodford, 2019). Manufacturing process The following is an excerpt of how touchscreens are made for the book Raspberry Pi® Electronics Projects for the Evil Genius (Norris, 2016) (https://www-accessengineeringlibrarycom.ezproxy.utech.edu.jm/content/book/9781259640582/chapter/chapter2) • Resistive Touchscreens: 7 Material Selection Material Science Group Assignment The touchscreen is made up of six layers, as you can see from the figure. The top layer is a protective flexible, clear-plastic layer, which is the one you press your fingertip or plastic stylus against. Immediately underneath the plastic overlay is the ITO X-layer. ITO is an acronym for "indium-tin-oxide," which is a mildly conductive metal alloy. The ITO layer is extremely thin and transparent. It can be thought of as a two-dimensional resistor that is used to detect the Xaxis touchpoint coordinate. I will discuss how this is accomplished after I introduce the remaining layers. Next follows a layer of nonconductive transparent dots that provide an air gap between the ITO X-layer and the ITO Y-layer, which is located immediately under the dot layer. The ITO Y-layer is made up of the same material as the X-layer, and it is used to detect the Yaxis touchpoint coordinate. A thin glass layer lies directly under the ITO Y-layer, and it provides a stable platform for all the layers above it. Finally, an LCD display with a backlight is positioned under all the layers just discussed. It should be noted that the LCD used in touchscreen design should be very quiet from an electrical noise perspective to minimize potential interference with the touch sensor elements. There are three flexible metalized traces printed on the X-axis ITO layer; two are vertical bus lines, and the third is a horizontal sense line. The left-hand bus line has +5 VDC applied to it from the touchscreen controller chip. The right-hand bus line is at ground or 0-VDC potential. These bus lines will cause a distributed current flow across the ITO layer because the ITO alloy acts more like a resistor than a perfect conductor. • Capacitive touchscreens The capacitive touchscreen functions in a somewhat similar fashion to the resistive version, but it uses a somewhat different layer structure. This touchscreen uses a glass top layer, which provides 100 percent clarity. The next layer is an ITO layer consisting of an array of closely spaced dots, which are one part of the capacitive sensing scheme. Following this layer is a pressure-sensitive adhesive (PSA) that closely couples the two ITO layers while providing an insulator between them. The next layer consists of more ITO dots, like the layer above. The two ITO layers make up a fine grid of micro capacitors, with the PSA layer acting as a dielectric. The display LCD is placed beneath the second ITO layer, completing the touchscreen assembly. 8 Material Selection Material Science Group Assignment The essence of touch sensing is that when a fingertip or appropriate stylus touches the top glass cover, it will slightly affect the capacitance of one or more of the micro capacitors beneath the touchpoint. The touch effect is not much, generally about a 4 to 5 percent change, but the touchscreen controller can detect this small change in capacitance. The touchscreen controller also uses individual wires to connect to each row and column of the micro capacitor array, and it will poll or sense these wires to detect the capacitors that have changed value as a result of the touch. Property- Control Methods • Resistive Touchscreens The ITO layer will deform when a fingertip or a plastic stylus is pressed onto the outermost poly layer. This deformation causes a slight disruption in current flow, which can be detected by the sense line as a voltage between 0 and 5 V. The deformed ITO layer acts as a virtual potentiometer in which the sense line is the virtual center tap (Norris, 2016). The sense line is connected to an analog-to-digital converter (ADC) within the touchscreen controller, and the digital equivalent to the sensed voltage is then sent to the RasPi for further processing. The ADC typically has either 10 or 12 bits of resolution depending on the size and resolution of the touchscreen sensor. However, you do not have to be concerned with the actual ADC bit resolution because that is already figured into the RasPi driver software. The Y-axis is essentially identical to the X-axis except that all the bus and sense lines are oriented 90° to those of the X-axis. The touchscreen controller will energize the Y-axis bus lines only milliseconds after completing the X-axis coordinate read operation. Obviously, the touchpoint is the same for the Y-axis as it is for the X-axis because the Y-axis ITO layer is directly under the X-axis, separated by the insulating dot layer (Norris, 2016). The touchscreen just described is also referred to as a four-wire touchscreen, as the number refers to the interconnecting wires between the ITO layers and the controller. Five- and eightwire resistive touchscreens are also available, as they offer improved accuracy and sensitivity (Norris, 2016). • Capacitive Touchscreen As you can imagine, this sensing scheme is quite stable and requires little to no recalibration once it is set up. There is, however, one issue regarding coordinate resolution. The problem is that placing a fingertip on the top glass screen will affect more than one or two micro capacitors, thus hindering accurate sensing of the desired touchpoint (Norris, 2016). The solution to this problem is to employ a technique known as projected capacitive sensing. This technique uses all the changed values of the micro capacitors in and around the touchpoint to determine the center of gravity of the touchpoint by a process of interpolation. Note that no physical changes were done to the ITO dots to implement this technique. It is all accomplished by software residing in the touchscreen controller (Norris, 2016). 9 Material Selection Material Science Group Assignment Performance Criteria Functionality: Interactive screens enhance the user’s experience by adding in tactile functionality and allowing the user to have more control over their device (Sirois, 2018). The touchscreen feature on laptops was developed primarily to make navigation easier and more convenient. Users get to perform plenty of tasks using this feature compared to trackpads and mouse devices. Launching applications and shifting between them is also made simpler (Haden, 2020). Appearance: Touchscreen laptops often come with excellent brightness and better colour accuracy, vibrancy and reproduction compared to standard ones. Most models with this feature also have displays with higher resolution. Touchscreen displays are glossy so they can respond to touch better than matte ones. Due to their excellent colour accuracy and brightness, lots of users who often work with colour choose touchscreen models (Haden, 2020). Insulator: Capacitive screens relies on electrical capacitance. In order for the consumer to not be shocked each time the device is used and to prevent wear on the conductive layer, an insulator (such as glass) is placed between two conductive layers (Poor, 2017). Ease of maintenance: A common problem associated with traditional laptops is keyboard failure. When crumbs, dirt or other debris falls into the laptop’s keyboard, it may prevent the keys from working properly. Since touchscreen laptops do not have keyboard, however, this is not an issue. With a touchscreen laptop, you can rest assured knowing that dirt or debris won’t affect its ability to register your input commands (Nelson-Miller Inc, 2019). 10 Material Selection Material Science Group Assignment Razor Blades Source: (Cadence Blades, n.d.) Definition When a person refers to razors, the first thing to come to mind is the item used to shave unwanted hairs from the body. While that is true, a more generalized definition according to the Cambridge Dictionary is that a razor blade is a thin flat piece of metal with a sharp edge for cutting (Cambridge Dictionary). For this experiment we will focus mainly on safety razors. A safety razor is a device used to remove hair from areas of the body where it is undesirable such as the face for men and the legs and underarm regions for women (How Products Are Made, n.d.). As safety razor usage has increased and become more popular, the available models and types of razor blades have also significantly increased (Fendrihan, 2014). History of The Razor Blade The razor took a long time to evolve to its present multifaceted use (Dibacco, 1992). During the last Ice Age, facial hair was considered dangerous since wet facial hair could freeze and cause frostbite. Early humans (according to cave painting and implements found) are believed to have been grooming their facial hair using seashells (like a pair of tweezers). This trend later developed to use of sharp and fine obsidian flakes and shards from clams and oysters. Subsequently, the agricultural revolution and metal age allowed for access to metalworking, tools for farming, and metal blades for shaving. Although unsafe, men and women were able to benefit significantly from the advent of these ages (Silva, 2019). The ancient Egyptians began the custom of shaving their beards and heads, which was eventually adopted by the Greeks and Romans around 330 B.C. This practice was advantageous for soldiers because it prevented enemies from grasping their hair in hand-to-hand combat. The unshaven, unkempt tribes they fought became known as barbarians, meaning the unbarbered (How Products Are Made, n.d.). In the 18th century, razor blades were finally made thin and sharp pieces of metal. Till this time, everybody presumed shaving could only be done by professionals 11 Material Selection Material Science Group Assignment and would employ daily barbers for the facial and personal grooming. French inventor JeanJacques Perret invented a safety razor by adding a wood guard to a regular blade thereby allowing men and women to shave without the help of a barber. The modern Sheffield razor is an evolved design version of this razor with a rotating guard. In 1880 the Kampfe brothers patented a design for the world’s first safety razors which had a wire guard along the edge and lathercatching head (Silva, 2019). Although numerous inventors tried to devise ways to keep the razor’s sharp edge from cutting the skin, it was King Camp Gillette, a Wisconsin-born salesman, who persevered in the quest for a safety appliance. But it was a long way from Gillette’s first efforts in 1895 to actual marketing of his gizmo in 1903. The problem was not the razor and its protective housing, which allowed only a small part of the double-edged blade to be exposed, thereby reducing the likelihood of cutting the skin. Rather, the challenge was to fashion a steel blade that was very thin, strong, inexpensive, --and safe. Still, the first year of marketing was a bummer for Gillette, who sold only 51 razors, at $5 each, and 168 blades. Three years later, however, word about Gillette’s bloodless means of shaving had spread, and about 300,000 razors and twice as many blades had been sold. For two decades Gillette, living up to his name, was king of the razor industry (Dibacco, 1992). Gillette manufactured carbon steel blades until 1960. These were rapidly rusting and required the user to change the blades frequently. In 1965, the British company Wilkinson Sword began selling stainless steel blades, which did not rust and could be used several times until they were blind. Wilkinson quickly dominated the British and European markets, and Gillette was forced to switch its production lines to stainless steel to compete. Today, almost all blades are stainless steel. Carbon steel blade is still available; Its modern version will not rust if it is washed in alcohol after each shave. Because Gillette holds the patent for stainless blades but did not act on them, the company was accused of exploiting customers by forcing them to buy rust-prone blades (Silva, 2019). Uses of Razor Blades Razors and razor blades have many uses, from personal hygiene to cutting a sewing stitch to opening a cardboard box sealed with heavy-duty tape (Dibacco, 1992). Common applications of razor blades would include to use it to deburr PVC conduit (Zoellner, 2017). If the PVC is cut and the edges are rough it can damage the insulation of the wires. To smoothen it out, running the blade along the inside of the conduit will do the trick. Other use of razor blades in the construction industry is where it is used to remove small imperfections from wood finishes (Pawlak, 2015) and scraping away paint overspray (Zoellner, 2017). Then there are razors that are used for shaving. Those types include disposable razors, electric razors, safety razors and many more (Centeno, n.d.). Razors have always been a necessity and are often called into service for a variety of tasks around the shop other than shaving (Pawlak, 2015). Materials Depending on which company that creates them, razor blades are made up of different compounds but all leading up to a form of steel alloy. Razor blades are periodically exposed to high levels of moisture and therefore must be made from a special corrosion resistant steel alloy 12 Material Selection Material Science Group Assignment (How Products Are Made, n.d.). So, the steel to be used must be a grade that is hard and malleable; allowing the blade to hold its shape and to be processed, respectively. The preferred type of steel is called carbide steel because it is made using a tungsten-carbon compound (How Products Are Made, n.d.). One patented combination of elements used in stainless steel blade construction includes carbon (0.45-0.55%), silicon (0.4-1%); manganese (0.5-1.0%); chromium (12-14%) and molybdenum (1.0-1.6%); with the remainder being iron (How Products Are Made, n.d.). The plastic portions of a safety razor include the handle and blade cartridge, or portions thereof, depending on the razor design. These parts are typically molded from several different plastic resins including polystyrene, polypropylene, and phenylene oxide-based resins as well as elastomeric compounds. These resins are taken in pellet form and are melted and molded into the razor components through a combination of extrusion and injection molding techniques. For example, in making the handle for their advanced shaving systems, Gillette uses a coextrusion process which simultaneously molds an elastomer molded over polypropylene to create a surface that is easy to grip (How Products Are Made, n.d.). Manufacturing Process The following explains the process in which the razor blade and its plastic housing are made. Source: (How Products Are Made, n.d.) • • • • 1. Cutting Blade Formation Blade manufacturing processes involve mixing and melting of the components in the steel. This mixture undergoes a process known as annealing, which makes the blades stronger. The steel is heated to temperatures of 1,967-2,048°F (1,075-1,120°C), then quenched in water to a temperature between -76- -112° F (-60- -80° C) to harden it. The next step is to temper the steel at a temperature of (482-752°F (250- 400°C). The blades are then die stamped at a rate of 800-1,200 strokes a minute to form the appropriate cutting-edge shape. The actual cutting edge of modern cartridge style razor blade is deceptively small. The entire cutting surface is only about 1.5 in (3.81cm) wide by 1 mm deep. This is compared to traditional razor blades which are almost 20 times wider and several times thicker. This design creates efficiencies in manufacturing by allowing the creation of a durable cutting surface using very little metal. Because the blade is so small, a special support structure is required to hold it inside the cartridge. 2. Support Member Formation At a separate workstation, another sheet of metal passes through a die and cutter device to form a series of L-shaped support members. These support members are formed in a line with two edge runners connected to each side. The row of supports, still connected to the edge runners is rolled onto a coil and transported to the next station. There the support pieces are severed from the edge runners which are collected in a waste bin. The support members are dropped into a funnel-like device equipped with a vibrating unit which deposits individual support members onto a conveyor belt. The belt transfers the members in a single file fashion the third workstation where they are welded onto the cutting blade. The finished blade 13 Material Selection • • • Material Science Group Assignment assembly is then ready for mounting in the cartridge. Because the entire process is automated, waste from broken or bent cutting blades and support members is minimized. 3. Plastic Component Molding Concurrent with the blade-making operations, the plastic components are molded and readied for assembly. The plastic resins are mixed with the plasticizers, colorants, antioxidants, stabilizers, and fillers. The powders are mixed and melted in a special heated screw feeder. The resultant mixture is cut into pellets which can be used in subsequent molding operations. Plastic razor parts are typically extrusion molded. In this process, molten plastic is shaped by being forced through the opening of a die. The parts can also be manufactured by injection molding, where plastic resin and other additives are mixed, melted, and injected into a two-piece mold under pressure. After the plastic has cooled, the mold is opened, and the plastic parts are ejected. Major manufacturers have extremely efficient molding operations with cycle times for molded plastic parts routinely below 10 seconds. These processes are so efficient that the thermoplastic runners and other scrap from the molding process are reground, remelted, and reused. 4. Assembly of Components The molded plastic components are fed to various workstations where the blade assembly is inserted into the cartridge. The work surfaces in these stations are equipped with vacuum lines to orient and hold the small blade parts in place during transport and insertion. Spring loaded arms push the blades into place and secure them in the cartridge slots. The finished cartridge may be attached to the razor handle during subsequent operations or they may be packaged separately. This step may include insertion of springs and other parts in the handle to allow ejection of the cartridge. Property-Control Methods Polished razor blades are separated into single pieces at this stage for the first time, then, they are bunched together and skewered. The back of the blade has the typical luster of stainless steel, but on the contrary, the sharp blade tip does not reflect the light and appears to be black. If the blade tips reflect light, it means that they do not have enough sharp angle and that they are defective products. Each razor blade is visually inspected in this way (Kai Industries Co. Ltd, n.d.). At the packaging stage, various sensors, put on the assembling machine and on the conveyor, check abnormalities, position of the resin parts, assembly precision and many other check items. In this way, high quality razors are completed (Kai Industries Co. Ltd, n.d.). All finished razor components must conform to tight specifications before they are released. For example, blades must meet a designated hardness rating and contain a certain amount of steel. Gillette blades must meet a standard knows as Vickers hardness of at least 620 and a carbide density of 10-45 particles per 100 square microns to avoid rejection. The equipment itself operates so precisely that Gillette measures its reject rate in parts per million. Similarly, molded plastic parts are closely inspected by operators with lighted magnifying glasses to check for loose flashing or rough edges; they alert technicians when problems are discovered. In addition, razor 14 Material Selection Material Science Group Assignment components are checked by a computerized vision system which compares a critical dimension to a reference (How Products Are Made, n.d.). Performance Criteria Availability: Razor blades are made from many companies, such as Gillette. They are also disposable brands as well as brands allowing for the razor to be removed and replaced. Corrosion resistance: Maximally sharpened blades are coated with hard metal film to make them difficult to be worn away. This coating has also the purpose to make blade tips difficult to rust (Kai Industries Co. Ltd, n.d.). Flexibility: Due to its thin shape, razors can handle an amount of bending. A razor cartridge including a razor blade having a bent portion can have certain advantages, such as decreased manufacturing costs and improved rinsability. This allows the user to be able to easily rinse cut hair and skin particles and other shaving debris from the razor cartridge and especially from between adjacent razor blades or razor blade structures (United States; The Gillette Company (Boston, MA, US) Patent No. 20160361828, 2016). Durability: Blades are additionally coated with fluorine resin, to allow them to move smoothly across the skin. Then, resin is heated and melted to form a film on the surfaces. This two-layer coating greatly improves the sharpness and the durability of razors (Kai Industries Co. Ltd, n.d.). 15 Material Selection Material Science Group Assignment Air Bags Description An airbag is a vehicle occupant restraint system using a bag designed to inflate extremely rapidly then quickly deflate during a collision. It consists of the airbag cushion, a flexible fabric bag, inflation module and impact sensor. The purpose of an airbag is to help the passenger in the car reduce their speed in collision without getting injured. An airbag provides a force over time. The more time the force must act on the passenger to slow them down, the less damage caused to the passenger. Properties High Tensile strength Good heat stability High Tear strength Low Air permeability Tensile strength is a measurement of the force required to pull something such as rope, wire, or a structural beam to the point where it breaks. The tensile strength of a material is the maximum amount of tensile stress that it can take before failure, for example breaking. As a result of breaking the air bag is pushed out to protect the passenger after impact. Thermal stability is the stability of a molecule at high temperatures, i.e. a molecule with more stability has more resistance to decomposition at high temperatures. Thermally stable means it will not break or disintegrate with change in temperature. Tear resistance (or tear strength) is a measure of how well a material can withstand the effects of tearing. The air permeability of a fabric is a measure of how well it allows the passage of air through it hence, the air bag requires a low one to reduce damage done to the passenger after impact. 16 Material Selection Material Science Group Assignment Working principle of the air bag For an airbag to be useful as protective device, the bag must deploy and inflate within the stipulated time. It takes only about 30-60 milliseconds to get activated at the event of collision. Airbags become energy-absorbing buffers between people and the hard-interior surfaces of vehicles. Normally air bags are hidden in the hub of the steering wheel or in the dash on the passenger’s side. Once the sensor has turned on the electrical circuit, a pallet of sodium azide (NaN3) is ignited, and a rapid reaction occurs, generating nitrogen gas. This gas fills a nylon or poly amide bag at a velocity of 150-230 miles per hour. For the air bag to cushion the head for maximum protection, the air bag must begin to deflate (decrease its interval pressure) by the time the body hits. Otherwise the high internal pressure of the airbag would create a surface as hard as stone – not the protective cushion. Reaction- (I) 2NaN3 = 2Na + 3N2 The sodium by product of this reaction, and the potassium nitrate generate additional N2, which also helps to fill airbag. Reaction-(ii) 10Na + 2KNO3 = K2O + 5Na2O + N2 This reaction leaves potassium oxide and sodium oxide to react with the 3-rd compound silicon dioxide, and forms alkaline silicate (“glass”), which is a safe and stable, unignitable compound. Reaction-(iii) K2O + Na2O + SiO2 = Alkaline silicate NaNO3 is very toxic in nature (0.2 mg/m3 is only allowed in workplace) is been converted to alkaline silicate. The Na metal, which is explosive in nature, is been converted to alkaline silicate using KNO3 and SiO2. Components Nylon 6,6 is the material of choice for airbags because Nylon offers various advantages in airbag application compared to other fibres. In general, the Nylon fibre exhibits high specific strength, abrasion resistance, and toughness or energy-absorption properties. The aging characteristics of Nylon are also very good (Keshav raj et al., 1996), which is important because airbags typically need to have a replacement period of at least 15 years (Sun and Barnes, 2010) Nylon fabric has a greater bi-axial elongation compared to other fabrics due to its lower stiffness. This is a major advantage because it provides a more uniform bi-axial stress distribution. (Keshav raj et al., 1996) Nylon is a synthetic polymer (man-made polymer) made up of repeating units which are linked by amide bonds. To make the repeating unit or the monomer, molecules with an acid (-COOH) group on each end are reacted with molecules containing amine (-NH2) groups on each end. The monomers are then reacted together to form long polymer chains. The resulting Nylon is named based on the number of carbon atoms donated by the monomers, the diamine first and the diacid 17 Material Selection Material Science Group Assignment second. So, for example, Nylon 6,6 refers to the diamine and the diacid donating 6 carbon atoms each to the polymer chain. Manufacturing Process Mostly used raw material for the airbag fabric is nylon 66 yarns in the deniers ranging from 420 to 840. The side impact airbags used 1880 D nylon-6.6. These fabrics are generally woven with the constriction of: • 840 X 840 D, 98 X 98 /dm plain weave, 60” width. • 420 X 420 D, 193 X 193 /dm plain weave, 60” width Commonly, the airbag made were coated by neoprene, but recently silicon coated, and uncoated varieties have become popular. Coated airbag is generally preferred for driver seats. The weight per unit length uncoated one is higher than coated bags, i.e. 244 to 257 Vs 175 g/m2. Usually Rapier with insertion rate of 400 m/min has been found most suitable for weaving airbags. Since, it can maintain warp tension with accuracy of 1 CN per warp. Methods of coating the substrates, comprises of water, continuous emulsion of a curable elastomeric polymer, and aqueous polyurethane dispersion, and an optional cure agent. The chemical structure of Nylon 6,6 is (C12H22N2O2)n. it comprises of two monomers hexamethylene diamine and adipic acid which gives nylon 6.6 its name. 18 Material Selection Material Science Group Assignment Contact Lens Description A contact lens is a thin, curved lens placed on the film of tears that covers the surface of your eye. The lens itself is naturally clear but is often given the slightest tinge of colour to make them easier for wearers to handle. Today's contact lenses are either hard or soft. Materials Soft lenses are made from gel-like, water-containing plastics called hydrogels. These lenses are very thin and pliable and conform to the front surface of the eye. Introduced in the early 1970s, hydrogel lenses made contact lens wear much more popular because they typically are immediately comfortable. The only alternative at the time was hard contact lenses made of PMMA plastic. Silicone hydrogel lenses are an advanced type of soft contact lenses that are more porous than regular hydrogel lenses and allow even more oxygen to reach the cornea. Introduced in 2002, silicone hydrogel contact lenses are now the most popular lenses prescribed in the United States. Manufacturing process Soft contacts are made of hydrophilic ("water-loving") plastic polymers called hydrogels. These materials can absorb water and become soft and pliable without losing their optical qualities. Soft contacts — including new highly oxygen-permeable varieties called silicone hydrogel lenses — can be made with either a lathe cutting process or an injection moulding process. Lathe cutting. In this process, non-hydrated disks (or "buttons") of soft contact lens material are individually mounted on spinning shafts and are shaped with computer-controlled precision cutting tools. After the front and back surfaces are shaped with the cutting tool, the lens is then removed from the lathe and hydrated to soften it. The finished lenses then undergo quality assurance testing. Injection moulding. In this process, the soft contact lens material is heated to a molten state and is then injected into computer-designed moulds under pressure. The lenses are then quickly cooled and removed from the moulds. The edges of the lenses are polished smooth, and the lenses are hydrated to soften them prior to undergoing quality assurance testing. 19 Material Selection Material Science Group Assignment Properties Some properties are: • • • Wettability Coefficient of friction Modulus The degree of wetting is determined by a balance between adhesive and cohesive forces acting on a lens surface. Contact lenses that can sustain complete wetting allow a thick coverage of the tear film, a smooth recovery of the tear layer after eye closure and good visual acuity. Wettability is determined by measuring the contact angle, the smaller the contact angle the greater the wettability. Contact angles can be classified as dynamic or static, advancing or receding. There are several methods that can be used to determine the contact angle: Wilhelm plate, captive bubble, and sessile drop. The property of modulus or "stiffness" is not something we used to think about with hydrogel lenses. It is relevant for silicone hydrogels as the addition of silicone often results in a lower amount of water in the lens; the combination and balance of these factors leading to silicone hydrogel lenses generally having a higher modulus than hydrogel materials. Modulus is a measure of how a material will deform and strain when put under pressure. Elastic or Young's modulus (E) is described as the ability of a lens material to align to the ocular surface and resist deformation under tension. The coefficient of friction (CoF) refers to how lubricious the surface of the contact lens is. It is sometimes referred to as lubricity and a lower CoF helps to give lenses a silky, smooth feel. It is quantitatively measured via micro tribometry. The set-up is designed to mimic on eye- eyelid interactions. Chemical Structure of Contact lenses The first polymer contact lenses became commonly available in the early 1960s and were made from a polymer called poly (methyl methacrylate) (PMMA). Lenses made of PMMA are called hard lenses. PMMA is still used in Plexiglas and Lucite, as well as for things like aquariums and ice hockey ring barriers. A different polymer was then made, poly (hydroxyethyl methacrylate) to create soft, flexible hydrogel lenses, which had the added advantage of being permeable to oxygen. These lenses were more comfortable, and as such could be worn for longer. 20 Material Selection Material Science Group Assignment Flywheel Description and Use A flywheel is a heavy wheel that is part of some engines. It regulates the engine's rotation, making it operate at a steady speed. A flywheel stores energy as it spins inside a casing. A flywheel that keeps an engine turning relies on its momentum to keep going, it is used to store rotational energy. Flywheels have an inertia called the moment of inertia and thus resist changes in rotational speed. For example, flywheels are used in reciprocating engines because the energy source, torque from the engine, is intermittent. Flywheels used in car engines are made of cast or nodular iron, steel or aluminium. Flywheels made from high-strength steel or composites have been proposed for use in vehicle energy storage and braking systems. If the hoop stress surpasses the tensile strength of the material, the flywheel will break apart. Material Selection and Properties For the fabrication of flywheel as per the priority five topmost material is Carbon steel 10657, Alloy steel AISI 43408, Maraging steel 18ni9, Alloy steel AISI E931010 and Stainless steel11. As per the decision makers, the following properties were chosen, they are Density, hardness, young’s modulus, bulk modulus, and Poisson’s ratio. Maraging steels are carbon free iron-nickel alloys with additions of cobalt, molybdenum, titanium and aluminium. The term maraging is derived from the strengthening mechanism, which is transforming the alloy to martensite with subsequent age hardening, Young's modulus is a measure of the ability of a material to withstand changes in length when under lengthwise tension or compression. Sometimes referred to as the modulus of elasticity, Young's modulus is equal to the longitudinal stress divided by the strain. Bulk’s Modulus is the relative change in the volume of a body produced by a unit compressive or tensile stress acting uniformly over its surface. 21 Material Selection Material Science Group Assignment Poisson’s Ratio is the ratio of the proportional decrease in a lateral measurement to the proportional increase in length in a sample of material that is elastically stretched. Manufacturing Process A flywheel is used primarily in manual transmissions. It is attached to the engine crankshaft and holds the ring-gear that is used to crank the engine. The wheel connects directly to the clutch, stores energy to move the vehicle from inertia, and provides a friction surface for the clutch to attach to. Because of this, these parts are usually cast, and are thick and heavy, to allow for the clutch’s surface. In addition, the heavy weight allows for more inertia once it is spinning. Flywheels are usually produced by the casting method, and for now, sand casting is the most common production process for flywheels. Depending on the application, the materials used are nodular iron, steel or aluminium. Once cast, the flywheel is finished by machining and boring. Next, a square or rectangular steel bar of a pre-set length is bent into a circle configuration and the ends welded together, with the major diameter larger than the finished gear size. The ring is then heated, and either stamped or bored to size on the minor diameter. Next, the gear teeth are hobbed onto the ring, and hardened to improve strength and resistance. Lastly, the ring is shrunk onto the flywheel (AmTech International, n.d.). Performance Criteria • High ductility • Low density • High yield strength • Corrosion resistance • High material index A material having high ductility have a clear change in its shape before it breaks or burst (flywheel burst like pressurize cylinder upon failure). This property will help us to replace the part before it causes any serious damage to machine but high ductility affect the working of flywheel in such a way that at very high rpm it start to lose its shape, affecting the working where flywheel is enclose inside a machine. Low density of a material allow you to have minimum mass under a given geometry, making your flywheel light weight, easy to carry and easy to assemble and disassemble but low less mass result is less kinetic energy of flywheel at given rpm which directly affect your output. High yield strength of a material enables him to restore its original shape after elastic deformation. It will help flywheel of resist the high rpm without being permanent deformed. Giving desire shape to a material required machining and for this good machinability is required. For long life material should be stable and should not react with surrounding atmosphere to form oxides. For this flywheel material should have good corrosion resistance. Material index is the most important property which shows material strength to density ratio enables us to select the best material (Green Mechanic, 2016). 22 Material Selection Material Science Group Assignment Property Control Methods 1. Production volume It is the number of pieces to be produce and it decide whether to use expandable mold or permanent mold and this factor also decide whether the organization should go for automation of the process or do it manually. If the volume is high the organization should go for automation to reduce the unit production time and cost but if the volume is small and design variation is high the organization should think of the integration of designing and manufacturing to have the fastest response to change in design of product. 2. Product Size Dimensions of the product is important for determine of the manufacturing process because of the factors associates with the size like mold size, amount of molten material, pouring rate, cooling rate and total solidification time. 3. Product shape features Product shape features defines the complexity involves in the manufacturing of the product for example irregular external shape and core for internal cavity can resist the flow of molten material. 4. Product Value Product value means the sensitivity of the function which it is going to perform. Product associated with human life security need more careful manufacturing. Sand casting which is most widely used manufacturing process was selected by manufacturer because of low production volume, small size, simple shape, and low product value. This can produce near net shape and can provide you desire mechanical properties using chillers or by careful design of mold V/A ratio. Sand use in this process can be reused again and again and waste material because of molding can be recycled making this process highly economical. Automation of sand casting can also be done to reduce the unit production time. Sand casting is a simple process but still there are some problems associated with it. 23 Material Selection Material Science Group Assignment Golf Club Head Overview In this chapter a vast amount of information will be unwrapped. Some of the information that can be anticipated are: • • • • Description of the golf club head and its usage. The performance criteria and control. The materials use to make the golf club head. The manufacturing processes. What is a golf club head? A golf club is used to strike the ball in the game of golf. The golf club consist of a long shaft with a grip on one end and a weighted head on the other. The head is positioned sideways at a sharp angle to the shaft, and the striking face of the head is graduated to give the ball a certain amount of upward flight. There are different classes of golf club to aid with different upward flight, with that said, a golf player is allotted to take a maximum of 14 golf clubs per match. These 14 variations of golf clubs differ in angle of projection, striking effect, the type of spin you want etc., some of these clubs are: • • • • • • • • Drivers Fairways Hybrids Iron 52° wedge 56° wedge 60° wedge Putters Although the golf club consist of different parts, the sole idea is to discuss a specific part, the golf club head. The golf club head is a vital part of the club, providing the platform to interact the golf ball. The golf club head also comprises of several parts. These parts are: • • • • • • • Hosel Ferrule Heel Face Sole Toe Crown Figure showing labelled golf club head. 24 Material Selection Material Science Group Assignment Purpose of each part. • Hosel- this is the entry point of the shaft into the head on any golf club. • Ferrule- the sleeve prevents the head of the club from slipping off the shaft. • Heel- this is where the club head is attached to the shaft. • Face- this is the part of the club head which interacts with the ball. • Sole- this is where the club rests on the ground in playing position. • Toe- far end of the club head (farthest from the hosel/neck/shaft). • Crown-is the part of the club that you see when you are in the address position, looking down. The performance criteria and control. In the production of practically everything, consideration of the materials to be used is important. Another important tip in production is performance criteria and control. Some key points in the production of golf club head are: • Biological and Chemical Factors of the Material- this has to do with whether the materials are biocompatible. • Mechanical Factors of the Material- this has to do with the mechanical properties of the material. • Aesthetic Factors of the Material- this has to do with the appearance of the material. Why should these performance criteria be noted when creating a golf club head? • Biological and chemical factors are important because chemicals are reactive, and this reactivity can either improve or lessen the performance of the golf club head. Personally speaking, I believe this is the most important criteria when selecting materials to make golf club head. Without the perfection of this criteria the success rate of production will be low. Lack of this criteria can create faulty productions which could be bad for the company. • Mechanical factor is another important factor to consider when making golf club heads. The golf club head has to possess a property of hardness (similar to the golf ball) to resist penetration, high fatigue strength which is a good factor in the durability of the material, high yield strength to resist permanent deformation, toughness and ductility (to some extent for design purposes). • Aesthetic Factors is key to rank up productions. People are attracted to beauty and unique in all aspects of life. So, this factor is a plus in the manufacturing of golf clubs. The materials use to make the golf club head. Golfers have many options available to them regarding club head materials. Availability of golf club head materials are: • Titanium. The use of titanium for golf clubs came from the technology used in the aerospace industry. The first golf clubs made from titanium date back to the early 1990’s and quickly became the material of choice for driver heads due to the high strength-to-weight ratio. Titanium is lighter 25 Material Selection Material Science Group Assignment than stainless steel and allows the designer to manufacturer a much larger club head that meets the weight specifications of a normal driver. The strength of the material has increased durability for even the strongest golfers in the world. There are many different titanium alloys (materials added to the raw titanium) to change both the weight and strengths requirements. With driver heads reaching the maximum volume of 460 cubic centimetres, the most common alloy is 6/4 Titanium, by which 90% of the material is titanium, 6% is aluminium and 4% is vanadium. There are many other alloys or grades of titanium (sometimes called Beta Titanium) such as 15-3-3-3, SP700, 10-2-3, etc. available to the club designer. If the higher grade of titanium is used, then it is normally for the face material only and not the entire head. The United States Golf Association (USGA) and the Royal and Ancient Golf Club of St. Andrews (R&A) – the two governing bodies in golf – established rules for how fast a ball can come off of the club face of a driver. Most manufacturers make drivers that go to this limit without exceeding it, so there really is no advantage of one material over another. Typically, smaller drivers (under 400cc) would utilize the higher cost beta titanium to increase how fast the ball comes off the face. But with clubs in the 460cc range, standard 6/4 titanium will be sufficient material for the maximum allowable ball speed. (Folely, n.d.) Titanium can also be used in other clubs, but normally you do not see it much for a couple of reasons. First, titanium is much more expensive than stainless steel used in fairway woods, hybrids, and irons. Second, the reason for titanium is for the strength and lightweight nature. If a fairway wood were made with titanium, it would normally be made much larger in size to achieve a normal weight. By doing so the head could become much taller and makes it effectively harder to hit off the fairway. The alternative is using a dense metal or affixing a heavier weight on the sole. The same can be said for titanium irons. However, you may have seen some irons with a titanium insert as a way of increasing the ball speed at impact verses an all stainless steel clubhead. • Stainless Steel. Stainless steel is the most used material in golf. The material is generally inexpensive and easy to cast into all the shapes that you see golf clubs made plus durable enough for everyday play. There are two main types of stainless steel used in golf club heads. One is 17-4 stainless steel (comprising of no more than 0.07% carbon, between 15% and 17% chromium, 4% nickel, 2.75% copper, and 75% iron and trace elements). 17-4 used primarily for metal woods, hybrids, and some irons. The other type of stainless steel is 431 (comprising of no more than 0.2% carbon, 1517% chromium, 1.25 – 2.5% nickel, and the remainder being iron and a few trace elements). This grade of stainless steel is used for irons and putters, but does have sufficient strength for fairway woods and hybrids. The majority of fairway woods today are manufactured from 17-4 stainless steel. Drivers can also be made of 17-4, but due to the high density of the material, the limit on size is approximately 250cc without the risk of cracking during normal play. Because golfers prefer larger, easier-to-hit drivers, virtually no drivers today are even manufactured from stainless steel. Investment cast irons can be made from either 431 or 17-4 grades. The 17-4 is slightly 26 Material Selection Material Science Group Assignment harder of the two. This allows the 431 to be adjusted for loft or lie a little more easily, but other than that, there is no one greater advantage of one verse the other. • Specialty Stainless Steel (Maraging Steel). In addition to the number of materials used in golf club head manufacturing is maraging steel, which is an alloy or family of steel with unique properties. Typically maraging steels are harder than non-maraging steels like 431 or 17-4 and used primarily for face inserts rather than the whole head. A driver head can be produced wholly from maraging steel, but there is still a limit on the size of the head (roughly in the low-300cc range). Plus, the cost of the head would not be that much less expensive than one made from titanium. Since the maraging steels are harder, the face insert can be made thinner than the normal stainless steel graded used in golf. As a result, the ball coming off the face will have a slightly high ball velocity upon impact. Maraging steels are more expensive to produce, therefore would be more in the premium price range, which is the trade-off for the higher performance. • Aluminium. Aluminium is a much lighter material than stainless steel. Early metal woods made from aluminium back in 1970’s and 80’s was not very strong or durable. This caused these low-cost club heads to gain a bad reputation for easily scratching and denting that still carries over today. However, the aluminium alloys today are much better than those used in the past and the head sized can be made to the maximum size for drivers (460cc) under the Rules of Golf or even larger. Heads manufactured from aluminium are much lower in cost than even stainless steel, which makes these clubs more affordable and ideal for woods of starter sets or junior sets. The only downside to the aluminium is that the walls must be made thicker as not to crack or cave in. Therefore, the ball speed coming off the face would be less than a comparable titanium driver. • Carbon Steel. Carbon graphite is an extremely lightweight material and can be used to create a wood (usually with some sort of metallic soleplate for durability and additional weight). Few clubs today are produced primarily from carbon graphite; however, there are a number that incorporate the carbon graphite material in the design. Carbon graphite is less dense than any other material used in golf and a perfect choice to replace the top shell (or crown or top of the head). The weight savings from incorporating the carbon graphite in the crown, allows additional weight to be repositioned elsewhere in the heads to improve the design. Heads made from or partially from carbon graphite demand a premium price and can be found, not only in drivers, but fairway woods and hybrids as well. Used in either irons, wedges or putters, carbon steel has been used in golf clubs for centuries. Most will associate carbon steel irons and wedges to be forged, as this was the primary method of fabricating these clubs. However, certain alloys of carbon steel can be cast as well (8620 carbon steel) to produce a club head. Regardless, carbon steel is a soft, malleable material that will rust without some sort of protective chrome finish. 27 Material Selection Material Science Group Assignment More skilled golfers tend to gravitate toward models made of carbon steel as some say that can tell a difference in the feel of the material verses the harder stainless steel. More importantly, head made of softer, carbon steel tend to be less of a game improvement design and are tended more for the lower handicapped golfer. Some of which are intentionally un-chromed to rust through normal use. The idea behind the unplated carbon steel wedges is softer feel and supposable greater spin. Irons, wedges, and putters produced from carbon steel will be more expensive than stainless steel. • Zinc. Heads produced from zinc are the least expensive of all the materials. Used mostly for irons, wedges and putters in both starter sets and junior sets, zinc heads are less durable than their stainless steel counterparts. Zinc heads can be identified by their non-magnetic properties and their larger-than-normal hosel diameters. • Wood. Wooden woods are rarely found as a club head material option anymore as it has lost favour amongst golfers to titanium drivers and stainless fairway woods. The manufacturing processes Creating a golf club head is a crucial process. There are several manufacturing processes that could be used to create the golf club head: sand casting, blow moulding, investment casting, etc. However, I chose the process of casting. • What is casting? Casting is a manufacturing process in which a liquid material is usually poured into a mold, which contains a hollow cavity of the desired shape, and then allowed to solidify. The solidified part is also known as a casting, which is ejected or broken out of the mold to complete the process. Casting materials are usually metals or various time setting materials that cure after mixing two or more components together. Step to step process to manufacture a golf club head. Before a golf club is put into production, it is designed on a computer using sophisticated CAD software. The computer design is used as the basis for the development of a proprietary mold. Once a mold has been produced it is used in the production of every club head. The figure above is showing a mirrored mold of the golf club head. The mold has two parts to it and has a small opening on the side. 28 Material Selection Material Science Group Assignment (Image showing wax injection moulding machine). The mold is inserted into a wax injection moulding machine and boiling hot wax is squirted into the mold. The outcome is a golf club head that is made of wax. A wax mold is made for every piece that is manufactured. For example, a set of 9 irons will require 9 wax moulds, each representing a different loft. The wax moulds are then checked individually for minor blemishes and a fine nail file is used to remove excess wax particles that might be present on the mold. This is important as any imperfections on the wax mold will be present in the production club head. Again, this takes place manually, and each club head piece is subject to this process. The wax club heads are then melted onto a wax tree in groups of 14 and dipped into quicksand. 29 Material Selection Material Science Group Assignment The quicksand adheres to the wax and forms a shell around the outskirts of the mold. The tree is left to dry in a refrigerated room and this process is repeated five times. Quicksand is used because it can withstand the extreme temperatures required when pouring the molten iron and because of its ability to form a perfectly smooth shell around the intricate details of the wax club head. Once the fifth round of quicksand has dried, the tree is inserted into a steam oven. The steam heats up the wax and it melts out from the inside of the quicksand tree. The top of the quicksand tree is shaped liked a funnel making it easy to pour the molten iron into the quicksand shell. The quicksand moulds are transported to a furnace. A stainless-steel alloy is heated up to 1500° Celsius at which point it becomes molten liquid and glows red hot. 30 Material Selection Material Science Group Assignment Once the metal is molten and the quicksand is the same temperature, the quicksand moulds are removed from the furnace and walked across to the pouring station where the molten steel is poured into the quicksand mold. The red-hot quicksand moulds containing the molten metal are placed on a shelf of sand and left to harden. Once the steel has hardened, the quicksand outer shell is cracked off the iron moulds and the unpolished golf heads are exposed. At this stage, the club heads are still connected to the tree. 31 Material Selection Material Science Group Assignment The club heads are individually cut off the tree by a metal cutter and the finishing process begins from a head. The finishing process is a long process. It begins by polishing the club head and sandblasting the face. Once the club has been polished and sand blasted, it goes through a quality assurance process where the loft, lie, weight, hosel diameter and variance measurements are tested to ensure they fall within the strict tolerances set by the manufacturer of the clubs and by the R&A. The club heads are then trucked to a different location where skilled workers paint the logos and score lines onto the club head. The logos are a part of the original mold however they must be coloured in before they are ready to be sold and used. 32 Material Selection Material Science Group Assignment Golf ball Overview In this chapter a vast amount of information will be unwrapped. Some of the information that can be anticipated are: • • • • Description of the golf ball and its usage. The performance criteria and control. The materials use to make the golf ball. The manufacturing processes. What is a golf ball? A golf ball is a special ball designed to be used in the game of golf. Under the rules of golf, a golf ball has a mass no more than 1.620 oz (45.93 grams), has a diameter not less than 1.680 in (42.67 mm), and performs within specified velocity, distance, and symmetry limits. Like golf clubs, golf balls are subject to testing and approval by the R&A. The first golf ball similar in size to today's came into existence around five or six hundred years ago, when the Dutchmen stuffed feathers into a 1.5 in (3.75 cm) leather pouch. The golf ball is composed of a cover and core. 33 Material Selection Material Science Group Assignment Types of golf balls. There are three types of golf balls, they are: • • • Two-piece- have a hard cover and solid inner core, they are created for distance and durability. These types of balls are good for beginners as it can hold up to being hit into the trees or hazards. Multi-layered- possesses a liquid or solid core with a moulded rubber outer core. Its cover is softer and designed for higher spin rates. The softer feel and high spin allow the intermediate golfer more control and better stopping power. These balls are more expensive and not as durable as the two-piece ball. High-performance- combines a high-spin capability and distance for the low-handicap golfer. These balls are not durable and are quite costly. (Scott, 2017) The performance criteria and control. There are many factors that designers should consider when choosing a material including the desired properties for the application and the available materials. By fully understanding the materials, designers can then make well-informed choices. The following must be taken into consideration when making golf balls: • Biological and Chemical Factors of the Material- this has to do with whether the materials are biocompatible. • Mechanical Factors of the Material- this has to do with the mechanical properties of the material. • Aesthetic Factors of the Material- this has to do with the appearance of the material. • Surface Finish • Durability • Appearance • Friction • Weight Why should these performance criteria be noted when creating a golf ball? • Biological and chemical factors are important because chemicals are reactive, and this reactivity can either improve or lessen the performance of the golf balls. Personally speaking, I believe this is the most important criteria when selecting materials to make golf ball. Without the perfection of this criteria the success rate of production will be low. Lack of this criteria can create faulty productions which could be bad for the company. • Mechanical factor is another important factor to consider when making golf ball. The golf ball must possess a property of hardness to resist penetration, high fatigue strength which is a good factor in the durability of the material, high yield strength to resist permanent deformation, toughness, and ductility. 34 Material Selection Material Science Group Assignment • Aesthetic Factors is key to rank up productions. People are attracted to beauty and • • unique in all aspects of life. So, this factor is a plus in the manufacturing of golf balls. Weight is a prime factor in the game of golf. Lighter balls will produce less gravitational pull. Appearance- this factor is not much of a big deal, however, can be useful if a golfer has difficulty seeing the colour white. The materials use to make the golf ball. Golf ball makers use different levels of firmness and different materials in both the core and cover of the ball to appeal to a wide audience. Modern golf ball covers are typically made of surlyn, urethane or elastomer. • Surlyn Surlyn is a material made from ionomer resin that was created by the brand DuPont. Since the mid-1960s, surlyn has been used on the outer shells of golf balls. The build is hard and synthetic material that is the cheapest and most durable of the three. It is usually found in the covers of two-piece golf balls. It provides low spin when hitting tee shots. Most Surlyn golf balls are hard two-piece balls. They usually have less control. • Urethane Urethane is a soft, synthetic material with higher-spin characteristics because the club face can "grab" the ball for slightly longer. Urethane covers are used mostly on multi-layered balls. • Elastomer Elastomer is the softest and most expensive choice of cover. This less-durable material covers many of the premium high-performance balls. (Rose, n.d.) The manufacturing processes. The manufacturing process of the golf ball can be difficult and time consuming. Golf balls can require more than 80 different manufacturing steps and 32 inspections, taking up to 30 days to make one ball. Two-piece balls require about half of these steps and can be produced in as little as one day. The common steps are: • Forming the Centre. 35 Material Selection Material Science Group Assignment The centre of the two-piece ball is a moulded core. It is a blend of several different ingredients, all of which are chemically reactive to give a rubber type compound. After heat and pressure is applied, a core of about 1.5 inches (3.75 cm) is formed. • Forming the cover and dimples. Injection moulding or compression moulding is used to form the cover and dimples on a two-piece ball using a two-piece mold. In injection moulding, the core is centred within a mold cavity by pins, and molten thermoplastic is injected into the dimpled cavity surrounding the core. Heat and pressure cause the cover material to flow to join with the centre forming the dimpled shape and size of the finished ball. As the plastic cools and hardens, the pins are retracted, and the finished balls are removed. With compression moulding, the cover is first injection moulded into two hollow hemispheres. These are positioned around the core, heated, and then pressed together, using a mold which fuses the cover to the core and forms the dimples. Three-piece balls are all compression moulded since the hot plastic flowing through would distort and probably cause breaks in the rubber threads. • Polishing, painting, and final coating. Rough spots and the seam on the moulded cover are removed. Two coats of paint are applied to the ball. Each ball sits on two posts, which spins so that the paint is applied uniformly. Spray guns that are automatically controlled are used to apply the paint. Next, the ball is stamped with the logo. The final step is the application of a clear coat for high sheen and scuff resistance. (Bodamer, n.d.) Drying and Packaging. 36 Material Selection Material Science Group Assignment After the paint is applied, the balls are loaded into containers and placed in large dryers. After drying, the balls are ready for packaging in boxes and other containers. 37 Material Selection Material Science Group Assignment $1 Coin The Jamaican $1 dollar coin is small circular shiny (silver) nickel-plated steel with a national hero on one side and the Jamaican coat of arm on the other. It has been the replacement for the former demonetized cupronickel $1 coin. It has been the monetary value of use from 1990 to present and changed shape over the years from a hexagonal shape to the present form. Application of Coins: Apart from the monetary use of coin, there are a wide variety of household uses that a coin brings with it due to its various properties. • Use a medium for the exchange of goods and services. • To tighten screws • To operate machines such as phone booth • Used to test tire tread Performance Criteria Mechanical Properties: • • • • • • High tensile strength very good young modulus good shear modulus (the ratio of shear stress to shear strain) Ductility is quite good Very good elastic limit Ability to withstand high temperatures and pressures 38 Material Selection Material Science Group Assignment While it is that the steel is plated with nickel most of the mechanical properties are contributed by the steel. The above stated mechanical properties are very important to produce coin as the strong tensile strength and shear modulus etc. are needed to withstand pressures of high magnitude. For example, several times coins are running over by cars and trucks. When this happens, the coin remains in its original shape. This helps with the number of coins be used replaced yearly. Electrical Properties: Commercially pure nickel has high electrical conductivity, however nickel-plated steel is commercially pure nickel has low electrical conductivity. This is very important for the products that nickel-plated steel are used to make because for example where it is used to make gas chambers, conducting an electric charge might cause a fire which is very hazardous. Chemical Properties: Nickel-plated steel is used for their outstanding corrosion and high temperature resistance. It is also known for its outstanding high temperature strength and oxidation resistance. In essence, it is the presence of the nickel that gives the nickel-plated steel great corrosion resistance. This property is very important for the products made such as the one-dollar coin as it gives the coin a long-life span without corroding in rain wind etc. Physical Properties: • • • • • • • Silvery look due to nickel plating flat circular shaped Weight 2.9g Dimension 18.5 × 18.5 mm Steel alloy density ranges 7.75 and 8.05 g/cm3 Melting Point ranges from 1430-1510oC Magnetic The physical properties are crucial to the coin as it helps with identity of the money and being light weight makes it easy to carry around. Types of materials used While in most cases steel is the main constituent of coins made there are different types of materials that can be used to make the $1 coin: • copper-nickel (Cupronickel)- Monel 400 (N04400) Composition: Minor additions of aluminum and titanium to the nickel-copper matrix. 39 Material Selection Material Science Group Assignment Structure: ordered CuNi (CN)4 sheets with copper(ii) in a square-planar environment • Copper-plated steel - Composition: 0.35% carbon 3.5% nickel 0.2% Silicon 0.54% Manganese 0.16% Phosphorus 98.7% Iron 40 Material Selection • Material Science Group Assignment Nickel-plated steel- Diagram showing the structure of Nickel-Steel alloy Manufacturing Processes: To make Nickle-steel Alloys manufacturers start with the purest available raw materials to achieve the required chemical composition. The alloys are then Melted, Hot-Rolled and Processed to final sizes using state-of-the-art technology. Raw Material • Only virgin materials used in melting for all alloys. • Nickel is sourced from reputable international suppliers. • All other metals sourced from high-quality suppliers. • Most of the metals used are pure/electrolytic grade to ensure highest purity levels. Melting • Completely integrated manufacturing facility; starting from the melting stage. • Melting performed in modern electric furnaces. • Capacity to melt in different batch sizes- big and small. • Special techniques to control impurities and inclusions. • Unique processing technique ensures consistency and high surface quality. Hot Rolling • Ingots pre-heated (red hot) and then hot-rolled on a high-speed rolling mill. • Ingots hot rolled to rods or strip form. • Assignment of roll-passes for different alloys. • Rolling carried out at high speeds to prevent high temperature oxidation of materials. 41 Material Selection Material Science Group Assignment Wire Drawing • Heavy gauge wire drawn to size on modern high-speed drawing blocks. • Wet drawing for wire sizes below 2 mm. • Over 60 different types of wet wire drawing machines available based upon wire diameter and alloy. • Diamond dies used to obtain bright and smooth surface quality. • Super fine wires up to diameters 0.05 mm also produced for special applications. Annealing • In-house batch annealing and continuous annealing furnaces • Hot-rolled material subjected to batch annealing in controlled atmosphere furnaces. • Annealed material thoroughly cleaned and coated with a suitable lubricant. • Continuous annealing for intermediate and fine size wire for desired surface finish. • JLC has over 15 continuous annealing furnaces designed to anneal various Ni alloys. • All furnaces have inert atmosphere to give bright annealed wires. Testing & Packing • All alloys produced undergo several stages of quality control for strict adherence to specifications. • In-house, well-equipped physical and chemical testing lab supports the production. • Well-equipped packaging department to ensure that all material is shipped defect-free and safely packaged. • Treated and IPPC marked wooden boxes. • Standard spools used as per DIN standards. Drum/pail packing is also available. • Thicker wires supplied in coils on pellets. • Specialized packaging in other forms provided as per the customer requirement. Alloy steel is a mixture of iron ore, chromium, silicon, nickel, carbon, and manganese, and it is one of the most versatile metals around. There are 57 types of alloy steel, each with properties based on the percentage amount of each element mixed into the alloy. Since the 1960s, electric furnaces and basic oxygen furnaces have been the standard forms of industrial alloy steel production, while other methods have become outdated. The technology of steel production and the quality of output have advanced, but the actual steps to manufacturing alloy steel have not changed and are rather simple to understand. Melt the base alloys in an electric furnace at 3,000 degrees Fahrenheit for 8 to 12 hours. Then anneal the molten steel by rapidly cooling and heating it in a controlled sequence. Dip the steel in a bath of hydrofluoric acid. The dip removes the buildup of mill scale caused by annealing. Mill scale is an iron oxide that peels from the surface of hot steel when it is air-cooled. Anneal and descale the steel one more time. Pour the molten unfinished steel into casts, blooms, billets, and slabs. Blooms are long rectangular bars; billets are round or square ingots; and slabs are long, thick sheets. Cast the 42 Material Selection Material Science Group Assignment blooms, billets, and slabs by pouring them into molds and allow them to cool for four hours. Roll the blooms, billets, and slabs through heated rollers to shear off the ends as scrap and to burn away surface defects. Each rolling method brings the steel closer to the final product. Use a series of grinders and abrasive rollers for a reflective finish. Property Control Method The steel constituent coin was plated with nickel to prevent erosion as nickel has a very high corrosion resistance. In addition, it is an alloy of several elements, which adds to its mechanical and physical properties. Being the multi-phase metal that it is, it is hardened by annealing which is stated in the manufacturing process. 43 Material Selection Material Science Group Assignment Airplane Wings 44 Material Selection Material Science Group Assignment Definition A wing is a thin and linear section of the plane found on both sides of the fuselage (main part of a plane) that produces lift and helps with the maneuvering of the plane through air and fluids. Description The structural make-up of the airplane wings is that they are held together and supported by metal spars, ribs, and stringers. While the covering of the plane is made of either fabric (such as carbon fibers), aluminum, or composite material shell. Wing is a rectangular finned shape structure which changes shape based on the changes of the flaps and ailerons. The wing consists of two edges: the leading edge and the trailing edge. The trailing edge consist of the spoilers and the ailerons which changes the shape of the wing throughout the different journeys of the flight. Ailerons are found near the tips of wings' trailing edges. They are rectangular-shaped airfoils that rise to disturb the airflow over the wing. Ailerons are used to turn the airplane by creating more lift on one wing than the other. Flaps are smaller airfoils found on the rear parts of the wings nearest to the fuselage. Flaps can be extended to increase the wing surface area, creating more lift for takeoff and landing. However while it is customary to have planes with wings that are linear and straight, there are wings that have edges with curved or vertical tips called winglets which reduce drag and enable the wings to produce lift more efficiently. (Bowler, 2014) 45 Material Selection Material Science Group Assignment Application of wings The wing is composed of different structures, which all play a part in the different aircraft phase whether it is take-off, landing, de-icing etc. Due to its long and slender shape, it is used to reduce drag and create lifts at a faster rate. While the main purpose of the wing is to create efficiency in climbing, rotating, descending, and cruising. It is also important to note that the carbon fibre covering that are used in most planes are used to gain aerodynamic performance and hold the engines that provide the power. In addition to the information stated, the wings are equipped with deicing system being the bleed air valve system, which allows hot air to travel along the leading edges, which warms up melting the ice accumulated. On the other hand, there are deicing boot system for which are inflatable rubber attached to the leading edge. As ice builds up along the wing, the boot inflates breaking up the ice formed. (Bowler, 2014) Performance Criteria The selection of the material used in the production of the airplane wing is one of the most crucial parts in its production. This is because the performance criteria are very much relatable to the operational requirement of the product and not just the material. However, it is important to note that it is the material, which contributes to the performance criteria. While it is that airplanes wings are covered with aluminum or carbon fiber this piece will be focusing on carbon fiber material which makes up the wing of the airplane. Carbon fibers are made of long carbon crystals aligned in a long axis with aromatic molecular bonds. It began to be the choice of material due to its mechanical, physical, electrical, and chemical properties. Mechanical Properties Mechanical Properties looks at the reaction or the physical properties that a material exhibits when placed under stress or when a force is applied. e.g. Fatigue limit, tensile strength, or modulus of elasticity. Carbon fibers has very good resistance to fatigue due to its carbon fiber 46 Material Selection Material Science Group Assignment composites, while damage to carbon fiber is seen as decrease in its stiffness. In addition to this, carbon fiber is well known for its high tensile strength or ultimate strength. Tensile strength is ultimate stress that a material can undergo just before it breaks or necks (which is when the cross-sectional area starts to contract which is measured in force per unit area- pressure). This property is very important regarding the production of the wing because the wing undergoes high speed with a great amount air resistance. It also important to mention that the wing stores the fuel load and hold the engines attached to it. With these loads being added to the wing then the high tensile strength becomes a necessity to withstand the loads without breaking. Stated below are some mechanical properties shown with their respective measurement: • • • • • Carbon fibers have high strength (3–7 GPa) Low Coefficient of Thermal Expansion High modulus (200–500 GPa) Compressive strength (1–3 GPa) Shear modulus (10–15 GPa) Chemical Properties Chemical properties are the changes observed in a material or substance when it partakes in a reaction. Carbon fiber is corrosion resistant and chemically stable which is very good for airplane use as it prevents the wing from corroding when it reacts with rain snow etc. This adds a longer life span to the wing and helps with less money being spent on maintenance. This property is very important because the corrosion of the wing means that the covering of the wing will be affected thus causing the plane’s wing to dismantle and to fall apart when met up with much drag from the wind when cruising at a very fast speed. (AirCraft Basic Construction, 2000) Physical Properties of Carbon Fiber: • • • • • • • • Low density (1.75–2.00 g/cm3) which is related to mass; hence it means that they are usually light in weight. Light colored appearance such as white or grey 4200 °C The opacity is usually very high allowing no electromagnetic light to pass through. Carbon fibers are non-magnetic The melting point usually has a temperature that ranges from 1,150 to 1,200 °C. The viscosity is good as it thick to withstand the strong drag it encounters giving it much resistance to deformation at any given rate. Carbon fiber is especially known for its high flexibility which is the reason it is used often in aerospace. The stated physical properties are very important in aerospace. This is so because when taking into considering the weight of the carbon fiber, which is very important to help with, take off and reduce the fuel consumption. Whenever the plane takes off it burns much fuel to act against gravity and the weight of the plane. In reducing the weight then it burns less fuel to take off saving the airlines millions from refueling the plane. They are usually light colored appearances which helps to keep the plan cool as this is set behind the principle of albedo effect where 47 Material Selection Material Science Group Assignment electromagnetic rays from the sun is reflected back into space which helps to reduce the amount of heat conducted in the wing which is where the fuel is stored. Electrical Property of Carbon Fiber: Carbon fibers are not electrically conductive which is very useful for the airplane’s safety. Throughout the year, airplanes are often met up with unfavorable weathers which can be very detrimental to the safety of the souls on board. Being that carbon fibers which makes up the wings are not electrically conductive then it means therefore that when in a thunderstorm which is characterized by heavy rainfall and lightning. Then it will not conduct the lightning as this can start a fire especially because the fuel is contained in the wings of the plane. Apart from conducting lightning, being electrically non-conductive then it means that it will not be affected by galvanic corrosion. (Bhatt & Goe, 2017) The type of materials used to make airplane wings: Over the years Airplane wings have been made from several materials such as: aluminum alloy and of lately carbon fiber composites. Aluminum: Aluminum alloys are widely used in modern aircraft construction. Aluminum alloys are valuable because they have a high strength-to-weight ratio. Aluminum alloys are corrosion resistant and comparatively easy to fabricate. The outstanding characteristic of aluminum is its lightweight Carbon Fiber: High-performance aircraft require an extra high strength-to-weight ratio material. Fabrication of composite materials satisfies this special requirement. Composite materials are constructed by using several layers of bonding materials (graphite epoxy or boron epoxy). These materials are mechanically fastened to conventional substructures. Another type of composite construction consists of thin graphite epoxy skins bonded to an aluminum honeycomb core. Carbon fiber is extremely strong, thin fiber made by heating synthetic fibers, such as rayon, until charred, and then layering in cross sections. (Bhatt & Goe, 2017) Materials used (Alloys) Aluminum Commercial Number Composition of the material 7075 aluminum alloys 5.6–6.1% zinc 2.1– 2.5%magnesium 1.2–1.6% copper, and less than a half percent of silicon, iron, manganese, titanium, chromium, and other metals Chemistry/Structure of the material Large extrusion with the section near the surface showing a layer of course recrystallized grain overlying fine subgrains 48 Material Selection Carbon Fiber Material Science Composite 101 or carbon composite Thermosetting Plastics Chemical Name: graphite fiber The composite material may contain aramid (e.g. Kevlar, Twaron), ultrahigh-molecularweight polyethylene (UHMWPE), aluminum, or glass fibers in addition to carbon fibers. They usually involve additives which contributes to the structure of the carbon composite. Group Assignment Consist of a highly cross-linked, 3D network. Bonds prevent chains moving relative to each other. The carbon atoms are bonded together in microscopic crystals (hexagonal aromatic rings) that are aligned parallel to the long axis of the fiber. The crystal alignment makes the fiber incredibly strong for its size. Several thousand carbon fibers are twisted together to form a yarn, which may be used by itself or woven into a fabric. Further heating at 700:C causes these rings to become aromatic pyridine groups due to the loss of hydrogen from the carbon atoms. Manufacturing Properties There are several ways in which an airplane wings are made, which are as follows: vacuum bagging, molding and compression molding and high-tech computer assisted design. Diagram showing assemblage of an aircraft wing 49 Material Selection Material Science Group Assignment Molding method: Wing geometry affects every aspect of an aircraft's flight. The wing area will usually be dictated by the desired stalling speed but the overall shape of the planform and other detail aspects may be influenced by wing layout factors. The construction of the wing starts with the rib which defines the airfoil shape. Ribs can be made of wood, metal, plastic or even composites. Firstly, the carbon fiber parts are produced by layering sheets of carbon fiber cloth into a mold in the shape of the final product. The alignment and weave of the cloth fibers is chosen to optimize the strength and stiffness properties of the resulting material. The mold is then filled with epoxy and is heated or air-cured. The resulting part is very corrosion-resistant, stiff, and strong for its weight. Parts used in less critical areas are manufactured by draping cloth over a mold, with epoxy either preimpregnated into the fibers or "painted" over it. High-performance parts using single molds are often vacuum-bagged and/or autoclave-cured, because even small air bubbles in the material will reduce strength. Secondly, the ribs are made using either grade aluminum or steel, which is corrosion resistant and possesses great tensile strength. Ribs are made and placed unto a metal bar and rubber forming die. A hydraulic press applies 150 tons of pressure stamping the rib to the die shape. Using a grinder, the sharp edges are smooth out and the plastic film removed that protects the rib from scratches. The same process is used to make the spar which is used to make the entire length of the wing. This takes even more pressure (222 tons) because this material is three times thicker than the ones used for the ribs. Spring clamps are manually pushed into the spar to ensure the ribs are aligned evenly, which holds the ribs in position. Workers hand drilled for larger rivets then smooth out the sharp edges. The completed airframe receives the carbon fiber covering after which spring clamps are used to position the covering unto the frame. The same procedure is used for the leading-edge wing nose. Once everything is together with spring clamps, the assembly is permanently riveted. While welders fuse the wings field tank using an organic gas torch. The tank is fitted in the wing chamber then secured by bolting steel belts unto the spars. After which the tanks covering plate is screwed unto the wing. Lastly, the wing tip is attached, and the wing is assembled unto the fuselage, which is the main part of the airplane. (Experimental Aircraft Info, n.d.) Property-control methods: Carbon fiber usually contains additives, where the most common additive is silica, but other additives such as rubber and carbon nanotubes can be used. These additives are very vital to the material as it helps with the strength and rigidity of the material (such as reinforced polymer). Also, the carbon fiber or carbon fiber reinforced polymer usually contains epoxy resin which gives it a good mechanical property. Carbon fiber may contain precursors which adds to its flexibility which is very vital when the wings are dancing against the motion of the drag force. (Bhatt & Goe, 2017) 50 Material Selection Material Science Group Assignment Bulletproof Vest Description and application A “Bulletproof vest” more accurately a bullet resistant vest is a type of armour that is used to protect the torso from firearm projectiles. Body protection was being use from early as 400 B.C, it can be seen in the Roman empire, Greek empire, Medieval and Modern day. Body armour was formalized in 1538 where steel plates were used in the gear. The body protection is important for the torso area contain most vital organs. Effective body Armor was introduced in the 1940s, where it was used by military and law enforcers. The vest was made up of ballistic nylon at the time until in 1965, Stephanie Kwolek created Kevlar. Kevlar is the most effective material because of its high resistance, strength, and light weight. The vests nowadays are made up of layers of polyethylene, strong fibres, ceramics, and Kevlar. Bulletproof vest is important whereas the different layers of the vest absorbs the impact so that the wearer does not suffer from the penetration of the shrapnel or bullet but probably minor internal bruising. The vest is made to spread force of a bullet in larger area. There are hard body and soft body vest. Hard body is strengthened by steel plates to make stronger and effective however it is heavier. Soft body however is more light weight they are most worn by police officers or guards whereas hard body is for the military. 51 Material Selection Material Science Group Assignment Materials • Kevlar This is a very strong plastic that is made from condensation polymerization. To make Kevlar is expensive because it requires a lot of concentrated sulphuric acid. Kevlar is a crystal liquid compound that can be woven into fiber. There are different types of Kevlar some are: Kevlar K-29 – Use to make Cables, tires, and brake lining Kevlar 119 – Can be stretched more, it is flexible and has high fatigue resistance. Kevlar that is applicable in bulletproof vest has a high strength to weight ratio like Kevlar K129 and Kevlar KM2. Kevlar fiber relative density is 1.44 whereas its tensile strength is 3620 MPa. It has such high strength because of its natural intermolecular forces. It has strong hydrogen bonds as well as the aromatic bonding which is a ring like structure bonded with another aromatic structure. • UHMWPE It is a high molecular weight polyethylene made from polymerization. This also has a high strength to weight ratio. This material is useful in stab proof vest whereas it passes the “ice pick” test. It is also use in bulletproof vest because of its ballistic resistance. Unlike Kevlar that lose strength when exposed to UV light UHMPE does not lose its strength. • Dyneema Dyneema is the most used polyethylene use in bulletproof vest. Kevlar is 5 times stronger than steel where as Dyneema is 15 times stronger and 40% stronger than Kevlar comparing their strength to weight ratio. Dyneema have different fibers namely HB212, HB56, SB115 and SB71. Bulletproof vest with best performance is normally use Dyneema along with Kevlar. The mix is better where as it improves the flexibility and lowers the weight of the vest. (Protection Group Danmark, n.d.) 52 Material Selection Material Science Group Assignment Manufacturing process • Making the cloth To make Kevlar requires you do work in a lab and perform a polymerization experiment to create poly-para-phenylene terephthalamide. Polymer is made using condensation polymerization whereas long chain compound created with a crystalline liquid structure. A process of wet spinning occurs in a spinneret (like a shower head) to form Kevlar fibre which is a composite with carbon fibre and glass fibre. The fibre is then hardened, wound, twisted and woven into a strong and stiff material. (Tex Tech Industries, 2020) Spectra is laid parallel to the Kevlar and coated with resin to form a spectra cloth. Two sheets of the cloth are placed perpendicular to each other and bonded together between two sheets of polyethylene film. • Cutting the panel The cloth is place on a table laying out 8 or more layers depending on the bulletproof protection level (Level 1, Level 2, etc.). They are placed in position and a handheld machine is used to cut out the pattern of each panel. • Sewing the panels The panels are placed in position and a stencil and chalk is used to mark out the sewing pattern. Kevlar vest are box stitched or quilt 53 Material Selection Material Science Group Assignment stitched. Box stitch is easier to do and it allows better movement of the vest therefore it is not as stiff whereas quilt stitch is harder to do but it creates a stiff vest and all components of the vest stays intact. • Finishing the vest The shells for the panel are held together whereas the panels are place in the shells. (How Products are Made, n.d.) Performance Criteria Important criteria for designing this product are: 1. 2. 3. 4. Flexibility Weight Tensile strength Toughness Flexibility is important because to allow better movement of the wearer. A solider wearing a bulletproof vest is going to do a lot of movement and would need to be comfortable holding a gun. Weight is another important factor whereas mobility is important for the wearer. The person may need to run and light weight equipment would be suitable. Tensile strength is important to absorb the energy of ballistic projectiles to reduce internal bruising. Toughness is another important feature whereas the ballistic project will not penetrate the material of the vest. Property Control Method To improve strength of bulletproof vest Graphene can be an added layer in making vest. It is lightweight as well it is two times stronger than Kevlar it can absorb more energy from the ballistic projectile. The only downfall is that is not as tough as Kevlar therefore it is between to blend with other materials. A Cordura cover would also be beneficial to avoid wear of the vest whereas it has a high wear resistance. 54 Material Selection Material Science Group Assignment Cutlery Parts Description and application Cutlery parts is used worldwide when preparing, serving, or eating food. It is a handheld instrument to make it easier to handle food other than using your hand. Using Cutlery parts is seen as “classier” than using your hands or other means. Cutlery parts are also known as silverware and this term was developed in the mid-19th century. The name Silverware was because at the time the Cutlery parts were made from silver however from 1970s to now, they are commonly made from stainless steel. The most common Cutlery parts are spoon, knife, and fork, each has specific use. A spoon is generally use when handling liquid, fork is used to handle solid food whereas it can penetrate the food to lift it, knife however is for cutting and slicing. Materials Cutlery is normally made with stainless steel or sterling silver. Silver sterling is used because pure silver is soft, and it is hard to mould and shape. Silver may also tarnish whereas it will react with air and will have a dirty look. Sterling silver however is an alloy of 92.5% silver and 7.5% of zinc and copper. Sterling silver is more durable and stronger along with it being cheaper than pure silver. Stainless steel however requires more extensive processes to make. These steps include: 1. Melting the Raw Materials Nickel, iron ore, chromium and silicon are placed in a furnace and heated to approximately 10 hours to form stainless steel compound. 2. Removal of excess carbon The molten stainless-steel compound is placed in a Vacuum oxygen decarburization system to remove excess carbon. The amount of carbon removed may affect the strength of the stainless steel. 55 Material Selection Material Science Group Assignment 3. Tuning The molten compound is stirred to ensure the components are evenly distributed it as well helps to separate impurities. 4. Forming While the compound is being cooled a hot roll is used to make blooms and billets which can be accurately designed using cold rolling. 5. Annealing This is a step in softening the metal as well as relieving internal stress of the steel. Age hardening may be used 6. Descaling In the annealing step it may cause a build-up of steel to be formed. Pickling or electro-cleaning may be used to descale the metal however pickling is the most common method. Pickling involves the use of nitric hydrofluoric acid whereas the metal is placed in the solution. 7. Cutting The stainless steel is then cut with machinery to the desired shape and dimensions 8. Finishing Stainless steel is cleaned, buffed, and polished to improve corrosion resistance. Abrasive substances are used to clean the stainless steel and grinding wheel are used to grind the edge of the steel. (Marlin Steel, 2020) Manufacturing Process • Rolling First step is to set out the stainless, silver or flatware whereas large rolls are stamped that are flat piece. The pieces are cut in small and they are made to the proper thickness and close to the shape that is trying to be made. This shape and thickness are achieved by rolling, it is rolled to its desired width first then to its length. The rolling process is carried out by a machine. (Webster, 2017) • Annealing The metal is heated using ovens to soften the metal. • Cutting The heated metal is then cut to correct shape of the cutlery being created. The excess metal is heated to be used again. 56 Material Selection Material Science Group Assignment • Patterning A die is used to create the patterns, it uses two dies, one at the front and one at the back. The piece of metal is placed in the die and a press of high pressure is used to form the pattern of the Cutlery part. The press improves the hardness of the Cutlery parts. Some utensils require unique manufacturing steps. For knives, the handle is made using two metals and bonds them with soldering tools. Forks require a different cutting whereas it has tines however it is press like normal. Spoons are made using a specific type of drop hammer or press to achieve the scoop in the spoon. • Silver-Plating Some may require silver coating by the process of electrolysis. The metal is cleaned first then electrolysis take place whereas silver is deposited on the metal. • Buffing Buffing is smoothing and polishing the cutlery. It is important for the ends of the handles may still be sharp from cutting. It is use to give the cutlery parts a shiny look. (How Products are Made, n.d.) (Webster, 2017) Performance Criteria Important criteria are: 1. 2. 3. 4. Availability Corrosion Resistance Safety Heat Resistance Availability is important whereas cutlery parts are used in everyday life therefore stainless steel must be a material that is easily accessible. Corrosion resistance is important for it is not safe to have handling food with rusty cutlery parts. Safety is important where some metals is poisonous therefore the material use must be safe to place in the mouth of the user. Heat resistance is important whereas the cutlery parts may be exposed to high temperatures there it would be sufficient for it to maintain its physical property after it being exposed. 57 Material Selection Material Science Group Assignment Property control method To prevent corrosion pure silver can be used to coat the product through the process of electrolysis. The coating will prevent the more susceptible metal from being oxidized whereas a less reactive metal is use for coating. Safety can be improved by using less poisonous metal or metal that will not leave a taste in your mouth. 58 Material Selection Material Science Group Assignment References AirCraft Basic Construction. (2000). Retrieved from http://home.iitk.ac.in/~mohite/Basic_construction.pdf AmTech International. (n.d.). Flywheel Assemblies – Single & Dual Mass. 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