UNIT CONVERSIONS: 1 N = 1 kg ∙ m⁄s 2 1 Pa = 1 N/m2 1J=1N∙m ` 1 lbf = 32.174 lbm ∙ ft⁄s 2 1 W = 1 J⁄s 1 J = 1 Volt ∙ Ampere ∙ s 1 bar = 105 Pa = 0.1 MPa = 100 kPa 𝑇(K) = 𝑇(℃) + 273.15 WORK, HEAT AND ENERGY BALANCE: 𝑡2 𝐸2 − 𝐸1 = 𝑄 − 𝑊 𝑊 = ∫ 𝑊̇ 𝑑𝑡 𝑑𝐸 = 𝑄̇ − 𝑊̇ 𝑑𝑡 𝑄 = ∫ 𝑄̇ 𝑑𝑡 𝑄̇𝑥 = −𝜅𝐴 𝑡1 𝑡2 𝑑𝑇 𝑑𝑥 𝑄̇𝑒 = 𝜀𝜎𝐴(𝑇𝑏4 − 𝑇s4 ) 𝑡1 𝑠2 Ʋ2 𝑊 = ∫ 𝑝 𝑑Ʋ 𝑄̇𝑐 = ℎ𝐴(𝑇b − 𝑇f ) 𝑊 = ∫ 𝐹 𝑑𝑠 𝑠1 Ʋ1 𝑊̇ = −ℰ𝑖 𝑊̇ = 𝐹𝑉 = 𝒯𝜔 ENERGY ANALYSIS OF CYCLES: 𝑄cycle = 𝑊𝑐𝑦𝑐𝑙𝑒 ∆𝐸cycle = 𝑄cycle − 𝑊𝑐𝑦𝑐𝑙𝑒 = 0 𝜂power = 𝑊𝑐𝑦𝑐𝑙𝑒 𝑄𝑖𝑛 𝛽ref = 𝑄in 𝑊cycle 𝛾hp = 𝑄out 𝑊cycle EVALUATION OF PROPERTIES: 𝑣 = 𝑣𝑓 + 𝑥(𝑣g − 𝑣f ) 𝑢 = 𝑢f + 𝑥(𝑢g − 𝑢f ) ℎ = ℎf + 𝑥(ℎg − ℎf ) 𝑠 = 𝑠f + 𝑥(𝑠g − 𝑠f ) 7 INCOMPRESSIBLE SUBSTANCE MODEL: 𝑇2 𝑢2 − 𝑢1 = ∫ 𝑐 (𝑇) 𝑑𝑇 𝑇1 𝑇2 𝑇2 ℎ2 − ℎ1 = ∫ 𝑐 (𝑇) 𝑑𝑇 + 𝑣 (𝑝2 − 𝑝1 ) 𝑠2 − 𝑠1 = ∫ 𝑇1 𝑇1 𝑐 (𝑇 ) 𝑑𝑇 𝑇 IDEAL GAS MODEL: 𝑃𝑉 = 𝑚𝑅𝑇 𝑃𝑣 = 𝑅𝑇 𝑇2 𝑇2 𝑢2 − 𝑢1 = ∫ 𝑐𝑣 (𝑇) 𝑑𝑇 ℎ2 − ℎ1 = ∫ 𝑐𝑝 (𝑇) 𝑑𝑇 𝑇1 𝑇1 𝑇2 𝑠2 − 𝑠1 = ∫ 𝑐𝑣 (𝑇) 𝑇1 𝑇2 𝑑𝑇 𝑣2 + 𝑅 𝑙𝑛 𝑇 𝑣1 𝑠2 − 𝑠1 = ∫ 𝑐𝑝 (𝑇) 𝑇1 𝑑𝑇 𝑃2 − 𝑅 𝑙𝑛 𝑇 𝑃1 POLYTROPIC PROCESS: 𝑃2 𝑉1 𝑛 =( ) 𝑃1 𝑉2 𝑃1 𝑉1𝑛 = 𝑃2 𝑉2𝑛 𝑛 𝑃𝑉 = 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡 2 𝑃2 𝑉2 − 𝑃1 𝑉1 ∫ 𝑃 𝑑𝑉 = 1−𝑛 1 2 ∫ 𝑃 𝑑𝑉 = 𝑃1 𝑉1 ln 𝑛≠1 1 𝑉2 𝑉1 𝑛=1 IDEAL GASS UNDER POLYTROPIC PROCESS: 𝑇2 𝑃2 (𝑛−1)⁄𝑛 𝑉1 𝑛−1 =( ) =( ) 𝑇1 𝑃1 𝑉2 2 𝑚𝑅 (𝑇2 − 𝑇1 ) ∫ 𝑃 𝑑𝑉 = 1−𝑛 1 2 𝑛≠1 ∫ 𝑃 𝑑𝑉 = 𝑚𝑅𝑇 ln 1 𝑉2 𝑉1 𝑛=1 MASS AND ENERGY BALANCE FOR CONTROL VOLUMES: 𝑑𝑚cv = ∑ 𝑚̇𝑖 − ∑ 𝑚̇𝑒 𝑑𝑡 𝑖 𝑒 𝑚̇ = 𝜌𝐴𝑉 = 𝐴𝑉 𝑣 𝑑𝐸𝑐𝑣 𝑉𝑖2 𝑉𝑒2 ̇ ̇ = 𝑄cv − 𝑊cv + ∑ 𝑚̇𝑖 (ℎ𝑖 + + 𝑔𝑧𝑖 ) − ∑ 𝑚̇𝑒 (ℎ𝑒 + + 𝑔𝑧𝑒 ) 𝑑𝑡 2 2 𝑖 𝑒 8 MASS AND ENERGY BALANCE FOR CONTROL VOLUMES (TRANSIENT ANALYSIS): ∆𝑚𝑐𝑣 = ∑ 𝑚𝑖 − ∑ 𝑚𝑒 𝑖 𝑒 ∆𝑈𝑐𝑣 = 𝑄cv − 𝑊cv + ∑ 𝑚𝑖 ℎ𝑖 − ∑ 𝑚𝑒 ℎ𝑒 𝑖 𝑒 THERMAL EFFICIENCY AND COEFFICIENT OF PERFORMANCE: 𝜂= 𝑊𝑐𝑦𝑐𝑙𝑒 𝑄𝐶 =1− 𝑄𝐻 𝑄𝐻 𝜂max = 1 − 𝛽= 𝑄𝐶 𝑄𝐶 = 𝑊𝑐𝑦𝑐𝑙𝑒 𝑄𝐻 − 𝑄𝐶 𝛽max = 1 𝑇𝐻 ⁄𝑇𝐶 − 1 𝛾= 𝑄𝐻 𝑄𝐻 = 𝑊𝑐𝑦𝑐𝑙𝑒 𝑄𝐻 − 𝑄𝐶 𝛾max = 1 1 − 𝑇C ⁄𝑇H 𝑇C 𝑇H SECOND LAW OF THERMODYNAMICS: ∮( 𝛿𝑄 ) = −𝜎cycle 𝑇 b 2 𝑆2 − 𝑆1 = ∫ ( 1 𝛿𝑄 ) 𝑇 int rev 𝑑𝑆 = ( 𝛿𝑄 ) 𝑇 𝑖𝑛𝑡 𝑟𝑒𝑣 𝑇 𝑑𝑆 = 𝑑𝑈 + 𝑃 𝑑Ʋ 𝑇 𝑑𝑠 = 𝑑𝑢 + 𝑃 𝑑𝑣 𝑇 𝑑𝑆 = 𝑑𝐻 − Ʋ 𝑑𝑃 𝑇 𝑑𝑠 = 𝑑ℎ − 𝑣 𝑑𝑃 2 𝑆2 − 𝑆1 = ∫ ( 1 𝛿𝑄 ) + 𝜎 𝑇 b 𝑆2 − 𝑆1 = 𝑄 + 𝜎 𝑇b 𝑄̇𝑗 𝑑𝑆 =∑ + 𝜎̇ 𝑑𝑡 𝑇𝑗 𝑗 9