3M(TM) Scotch-Weld(TM) Plastic & Rubber Instant Adhesive PR1500, Clear Safety Data Sheet Copyright,2021, 3M Canada Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document group: Issue Date: 32-7916-3 2021/03/01 Version number: Supercedes Date: 3.02 2020/10/22 This Safety Data Sheet has been prepared in accordance with the Canadian Hazardous Products Regulations. SECTION 1: Identification 1.1. Product identifier 3M(TM) Scotch-Weld(TM) Plastic & Rubber Instant Adhesive PR1500, Clear Product Identification Numbers 62-6137-0260-4 62-6137-0265-3 62-6165-3860-9 62-6165-3865-8 UU-0015-0377-8 UU-0015-0378-6 62-6165-0360-3 62-6165-3866-6 UU-0015-0446-1 62-6165-0365-2 UU-0015-0267-1 UU-0015-0457-8 62-6165-0366-0 UU-0015-0368-7 UU-0015-0463-6 1.2. Recommended use and restrictions on use Intended Use Adhesive Restrictions on use Not applicable 1.3. Supplier’s details Company: Division: Address: Telephone: Website: 3M Canada Company Industrial Adhesives and Tapes Division 1840 Oxford Street East, Post Office Box 5757, London, Ontario (800) 364-3577 www.3M.ca N6A 4T1 1.4. Emergency telephone number Medical Emergency Telephone:1-800-3M HELPS / 1-800-364-3577; Transportation Emergency Telephone (CANUTEC): (613) 996-6666 SECTION 2: Hazard identification 2.1. Classification of the substance or mixture Flammable Liquid: Category 4. Serious Eye Damage/Irritation: Category 2A. Specific Target Organ Toxicity (single exposure): Category 3. 2.2. Label elements Signal word __________________________________________________________________________________________ Page: 1 of 9 3M(TM) Scotch-Weld(TM) Plastic & Rubber Instant Adhesive PR1500, Clear Warning Symbols Exclamation mark | Pictograms Hazard statements Combustible liquid. Causes serious eye irritation. May cause respiratory irritation. Precautionary statements Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Wash exposed skin thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a POISON centre or doctor/physician if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Other hazards May bond tissue rapidly. SECTION 3: Composition/information on ingredients This material is a mixture. Ingredient Ethyl Cyanoacrylate Non-Hazardous Resin C.A.S. No. 7085-85-0 Trade Secret % by Wt 80 - 100 Trade Secret * 5 - 15 Common Name 2-Propenoic acid, 2-cyano-, ethyl ester Not Applicable Non-Hazardous Resin is a non-hazardous Trade Secret material according to WHMIS criteria. *The actual concentration of this ingredient has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: __________________________________________________________________________________________ Page: 2 of 9 3M(TM) Scotch-Weld(TM) Plastic & Rubber Instant Adhesive PR1500, Clear Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: FOR SKIN BONDS: Quickly soak in warm water and avoid use of excessive force to free bonded area. If unable to free bonded area, or if lips or mouth are bonded, get medical attention. If irritation persists, get medical attention. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. DO NOT force eyelids open. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Irritating to the respiratory tract (coughing, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain). 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Hydrogen Cyanide Oxides of Nitrogen Condition During Combustion During Combustion During Combustion During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. bodies of water. For larger spills, cover drains and build dikes to prevent entry into sewer systems or 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as __________________________________________________________________________________________ Page: 3 of 9 3M(TM) Scotch-Weld(TM) Plastic & Rubber Instant Adhesive PR1500, Clear possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store away from amines. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethyl Cyanoacrylate 7085-85-0 ACGIH TWA:0.2 ppm;STEL:1 ppm Dermal/Respiratory Sensitizer ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. protection(s) are recommended: Indirect Vented Goggles The following eye/face Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Do not wear cotton gloves. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate When only incidental contact is anticipated, alternative glove material(s) may be used. If contact with the glove does occur, remove immediately and replace with a set of new gloves. For incidental contact, gloves made of the following material(s) __________________________________________________________________________________________ Page: 4 of 9 3M(TM) Scotch-Weld(TM) Plastic & Rubber Instant Adhesive PR1500, Clear may be used:Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour threshold pH Melting point/Freezing point Boiling point Flash Point Evaporation rate Flammability (solid, gas) Flammable Limits(LEL) Flammable Limits(UEL) Vapour Pressure Viscosity/Kinematic Viscosity Viscosity/Kinematic Viscosity Density Relative density Water solubility Solubility- non-water Partition coefficient: n-octanol/ water Autoignition temperature Decomposition temperature Viscosity/Kinematic Viscosity Volatile Organic Compounds Percent volatile VOC Less H2O & Exempt Solvents Liquid Colourless Sharp Odour, Pungent Odour No Data Available Not Applicable Not Applicable 150 ºC 85 ºC [Test Method:Closed Cup] No Data Available Not Applicable No Data Available No Data Available 39.1 Pa [@ 23.9 ºC ] No Data Available 1.08 g/ml 1.08 [Ref Std:WATER=1] Nil No Data Available No Data Available No Data Available No Data Available 1,275 - 1,650 mPa-s [@ 23 ºC ] <=0.6 % 85 - 95 % weight [Test Method:Estimated] <=6 g/l Nanoparticles This material does not contain nanoparticles. SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions __________________________________________________________________________________________ Page: 5 of 9 3M(TM) Scotch-Weld(TM) Plastic & Rubber Instant Adhesive PR1500, Clear Hazardous polymerization may occur. Material polymerizes rapidly by contact with water, alcohol, amines and alkalis. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong oxidizing agents Water Strong bases Amines Alcohols 10.6. Hazardous decomposition products Substance None known. Condition Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: and throat pain. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose Skin Contact: Bonds skin rapidly. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Contact through clothing may cause thermal burns. Eye Contact: Bonds eyelids rapidly. Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Overall product Route Ingestion Species Value No data available; calculated ATE >5,000 mg/kg Ethyl Cyanoacrylate Dermal Rabbit LD50 > 2,000 mg/kg __________________________________________________________________________________________ Page: 6 of 9 3M(TM) Scotch-Weld(TM) Plastic & Rubber Instant Adhesive PR1500, Clear Ethyl Cyanoacrylate Non-Hazardous Resin Ingestion Dermal Rat LD50 > 5,000 mg/kg LD50 estimated to be > 5,000 mg/kg Non-Hazardous Resin Ingestion Rat LD50 > 5,000 mg/kg Name Species Value Ethyl Cyanoacrylate Non-Hazardous Resin Rabbit Rabbit Mild irritant No significant irritation Name Species Value Ethyl Cyanoacrylate Non-Hazardous Resin Rabbit Rabbit Severe irritant Mild irritant Species Human Value Not classified Name Species Value Ethyl Cyanoacrylate Human Not classified ATE = acute toxicity estimate Skin Corrosion/Irritation Serious Eye Damage/Irritation Skin Sensitization Name Ethyl Cyanoacrylate Respiratory Sensitization Germ Cell Mutagenicity Name Route Value Ethyl Cyanoacrylate In Vitro Not mutagenic Carcinogenicity For the component/components, either no data are currently available or the data are not sufficient for classification. Reproductive Toxicity Reproductive and/or Developmental Effects For the component/components, either no data are currently available or the data are not sufficient for classification. Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test result Ethyl Cyanoacrylate Inhalation respiratory irritation May cause respiratory irritation Human NOAEL Not available Exposure Duration occupational exposure Specific Target Organ Toxicity - repeated exposure For the component/components, either no data are currently available or the data are not sufficient for classification. Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information __________________________________________________________________________________________ Page: 7 of 9 3M(TM) Scotch-Weld(TM) Plastic & Rubber Instant Adhesive PR1500, Clear No data available. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Global inventory status Contact 3M for more information. The components of this material are in compliance with the provisions of the Korea Chemical Control Act. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. This product complies with Measures on Environmental Management of New Chemical Substances. All ingredients are listed on or exempt from on China IECSC inventory. The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. SECTION 16: Other information National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Health: 2 Flammability: 2 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. __________________________________________________________________________________________ Page: 8 of 9 3M(TM) Scotch-Weld(TM) Plastic & Rubber Instant Adhesive PR1500, Clear Document group: 32-7916-3 Version number: 3.02 Issue Date: 2021/03/01 Supercedes Date: 2020/10/22 The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. The manufacturer MAKES NO WARRANTIES, EXPRESS OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY IMPLIED WARRANTY OR CONDITION ARISING OUT OF A COURSE OF PERFORMANCE, COURSE OF DEALING, CUSTOM OR USAGE OF TRADE. User is responsible for determining whether the product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M Canada SDSs are available at www.3M.ca __________________________________________________________________________________________ Page: 9 of 9