SCH 3U9 – Chemistry 11 Advanced Placement Final Examination - Millcreek Secondary School Student Number: ________________ Full Name: ______________________ Time: 2.5 hours Teacher’s Name: Dr. McNally Course Code and Section: SCH 3U9 - Total Pages: 14 Number of Sections: 4 Period: 3 Instructions: 1. Print your full name and student number on the title page and of the examination booklet along with every additional sheet you hand in to the teacher. 2. Ensure to check that no pages are missing from the examination booklet. 3. Read all the instructions and questions carefully. 4. Scientific calculators and reference sheets are permitted, however, cannot be shared during the examination. 5. Do not separate the examination booklet unless given permission. Evaluation: SECTION/PART STUDENT SCORE TOTAL Section A – Chemical Foundations and Matter [ ] 30 Section B – Atomic Structure and Properties [ ] 30 Section C – Quantities in Chemical Reactions [ ] 20 Section D – Solutions and Solubility [ ] 20 TOTAL: 100 For Exam Review Day Only: I, _____________________, have reviewed the exam and results. Student Signature: _______________________________ Name: _______________ FINAL EXAMINATION – SCH 3U9 SECTION A: Chemical Foundations and Matter 1. Examine the following reactants. Predict the product(s) and type of reaction that will occur (S, D, C, DD, SD). Write a balanced chemical equation for each reaction. If no reaction occurs, write “N.R”. States of products and reactants are only required for double displacement reactions. [9] a. ___ MgCl2 + ___ K2SO4 b. ___ Li + ___ N2 Type: ________ Type: ________ c. ___ Na + ___ Al(NO3)3 Type: ________ d. ___ CH6 + ___ O2 Type: ________ e. ___H2SO4 + ___ RbOH Type: ________ f. ___ CaCO3 Type: ________ g. ___ Mg + ___ CaCl2 Type: ________ h. ___ AgBr Type: ________ i. ___Na2O + ___ HCL Type: ________ 2. A chemistry professor conducts an experiment for his students. He mixes sodium chloride and ammonium sulfate. [5] a. Predict the type of reaction and write a balanced chemical equation for this reaction. b. Write the total ionic equation for this reaction. 2 Name: _______________ FINAL EXAMINATION – SCH 3U9 c. Write the net ionic equation for this reaction. Ensure to include the states. d. What were the spectator ions for this reaction? e. Briefly describe the difference between a total ionic equation, and a net ionic equation. Describe the importance of both in your explanation. 3. Why is selective precipitation important? What compound could be added to precipitate the sodium ions in a solution of NaCH3COO and Mg(CH3COO)2? [4] 3 Name: _______________ FINAL EXAMINATION – SCH 3U9 4. Fill in the table by describing the three fundamental laws of chemistry. [9] Law Name/ Person Who Invented the Law Law Explanation Example of Law 4 Name: _______________ FINAL EXAMINATION – SCH 3U9 5. Using a balance that is +/- 0.02 g and a graduated cylinder that is +/- 0.04 mL, the following measurements were made for an object. Mass = 30.20 g, V1 = 15.2 mL, V2 = 16.3 mL. Using these observations, calculate the density of the object and indicate the +/- uncertainty. Remember to number your steps and round your answer to significant digits. [3] 5 Name: _______________ FINAL EXAMINATION – SCH 3U9 SECTION B: Atomic Structure and Properties 1. Determine if CH3Cl is a polar molecule. Ensure to include a Lewis structure diagram, bond angles, AXE code, VSPER shape, and a few words of explanation in your answer. [4] 2. Write formulas or names for the following compounds. [10] a. CuClO3 f. TiO2 b. sodium nitrate trihydrate g. chromium (II) hydroxide c. HCLO2 h. Al2(SO4)3 d. P2S5 i. manganese (III) sulfite e. iron (III) carbonate j. Mg3PO4 . 8H2O 6 Name: _______________ FINAL EXAMINATION – SCH 3U9 3. What amount of energy is contained in a photon of blue light with a wavelength of 450 nm? How many of these photons are required to produce 0.75 J of energy? [4] 4. Using the following diagram sketch and label the type of intermolecular forces you would expect to find between the two molecules. Would you expect this molecule to have a high or low boiling point? Explain. [4] 7 Name: _______________ FINAL EXAMINATION – SCH 3U9 5. Bromine (atomic weight 79.90 u) has two stable isotopes with isotopic weights 78.918 u and 80.916 u. [8] a. What is the percentage abundance of the heavier isotope? b. Draw the energy level diagram for Bromine. 8 Name: _______________ FINAL EXAMINATION – SCH 3U9 SECTION C: Quantities in Chemical Reactions 1. A hydrate of CaCO3 has a mass of 8.45 g before heating. After heating, the anhydrous compound’s mass is found to be 5.20 g. Determine the formula of the hydrate. [3] 2. A compound’s percentage composition is 30.0 % carbon, 8.6 % oxygen and the remainder is hydrogen. If the compound’s molar mass was determined to be 110.5 g/mol, what is the compound’s molecular formula? [3] 9 Name: _______________ FINAL EXAMINATION – SCH 3U9 3. When 0.85 g of sodium hydroxide reacts with 1.13 g of barium chloride, 0.23 g of sodium chloride is collected. BaCl2 + 2NaOH Ba(OH)2 + 2NaCl a. Determine the limiting reagent [2] b. Determine the theoretical yield in grams of NaCl [2] c. What was the percent yield of this reaction? [1] d. Why is it important to balance equations in stoichiometric calculations? [2] 10 Name: _______________ FINAL EXAMINATION – SCH 3U9 4. An impure sample of MgCO3 has a mass of 2.68 grams and is dissolved in water. Addition of NH3 solution produced a precipitate of magnesium hydride with mass 2.32 g. What is the percentage of MgCO3 in the impure sample? [3] 3MgCO3 + 2NH3 3MgH2 + N2(CO3)3 5. A 0.585 g sample containing carbon, hydrogen and oxygen is burned and analyzed using a carbon hydrogen analyzer from which 0.358 g of H2O and 5.357 g of CO2 are collected. The compound’s molar mass is 286 g/mol. If the sample contains carbon, hydrogen and oxygen, determine its molecular formula. [4] 11 Name: _______________ FINAL EXAMINATION – SCH 3U9 SECTION D: Solutions & Solubility 1. Several 10.00 mL samples of HNO2 (aq) of unknown concentration are titrated with a 0.300 mol/L solution of KOH (aq). The results for three trials are shown below. Trial Final Burette Volume Reading (mL) Initial Burette Volume Reading (mL) Volume of Titrant KOH Added (mL) 1 11.66 00.10 11.56 2 24.97 13.45 11.52 3 30.47 18.93 11.54 a. Balanced Equation: ________________________________________________________ b. What is the concentration of HNO2 (aq)? c. What is the significance of running multiple titration trials? 12 Name: _______________ FINAL EXAMINATION – SCH 3U9 2. Using square arrows, identify the acid, base, conjugate acid and conjugate base for the following reactions. [5] a. HF H2O + b. HNO2 + F- H2O + H3O+ H3O+ + NO2- c. HCLO4 + OH- CLO4- + H2O d. HSO4- + PO43- SO42- + HPO42- e. HCN + NH3 CN- + NH4+ 3. The World Health Organization’s guideline for safe levels of arsenic in water is 0.01 ppm (0.01 mg/L). When 1.3 L of water from the Hudson River was tested, it was found to contain 0.4 mg of arsenic. Is the water safe to drink? 13 Name: _______________ FINAL EXAMINATION – SCH 3U9 4. How would you prepare 3.2 L of 0.4 mol/L solution of HCL (aq) starting from a 15 mol/L stock solution purchased from a chemical company? 5. How much water should be added to 400.0 mL of a solution of HCL with a pOH of 11.00 to raise the pH to 5.00? 14