Springer Series in Optical Sciences 127 Dominik Gerhard Rabus Cinzia Sada Integrated Ring Resonators A Compendium Second Edition Springer Series in Optical Sciences Volume 127 Founding Editor H.K.V. Lotsch, Nußloch, Baden-Württemberg, Germany Editor-in-Chief William T. Rhodes, Florida Atlantic University, Boca Raton, FL, USA Series Editors Ali Adibi, School of Electrical and Computer Engineering, Georgia Institute of Technology, Atlanta, GA, USA Toshimitsu Asakura, Toyohira-ku, Hokkai-Gakuen University, Sapporo, Hokkaido, Japan Theodor W. Hänsch, Max Planck Institute of Quantum Optics, Garching b. München, Bayern, Germany Ferenc Krausz, Max Planck Institute of Quantum Optics, Garching b. München, Bayern, Germany Barry R. Masters, Cambridge, MA, USA Katsumi Midorikawa, Laser Tech Lab, RIKEN Advanced Science Institute, Saitama, Japan Herbert Venghaus, Fraunhofer Institute for Telecommunications, Berlin, Germany Horst Weber, Berlin, Germany Harald Weinfurter, München, Germany Kazuya Kobayashi, Department of EECE, Chuo University, Bunkyo-ku, Tokyo, Japan Vadim Markel, Department of Radiology, University of Pennsylvania, Philadelphia, PA, USA Springer Series in Optical Sciences is led by Editor-in-Chief William T. Rhodes, Florida Atlantic University, USA, and provides an expanding selection of research monographs in all major areas of optics: • • • • • • • • lasers and quantum optics ultrafast phenomena optical spectroscopy techniques optoelectronics information optics applied laser technology industrial applications and other topics of contemporary interest. With this broad coverage of topics the series is useful to research scientists and engineers who need up-to-date reference books. More information about this series at http://www.springer.com/series/624 Dominik Gerhard Rabus Cinzia Sada • Integrated Ring Resonators A Compendium Second Edition With 328 Figures and 15 Tables 123 Dominik Gerhard Rabus Department of Applied Chemistry, Process Analysis and Technology (PA&T) Reutlingen University Reutlingen, Germany Cinzia Sada Department of Physics and Astronomy “Galileo Galilei” University of Padova Padua, Italy ISSN 0342-4111 ISSN 1556-1534 (electronic) Springer Series in Optical Sciences ISBN 978-3-030-60130-0 ISBN 978-3-030-60131-7 (eBook) https://doi.org/10.1007/978-3-030-60131-7 1st edition: © Springer-Verlag Berlin Heidelberg 2007 2nd edition: © Springer Nature Switzerland AG 2020 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, expressed or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. This Springer imprint is published by the registered company Springer Nature Switzerland AG The registered company address is: Gewerbestrasse 11, 6330 Cham, Switzerland Inspiration “Progress is a never-ending spiral toward the future. When looked from one side, it can seem either a ring or a line. Its real natural evolution can be seen, loved, and appreciated only by changing the viewing angle thus the perspective.” The Authors v Preface This book is all about integrated ring resonators made out of optical waveguides in various materials for different applications. Integrated ring resonators are used to build optical filters, lasers, sensors, modulators, dispersion compensators, just to name a few. The book covers the range from simulation of various ring resonator configurations to the fabrication processes currently used, to the description of the application of integrated ring resonator in various fields. The book presents a summary of the activities in this field from the past to the current state of the art giving several examples. It has been written for students, graduates, professionals, academics and industry alike, working in this exciting and ever thriving field. The examples in literature used in this book have been collected over the last 20 years, categorizing the different examples into what are now the chapters of this book. Integrated ring resonators have been and still are a fascinating class of devices. Since the beginning they have gained great attention from the integrated optics community, especially in the frantic search to optimize their performances and win the competition to be the first to get the smallest device dimensions. This race has brought to the surface several astonishing results, later interpreted as new paths for outstanding applications even outside the mere integrated optics field. Those technologies that have been initially addressed as too much complicated to be of real practical interest, have become progressively available. As a consequence, a new inspiring light and weight have been implied to re-read and re-interpret the results published since the nineties, at that time mainly classified as pure academic achievements. Nowadays integrated ring resonators can therefore proudly boast to be the pulsing heart in new sensing approaches which are of great interest surely in biology, medicine and chemistry but not limited to these application fields. The huge advances in the fabrication technologies have covered the gap to match the micrometer/sub-micrometer scales needed for integrated ring resonators with the endless power of dreaming visioners in search of progress and improvement. It is in this frame of reference and mindset that the authors have come to this new version of the compendium on Integrated Ring Resonators. vii viii Preface Due to high demand and continued interest in the topic, the first version from 2007 is upgraded in this second edition considering the progress made in the field and extending the fabrication material range to polymers, crystals and hybrids which had been briefly discussed in the first edition and have now received a major upgrade in Chap. 3. Among others, Lithium Niobate has been introduced into the second edition reflecting the growing interest and achievements in Chap. 3.9. In Chap. 4, on building blocks for ring resonators, a brief overview on gratings for light in- and outcoupling is presented, making this chapter now updated with some of the most recent achievements. Chapter 5 has been “enriched” with interesting results on modulators and a short introduction on ring resonator switching in telecom operations. Chapter 6 on sensors has been upgraded to reflect the advances in biosensing and opto-microfluidics as both research fields have reached a considerable maturity state with direct impact on implementation of future applications with a clear path to productization. Chapter 7 on whispering gallery mode ring resonators has received an extension as well to serve even more as an introduction into this topic from a material science point of view. The authors are grateful to the entire integrated ring resonator community for providing exciting and cutting-edge research material which enabled the writing of this book. Due to the enormous amount of publications in this attractive field, we hope, that we were able to refer to most of the work done so far and would be thankful if we are made aware of any “undiscovered” work. As research on integrated ring resonators is ongoing, we would be more than happy to receive material for our growing database which can then of course be included in further editions. Reutlingen, Germany Padua, Italy Dominik Gerhard Rabus Cinzia Sada Contents 1 Introduction .......................................... 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 3 3 17 19 19 23 27 28 36 43 43 44 3 Materials, Fabrication and Characterization Methods . . . . . . . 3.1 Wafer Bonding . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.1.1 Bonding with Intermediate Layer . . . . . . . . . . . . . . 3.1.2 Bonding Without Intermediate Layer . . . . . . . . . . . 3.1.3 Benzocyclobutene Wafer Bonding . . . . . . . . . . . . . 3.2 Dry Etching . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.3 Si-Based Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.3.1 Ring Resonators Based on Si–SiO2 . . . . . . . . . . . . 3.3.2 Ring Resonators Based on Ta2O5–SiO2 . . . . . . . . . 3.3.3 Ring Resonators Based on SiN, SiON, and Si3N4 . . 3.3.4 Ring Resonators Based on SiO2–GeO2 . . . . . . . . . 3.4 III–V Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.4.1 The Quaternary Semiconductor Compound GaInAsP 3.4.2 The Semiconductor Compound AlGaAs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 51 51 52 53 55 56 56 60 62 65 66 66 68 2 Ring Resonators: Theory and Modeling . . . . . . . . . 2.1 Single Ring Resonators . . . . . . . . . . . . . . . . . . 2.1.1 Ring Structure . . . . . . . . . . . . . . . . . . . 2.1.2 Racetrack Shaped Resonators . . . . . . . . 2.2 Double Ring Resonators . . . . . . . . . . . . . . . . . . 2.2.1 Serially Coupled Double Ring Resonator 2.2.2 Parallel Coupled Double Ring Resonator 2.3 Multiple Coupled Resonators . . . . . . . . . . . . . . . 2.3.1 Serially Coupled Ring Resonators . . . . . 2.3.2 Parallel Coupled Ring Resonators . . . . . 2.4 Microring Resonator Based Electro-optic Effect . 2.5 Microring Resonator Modulator . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ix x Contents 3.4.3 Lateral Coupling in GaInAsP/InP . . . . . . . . . . . . . 3.4.4 Vertical Coupling in GaInAsP/InP . . . . . . . . . . . . . 3.4.5 Lateral Coupling in AlGaAs/GaAs . . . . . . . . . . . . . 3.4.6 Vertical Coupling in AlGaAs/GaAs . . . . . . . . . . . . 3.4.7 Implementation of Gain in Ring Resonators . . . . . . 3.5 Polymers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.5.1 Conventional Fabrication Techniques . . . . . . . . . . . 3.5.2 Replication and Nanoimprinting . . . . . . . . . . . . . . 3.5.3 Novel Polymer Devices . . . . . . . . . . . . . . . . . . . . . 3.6 Temperature Insensitivity . . . . . . . . . . . . . . . . . . . . . . . . . 3.7 Polarization Independence . . . . . . . . . . . . . . . . . . . . . . . . 3.8 Characterization Methods . . . . . . . . . . . . . . . . . . . . . . . . . 3.8.1 Conventional Characterization . . . . . . . . . . . . . . . . 3.8.2 Optical Low Coherence Reflectometry . . . . . . . . . . 3.8.3 Evanescent Field Measurement Methods . . . . . . . . 3.9 Lithium Niobate and Hybrid Solutions . . . . . . . . . . . . . . . 3.9.1 Ring Resonators Based on Lithium Niobate . . . . . . 3.9.2 Ring Resonators Based on Lithium Niobate on Insulators (LNOI) . . . . . . . . . . . . . . . . . . . . . . 3.9.3 Ring Resonators Based on Lithium Niobate on Insulators in Hybrid Configuration with Nitrides and Semiconductors . . . . . . . . . . . . . . . . . . . . . . . 3.9.4 Microring Modulators Based on Lithium Niobate and Chalcogenide Glasses on Silicon . . . . . . . . . . . 3.10 Microring Modulators in LN, LNOI and Hybrids: Limits and Improvements . . . . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 76 80 82 83 91 92 98 102 111 114 117 118 121 125 127 140 . . . . 146 . . . . 156 . . . . 161 . . . . 163 . . . . 170 4 Building Blocks of Ring Resonator Devices . . . . . . . . . 4.1 Couplers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.1.1 Directional Couplers . . . . . . . . . . . . . . . . . 4.1.2 Multimode Interference Couplers . . . . . . . . 4.1.3 Y-Couplers . . . . . . . . . . . . . . . . . . . . . . . . 4.2 Bends . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.3 Spot Size Converters for Light in- and Outcoupling 4.4 Gratings for Light in- and Outcoupling . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179 180 180 182 184 186 191 192 196 5 Devices . . . . . . . . . . . . . . . . . . . . . . . . 5.1 Filters . . . . . . . . . . . . . . . . . . . . 5.1.1 Passive Devices . . . . . . . 5.1.2 Devices with Gain Section 5.2 Tunability Methods . . . . . . . . . . 5.2.1 Wavelength Tuning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 200 200 216 223 224 .... .... .... ... .... .... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Contents xi 5.2.2 Center Wavelength Trimming . . . . . . . . . . . 5.2.3 Tunable Couplers in Ring Resonators . . . . . 5.3 Dispersion Compensators . . . . . . . . . . . . . . . . . . . . 5.4 Mach–Zehnder Interferometers Combined with Ring Resonators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.5 Modulators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.6 Lasers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.6.1 All Active Lasers . . . . . . . . . . . . . . . . . . . . 5.6.2 Devices with Gain Section . . . . . . . . . . . . . 5.6.3 Passive Ring Resonator Coupled Lasers . . . . 5.7 Wavelength Converters . . . . . . . . . . . . . . . . . . . . . 5.8 Optical Signal Processing . . . . . . . . . . . . . . . . . . . . 5.8.1 Logic Gates . . . . . . . . . . . . . . . . . . . . . . . . 5.8.2 Switching . . . . . . . . . . . . . . . . . . . . . . . . . . 5.8.3 Telecom Operations . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232 . . . . . . . . . 236 . . . . . . . . . 238 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 241 245 251 251 259 264 270 275 275 278 282 286 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293 303 305 311 323 7 Whispering Gallery Mode Devices . . . . . . . . . . . . . . . . . . . . . . . . 7.1 Whispering Gallery Modes (WGM) . . . . . . . . . . . . . . . . . . . 7.2 WGM Filters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7.3 WGM Lasers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7.4 WGM Microresonators in LN: Recent Advances in Dielectric Crystalline Configurations . . . . . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 327 327 328 330 6 Sensors . . . . . . . . . . . . . . . 6.1 Microfluidics . . . . . . . 6.2 Optofluidic Resonators 6.3 Biosensors . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 342 . . 347 8 Outlook . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351 Bibliography . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 353 Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 359 Abbreviations x η j C K a an h b K C/ Dk U(x) Dxn k0 e0 acoupling kg ainsertion /k wk apropagation xRn ut ath 1/s 2dk A(z) AFM APF Angular frequency Coupling efficiency to the fundamental waveguide mode Coupling parameter Gain of the filter Length of waveguide segment Loss coefficient of the ring (zero loss: a = 1) Absorption coefficient Phase Propagation constant Wavelength Complex angular propagation constant Free spectral range (see also FSR) Phase shift Complex frequency deviation Center wavelength of the passband Permittivity of free space Fiber–chip coupling losses Bandgap wavelength Insertion loss Coupling angle Phase shift Intrinsic losses Resonant frequency of ring resonator n Phase of the coupler Coefficient of thermal expansion Amplitude decay time constant 3 dB bandwidth Polynomial Atomic force microscope All-pass filter xiii xiv ASE B B(z) BCB BH BHF BPF BW c c0 CAIBE Cn Cp CROW CTE CVD cw DEMUX DFB DGD DI dk DR-RCL DTFT DUT E e(t) E(t) E-beam ECL ECR-CVD EIM EO F FHD FSK FSR FWHM FWM GRIN h(n) HEMT I ICP-RIE Abbreviations Amplified spontaneous emission Intensity enhancement or buildup factor Polynomial Benzocyclobutene Buried heterostructure Buffered hydrofluoric acid Bandpass filter Modulation bandwidth Phase velocity of the ring mode (c = c0/neff) Vacuum speed of light Chemically assisted ion beam etching Auger recombination coefficient AUGER recombination coefficient Coupled resonator optical waveguides Coefficient of thermal expansion Chemical vapor deposition Continuous wave Demultiplexer Distributed feedback Differential group delay Deionized Length of the ring waveguides Double ring resonator coupled lasers Discrete-time Fourier transform Device under test Complex mode amplitude Energy amplitude Time-dependent mode amplitude Electron beam External cavity laser Electron cyclotron resonance chemical vapor deposition Effective index method Electro-optic Finesse Flame hydrolysis deposition Frequency-shift keying Free spectral range Full width at half maximum Four wave mixing Gradient index Impulse response of a filter High-electron-mobility transistors Intensity/current Inductively coupled plasma reactive ion etching Abbreviations IPA K k L LC lk LN LPCVD m MBE MEMS mh ml MIBK mlp MMI mn mo MOVPE MQW mt MUX MZI neff ng NMP NSOM OEC OLCR OSA OSP P P(t) p(t) PBS PD PECVD PhC PIC PLC PMD PMMA pn PRRM xv Isopropanol or 2-propanol Contrast/confinement factor Vacuum wavenumber Circumference of the ring/optical output Lattice constant Length of the coupler (note: this is not the coupling length) Lithium niobate Low-pressure chemical vapor deposition Integer Molecular beam epitaxy Microelectromechanical system Effective hole masses Effective electron masses Methyl isobutyl ketone Effective hole masses Multimode interference Mode number Mode order Metal organic vapor-phase epitaxy Multiple quantum well Effective electron masses Multiplexer Mach–Zehnder interferometer Effective refractive index Group refractive index n-methyl-2-pyrrolidone or C5H9NO Near-field scanning optical microscopy Optimum end-fire coupling Optical low-coherence reflectometry Optical spectrum analyzer Optical signal processing Transmission power Time-dependent power Total energy stored in the ring Polarization beam splitter Photodiode Plasma-enhanced chemical vapor deposition Photonic crystal Photonic integrated circuit Polarization controller Polarization mode dispersion Polymethylmethacrylate Poles of H(z) Pulse repetition rate multiplication xvi PSTM Q QC QCSE QW R r RF RIBE RIE RPM RTFT RW RZ S SAMOVPE SCCM SCISSORS SE SEBL SEM SM SMSR SNOM SOA SOG SOI SPM STM STP T t TE Tg TIR TM TN(x) TO UMatrix vg w WDM WGM x0 xC Abbreviations Photon scanning tunneling microscope Quality factor Quantum cascade Quantum-confined Stark effect Quantum wells Effective radius of curvature/end-face reflectivity Radius Radio frequency Reactive ion beam etching Reactive ion etching Rounds per minute Real-time Fourier transformation Ridge waveguide Return-to-zero Optical path length Selective area metal-organic vapor-phase epitaxy Standard cubic centimeters per minute Side-coupled, integrated, space sequence of resonators Switching element Scanning electron-beam lithography Scanning electron microscope Switching module Side-mode suppression ratio Scanning near-field optical microscopy Semiconductor optical amplifier Spin on glass Silicon on insulator Scanning probe microscopy Scanning tunneling microscopy Standard temperature and pressure Characteristic matrix/temperature/tuning enhancement factor Coupling parameter/time Transverse electric Glass transition temperature Total internal reflection Transverse magnetic Nth-order Chebyshev polynomial Thermo-optic Unit matrix Group velocity Width Wavelength division multiplexing Whispering gallery mode 3 dB cutoff frequency Center frequency Abbreviations xn xP xS zm xvii Vector Changeover region on the passband Changeover region on the stopband Zeros of H(z) Chapter 1 Introduction Integrated ring resonators have emerged in the last years in integrated optics and have found their way into many applications and are still highly relevant both in applied and advanced research. Integrated ring resonators do not require facets or gratings for optical feedback and are thus particularly suited for monolithic integration with other components. The wavelength and thus frequency response from coupled ring resonators can be custom designed by the use of different coupling configurations. In this way for example, the response from ring resonator filters can be designed to have a flat top and steep roll of. Other coupling configurations lead for example to a ring resonator reflector device, which can be used on one side or on both sides of an integrated semiconductor optical amplifier serving as a laser. Numerous examples of ring resonator applications exist and several of them are highlighted in this book, demonstrating their unique use. Ring resonators do not only find applications in optical networks, they have recently been demonstrated to be used as sensors and biosensors. The book is organized as follows: Chap. 2 covers the main aspects of ring resonator theory. Chapter 3 gives an overview of the various fabrication methods and material systems. Chapter 4 serves as a brief introduction into the building blocks of ring resonator devices like couplers and bends. Chapter 5 describes the numerous applications of fabricated ring resonator devices. Chapter 6 highlights sensors and related applications whilst Chap. 7 provides a short introduction into whispering gallery mode resonators. The book ends with an outlook given in Chap. 8. The intention of the authors is to provide the reader with a comprehensive starting point into this hot topic of integrated ring resonators fulfilling the requirement of a true compendium. © Springer Nature Switzerland AG 2020 D. G. Rabus and C. Sada, Integrated Ring Resonators, Springer Series in Optical Sciences 127, https://doi.org/10.1007/978-3-030-60131-7_1 1 Chapter 2 Ring Resonators: Theory and Modeling One of the first papers to deal about the simulation of an integrated ring resonator for a bandpass filter has been published in 1969 by E. A. Marcatili. The layout of the channel dropping filter which he proposed is shown in Fig. 2.1. This can be regarded as the standard configuration for an integrated ring resonator channel dropping filter. Two straight waveguides also known as the bus or the port waveguides are coupled either by directional couplers through the evanescent field or by multimode interference couplers to the ring resonator. A simpler configuration is obtained, when the second bus or port waveguide is removed. Then the filter is typically referred to as “notch” filter because of the unique filter characteristic. In the following chapter, the ring resonator simulation model is described beginning with the basic notch configuration and adding more bus waveguides and ring resonators to eventually build a multiple coupled ring resonator filter. Different types of ring resonator simulation models will be explained, so as to be able to chose from a range of models which best suit the need. 2.1 Single Ring Resonators 2.1.1 Ring Structure The Basic Configuration The basic configuration, which consists of unidirectional coupling between a ring resonator with radius r and a waveguide, is described in Fig. 2.2, based on Yariv (2000, 2002). Defining that a single unidirectional mode of the resonator is excited, the coupling is lossless, single polarization is considered, none of the waveguide segments and coupler elements couple waves of different polarization, the various kinds of losses occurring along the propagation of light in the ring resonator filter are incorporated © Springer Nature Switzerland AG 2020 D. G. Rabus and C. Sada, Integrated Ring Resonators, Springer Series in Optical Sciences 127, https://doi.org/10.1007/978-3-030-60131-7_2 3 4 2 Ring Resonators: Theory and Modeling Fig. 2.1 Ring resonator channel dropping filter Fig. 2.2 Model of a single ring resonator with one waveguide in the attenuation constant, the interaction can be described by the matrix relation: E t1 E t2 = t κ −κ ∗ t ∗ E i1 E i2 (2.1) The complex mode amplitudes E are normalized, so that their squared magnitude corresponds to the modal power. The coupler parameters t and κ depend on the 2.1 Single Ring Resonators 5 specific coupling mechanism used. The * denotes the conjugated complex value of t and κ respectively. The matrix is symmetric because the networks under consideration are reciprocal. Therefore: 2 2 κ + t = 1 (2.2) In order to further simplify the model, E i1 is chosen to be equal to 1. Then the round trip in the ring is given by: E i2 = α · e jθ E t2 (2.3) where α is the loss coefficient of the ring (zero loss: α = 1) and θ = ωL/c, L being the circumference of the ring which is given by L = 2π r, r being the radius of the ring measured from the center of the ring to the center of the waveguide, c the phase velocity of the ring mode (c = c0 /neff ) and the fixed angular frequency ω = kc0 , c0 refers to the vacuum speed of light. The vacuum wavenumber k is related to the wavelength λ through: k = 2π /λ. Using the vacuum wavenumber, the effective refractive index neff can be introduced easily into the ring coupling relations by: β = k · n eff = 2π · n eff λ (2.4) where β is the propagation constant. This leads to: θ= kc0 L r 2π · n eff · 2πr ωL = = k · n eff · 2πr = = 4π 2 n eff c c λ λ (2.5) From (2.1) and (2.3) we obtain: E t1 = −α + t · e− jθ −αt ∗ + e− jθ (2.6) E i2 = −ακ ∗ −αt ∗ + e− jθ (2.7) −κ ∗ 1 − αt ∗ e jθ (2.8) E t2 = This leads to the transmission power Pt1 in the output waveguide, which is: Pt1 = |E t1 |2 = α 2 + |t|2 − 2α|t| cos(θ + ϕt ) 1 + α 2 |t|2 − 2α|t| cos(θ + ϕt ) (2.9) where t = |t| exp( jϕt ), |t| representing the coupling losses and ϕ t the phase of the coupler. 6 2 Ring Resonators: Theory and Modeling The circulating power Pi2 in the ring is given by: Pi2 = |E i2 | = α 2 1 − |t|2 2 1 + α 2 |t|2 − 2α|t| cos(θ + ϕt ) (2.10) On resonance, (θ + ϕ t ) = 2π m, where m is an integer, the following is obtained: Pt1 = |E t1 |2 = (α − |t|)2 (1 − α|t|)2 (2.11) and Pi2 = |E i2 | = 2 α 2 1 − |t|2 (1 − α|t|)2 (2.12) A special case happens when α = |t| in (2.11), when the internal losses are equal to the coupling losses. The transmitted power becomes 0. This is known in literature as critical coupling, which is due to destructive interference. In using the above equations, it is possible to get a good idea of the behavior of a simplified basic ring resonator filter configuration consisting of only one waveguide and one ring. The wavelength dependent filter characteristic for a ring resonator configuration with a radius of r = 148 µm with matched coupling and loss coefficient, derived using (2.1)–(2.11), is shown in Fig. 2.3. This model can be extended to suit the requirement of various types of ring resonator configurations. The next configuration which is discussed is the basic ring resonator add-drop configuration, consisting of one input, one output waveguide and the ring resonator. The four ports of the ring resonator are referred to in the following as input port, throughput port, drop port and add port (Fig. 2.4). Fig. 2.3 Notch type ring resonator filter characteristic 2.1 Single Ring Resonators 7 Fig. 2.4 Model of a basic add-drop single ring resonator filter The ring resonator simulation model has been updated according to Fig. 2.4. For simplification E i1 is as defined before equal to 1. The throughput mode amplitude in the first waveguide is given by: E t1 = t1 + 2 e jθ −κ1 κ1∗ t2∗ α1/2 2 1 − t1∗ t2∗ α1/2 e jθ |t1 |2 +|κ1 |2 =1 = 2 t1 − t2∗ α1/2 e jθ 2 1 − t1∗ t2∗ α1/2 e jθ = t1 − t2∗ αe jθ 1 − t1∗ t2∗ αe jθ (2.13) In this calculation, α 1/2 and θ 1/2 are used which are the half round trip loss and 2 and θ = 2θ 1/2 . phase respectively. It is α = α1/2 Now, the mode amplitude in the ring has to pass the second coupler as can be seen from the schematic to become the new dropped mode amplitude E t2 . The dropped mode amplitude in the second waveguide is then given by: E t2 = −κ1∗ κ2 α1/2 e jθ1/2 1 − t1∗ t2∗ αe jθ At resonance, the output power from the drop port is given by: Pt2-Resonance = (2.14) 8 2 Ring Resonators: Theory and Modeling |E t2-Resonance | = 2 1 − |t1 |2 · 1 − |t2 |2 · α (1 − α|t1 t2 |)2 (2.15) The throughput port mode amplitude E t1 (2.13) will be zero at resonance for identical symmetrical couplers t 1 = t 2 if α = 1, which indicates that the wavelength on resonance is fully extracted by the resonator. The value of α = 1 can only be achieved by the implementation of gain incorporated in the ring resonator to compensate the waveguide losses. The value of the loss coefficient α is fixed in a purely passive ring resonator. A possibility of achieving minimum intensity (Pt1 = 0) at resonance of the output transmission Pt1 at the throughput port is to adjust the coupling parameters t 1 , t 2 to the loss coefficient α. From (2.13) we obtain: t1 (2.16) α = t2 If the ring resonator is lossless (α = 1), then the couplers have to be symmetric in order to achieve minimum intensity. The transmission of a lossless ring resonator add drop filter with radius of r = 148 µm is shown in Fig. 2.5. There are different kinds of requirements on the simulation of various kinds of ring resonator configurations. Starting of with the given equations satisfies most basic models. The ring model can for example be divided into more segments to account for different materials or modified waveguide paths. Examples of calculated models can be found in Rabus (2002) and Michelotti et al. (2004). Ring Resonator Parameters Ring resonator filters can be described by certain figures of merit which are also generally used to describe optical filters. One important figure is the distance between Fig. 2.5 Add drop ring resonator filter characteristic 2.1 Single Ring Resonators 9 resonance peaks, which is called the free spectral range (FSR). A simple approximation can be obtained for the FSR by using the propagation constant from (2.4), neglecting the wavelength dependency of the effective refractive index. β ∂n eff β ∂β =− +k ≈− ∂λ λ ∂λ λ (2.17) This leads to the FSR λ, which is the difference between the vacuum wavelengths corresponding to two resonant conditions. FSR = 2π λ=− L ∂β ∂λ −1 ≈ λ2 n eff L (2.18) Note that (2.18) is for the resonant condition next to a resonance found for the used propagation constant. If the wavelength dependence of the effective index can not be neglected, it can be incorporated in the following way to obtain a modified version of (2.17). ∂β k = − ng ∂λ λ (2.19) where ng is the group refractive index, which is defined as: n g = n eff − λ ∂n eff ∂λ (2.20) The group refractive index can be used instead of the effective index whenever appropriate avoiding the approximation and obtaining more accurate values. The modified FSR λ is then given by: FSR = λ= λ2 ng L (2.21) The next parameter of importance is the resonance width which is defined as the full-width at half-maximum (FWHM) or 3 dB bandwidth 2δλ of the resonance lineshape. Using the expressions for the drop port (2.14, 2.15): ∗ 2 2 −κ1 κ2 α1/2 e jθ1/2 2 = 1 |κ1 | |κ2 | α 1 − t ∗ t ∗ αe jθ 2 (1 − α|t1 t2 |)2 1 2 (2.22) Assuming that the coupling coefficients are real, lossless and without a phase term, (2.22) can be written as: 2 κ1 κ2 α1/2 2 1 κ1 κ2 α1/2 = 2 (1 − t1 t2 α)2 1 − 2t1 t2 α cos(θ ) + (t1 t2 α)2 (2.23) 10 2 Ring Resonators: Theory and Modeling Then: 2(1 − t1 t2 α)2 = 1 − 2t1 t2 α cos(θ ) + (t1 t2 α)2 (2.24) For small θ, using the real part of the series expansion of the Euler formula: θ2 2 (2.25) (1 − t1 t2 α)2 t1 t2 α (2.26) cos(θ ) = 1 − Therefore: θ2 = This equation can further be simplified if the loss in the ring is negligible and the coupling is symmetric (t = t 1 = t 2 ) to: θ= 2 1 − t2 1 − t2 = t2 t (2.27) Using (2.5) and (2.17) to translate into the wavelength domain: 2δλ = λ2 1 − t 2 π Ln eff t (2.28) The expression which is commonly used can be obtained by assuming weak coupling and λ δλ: FWHM = 2δλ = κ 2 λ2 π Ln eff (2.29) Another parameter which can now be directly calculated from the parameters in the previous chapter is the finesse F of the ring resonator filter. It is defined as the ratio of the FSR and the width of a resonance for a specific wavelength (FWHM): F= λ t κ1 π FSR = =π ≈ 2 FWHM 2δλ 1 − t2 κ (2.30) A parameter which is closely related to the finesse is the quality factor Q of a resonator, which is a measure of the sharpness of the resonance. It is defined as the ratio of the operation wavelength and the resonance width: Q= n eff L t n eff L λ =π F = 2δλ λ 1 − t2 λ (2.31) 2.1 Single Ring Resonators 11 The quality factor can also be regarded as the stored energy divided by the power lost per optical cycle. The intensity in the ring resonator can be much higher than that in the bus waveguides, as the traveling wave in the ring resonator interferes constructively at resonance with the input wave and thus the amplitude builds up. In addition to this intensity increase, the field also experiences a phase-shift of an integral multiple of 2π in one round trip. The intensity enhancement or buildup factor B is given by (for a configuration shown in Fig. 2.2): 2 E i2 2 −ακ ∗ = B= ∗ − jθ E i1 −αt + e (2.32) For a configuration like Fig. 2.4, the buildup factor is given by: 2 2 −κ1∗ = 1 − t ∗ t ∗ αe jθ i1 1 2 Er B = E (2.33) On resonance, the intensity enhancement factor is: −κ1∗ 2 B = 1 − t1∗ t2∗ α (2.34) For a lossless resonator and setting κ 1 = κ 2 = κ which is 1, B can be written as: B= 1 (2.30) F −−−→ κ2 π (2.35) This equation directly relates the intensity enhancement factor B to the finesse F. For the all-pass configuration and on resonance, the buildup factor is given by (t 1 = t 2 = t): B= 1+t 1−t (2.36) Ring resonators can be used for nonlinear optical devices since the intensity in the resonator can be much higher than in the bus waveguide. Examples of devices utilizing nonlinearities in ring resonators are given in Sects. 5.7 and 5.8. Loss in Ring Resonator In the previous sections, losses are basically included by insertion of the parameter α in the formulas. They can originate either from light scattering, material absorption or bending losses. The first two causes are well known in light propagation in straight waveguides and, consequently will not further discussed in this chapter (the reader is referred to Hunsperger 2002 for details). In curved waveguides, instead, the effective 12 2 Ring Resonators: Theory and Modeling index decreases as light propagates radially away from the ring-center, due to the increase in the phase velocity. As a consequence, light radiates at a certain (caustic) point, corresponding to the condition of matching between the waveguide effective index and ring cladding’ refractive index respectively. When the refractive index contrast n = nc − ns between the ring (nc ) and the surrounding (ns ) is high, the caustic point is moved far away from the ring core leading to radiation losses. Being connected to the curvature of the waveguide, they are referred to bending losses α bend . In case of planar/channel waveguides they scale with the curvature radius r with a complex expression that can be approximated by semi-empirical relations: αbend |planar αbend |channel Prad = − ln Pinc ∼ α0 e − 23 · 2π λ r √ 3 2 n c −n 2s n c2 − 1 · 2π ·r n s 3 4π ∼ 0.72 (n c − n s )10 7.6 λ λ n 2c −n 2s n 2s (2.37) where Prad is the radiated power due to the bend, Pinc in the incident power, α 0 is a constant depending on the waveguide thickness. It clearly emerges that low losses can be achieved by higher refractive index contrast n and larger curvature radius. In Fig. 2.6 an typical example of the dependence of r respect the nc value is reported at the wavelength λ = 1.55 µm, assuming the ring embedded in a material with refractive index ns = 1.55 and a reference radius r 0 = 12 µm. A microring with radius 12 µm requires a material with refractive index ∼2 for bending losses <2 dB/cm. If higher losses can be accepted, nc must be higher than 1.9 and hence n ≈ 0.35 in order to have an acceptable performance. The Time Dependent Relations Before going on to extend the previous model incorporating additional ring resonators, the time dependent relations are adapted from Little et al. (1997) for the basic ring resonator add-drop configuration. Like in the previous model, it is assumed that the ring supports a traveling wave of amplitude E(t), P(t) represents Fig. 2.6 Refractive index of the microring material against the ring radius, yielding bending losses of 2 and 100 dB/cm, respectively for λ = 1.55 µm and ns = 1.55. Courtesy of dr Koechlin Manuel. https://doi. org/10.3929/ethz-a-006 037351 2.1 Single Ring Resonators 13 the total power flowing through any cross section of the ring waveguide at time t. The ring is regarded as an oscillator of energy amplitude e(t), normalized so that p(t) represents the total energy stored in the ring. Energy and power in the ring are related through: p(t) = |e(t)|2 = P(t) 2πr vg (2.38) vg is the group velocity. The ring resonator has a resonant frequency of ωR and amplitude decay time-constant of 1/τ. The decay rate and the power exciting the ring resonator are related to each other. The decay rate includes the power coupled to the transmitted wave 1/τ tr , the power lost due to intrinsic effects 1/τ ie , and power coupled to the output waveguide 1/τ t2 . This leads to: 1 1 1 1 = + + τ τtr τie τt2 (2.39) The time rate of change in ring energy can then be written as: d e= dt jω R − 1 e − κ ∗ · E i1 τ (2.40) The relation between the coupling parameter κ and the decay rates of the transmitted wave 1/τ tr and the output waveguide 1/τ t2 , is determined by power conservation. The case is considered, when the ring resonator is excited to an energy of |e0 |2 , no output waveguide is present and no input wave E i1 . The ring energy, with no intrinsic loss, then decays as follow: −2t |e(t)| = |e0 | exp τtr 2 2 (2.41) From these set of (2.14)–(2.17), the power transfer characteristic for the drop port can be calculated with the input wave E i1 being proportional to exp(jωt): e= −j 2 τtr j(ω − ω R ) + 1 τ E i1 (2.42) From this equation, we can calculate the transmitted wave at the throughput port: ∗ E t1 = E i1 − κ e = j(ω − ω R ) + 1 τ + jκ ∗ j(ω − ω R ) + 1 τ 2 τtr E i1 (2.43) Finally the drop port power transfer characteristic is obtained by using the equation for power conservation (note, E i2 = 0): 14 2 Ring Resonators: Theory and Modeling 4 |E t2 |2 = |E i1 |2 − |E t1 |2 = 2 2 τt2 τtr |e| = |E i1 |2 τt2 (ω − ω R )2 + τ1 (2.44) This equation can be simplified further if both waveguides couple equally to the ring, then τ t2 = τ tr . The Z-Transform Another approach to simulate ring resonator filters is by using the Z-transformation to describe the spectral and temporal response of ring resonator filters, described in detail in Madsen and Zhao (1999). Z-transform relationships for basic optical elements were first developed for fiber optic filters in Moslehi et al. (1984). This technique is used in pole-zero diagrams to design ring resonator filters in Kaalund and Peng (2004). In the following chapter, the Z-transform for the basic add-drop configuration (consisting of one ring resonator and two waveguides) is given which shall serve as a starting point for the calculation of more complex devices. Z-transforms are discussed extensively in the aforementioned literature on digital signal processing, therefore only a brief introduction is given here. The Z-transform is an analytic extension of the discrete-time Fourier transform (DTFT) which converts a discrete time signal into a complex-variable frequency signal: ∞ H (z) = h(n)z −n (2.45) n=−∞ Z is a complex variable and h(n) is the impulse response of a filter or the values of a discrete signal. Each term z−n represents a delay. Of particular interest is when the absolute value of |z| = 1. This is called the unit circle in the complex plane where pole and zero locations of the function H(z), which is evaluated along z = exp(jω), are plotted. In the case of ring resonator filters, |z| = 1 corresponds to resonant frequencies. A complete roundtrip of the unit circle corresponds to the FSR of the filter. Poles and zeros are related to the filter’s frequency spectrum by their position on the complex plane. A zero positioned on the unit circle results in zero transmission at the frequency corresponding to the angle of this zero. A pole on the other hand on the unit circle causes unity transmission at the corresponding frequency. As poles and zeros move away from the unit circle, their effect on the magnitude spectrum is reduced. A linear discrete system with input signals x has the following output signal: y(n) = b0 x(n) + b1 x(n − 1) + · · · + b M x(n − M) − a1 y(n − 1) − · · · − a N y(n − N ) The Z-transform for this type of filter is then given by: (2.46) 2.1 Single Ring Resonators 15 H (z) = 1 M −m m=0 bm z N + n=1 an z −n = B(z) A(z) (2.47) A(z) and B(z) are Mth and Nth-order polynomials. The zeros zm and poles pn of H(z) can be derived from the roots of the polynomials as follows: H (z) = z N −M M m=1 N n=1 (z − z m ) (z − pn ) = B(z) A(z) (2.48) where is the gain of the filter. In passive filters, the transfer function can never be greater than 1, so has a maximum value determined by max{|H(z)|z=exp(jω) } = 1 for these types of filters. A ring resonator has a response which can be expressed in the form: ∞ H (z) = n=0 a n z −n = 1 1 − az −1 (2.49) The basic configuration of an add-drop ring resonator filter (Fig. 2.4) is the simplest filter with a single pole response. The sum of all optical paths for the drop port is given by: E t2 (z) = −κ1 κ2 αz −1 1 + t1 t2 αz −1 + · · · E i1 (z) (2.50) Using the Taylor series expansion, the equation can be simplified to give the drop port transfer function: √ −κ1 κ2 αz −1 E t2 (z) = H21 (z) = E i1 (z) 1 − t1 t2 αz −1 (2.51) There is a single pole at t 1 t 2 α. As the matrix is symmetric, the transfer function H 21 (z) is equal to H 12 (z). The sum of all optical paths for the throughput port resulting in its transfer function H 11 (z) is given by: E t1 (z) = t1 − κ12 t2 αz −1 1 + t1 t2 αz −1 + · · · E i1 (z) κ12 t2 αz −1 E i1 (z) = t1 − 1 − t1 t2 αz −1 t1 − t2 αz −1 E i1 (z) = 1 − t1 t2 αz −1 t1 − t2 αz −1 E t1 (z) ⇒ H11 (z) = = E i1 (z) 1 − t1 t2 αz −1 (2.52) 16 2 Ring Resonators: Theory and Modeling Similarly, the transfer function H 22 (z) can be derived to be: t2 − t1 αz −1 E t2 (z) = E i2 (z) 1 − t1 t2 αz −1 H22 (z) = (2.53) The obtained results for each transfer function can be expressed in two different matrix forms. The first form relates the input ports to the output ports and is called the scattering matrix (see also 2.1) which is given by: E t1 (z) E t2 (z) E i1 (z) = SRR (z) E i2 (z) √ −1 SRR (z) = t1 −t2 αz −κ1 κ2 αz −1 −1 1−t1 t√ 1−t1 t2 αz −1 2 αz −κ1 κ2 αz −1 t2 −t1 αz −1 1−t1 t2 αz −1 1−t1 t2 αz −1 (2.54) The second form relates the quantities in one plane to the ones in another plane as can be seen in Fig. 2.6. This type of matrix is called the transfer matrix which is given by: E i1 (z) E t1 (z) = RR (z) RR (z) = 1 √ E i2 (z) E t2 (z) −κ1 κ2 αz −1 1 − t1 t2 αz −1 −t2 + t1 αz −1 t1 − t2 αz −1 1 + κ1 κ2 αz −1 (2.55) The scattering matrix form is used to express the implication of power conservation and reciprocity. The transfer matrix form is used for describing multi-stage filters. It is therefore also referred to as the chain matrix. This type of transfer matrix is suitable to describe multiple serially coupled ring resonators. The transfer matrix to be used for describing multiple parallel coupled resonators has the form Grover et al. (2002): E t1 (z) = RR (z) E i2 (z) √ −1 1 κ1 κ2 αz −1 1 − t1 t√ 2 αz RR (z) = t1 − t2 αz −1 −κ1 κ2 αz −1 t1 t2 − αz −1 E i1 (z) E t2 (z) (2.56) Using the different simulation techniques described in this chapter it is possible to build a simulation model for all relevant lateral and vertically coupled ring resonator filter configurations. Incorporating Loss in Ring Resonator Filters In the previous section, losses were briefly discussed to explain the nature of the α parameter included in the formulas. In particular, loss in ring resonator filters scales the spectral curves without changing them significantly if the loss is not too large. 2.1 Single Ring Resonators 17 Different types of losses have been considered and described in literature to account for various fabrication methods and tolerances. A few examples will be given in the following paragraph to give a starting point for the calculation and simulation of losses in ring resonators. A loss which is most obvious is the radiation loss which occurs in the curved section of ring resonators (Chin and Ho 1998). The radiation loss will become large for a large surface roughness. The surface roughness on the other hand can induce contradirectional coupling which can degrade the performance of a ring resonator filter and even can cause a splitting of the resonant peak (Little et al. 1997). The calculation of the radiation and scattering losses in ring resonators is presented in detail in Rabiei (2005). Here a perturbative method for the calculation of losses due to an arbitrary variation in the refractive index of the core or due to an arbitrary variation in the shape of ring resonator is described. Loss in ring resonator devices can also be used advantageously as was demonstrated using (2.16). An analysis of how loss and gain can be used to tune, trim, or compensate the wavelength response of ring resonator filters is described in Little and Chu (2000). In the following chapter the basic model of a ring resonator is extended to analyze a racetrack shaped ring resonator. 2.1.2 Racetrack Shaped Resonators The equations in the previous chapter described the general behavior of a basic ring resonator filter. However, to simulate certain ring resonator configurations, this set of equations has to be extended. In a waveguide-coupled ring resonator filter, the coupling gap size is determined by the amount of coupling required and the coupling length available. Using lateral coupling, a larger gap is desirable as it increases the fabrication tolerance. In this case, for a given coupling coefficient, the gap size can be enlarged if the coupling distance is increased to obtain a racetrack shaped ring resonator (Fig. 2.7). The coupling distance can be increased by using a lateral or vertical geometry (Chin and Ho 1998). In the case of the racetrack shaped ring resonator, the coupling distance is approximately the length of the straight sections (if no coupling occurs before the actual coupler region starts), which are tangential to the circular arcs at output and input ports. At the transitions between the curved and the straight sections, the mode will change adiabatically between the radial mode in a curved waveguide and the normal mode in a straight waveguide. As the straight sections are lengthened the radius of the curved sections must be reduced if the total cavity length is to remain constant. This can not be always achieved in practical applications. In the case of racetrack resonators, it is important to consider the variation of phase difference ϕ which occurs in the coupling region in both couplers between t and κ. The phase difference is length-dependent and affects the output characteristics, not 18 2 Ring Resonators: Theory and Modeling Fig. 2.7 Z-transform layout of an add-drop ring resonator filter only in the magnitude but also in the resonant conditions. This phase difference can be implemented in (2.13) and (2.14) using the method described in Lee et al. (2004). For the throughput port: E t1 = 2 e jθ t1 t1∗ e j2ϕt1 − κ1 κ1∗ e− j2ϕκ2 e jϕt2 t1 e jϕt1 − t2∗ α1/2 2 1 − t1∗ t2∗ α1/2 e jθ e jϕt1 e jϕt2 (2.57) For the drop port: E t2 = −κ1∗ κ2 α1/2 e jθ1/2 e− jϕκ1 e− jϕκ2 1 − t1∗ t2∗ αe jθ e jϕt1 e jϕt2 (2.58) The resonant condition (θ + ϕ t1 + ϕ t2 ) = 2π m has changed slightly compared to (2.9). The output transmission at resonance is no longer independent of t and κ which can be seen comparing the relevant terms in (2.50) and (2.51). This leads to a significant performance change and confirms the importance of taking into account the phase difference when analyzing racetrack shaped ring resonator configurations. The phase difference is not only of importance in directional couplers, but also in multimode interference (MMI) couplers. An analysis of a racetrack shaped ring resonator add-drop filter having two MMI couplers is given in Caruso and Montrosset (2003). The MMI length should be selected in order to satisfy the π /2 relation between the phases of the transmission and the coupling terms to obtain a symmetric transmission characteristic of the throughput and of the drop port. If the π /2 relation is not satisfied, a strong asymmetry in the transmission characteristic will be obtained. A further description of the implementation of directional and MMI couplers in ring resonators is given in Sect. 4.1. 2.2 Double Ring Resonators 19 2.2 Double Ring Resonators Double ring resonators offer the possibility of realizing a “box like” filter characteristic which is favorably used in optical networks. This is not the only advantage, but also from the point of characterization, two rings if coupled in series have the drop port in the same direction as the input port, which is also convenient for interconnection of many 2 × 2 devices. Serially and parallel coupled ring resonator configurations have been described in detail in Chu et al. (1999), Little et al. (1997, 2000), Melloni (2001), and Emelett and Soref (2005). In the serially coupled configuration, each ring resonator is coupled to one another, and a signal that is to be dropped from the input port to the drop port must pass sequentially through each resonator. Because of this sequential power transfer, all resonators must be precisely resonant at a common wavelength. The resulting resonant line shape in the series configuration is determined physically by the separations between the ring resonators. In the parallel-coupled configuration, all resonators are coupled to both the input and drop port waveguides, but usually not directly to one another (the resonators can also be coupled to one another resulting in a wavelength selective reflector as is described in Sects. 2.2.2 and 2.3.1). The resonators are instead indirectly coupled to each other by the optical path lengths along the input and output waveguides that interconnect them. These lengths determine the details of the resonant line shapes. An optical signal in the parallel configuration passes through all ring resonators simultaneously. This softens the requirement that the resonances of each ring have to be precisely identical. Nonaligned resonant frequencies instead lead to multiple peaks, or ripple in the lineshape. The ready to use transfer functions of serially and parallel coupled double ring resonators will be described in the following sections. 2.2.1 Serially Coupled Double Ring Resonator The schematic of a serially coupled double ring resonator is depicted in Fig. 2.8. From this model and using the same procedure as in Sect. 2.1.1 the fields depicted in Fig. 2.8 can be calculated as follows: θ1 E 1a = −κ1∗ E i1 + t1∗ α1 e j 2 E 1b θ1 θ1 E 1b = t2∗ α1 e j 2 E 1a − κ2∗ α2 e j 2 E 2b θ2 θ2 E 2a = κ2 α1 e j 2 E 1a + t2 α2 e j 2 E 2b θ2 E 2b = −κ3∗ E i2 + t3∗ α2 e j 2 E 2a (2.59) (2.60) (2.61) (2.62) 20 2 Ring Resonators: Theory and Modeling Fig. 2.8 A racetrack shaped ring resonator filter with integrated platinum resistors on top of the curved sections and the coupler (contact pads visible) θ1 E t1 = t1 E i1 + κ1 α1 e j 2 E 1b θ2 E t2 = t3 E i2 + κ3 α2 e j 2 E 2a (2.63) (2.64) where α1,2 = α R11/2 ,R21/2 represent the half round trip loss coefficients of ring resonator one and two respectively. From (2.58) to (2.63) the general expressions for the transfer functions for the throughput and the drop port can be derived. A simplified form can be obtained by assuming a coupler without losses and symmetric coupling behavior, setting t = t* and κ = −κ* (note that the phase factor −j has not been introduced into the assumption and can be added if required) which gives the ready to use amplitude forms for the throughput port (E i2 = 0): −t1 κ12 α1 e jθ1 t3 α2 e jθ2 − t2 E t1 = E i1 1 − t3 t2 α2 e jθ2 − t2 t1 α1 e jθ1 + t3 t1 α1 α2 e jθ1 e jθ2 (2.65) and for the drop port: θ1 θ2 E t2 κ3 κ2 κ1 α1 α2 e j 2 e j 2 = jθ E i1 1 − t3 t2 α2 e 2 − t2 t1 α1 e jθ1 + t3 t1 α1 α2 e jθ1 e jθ2 (2.66) For realizing a double ring resonator with maximally flat response, first the input/output waveguide ring coupling coefficient κ 1 (κ 3 ) has to be determined. To simplify the model further, it is defined that the input/output waveguide-ring coupling coefficients κ 1 = κ 3 . The calculation of the coupling coefficients to obtain the appropriate coupling values between the two ring resonators in order to achieve maximally flat response can be made according to Emelett and Soref (2005) and Little et al. (1997) by using the geometry and index profile shown in Fig. 2.9, where two coupled waveguides of width 2wp and 2wq with indexes of np and nq , surrounded by a cladding 2.2 Double Ring Resonators 21 Fig. 2.9 Two ring resonators coupled in series of n0 , at the plane of smallest separation 2s0 , defined as the center to center gap are shown. The approximate coupling coefficient is then given by: π R [αq (wq −2s0 )] ωε0 cos k x p,q wq 2 2 n p − n0 e κ= αq 2 Pp Pq k x2p + αq2 × αq cos k x p w p sinh αq w p + k x p sin k x p w p cosh αq w p (2.67) Using: Pp,q β p,q 1 w p,q + = 2ωμ0 α p,q k x p,q = α p,q = (2.68) n 2p,q k 2 − β 2p,q (2.69) β 2p,q − n 20 k 2 (2.70) where Pp,q is the mode power, k x p,q is the transverse propagation constant of the core, and α p,q is the decay constant in the cladding, β p,q is the propagation constant, ω is the circular frequency, ε0 is the permittivity of free space, all within waveguide 22 2 Ring Resonators: Theory and Modeling p or q. The refractive index n0 of the surrounding media is set equal to 1 (air). The coefficient R is defined as the effective radius of curvature of the ring and is given by: R= r1 r2 r1 + r2 (2.71) where r 1,2 represents the radius of ring one and two respectively. The radii of the rings are chosen to satisfy the 2π phase shift condition with the completion of one round trip in the ring resonator which is given by: mλm = 2πr1,2 n eff (2.72) In order to realize a flat passband, the analysis of the power loss ratio, which is the ratio of total input power to power present at the detected port, is required. The power loss ratio in polynomial form is given by: PLR where by: 2 4 2 μ1 μ41 4 2 2 2 =1+ 1 − 2μ2 ω + (2.73) ω + μ2 − 2 4 μ41 μ42 t2 Ei = E ω is the frequency deviation which is related to the resonant frequency ωm ω = ω − ωm (2.74) The coefficient μ is the fractional power coupled. It is given by: μ21 = κ12 vg1 κ 2 vg1 vg2 and μ22 = 2 2 2πr1 4π r1r2 (2.75) The goal of realizing a maximally flat response is obtained when the power loss ratio is zero at the defined resonance. This is the case for: μ22 = 0.250μ41 (2.76) Assuming identical rings, this leads to the coupling coefficient: κ22 = 0.250κ14 (2.77) Using these equations, it is possible to design a double ring resonator filter with maximally flat response for the drop port. A serially coupled double ring resonator opens up the possibility of expanding the FSR to the least common multiple of the FSR of individual ring resonators. This is done by choosing different radii in the double ring resonator. In the case of different radii, the light passing through the double ring resonator is launched from the drop 2.2 Double Ring Resonators 23 port when the resonant conditions of both single ring resonators are satisfied. The FSR of the double ring resonator with two different radii is expressed by: FSR = N · FSR1 = M · FSR2 (2.78) which leads to: FSR = |M − N | FSR1 · FSR2 |FSR1 − FSR2 | (2.79) where N and M are natural and coprime numbers. The use of two ring resonators with different radii opens the possibility to realize a larger FSR than would be achieved using only a single ring resonator. The transmission characteristic of the throughput port has mainly a Lorentzian shape. A box-like filter response using two different radii can only be realized by using two parallel coupled double ring resonators (R1 = R2 ). The use of such configurations as optical filters is limited by unwanted additional resonant peaks. Investigations on these types of filters have been performed in Suzuki et al. (1995) and Sorel et al. (1999). Different types of waveguide coupled ring resonator configurations to expand the free spectral range have been analyzed in Hidayat et al. (2003). 2.2.2 Parallel Coupled Double Ring Resonator The schematic of a parallel coupled double ring resonator is shown in Fig. 2.10. From this model, the fields in Fig. 2.10 can be calculated as follows: θ1 E 1a = −κ1∗ E i1 + t1∗ α1 e j 2 E 1b (2.80) θ1 θ2 E 1b = t2∗ α1 e j 2 E 1a − κ2∗ e jθW κ4 α2 e j 2 E 2a − t4 E i2 (2.81) θ1 θ2 E 2a = −κ3∗ e jθW t1 E i1 + κ1 α1 e j 2 E 1b + t3∗ α2 e j 2 E 2b (2.82) θ2 E 2b = −κ4∗ E i2 + t4∗ α2 e j 2 E 2a Fig. 2.10 Index profile and geometry of coupled waveguides (2.83) 24 2 Ring Resonators: Theory and Modeling θ1 θ2 E t1 = t3 e jθW t1 E i1 + κ1 α1 e j 2 E 1b + κ3 α2 e j 2 E 2b (2.84) θ2 θ1 E t2 = t2 e jθW t4 E i2 + κ4 α2 e j 2 E 2a + κ2 α1 e j 2 E 1a (2.85) θW = k W · n Weff · (2.86) where θ W is the phase shift introduced by the segment of length with effective refractive index n Weff of the input waveguide joining both ring resonators. From (2.79) to (2.85) the general expressions for the transfer functions for the throughput and the drop port can be derived. A simplified form can again be obtained by assuming couplers and bus waveguides without losses and symmetric coupling behavior, setting t = t* and κ = −κ* (note that the phase factor −j has not been introduced into the assumption and can be added if required) which gives the amplitude forms for the throughput port (E i2 = 0): θ f (a + bc) a + bc E t1 jθW jθW 21 h+ + κ3 t4 α22 e jθ2 = t3 t1 e + t3 κ1 α1 e E i1 1−d 1−d (2.87) And for the drop port: θ θ2 a + bc f (a + bc) E t2 j 21 2 jθ1 h+ + t2 κ4 α2 e jθW 2 (2.88) = κ1 κ2 α1 e + κ2 t1 α1 e E i1 1−d 1−d where: a= κ3 t1 e jθW 1 − t3 t4 α22 e jθ2 (2.89) θ1 κ1 α1 e j 2 b= 1 − t3 t4 α22 e jθ2 (2.90) θ1 c= κ1 t2 α1 e j 2 1 − t1 t2 α12 e jθ1 f = κ2 κ4 α2 e jθW 2 1 − t1 t2 α12 e jθ1 h= κ1 t2 α1 e j 2 1 − t1 t2 α12 e jθ1 (2.93) d =b· f (2.94) (2.91) θ2 (2.92) θ1 2.2 Double Ring Resonators 25 Similar to the serially coupled double ring resonator, it is possible to increase the overall FSR of this configuration by adjusting the length of the waveguide joining the two ring resonators. The parallel configuration can be treated as a grating. Constructive interference of the reflected waves from each ring resonator is obtained by choosing to be equal to an odd multiple of a quarter wavelength. = (2m + 1) λ0 4n Weff (2.95) where λ0 is the center wavelength of the passband. If the length is chosen such that the FSR of the ring resonators and the FSR of the “grating” obey the following condition: FSR = NRing · FSRRing = MGrating · FSRGrating (2.96) The Vernier effect (Griffel 2000) causes the transmission peaks of the ring resonators within the overall obtained FSR to be suppressed, which results in a larger FSR than would be achieved for a single ring resonator. The distance between the resonators can be calculated in this case using: = Mgrating n eff πr NRing n Weff (2.97) These set of equations can of course be transferred to multiple coupled parallel ring resonator configurations as will be shown in Sect. 2.3. Parallel Coupled Double Ring Resonator with Coupling Between the Two Ring Resonators A special double ring resonator configuration is obtained, when coupling between the two ring resonators is allowed (Fig. 2.11). The reflective properties of such a device have been analyzed in Chremmos and Uzunoglu (2005) and the following transfer functions are based on this reference. A similar wavelength reflective filter consisting of four interacting ring resonators has been presented in Poon et al. (2004d) which is going to be described in Sect. 2.3.1 (Fig. 2.12). Using the fields and coupling coefficient in Fig. 2.11, it is possible to derive the general expressions for describing the transfer characteristics of this type of configuration. A simplified expression for the reflectivity at port E i1 (denoted by the symbol ← as the superscript) is obtained for the lossless case and symmetric coupling coefficients between the ring resonator and the bus waveguide (κ = κ 1 = κ 3 ): 26 2 Ring Resonators: Theory and Modeling Fig. 2.11 Parallel coupled double ring resonator Fig. 2.12 Double ring resonator with inter ring coupling 2 2 2 t 1+t 2 2 cos θ − 2 ( 2t ) 4 κ22tκ ← E i1 = 2 2 2 2 t 1+t 2 cos θ − 2 ( 2t ) + κ22tκ (2.98) The phase factor for the distance between the rings does not appear and therefore does not have an influence on the transfer characteristic. This is a special property of the double coupled configuration and does not apply for multiple serially coupled ring resonators. Different reflectivity profiles can be realized using appropriate coupling 2.2 Double Ring Resonators 27 coefficients. Weakly coupled ring resonators lead to single reflection peaks in the reflectivity function where the height of the peak depend on the value of the coupling coefficients. In order to realize a maximally flat response with a single peak, the coupling coefficients have to obey the following equation: κ2 κ2 = √ √ 2 1 + t 2 + 2t (2.99) The corresponding FWHM is given by: κ2 FWHM = 4 sin−1 κ 3 22 t (2.100) The expression for the reflectivity at port E i1 incorporating loss parameter α is given by: 2 2 2 κ2 κ (α +1) 2 ← 2αt E i1 = 2 2 2 t2 (1+α 2 t 2 ) 2 κ2 (1−α 2 t 2 ) cos θ − + 2αt 2αt ⎡ t 1+α 2 t 2 cos θ − 2 ( 2αt ) + ⎣ · 2 sin2 θ + 1−α 1+α 2 2 ⎤ 2 2 2 t2 (1−α )(1−α t ) 2 2αt 1+α ⎦ (2.101) So far ready to use transfer functions for single and double ring resonator configuration have been presented. In the following chapter, different calculation methods are presented to derive the transfer function of different types of multiple coupled ring resonators. 2.3 Multiple Coupled Resonators The use of multiple vertical or lateral coupled ring resonator configurations opens up the possibility to realize custom designed transmission functions and thus is suitable for a wide variety of device implementations (Schwelb and Frigyes 2001). Vertical and lateral ring resonator architectures where the rings are either coupled in series or in parallel have been implemented in the past. A detailed theoretical analysis of a vertically stacked multiple coupled ring resonator, where the ring resonators are on top of each other is presented in Sumetsky (2005). The use of multiple coupled ring resonator configurations together with other photonic devices like grating couplers or Mach Zehnder interferometers increases the functionality and transmission characteristic even further (Weiershausen and Zengerle 1996). One of the main targets 28 2 Ring Resonators: Theory and Modeling of realizing optical filters is to tailor the passband shape. In analogy to electronic filter design, Butterworth (Butterworth 1930) and Chebyshev type of optical filters are preferred. Butterworth filters are maximally flat and do not have any ripples in the passband. The shape of the transfer function does not change for higher order filters except that the roll off becomes steeper as the order of the filter increases. Chebyshev filters have a steeper roll off than Butterworth type of filters and have ripples either in the passband or stopband which distinguishes Chebyshev type I and type II filters. The square magnitude response of a Butterworth filter has the form (Madsen and Zhao 1999): |HN (x)|2 = 1+ 1 2N (2.102) x x0 where x 0 is the 3 dB cutoff frequency. The response of Chebyshev type I and II filters have the form (Madsen and Zhao 1999): Type I 1 1 + y 2 TN2 xxC −1 x for |x| ≤ 1 cos N cos −1 TN (x) = cosh N cosh x for |x| > 1 |HN (x)|2 = (2.103) Type II 1 |HN (x)|2 = 1+ y2 TN2 TN2 ( xS xP xS x (2.104) ) where T N (x) is the Nth-order Chebyshev polynomial, y determines the passband ripples, x C is the center frequency of the filter, x P and x S define the changeover region on the passband and stopband respectively. 2.3.1 Serially Coupled Ring Resonators One of the first papers to present a calculation method for serially coupled ring resonator synthesis is (Orta et al. 1995). The method is based on the Z-transformation using the transfer matrix (see 2.54). The Z-transformation has also been used in Madsen and Zhao (1996) to simulate and fabricate a serially coupled ring resonator filter. The transfer matrix method has also been used in Melloni and Martinelli (2002) and Poon et al. (2004b) for simulating and designing various serially coupled ring 2.3 Multiple Coupled Resonators 29 resonator configurations. Serially coupled ring resonators are also referred to as coupled-resonator optical waveguides (CROW) (Poon et al. 2004c). A model for deriving the transfer functions of serially coupled ring resonators based on the time dependent calculation as described in Sect. 2.1.1 is presented in Little et al. (1998). Another method of simulating the transfer function of serially coupled ring resonators is by using a characteristic matrix approach presented in Chen et al. (2004). These different methods for analyzing serially coupled ring resonators will be used in the following to derive the transfer functions. The Z-transformation is used to start with in the beginning. In order to describe a serially coupled ring resonator, the filter can be broken down into two components, a symmetrical directional coupler and a pair of uncoupled guides as shown in Fig. 2.13 (Orta et al. 1995). Another way to describe the transfer function of a directional coupler is to use a chain matrix, which is given by: HkC = je Fig. 2.13 Photograph of a serially coupled triple ring resonator jβlk −e− jβlk cot(φk ) csc(φk ) − jβlk e cot(φk ) −e−2 jβlk csc(φk ) (2.105) 30 2 Ring Resonators: Theory and Modeling where φ k is referred to as the coupling angle and lk is the length of the coupler (note: this is not the coupling length). The chain matrix of the uncoupled guides is given by: HkR =e jβdk 1 0 0 e−2 jβdk (2.106) where d k is the length of the ring waveguides. The chain matrix for the entire system is then expressed by: csc(φk ) z −1 e− jψk cot(φk ) csc(φ0 ) cot(φ0 ) H= cot(φk ) z −1 e− jψk csc(φk ) cot(φ0 ) csc(φ0 ) (2.107) k=N ,1 where ze jψk = −e jβ(lk +lk−1 +2dk ) (2.108) As previously described in Sect. 2.1.1 the elements of the matrix H are N degree polynomials. The chain matrix can also be compared to the chain matrix derived in (2.54). Of interest is again the transfer function for the throughput and the drop port, both related to the signal at the input port. The polynomials are given by: E t1 = H11 (z) = E i1 N ak z −k (2.109) bk z −k (2.110) k=0 and E t2 = H21 (z) = E i1 N k=0 The transfer functions of the filter are now based on the definition of these polynomials. Assuming, that the filter is lossless, the scattering matrix is unitary for |z| = 1. On |z| = 1, z* = z−1 , then the relationship between (2.108) and (2.109) can be written as follows: 1 1 ∗ ∗ (2.111) H11 (z)H11 ∗ = 1 + H21 (z)H21 ∗ z z Using this equation, it is possible to calculate H 11 (z) for a given H 21 (z). The coupling angles φ k (k = 0, …, N) and the phase shift ψ k (k = 1, …, N) are calculated as follows. First, a superscript is introduced which denotes elements belonging to the structure formed by the first n + 1 coupler. Then the elements of the chain matrix [N −1] [N −1] [N ] and H21 are related to H11 relative to the first (N − 1) ring resonators, H11 2.3 Multiple Coupled Resonators 31 [N ] and H21 through: csc(φ N ) z −1 e− jψ N cot(φ N ) cot(φ N ) z −1 e− jψ N csc(φ N ) [N −1] H11 [N −1] H21 = [N ] H11 [N ] H21 (2.112) This leads to the equations for the coefficients of the polynomials (2.108 and 2.109), which are given by: ak[N −1] = ak[N ] csc(φ N ) − bk[N ] cot(φ N ) (2.113) [N ] [N ] cot(φ N ) + bk+1 csc(φ N ) e jψ N bk[N −1] = −ak+1 (2.114) and where k = 1, …, (N − 1) and: −1] [N −1] a [N = b−1 =0 N (2.115) Then the coupling angle of the Nth coupler is given by: cos(φ N ) = b0[N ] a0[N ] = ] a [N N ] b[N N (2.116) Equation 2.115 is satisfied if the ratio is real. Next step is to determine the phase shift ψ k using (2.115) and (2.113). All other coefficients follow the same procedure. In order to start this calculation method and derive a transfer filter characteristic, [N ] has to be determined. As stated before in Sect. 2.3, a bandpass the polynomial H21 filter characteristic is preferred. When using the Z-transform, the resonant frequencies of the ring resonator filter are all placed on the circumference |z| = 1. For a Butterworth type filter, the “zeros” are located on z = −1. The zeros for a Chebyshev type of filter are given by: ! " 2 j arccos sin( FWHM ) cos (2k−1)π 4 2N z 0k = e k = 1, . . . , N (2.117) This is an intuitive approach to design ring resonator filters, however it is challenging to extract the poles of the frequency response. The time dependent relations which have been presented for a single ring resonator can be extended to multiple serially coupled resonators. The response of the first ring (counted from the bottom of the ring filter) can be written as (Little et al. 1998): 32 2 Ring Resonators: Theory and Modeling e1 = −κ ∗ E i1 j ω R1 + 2 −κ1∗ ∗2 −κ N −1 j ω R2 ...+ j ω RN ⎧ ⎫ 1 ⎪ ω − ω − j , n = 1, N ⎪ Rn ⎨ ⎬ τn ωn = ω − ω Rn − j τ1n − j τ1tr , n = 1, N ⎪ ⎩ω − ω − j 1 − j 2 , N = 1 ⎪ ⎭ Rn τn τtr (2.118) where ω is the optical frequency of the input wave, ωRn is the resonant frequency of ring resonator n and ωn is the complex frequency deviation. The energy decay rate of each ring is given by τ n . The response of resonator N can be expressed by a product of continued fractions: e N = E i1 N Tn n=1 where TN = T1 = ∗ −κn−1 j ωn + −κ ∗ j ω R1 2 ∗ −κn−1 j ωn−1 + ∗2 −κn−2 2 −κ ∗ j ωn−2 ...+ j ω1 R1 (2.119) The coefficients for maximally flat and Chebyshev filter characteristics are given in Table 2.1 for two to six serially coupled ring resonators (Little et al. 1997). Table 2.1 Coefficients for maximally flat and Chebyshev filter characteristics No. Maximally flat Chebyshev 2 κ1∗2 = 0.250κ ∗4 κ1∗2 = 0.250κ ∗2 (1 + 2y) 3 κ1∗2 = κ2∗2 = 0.125κ ∗4 κ1∗2 = κ2∗2 = 2 0.125κ ∗4 1 + 1.5y 3 4 κ1∗2 = κ3∗2 = 0.100κ ∗4 κ2∗2 = 0.040κ ∗4 5 κ1∗2 = κ4∗2 = 0.0955κ ∗4 κ2∗2 = κ3∗2 = 0.040κ ∗4 6 κ1∗2 = κ5∗2 = 0.0915κ ∗4 κ2∗2 = κ4∗2 = 0.0245κ ∗4 κ3∗2 = 0.0179κ ∗4 y determines the passband ripples of the Chebyshev filter 2.3 Multiple Coupled Resonators 33 Another method of calculating the transfer functions of serially coupled ring resonator filters is by using a so called characteristic matrix approach, which has been presented in Chen et al. (2004). The method is based on defining the optical paths which an optical signal travels form the input port to the drop port. There are several paths and the shortest path is called the common path or the zeroth-order path which is defined to be unity. Looking at a serially coupled triple ring resonator, the light using the first order paths for example has three choices, one additional ring resonator path and the common path. The mth order transfer function is related to the m + 1th order transfer function by: ⎤ ⎡ ⎤ ⎡ ⎤ T11 T12 T13 H1,m H1,m+1 = ⎣ H2,m+1 ⎦ = ⎣ T21 T22 T23 ⎦ · ⎣ H2,m ⎦ = T · Hm H3,m+1 T31 T32 T33 H3,m ⎡ Hm+1 (2.120) t ij are the transfer functions of the additional path in ring resonator i, with previous path ends in ring resonator j. T is called the characteristic matrix. Using the coefficients for the ring resonators as described previously for symmetric coupling (t = t* and κ = −κ*), T is given by: ⎤ −κ 2 t1 t2 α1 e jθ1 1 t 2 2 0 2 ⎥ ⎢ −κ 2 ⎥ jθ =⎢ ⎣ t2 t3 α2 e 2 1 1 t32 3 ⎦ t3 t4 α3 e jθ3 1 1 1 ⎡ TDropPort (2.121) The general expression for the characteristic matrix for a filter consisting of n ring resonators is given by: ⎤ −κ 2 t1 t2 α1 e jθ1 1 t 2 2 0 . . . 0 2 ⎥ ⎢ ⎢ t t α e jθ2 1 1 −κ32 0 . . . 0 ⎥ 2 ⎥ ⎢ 23 2 t3 ⎥ ⎢ =⎢ ⎥ . . . 1 . . . 1 . . . 0 ⎢ ⎥ ⎥ ⎢ −κn2 ⎦ ⎣ . . . 1 . . . . . . 1 tn2 tn tn+1 αn e jθn 1 . . . . . . 1 1 ⎡ TDropPort (2.122) The general expression for the transfer function for the drop port is then given by: HDropPort j θk , , k k κk k αk e = UMatrix − TDropPort k = 1, . . . , n where U Matrix is the unit matrix. (2.123) 34 2 Ring Resonators: Theory and Modeling Filter synthesis using (2.121) and (2.122) can be done by solving a matrix eigenvalues equation. The poles of a filter function correspond to unity minus the eigenvalues of T DropPort . The eigenvalues and power coupling ratios for a maximally flat transfer function are given in Table 2.2 assuming lossless devices. Using the aforementioned techniques, it is possible to find the transfer functions for arbitrary serially coupled ring resonators. Each method has its pros and cons and therefore it is left to the designer to choose the right method which seems convenient to solve the problem. When designing ring resonator filters, it is appropriate to evaluate the technological feasibility of certain parameters like coupling coefficients and loss in order to easily transfer the design to fabrication. A special serially coupled ring resonator design (Fig. 2.14) has been proposed and analyzed in Poon et al. (2004a). The following calculation method is based on this literature. Depending on the number of rings used the filter can either be reflecting or nonreflecting. The filter acts as a reflector for an odd number of rings (N ≥ 3), whereas a nonreflecting filter is obtained for an even number of rings (N ≥ 4). The transfer functions are derived by using a transfer matrix method, starting in defining a vector x n , which represents the field component in ring resonator n − 1: Table 2.2 Eingevalues and power coupling ratios for a maximally flat transfer function No. Eigenvalues (= 1 − Poles) Power coupling ratios 2 0.63 + 0.32i; 0.63 − 0.32i 0.5; 0.2; 0.5 3 0.73 + 0.42; 0.71; 0.73 − 0.42i 0.5; 0.14; 0.14; 0.5 4 0.78 + 0.45i; 0.77 + 0.17i; 0.77 − 0.17i; 0.78 − 0.45i 0.5; 0.13; 0.09; 0.13; 0.5 5 0.81 + 0.46i; 0.8 + 0.26i; 0.81; 0.8 − 0.26i; 0.81 − 0.46i 0.5; 0.13; 0.08; 0.08; 0.13; 0.5 10 0.86 + 0.48i; 0.85 + 0.42i; 0.86 + 0.33i; 0.88 + 0.21i; 0.9 + 0.07i; 0.9 − 0.07i; 0.88 − 0.21i; 0.86 − 0.33i; 0.85 − 0.42i; 0.86 − 0.48i 0.5; 0.12; 0.07; 0.07; 0.07; 0.07; 0.07; 0.07; 0.07; 0.12; 0.5 Chen et al. (2004) Fig. 2.14 Components of a serially coupled ring resonator filter 2.3 Multiple Coupled Resonators 35 ← ← xn = E t E i Ei Et T (2.124) n The arrows used as superscripts are as described earlier for the double ring the direction of the propagating field, clockwise or anticlockwise without mixing of waves between the two directions. The coupling between the ring resonators can be represented by the following 4 × 4 matrix (n ≥ 0): ⎤ 0 0 0 0⎥ ⎥ =⎣ −t 1 ⎦ · x n = M P · x n 0 0 κ κ ∗ 0 0 − κ1 tκ ⎡ xn+1 −t κ ⎢−1 ⎢ κ 1 κ t∗ κ (2.125) Assuming only the phase matched waves are being coupled (L Coupler λ). The vector xn is related to x n by the following propagation matrix: ⎡ ⎢ xn = ⎢ ⎣ 0 0 0 0 0 jβr (2π−θ ) e 0 e− jβr θ π (N − 2) θ = 2π − N 0 e jβr (2π−θ ) 0 0 ⎤ e− jβr θ 0 ⎥ ⎥ · xn = M Q · xn 0 ⎦ 0 (2.126) Combining (2.124) and (2.125): xn+1 = M P · xn = M P · M Q · xn = MT · xn (2.127) For an N type ring resonator configuration with N > 2, 2.126) yields: x N = MTN −1 · M P · x0 = M A · x0 (2.128) Only the components of vector xin hold the transfer functions, therefore the transfer functions of the ring resonator configuration are derived using the relation for the coupling to the external waveguide and the phase relations in the first resonator: xin = M Pin · xin θ Et0 = Etin e− jβr 2 ← ← ← ← θ E i0 = E tin e jβr 2 Ei0 = Ei N e jβr (2π−θ ) E i0 = E i N e− jβr (2π−θ ) ← ← θ θ E t N = E iin e− jβr 2 Et N = Eiin e jβr 2 (2.129) Using (2.127) and (2.128), x N and x0 can be expressed by elements of x in . Equation 2.127 can then be rewritten as: 36 2 Ring Resonators: Theory and Modeling m M Pin xin = MTN −1 M P wM Pin xin ⇒ xin = M B xin (2.130) ← where m and w represent matrices which express the terms E in , Ein and Ei0 , Ei0 , using components of vector x in respectively. The matrix M B can then be expressed by: m −1 MTN −1 M P wM Pin M B = M P−1 in (2.131) If only one input is considered as in the previous ring resonator examples, xin can be expressed by: ← xin = 0 E 1 E rin i in T (2.132) ← The reflection and transmission function Eiin and E rin can then be derived using elements of matrix M B and solving the following matrix equation: M B 4,2 1−M B 4,4 1 1 M B 2,4 − 1−M B 2,2 Eiin ← E rin = M B 4,3 1−M B 4,4 M B 2,3 1−M B 2,2 (2.133) The following equations are also valid for the solutions: ← M B 3,2 Eiin + M B 3,3 + M B 3,4 E tin = 1 ← M B 1,2 Eiin + M B 1,3 + M B 1,4 E tin = 0 (2.134) In using the above equations, it is possible to calculate the reflectance and the transmittance spectra of this type of serially interring coupled ring resonator. 2.3.2 Parallel Coupled Ring Resonators Parallel coupled ring resonators have been addressed in literature and the transfer functions have been derived by several methods. One of the advantages of parallel coupled ring resonators over serially coupled ring resonators is that their transfer functions are less sensitive to fabrication tolerances, as each ring resonator can compensate errors in any of the others. Two configurations are discussed, one where the ring resonators are coupled to two input/output waveguides and the other, where all share one input/output waveguide. 2.3 Multiple Coupled Resonators 37 Coupled to Two Input/Output Waveguides As can be seen from Fig. 2.15, parallel coupled ring resonators coupled to two waveguides share the same input, throughput, drop and add port. The synthesis of the transfer functions of parallel coupled ring resonators using a recursive algorithm is presented in Little et al. (2000). A complex matrix formalism employing racetrack ring resonator filters is derived in Griffel (2000). A technique using simple closed-form formulas to determine the Q factor of each involved ring resonator which leads to the coupling coefficients is demonstrated in Melloni (2001). These different methods for analyzing the transfer functions will be used in the following. The model which has been presented in Fig. 2.10 can be easily extended for multiple parallel coupled ring resonators. The distance between the uncoupled ring resonators is chosen so that the transfer functions of each ring resonator add in phase. The transfer function derived by the recursive algorithm used in Little et al. (2000) is given by: Tn = E tin E tOn Et = Rn − −1 j2θWn−1 Ei Rn − Tn−1 e Fig. 2.15 Ring resonator configuration with interring coupling 38 2 Ring Resonators: Theory and Modeling μin μon 2 2 j ω + 21 μi,o + 21 μi,o n n i,o 2 μn = Rn − 2 2 j ω + 21 μi,o + 21 μi,o n n Rn = − E ti,o n (2.135) where the indices i, o correspond to the through responses of each ring resonator n in the waveguides joining the ring resonators and ω is the frequency deviation away from resonance. The term μ is related to the coupling coefficient κ (2.74): μi,o n = κni,o vgn 2πrn (2.136) The recursion is started with T 1 = R1 . Loss can also be incorporated into this algorithm by substituting j ω with j ω + 1/τ. In this type of synthesis, the transfer function is directly related to the coupling coefficient to obtain any desired filter shape. In the methods described earlier, the transfer functions are rational polynomials related to frequency, wavelength or z where the coefficients of the polynomials are adjusted for any specific filter function. In using the recursive algorithm, it is possible to suppress unwanted sidelobes by apodization, which is realized by adjusting the coupling coefficients properly. A straight forward method of designing parallel coupled ring resonator filters is presented in Melloni (2001). The filter shape can be calculated by using the given specifications for bandwith, FSR, out of band rejection and selectivity. The formulas for a parallel N coupled ring resonator filter are as follows: FSR gn FWHM √ 2n − 1 π gn = 2 sin 2N Qn = (2.137) The coupling coefficients are given by: π2 κn = 2Q 2n 4Q 2n 1+ 2 −1 π (2.138) A specific filter characteristic can be derived by using this method and the relations described in Sect. 2.1.1. For deriving the transfer functions for parallel coupled racetrack shaped ring resonators, the matrix formalism described in Griffel (2000) is used. The parallel coupled filter can be broken down into two components, similar to the method shown for the serially coupled ring resonator filter, into a ring resonator coupled to two waveguides and into a pair of uncoupled guides as shown in Fig. 2.16 (Fig. 2.17). 2.3 Multiple Coupled Resonators 39 Fig. 2.16 Photograph of a parallel coupled triple ring resonator Fig. 2.17 Schematic of a parallel coupled ring resonator filter The transfer matrix for the ring resonator coupled to two waveguides is given by: ⎛ ⎛← ⎞ a1n a2n −bn2 0 Ei a2n ⎜ ⎜ ⎟ 1 ⎜ 0 E ⎜ i⎟ a1n ⎜← ⎟ =⎜ ⎜ ⎝ Et ⎠ 0 − ab1nn ⎝ b n 0 Et n a2n 0 bn a1n a1n a2n −bn2 a1n 0 ⎞ ⎛ ⎞ ← − ab2nn ⎟ ⎜ Ei ⎟ 0 ⎟ Ei ⎟ ⎟·⎜ ← ⎟ ⎟ ⎜ 0 ⎠ ⎝ Et ⎠ 1 Et a 2n (2.139) n+1 The transfer matrix for the pair of uncoupled waveguides is given by: ⎛← ⎞ ⎞ ⎛← ⎞ ⎛ jβW L W n Ei 0 0 0 Ei e ⎜ ⎟ − jβW L W n ⎟ ⎜ ⎜ 0 ⎟ 0 0 e ⎜ ⎜ Ei ⎟ ⎟ · ⎜ Ei ⎟ ⎜← ⎟ =⎜ ← ⎟ jβW L W n ⎠ ⎝ 0 0 0 e ⎝ Et ⎠ ⎝ Et ⎠ − jβW L W n 0 0 0 e Et Et n n+1 The coefficients a1n , a2n and bn are given by: κ1n κ2n e− j(2βW L Cn +β R πrn ) 1 − t1n t2n e−2 j(βW L Cn +β R πrn ) t2n e− jβW L Cn − t1n e− j(3βW L Cn +2β R πrn ) = 1 − t1n t2n e−2 j(βW L Cn +β R πrn ) bn = a1n (2.140) 40 2 Ring Resonators: Theory and Modeling a2n = t1n e− jβW L Cn − t2n e− j(3βW L Cn +2β R πrn ) 1 − t1n t2n e−2 j(βW L Cn +β R πrn ) (2.141) The arrows used as the superscripts indicate whether the field is propagating to the left or the right direction. Multiplying the transfer matrices in an alternating rhythm, the transfer functions for a parallel N coupled ring resonator filter can be derived. Note that in the calculation the propagation constant for the uncoupled waveguides and for the ring resonators is assumed to be the same for each one, respectively. The ← drop port E t1 and the throughput Ei N responses from the resulting Matrix H, where h represent the elements of the matrix, are then given by (assuming only one input, Ei1 = 1): ← E t1 = h 3,2 h 2,2 1 Ei N = h 2,2 ← where Et N = E i1 = 0 (2.142) As in the recursive algorithm mentioned earlier in this chapter, the coupling coefficients can also be varied to control the bandwidth of the filter and thus reducing the sidelobes by apodization. Several configurations to obtain a box-like filter response using an array of parallel coupled ring resonators are presented in Ma et al. (2005). A special configuration consisting of a parallel coupled double ring resonator (with two waveguides), serially coupled with a single ring resonator has been analyzed in Okamoto et al. (2003). Coupled to One Input/Output Waveguide The basic ring resonator filter configuration consisting of a ring and a waveguide is used to realize a multiple parallel coupled filter. Another term for parallel coupled ring resonators with only one input/output waveguides is side-coupled, integrated, space sequence of resonators (SCISSORS) (Heebner et al. 2002). The transfer functions of these types of filters can be derived using the methods and formulas described earlier in this chapter. In this chapter the focus lies on the optical properties of this kind of device which have been analyzed in detail in Heebner et al. (2002) and Pereira et al. (2002). The following expressions are based on this literature. In order to describe linear propagation effects, a pulse is considered, which travels through a single ring resonator, obtaining a frequency dependent phase shift that results in a delay or distorts the pulse shape (see also Sect. 2.1.1. The time dependent relations). The effective propagation constant for a resonator spacing of is then given by: β0 (ω) = n eff ω (ω) + c0 (2.143) where (ω) is the phase shift which a field acquires when traversing a ring resonator. It is derived from the transfer function of a single ring resonator (Fig. 2.2) where the 2.3 Multiple Coupled Resonators 41 throughput field is related to the input field (2.9). E t1 (ω) = e j(ω) E i1 (ω) t sin θ (ω) (ω) = π + θ (ω) + 2 arctan 1 − t cos θ (ω) (2.144) The transfer function of a single ring resonator can be expanded into two terms using the Taylor series, representing the transmitted (expanded about the normalized detuning θ 0 ) and the exponential phase shift (expanded about the transmitted phase shift of the carrier 0 ). The transfer function is given by: 3 H (ω) = e j =e j0 ∞ 1+ n=1 jn n! n 4 1 dm m × (θ − θ0 ) m! dθ m θ0 m=1 ∞ (2.145) Using this equation, the field at some point zl+1 expressed by the field at another point zl which is only a small distance δz away is given by (the transmitted phase shift induced by each ring resonator is assumed to be distributed over the separation , leading to an effective propagation constant which is independent of propagation distance): 0 n eff ω0 δz · El+1 (ω) = exp j + c0 3 n 4 ∞ ∞ j n n eff 1 δz d m m 1+ ωδz + El (ω) (θ − θ0 ) n! c0 m! dθ m θ0 n=1 m=1 (2.146) The Fourier transform of (2.145) leads to a difference equation for the transfer function expanded to two Tailor series (transmitted and exponential phase shift): Al+1 (t) = Al (t) ∞ + n=1 n ∞ j ∂ m j n n eff ∂ 1 δz dm δz + Al (t) j n! c0 ∂t m=1 m! dωm θ0 FSR ∂t (2.147) For weak coupling, (2.146) can be rewritten using: Al+1 (t) − Al (t) δz→0 dA −−−→ δz dz (2.148) leading to: ∞ j ∂ m dA 1 1 dm n eff ∂ A = − +j dz c0 ∂t m! ωm θ0 FSR ∂t m=1 (2.149) 42 2 Ring Resonators: Theory and Modeling This equation yields the group-velocity reduction and group-velocity dispersion including higher order dispersion. The group-velocity reduction, which is proportional to the inverse of the first frequency derivative of the propagation constant, is given by the term: dβeff 1 d n eff + = dω c0 dω 4r θ0 =0,t≈1 n eff 1+ F −−−−−→ c0 βeff = (2.150) where F is the finesse and r the radius of the ring resonator (see 2.30). The groupvelocity dispersion, which is proportional to the second frequency derivative of the effective propagation constant, is given by: 2 dβeff 1 d2 = dω2 dω2 √ π √ θ0 =± F 3 3 3F 2 −−−−−→ ∓ 2 4π FSR2 βeff = (2.151) The dispersion maxima are obtained at a detuning of θ0 = ± Fπ√3 . Higher order dispersion is derived in a similar way as described before. The expression for the third-order dispersion is given by the term: 1 d3 dω3 F3 4 θ0 =0,t≈1 −−−−−→ − 3 π FSR3 βeff = (2.152) All orders of dispersion have to be taken into account if the pulse bandwidth corresponds approximately to the resonance bandwidth given by the FWHM. Ring resonators are versatile devices and do not only exhibit linear properties, but can also be used to realize nonlinear effects. This can be accomplished by using a material system like InGaAsP or GaAs for example. The effective nonlinear propagation constant is given by (assuming that the nonlinearity of the bus waveguide does not contribute significantly and can be neglected): 1 d 1 d dθ d|E i2 |2 = d|E i1 |2 dθ d|E i2 |2 d|E i1 |2 8r 2 θ0 =0,t≈1 F −−−−−→ β nl π nl = βeff The linear propagation (2.148) can then be modified to: (2.153) 2.3 Multiple Coupled Resonators 43 ∞ n eff ∂ dA 1 1 dm = − +j dz c0 ∂t m! ωm θ0 m=1 j ∂ m A × β nl 2πr B|A|2 + FSR ∂t (2.154) where B is the intensity enhancement or buildup factor (see 2.32–2.36). This configuration of side-coupled ring resonators exhibits strong dispersive and nonlinear properties and also supports solitons. As fabrication technologies mature, integration of these kinds of devices becomes feasible. The following chapter highlights the realization and characterization of ring resonator devices in different material systems. 2.4 Microring Resonator Based Electro-optic Effect When a microring resonator is realized in a substrate showing electro-optic effect, it is possible to tune its resonance by applying a suitable electric field E. In this case the guided mode effective index undergoes to a variation: δn eff = ∂n eff 1 3 ∂n eff δn = − n reo E ∂n ∂n 2 (2.155) where r eo is electro-optic coefficient the By recalling that the sensitivity of the microring resonator is defined as δλ = λδneff /ng , in electro-optic materials it results that: δλ = − ∂n eff λ 1 3 n reo E ∂n n g 2 (2.156) that represents the wavelength variation induced by a change in the refractive index. Equivalently, the electro-optic turnability T is often used by normalizing the sensitivity to the applied electric field E. Finally, δλ can be expressed in function of the Q value and it is straightforward to verify that high Q-factor resonators with require lower applied electric field thanks to the sharper resonances. It is worth mentioning that E can be written in term of the Voltage applied across the electrodes and its intensity depends on the geometry of the microring resonator. 2.5 Microring Resonator Modulator Microring resonator modulators have attracted significant scientific and technological interest in recent years (Sacher and Poon 2008) thanks to their low power 44 2 Ring Resonators: Theory and Modeling consumption and compact size. Their geometrical configuration can be quite simple, consisting of a ring coupled to a straight optical waveguide. In this case a continuouswave (CW) incoming optical wave is modulated by varying a certain physical parameter of the microring resonator in a controlled way. This can be achieved by varying the refractive index of the microring, the losses or the coupling efficiency between the microring and the bus waveguide respectively. Among the others, modulation by refractive index variation has been demonstrated to be quite promising because it acts directly on the optical length of the ring. The modulation of the effective index in the ring can be achieved exploiting different mechanisms such as, for instance, temperature variations and the electro-optic effect. The first one presents relatively large time constants being therefore unsuitable for fast signals processing. The electrooptic effect instead has demonstrated to be finely tunable and as fast as needed. Amplitude modulators based on microrings are quite common and have already been demonstrated in polymers„ lithium niobate, silicon and compound semiconductor materials respectively, with typical modulation rates in the range of tens of gigahertz. Microring phase modulators have also been realized although with less success. A discussion of some modulators devices is presented in Chap. 5. As a final comment, it is worth mentioning to remember that in a ring modulator, the resonator is working at an operating wavelength lying on the slope of the resonance peak. As a consequence, the modulating the of optical length of the ring shifts the resonance peak, changing the transmission/reflection of the cavity. In general, a greater efficient modulation is expected at higher finesse and Q values. The best control in the ring modulator is normally obtained in the so-called linear regime, i.e. when the slope of the resonance is well approximated to a straight line. However, this configuration limits the modulation depth and introduces IL. Fast modulators rings have a typical Q values in the range of 5000–25,000: for higher Q the modulation speed is strongly limited due to the longer trapping time of light in the ring. 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Lett. 14, 483–485 (2002) Chapter 3 Materials, Fabrication and Characterization Methods Recently, advancing fabrication technologies enabled the realization of ring resonators in many material systems with excellent optical properties. In this chapter ring resonators made of different materials using corresponding manufacturing processes will be presented based on the current state-of-the-art in literature. Device performance details will be given in Chap. 5. There are principally two configurations for the coupling between the ring or disk resonator and the bus waveguides, namely, a vertical coupling configuration, where the bus waveguides are either on top or beneath the ring or disk resonator and the lateral coupling configuration, where the bus waveguides and the ring or disk resonator are in the same plane. The vertical coupling method allows the precise control of the coupling distance and thus the coupling coefficient by using epitaxial growth. In this configuration it is also possible to fabricate the ring and the bus waveguides out of separate materials which opens up the possibility of creating active ring or disk structures when using an appropriate material. Realizing vertically coupled ring or disk resonators increases the fabrication complexity because processes like wafer bonding, regrowth or re-deposition are required. The lateral coupling method is useful for realizing ring resonators with larger radius (>100 μm) utilizing a weak guiding waveguide layout where however the confinement of the waveguide mode is still high enough to fabricate ring resonators with negligible bending loss. Ring resonators with small radii have also been fabricated utilizing the lateral coupling scheme as will be shown in Chap. 5. Choosing a suitable waveguide design reduces the tight requirements of fabricating a very small coupling gap which is usually much less than 1 μm in the case of very strong guiding waveguides. The lateral coupling approach allows the use of multimode interference couplers with higher processing tolerances with respect to the power coupling coefficient which eliminates the fabrication of small (<1 μm) and deep coupling gaps. The incorporation of gain sections inside the ring resonator using a suitable material can be accomplished by selective area metal organic vapor phase epitaxy (SAMOVPE). © Springer Nature Switzerland AG 2020 D. G. Rabus and C. Sada, Integrated Ring Resonators, Springer Series in Optical Sciences 127, https://doi.org/10.1007/978-3-030-60131-7_3 47 48 3 Materials, Fabrication and Characterization Methods Both coupling schemes have advantages and disadvantages and it is up to the device designer to decide which one is more suitable. As underlined in Chap. 2, the following key parameters need to be defined in order to achieve a performant integrated ring resonator: • • • • • Free Spectral Range (FSR); Spectral Width of Resonance (FWHM); Finesse F; Quality (Q-) factor; Intensity enhancement I. Depending on the application, these parameters must be adjusted to fit the desired requirements and, consequently, the choice of the material must be adequately triggered. In general, the characteristic equations of microring resonators described in Chap. 2 have shown that smaller cavity are expected to provide better performances. In this case, however, bending losses set a lower limit for the practically possible radius. As a matter of fact, they depend significantly on the refractive index contrast of the microring resonator material and, therefore, are actually one of the main issues hindering the realization of low-loss devices. For this reasons, small rings with acceptable low bending losses have been proposed and realized only in high-contrast materials. Best configurations have been found in waveguides totally embedded in a low-index material to provide an adequate light confinement in the integrated microring resonators. The refractive index contrast is not the only one parameter to look for. In Telecom applications such as in Wavelength De Multiplexers (WDM), for instance, the definition number of channels is the one of driving force. If 32 channels in the C-band (λ = 1520–1560 nm) are processed, a finesse F ≈ 32 would be needed. With a 50 GHz channels separation (i.e. a dense WDM, or ~0.4 nm in the C-band), a FSR of 13 nm is consequently required, with a corresponding ring radius r = 12 μm and a minimal attenuation α R ≈ 13 cm−1 . These requirements imply that the microring resonator must be realized on materials compatible with the micro-scale structuring in nanoscale precision. High values of Finesse are of extreme interest also for other applications such as second harmonic generation and nonlinear optics in general, where high optical intensities are demanded. A microring with a finesse of 30, in fact, could guarantee a factor 10 of enhancement in the light at resonance. In that case, a material able to resist to high light power density without changing its properties is mandatory (Koechlin et al. 2009). For high-speed switching applications, instead, the maximum switching frequency (ν max) of the device should be considered. Since a large finesse or Q-factor reduces the maximum switching speed, for WDM applications an optimized finesse is therefore required, yielding a trade-off between the sensitivity and the switching speed of the resonator. In the same configuration stated before, i.e. a microring resonator of radius r 0 = 12-μm and made of and embedded waveguide with refractive index ng = 2.3, the finesse should be smaller than 50 if a modulation speed of 100 GHz is requested (Koechlin et al. 2009). 3 Materials, Fabrication and Characterization Methods 49 A more detail discussion of the devices’ characteristic will be dedicated in Chaps. 4 and 5. However, these examples show that the design of the microring resonator is the result of compromises and, in general, the best material is the one that minimize them. Material Choice for Optical Microring Resonators The choice of the material to achieve given performances starts from the best compromise among the following parameters: • • • • • adequate refractive index contrast n; high tunability; high optical transparency in the required spectral range; mechanical, thermal and photochemical stability on time; compatibility with micro-structuring and patterning techniques to define the desired geometry. Materials able to fulfil the requirements, at least partially, can be found among inorganic insulator oxides, semiconductors and polymers respectively. In order to achieve high refractive index contrasts, thin films, either bonded or grown, on another material with lower refractive index have been widely investigated. This parameter can be therefore finely tuned from the design point of view but can have a deep impact on the durability and mechanical resistance of the device. This is particularly true when polymers are exploited as low refractive index embedding material. On the other hand, polymers have proven to be easily patternable and compatible with photolithography design and therefore among the materials used in hybrid configurations. Tunability of a microring resonator is the most demanded feature, being connected to resonances shifts and light modulation. Among the others, the electro-optic effect is the tuning mechanisms that gained greatest attention. As a matter of fact, it allows fast responses (switching speeds >100 GHz) and can be fruitfully combined with other nonlinear optical properties. For this reason, inorganic and organic electrooptic materials have been exploited in electro-optic based devices. The most common non-centrosymmetric materials with high electro-optic coefficients are ferroelectric oxides such as BaTiO3 , KNbO3 , LiNbO3 . Apart oxides, hypothiodiphosphate crystal (Sn2 P2 S6 , SPS) as well as the organic N-dimethylamino-N-methyl-stilbazolium tosylate (DAST) and the well known semiconductors such as GaAs, GaN and AlN have been considered. Since the nineties, LiNbO3 has been playing a great role in the telecom applications as host material for commercially available high performant optical modulators and, consequently, has gained more attention than other oxides. The waveguide integration technology in this material has become very mature and already optimized for high volumes batch processing. In Table 3.1 the most common electro-optic materials are listed together with some of their properties for comparison. As it clearly emerges, although SPS presents an electro-optic effect 5 times greater than LiNbO3 , for instance, the figure of merit is only 20% higher. This is to say that the electro-optic coefficient is an useful indicator but cannot be used as 50 3 Materials, Fabrication and Characterization Methods Table 3.1 Materials for electro-optic microresonators (Koechlin 2009) and references therein cited Material LiNbO3 Wavelength [nm] Dielectric constant j Refractive index ni Electro-optic coefficient r ij [pm/V] Figure of merit ri j n i2 / j [pm/V] 633 3T = 28 n 3 = 2.2 T = 31 r33 5.4 633 3T 3T 3T 1T 1S T = 28 n 3 = 2.3 1.9 = 44 n 3 = 2.2 = 130 n 3 = 2.4 = 230 n 1 = 3.0 = 5.2 n 1 = 2.4 = 13 n = 3.5 T = 10 r13 T = 64 r33 T = 105 r33 T = 174 r11 T = 48 r11 r T = 1.2 KNbO3 633 BaTiO3 633 Sn2 P2 S6 633 6.9 3.5 6.8 DAST 720 GaAs 1020 GaN 633 T = 11 n = 2.35 T = 1.9 r33 1.0 633 T n = 2.0 T r13 = 1.0 0.4 AlN = 10 102 1.1 threshold to qualify the material performances. Semiconductors have 1/5 of the figure of merit of the oxides competitors but take advantage of an extremely advanced technology provided by microelectronics. Depending on the applications and the relative operational wavelengths, in principle the best material can be identified as the one optimizing the previously quoted parameters. The interest on micro-resonators has undergone a great step forward thanks to the strong improvement of the processing technologies needed for reproducible and affordable devices. However, the material’s choice cannot exempt from budget considerations in the perspectives of getting batch processing and commercially available solutions. As a consequence, despite of interesting performances, some alternatives have proved to be unrealistic to enter into the market and will be not treated in this book. Despite the promising properties of microring resonators proposed in a variety of materials like semiconductors (Xu et al. 2005, 2006; Niehusmann et al. 2004; Zhou and Poon 2006), silica (Little et al. 2004) and polymers (Leinse et al. 2005; Tazawa et al. 2006) in the last 20 years, improvements have been seeking for faster responses, wider tunability and spectra range. In summary, although polymers are surely attractive alternatives thanks to their easy-way of processing and structuring, they suffer from a relative low refractive index that impact on the minimum resonator size and consequently in the available spectral range. On the other hand, silica-based ring resonators (see Sect. 3.3) are unable to provide a fast nonlinear and electro-optical response and therefore has appeared less performant respect the other competitor materials. Among the others, semiconductor-based ring resonators have demonstrated to be the most promising: they have strongly benefitted from the advances in microelectronic technologies to realize efficient High-Q resonators with radii lower than 10 μm as presented in Sect. 3.4. The possibility of tuning the Silicon-based resonators by way of electrically-driven carriers injection in the core have increased their popularity in this field although limited to the infrared spectral range due to its material optical transparency. It is in this scenario that other materials have 3 Materials, Fabrication and Characterization Methods 51 been started to be investigated to overcome these limiting factors and among them, lithium niobate is surely the most promising as complementary to semiconductors. Its wide transparent spectral range as well as high electro-optic coefficient enables to conjugate fast response in a wavelength region not accessible for semiconductors. In the following sections the most promising materials to realize high quality microring resonators will be presented. Their performances but also their limits and constraints will be highlighted for further comparisons. Moreover, in the following chapters, dry and wet etching, wafer bonding techniques and other lithography applications for realizing laterally and vertically coupled ring resonator devices will be briefly explained. 3.1 Wafer Bonding Wafer bonding is referred to a process in which two similar or dissimilar semiconductor wafers are bonded with various crystallographic orientations and lattice constants to form a single substrate which then features specific properties. The bonding process is activated by temperature, force, chemicals or plasma. An overview on wafer bonding can be found in Alexe and Gösele (2004). Wafer bonding techniques can be divided into two groups, one using an intermediate layer (e.g., adhesion bonding, eutectic bonding) and another without using an intermediate layer (e.g., fusion bonding, anodic bonding) to realize the bond. Wafer bonding allows using the advantages of different materials, while avoiding their disadvantages, allowing combinations of materials otherwise unachievable with other techniques. Wafer bonding is commonly applied to form silicon-on-insulator (SOI) substrates. Bonding of wafers of different materials has attracted great interest lately, e.g., GaAs on Si (Georgakilas et al. 2002), or SiC on Si (Kim and Carpenter 2003). Different methods exist for bonding various materials and it is again up to the realized device which process is more suitable. In the following sections common wafer bonding methods are described. 3.1.1 Bonding with Intermediate Layer Adhesion Bonding Adhesive bonding uses photoresist, spin on glasses or polymers to deposit a planarizing material between two wafers. Such materials can be annealed at low temperature to provide a low-stress wafer stack. It is a relatively simple and inexpensive process. The use of polymers has the advantage of bonding samples which have been structured already which is the case for vertically coupled ring resonators, where the bus waveguides have been fabricated before the bonding takes place. 52 3 Materials, Fabrication and Characterization Methods Eutectic Bonding Eutectic bonding is a special kind of metal bonding, where the low melting temperature of the eutectic alloy is exploited to achieve low temperature bonding. Eutectic is a mixture of two or more elements and has a lower melting point than any of its constituents. Eutectic comes from the Greek word “eutektos” which means “easily melted.” Eutectic bonds are used when a hermetic or vacuum seal is required. Eutectic alloys which are used for example are gold–silicon, gold–tin, or lead–silicon. The metal is usually deposited by plating, while the silicon source can be the wafer or chemical vapor deposition (CVD). Solid–liquid mixing occurs at temperatures slightly above the eutectic point and a high contact force (40 kN). A gold–silicon eutectic bond for example is realized by coating a silicon wafer with ~500 nm gold. The Au–Si eutectic point is about 370 °C. Au atoms diffuse into Si and the eutectic alloy is formed. The bonding temperature is higher than the eutectic point which is due to solid–liquid inter-diffusion at the interface. 3.1.2 Bonding Without Intermediate Layer The requirements of the surface quality (cleanliness and roughness) and flatness of the used wafers are very tight when it comes to direct wafer bonding. There are basically three types of primary interactions which are responsible for forming a first bond, Van der Waals, electrostatic Columbic, and capillary forces. Van der Waals forces are, however, quite small and decrease very rapidly as the distance between two molecules increases. Covalent bonds are established, when the wafers come into very close contact. Electrostatic Coulomb forces between two surfaces are usually stronger than the interaction between two contacted samples if one of the surfaces has been electrically charged by adsorbing or desorbing electrons or ions. Capillary forces come into play when water is used in the bonding process. Water helps to activate the bonding process at room temperature. Due to the surface tension, the water between the two surfaces pulls the samples together and smoothens out any surface roughness present, thus increasing the contact area. During the following heating process, the water reacts with the surrounding oxide or diffuses away from the surface leading to the formation of covalent bonds. True crystal-to-crystal bonding is achieved by using hydro-phobic bonding which requires a removal of the naturally formed oxide present at the surface of the samples. Fusion Bonding Fusion bonding uses applied temperature and pressure and is used for example to bond silicon to silicon without depositing an intermediate SiO2 layer using the native oxide formation on the surface of the Si wafers. Fusion bonding is commonly used in mass production of bulk micromachined micro-electromechanical systems (MEMS) packaging. As the same materials are used in this bonding process, no thermal stress 3.1 Wafer Bonding 53 is induced, which results in a very strong bond strength. Initial bonding is performed in a temperature range between 300 and 800 °C, annealing is done between 800 and 1100 °C which strengthens the bond. This high annealing temperature is also a key drawback to fusion bonding. Alternatively work is being conducted by using plasma processing to reduce the annealing temperatures from ~1000 °C to the range between 200 and 300 °C. Regardless of this plasma pretreatment, most of the work performed on direct bonding of III/V materials uses hydrophobic surfaces, where the oxide has been removed, to assure a true crystal-to-crystal bond and good electrical contacting through the bond. Anodic Bonding Anodic bonding or electrostatic bonding is performed by applying a high electric field across the two substrates. Temperatures used in this process are ~400 °C. An example of this type of bonding is the bonding of glass/Si. Here a voltage of ~1.2 kV is applied. Silicon is attached to the positive, glass to the negative electrode. The positive ions in glass are attracted to the interface between Si/glass where a permanent chemical bond is formed. The used glass has to be of course electrically conductive. The Si/Si anodic bonding process, is of course also used, when an intermediate glass layer (0.5–4 μm) is present. Sputtering or evaporation of for example Pyrex™ or spin on glass (SOG) is used in this bonding process. The advantage is the use of a low voltage which is between 30 and 60 V. The temperature is in the range of 350–450 °C. 3.1.3 Benzocyclobutene Wafer Bonding As described in the previous sections, several bonding techniques exist. Due to the fact that benzocyclobutene (BCB) wafer bonding is widely used to fabricate vertically coupled ring and disk resonators, the BCB wafer bonding process will be briefly explained in this section. BCB wafer bonding was first presented in Sakamoto et al. (1998) for realizing electro-optic modulators on GaAs. A detailed description of a BCB bonding process for realizing vertically coupled ring resonators is presented in Christiaens et al. (2004), Christiaens (2005) which will be used in the following. BCB is distributed by The Dow Chemical Company under the trade name Cyclotene∗ .1 There are two varieties: the Cyclotene 3000 series resins (dry etch type) and the Cyclotene 4000 series resins (photosensitive type). Wafer bonding has so far been only demonstrated with the dry etch variety. The resins are derived from B-staged bisbenzocyclobutene-based (BCB) monomers. Typical properties of Cyclotene are: low curing temperature (~250 °C), excellent planarization properties, a dielectric constant between 2.65 and 2.5 (1 MHz–10 GHz) and low moisture uptake (<0.2%). One of the downsides of BCB is its insulating nature like all common 1® ™* Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow. 54 3 Materials, Fabrication and Characterization Methods polymers and the low thermal conductivity, which is not suitable for realizing active devices. The refractive index of two types of resins is shown in Fig. 3.1 (https://www. dow.com/cyclotene/solution/refwave.html). A schematic of a BCB bonding process is presented in Fig. 3.2. Principally the process flow for realizing vertically coupled devices is started by growing the waveguiding layers on a suitable substrate (e.g., InP). An etch stop layer is grown between the substrate and the waveguiding layers which is necessary for a later removal of 1.62 λ = 0.63 λ = 1.31 λ = 1.55 Index of Refraction 1.60 1.58 1.561 1.56 1.552 1.544 1.543 1.537 1.535 1.54 3022 (Hard Cure) 4024 (Hard Cure) 1.52 0.2 0.6 1.0 1.4 1.8 Wavelength (μm) Fig. 3.1 Index of refraction as a function of wavelength for photo Cyclotene (4024–40) and nonphoto Cyclotene (3022–46) resins after curing at 250 °C for 60 min Fig. 3.2 BCB wafer bonding process 3.1 Wafer Bonding 55 the substrate after bonding. After the growth of the layers, the bus waveguides are defined using photolithographic techniques and etched using a suitable dry etching recipe. The sample is then spin coated with BCB using an adhesion promoter. The BCB sample is then placed on a hotplate for outgassing which is followed by the bonding and a curing process in a nitrogen environment. As transfer substrate GaAs can be used for example which is chemically inert during the selective chemical etching if an InP substrate is being removed. The bonding process can also be performed in a vacuum chamber. The substrate is removed by a combination of mechanical polishing and selective chemical wet etching to the etch stop layer. Then the etch stop layer can be removed by using a selective chemical wet etching which does not etch the ring or disk layers. Finally the ring or disk resonator is fabricated using dry etching and the samples are cleaved. The samples can be antireflection (AR) coated in order to avoid Fabry–Perot resonances in the bus waveguides. Several BCB bonded vertically coupled ring and disk resonators will be presented in Sect. 3.4. 3.2 Dry Etching Dry etching is a technology widely used in semiconductor processing and has been developed in recent years to obtain reproducible etching results. In reactive ion etching systems, ions are accelerated towards the material to be etched, and the etching reaction is enhanced in the direction of travel of the ion. Different dry etching systems are available on the market with recipes for etching various material systems. Examples of systems are conventional reactive ion etching (RIE), inductively coupled-plasma reactive ion etching (ICP-RIE), reactive ion beam etching (RIBE), or chemically assisted ion beam etching (CAIBE). Gases which are commonly used (combining several) in dry etching processes are methane (CH4 ), hydrogen (H2 ), hydrogen bromide (HBr), nitrogen (N2 ), chlorine (Cl2 ), silicon tetrachloride (SiCl4 ), argon (Ar), and xenon (Xe). Despite the existence of numerous recipes, it is important to note that same conditions and used gases in etching processes can differ from machine to machine leading to different etching results. The reasons for this are multiple and can depend on the mixture and quality of gases and samples being etched regularly in the dry etching equipment which determine the chemical composition of the sidewalls in the reaction chamber. The wanted specific chemical deposition of the sidewalls is also referred to as conditioning or seasoning of the chamber and is usually done before etching of devices to obtain stable etch parameters. This conditioning affects the plasma in the etch chamber physically and/or chemically resulting in changes in the current and power density in the discharge and reaction rate. Two ways of etching are distinguished, isotropic and anisotropic etching. RIE is an anisotropic etching technique. The etch rate which defines the rate of removal of the semiconductor material is the same in all directions in the case of isotropic etching. The etch rate is direction dependent in the case of anisotropic etching, which 56 3 Materials, Fabrication and Characterization Methods is important in the fabrication of ring resonators, where deeply etched waveguides are needed to obtain a strong mode confinement of the field which in turn results in a small radius of curvature with acceptable loss. The pattern of a ring resonator layout is transferred to the material used by choosing the right masking technique. The unmasked regions like the coupling gap for example are “etched” away. There are three broad categories of masking materials: metals [nickel (Ni), chrome (Cr), nickel chrome (NiCr), titanium (Ti), aluminum (Al), wolfram (W), and platinum (Pt)], dielectrics (SiOx , SiNx ) and polymers (Photoresist, E-beam resist). Metal masks are extremely etch resistant and good choices for deep etching, however, metal masks are difficult to remove and the metal grains result in transferred striations. Dielectric masks provide good etch resistance, and can be used to etch nanostructures. Dielectric masks are regarded as “soft” which results in very little transferred striations to the underlying material. Polymers are highly etch resistant when fully cured and can be used as masks for deep etching. However, polymers as etch resistance are not sufficient to etch the depths (>1 μm) required for realizing waveguides used for ring resonator circuits and there is a risk of contaminating the etch chamber. 3.3 Si-Based Materials Silicon-based devices in photonic integrated circuits are known for quite some time. A summary of the properties of silicon can be found in Table 3.2. Pure silicon has an absorption loss much smaller than 0.1 dB cm−1 at the telecom wavelength of 1.55 μm which makes this material interesting for telecommunication devices. The processing and fabrication technologies for this material system are mature also to the fact that the electronics industry is a driving force for these enabling technologies. Another advantage in using silicon is the possibility of combining photonic devices with electronic circuits, enabling pre- and postprocessing of optical/electrical signals. An overview of manufactured and characterized integrated ring resonators in silicon is provided in Wim Bogaerts and coworkers (Bogaerts et al. 2012). 3.3.1 Ring Resonators Based on Si–SiO2 One of the first and smallest ring resonators in the Si–SiO2 material system which is also known as SOI has been presented in Little et al. (1998) with radii of 3, 4, and 5 μm. The devices have quality factors up to 250, and an FSR of 20, 24, and 30 nm for a wavelength of 1550 nm, respectively. The intensity difference between the on-resonance and the off-resonance state is measured to be more than 15 dB. The layout of a typical SOI waveguide is shown in Fig. 3.3. The width of the waveguide should be less than 600 nm in order to achieve single mode operation. 3.3 Si-Based Materials Table 3.2 Properties of silicon at 300 K 57 Symbol Lattice constant 5.431 Å Density 2.329 g cm−3 Dielectric constant 11.7 Auger recombination coefficient Cn 1.1 × 10−30 cm6 s−1 Auger recombination coefficient Cp 3 × 10−31 cm6 s−1 Debye temperature 640 K Effective electron masses m1 0.98 mo Effective electron masses mt 0.19 mo Effective hole masses mh 0.49 mo Effective hole masses m1p 0.16 mo Electron affinity 4.05 eV Optical phonon energy 0.063 eV Infrared refractive index n(λ) 3.42 3.38 (1 + 3.9 × 10−5 T) 77 K < T < 400 K Absorption coefficient αn 10−18 · no · λ2 λ ≥ 5 μm https://www.ioffe.rssi.ru/SVA/NSM/Semicond/Si/basic.html Fig. 3.3 Typical SOI waveguide layout The refractive index of SiO2 plotted against the photon energy is shown in Fig. 3.4.2 The fabrication process is made up of a deposition of a 1 μm thick buffer layer of SiO2 , followed by a deposition of a waveguiding core layer of amorphous Si 2 https://www.ioffe.ru/SVA/NSM/nk/Oxides/Gif/sio2.gif. 58 3 Materials, Fabrication and Characterization Methods Fig. 3.4 Refractive index of SiO2 versus photon energy at 560 °C with a thickness of 0.2 μm. The amorphous Si was annealed at 900 °C for 2 h to convert it to polycrystalline silicon (polySi) out of which the ring and bus waveguides (width: 0.5 μm, height: 0.2 μm) were patterned using an HBr–Cl plasma etch process. In order to increase the fiber-chip coupling efficiency, the bus waveguides are flared to an 8 μm width. The achieved index contrast is either 3.5:1.5 or 3.5:1.0, depending on whether the material external to the Si waveguide is SiO2 or air, respectively. An SEM photograph of a fabricated device is shown in Fig. 3.5. Racetrack shaped ring resonators based on a similar fabrication process have been presented in Vörckel et al. (2003) where the radius is 3 μm and the length of the straight coupling region is 1 μm, obtaining an FSR of about 24 nm and a Q-factor of 1800. The device exhibits asymmetrical coupling to achieve minimum intensity at the throughput port on resonance [see Sect. 2.1.1 (2.16)]. Fig. 3.5 SEM of a filter incorporating a 3 μm radius ring, with 0.5 μm wide by 0.2 μm-thick waveguides Little et al. (1998) 3.3 Si-Based Materials 59 The thickness of the silicon layer and the buried oxide layer of the SOI substrate are 0.4 μm, respectively. The racetrack shaped ring resonators are defined by electron beam lithography. The waveguides are etched down to the buried oxide layer by an HBr inductive coupled plasma reactive ion etching process. The width of the waveguides is 0.4 μm. The bus waveguides are tapered to a 10 μm width to increase the fiber–chip coupling efficiency. Two types of coupling distance variations have been used. In the first one, the fixed coupling distance is 0.2 μm and the other coupling separation is varied between 0.1 and 0.2 μm. The second configuration used a fixed coupling distance of 0.25 μm and varying the other coupling separation between 0.125 and 0.25 μm. The throughput port minimum on resonance has been increased from −7.2 to −12.8 dB. Due to the unreproducibility of the waveguide loss and the coupling coefficients, an exact adjustment of the critical coupling cannot be possible. Ring resonators with similar dimensions and figures of merit have been realized in Dumon et al. (2004) by deep UV lithography with an illumination wavelength of 248 nm. An SEM photograph of a fabricated racetrack shaped ring resonator is shown in Fig. 3.6. Racetrack shaped ring resonators based on the design in Fig. 3.3 but having an SiO2 cladding with radii down to 20 μm are presented in Kiyat et al. (2005). A vertically coupled disk resonator fabrication process based on a separation by implantation of oxygen (SIMOX) has been presented in Koonath et al. (2003); Koonath et al. (2004, 2005). The SIMOX process involves the implantation of oxygen ions into a silicon substrate, followed by a high temperature (~1300 °C) annealing of the substrate in order to cure the implantation damage and to effect SiO2 formation. The thickness and the depth of the buried oxide layer are determined by the implantation dose and energy. The implantation dose should be in the range of 1 × 1017 –9 × 1017 ions per cm2 , with implantation energies in the range of 40–200 keV to keep the defect densities below 105 cm−2 . The implantation of oxygen ions is performed on an SOI substrate which is patterned with thermally grown oxide. The thickness of the oxide mask is chosen such that the oxygen ions that penetrate into the area underneath the mask are decelerated. After the high temperature annealing, angled Fig. 3.6 Racetrack resonator in SOI. The isolated wire width is 500 nm, the gap width is 230 nm. Note that when the wires get closer together, the wire width decreases to 450 nm due to optical proximity effects during lithography Dumon et al. (2004) 60 3 Materials, Fabrication and Characterization Methods Fig. 3.7 SEM picture of the fabricated microdisk resonators on the top silicon layer with bus waveguides underneath Koonath et al. (2003) side-walls of the buried rib waveguide are obtained due to the lateral spread out of the implanted oxygen ions. After annealing, rib waveguides can be defined on the top layer using a conventional lithography and etching process. Disks with radii of 20, 20.5, and 21 μm have been fabricated. The free spectral rang of these devices is ~5 nm. In order to fabricate the devices, an SOI wafer with 0.6 μm of silicon on top of a buried oxide layer of 0.4 μm thickness was oxidized and patterned using a reactive ion etching process to form oxide stripes of thickness 0.06 μm, with widths varying from 2 to 12 μm. The patterned wafer was then implanted with oxygen ions with a dose of 5 × 1017 ions cm−2 , at energy of 150 keV. The implanted wafers were then annealed at 1320 °C for 7.5 h in an ambient of argon, with 1% oxygen, to cure the implantation damage. To form the disks, a silicon nitride layer of thickness 0.1 μm was deposited on top, and patterned using standard lithography and reactive ion etching. The substrate was then oxidized to remove the silicon on the top layer, everywhere except underneath the disks, realizing vertical coupling to the buried bus waveguides. An SEM photograph of a vertically coupled disk is shown in Fig. 3.7. 3.3.2 Ring Resonators Based on Ta2 O5 –SiO2 The Ta2 O5 –SiO2 material system has also been used very successfully to realize ring resonator devices. The advantage of using this material system is the ability to control the refractive index by adjusting the ratio of Ta2 O5 to SiO2 . Vertically coupled ring resonators with a radius of 10 μm have been presented in Little et al. (1999). Here alternating layers of SiO2 and Ta2 O5 –SiO2 are deposited by radiofrequency (RF) sputtering. The waveguides for the ring and the bus are made using a composition of 30 mol.% of Ta2 O5 and 70 mol.% of SiO2 leading to a refractive index of 1.7825 at a wavelength of 1550 nm. The bottom cladding layer is made up of 10 μm SiO2 . Then a 0.5 μm layer of Ta2 O5 –SiO2 material is deposited on top. In order to fabricate the bus waveguides, a 150-nm-thick Cr mask was evaporated on to the sample and 3.3 Si-Based Materials 61 Fig. 3.8 Dimensions and layer sequence of a vertically coupled Ta2 O5 –SiO2 ring resonator patterned by photolithography and dry etched to a depth of 0.5 μm. While the Cr on top of the bus waveguides remained intact, 0.5 μm of SiO2 was sputtered onto the sample to fill in the amount of bus material etched away. In the Cr liftoff process, the sample was first soaked in buffered hydrofluoric acid (BHF) for 10 s to remove the SiO2 deposited on the vertical walls of the Cr. This resulted in a liftoff, of both the Cr and the SiO2 on top of it. For the vertical separation of the bus and ring waveguides, a layer of SiO2 is sputtered onto the sample. The thickness of this layer defines the coupling coefficient between the ring and the bus waveguide. The ring resonator which is on top of the bus waveguide is made by deposition of a Ta2 O5 layer with following Cr mask patterning process. The dimensions and the layer sequence of the device are sketched in Fig. 3.8. A similar process realizing an eight channel add–drop filter is described in Chu et al. (1999a). Here the ring and bus waveguide cores are composed of Ta2 O5 – SiO2 [17:83] mol% which gives a refractive index of 1.6532. SiO2 is used for the cladding and the buffer layers. The bus waveguides has been slightly offset from the ring resonator waveguide. The dimensions and the waveguide layout are shown in Fig. 3.9. The same waveguide and ring resonator layout has been used in Chu et al. (1999b) to realize a double ring resonator configuration. Here the composition of Ta2 O5 –SiO2 has been chosen to give a refractive index of 1.539. The ring and bus waveguide width Fig. 3.9 Waveguide parameters of the eight channel add-drop filter 62 3 Materials, Fabrication and Characterization Methods are both 2 μm. The SiO2 pedestal height for the ring waveguide is 0.5 μm. The bus waveguide are buried 0.5 μm below the surface with an offset of 0.8 μm. A vertical coupled ring resonator configuration using the Ta2 O5 –SiO2 compound has been presented in Hatakeyama et al. (2004) and Kokubun et al. (2005). The ring resonators are coupled to the bus waveguides using multilevel crossings which means that there is a lower and an upper bus waveguide. Single, double and quadruple coupled ring resonators have been demonstrated. The advantage of using a multilevel structure is to eliminate the scattering loss at bus waveguide crossings. The fabrication process is similar to the previously described methods, involving an RF sputtering and photolithography technique. The patterns of the waveguides are transferred using a Cr mask and a reactive ion etching (RIE) process with C2 F6 gas. The waveguide core layers are made of Ta2 O5 –SiO2 compound glass (Ta2 O5 30 mol.%, n = 1.785 at the wavelength of 1550 nm), and the cladding and separation layers are SiO2 (n = 1.451 at the wavelength of 1550 nm). The fabrication of the vertically coupled ring resonator with multilevel bus waveguide crossing is started by patterning and RIE etching of the lower bus waveguide. Then the bus waveguide is covered by depositing SiO2 . The SiO2 layer which has been deposited onto the lower bus waveguide is eliminated by a liftoff process through chemical etching of the Cr mask using a solution of Cerium (IV) diammondium nitrate 13.3 wt%, perchloric acid 70% and water. In order to realize a perfect planarized surface for the coupling to the ring resonator, SOG is used. SOG is spin coated and baked at 400 °C for 40 min under N2 gas, realizing a height of only 0.2 μm. SOG is made up of ethyl–silicate-polymer 9% (Si 5.9%), ethanol 73%, and methyl acetate 18%. The width and thickness of a ring waveguide is 1.2 and 0.7 μm, respectively. The thickness of the separation layer between the ring resonator and bus waveguides is 0.6 μm. The ring radius is 5 μm, obtaining a record 37 nm FSR. Other configurations with different dimensions have also been realized. 3.3.3 Ring Resonators Based on SiN, SiON, and Si3 N4 Serially coupled triple ring resonators in SiN have been demonstrated in Barwicz et al. (2004). The ring and bus waveguides are made of a single layer of SiN. The high index contrast which is achieved by using this material combination induces strong polarization dependence. Therefore the device is optimized for transversal electric (TE) polarization operation. A photograph of a triple ring resonator is shown in Fig. 3.10. The fabrication of the device is started by thermally oxidizing a silicon wafer to obtain a bottom SiO2 layer. Then, a SiN layer is deposited by low-pressure chemical vapor deposition (LPCVD) in a vertical thermal reactor using a gas mixture of SiH2 Cl2 and NH3 . Next, 200 nm of polymethyl-methacrylate (PMMA) and 40 nm of Aquasave were spun on. PMMA is a positive E-beam resist while Aquasave is a watersoluble conductive polymer from Mitsubishi Rayon used to prevent charging during direct-write scanning-electron-beam lithography (SEBL). PMMA is exposed 3.3 Si-Based Materials 63 Fig. 3.10 Third-order add–drop filter based on series-coupled microring resonators. The rings’ outer radius is 7.3 μm. The ring-to-bus gap is 60 nm and the ring-to-ring gap is 268 nm Barwicz et al. (2004) at 30 keV using a Raith 150 SEBL system. The Aquasave is removed, and the PMMA is developed. Next, 50 nm of Ni is evaporated on the structure, and a following liftoff is performed by removing the nonexposed PMMA. The waveguides are defined by conventional reactive ion etching (RIE) using Ni as a hardmask. A gas mixture of CHF3 –O2 in a 16:3 flow-ratio was used during the dry etching process to obtain vertical and smooth sidewalls. The accuracy of the etch depth is monitored using several etch steps and is measured with a profilometer. Finally, the Ni is removed using a nitric-acid-based commercial wet Ni etchant. The design and the dimensions of the used waveguide are shown in Fig. 3.11. The device is designed to have an FSR of 24 nm. A similar design is presented in Wang et al. (2005) with a radius of 25 μm resulting in an FSR of about 8 nm. Ring resonators based on SiON are analyzed in Melloni et al. (2003). The ring radius is 300 μm. The SiON waveguides are made by deposition using standard Fig. 3.11 Waveguide dimensions. The refractive index is given for λ = 1550 nm 64 3 Materials, Fabrication and Characterization Methods Fig. 3.12 Cross-section and layer sequence of SiON waveguide Fig. 3.13 Refractive index of Si3 N4 versus photon energy plasma-enhanced chemical vapor deposition (PECVD) techniques and dry etching. The cross-section and the dimensions of the used waveguides are sketched in Fig. 3.12. Lateral and vertically coupled ring and disk resonators in Si3 N4 –SiO2 and SiON are presented in Klunder et al. (2001, 2003), respectively. The refractive index of Si3 N4 plotted against the photon energy is shown in Fig. 3.13.3 The dimensions and the layout of the lateral coupled configuration are shown in Fig. 3.14. Laterally coupled devices with a radius of 25 μm with and without a cladding of PMMA have been fabricated. The radius of the realized disk resonator is 15 μm. The fabrication of the device is performed using standard lithography and reactive ion etching. Buffered hydrofluoric acid (BHF) etching is done after RIE to reduce 3 https://www.ioffe.ru/SVA/NSM/nk/Nitrides/Gif/si3n4.gif. 3.3 Si-Based Materials 65 Fig. 3.14 Cross-section of a laterally coupled ring resonator Fig. 3.15 Cross-section of a vertically coupled ring resonator the surface roughness and to obtain smoother sidewalls. The layer sequence of a vertically coupled ring resonator is shown in Fig. 3.15. Here an additional SiO2 layer is grown by PECVD which defines the coupling strength between the ring and the bus waveguides. A high-index contrast silica on silicon technology with neff = 0.02 was developed at the IBM Zurich Research Lab4 based on PECVD deposited silicon oxynitride (SiON) films for realizing integrated ring resonators (Horst et al. 1998). The minimum bending radius is 1.5 mm. The waveguide layout is shown in Fig. 3.16. 3.3.4 Ring Resonators Based on SiO2 –GeO2 Ring resonators using GeO2 doped silica waveguides and vertical coupling have been demonstrated in Suzuki et al. (1992). The GeO2 doped silica waveguides are fabricated by a combination of flame hydrolysis deposition (FHD), electron cyclotron 4 www.ibm.zurich.com. 66 3 Materials, Fabrication and Characterization Methods Fig. 3.16 Waveguide layout developed at IBM Zurich Research Lab resonance CVD (ECR-CVD) with an applied RF bias (bias-CVD), and RIE. The waveguides for the ring resonator are realized in a first step unlike the configurations previously discussed, where the ring resonator is on top of the bus waveguides. The ring waveguides are made of GeO2 doped silica with a 2% refractive index difference. The dimension of the ring waveguide etched into an under cladding layer of thickness 30 μm is 3.5 μm × 4 μm. The coupling distance is adjusted to a height of 2.5 μm between the ring and the bus waveguides by deposition. The dimension of the bus waveguides with a 0.75% refractive index difference is 5 μm × 6.5 μm. Finally the bus waveguides are covered by a cladding layer deposited again using FHD. The radius of the ring is 1.5 mm. The advantage of using this kind of material is the low propagation loss which is smaller than 0.1 dB cm−1 at a wavelength of 1550 nm. Several integrated devices based on this material are presented in Suzuki et al. (1994) using different refractive index differences for the employed waveguides. The idea which has been followed is the use of two types of waveguides, weak and strong guiding. Weak guiding waveguides are used for in and out coupling to reduce the fiber to chip coupling loss. 3.4 III–V Materials In this chapter the most commonly used III–V material systems GaInAsP on InP and AlGaAs on GaAs are treated. Ring resonators both vertically and laterally coupled have been demonstrated in these material systems. 3.4.1 The Quaternary Semiconductor Compound GaInAsP III/V semiconductors on the basis of InP with a direct bandgap are used for a variety of components in the all-optical network. The composition of the quaternary (III–V) 3.4 III–V Materials 67 Fig. 3.17 Bandgap of III–V semiconductor compounds in eV and wavelength semiconductor compound GaInAsP lattice matched to InP, can be changed, so that the bandgap can be adjusted in the range between 0.97 and 1.65 μm. The choice of the appropriate bandgap, which is smaller than the signal wavelength, enables the fabrication of passive, transparent waveguides with low loss (<1 dB cm−1 ). This material system is also used for the realization of lasers and optical amplifiers in the spectral window around 1.55 and 1.3 μm. A summary on optoelectronic and photonic integrated circuits on InP can be found in Kaiser and Heidrich (2002). Electronic components can also be fabricated with this material system, by incorporating Si, Be, Zn, and realizing p- or n-doped areas. The properties of the semiconductor compound (Gax In1−x Asy P1−y ) can be described by Vegard’s law. Using this law and the known semiconductor compounds GaAs, GaP, InAs, and InP it is possible to determine the coefficients x and y (Fiedler and Schlachetzki 1987). L C Gax In1−x As y P1−y = x y L C (GaAs) + x(1 − y)L C (GaP) + y(1 − x)L C (InAs) + (1 − x)(1 − y)L C (InP), where L C is the lattice constant. The composition of the semiconductor compound is displayed over the bandgap energy or the bandgap wavelength at room temperature in most diagrams and not x and y. The bandgap of common semiconductors is displayed in Fig. 3.17. Physical properties of InP and of lattice matched Gax In1−x Asy P1−y at room temperature (300 K) are presented in Table 3.3 (Fiedler and Schlachetzki 1987; Della Corte et al. 2000). The refractive index of InP plotted against the photon energy is shown in Fig. 3.18.5 5 https://www.ioffe.ru/SVA/NSM/nk/A3B5/Gif/inp.gif. 68 3 Materials, Fabrication and Characterization Methods Table 3.3 Physical properties of InP and of lattice matched Gax In1−x Asy P1−y at room temperature (300 K) Lattice constant Symbol Unit InP LC nm 0.58688 Gax In1−x Asy P1−y y = 2.202x/ (1 + 0.0659y) Lattice match to InP 1.35 1.35 − 0.72y + 0.12y2 me /m0 0.077 0.07 − 0.0308y Heavy hole mass/m0 mhh /m0 0.6 0.6 − 0.218y + 0.07y2 Light hole mass/m0 m1h /m0 0.12 0.12 − 0.078y + 0.002y2 Bandgap energy Wg Electron mass/m0 eV Refractive index (λ = neff 1.55 μm) 3.169 Dielectric constant (static) Es 12.35 12.35 + 1.62y − 0.055y2 Dielectric constant (high frequency) E∞ 9.52 9.52 + 2.06y − 0.205y2 Density W g / T ρ g cm–3 10–4 eV K–1 4.81–2.67 4.81 + 0.74y − 2.67 + 0.102y + 0.073y2 Temperature dependence of the refractive index at 300 K dn dT K–1 2.01 × 10- - 5 Temperature dependence of the refractive index (λ = 1.523 μm) dn dT K–1 –2.17 × 10–10 × T 2 + 3 5 × 10–7 × T + 1.15 × 10–4 Length increase due to temperature 1 l K–1 0.475 × 10–5 · dl dT 3.4.2 The Semiconductor Compound AlGaAs The AlGaAs material system is used in the same context as the GaInAsP material system and is a major optical material used for lasers and passive waveguide based devices. This material system is used as a barrier material in GaAs-based heterostructure devices. It is favorably used to fabricate field effect transistors like for example high electron mobility transistors (HEMTs). Some common physical properties of GaAs and AlGaAs are listed in Table 3.4. The refractive index of GaAs plotted against the photon energy is shown in Fig. 3.19.6 6 https://www.ioffe.ru/SVA/NSM/nk/A3B5/Gif/gaas.gif. 3.4 III–V Materials 69 Fig. 3.18 Refractive index of InP versus photon energy 3.4.3 Lateral Coupling in GaInAsP/InP One of the first passive ring resonator filters in this material system are presented in Vanderhaegen et al. (1999). Racetrack shaped ring resonators with a radius of 125 μm and coupler lengths of 80 μm are demonstrated. The layout and the layer sequence of the waveguide are shown in Fig. 3.20. The waveguide layers are grown by metal organic vapor phase epitaxy (MOVPE). A 100 nm thick SiN layer is used as the etching mask which is grown by PECVD. The waveguide patterns are transferred to the SiN layer by photolithography and a CHF3 based RIE process. The waveguides are etched using a CH4 /H2 and O2 process. A bi-level etching technique that permits the use of standard photolithography for lateral coupling to deeply etched racetrack shaped ring resonator structures is presented in Griffel et al. (2000), where a ring laser is fabricated and characterized. Here, deep etching is used to reduce the bending loss at the curved sections, but is avoided in the coupling region where the straight sections of the racetrack shaped ring resonator and the input/output waveguides form a gap whose distance defines the power coupling coefficient (Fig. 3.21). This is a way of eliminating the drawback of lateral coupling and realizing defined coupling parameters. A radius of curvature of 150 μm is combined with four different coupler lengths of 50, 100, 150, and 200 μm, positioned at the center of the straight section of the racetrack, which is 50 μm longer. The width of the used ridge waveguides is 2.5 μm and the gap between resonator and coupling waveguides is 2 μm. The active waveguide consists of three compressively strained GaInAsP quantum wells imbedded in a 70 nm waveguide structure of two compositions with bandgap energy E g = 1.13 and 1.00 eV. The layer sequence of the used waveguide is shown in Fig. 3.21. 70 3 Materials, Fabrication and Characterization Methods Table 3.4 Physical properties of GaAs and of Alx Ga1−x As at room temperature (300 K) Lattice constant Symbol Unit GaAs Alx Ga1-x As Lc nm 0.565325 0.56533 + 0.00078x x < 0.45: 1.424 + 1.247x Bandgap energy Wg eV 1.424 x > 0.45: 1.9 + 0.125x + 0.143x 2 0.063 + 0.083x (x < 0.45) Electron mass/m0 me /m0 0.063 Heavy hole mass/m0 mhh /m0 0.51 0.51 + 0.25x Light hole mass/m0 mlh /m0 0.082 0.082 + 0.068x Refractive index (λ = 1.55 μm) neff 3.3 3.3 − 0.53x + 0.09x 2 Dielectric constant (static) Es 12.9 12.90 − 2.84x Dielectric constant (high frequency) E∞ 10.89 10.89 − 2.73x Density temperature T dependence of the energy gap E g (0 < T < 103 in K) ρ g cm−3 eV 5.32 1.519 − 5.405 × 10−4 × T 2 /(T + 204) 5.32 − 1.56x Temperature dependence of the refractive index (λ = 1.523 μm) dn dT K−1 −1.86 × 10−10 × T 2 + 3.49 × 10−7 × T + 1.47 × 10−4 https://www.ioffe.rssi.ru/SVA/NSM/Semicond/GaAs/index.html https://www.ioffe.rssi.ru/SVA/NSM/Semicond/AlGaAs/index.html Della Corte et al. (2000) A similar method is used in Rabus and Hamacher (2001) where a 3 dB MMI coupler of length 150 μm is used for coupling in and out of single and serially double coupled racetrack shaped ring resonators. Here the rings were deeply etched along the outer wall of their curved sections (Fig. 3.22) leading to a stronger optical confinement. Passive single and double racetrack shaped ring resonator with a radius of 100 and 200 μm, respectively, are presented. The layer sequence of the used waveguide is shown in Fig. 3.23. The GaInAsP waveguide material used for the realization of the devices has a bandgap wavelength of λg = 1.06 μm at room temperature which can also be written as Q(1.06) referring to quaternary material. The fabrication of the waveguides starts with depositing the silicon nitride (SiNx ) mask, realized by PECVD. It serves as the etching mask for the waveguides. The thickness of the SiNx is ≈200 nm and is deposited at a temperature of 370 °C. The structuring of the SiNx layer is performed using standard photolithography. The 3.4 III–V Materials Fig. 3.19 Refractive index of GaAs versus photon energy Fig. 3.20 Waveguide structure and composition Fig. 3.21 Layer sequence of the waveguides in the coupling region 71 72 3 Materials, Fabrication and Characterization Methods Fig. 3.22 Scanning electron microscope (SEM) photograph of the input region of an MMI coupler with deep etching along the outer walls of the curved sections Fig. 3.23 Layer sequence of the waveguide photoresist used is AZ5214. An exposure dose of 12 mW cm−2 is used. The exposing time is 24 s and the developing time is between 40 and 50 s for a positive exposure. The developer used is MIF724. The developed photoresist serves as the etching mask for the following RIE process. The etching is done using the gases CHF3 (22 sccm) and O2 (2.2 sccm) at a pressure of 12 μbar and 50 W. The photoresist is removed after this RIE step and the structured SiNx layer serves as the mask for the next RIE step. The gases now used for etching the waveguide are CH4 and H2 (6, 40 ml min−1 ). In order to reduce the formation of polymers during dry etching and to minimize the sidewall roughness, a small fraction of O2 (0.3 ml min−1 ) is added. The power used is 150 W at a pressure of 0.02 mbar. The etching is controlled by an ellipsometer and a mass spectrometer. The etching is stopped when the InP etch stop layer is detected. The next dry etching step is the realization of the deeply etched section on the outer wall of the waveguides in the curvatures. The SiNx layer from the previous step serves as the etching mask which is structured again with standard lithography to open an etching window for this process. The photoresist which is used to structure the SiNx layer therefore covers only a part of the waveguide, ideally only half of it. This self aligning process assures that the width of the waveguide is not changed 3.4 III–V Materials 73 Fig. 3.24 SEM photograph of a waveguide in the curvature by this processing step. The etching is again performed using RIE, but this time without the portion of oxygen which could partly remove the photoresist mask and cause etching errors. The photoresist is removed after dry etching by the use of an oxygen plasma (15 min, power = 500 W, T ≤ 200 °C). An SEM photograph of a waveguide in the curvature is shown in Fig. 3.24. The samples are AR coated to avoid Fabry–Perot resonances in the bus waveguides. In Rommel et al. (2002) a Cl2 /Ar/H2 chemistry is used to etch InP-based racetrack ring resonators using inductively coupled plasma reactive ion etching. An SEM photograph of a fabricated racetrack shaped ring resonator notch filter is shown in Fig. 3.25. The composition of Cl2 /Ar/H2 has a strong influence on the degree of undercut in the profile. A nearly perfect anisotropic profile is achieved for ratios between 2/3/1 and 2/3/2. Waveguide losses of 2 dB cm−1 are obtained. The straight length of the coupling region is 90 μm. The ridge width is 0.9 μm, and the coupling gap has a width of 275 nm. A radius of 15 μm is used in the curved regions. The etching depth is 4 μm. Three distinct etching profiles are obtained by adding H2 . For the Cl2 dominated region (Cl2 /Ar/H2 ratios between 2/3/0 and 2/3/1.5), high etch rates: 1.8 μm/min and large undercuts of InP and GaInAsP layers are reported. The second region (Cl2 /Ar/H2 ratios between 2/3/1.5 and 2/3/2.5) has balanced chemistry yielding low but uniform etch rates between 0.5 and 0.6 μm min−1 and highly anisotropic InP/GaInAsP profiles. A H2 dominated region is reported for Cl2 /Ar/H2 ratios above 2/3/2.5. In this region, InP layers exhibit large undercuts, whereas GaInAsP layers showed little lateral etching. The authors suggest that the selectivity of GaInAsP layers relative to InP may be increased by increasing the As concentration. One of the smallest racetrack shaped ring resonators in InP with a radius in the curved sections of 2.25 μm is presented in Grover et al. (2003) where an FSR of 19 nm near 1550 nm, with an extinction of more than 25 dB is reported. The length 74 3 Materials, Fabrication and Characterization Methods Fig. 3.25 The ridge is etched to a depth of 5 μm, and has a width of 0.9 μm and gap of 275 nm Rommel et al. (2002) of the straight sections is 10 μm and the coupling gap is only 200 nm. The bus waveguide is tapered to a width of 3 μm away from the coupling region to improve the fiber to chip coupling. The layer sequence of the device is shown in Fig. 3.26. The refractive index of the used Ga0.31 In0.69 As0.71 P0.29 compound is 3.39. The fabrication details are taken from Grover (2003). The process is started by depositing a wafer with 900 nm of silicon dioxide by PECVD. A Leica VB6 e-beam lithography machine is used to pattern a bilayer film of polymethyl-methacrylate (PMMA). The patterning is started by spinning on 100 K MW 5% PMMA in Anisole at 4000 rounds per minute (RPM) for 60 s, which gives a 113 nm thick film. A bake follows for 15 min at 170 °C. Next 495 K MW PMMA A4 in Anisole is spin-coated at 2000 RPM for 60 s, which leads to a 204 nm thick film. This is followed by a bake for 15 min at 170 °C. Finally the pattern is written using a dosage of 736 μC/cm2 for waveguides and ring resonators, and 610 μC cm−2 for device labels. The PMMA-based resist Fig. 3.26 Layer structure of laterally coupled ring resonator in InP 3.4 III–V Materials 75 is developed with 2-methyl-2-pentanone (methyl isobutyl ketone or MIBK) diluted with 2-propanol as 1:3 for 2 min 30 s. In a final step the wafer is rinsed with 2-propanol and nitrogen is used to blow-dry. The reason for choosing two layers of PMMA is to have the lower resolution PMMA on the bottom and the higher resolution PMMA on top, so that there is an overhang of the higher resolution PMMA where the pattern is written. This also enables a better liftoff in the following process. Next, a 50 nm thick layer of chromium is deposited and patterned by liftoff in warm 1-methyl-2-pyrrolidone (C5 H9 NO) also referred to as NMP. The pattern is transferred to the underlying silicon dioxide by dry etching in trifluoromethane oxygen plasma. Then the InP and quaternary layers are etched by a methane hydrogen plasma to a depth of 3.2 μm using a Cr–SiO2 mask. The methane based dry etching process evaluating several mask (Ni, NiCr, Ti, SiO2 , and Ti–SiO2 ) is presented in Grover et al. (2001a). Then in a final step, the mask is stripped with buffered hydrofluoric acid. InP based devices are usually thinned to a thickness between 100 and 200 μm by a bromine methanol based lapping process. This ensures a better cleavage of the samples and reduces the contact resistance if active devices with top side p and backside n contact are realized. Buried heterostructure ring resonators are presented in Choi et al. (2004a). Ring resonators with a radius of 200 μm are fabricated by first growing a 0.4 μm thick GaInAsP (λg = 1.25 μm) waveguide layer on a (001) oriented InP substrate by metal organic chemical vapor deposition (MOCVD). The waveguide layer is then covered by a SiNx layer which serves as the mask for the following CH4 based dry etching process. The bus waveguides are aligned parallel to the [110] direction in the crystal lattice. The width of the buried waveguides is between 0.8 and 0.9 μm. The polymers generated on the sidewalls during the dry etching process are removed by an oxygen plasma treatment and the SiNx mask is removed by a buffered oxide etchant. The waveguides are covered by a 1.5 μm thick InP layer. Finally the sample is thinned, cleaved, and AR coated. The waveguide loss of the straight bus sections is measured to be between 0.2 and 0.3 cm−1 . The dimensions and layout of the buried waveguide are shown in Fig. 3.27. SEM photographs of a waveguide section and a cross-section of a buried waveguide are shown in Fig. 3.28 (Choi et al. 2004a). Fig. 3.27 Dimensions and layout of the buried waveguide 76 3 Materials, Fabrication and Characterization Methods Fig. 3.28 a SEM image of a dry-etched ring resonator mesa. b SEM cross-sectional view of a buried waveguide Choi et al. (2004a) 3.4.4 Vertical Coupling in GaInAsP/InP One of the first vertically coupled disk resonators with a diameter of 44 μm, both in the GaAs and InP materials systems, fabricated by wafer bonding is presented in Tishinin et al. (1999). The device design in both material systems incorporates an etch-stop layer (0.2 μm thick layer of InGaAs/InP and Al0.95 Ga0.05 As/GaAs) and two waveguiding layers (waveguide layers 0.5 μm thick and disk layers 0.3 μm thick) with low index material layer (thickness 0.5 μm) in between. In the GaAs sample, Alx O is used for lateral confinement of the light in the disk structure. The bus waveguides and disk are fabricated by standard optical lithography and chlorine based ECR-RIE. First, the waveguides are etched down through both the top cladding layer and the waveguiding layer and etching is stopped within the separation layer. The bus waveguides are multimode and have a width of 2 μm. After etching the bus waveguides, this processed side is wafer bonded to another substrate and the original substrate is removed after it has been lapped down to a thickness of 100–150 μm by 3.4 III–V Materials 77 selective chemical wet etching. GaAs samples are bonded to GaAs and InP samples to InP substrates. A bonding temperature for GaAs wafers of 750 °C and of 400 °C for InP-based materials is used. It is important to mention that the transfer substrate need not be the same material. After the removal of the original substrate, the disk is fabricated by back side alignment optical lithography and ECR-RIE. A vertically coupled GaInAsP thin film disk resonator with a diameter of 10 μm resulting in an FSR of 20 nm using polymer wafer bonding with benzo-cyclobutene (BCB) is presented in Ma et al. (2000). The wafer structure with a 0.4 μm thick GaInAsP (λg = 1.2 μm) guiding layer is grown on an InP substrate by molecular beam epitaxy (MBE). A 400 nm thick SiO2 layer is used as a hard mask and is deposited by PECVD. The wafer is patterned using electron beam lithography with a 180 nm thick 2% polymethylmethacrylate (PMMA) resist. The structured PMMA resist is transferred to the underlying SiO2 layer using RIE. Inductively coupled plasma (ICP) RIE with a gas mixture of Cl:Ar (2:3) is used to transfer the pattern onto the epitaxy wafer through the SiO2 hard mask at a temperature of 250 °C. The waveguides are etched to a depth of about 1.3 μm. The SiO2 hard mask is removed after RIE using buffered HF. The BCB bonding process is started by spin coating BCB onto both the patterned wafer and the transfer wafer (here GaAs is used). Then the wafers are brought into contact with their BCB side facing each other using an appropriate weight. The wafer stack is put into a nitrogen filled furnace at 250 °C for 1 h. BCB becomes fully cured and the two wafers are glued together. The overall thickness of BCB is 3 μm. The InP substrate is removed after bonding using selective wet etching (HCl:H3PO4 = 2:3). The input and output waveguides are 2 μm wide and are tapered down (taper length = 500 μm) to 0.4 μm in the disk region. The bus waveguides and the disk are separated by a gap of approximately 180 nm. Vertically coupled single mode ring resonators also using BCB wafer bonding with a radius of 5 and 10 μm are presented in Grover et al. (2001b) and Grover (2003). The layer sequence of the used device is shown in Fig. 3.29. The patterns are transferred by photolithography to a 400 nm thick SiO2 layer using a 10× i-line stepper and a CHF3 /O2 plasma RIE process. The waveguides and ring resonator in GaInAsP–InP are etched using SiO2 as the mask in a reactive ion etching system with a CH4 /H2 /Ar plasma. Fig. 3.29 Layer structure used for BCB bonded vertically coupled ring resonators 78 3 Materials, Fabrication and Characterization Methods The fabrication process starts with etching of alignment keys to a depth of 2 μm down to the GaInAs layer. The use of Alignment keys eliminates the use of infrared (IR) backside alignment for processing the other side. Then the waveguide layer is etched to a depth of 0.9 μm. Benzocyclobutene (BCB; n = 1.5) is used for bonding to a GaAs transfer substrate. A thickness of 1–2 μm is chosen for the BCB layer. The growth substrate is thinned to a height of about 100 μm by chemo-mechanical polishing. The remaining growth substrate is selectively etched and removed using H3 PO4 :HCl (1:1) which stops at the GaInAs etch stop layer. This etch stop layer is then selectively etched using H2 O2 :H2 SO4 :H2 O (1:1:10) which stops at the InP layer opening the second GaInAsP–InP layers for fabricating the ring resonator. The top layer is etched to a depth of 0.9 μm, leaving a gap of 200 nm to decrease losses caused by leakage to the substrate. Finally the whole device is encapsulated with BCB. This fabrication process uses the advantages of both materials combining GaInAsP and GaAs. As appropriate, either layers of GaInAsP or GaAs are removed leading to a vertically coupled device. A thermal wafer bonding process is used in Djordjev et al. (2002b) to realize vertically coupled disk resonators with radii of 4, 6, 8, 10, 12 μm. The layer sequence and design are shown in Fig. 3.30. A novel feature which is incorporated in the design of the disk resonator is a circular post below the resonator. It improves the mechanical stability of the structure, improves current/field uniformity in active devices and suppresses higher order modes improving the transmission characteristics. A disk supports whispering gallery modes, which propagate by means of total internal reflection from the disk/air interface (see Chap. 7). The first order mode has the smallest volume and occupies the outmost region of the disk in the radial direction. All of the higher order modes have larger volume and are therefore closer to the center of the disk which results in a leakage into the post. The post and the waveguides are separated by 1.2 μm which is large enough to prevent coupling between them. The fabrication process is described using (Djordjev 2002). The layers are grown by low pressure MOCVD on a (001) InP substrate at 655 °C. A 100 nm thick SiNx is used as a hard mask for the bus waveguide and disk etching process which is Fig. 3.30 Design of vertically coupled disk resonator 3.4 III–V Materials 79 deposited at 275 °C with a power of 30 W using a pressure of 450 m Torr7 and the gases SiH4 /NH3 /N2 at a ratio of 40/20/60. This silicon nitride layer is structured using Shipley S1813 photoresist and a low pressure (10 mTorr) ECR-RIE CF4 (30 sccm) plasma at 20 °C, 500 W for 300 s. Before spin coating the photoresist, Silicon Resources AP405 is used to increase the adhesion of the photoresist on the silicon nitride. The photoresist is developed using Microposit MF321 developer. The bus waveguides are etched using a CH4 / H2 / Ar RIE process. The process used is described in detail in Choi et al. (2002). The width of the waveguides is between 0.7 and 0.9 μm. The waveguide width is tapered adiabatically to 2.5 μm to the edge of the chip to enhance fiber chip coupling. After the etching of the bus waveguides, the sample, which is usually 1 cm2 , is bonded to a transfer substrate of the same size. The cleanliness of the surface of the samples is vital for the following bonding process and many cleaning steps are performed (deionized (DI) water, trichloroethylene (TCE), acetone, methanol). After a final DI water rinse, both samples are brought into contact under water and are “wet bonded.” This prevents oxidation and contamination of the surfaces. The samples are then loaded into a chamber which is evacuated and heated to 100 °C for 10 min. Then H2 is led into the chamber and the samples are heated to a bonding temperature of 505 °C for 30 min. In a final bonding step, the samples are cooled down to room temperature in 15 min. The fabrication of the disk starts by removing the InP substrate which is done using mechanical polishing and a selective chemical wet etch (HCL:H2 O—3:1). The etching is automatically stopped, when the InGaAs layer is reached. The etch stop layer is then removed using H2 SO4 :H2 O2 :H2 O (1:1:3) which opens the waveguide layers of the disk. In order to align the bus and the disk waveguides, the sample is etched down to the waveguide pattern on the edge in a small area making the alignment marks visible which have been patterned together with the bus waveguides. The disk is etched after the opening of the alignment marks using the same processing steps as for etching the bus waveguides. One of the first ring resonators coupled to buried heterostructure (BH) bus waveguides in GaInAsP are presented in Choi et al. (2004b). A two step regrowth process is used in fabricating the devices. The radius of the ring resonators is 10 μm. The buried bus waveguides are made by growing a 0.4 μm thick layer of GaInAsP with a bandgap wavelength of 1.1 μm on to an InP substrate followed by an SiNx masking and etching step. The width of the bus waveguides is 1 μm. The area between the bus waveguides is filled with epitaxially grown InP. The silicon nitride masking layer is removed and the second growth step is initiated leading to the ring resonator. The material for the waveguide layer which has a thickness of 0.4 μm is GaInAsP with a bandgap wavelength of 1.4 μm. The ring waveguide and the bus waveguides are separated by a 0.8 μm thick InP buffer layer. The InP cladding layer for the ring waveguides has a thickness of 1 μm. An SEM photograph of a cross section of the ring resonator device showing the buried bus waveguides and the layer for fabricating the ring resonator is shown in Fig. 3.31. The fabricated ring resonator is shown in Fig. 3.32. The bus waveguides are AR coated to avoid Fabry–Perot resonances. 7 760 Torr = 1 atm = 101,325 kPa = 1013,25 h Pa = 101,325 bar. 80 3 Materials, Fabrication and Characterization Methods Fig. 3.31 Cross-section of a planar vertically stacked waveguide produced on BH mesas Choi et al. (2004b) Fig. 3.32 Ring resonator coupled to buried heterostructure bus waveguides Choi et al. (2004b) 3.4.5 Lateral Coupling in AlGaAs/GaAs One of the first ring and disk resonators based on this material system are presented in Rafizadeh et al. (1997). Ring and disk resonators with diameters of 10.5 and 20.5 μm have been fabricated and characterized. The layer sequence of the used device is shown in Fig. 3.33. The layers are grown by MBE. The coupling gap used is only 100 nm wide. A waveguide loss of 3.2 cm−1 is measured for TM polarized light at a wavelength of 1.55 μm. The devices are created by writing patterns upon a PMMA 3.4 III–V Materials 81 Fig. 3.33 Layer structure of AlGaAs/GaAs based ring and disk resonator Fig. 3.34 Layer sequence and dimensions of AlGaAs/GaAs waveguide resist layer by electron-beam lithography (JEOL JBX 5DII). The AlGaAs/GaAs is etched using chemically assisted ion-beam etching (CAIBE). The electron-beam lithography exposure conditions are a 300 pA probe current, a 50 eV acceleration potential, an 80 μm × 80 μm field, and an 11 mm working distance. The PMMA mask is transferred to an underlying SiO2 layer by RIE which provides a robust mask capable of withstanding the CAIBE process. The CAIBE parameters used, are a beam voltage of 500 V, a beam current density of 0.14 mA cm−2 , a chlorine flow rate of 15 standard cubic centimeters per minute (SCCM) at STP,8 an argon flow rate of 2 SCCM, and an elevated substrate temperature of 100 °C. The SiO2 mask is removed after the CAIBE process. The etch rate achieved is 0.1 μm min−1 . The sidewall roughness (vertical striations) observed under the SEM is 10–20 nm. A similar layer sequence with waveguide parameters in the same range is presented in Absil (2000) where racetrack shaped ring resonators with radii between 1.2 and 10 μm have been realized. The layer sequence and dimensions of the used waveguide is shown in Fig. 3.34. A coupling gap between 0.1 and 0.3 μm is envisaged. The fabrication of the laterally coupled ring resonator devices starts by depositing a 420 nm thick SiO2 layer with a nominal deposition rate of 13.6 nm min−1 by PECVD at 300 °C which serves as the mask for the CAIBE process. Before deposition of the SiO2 layer, the sample is rinsed in acetone, methanol and isopropanol followed by a 20 min soak in 8 Standard temperature and pressure. The volume measurement is made at or adjusted to a temperature of 0 °C and a pressure of 1 atmosphere, or 101.325 kPa. 82 3 Materials, Fabrication and Characterization Methods OPD 4262 (a photoresist developer) to increase oxide adhesion on the surface of the wafer. After deposition of the oxide mask layer, the sample is solvent cleaned and dried in a vacuum oven at 120 °C for 1 h. This step is used to increase the adhesion of the electron beam PMMA resist on the oxide. The PMMA resist is spin coated onto the sample leading to a thickness of 500 nm. The resist is cured on a hotplate at 195 °C for 150 s. A Leica Cambridge EBMF 10.5 is used at 50 keV to transfer the ring resonator patterns to the resist. The sample is developed using a solution of MIBK:IPA (1:3) at 25 °C for 150 s and rinsing with isopropanol. The patterns are transferred from the PMMA to the underlying oxide mask layer by RIE using CHF3 and O2 (18:2) with a pressure of 40 mT and an RF power of 175 W. The etch rate of the oxide is 32.5 nm min−1 . The waveguides are etched using a CAIBE process in an ultrahigh vacuum system with 200 eV argon ions and chlorine gas. The etch rate for GaAs is 0.08 μm min−1 . The etching process is performed in three etching runs in order for the sample to cool down. After etching, the oxide mask is removed in an HF dip. Then the sample is spin coated with a 4 μm thick layer of cyclotene or BCB which serves as a protection and planarization layer. The polymer is cured at 200 °C for 2 h. The chip is thinned down in a final step to a thickness of 100 μm which is similar to the InP based devices, also using a bromine/methanol chemo-mechanical process. In order to avoid Fabry–Perot resonances in the bus waveguides, the facets are AR coated using a 250 nm Al2 O3 layer which has a refractive index of n = 1.62. 3.4.6 Vertical Coupling in AlGaAs/GaAs One of the first BCB bonded vertically coupled ring resonators in this material system is presented in Absil et al. (2001), Grover et al. (2001c). Here a single ring resonator channel dropping filter and a 1 × 4 multiplexer/demultiplexer (MUX/DEMUX) crossbar array with double ring resonator filters is demonstrated. The radius of the fabricated ring resonators is 2.5, 5, and 10 μm. The waveguide width is 0.7 μm. The waveguides are tapered to 2.5 μm towards the facet of the chip to improve the fiber to chip coupling efficiency. The layer sequence of the used device is shown in Fig. 3.35. The layers are grown by MBE. A 10× i-line stepper is used for transferring the patterns by photolithography. ICP etching is used for fabricating the bus and ring waveguides. BCB with a thickness between 1 and 2 μm is used to bond the sample to a GaAs transfer substrate and cured at 200 °C. After removing the original substrate, alignment of the ring resonator layer and etching the same, the sample is encapsulated with BCB. This ensures a refractive index symmetry profile, which is also necessary when identical ring resonator structures are realized on both layers for multiring resonators. In order to reduce the effect of layer misalignment a thin layer (~0.2 μm) of AlGaAs is being unetched. 3.4 III–V Materials 83 Fig. 3.35 Layer sequence of vertically coupled GaAs–AlGaAs ring resonators 3.4.7 Implementation of Gain in Ring Resonators Introducing gain inside the ring resonator adds additional functionality and device features. One of the first ring resonators with integrated semiconductor optical amplifiers (SOA) in the GaInAsP material system is demonstrated in Rabus et al. (2002). Single, double and triple parallel and serially coupled ring resonators are presented in Rabus (2002). A photograph of a ring resonator with integrated SOA is shown in Fig. 3.36. The SOA integration is based on a selective area MOVPE process which has also been used in Hamacher et al. (2000) to integrate lasers, photodiodes, waveguides, and spot size converters. The cross section of the used ridge waveguide (RW) semiconductor optical amplifier (SOA) structure is shown in Fig. 3.37. The dimensions are given in Fig. 3.38. The layer sequence is given in Table 3.5. The layer sequence and composition of the used SOA is as follows (from bottom to top). The calculated mode field profile of the RW structure is given in Fig. 3.39. The quantum wells (QWs) and the barrier layers have been considered as one layer with Fig. 3.36 Photograph of a ring resonator with integrated SOA 84 3 Materials, Fabrication and Characterization Methods Fig. 3.37 SEM of cross-section of ridge waveguide SOA, covered with metal contact layer Fig. 3.38 Device structure of the SOA ridge waveguide Table 3.5 Layer stack of the used SOA No. Material λg (nm) Thickness Dopand (cm−3 ) Function 1 InP–Sn-sub 360 μm 2 InP-buffer 500 nm Si: 3 × 1018 Buffer 3 n-GalnAsP 1150 250 nm Si: 3 × 10 n-contact 4 n-GalnAsP 1290 10 nm Undoped Barrier 5 Q 1% compressive strained 6 nm Undoped 6 × QW 6 Q-1.29 1290 10 nm Undoped 6 × barrier 7 GalnAsP 1150 180 nm Undoped LD-WG 8 InP 1500 nm Zn: 5 × 1017 p-top 50 nm Zn: 1 × 200 nm Zn: 1 × 1019 9 GalnAsP 10 InGaAs 1300 Substrate 1018 p-top p-contact 3.4 III–V Materials 85 Fig. 3.39 Mode profile of the SOA (TE polarization) an effective refractive index of neff = 3.4. Due to the multiquantum well structure, the SOA was designed for favoring TE polarization. The effective index of the SOA is determined to be neff = 3.238. The center of the guided mode in the RW structure is located lower compared with the passive waveguide structure. Thus, it is necessary for the integration process to adjust the height of the active–passive transition to assure minimal coupling losses. The butt coupling losses at the passive–active waveguide interface have been calculated by the finite difference method (Fig. 3.40). The calculated vertical and lateral offset between the active and passive waveguide results in a minimum theoretical coupling loss of <1 dB. The starting point for the calculation of the horizontal shift has been chosen so that the passive structure is located symmetrical in the center of the active section. The calculation of the vertical shift starts with the passive–active section, butt coupled Fig. 3.40 Calculated butt-joint losses 6 μm 86 3 Materials, Fabrication and Characterization Methods Fig. 3.41 Lateral dimensions of the active–passive waveguide interface at the position where the rib starts for the passive structure and in the middle of the active layers for the SOA section. The practical realization of the active–passive transition is done in using a special taper structure at the interface. The lateral design is shown in Fig. 3.41. The use of the tapered structure enables the propagating wave coming from the passive waveguide to laterally broaden, interfere, and propagate into the active waveguide with a different refractive index and scale down to the dimension of the active waveguide. Another technological challenge is the fabrication of a low resistance contact of the active section. As directly contacting the SOA on the ridge with a metal needle would destroy the SOA in the worst case, so called “support mesa” are designed at a distance of a few micrometer away from the SOA ridge on either side. The pcontact of the SOA is then located on these mesa for securely placing a measurement needle and for later wire bonding. The support mesas have the same active material layer stack as the SOA. The technological challenge lies in creating a low metal– semiconductor p-contact on the SOA. The isolation of the metal layer on top of the support mesa is performed with a SiNx layer, which is removed only on top of the SOA waveguide. A sketch of the cross section of the SOA with support mesa is shown in Fig. 3.42. The n–contact is realized by metal coating the backside of the wafer. The fabrication starts with the epitaxial growth of the SOA layers by using MOVPE. The first CVD processing step is the deposition of an SiNx layer which is ≈230 nm thick at a temperature of 370 °C for the fabrication of the etching mask. The lateral active mesa structures are defined in a resist pattern by using standard photolithography (positive process, photoresist AZ5214, exposing time ≈24 s, developer MFI724, developing time ≈50 s). The resist pattern serves as an etching mask for the following reactive ion etching step (CHF3 —22SCCM and O2 —2.2 SCCM, Fig. 3.42 Cross-section of the SOA section with support mesa 3.4 III–V Materials 87 pressure = 0.012 mbar, power = 50 W). The photoresist is removed with an O2 plasma (10 min, power = 500 W, T < 250 °C) after this process. The p-top mesa are etched in the following step by using RIE (CH4 —8 ml min−1 and H2 —20 ml min−1 , pressure = 0.006 mbar, power = 200 W). In order to remove the polymer which is formed during reactive ion etching, an O2 plasma (20 min, power = 550 W, T < 250 °C) and a solution of KOH (20%) are used. The p-top is etched down to a distance of about 1.1–1.2 μm followed by a wet etching step by using a solution of 20 H2 O:5 HBr:H2 O2 . This wet etching process is the “undercut” etching. In this step, part of the sidewall is removed. A layer of InP protects the active sections underneath. The etching of the undercut is indispensable for the second epitaxial growth step of the passive waveguide. The undercut reduces the formation of high “rabbit ears” during selective area MOVPE at the vicinity of the mask and enables adequate control of the layer thickness in order to achieve the necessary vertical alignment within the active–passive transition. For further improvement of the SAMOVPE growth step, the “undercut” is covered by a layer of SiNx which is realized by depositing the entire wafer with SiNx and removing the material on the bottom of the wafer by reactive ion etching, leaving the sidewalls covered. The next step is the final etching of the p-top and the active layers using RIE (CH4 —8 ml min−1 and H2 —20 ml min−1 , pressure = 0.006 mbar, power = 200 W). The control of the etch depth is very important in order to adjust the re-growth of the passive material. The following step is the regrowth of the passive material using selective area MOVPE (SAMOVPE). The correct height of the passive material is defined by the thickness of an InP buffer layer. The regrowth process is followed by the removal of the entire SiNx at the “undercut” using hydrofluoric acid (HF—5%). After this step, the entire wafer is covered again with a SiNx layer (≈190 nm) at a temperature of 370 °C. An SEM photograph of the active–passive transition is shown in Fig. 3.43. The SiNx is removed at the top of the active mesa using a photolithographic step, followed by a dry etching step (CHF3 —22 SCCM and O2 —2.2 SCCM, pressure = 0.012 mbar, power = 50 W). The photoresist is removed after the dry etching step using KOH (20%). The following diffusion process (T = 575 °C, 18 s) is carried Fig. 3.43 Active–passive transition 88 3 Materials, Fabrication and Characterization Methods out using zinc arsenide as the dopand. In the next step, the waveguide is etched together with the laser ridge in a so called self-aligning process, where the active– passive interface is generated using RIE (CH4 —6 ml min−1 , H2 —40 ml min−1 , O2 —0.3 ml min−1 , pressure = 0.02 mbar, power = 150 W). Due to the larger height of the laser ridge, the remaining material is etched by selective wet chemical etching using a solution of HCl and H3 PO4 (1:4). The wet etching is automatically stopped, when the quaternary layers are reached. The deep etching of the passive waveguide, which is necessary in order to achieve sufficient optical confinement in small bent waveguides (radii < 200 μm), is the next processing step. The etching mask material is again a SiNx layer structured in a photolithographic and dry etching step. The SiNx layer also serves as a protection layer for the laser ridge. The deep etching of the passive waveguide is done by reactive ion etching using CH4 (8 ml min−1 ) and H2 (20 ml min−1 ) with a pressure of 0.006 mbar and a power of 200 W. The SiNx which was deposited for the protection of the SOA ridge has to be removed only at the very top of it, to be able to place a metal layer for realizing an electric contact. Therefore, the entire wafer is covered with photoresist and is exposed for a few seconds (≈14 s) at the areas of the SOA ridge which results in opening the tip of the laser ridge. The photograph of the top view of an SOA ridge with structured photoresist is shown in Fig. 3.44. In this process the exposing time of the photoresist is the key figure. If the time is too high, the photoresist will become very thin between the SOA ridge and the support mesa and might uncover the insulating SiNx layer which will be etched in the next fabrication step and so cause unwanted short cuts. On the other hand, if the exposing time is too short, only part of the photoresist on top of the SOA ridge is removed and the SiNx layer can not entirely be etched away in the following process. The SEM photograph of the cross-section of a developed SOA ridge is shown in Fig. 3.45. The SiNx layer at the top of the SOA ridge is completely free of photoresist. The area in between the SOA ridge and the support mesa and also the entire wafer are Fig. 3.44 Top view of an SOA ridge with structured photoresist 3.4 III–V Materials 89 Fig. 3.45 SEM photograph of the cross section of a developed SOA ridge covered by photoresist with a thickness of about 800 nm which is a sufficient amount for protecting the SiNx layer from being etched in the next step. The SiNx is removed from the p-top in a dry etching process (CHF3 —24SCCM, H2 —1SCCM, pressure = 0.012 mbar, power = 50 W). Now, the metal contacts are fabricated starting with a photolithographic step for the definition of the contacts. The p-top of the SOA, the area in between the ridge and the support mesa and the top of the support mesa is deposited with titanium, platinum, and gold and the remaining metal is removed in a “liftoff” process using NMP (n-methyl-2-pyrrolidon, C5 H9 NO). A vertically stacked asymmetric twin waveguide structure is used in Menon et al. (2004) to integrate an SOA into an MMI coupled single ring resonator notch filter. The asymmetric twin waveguide structure is grown on a (100) n+ InP substrate using gas source MBE. The layer sequence is shown in Fig. 3.46. The width and height of the single mode passive waveguide is 4 μm and 1.9 μm, respectively. The SOA is formed by etching a 500 μm long stripe, and is coupled optically to the lower passive guide via two-section adiabatic lateral tapers. The width of the taper varies linearly from 3.5 to 2 μm over a 25 μm length followed by a second linear section that varies from 2 to 0.5 μm over a 150 μm length, resulting in a coupling loss of <0.5 dB per taper. The length and width of the MMI is 685 μm and 12 μm, respectively. The input and output waveguides are angled at 7 °C to the cleaved edge of the chip in Fig. 3.46 Layer sequence of asymmetric twin waveguide structure 90 3 Materials, Fabrication and Characterization Methods Fig. 3.47 Layer sequence of active and passive waveguide used in TIR ring resonator order to avoid Fabry–Perot resonances in the bus waveguide. The wafer is planarized using silicon nitride (SiNx ) followed by a short etch back to open the SOA ridges and the taper. Electron beam evaporation was used to deposit Ti–Ni–Au p-contacts on the active ridge including the tapers. The p-contacts are annealed at 415 °C for 30 s. The wafer is thinned to 130 μm, and a Ge–Au–Ni–Au n-contact is deposited on the back of the substrate, and annealed at 360 °C for 90 s. Total internal reflection (TIR) mirror based GaInAsP ring resonator notch filters integrated with SOAs are presented in Kim et al. (2005a). The ring resonators are made out of four TIR mirrors, an MMI coupler with a length of 113 μm and the SOA (see also Fig. 5.36). The layer sequence of the active and passive waveguide is shown in Fig. 3.47. The passive waveguide A which leads to the facet and the TIR mirrors is tapered down (taper length 15 μm) from a width of 1.5 μm to a width of 3 μm. The edge depth is 1.8 μm for this type of waveguide as well as for the active waveguide. The passive waveguide B is connected to waveguide A and differs only from type A by a deeper etch depth which is 4.5 μm. The fabrication of the device is started by growing the active layers on a n+ InP substrate. The multiquantum wells consist of seven quantum wells, each 6.5 nm thick, separated by barrier layers with a thickness of 8 nm. The active layers are etched away in unwanted areas in the next step, which is followed by a regrowth step with passive material. Standard RIE and metallization techniques are used for realizing the device. Vertically coupled disks with radii of 10 μm employing gain are demonstrated in Djordjev et al. (2002a). The fabrication of the vertically coupled disk is based on the passive disk explained earlier (see Fig. 3.30). The layer sequence of the active disk is listed in Table 3.6. In order to limit the interaction of the optical field with the metal bond pads, a 3 μm thick layer of polyimide is applied between the surface of the substrate and the metal layer by using a standard liftoff process which leaves the active regions polyimide free for creating the metal contact. Finally the sample is thinned down to a thickness of 100 μm, the n-metal contact is deposited and contact annealing is performed. Then the samples are cleaved into 3.4 III–V Materials 91 Table 3.6 Layer sequence of active disk (Djordjev 2002) Bandgap λ Layer No. Material Thickness (nm) Doping 17 InP 300 n+ , 106 16 InP 700 n, 5 × 1017 15 GaInAsP 400 n, 3 × 1017 14 InP 800 n, 3 × 1017 13 GaInAsP 1.25 170 12 GaInAsP 1.55; 1% strain 4×8 11 GaInAsP 1.25 3 × 10 10 GaInAsP 1.25 170 9 Inp 100 8 InP 100 p, 3 × 1017 7 InP 100 p, 5 × 1017 6 InP 600 p, 1 × 1018 5 InGaAs 200 p+ , 1 × 1019 4 InP 100 3 InGaAs 200 2 InP 100 1 InP 1.1 n, 3 × 1018 n+ bars and deposition of AR coating on both facets is applied. A SEM photograph of the cross section of a vertically coupled disk is shown in Fig. 3.48. These active disk resonators are the first of its kind employing gain to change the resonant filter characteristic. A detailed theoretical analysis of vertical coupled ring resonators employing active and passive layers is presented in Tee et al. (2006). A design layout based on the calculations is developed. 3.5 Polymers Polymer photonic integrated circuits have always been playing an important role in literature (Ma et al. 2002). Polymers have recently attracted again a lot of attention due to the lower cost of the material (if standard polymers are used), easier processibility and integration than semiconductor materials. Polymers can be doped with appropriate materials for engineering desired properties. Different polymer material systems exist on the market today for realizing not only purely passive devices, but also electro-optic and thermooptic devices. In the following chapter polymer based ring resonators made by using different fabrication technologies will be presented. 92 3 Materials, Fabrication and Characterization Methods Fig. 3.48 Cross-sectional scanning electron microscope photograph of an active microdisk device Djordjev et al. (2002a) 3.5.1 Conventional Fabrication Techniques In order to fabricate polymer waveguide based components, mainly two processing methods are used, which are well known from the semiconductor field, namely photoresist based patterning and direct lithographic patterning (laser direct writing, photobleaching, electron beam direct writing). Both methods are briefly sketched in Fig. 3.49. A polymer waveguide generally consist of a core and a cladding polymer where the refractive index of the core is higher than the cladding to enable the propagation of optical waves. Of course the cladding can also be left out and air can be used instead, which depends on the application. Figure 3.50 shows a typical photograph of the facet of a polymer waveguide, realized by RIE and spin coating in poly (perfluorocyclobutylaryl ether) (PFCB). As can be seen from the photograph the core waveguide has a nearly rectangular shape. RIE processes are aimed for obtaining smooth and vertical sidewalls to reduce scattering losses. One of the first integrated polymer ring resonator add drop filters with a radius of 4.5 cm is presented in Haavisto and Pajer (1980). The ring resonator is fabricated by photopolymerization of doped polymethylmethacrylate (PMMA) films spun onto a silicon wafer. The patterns are written by a focused 325 nm He–Cd laser. The width of the achieved waveguides is 10 μm. The coupling gap is 17.5 μm, measured from the waveguide center to center. A prism coupling arrangement is used for measuring the device. 3.5 Polymers 93 Fig. 3.49 Photoresist (left) and direct lithographic (right) patterning for realizing polymer waveguides Fig. 3.50 Polymer waveguide realized by RIE and spin coating A ring resonator notch filter with a radius of 15.9 mm using polymers synthesized from deuterated9 methacrylate and deuterated fluoromethacrylate are described in Hida et al. (1992). The ring resonator is fabricated on a silicon substrate by spin coating, photolithography and dry etching. The height and width of the waveguide core is 6.4 and 7.0 μm, respectively. The relative refractive index difference between the core and the cladding is set to 0.5% by controlling the copolymerization ratio of the two monomers. A coupling gap of 3 μm is realized between the bus waveguide and the ring. Polymer ring resonator filters and modulators with vertically coupled input and output waveguides are demonstrated in Rabiei et al. (2002). Two different kinds of 9 Introduction of deuterium into the chemical compound. 94 3 Materials, Fabrication and Characterization Methods Fig. 3.51 Layer sequence and dimensions of waveguides (refractive indices are given for a wavelength of 1550 nm) Fig. 3.52 Photograph of a passive polymer ring resonator add-drop filter Rabiei et al. (2002) ring resonator filters are fabricated, one with an index difference between core and cladding of 0.1 and a radius greater than 220 μm, and a second one with an index difference of 0.3 between core and cladding and radius greater than 25 μm. The layer sequence and the dimension of the waveguides used in the passive ring resonator filter are shown in Fig. 3.51. A photograph of a passive ring resonator filter is shown in Fig. 3.52. The fabrication of the device with an index difference of 0.3 between core and cladding starts by spin coating a 2.8 μm Teflon film (11% solution of Teflon AF 1600 (Dupont) in 3M FC-40 solvent) on a silicon substrate. The Teflon layer is etched for 2 min in oxygen by RIE to improve the adhesion of the Teflon to the next layer. A 1.5 μm SU-8 (negative photoresist) layer is spin coated onto the etched Teflon layer and patterned by lithography to form the ring resonator. The ring resonator waveguides are planarized by spin coating a 4.5 μm thick Teflon layer. The Teflon layer is again etched by RIE in oxygen to increase the adhesion of the following polymer layer. The bus waveguides are realized by lithographic patterning, RIE etching of the Teflon cladding layer, spin coating a UFC 170A (URAY Co., Korea) layer, UV curing, and baking. Remaining UFC 170A which is not part of the waveguide is removed using RIE. For the fabrication of the ring resonator filter with an index difference of 0.1 between core and cladding layers the cladding material is UFC 170 A and the vertically coupled bus waveguides are made out of NOA61 (Norland 3.5 Polymers 95 Fig. 3.53 Layer sequence and dimensions of waveguides used in the modulator Products). The fabrication of the polymer ring resonator modulator is in principal the same as for the passive device. The layer sequence of the ring resonator modulator is shown in Fig. 3.53. The CLD1/APC polymer is aligned using corona polling for 30 min at a polling temperature of 145 °C and an applied voltage of 10 kV. An upper gold electrode is deposited and patterned on top of the device to cover the ring resonator modulator. A photograph of a fabricated ring resonator modulator is shown in Fig. 3.54. A free standing polymer ring resonator notch filter is presented in Paloczi et al. (2003a), Huang et al. (2004). The polymer waveguides are embedded in a lower cladding of UV-15 (n = 1.5, λ = 1.55 μm) and an upper cladding of OG-125 (n = 1.46, λ = 1.55 μm). The waveguide cores which are made of SU-8 (n = 1.57, λ = 1.55 μm) are 2 μm wide and 1.6 μm thick. The SU-8 waveguides are patterned by direct electron beam lithography and following development process. The upper cladding is spin coated and UV cured. The free standing feature is achieved by a thin gold layer deposited on to the silicon substrate onto which the UV-15 layer is spin coated. Due to the weak adhesion of the UV-15 layer, it is possible to peal of the polymer layer (thickness ~10 μm) with the integrated ring resonators. Optical quality facets are realized by simple cutting with a scalpel. One of the smallest ring resonator add drop filters with a radius of 10 μm is demonstrated in Chen et al. (2004) in the polymer BCB (Cyclotene 3022-46 from the Dow Chemical Company). An SEM photograph of a fabricated ring resonator is shown in Fig. 3.55. Racetrack shaped ring resonators with bending radius of 10 and 4 μm straight coupling sections are also presented. The layer sequence of the device is shown in Fig. 3.56. BCB is cured at a temperature of 250 °C. SiO2 is used as an etch mask to transfer the patterns of the waveguides from photoresist to the used BCB. SiO2 is etched using a trifluoromethane and oxygen plasma, BCB is etched using a sulfur hexafluoride 96 3 Materials, Fabrication and Characterization Methods Fig. 3.54 Fabricated polymer ring resonator modulator Rabiei et al. (2002) Fig. 3.55 BCB microracetrack resonator. The filter section has 0.9 μm wide waveguides, which are tapered to 2.5 um at the input–output sections Chen et al. (2004) 3.5 Polymers 97 Fig. 3.56 Layer sequence of BCB ring resonator Fig. 3.57 Left: Microscopic front view of a cleaved sample showing the Si substrate, the SiO barrier, and the cross-section of a port waveguide. The structures are by about 10% thinner than the films before development since the oxygen at the surface reduces the polymerization during the exposure. Right: Microscopic top view of a laterally coupled ring resonator of Ormocore. The external radius of the ring is 50 μm with a cross-section of 3.8 μm width and 4.5 μm height; the port waveguides are 2.7 μm wide and 3.6 μm high. The gaps at the couplers are 0.3 μm wide Rezzonico et al. (2006) and oxygen plasma. The etch mask is removed by buffered hydrofluoric acid. The width of the waveguides is 0.9 μm at the coupling gap and is tapered to 2.5 μm at the facets. Laterally coupled organic–inorganic hybrid polymer ring resonator add drop filters with a radius of 50 μm are presented in Rezzonico et al. (2006). A photograph of a fabricated ring resonator and a cross-section of a waveguide are shown in Fig. 3.57. The waveguides are made out of Ormocore, from the family of Ormocer®10 a commercially available inorganic–organic hybrid polymer (negative photoresist, n = 1.536, 0.6 dB cm–1 at a wavelength of 1.55 μm, T g > 270 °C). A two step lithography process is used to realize the laterally coupled ring resonator add drop filter. The layer sequence is similar to the one shown in Fig. 3.56 for the BCB ring resonator, 10 Trademark München. of the Fraunhofer–Gesellschaft zur Forderung der angewandten Forschung e.V. 98 3 Materials, Fabrication and Characterization Methods substituting Ormocore for BCB. The SiO2 layer used has a thickness of 4 μm. In a first step, the port waveguides are defined using an exposure in oxygen poor atmosphere through a negative chrome mask. The sample is developed in methylpentanone. Then the sample is spin coated again with Ormocore, patterned and developed for realizing the ring resonator. The gap between the ring and the bus waveguides is aimed to be 0.5 μm (measured 0.3 μm). The sample is hard baked at 150 °C in inert atmosphere. The width and height of the bus waveguides is 2.7 and 3.6 μm, respectively. The width and height of the ring waveguide is 3.8 and 4.5 μm. 3.5.2 Replication and Nanoimprinting One of the first ring resonators realized using a nanoimprint technique is presented in Chao and Guo (2002). Here waveguides made out of PMMA, polystyrene (PS) and polycarbonate (PC) are demonstrated. SEM photographs of directly imprinted polycarbonate racetrack and disk resonators are shown in Fig. 3.58. Two fabrication methods are demonstrated, direct imprinting (Fig. 3.59) and template filling (Fig. 3.60). The fabrication (Fig. 3.59) of the molding tool is performed in two steps. First, a silicon substrate is etched using RIE, realizing the first molding tool for imprinting the device pattern into PMMA which is used as a resist for the following Ti/Ni liftoff process. The remaining PMMA on the surface of the sample is etched using an oxygen RIE process, thus only leaving the structured PMMA in place. Ti/Ni which is deposited on to the sample is used as a hard mask for the following RIE process to etch the SiO2 layer, realizing the second and final molding tool for imprinting the waveguides again in PMMA with a molecular weight of 15,000 (imprinting time = 10 min). In order to increase the optical confinement of the mode in the waveguides, a buffered hydrofluoric acid (BHF) etch is performed, resulting in an undercut of the SiO2 layer underneath the waveguides forming a pedestal. In order to separate the molding tool from the polymer waveguides, the molding tool is coated with a Fig. 3.58 Directly imprinted polycarbonate racetrack and disk resonators Chao and Guo (2002) 3.5 Polymers 99 Fig. 3.59 Process flow for directly imprinting into a polymer Fig. 3.60 Process flow for polymer template filling surfactant to provide a low surface energy. SEM photographs of PMMA waveguides sitting on top of a thermally grown SiO2 pedestal are shown in Fig. 3.61. In the template filling method (Fig. 3.60), a second layer of SiO2 is grown by PECVD which is structured using the same processing steps as in the direct imprinting method for obtaining the molding tool, spin coating PMMA, imprinting and removal of residual PMMA by dry etching, deposition, and liftoff of Ti/Ni for the hard mask fabrication, dry etching of the PECVD SiO2 layer and removal of the metal layer. The molding tool is filled with polymer. Planarization is done with a flat molding tool. The residual polymer is removed by RIE and the sample is heated to remove unwanted air bubbles in the polymer. Finally, the sample is again etched with a buffered HF 100 3 Materials, Fabrication and Characterization Methods Fig. 3.61 Cross-section SEM picture of a rectangular PMMA waveguide sitting on top of a SiO2 pedestal. b PMMA waveguides in the coupling region of a microring device Chao and Guo (2002) realizing the pedestal for the polymer waveguides. To reduce the surface roughness induced scattering loss and therefore increase the performance of the polymer ring resonator devices, the authors propose a thermal reflow technique in Chao and Guo (2004). Polymer ring resonator devices are heated with controlled time duration (60– 150 s) in a temperature range of 10–20 °C below the glass transition temperature of the polymer. This lowers the viscosity and enhances the fluidity of the polymer, resulting in a reflow which reduces the surface roughness significantly under the action of surface tension. The variance of surface roughness is estimated to decrease by 35–40 nm in the ring and by 15–20 nm in straight waveguides. Replication of polymer ring resonators using a soft lithography method is demonstrated in Huang et al. (2003). The fabrication process is illustrated in Fig. 3.62. Ring resonators made out of SU-8 are presented. The samples are cleaved after molding and curing to achieve optical quality facets. A photograph of a ring resonator is shown in Fig. 3.63. This soft lithography method has also been used in Poon et al. (2004) to fabricate ring resonator devices without cladding and cladding in polystyrene (PS) and SU-8, respectively. Here a 3 μm thick layer of OG-125 (n = 1.456, a UV curable epoxy) is used as the under cladding instead of growing a SiO2 layer with PECVD as previously done which is UV cured at 80 °C for 2 min. The ring resonators without cladding are fabricated by deposition of 10 μl of PS solution (4 wt% in toluene) on the sample and pressing the mold against the chip with a force of 25 N for 20 min. The toluene evaporates through the PDMS mold, leaving behind a 200 nm residual film which does not influence the characteristic of the ring resonator. Finally the chip is baked at 80 °C for 3–5 min. The SU-8 ring resonator is fabricated in a similar way. The only difference is that SU-8 is UV cured and the sample is baked at 80 °C for 3 min. Another layer of OG-125 with a thickness of 3 μm is spin coated, UV cured and baked at 80 °C for 3–5 min to form the upper cladding. All samples are cleaved 3.5 Polymers 101 Fig. 3.62 Replication of polymer ring resonators by soft lithography Fig. 3.63 Optical microscope image of microring optical resonator fabricated by soft lithography. The inset shows the detail of coupling region. The ring diameter is 200 μm, the waveguide width is 2 μm, and the gap between the straight waveguide and the microring is 250 nm Huang et al. (2003) for device separation. The ring radius is 200 μm and the height and width of the waveguide is 1.5 and 1.9 μm, respectively. Polymer racetrack shaped ring resonator notch filters with radii of 100 μm and 200 μm and a coupling length of 100 μm and 40 μm, respectively, fabricated using an imprinting technique with a smoothing buffer layer are presented in Kim et al. (2005b). The width of the coupling gap used is 200 nm. The layer sequence and dimensions of the used waveguide is shown in Fig. 3.64. The stamp fabrication starts by patterning a quartz glass wafer coated with chromium using photoresist. After UV exposure, the chromium is etched and the so achieved hard mask is used to transfer the pattern to the substrate by RIE. The smoothing buffer layer is made by depositing an SiN film using LPCVD. The pattern on the stamp is transferred to the cladding of the sample by general imprinting, where the stamp is pressed against the polymer layer. The cladding is UV cured and 102 3 Materials, Fabrication and Characterization Methods Fig. 3.64 Layer sequence and dimensions of waveguide the stamp is removed, leaving behind the trench for the core waveguide. The core polymer is spin coated onto the sample and cured. Finally the sample is cleaved and the devices are separated. Imprinting technologies are an attractive way of realizing ring resonators, especially due to the fact that the manufactured stamp can be used several times. This aspect is important, when it comes to producing a large number of devices which is a requirement for realizing low cost products for the telecommunication and sensor market. The rise of these fabrication technologies enables a renaissance of polymer materials and opens up the way for new materials with appropriate manufacturing properties suitable for replication. 3.5.3 Novel Polymer Devices In the early 2000s, micro-ring wavelength filters and resonant modulators using polymer materials at 1300 and 1550 nm have been started to be massively designed and demonstrated, as already reviewed in the previous sections. Initial results referred to rings integrated with vertically coupled input and output waveguides (Rabiei et al. 2002) where devices have been realized by optical lithography. Filters with a finesse of 141 and free spectral range of 5 nm at 1300 nm and finesse of 117 with a free spectral range (FSR) of 8 nm at 1550 nm have been therefore reported (Rabiei et al. 2002) with a Q value close to 1.3 × 105 at 1300 nm. The interesting feature of these filters was the temperature tuning at the rate of 14 GHz/°C. In parallel resonant ring modulators based on electrooptic polymers granted resonance wavelength voltage tunes at the rate of 0.82 GHz/V and bandwidth larger than 2 GHz. Using the resonant modulator, and open eye diagram at 1 Gb/s is demonstrated. Inorganic–organic hybrid polymer polysiloxane-liquid (PSQ-L) have also been used for all-polymer microring resonators fabrication (Teng et al. 2009). In this case the waveguide circuits have replicated by a simple ultraviolet-based soft lithography method bringing to 6-dB extinction ratio at the through port and 18-dB extinction ratio at the drop port is demonstrated. A Q-factor of 4.2 times 104 has been reported, with scattering loss of the ring waveguides estimated to be about 1.6 dB/cm. These promising results have been continuing to push for further research and applications because polymers present the great advantage of being cheap and scalable for mass production, and compatible with both 2D and 3D geometries. Several different techniques have been optimized such as the previously cited soft lithography. Among the others soft 3.5 Polymers 103 nano imprint lithography (NIL) process have been exploited for producing devices with smooth surfaces, combined with fast sol–gel technology providing highly transparent materials (Bar-on et al. 2018). Standard soft NIL is based on casting an elastomeric material such as Polydimethylsiloxane (PDMS) on a prefabricated template exhibiting the desired geometry of the final device. The PDMS is cured and peeled off from the master, forming a mold with the negative geometry of the master that can be used for further replicas by imprinting\molding. This process can be performed also in a dual step configuration, the first step to eliminate the roughness of the device surfaces while the second step transforms the device into fast sol–gel respectively (Bar-on et al. 2018). The combination of these two steps allow to achieve low surface roughness but highly transparent material based devices, in both 2D and 3D geometries. A sketch of this two steps procedure is reported in Fig. 3.65. This approach has demonstrated to be highly efficient in realizing micro ring resonators made by direct laser writing (DLW) to achieve a quality factor improvement from one hundred thousand to more than 3 million, a step forward in getting higher and higher Q-factor devices for UV-curable integrated micro-ring resonators (Bar-on et al. 2018) (Fig. 3.66). An example of the resulting transmission and Q-factors are reported in Fig. 3.67. The absorption limited Q-factor is determined by the propagation losses approximately close to 10−3 dB cm−1 . This value corresponds to a potential intrinsic quality factor of Q ~ 6 × 108 . Fig. 3.65 Dual-step soft nano imprint lithography process. a Master device fabricated using DLW made of crosslinked SU-8 (Grey). b First soft NIL step—Replication of the master device into non-crosslinked SU-8 (Yellow). c Reflowed replica from non-crosslinked SU-8 (Yellow). d Second soft NIL step—Replication of the reflowed resonator into sol–gel (Blue) (Bar-on et al. 2018) 104 3 Materials, Fabrication and Characterization Methods Fig. 3.66 SEM images of sol–gel micro-resonators generated using a Standard soft NIL. b DSSNIL. The numbers on figure ‘a’ point to defects from the original fabrication process. (1) Roughness resulted from the finite voxel size. (2) Bump resulted from the start stop point of the DLW process. As can be seen, both of these defects almost disappear entirely after the reflow process (Bar-on et al. 2018) Fig. 3.67 a Transmission spectra of a reflowed resonator. b Q-factor comparison between resonators generated using standard NIL compared to DSS-NIL (Bar-on et al. 2018) Starting from these technological improvements on the preparation techniques, novel polymer devices have been recently launched and gained extreme interest and some will be briefly commented in the following. Novel Polymer Microring Resonators for Optical Modulation The microring phase response can be suitably converted to an intensity modulation by combination with a Mach–Zehnder interferometer (MZI). An example of this principle has been presented in polymer based structures in Leinse (2005). When switching between the on and off-resonance conditions, in fact, the difference between the two branches of the MZI can be switched from π to zero. An example 3.5 Polymers 105 of such a combination between an microring resonator and MZI, as is shown in Fig. 3.68. The functionality of polymeric electrooptic microring resonators have been shown in a device with waveguide and the microring done by reactive ion etching (RIE). It is worth mentioning that RIE can induce roughness and therefore introduces losses in both the ring and the waveguides. This problem can be overcome by exploiting an etch-free lithographic process. In order to achieve a MZI+ring configuration, Leinse and coworkers optimized the process by sesigning the waveguide with the aid of a negative photoresist (SU8, n = 1.57 at 1550 nm) in a two-layer lithographic process. The first layer defined the 0.7 μm-thick slab of the waveguide, of which t he part under the microring is removed. The second layer is a thin layer of 300 nm in which 2-μm-wide waveguides are defined lithographically. Between the waveguides and the MR, a 1-μm-thick layer of a methyl-silicone based resin (n = 1.4 at 1550 nm) was used. The same was exploited for the 4-μm cladding layer over the microring. The last had a height of 0.8 μm and a radius of 150 μm respectively. It is important to notice that the microring losses have been reduced by post heating processes so that the polymers could reach temperature close to the glass transition temperature and consequently smooth the sidewalls. The MZI was balanced by applying a heater over one of the branches (Leinse 2005). The measured spectrum of the MZI ring device is reported in Fig. 3.69 (Leinse 2005). Fig. 3.68 Top: MZI+ring schematic three-dimensional view; Bottom: section through MR and waveguides (Leinse 2005) 106 3 Materials, Fabrication and Characterization Methods Fig. 3.69 Measured spectrum (TE) of the MZI ring device. The vertical line indicates the wavelength of the CW tunable laser chosen for the modulation measurements (Leinse 2005) Novel Polymer Microring Resonators for Lasing A novel polymer based microring resonator configuration for lasing has been proposed by Chandrahalim (2015): in their work a wavelength configurable on-chip solid-state ring lasers fabricated by a single-mask standard lithography is made. A single- and coupled-ring resonator hosts were realized on a fused-silica wafer and filled with Dye doped polymers. In particular d3,3 -Diethyloxacarbocyanine iodide (CY3), Rhodamine 6G (R6G), and 3,3 -Diethylthiadicarbocyanine iodide (CY5)doped polymer as the reconfigurable gain media have been used. In Fig. 3.70 a sketch of the realized device is depicted (Fig. 3.71). The system demonstrated a lasing threshold ~220 nJ/mm2 per pulse for the singlering resonator laser with R6G. This achievement results in being among the lowest threshold shown by solid-state dye-doped polymer lasers fabricated with a standard lithography process on a chip. A single-mode lasing from a coupled-ring resonator system with the lasing threshold of ~360 nJ/mm2 per pulse was also demonstrated through the Vernier effect. As far as the renewability of the dye-doped polymer is concerned, the authors in Chandrahalim (2015) removed and redeposited the dyedoped polymer on the same resonator hosts for multiple cycles. They recorded consistent emissions from the devices for all trials, showing that the proposed technology can be applied in numerous photonic and biochemical sensing applications that entail for sustainable, reconfigurable, and low lasing threshold coherent light sources on a chip. An example of the achieved results is reported in Fig. 3.72 were different Lasing spectra are represented depending on the dye system under consideration. Recent advances have been shown also in the application of roll-to-roll nanoimprint lithography (R2RNIL) to produce all-polymer devices, including microring resonators, waveguides, photonic crystals, diffraction gratings (Shnneidman et al. 2018). In particular loaded quality factors as high as 57,500 have been measured in ring resonators at the telecom wavelength range and frequency resolution of ~25 pm, 3.5 Polymers 107 Fig. 3.70 3-D and cross-sectional schematic of the fused-silica ring resonator coated with a gain medium doped high refractive index polymer (Chandrahalim and Fan 2015) Fig. 3.71 Scanning microscope images of the fabricated ring resonators: a Single ring resonator with inner and outer radii and depth of 110, 150, and 12 μm respectively. b Coupled ring resonators with an outer radius of 150 μm and 145 μm, respectively. Both ring resonators are 40 μm wide and 12 μm deep. The coupling distance between the two rings is approximately 1 μm (Chandrahalim and Fan 2015) enabling on-chip high resolution sensors and spectrometers. Examples of produced devices are reported in Fig. 3.73: a master of a 1 mm ring resonator coupled to an sshaped waveguide (3.2 μm wide, 1.5 μm tall) via a 1.2 μm coupling gap is presented s (Shnneidman et al. 2018). The related results of the optical transmission measurements are summarized in Fig. 3.74. Microring resonators have been also realized by femtosecond laser-induced twophoton photopolymerization in photoresist SU-8 (Zhang et al. 2020). By tuning the 108 3 Materials, Fabrication and Characterization Methods Fig. 3.72 Lasing spectra of a CY3-doped SU-8, b R6G-doped SU-8, and (C) CY5-doped SU-8 single ring resonator lasers. All spectra are vertically shifted for clarity. d–f Spectrally integrated laser outputs (542–548 nm for CY3-doped SU-8, 586–601 nm for R6G-doped SU-8, 760–770 nm for CY5-doped SU-8) after fluorescence background removal as a function of the pump intensity extracted from (a–c). The lasing thresholds for CY3, R6G, and CY5-doped SU-8 are approximately 1.9, 0.2, and 3.9 μJ/mm2 , respectively. Error bars are obtained with 3 measurements (Chandrahalim and Fan 2015) laser parameters, it has been demonstrated that the performance of the polymeric microring resonator can be tailored with high accuracy, including the magnitudes of the radius and cross section. These authors have reported that the free spectral range of the microring resonator is closely related to the values of ring radius, resonance wavelength, cross section of the microring as well as the polarization of the light. In particular it has been demonstrated that a ring resonator has a free spectral range linearly increasing with the ring radius and in particular a radius of 60 μm corresponds to a free spectral range of 3.9 nm (Zhang et al. 2020). A summary of these results is reported in Fig. 3.75 together with a micrograph of the obtained microring structure. Although it is expected that the free spectral range does not change in multiple microrings, in this case the full-width half-maximum of the resonance is larger. Moreover, the polarization modes of the microring resonator present different resonance wavelengths due to different effective refractive indices. The transmission spectra of microring resonators with different radii values in SU8 are reported in Figs. 3.76 and 3.77 respectively. Among the various structures for integrated waveguide photonic based polymers devices, it is worth mentioning that polymers based microring resonators have attracted great attention especially in the frame of developing biosensors. Thanks to their high Q-factor, compactness, and potential high-density array they in fact are excellent candidate for sensing multiple targets. A recent comprehensive review of the optical sensing properties of ring resonators has been made in Ciminellin et al. (2013). In particular the high Q-factor provides an enhanced interaction between the 3.5 Polymers 109 Fig. 3.73 Variety of structures fabricated by the R2RNIL method. SEM images of a master (top), stamp (middle), and replica (bottom) for a 1D nanobeam photonic crystal cavity (the waveguide width and height are 700 and 220 nm, respectively, the pitch is 300 nm, and the hole diameter decreases from 165 nm at the center to 80 nm at both ends); b master (top) and replica (bottom) of a 1D nanobeam photonic crystal cavity with elliptical holes (3.2 μm wide and 500 nm tall waveguide, pitch was 550 nm, ellipse minor and major axes linearly decrease from the center to both ends from 165 to 140 nm, and from 1.44 to 1.22 μm, respectively); c master (top) and replica (bottom) of a portion of a photonic crystal slab featuring 100 × 100 array of holes with 100 nm radii, 700 nm center-to-center distance, and approximately 90 nm hole depth; d master of a 1 mm ring resonator coupled to an s-shaped waveguide (3.2 μm wide, 1.5 μm tall) via a 1.2 μm coupling gap (inset, SEM of the coupling region in the replica coated with 10 nm of 80:20 Pt:Pd to prevent charging) (Shnneidman et al. 2018) optical evanescent field and the biological analyte that can be put into contact with the ring structure and therefore be sensed or analyzed as it will be detailed in Chap. 5. In this cases, polymer microring-based biosensors have been designed with ridge shape waveguide structure by selective imprinting technique (Wang et al. 2012). Polymer microrings have been shaped in racetrack with a radius of 350 μm, with a gap and coupling length between the straight waveguide and the microring waveguide are 1 and 70 μm, respectively. 110 3 Materials, Fabrication and Characterization Methods Fig. 3.74 Optical transmission measurements. a Cartoon of the full device, consisting of a ring coupled to an s-waveguide. b Transmission measurement at telecom wavelengths, showing dips in transmission due to ring resonances. c Images taken with an IR camera when the laser wavelength is fixed either off resonance (red border), where scattering is seen from the waveguide only, not from the ring, or on resonance (green border), where scattering is seen both from the waveguide and the ring. d High resolution scan of one resonance dip. Q from fit: 57,500 ± 200 (Shnneidman et al. 2018) Fig. 3.75 Morphologies of microring resonators fabricated in SU8 systems: a a microring with a radius of observed by an optical microscope. b Dependence of free spectral range on 1/R (Zhang et al. 2020) 3.6 Temperature Insensitivity 111 Fig. 3.76 Transmission spectra of microring resonators with radii of a 60, b 80, c 100, and d, respectively. e Dependence of free spectral range on 1/R (Zhang et al. 2020) 3.6 Temperature Insensitivity Temperature stability of photonic integrated circuits is a key challenge which applies to all devices, especially resonant based devices like ring resonator filters. In ring resonator filters, the wavelength to be filtered out for example has to exactly match the rings resonance wavelength. Temperature shifts the resonance spectra of ring resonator filters depending on the materials used for fabricating the device. For stabilizing the resonance wavelength of ring resonator filters, a temperature control unit with a heater or a Peltier cooler is needed. This requires a permanent power consumption of a few watts and electronic control circuits. The major goal is therefore to eliminate these additional expenses and sources of defect. For this reason, temperature insensitive or athermal waveguide based devices have been investigated (Kokubun et al. 1993; Chu et al. 1999c; Keil et al. 2001). The temperature dependence of photonic integrated circuits (PICs) is mainly caused by the temperature dependence of the optical path length. In the case of ring resonator add/drop filters, the center wavelength of the passband is determined only by the optical path length of the ring resonator. The temperature induced effective index shift in a ring waveguide cannot be compensated by a similar induced effective index change of the bus waveguides. 112 3 Materials, Fabrication and Characterization Methods Fig. 3.77 Morphologies and transmission spectra of single-ring and four-ring resonators with a radius of 80μ and ring cross section of 4.48 μm × 4.23 μm (Zhang et al. 2020) The basic principle of an athermal waveguide is derived in the following using (Kokubun et al. 1997). The temperature dependence of the center wavelength of a device can be expressed by dλ0 = dT 1 dS L dT · λ0 , n eff (3.1) where λ0 is the central wavelength, L is the waveguide length of the device, T is the absolute temperature and neff is the effective index of the waveguide [see also (2.4)]. S is the optical path length and is given by S = n eff · L . (3.2) The temperature dependence of the optical path length of an optical waveguide on a substrate is given by differentiating (3.2) with T, dividing both sides by L 1 dL 1 dS dn eff dn eff = + n eff = + n eff αth , L dT dT L dT dT (3.3) 3.6 Temperature Insensitivity 113 where α th is the coefficient of thermal expansion. In the case of a waveguide, the coefficient of thermal expansion is the one of the substrate, since the thickness of the substrate is much larger than the waveguide layer. Table 3.7 gives the coefficient of thermal expansion for some bulk materials. In order to achieve an athermal condition, the following equation has to be satisfied. dn eff + n eff αth = 0 dT ⇒ αth = − 1 dn eff . n eff dT (3.4) From (3.4), two possibilities exist of designing an athermal waveguide based device. Either a substrate with a negative value of α th or a waveguide material with a negative value of dneff /dT can be chosen. One of the first temperature independent ring resonator filters based on a striploaded athermal waveguide is presented in Kokubun et al. (1997). Here, a transparent material having a negative value of dneff /dT is chosen for the design of the waveguide. This gives more freedom in designing the waveguide, as the parameters of used bulk materials obviously cannot be changed. The structure and dimensions of the athermal waveguide used are shown in Fig. 3.78. The design makes use of the negative value of dneff /dT for PMMA which is −105 × 10−6 at λ = 633 nm for bulk material. Table 3.7 Coefficients of thermal expansion of some materials Fig. 3.78 Dimensions of athermal waveguide design Material Coefficient of thermal expansion α th (×10−6 /°C) BCB 42 MMA 68 Si 2.6 InP 4.6 GaAs 5.8 Au 14 Al 24 Ag 18 Pt 9 114 3 Materials, Fabrication and Characterization Methods The radius of the ring is 5 mm resulting in a free spectral range of 0.037 nm. The finesse is measured to be 2.6. The athermal design leads to a temperature coefficient for the central wavelength of 7 × 10−4 nm K−1 . Another ring resonator filter where the temperature dependence of the center wavelength is compensated by application of a polymer overlay is demonstrated in Chu et al. (1999c). The design of the waveguide is similar to the one described in Figs. 3.8 and 3.9. The material which is used as the polymer overlay is a copolymer made by a combination of PMMA and tri-fluoroethyl-methacrylate (TFMA). The refractive index at room temperature is 1.44 and the value of dneff /dT is −1.44 × 10−4 /°C. The material is deposited onto the device using spin coating realizing a height of more than 3 μm. The center wavelength shift due to rising temperature increases linearly without compensation by 0.0137 nm °C−1 from room temperature to 103 °C. Using the polymer overlay, this value is decreased in the temperature range between 25 and 55 °C resulting in a wavelength shift of −0.0025 nm °C−1 . Above 55 °C this value increases to −0.03 nm °C−1 mainly due to the low glass transition temperature (T g ) of the polymer which is around 80 °C. Polymers with a higher T g like polymides are preferred in utilizing this method to realize an athermal behavior. A similar method employing a birefringent polymer overlay can also be used to realize polarization independent ring resonator filters (Kokubun et al. 2001). A different approach for realizing athermal waveguide based devices is presented in Keil et al. (2001). Here an all-polymer approach is used. Polymer materials are used for both the waveguide and the substrate. The substrate is chosen to have a positive coefficient of thermal expansion (CTE) and the polymer used for the waveguides is chosen to have a negative thermo-optic (TO) coefficient (dneff /dT ). An athermal (measured between 25 and 65 °C) and polarization independent arrayed waveguide grating (AWG) is demonstrated. The CTE of the substrate is 80 ppm K−1 . The temperature dependent drift of the center wavelength of the device is ±0.05 nm over the entire temperature range between 25 and 65 °C. This approach can readily be adapted for realizing athermal ring resonator devices. 3.7 Polarization Independence Handling polarization has been and is an issue when developing photonic integrated circuits especially for telecommunication systems. A polarization insensitive ring resonator filter is desirable as different polarization states lead to undesired shifts in the filter spectrum of the resonator and degrade the optical performance of the filter. A well-know method for realizing polarization insensitive devices is by using a so called polarization diversity architecture. The idea behind this method is to split the optical input signal into two signals having an orthogonal polarization state, like for example one arm is for TE polarized signals, the other arm is for TM polarized signals. In order to perform integrated polarization handling of the input signals, polarization splitters, and rotators are needed. Polarization converters using sharp bends are demonstrated for example in van Dam et al. (1996). An example of a 3.7 Polarization Independence 115 polarization insensitive heterodyne receiver in InP employing polarization rotator and splitter elements is presented in Kaiser et al. (1996). A theoretical analysis of a filter comprising two identical ring resonators, two identical polarization converters, straight and curved sections which is based on the polarization-dependent architecture is presented in Klunder et al. (2002). The layout of the filter is sketched in Fig. 3.79. The ring resonators are assumed to be ideal polarization splitters which drop the TE polarized light with wavelengths within the pass band completely and the TM polarized light and the remaining TE polarized light not in the passband, pass the ring resonator unaffected. The polarization converters are also assumed to ideally convert from one polarization state into the other without losses. The calculated polarization dependence of the filter for the drop port is 0.7 dB, using a polarization converter with a conversion efficiency of 98%. A tunable ring resonator filter utilizing a Vernier architecture with polarization diversity is presented in Van et al. (2004). Here a polarization beam splitter separates TE and TM polarized light into a waveguide which leads to two third order ring resonator filters with two different FSRs, 575 and 650 GHz. The two waveguide arms are joined using a polarization beam combiner after the light passes the ring resonators. A polarization dependent loss of 0.4 dB and a differential group delay of better than 5 ps are obtained. A similar architecture is realized in Watts et al. (2005) using integrated polarization splitters and rotators and third-order ring resonators with a diameter of 16 μm. Polarization converters with periodical spectral response based on ring resonators are theoretically proposed and discussed in detail in Morichetti and Melloni (2006). Several device layouts of parallel coupled and directly coupled ring resonator configurations are presented. Polarization independent ring resonator filters are also analytically analyzed in Chin et al. (2004). Two approaches are being considered. In the first approach, laterally strong confined single mode waveguides with a large etch depth are analyzed Fig. 3.79 Layout of a polarization independent filter 116 3 Materials, Fabrication and Characterization Methods regarding the effective refractive index for TE and TM polarization depending on the width of the waveguide. The effective indices become equal at the critical width where the mode is circular. Another issue despite achieving a critical polarization independent waveguide width is the critical bending radius below which no etchdepth can meet the differential loss criterion, as losses for the fundamental modes also become to high for achieving an acceptable filter performance. In this case, this radius should not be smaller than 30 μm. The next approach is to realize polarization independent coupling. MMI couplers (see also Sect. 4.1.2) are proposed, which can be designed for polarization insensitive operation. Finally in adding polarization independent waveguides and couplers, polarization insensitive ring resonators can be fabricated. The idea of polarization independent waveguides and couplers is used in Headley et al. (2004) for fabricating a racetrack shaped ring resonator notch filter in SOI. A layout and layer sequence of the waveguide used is shown in Fig. 3.80. A coupling length of 500 μm and a bending radius of 400 μm are used in realizing polarization insensitivity within a shift of the resonance peaks of 2 pm between TE and TM polarized input over a spectral range of four times the FSR of 192 pm. The devices are covered with a passivating surface oxide after etching of the waveguides and the coupler, which helps to protect the waveguides during end facet preparation. The wafers are diced and the end facets are polished and AR coated in order to minimize Fresnel reflections and to reduce Fabry–Perot resonances inside the device. One of the first polarization independent filters using a birefringent fluorinated polyimide overlay (birefringence = 0.11) is presented in Kokubun et al. (2001). Here a vertical coupling scheme is used together with single mode rib waveguides for achieving polarization independent operation. The geometry and layer sequence of the used waveguides is shown in Fig. 3.81. Fig. 3.80 Layer sequence and dimension of used waveguides Fig. 3.81 Layer sequence and waveguide dimensions the refractive indices are given for a wavelength of 1.55 μm 3.7 Polarization Independence 117 All glass layers are deposited by RF sputtering and patterned by RIE. The polyimide cladding layer is spin coated onto the sample. The RIE parameters are: RF power (30 W), gas pressure (0.67 Pa), flow rate of CF4 and O2 (10:3 SCCM). An advantage in using a polymer overlay is that remaining polarization dependence can be eliminated by UV trimming of the polyimide film, due to the fact that the thickness of the film can be reduced by more than 20% by UV irradiation while keeping the refractive index and the birefringence constant (see also Sect. 5.2). Several methods exist for realizing polarization insensitive devices and as can be seen, the chosen method again depends on the material system and the device layout for appropriate polarization compensation. Now that ring resonator theory and device fabrication have been addressed, the focus in the following chapter lies on determining the performance of the devices, therefore possible characterization methods will be explained in Sect. 3.8. 3.8 Characterization Methods The standard characterization of waveguide based devices usually involves fibers for in and out coupling of the device, a light source and a detector. Due to the advance in current fabrication methods, analyzing the performance of ring resonator filters with regard to where the loss occurs is necessary for improving the manufacturing process and thus improving the characteristic of the filter. Besides the standard optical fiber characterization setup, microscope examination, SEM and atomic force microscopy (AFM) measurements, several methods exist to analyze the performance of waveguide based devices such as cut-back (destructive), Fabry–Perot (requires single mode lasers) (Park et al. 1995), prism coupling method (requires a minimum length of the waveguide of several cm), optimum end-fire coupling (OEC) method (Haruna et al. 1992) and many others. The description of some of the mentioned characterization methods will be done in the following paragraphs. The main goal of each method is to determine the losses of the device. In order to compare the loss parameters, a definition for the standard parameters is given in the following paragraph. The insertion loss α insertion of the device is the minimum transmission for a specific wavelength range for all polarization states. It represents the worst possible loss through the device. The insertion loss uniformity of a device is the difference between the insertion loss of the best-case and worst-case channels. The insertion loss α insertion is defined for an input intensity I in and output intensity I out as αinsertion = −10 · log Iout . Iin (3.5) The total insertion losses α insertion includes the intrinsic losses α propagation and the fiber–chip coupling losses α coupling αinsertion = αpropagation + αcoupling (dB cm−1 ). (3.6) 118 3 Materials, Fabrication and Characterization Methods The intrinsic losses can be described by the following equation: αpropagation Iout 1 10 · log =− + αcoupling (dB cm−1 ), L Iin (3.7) where L is the total length of the measured waveguide. 3.8.1 Conventional Characterization One of the standard setups for the measurement of ring resonator devices is shown in Fig. 3.82. Here an external cavity laser (ECL) is used as the light source which is connected via a polarization controller (PLC) and a tapered or lensed fiber to the input waveguide. The transmitted signal is detected using for example the lock-in technique employing a photo diode and a lock-in amplifier. The ECL signal is coupled to the input waveguide by using for example a tapered fiber, which can be adjusted by a three axis piezo drive. Tapered fibers are usually used to couple into strong guiding waveguides and reduce the fiber to chip coupling loss considerably compared to a standard butt fiber due to the reduction of the mode field diameter which suits the high index contrast waveguides better than the large field diameter of the butt fiber. The near field of the output waveguide can then be focused on a photodiode (PD) by using a microscope lens which has a sufficient aperture to guarantee correct power measurement. The device under test (DUT) is placed on a Peltier—cooler/heater so that all measurements are performed at a definite temperature. Instead of using a microscope lens on the output side, a tapered fiber can again be used to couple light from the drop or throughput port which is fed to an optical power meter or an optical spectrum analyzer. This setup can now be used to extract various device parameters including the filter characteristic. The coupling losses can for example be calculated from measuring the Fig. 3.82 Example of a standard optical measurement setup 3.8 Characterization Methods 119 loss of different waveguide lengths of the same device. This internationally recognized reference test method is known as the cut-back technique. The measured insertion loss is plotted against different lengths of the measured devices. The slope of the obtained curve is determined by the propagation losses of the waveguide. The coupling losses are obtained from the point, where the extrapolated measurement curve crosses the Y-axis at a device length of zero (unit length). The cut-back method is a destructive method to obtain the propagation and coupling losses of straight waveguides. A nondestructive method which is commonly used is the Fabry–Perot method. This method has first been introduced in 1978 by Kaminow and Stulz. The chip is regarded as a Fabry–Perot resonator for waveguide losses <1 dB cm−1 , where the facets of the chip serve as the mirrors of the resonator. The optical wave is reflected back and forth within the waveguide. The resulting “filter” spectrum depends on the intrinsic losses and the reflection factor of the facets. The optical length is changed by varying the temperature of the whole chip or the wavelength exploiting the group velocity dispersion. The following calculations closely follow (Regener and Sohler 1985; Feuchter and Thirstrup 1994). The transmission spectrum of a Fabry–Perot resonator is given by IT = I0 η 1− T 2 e−αinsertion L , 2 + 4R sin2 φ R (3.8) 2 The equation for describing the Fabry–Perot resonator is very similar to the one describing a single ring resonator notch filter. Here It is the transmitted intensity, I0 is the intensity of the input laser signal, η is the coupling efficiency to the fundamental waveguide mode, φ = 2βL is the internal phase difference, R is the end-face reflectivity, L the length of the resonator and α insertion the insertion losses of the waveguide. The contrast K of the Fabry–Perot resonances, which is independent of I0 and η, is given by K = Imax − Imin . Imax + Imin (3.9) The transmitted maximum and minimum intensities can be described by Imin = (1 − R)2 · e−αinsertion L (1 + R · e−αinsertion L )2 (3.10) Imax = (1 − R)2 · e−αinsertion L . (1 − R · e−αinsertion L )2 (3.11) From (3.10) and (3.11) K can be rewritten as 120 3 Materials, Fabrication and Characterization Methods K = 2R . 2 1+ R (3.12) This leads to = 1 1 − R R 1 − K2 . (3.13) The value of K is taken from the measurement of the Fabry–Perot resonances. The maximum value of K is obtained for lossless waveguides. Increasing losses on the other hand reduces the contrast. If the end-face reflectivity is known, the insertion loss of the device is given by αinsertion = 4.34 + ln R − ln R L (dB cm−1 ). (3.14) Equation (3.14) can also be written using I min and I max directly √ −1 1+ u 1 ln cm √ + ln R L 1− u Imin u= . Imax αinsertion = (3.15) When the reflection factor of the chip is unknown, it can be calculated from the insertion loss measurements plotted for different device lengths using (3.14) or (3.15). The measurement is approximated by a straight line from which the reflection factor can directly be taken. The slope of the curve is again the value for the intrinsic losses α propagation of the waveguide, which is given by √ 1+ u (dB cm−1 ). 4.34 · ln √ or − 4.34 · ln R 1− u (3.16) Another way of calculating the reflectivity of the end faces, which is valid for weak guiding waveguide structures, is by using: R= n eff − 1 n eff + 1 2 . (3.17) When the reflection factor is known, the intrinsic losses of the chip are easily determined without the necessity to cut the waveguide several times for characterization. 3.8 Characterization Methods 121 3.8.2 Optical Low Coherence Reflectometry In optical low-coherence reflectometry (OLCR), the output of a low-coherence source is coupled into an optical fiber and split in a 3-dB coupler as sketched in Fig. 3.83. It is basically a white light Michelson’s interferometer. Half of the input signal travels to the DUT, while the other half is launched into free space towards a mirror on a scanning translation stage. When the optical path length from the coupler to the mirror equals the optical path length from the coupler to a reflection in the DUT, the signals from the two arms add coherently to produce an interference pattern which is measured in the detector arm of the coupler. When the optical path length difference becomes larger than the coherence length of the source, this interference signal fades and is lost eventually. Therefore the spatial resolution critically depends on the coherence length of the light source. Reflections with a spatial resolution better than 10 μm can be localized. Refractive index discontinuities less than 10−4 (dynamic range of ≈ −80 dB) in the device can be detected. The amplitude of the interference signal is proportional to the magnitude of the reflection from the DUT. Movement of the mirror allows the reflectivity of the DUT to be mapped as a function of distance, which allows the localization of waveguide discontinuities and imperfections. To achieve precise control of the fiber chip coupling and to record the transmission data, the output end of the setup can be coupled to an infrared-sensitive camera and an optical spectrum analyzer (OSA), respectively. This setup is referred to as the reflection mode. The reflection mode setup is used to characterize for example an active–passive butt joint, but can also be used to measure ring resonator devices without AR coated facets. Due to the AR coating of the facets, which is applied to most devices incorporating ring resonator filters, a setup called the transmission mode (Fig. 3.84) is used for the characterization of ring resonator devices. A detailed analysis of ring resonator filters using OLCR is presented in Gottesman et al. (2004). An example of a so called reflectogram of a ring resonator notch filter without AR coating with a codirectional coupler (length = 150 μm, coupling gap = 0.9 μm) and radius r = 100 μm is shown in Fig. 3.85. The first peak is measured at the input facet of the device. The second peak (out1 ) is measured at the output facet. There are no significant reflection peaks in between those peaks coming from the ring resonator, which shows that the input signal has passed the resonator undisturbed. Fig. 3.83 Basic OLCR measurement setup in reflection mode 122 3 Materials, Fabrication and Characterization Methods Fig. 3.84 OLCR measurement setup in transmission mode − − − − Fig. 3.85 Reflectogram of ring resonator with r = 100 μm without AR, measured in reflection mode The peaks in between peak out1 , peak out2 , and peak out3 result from multiple roundtrips in the ring resonator. The distance between the peaks out1–2 is 2 mm which corresponds to the chip length. The distance between two peaks coming from the ring resonator is equal to half of the cavity length which is measured to be ≈466 μm (physical value 464 μm). A reflectogram of a ring resonator notch filter measured in transmission mode is shown in Fig. 3.86. The first peak is the transmission passing the coupler without entering the ring. The second peak is the transmission from one roundtrip in the ring. The third peak is the transmission from two roundtrips and so on. The roundtrip loss is evaluated from the transmission data beginning from the second peak. In this calculation the loss in the straight waveguide is not considered and is contained in the coupling factor and the roundtrip loss. The length between the peaks is equal to half of the optical length of the ring resonator. The average optical length (in the ring) is taken from the 3.8 Characterization Methods 123 − − − − − − Fig. 3.86 Reflectogram of ring resonator with r = 100 μm without AR, measured in transmission mode measurement (e.g., distance between peak 2 and 3) and is equal to 6171.86 μm. The measured ring has a resonator length of 1776.64 μm. The group index is calculated from this data to be ngr = 3.47. This is the average group index which the traveling light wave experiences when it passes the coupling region, the curved sections and the straight section in the resonator. The active–passive transition can also be analyzed using the OLCR measurement. The result for a straight waveguide with a 500 μm long SOA section, measured in reflection mode is shown in Fig. 3.87. - Fig. 3.87 Reflectogram of a straight waveguide with integrated SOA 124 3 Materials, Fabrication and Characterization Methods The facets are not AR coated which is shown in the high reflection peaks at the input and output facets. The return loss from the first butt joint is about −32 dB. The length of the SOA section can also be taken from the OLCR measurement and is proven to be 500 μm. The reflectogram of a single ring resonator with SOA (see inset) is shown in Fig. 3.88. The ring resonator has a radius of r = 200 μm, a coupler length of 150 μm (coupling gap = 1 μm) and a gain length of 100 μm. The return loss resulting from the butt joint is only −50 dB which indicates a lower reflection than from the straight waveguide with SOA. This is due to the bending loss in the ring resonator, where part of the reflected intensity from the butt joint is lost, leading to a lower value for the return loss. There are again no reflection peaks due to imperfections in the resonator or straight waveguide which indicates a high quality cavity. The OLCR method shows only a qualitative indication of the reflection coefficient, because OLCR takes into account the unknown absorption during propagation. A technique to evaluate the coupling efficiencies and reflection coefficients simultaneously at the butt-joint interface is presented in Song et al. (2005). The technique described here is based on the Hakki–Paoli method (Hakki and Paoli 1975), which is widely used to extract the gain spectra of semiconductor lasers and the reflectivity of the AR coating by measuring amplified spontaneous emission (ASE) spectra. In summary, the OLCR measurement method enables an insight study of the quality of the ring cavity and has the potential to efficiently extract all necessary ring parameters to describe the spectral behavior of the ring resonator configuration. - Fig. 3.88 Reflectogram of a ring resonator with integrated SOA 3.8 Characterization Methods 125 3.8.3 Evanescent Field Measurement Methods Near field techniques have become attractive for optical characterization. Probing the near field enables to overcome the diffraction limit of conventional microscopy. Spatial resolutions much smaller than the optical wavelength can be obtained, approaching λ/50. Near-Field Scanning Optical Microscopy Near-field scanning optical microscopy (NSOM) or scanning near-field optical microscopy (SNOM) which is used as an alternative name is another scanning probe microscopy (SPM) related technique. An optic fiber is stretched and thinned such that it has a very sharp point. The fiber is coated with metal such that a small aperture (approximately 25 nm diameter) is formed at the tip of the fiber. This aperture serves to illuminate a small spot on the sample which is much smaller than the conventional diffraction limit. The sample is then scanned beneath the tip and the image is formed in the same fashion that a dot matrix printer prints a picture. The tip is brought very close to the surface. The tip–surface distance can be measured via the force acting between the two. The tip is scanned across the surface as in scanning tunneling microscopy (STM). NSOM (or SNOM), can detect objects below the diffraction limit (down to the nm regime) and thus represents a powerful new technique in optical microscopy. The significance of NSOM is that it allows spatial resolution with more than an order of magnitude improvement over the best conventional optical methods, including laser scanning confocal microscopy. Although optical characterization is the most widespread method to analyze materials from biology to the semiconductor industry, it suffers from one inherent problem: the diffraction limit provides a spatial resolution limit of about half of the wavelength of light. Thus, features smaller than 250 nm can not be imaged or spectrally characterized with visible light. NSOM combines scanning probe microscopy instrumentation with optical microscopy and spectroscopy to provide optical characterization with, in some cases, 15 nm resolution in using visible light. One of the first experiments using NSOM to measure the internal optical modes inside ring resonators with a radius of 25 μm is presented in Vander Rhodes et al. (2000). The ring resonators which are analyzed are described in detail in Chu et al. (1999a) and have also been described in Sect. 3.3.2. The setup used in the NSOM experiment consists of a standard optical measurement setup as described in Sect. 3.8.1 using a lensed fiber for coupling into the ring resonator, an ECL and a photodiode at the output port and in addition the NSOM probe, which is fed into an InGaAs detector to collect the light from the sample. A multimode fiber optic is used at the output facet of the ring resonator chip which enables the simultaneous monitoring of both the through and drop port of the ring resonator when performing the NSOM scans. The NSOM probe is scanned over the surface of the waveguide with a tip–surface separation of 10 nm using an interferometrically calibrated translation stage to scan the tip with an accuracy of ±0.3 nm. Results of NSOM scans of a ring resonator are shown in Fig. 3.89. 126 3 Materials, Fabrication and Characterization Methods Fig. 3.89 Multiple NSOM scans of the ring resonator, stitched together for an image of almost the entire ring on resonance. Entire scan is 58 μm square: a shows the optical modes, clearly showing the light coming into the resonator in the upper right, with about half of that light leaving the resonator at the drop port in the upper left. The launch orientation used here is not especially efficient in coupling to the drop port, which is why very little light is seen at the drop port in the upper right and b is topography, with a height difference of 1.45 μm from black to white Vander Rhodes et al. (2000) Photon Scanning Tunneling Microscope Photon Scanning Tunneling Microscope (PSTM) is another configuration of a scanning near field system described before. A PSTM is a device where the object is illuminated by an evanescent wave generated at the face of a prism or slide and the field is detected via a fiber probe in the near-zone of the sample (as in NSOM). PSTM measurements are inherently holographic since the sample is illuminated by an evanescent field and that same field serves as reference. The PSTM tips are obtained in a similar way as NSOM probes, by pulling an optical fiber, coating it with about 7 nm of Cr, which results in no aperture at its very extremity. The PSTM tip scans at constant height. In this mode of operation, the signal detected by a PSTM is related to the spatial distribution of the intensity of the optical electric field in the near-field zone. Ring resonators have been analyzed using photon scanning tunneling microscopy in Quidant et al. (2004). A photograph of a fabricated ring resonator is shown in Fig. 3.90. The used ring resonators are made of a 150 nm thick TiO2 layer (residual roughness of 3 nm) coated on a glass substrate with a residual roughness of 1 nm by ion assisted deposition. The waveguides are fabricated using RIE. The dimensions of the ring resonators are 6 μm in diameter, 250 nm wide and 150 nm high. In this PSTM experiment, an He–Ne laser (633 nm) injected in a lensed single mode fiber is used to illuminate the ring resonator. The end of the fiber is oriented in such a way that the beam can be focused at the interface between the dielectric 3.8 Characterization Methods 127 Fig. 3.90 Scanning electron microscopy picture of a TiO2 ring coupled with a linear waveguide ridge. Photograph courtesy of Dr. Romain Quidant [ICFO—Institut de Ciències Fotòniques, Parc Mediterrani de la Tecnologia, Av. del Canal Olímpic s/n, 08860 Castelldefels, (Barcelona), Spain] ridge and the glass substrate. Only TM polarized incident light is being considered. The Gaussian beam is focused at the right end of the straight bus waveguide in such a way that the components of the incident wave vector parallel to the surface of the substrate align along the longitudinal axis of the bus waveguide. The tip is scanned at a constant height above the sample surface while monitoring the light intensity level. A photograph of the resulting image is shown in Fig. 3.91. Several state-of-the-art characterization techniques have been described. Due to the decreasing dimensions of ring and disk resonator devices and the increase in integration density, a combination of several characterization methods is inevitable in the future to guarantee optimum device performance. 3.9 Lithium Niobate and Hybrid Solutions Lithium Niobate (LN) is a key material in photonic industries because of its peculiar combination of functional properties and its commercial availability. Although discovered in the sixties, in the nineties it made its successful in optical communications due to the pushing demand of greater bandwidth as well as the ability to route signals without complicated electronic interfaces (Lawrence 1993; Wooten et al. 2000; Wang et al. 2018a, b). As a matter of fact, lithium niobate is an insulator material benefitting from excellent properties such as high optical transparency in a wide spectral range (0.33–4.6 μm), high refractive index and birefringence (no ≈ 2.28, ne ≈ 2.20 at 0.63 μm), high electro-optic coefficients (r 33 ≈ 30.8 × 10−12 3 Materials, Fabrication and Characterization Methods Intensity (arb. units) 0 −4 −2 0.2 0 x (µm) 0.4 2 4 0.6 128 −4 −2 0 y (µm) 2 4 Fig. 3.91 PSTM image recorded above the microring. The probe tip scans in plane parallel to the sample located at 50 nm from the TiO2 structures. Photograph courtesy of Dr. Romain Quidant m/V at λ = 0.63 μm) and piezoelectric ones, chemical resistance and even biocompatibility. It is commercially available up to 4 inches wafers, commonly in X, Y, Z cut configurations, i.e. where the optical axis is parallel to the Z direction and it is normal to the Z-cut surface. The material is grown by the Czochralski technique at a very high optical quality. Furthermore, lithium niobate has a high second order optical nonlinearity (d33 ≈ −33 pm/V at λ = 1.064 μm) enabling parametric wavelength conversion and optical signal generation. It is not by chance that Periodically Poled LN crystals are commercially available for Second harmonic generation units. Its properties can be tailored by suitable doping, either locally or in the bulk (Bazzan and Sada 2015), to increase its resistance to the optical damage or its photorefractivity, to host active ions or to produce optical waveguides as well. These features allowed to integrate in this material complex integrated optics circuits including fiber pigtailed light sources, beam splitters, optical modulation systems, polarizers and polarizer combiners if needed, signal detection such as a photodiode or laser-fibre detector system, dependently on the application. Although widely investigated since the last twenty years, LiNbO3 has still continued to attract great attention in developing optical components for Integrated Optics (IO) systems and in the last ten years great advances have been made in realizing LN based microring resonators. Several different commercially available waveguiding configurations have been realized combining local doping on pure LN crystal and bulk doped ones (such as Mg-doped LN crystals). Others are promised to become mature in a short time but are still not commercially available. Local doping by thermal diffusion and proton exchange are those optimized in LN-based IO devices thanks to their 3.9 Lithium Niobate and Hybrid Solutions 129 scalability and batch processing compatibility. Recently, the combination of several techniques has paved the way of great improvements in the waveguiding properties especially for what concerns the optical confinement and mode overlap. In particular ion implantation combined with etching techniques and local doping, have been used to get complex but extremely performant devices even in LN thin film bonded with low refractive index materials. These opportunities have been widely exploited to get micro-ring resonators with high tunability provided by its high electro-optic response. In this case local doping was used to realize the optical waveguides whilst ion implantation was exploited to allow to get thin film as it will be described in the following sections. Lithium Niobate Waveguides: Ti-Indiffusion Ti in-diffusion is one of the most widespread technology to prepare optical waveguides in LN crystals. Thin Ti film are deposited on the material surface and then thermally annealed under controlled atmosphere. It is compatible with standard photolithographic techniques to obtain channel waveguides and more complicated optical circuit configurations such as optical switches, Mach–Zehnder interferometers and optical modulators (Janner et al. 2009), couplers with high coupling efficiencies and large bandwidth around 1.55 μm (Bazzan and Sada 2015). The technology is so mature that LN-based modulators are commercially available and cover a big slice of the current market. Ti-indiffused waveguides present significant light confinement on both ordinary and extraordinary refractive indices, allowing both TE and TM propagation modes and preserving to a good extent the electro-optical properties of the material. For a conventional Ti:LN waveguide, which is usually fabricated by diffusion of 6–10-μm wide, ~100 nm-thick Ti-strip at 1030–1060 °C for 9 h, the surface Ti4+ concentration is around 1021 ions/cm3 and no (ne ) is ~0.006 (0.012) at the 1.55 μm wavelength, respectively. A sketch of the Channel waveguide process is reported in Fig. 3.92. Depending on the Ti content, no lies in the range 0.003–0.01 for Y cut and 0.001–0.01 in Z-cut crystals, whilst ne lies in the range 0.002–0.04 for Y cut and 0.002–0.02 for Z-cut. Its drawback relies mainly on the optical damage induced by waveguiding high power densities, crosstalk in switches and drift in interferometers, especially in visible range (that starts to be a limiting factor even below 1 μW at 0.633 μm). For this reason, Ti-in diffusion has been widely exploited in the NIR region (wavelengths longer than 1 μm, with optimization in the telecom spectral range). Recent works on the topics, however, have been more focused on the study of co-diffusion with other dopants to remove or, at least, smooth the optical damage. Since the Eighties, Ti diffusion in MgO-doped lithium niobate has been widely investigated, and co-doping with at least 4.9 mol.% of MgO turned to be effective in suppressing the optical damage effect. Other dopants that have similar effect are Zn2+ , Sc3+ , In3+ and Tm3+ , Hf4+ , Zr4+ , and Sn4+ but have not been successful from a commercial point of view. The need to further optimize the growth process led their use limited to research, being to much expensive so far. Despite of these limitations, Ti:Zr co-diffused waveguides have demonstrated to support both TE and TM in single-mode at the 1.5 μm wavelength with losses ≤1.3/1.5 dB/cm for the 130 3 Materials, Fabrication and Characterization Methods Fig. 3.92 a Scheme of the Ti Channel waveguide realization process; b Ti compositional in-depth profile; example of Near field Optical mode detected from a 6 μm wide and 2 μm thick channel waveguide TE/TM mode, respectively (Zhang et al. 2015). The refractive index at 1.553 μm was measured to be close the Ti:LN doped sample, i.e. the presence of Zr slightly affects it with a contribute close to 10−4 for both no and ne . Lithium Niobate Waveguides: Proton Exchange As an alternative to Ti in-diffusion, the Ion Exchange technique has been widely used and in particular the Proton Exchange (PE). PE consists in the immersion of a lithium niobate specimen into a liquid source of hydrogen at high temperature. Under these conditions, the replacement of Lithium ions (Li+ ) by hydrogen ions, or protons (H+ ), causes an increase in the extraordinary refractive index (ne close to 0.1) and, normally, a reduction in the nonlinear coefficients. The waveguide, therefore, supports modes only on the extraordinary polarization. For this reason, proton exchange has been preferred for every application where propagation is in the visible spectrum. The most common sources of H+ are the benzoic acid and the toluic acid, heated at temperatures ranging from 150 to 400 °C (Korkishko and Fedorov 1999). PE is often followed by annealing in a controlled atmosphere, leading to the so-called Annealed Proton Exchange (APE) to increase the high polarization rejection and promote a better resistance to the optical damage as well as to recover the nonlinear coefficients. For nonlinear optical applications, Soft Proton Exchange (SPE) and Reverse Proton Exchange waveguides are used when the refractive index jump ne can lay between 0.01 and 0.03 and better optical confinement is requested (Korkishko and Fedorov 1999). Vapor-phase Proton Exchange (VPE) was also investigated to combine a strong confinement (ne = 0.09) and preserved nonlinearities, but difficulties in controlling the fabrication conditions limited its industrial application 3.9 Lithium Niobate and Hybrid Solutions 131 (Tsou et al. 2002). As an alternative, High Vacuum Proton Exchange (HiVacPE) has been recently proposed (Rambu et al. 2018): it consists in vacuuming the exchange ampoule to decrease the water content of the acidic bath to the greatest extent. In this case, a refractive index contrast in X-cut crystals as high as 0.04 was demonstrated with low propagation losses close to 0.16 dB/cm and preserved optical nonlinearity. Different devices already realized in the years 1990–2005, such as modulators, switches, multiplexers and de-multiplexers (Castaldini et al. 2007; Wang et al. 2007), Y branches and micro-ring resonators as well (Korkishko and Fedorov 1999). High quality channel waveguides with propagation losses as low as 0.086 dB/cm and a coupling efficiency to optical fibers of 90 per cent at 1.550 μm: the splitting ratio of a set of directional couplers could be predicted with an accuracy of ±0.06. The combination of PE with other technique was explored to get new configurations as well: PE LiNbO3 crystals were subjected to 70-meV argon-ion irradiation as well as performed on photorefractive—resistant substrates such as MgO:LiNbO3, and even combined with Ti indiffusion, in periodically poled structures and even in Zr:LiNbO3 bulk doped substrate (Langrock et al. 2016). Lithium Niobate Waveguides: Ion Implantation Ion implantation is another widespread technology exploited to realize optical waveguides in LN crystals. It consists in bombarding a surface with ions at an impact energy Eo so that they implant within the material after releasing their energy. In this process, the energy of the bombarding ion beam is transferred to the crystal lattice by way of two main processes dependent on the ions’ velocity: energy loss due to electronic excitations and nuclear collision losses. Nuclear collisions induce displacement damage, resulting in the formation of point and/or extended defects responsible for the refractive index change. Moreover, both the electronic and nuclear processes tend to create colour centres (optical absorption sites). Consequently, an annealing treatment is commonly necessary for all the ion-implanted waveguides in crystals in order to recover the optical properties of the material. When combined with photolithographic patterning of the surface, this procedure allows for selective implantation in 2D structures: high resolved patterns can be achieved by focusing the ion beam down to about 100 nm (Focused Ion Beam, FIB), as already demonstrated also in LiNbO3 . The first works were published on the Ar+ and Ne+ in the seventies (Naden and Weiss 1984), although He+ -implantation in LiNbO3 at high fluences (1016 ions/cm2 ) has reported the greater success promoting a ordinary refractive index with a typical barrier-type profile, whilst the extraordinary refractive index showed more complex changes. Following the implantation of other ions at low fluences, such as B, C, O, F, Si, and P, ne was found to be sufficient to realize high quality guided regions (a review on recent results is in Bazzan and Sada 2015), with good confinement and low losses, around 1 dB/cm. Ion implantation of Si was exploited as well, realizing monomode optical waveguides and indicating the potential generality of the method. Waveguides in co-doped Nd (0.3 At.%):MgO (5 mol.%) X-cut LiNbO3 crystals were also obtained using O ions as well with irradiation in the regime of high electronic stopping power (~5–6 keV/nm) and ultra-low fluence (2 × 1012 cm−2 ), because of the short irradiation time required. Recently, the 132 3 Materials, Fabrication and Characterization Methods use of swift heavy ion (Ar) irradiation to modify refractive indices of optical materials was reported for fabrication of single and multimode waveguides at 1.064 μm (Chen et al. 2017). Surface and cladding-like optical waveguides with thicknesses of ~13, ~36 and ~23 μm at Ar implantation energies of ~120, ~240, and ~(120 + 240) MeV, respectively have been reported. The modal confinement and the optical losses were measured together with the second harmonic generation (SHG) at 532 nm with an efficiency close to 6% at room temperature. In the case of H+ implantation, the values of the electro-optic coefficients (r13 and r33 ) were well preserved in the waveguides, independently of the implanted-proton fluence in the investigated range (1–10 × 1016 ions/cm2 ). Even the non-linear d33 coefficients had almost the same value of virgin LiNbO3 . Olivares et al. studied the SHG of 20 and 22 meV F-implanted LiNbO3 waveguides, and high SHG coefficients were obtained (50–80% of a bulk LiNbO3 ). Recent advances were reported on Zr:doped LiNbO3 crystals (2 and 4 mol.% of ZrO2 ), where planar and channel waveguides were fabricated in Z-cut wafers by the double-energy proton beam implantation at 470 keV (at the fluence of 1 × 1016 ions/cm2 ) and 500 keV (at the fluence of 2 × 1016 ions/cm2 ). The propagation losses of the channel waveguide were measured close to 3.6 dB/cm. The proton implanted waveguides in Zr:LiNbO3 crystals showed a relatively high optical damage threshold at the wavelength of 532 nm, which was one order of magnitude higher than that of the previously reported ion implanted waveguides in undoped LiNbO3 . It was also found that the optical damage threshold (9.0 × 104 W/cm2 ) of Zr:LiNbO3 channel waveguides was much higher than that of the corresponding planar waveguide (2.0 × 103 W/cm2 ). These promising results of ion implantation have not been enough to let this technology replace Ti-indiffusion, mainly because of the bulky and expensive equipment required when implantation energies higher than 500 keV are needed. However, it has become attractive for other applications requiring impact energy lower that about 200 keV such as the needed for LN micro-structuring approaches such as smart cutting. As it will be detailed in the following sections, in fact, the nuclear damaged region become amorphous with different mechanical resistance respect the surrounded unaltered material. The damaged region can be tailored to become “cleavage plane”, i.e. the starting point where to exfoliate thin LN film. On the detached LN film high refractive index contrast stacks can be produced as building blocks of micro-ring resonators devices. Lithium Niobate Waveguides: Ridge Waveguide In combination to the previously quoted technologies, high lateral optical confinement respect to the previously reported cases can be achieved by using the so-called ridge waveguide configuration. This is a key aspect in the design of micro-ring resonator where high index contrast must be achieved. Different alternative technologies have been used to design ridge waveguides such as reactive ion etching (RIE), ion beametching with inert and reactive ions (IBE, RIBE), sputtering with focused ion beam (FIB) as well as wet chemical etching, ion exchange and ion irradiation (IBEE: ion beam enhanced etching) respectively. The most widespread is surely chemical etching, either wet or dry, or by plasma activated processes starting from 3.9 Lithium Niobate and Hybrid Solutions 133 a previously fabricated planar waveguide by conventional processes as those previously described. Most often, a mixture of HF and HNO3 is used on the Ti:LiNbO3 and LiNbO3 patterned surface by way of chromium (Cr) stripes. Low-loss monomode ridge guides with a height of up to 8–10 μm and a width between 4.5 and 7.0 μm were demonstrated by etching Ti-planar waveguides, with propagation losses close to 0.3 dB/cm for transverse-electric and 0.9 dB/cm for transverse-magnetic polarization, respectively, at 1.55 μm wavelength (Hu et al. 2007). Ridge waveguides demonstrated to have reduced bending losses for small curvature radii, thus improving the level of integration, and also to reduce the modal sizes, enhancing the efficiency of non-linear devices, or lowering the threshold in integrated lasers (Brüske et al. 2017). Since imperfections at the edges could strongly affect the propagation losses, the quality of the ridging process is determinant. However, the propagation losses were significantly decreased to 0.05 dB/cm by exploiting the proper etching protocol respect to the Ti-in-diffusion step. New advances in the state of the art were recently proven by the development of high precision machining: by employing a diamond blade (optical grade dicing) (Courjal et al. 2011) high aspect ratio ridge waveguides were demonstrated, with depth greater than 10 μm (Courjal et al. 2016; Caspar et al. 2018), and used to successfully realize electro-optic modulators. An example of achievable results by commercially available Diamond blade-slicing technique in lithium niobate is reported in Fig. 3.93 with optically polished array of ridges with micron-scale. It is worth mentioning that an optimized process for fabrication of Ti:LiNbO3 ridge waveguides with propagation losses lower than 0.2 dB/cm was demonstrated, exploiting waveguide sidewall smoothening during high temperature Ti diffusion (Gerthoffer et al. 2014). The turning point in the developing of microring and integrated optics devices has come from patterning of sub-micrometer wide waveguides and coupling gaps by way of electron-beam- and laser-lithography as well as electron-beam written mask for standard UV photolithography. These advanced technologies have reached a mature level and affordable costs to widespread their use not only in research labs but also at in industries environment. In general electron-beam lithography systems have higher resolution than laser writers one. However, the last are more exploited for fast prototyping of integrated optical devices. Electron-beam written masks to define high precision photoresist stripes with 1–7 μm width and a thickness close to 1.7 μm have been optimized as etch masks by the Group of University of Paderborn). Inductively coupled plasma (ICP) etching with Ar-ions has been implemented to pattern suitable design upon demand. Typical examples of structures that can be achieved are shown in Fig. 3.94: 500–700 nm LN layers are bonded on 0.7–1.5 μm thick SiO2 layer on a Z-cut LiNbO3 substrate with final rms surface roughness of about 0.5 nm. This technology represents the core business to develop high resolved and precise Lithium on Insulator (LNOI) patterned microstructures, the building block of microring resonator and new concept ridge waveguides. A step forward in the accuracy and precision have been also achieved by IBEE thanks to its high selectivity, independence from the crystal symmetry and short production times. In this case multiple implantation with different energies and 134 3 Materials, Fabrication and Characterization Methods Fig. 3.93 Top: SEM views of the ridge structures obtained by diamond blade slicing. a Trenches with a depth of 526 μm. Rights: inserts show zoom views of the thinnest ridge of the serie. b Different depths can be achieved on the same sample. Bottom: Ridge-based EO device. a Electro-optical ridge buffer layer with electrodes and spot-size-converters. b SEM image of an EO ridge with vertical buffer layer and electrodes (Courjal et al. 2016) Fig. 3.94 Schematic diagram of the cross-section of a LNOI sample (left) used to fabricate photonic wires by Ar-milling (Hu et al. 2009) fluences can be used to obtain deep structures with smooth bottoms and vertical walls (Hartung et al. 2008). For lateral patterning, chromium layer with a thickness around 500 nm and a photoresist layer of 1000 nm standard photoresist were deposited onto the substrate by means of sputtering and spin coating, respectively. Using a mask aligner and an electron-beam-written mask, waveguide structures with different widths could be realized by means of photolithography. Chromium was 3.9 Lithium Niobate and Hybrid Solutions 135 easily etched by standard RIE using a chlorine–oxygen plasma so that IBEE process can be carried out and be affective of unpatterned regions. Commonly Ar+ ions are irradiated a different multiple energies (i.e. 60, 150, 350, and 600 keV at suitable ion fluences) to generate an amorphous layer within the noncovered regions starting at the surface down to a depth of approximately 450 nm. Amorphous lithium niobate was then removed by wet etching for 10 min in a 3.7% solution of hydrofluoric acid at an etching temperature of 40 °C. At this process the ratio of the etching rates of amorphous and crystalline lithium niobate has been reported to be beyond 1000:1 and the chromium mask was not affected by the etching process. The standardization of this procedure allowed the definition of sharp and accurate structures as those needed in the microring resonators, with a technology that is commercially available and largely exploited at industrial level. In order to get a faster process, compact laser lithography systems have been tested and let be commercially available. In this case a continuous-wave, frequency stabilized diode laser (the most common is operating at with 375 nm wavelength) has been shaped and focused by acousto-optic deflectors to provide a two-dimensional scanning system. The focused laser beam is shaped at the right spot size on the sample that can be moved and positioned in a controlled way by three XYZ motorized linear stages a sample (Koechlin et al. 2009). Channel guides with dimensions in the range of sub-micrometer widths and heights respectively have been optimized with optical polishing to enable efficient end-fire coupling of light. Recently, even fs-laser writing technique has been used to define ridge waveguide lasers in z-cut Nd-doped LiNbO3 substrates as well as Y-branch waveguiding structures (1 × 2 beam splitters) which reach splitting ratios of ~1:1 at 4 μm in LiNbO3 (Li 2017). Laser ablation was also combined to get ridged waveguide in ion implanted planar waveguides (Yao et al. 2018) for efficient beam splitters configurations. High confinement ridge waveguides have been then achieved using smart-cut slab waveguides and lateral ion milling techniques with a lithographically defined mask. The thickness of the smart-cut waveguide is normally in the range 0.6–0.75 μm, and the lateral width was reduced down to 1 μm, with mode field area close to 0.3–0.4 μm2 at 1.55 μm wavelength, i.e. about one order of magnitude smaller than conventional Ti-diffused waveguides. The optical losses were reported to be lower than 10 dB/cm for both polarizations. This is of great interest for non-linear optical application, as it allows obtaining high power densities even at low input powers. It was already reported that channel waveguides embedded in BCB (n = 1.55) and SiO2 (n = 1.45) can be narrower than 1 μm in order to achieve single-mode waveguiding at λ = 1.55 μm. Lithium Niobate Thin Film and Waveguides: Smart Cut In microring resonators the need of high refractive contrast between the ring and the environment is a key parameter and, consequently, several attempts have been made to integrate LiNbO3 films onto lower refractive index structures. Different 136 3 Materials, Fabrication and Characterization Methods techniques started to be investigated and optimized, including deposition of ferroelectric thin films by molecular beam epitaxy (Betts and Pitt 1985), radio frequency sputtering (Lansiaux et al. 2001), sol–gel (Yoon and Kim 1996) and chemical-vapor deposition (Sakashita and Segawa 1995; Saulys et al. 2000) respectively. Despite the promising results and the clear advantage of having integrated built-in stack configurations, no disruptive advances were reported in the last decade in terms of process reproducibility. The main limiting factors come from difficulties in achieving high crystalline quality, the cost and long time of deposition, the level of contaminants or the final surface quality. It is in this scenario that the so called smart-cut technology has made its debut. It consists of detaching a thin high quality single crystalline Lithium niobate slice from the surface of a LN wafer. This thin LN film can be used as standing alone or bonded on the top of another lower refractive index insulator substrates i.e. “lithium niobate on insulator” (LNOI) structures. They present high refractive index, which can be as high as n ~ 0.7 thanks to the LiNbO3 /dielectric interface (Boes et al. 2018). Called ‘smart cut’ as heritage of the industrial silicon-oninsulator (SOI) wafer fabrication, films produced by this technique preserve basically the same crystalline properties of the starting material and its high refractive index. In the bonded configuration, the thin LN layer is sandwiched among lower refractive index materials to achieve the desired high refractive index contrast stack and provide for the needed optical barrier. Slab waveguides with superior optical and structural properties can be therefore achieved with respect to other bottom-up approaches, such as epitaxial growth, chemical vapor deposition, pulsed laser deposition, sol– gel, and so on. In order to detach the thin LN slice the best approach is Crystal Ion Slicing (CIS) technique exploiting the ion implantation as proposed at the end of the 90s by the Osgood’s group. Normally light ions have been exploited such as H and He, the last being preferred due to its inert activity in the material. In the implanted layer, He forms so called blisters, i.e. gaseous bubbles (Poberaj et al. 2009, 2012). At this stage LN thin film can be either exfoliated or lifted-off either by wet-etching or thermal treatment. Depending on the technique, different bonding approaches have been used. In the pioneering work of Osgood’s group, Z-cut single crystal LN wafer was implanted with a 3.8 meV He ions with a fluence of 5 × 1016 at/cm2 . At this condition, a buried amorphous layer was generated at 10 μm below the surface, dissolved by wet etching with diluted hydrofluoridic acid. It is well known that LiNbO3 has excellent resistance to chemical attack. As a consequence, the buried amorphous later could be etched in several hours without impacting on the undamaged LiNbO3 surface quality. With this technique a free-standing LN single crystal membrane could be obtained with a thickness equal to the implantation range. The eventual residual damage induced by the ion implantation process can be easily removed by a thermal annealing process so that to recover the pure single crystal LN linear and nonlinear optical properties of the starting wafer (Levy et al. 1998; Radojevic et al. 1999). The chemical etching procedures have reached a mature optimization, with etching selectivity as high as 10,000 (Radojevic et al. 1999) Despite of these results, wet-etching is suitable for films of several micrometer thick, with thickness that can vary from the center towards the edges, where the exposure to HF was longer (Levy and Radojevic 2004). 3.9 Lithium Niobate and Hybrid Solutions 137 As an alternative, uniform sub-micrometer thin LiNbO3 films have been obtained by the so called thermally induced exfoliation. In this case a thermal treatment at temperature of the order of 200 °C, is performed to promote the growth of microcavities in the damaged layer. When micro-cracks form, the implanted layer is detached from the substrate that can be achieved in a controlled way by split-off or exfoliation (Poberaj et al. 2009). In this way a LN membrane could be realized with desired thickness tailored by varying the ion implanted energy. By tuning the implantation conditions improvements have been achieved since the nineties to arrive to produce 500 nm thick LN single crystal slices that are now commercially available. With hundred of KeV light implanted ions, in fact, LN smart cut slices with thicknesses below 1 μm can be obtained. In order to prepare high refractive index contrast stacks, the smart cut technology has been combined with wafer bonding. The bonding consists of pressing one against the other two carefully cleaned and polished surfaces promote chemical bonding by heating. Bonding is surely one of the most critical steps in fabrication of large-area thin films. Depending on the materials bonded to LN, the heating temperature can span from 100 up to 250 °C and the treatment can require up several hours. A sketch of the process step is presented in Fig. 3.95. A LN single crystal substrate (LN-A) is ion-implanted to achieve a damaged region below the surface. Another substrate (LN-B) is deposited with a lower refractive index (in the figure, SiO2 with refractive index close to 1.45 in the visible range). The two substrates, adequately cleaned and polished, are therefore bonded by thermally assisted mechanical pressure. By performing a suitable thermal treatment to recover Fig. 3.95 Smart-cut technology (Bazzan 2015) 138 3 Materials, Fabrication and Characterization Methods eventual residual damage followed by chemical etching, the cut in two pieces is achieved at the level of implanted region. A part of the wafer A is therefore sacrificed whilst the rest is used to produce the high refractive index contrast stack. Moreover, SiO2 , Si, SiC and polymers have been already demonstrated to be efficiently bonded to lithium niobate and the relative process optimized. More sophisticated configurations have been tested such as embedding a metallic interlayer playing the role of electrode between SiO2 and LN interface. This has represented a significant improvement allowing the exploitation of the electro-optic properties of the material even in an embedded LN thin film (Rabiei et al. 2013). The geometry of the stack has been widely investigated in order to prevent residual strain induced by thermal mismatch. This configuration requires SiO2 layers of the thickness of about 1 μm. Examples of LN smart cut slices of less than 1 μm are presented in (Sulser et al. 2009; Geiss et al. 2010). Among the polymers, excellent results have been achieved by implement the crystal ion slicing technique in LiNbO3 bonded with benzocyclobutene (BCB). The BCB binding technique has been described in Sect. 3.1.3 and only applications to LiNbO3 will be provided in this context. The use of polymer adhesive relaxes the requirements for flatness, roughness, and cleanliness of the bonded surfaces. Moreover, LN substrate can also be coated with a thin metal layer before the bonding procedure take place, providing electrodes integration suitable for electro-optically active devices. Often 50 nm Cr is used as adaptive interlayers to optimize the Au overlayer adhesion. First applied to LiNbO3 at ETH Zurich by Guarino et al. (2007), BCB has excellent properties such as high transparency in the visible and infrared region and low refractive index (n ~ 1.55). Best results have been achieved by implanting a fluence of 4.5 × 1016 /cm2 He+ ions at 195 keV to provide an implanted project range close to 670 nm (Guarino et al. 2007; Poberaj et al. 2009). The implanted wafer, cleaned with RCA 1 standard solutions, has been bonded to a 2-μm BCB layer coated LiNbO3 substrate. Afterwards the sample has been gradually heated up to 220 °C to strengthen the bonding and to enable the sacrificial layer to split off the thin film from the donor wafer. The transferred film has been then annealed at a temperature of 300 °C for several hours to recover any residual defects induced by implantation. Finally, the surface of the thin film could be smoothened by Ar+ ion etching or mechanical polishing depending on the finitude requirements. This procedure has resulted in a 600-nm thick LiNbO3 film with an area of >1 cm2 , a surface roughness of 4 nm (rms), and a high index contrast of n = 0.65. Alternatively, mechanical polishing can be applied to reduce the surface roughness below 1 nm rms. The described procedure enables the fabrication of both X- and Z-cut LiNbO3 thin films, which are needed for different integrated optics devices (Sulser et al. 2009). A scheme of the fabrication steps is reported in Fig. 3.96. Sophisticated structured have been demonstrated with polished edge: 200-nm thick LiNbO3 film with a 600-nm high ridge waveguide for end-fire light coupling (see Fig. 3.97) (Poberaj et al. 2009). They have been exploited as a platform for the first realization of electro-optically tunable microring resonators as well as singlecrystalline LiNbO3 photonic crystal slabs as will be presented in ten following sections. 3.9 Lithium Niobate and Hybrid Solutions 139 Fig. 3.96 Schematic of the LiNbO3 thin film fabrication method. Left: an implanted He+ substrate of LiNbO3 donor wafer is bonded to another LiNbO3 substrate already deposited with Cr and BCB layers respectively. Right: a slow-ramp thermal treatment promotes a strong bonding, LN film split-off, and annealing Fig. 3.97 a Photograph of an ion-sliced LN thin film (12 mm × 10 mm × 600 nm) bonded on a Cr-coated LN substrate. b Polished edge of a LN thin film with a structured ridge waveguide for end-fire light coupling (Poberaj et al. 2009) For completeness, it is worth mentioning that lithium niobate suspended structures can be achieved as well by combining ion implantation–induced amorphization with the etching by other microfabrication techniques such as Focused Ion Beam (FIB) milling. This exfoliation technique has been used to get LiNbO3 membranes with thickness lower than 1 μm. Apart from being a technology to realize optical waveguide. it has been recently demonstrated as valid alternative to achieve microring resonators as will be briefly presented in the following section. The typical scheme representing how FIB milling can be used to achieve suspended structures is reported in Fig. 3.98. Fig. 3.98 Fabrication of a suspended waveguide (Bazzan and Sada 2015) 140 3 Materials, Fabrication and Characterization Methods 3.9.1 Ring Resonators Based on Lithium Niobate The development of high performant photolithographic and etching techniques optimized in lithium niobate allowed the realization of complex configurations required in ultra-efficient integrated photonics circuits, in quantum photonics and optical communications respectively such as those micro-rings and racetrack resonators. In general, the possibility to shift the microring resonator resonances by applying an external perturbation is of high interest. This is especially true when searching for WDM dynamic filtering, intensity modulation switching and resonance tuning of a to the optical signal in second-harmonic generation. In lithium niobate it can be achieved by exploiting its high electro-optic effect to get a fine tuning in the resonance conditions. Two main approaches have been used in lithium niobate to prepare efficient microring resonators: • a monolithic approach that requires the direct microstructuring of LN to achieve high optical confinement in the active region. This type of process has been normally carried out by etching and have been optimized to reduce the propagation loss; • hybrid configurations integrating an easy-to-etch material (such as silicon or silicon nitride) with LN thin films to guide light with a relatively low propagation loss (0.3 dB/cm). In the following the most important achievements will be revised, with special care devoted to those peculiarities that characterize LN crystals respect other material and justify why LN based microring resonators needs to be developed, such as the electro-optic tuning of resonance. Electro-Optic Tuning of the Resonance Conditions in LN In electro-optically active microring resonators, the application of an applied electricfield δE changes the effective index of the guided core mode. In this case it is worth mentioning that the microring resonator’s sensitivity and its electro-optic tunability do not depend on the size of the ring. As a consequence the constraints on the radius ring can be relaxed. In the case of lithium niobate crystal, however, one should take into account the birefringent nature of the material. By applying δE parallel to the Z axis, the ordinary no and extraordinary refractive index ne of the microring resonator can be achieved by way of both r13 and r33 electrooptic coefficients. For small δE it results that the effective refractive index neff varies according to: ∂n eff r33 n 3e ∂n eff r13 n 3o + δE n eff ≈ − ∂n o 2 ∂n e 2 (3.18) Since TE mode is sensitive to the ordinary refractive index only, while the TM mode is sensitive to both, an acccurate design of the optical waveguides and microring resonators is needed to achieve the desired performance. In particular, it is necessary to estimate the applied electric field at the LN stage (δE LN ). It consequently requires 3.9 Lithium Niobate and Hybrid Solutions 141 at least simulations depending on the geometry starting from the external applied voltage δV using the continuity of the vertical component of the electric displacement field D. To simplify the description and standardize the way of setting the operational parameters, an effective thickness d eff is often introduced so that δE LN = δV /d eff . The shift of the resonance wavelength, due to the induced in modification of the effective index, therefore results in: δλ = − λ ∂n eff r13 n 3o λ ∂n eff r13 n 3o ∂n eff r33 n 3e ∂n eff r33 n 3e δV + δ E LN = − + n g ∂n o 2 ∂n e 2 n g ∂n o 2 ∂n e 2 deff (3.19) where ng is the group refractive index. while the tunability T defined as frequency shift per voltage δν/δV is consequently estimated. Ring Resonators in LN by Proton Exchange One of first examples of ring resonators in lithium niobate was presented in 1985 (Mahapatra and Robinson 1985) by exploiting proton-exchanged in Z-cut Lithium niobate crystals. Thanks to the high refractive index obtained by this doping technique, a ring resonator with a finesse close to 6 at a wavelength of about 790 nm was reported and as high as 22 at 1.3 μm was achieved with a Rung radius of 1500 μm operating only along the extraordinary polarization state. In order to achieve this result, an e-beam was exploited to pattern the suitable on a Cr thin film deposited on the surface. The patterned sample was then immersed in benzoic acid carried out at 249 °C for 30 min. A scheme of the ring resonator is reported in Fig. 3.99: at that time this result was pioneering especially for the realization of resolved bended Fig. 3.99 A scheme of the ring resonator obtained by proton exchange in LiNbO3 142 3 Materials, Fabrication and Characterization Methods Fig. 3.100 Device structure of a wavelength-tunable microring resonator on LN. Left: scheme of the index distribution of Ti-diffused ridge waveguide; Right: scheme of the device microstructures. Relative high losses were deriving mainly by the significant roughness of the optical circuit, limited by the spit size of the e-beam (close to 0.25 μm, relatively high respect the waveguide width close to 2 μm). Recently, advances on this topic have been reported by exploiting the annealed proton exchange (APE) method on LN crystals. By making use of Cr film as electrodes, a tunability of 2 pm/V has been obtained by applying 150 V, getting a measured extinction ratio is approximately 13 dB (Siew Shawn et al. 2016). Microring Resonators on Ti-Indiffused LN Crystals Wavelength-tuneable microring resonators have been realized also on Ti-indiffused substrate with integrated microheater allow wavelength tuning by way of the thermooptic effect (Wang et al. 2007). In this case ridge structures have been patterned on the Ti-indiffused waveguide to increase the lateral index contrast and a ring radius of 100 μm. A scheme for the presented resonator is reported in Fig. 3.100. The performances of this typology of ring resonators have been tested by varying the physical parameters such as the ring radius and the current injected in the microheater to achieve wavelength tuning. In particular Zhang and coworkers found that the FSR curves present a trend that is in agreement with FSR equation relating to the round-trip length (2π · R + 2 · L) and the effective index of guided mode neff respectively. In particular this measured FSR in function of R is in coherent with the FSR equation. Slight mismatch from the fitting curve has been ascribed to the dependence of neff on the wavelength and microring radius. In lithium niobate the ordinary refractive index (for TE) is higher than the extraordinary refractive index (for TM): as a consequence, for TE polarization the authors reported aa smaller FSR than TM polarization for various microring radiuses. In any case for both polarizations, the resonant wavelength shift approximately has shown a linear increase with the current. In particular the experimental tuning rates for TM and TE polarizations has been estimated to be 2.54 × 10−2 nm/mA and 3.40 × 10−3 nm/mA respectively. 3.9 Lithium Niobate and Hybrid Solutions 143 It is worth citing that the corresponding currents values required for the resonant wavelength shift of FSR value have been settled to be 55 and 400 mA. Microring Resonators by Ion Implantation in LN Crystals Fluorine ion implantation has been combined with high-ridge planar structuring to realize sub-100 μm radius microrings on Z-cut LiNbO3 wafers (Majkic et al. 2009). Ridge geometry allowed efficient optical confinement of transverse-electrically (TE) polarized waves. Planar waveguides were first produced by implantation of fluorine ions into the Z-cut LiNbO3 wafers at room temperature, at implantation energy equal to 14.5 meV and fluence of 2.5 × 1014 ions/cm2 respectively. Single-mode waveguides with a thickness of 1.35 μm and separated from the substrate by a 2 μm wide optical barrier have been therefore produced. Post annealing at 300 °C allowed to recover the crystal properties after the implantation and was followed by a photoresist deposition. After the deposition and the sub-μm gap between the microring and waveguide was granted by patterning the photoresist with laser writing and then transferring the pattern on the implanted substrate by Ar+ sputtering, producing microrings with radius R = 80 μm, 3.2 μm width and 1.2 μm height. To perform electro-optic tuning, the Cr/Al lower electrode was deposited in close proximity to the microring outer rim, whilst the upper electrode above the microring. A buffer layer of PVA was used to optically isolate the waveguides from the upper electrode. A scheme of the realized microring resonator is reported in Fig. 3.101. The device was fully characterized at a wavelength of 1.5 μm showing optical resonances with a modulation depth of 11 dB, separated by a 2.0-nm FSR for TE waves. Resonances were not observed with TM polarized light, presumably due to smaller index contrast and higher propagation losses. Fig. 3.101 a Optical micrograph of the microring resonator device, prior to applying the PVA buffer layer and the upper electrode. MR: microring; BW: bus waveguide; CR: coupling region; LE: lower electrode encircling 88% of the ring. b Microring waveguide cross-section, simulated optical intensity profile of the first TE mode (light gray), and the equipotential lines (1-V separation) upon application of an electrode voltage difference of 10 V (black) (Majkic et al. 2009) 144 3 Materials, Fabrication and Characterization Methods Fig. 3.102 a Measured TE wave transmission spectrum of the fabricated microring resonators. b Measured transmission spectra upon applying a bias voltage of 10, 0, and 10 V on the electrodes. Marked points represent: (1) maximum-slope point, (2) maximum transmission, and (3) minimum transmission upon applying a 10-Hz sinusoidal modulation voltage (Majkic et al. 2009) The final performances can be summarized as follows: electrooptical tunability of 10 pm/V, full-width at half-maximum spectral width of 0.5 nm and a measured microresonator’s FSR of (2.03 ± 0.02) nm respectively. the modulation depth at the strongest resonances was 14 dB. The resonator finesse was F = = 4 ± 0.4 and the corresponding quality factor Q = 3100 ± 300 (Majkic et al. 2009). The measured TE wave transmission spectrum of the fabricated microring resonators is reported in Fig. 3.102. It is worth mentioning to recall that the resonance shift depends on the change of the effective index but is independent of the resonator’s perimeter L = 2π r. Thanks to the LN birefringence and the ring’s axial symmetry, in the proposed configuration the δneff for TE waves depended mostly on the vertical component of the applied electric field (Ez ) and with approximation only electro-optical coefficient r13 could be considered. Zhao et al. fabricated ridge waveguides on lithium niobate using implantation of O+ ions combined with Ar ion beam etching, reporting 2 dB of losses. Microring Resonators by Argon-Milling (ICP-Etching) Micro-ring resonators with coupling waveguides have been efficiently realized by exploiting the Argon Milling (ICP-etching) technique described in Sect. 3.9. A typical result of a microring with a coupling waveguide is reported ion Fig. 3.103. The micro-structuring process has been achieved by the laser lithography system in a negative-tone photoresist film deposited on a LiNbO3 crystal. Coupling gaps, as narrow as 200 nm width, have been realized by a double step lithography process where initially a coupling waveguides have been written in the photoresist film by moving the sample with the translation stages followed by the photoresist developing and hardening. In a second step, a second lithography process has been added on a newly deposited photoresist film and the rings in order to achieve fine written 3.9 Lithium Niobate and Hybrid Solutions 145 Fig. 3.103 Scanning electron micrographs of a microring resonator with a coupling waveguide: a photoresist mask on a LiNbO3 wafer written by the laser lithography system; b final structure transferred onto a LiNbO3 crystal surface by Ar+ ion ICP-etching (Ar-milling) (Poberaj et al. 2009) structures by accurate and precise steering of the laser beam by way of the acoustooptic deflectors. The final structure transferred onto a LiNbO3 crystal surface by Ar+ ion ICP-etching (Ar-milling) respectively, bringing a microring with a coupling waveguide on a LiNbO3 that after after Ar+ ion etching has an etching depth of about 400 nm. Ring Resonators in LN: Performances Comparison In the following table a comparison among the performances of LN based micro-ring devices is reported. The previously quoted fabrication techniques as well as some key design parameters are listed such as the operating wavelength, the ring radius together with the λFSR and the best value achievable. The data have been taken from the references already cited in the previous sections for further details: it is worth mentioning that the waveguide propagation losses are highest in the case of crystal ion slicing and the best values are achieved in Ti-indiffused case. λFSR is below 2.0 nm even if 4.0 has been demonstrated in F implantation (Table 3.8). 146 3 Materials, Fabrication and Characterization Methods Table 3.8 Properties of LN based microring resonators Fabrication technique λ [μm] n Curvature radius [μm] Prop. losses [dB/cm] λFSR [nm] Max. λ∗FSR [nm] Proton exchange 0.79 ~0.01 1500 1.4–4.2 0.027 ~0.1 Titanium indiffusion 1.5 ≤0.04 100 – 1.42 1.0 Fluorine implantation 1.5 0.17 80 7.8 2.0 4.0 Crystalion slicing 1.5 0.65 100 17 1.66 14 Although these results could have been considered promising but still in the need of improvement, LN crystals can be exploited also in other configurations such as thin slices on insulators. In this case the performances have been drastically increased and the real potentialities of LN have been exploited. In the following sections details on ring resonators based on lithium niobate on insulators will be therefore provided. 3.9.2 Ring Resonators Based on Lithium Niobate on Insulators (LNOI) The first demonstration micro-resonating device based on a LNOI structure have been published since 2007, with the pioneering work of Guarino and coworkers (Guarino et al. 2007). They were able to demonstrate a LN based microring resonator with a radius of 100 μm whose tunability can be driven by the electrooptic effect. To achieve this result, they realized LN thin films by implanting z-cut lithium niobate wafers with He+ ions followed by bonding to another lithium niobate wafer, covered by a metallic electrode and a benzocyclobutene (BCB) layer of approximately 2.5 μm thickness as described in the previous sections. This planar structuring method of BCB-bonded LNOI samples is suitable for high-density integration on a single chip and therefore has been later optimized. However in the initial work of Gaurino, Ar+ ion etching has then exploited to reduce the film thickness to about 60 nm. Rings and waveguides were then realized by standard photolithographic techniques to achieve a 0.4 μm ridge structure. To reduce scattering looses and guarantee a good optical insulation between the chromium electrode and the core so that the applied electric field could be considered parallel to the z-axis, a 0.85 μm-thick SiO2 layer was finally deposited to cover the above mentioned device. A scheme of section of the LN microring resonator is reported in Fig. 3.104. In particular a straight waveguide was integrated as well at a distance (gap) of 0.2 μm from the ring. An image of the final devices reported in Fig. 3.105. An example of the achieved transmitted spectrum and relative geometry is presented in Fig. 3.106 at λ = 1.55 μm for both TE (electric field direction mainly 3.9 Lithium Niobate and Hybrid Solutions 147 Fig. 3.104 Schematic cross-section of an electro-optically tunable microring resonator based on BCB-bonded LN Fig. 3.105 Structured lithium niobate microring resonator. Scanning electron microscopy images of a lithium niobate microring resonator with radius R = 100 μm and b zoom of the coupling region between the waveguide and the ring. The gap size is approximately 0.2 μm (Guarino et al. 2007) Fig. 3.106 Transmission spectrum of a 100 μm-radius ring resonator. The measured normalized transmitted light at the through port for both TE (left) and TM (right) modes using a tunable source in the λ = 1.55–1.57 μm region is shown. The free spectral range is 1.66 nm and the finesse 5. The modulation depth is approximately 7 dB (Guarino et al. 2007) 148 3 Materials, Fabrication and Characterization Methods parallel to the film) and TM (perpendicular to the film) polarisations of the waveguide respectively. An extinction ratio at the resonant wavelengths close to 7 dB, a free spectral range of the resonator of about λFSR ≈ 1.66 nm has been found. The resonator finesse was approximately F = λFSR /δλFWHM ≈ 5 and the corresponding Q value is Q = 4 × 103 . This value is probably limited by implantationinduced defects and scattering losses. The propagation losses were measured to be approximately 4 cm −1 . This LN based ring resonator was characterized by a high-refractive index contrast in the stack (n ≈ 0.65), requiring stringent geometrical conditions to a single mode propagation such as a waveguide width ≈1 μm. At that time the technology was not optimized not easy to be achieved). It was however demonstrated that a 4 μm multimode waveguide could be used because of high losses of higher modes than the fundamental mode propagation. In the configuration presented by Guarino and coworkers, low bending losses have been obtained. Simulations suggested that they remain negligible even at ring radii as low as 10 μm. The electro-optical shift of the resonance curve is reported in Fig. 3.107 showing λ = 105 pm-shift in response to an applied voltage of V = 100 V, corresponding to a frequency tunability of 0.14 GHz/V. As an order of magnitude, for δV = 100 V a TM tunability of 0.3 GHz/V and TE tunability 0f 0.1 GHz/V are expected and have been experimentally confirmed in a LN based microring resonator with a radius of 100 μm. Similarly resonance shifts of the order of 100 pm and 30 pm have been measured for TM and TE mode respectively (Guarino et al. 2007). Disruptive advances in the lithography procedures have been achieved by exploiting laser lithography instead of standard mask alignment techniques. This approach allowed to overcome the initial limitations encountered that somehow constrained the microring radius to be not less than 100 μm. By using laser lithography, only two years later the pioneering work of Gaurino, Koechlin and coworkers in Koechlin (2009) demonstrated that the optical waveguides Fig. 3.107 Electro-optic shift of the resonance curve. Resonance curve at a wavelength around 1.555 μm (blue) and the corresponding electro-optically shifted curve (red) by applying a voltage V = 100 V to the device electrodes. The shift corresponds to an approximate tunability of 0.14 GHz/V (Guarino et al. 2007) 3.9 Lithium Niobate and Hybrid Solutions 149 surface quality could have been strongly improved allowing the realization of smaller curvature radii. They have been able to realize racetrack microring resonators with a curvature radius of 20 μm and a 10-μm long coupling region with a gap of 200 nm has been reported. In this case transmission measurements showed that a FSR value of 7 nm can be achieved as well as a quality factor Q of around 10,000. Finally a Transmission resonance dip with a width of 0.15 nm (FWHM) at a wavelength of 1544.8 nm (Poberaj et al. 2012). The micro-resonators milled in LNOI samples (Diziain et al. 2015) have been realized. LNOI wafers consisted of a 750 nm thick Z-cut LiNbO3 membrane bonded on a 1200 nm thick SiO2 layer deposited by plasma enhanced chemical vapor deposition (PECVD) on a LN substrate. The argon ion beam etching has been used to thin the sample (as an order of magnitude, the etching rate of LN is around 10 nm/min for an Ar + beam with an energy of 400 eV and a current density of 0.3 mA/cm2 ). The gross removal of material to get the final disk configuration have been then finely tuned by scanning the FIB on the LNOI surface and achieve a precise ring shape. With this two-steps approach, two types of self-suspended micro-resonators have been prepared: a Photonic Crystal (PhC) cavity in a 373 nm thick LiNbO3 layer and a micro-disk in a 512 nm thick membrane respectively. Devices using 600 nm thick X-cut LN thin films on 2 μm of silicon dioxide (SiO2 ) on silicon substrates have been proposed by Zhang et al. (2017). They used a standard electron beam lithography to define patterns in hydrogen silsesquioxane (HSQ) resist with multipass exposure. The patterns were then transferred into the LN thin film by commercial reactive ion etching (ICP RIE) set-up. LN etching was perfomed with an Ar+ plasma to get a ridge configuration eith a final height of hrib = 350 nm of LN with a hslab = 250 nm thin LN slab. After cleaning and removal of the resist, the devices have been cladded by depositing 1.5 μm of SiO2 using plasma-enhanced chemical vapor deposition (PECVD). The final configuration therefore achived is depicted in Fig. 3.108. Fig. 3.108 a Scanning electron microscope (top) and optical microscope (bottom) images of a microring and micro-racetrack resonators of various lengths. Inset: Close-up of the etched waveguides. b Simulated optical modes in straight and bent waveguides (Zhang et al. 2017) 150 3 Materials, Fabrication and Characterization Methods Fig. 3.109 a Resonance linewidth in the best devices is as narrow as 38 MHz, corresponding to loaded QL = 5 × 106. The laser is modulated by a precise frequency source at 500 MHz for calibration. Inset: Transmission spectrum in logarithmic scale indicating that the resonator is nearly critically coupled. b Ring-down measurement of the same device. c Measured quality factors for different resonators on several chips. d Extracted propagation loss for racetrack resonators. All the measurements are conducted around 1590 nm (Zhang et al. 2017) Despite of the high values of Q-factor, as depicted in Fig. 3.109, the proposed configuration was still suffering from sidewall scattering losses. As the same authors underlined, increasing the waveguide width from 800 nm to 2.4 μm can lead to a Q improvement from ~1.5 to ~4 × 106 when the reduced interaction of the light and the etched sidewalls can be achieved, basically connected only to improvements in preparation procedures. Recently, all-pass microring resonators have been monolithically integrated in Zcut LNOI from small, low-loss, high-index contrast and single mode C-band waveguides (Krasnokutska et al. 2019). Multiple rings with radii ranging from 30 to 90 μm have been proposed to obtain an FSR from 1.5 to 5.7 nm respectively. To achieve these results, a 500 nm thick LN film by smart-cut technique on 2 μm of SiO2 layer and supported by a 500 μm LN substrate have been produced. By way of electron beam lithography and lift-off of the e-beam evaporated metal layer, a hard mask defining the photonic components have been obtained. The components underwent a dry etching in a reactive ion etcher and, afterwards, optical waveguides have been cladded with 3 μm SiO2 thick film realized by plasma-enhanced chemical vapor deposition (PECVD). The rib waveguide cross-sections, have been designed via 3.9 Lithium Niobate and Hybrid Solutions 151 focused ion beam (FIB) slicing and scanning electron microscopy (SEM). A final sidewall angle of 75° and an etch depth of 350 nm have been finalized: optical grade dicing has been added as a final step in order to optimize the butt-coupling. A 6 mm chip has been therefore produced: the total input and output coupling and propagation loss is 8 dB have been obtained thank to the mode matching between the lensed coupled fiber and the waveguide made with linear inverse tapers from 200 μm down to 200 nm wide tips (Fig. 3.110). The simulated and measured performances of the Q value are reported in Fig. 3.111 in both TE and TM cases respectively in function of the ring radius as well as examples of the spectral response. In general, a Q-factor of ~9000 was achieved for the TM mode whilst for the TE mode the Q-factor is ~1200. As the radius of the ring increases, the Q-factor for TM mode remains almost unchanged (Krasnokutska et al. 2019). As far as the FSR values is concerned, as shown in Fig. 3.112, it lays in the range between 1.6 and 5.5 depending on the ring radius. Highest values are achieved when r is lower than 30 μm. In order to exploit the electro-optic effect of the material, a Cr/Al (20 nm/500 nm) electrode has been deposited directly on the upper cladding of the waveguide, with Fig. 3.110 a Simulation of Q-factor as a function of the coupling region gap for a 30 μm radius microring—the light red dashed lines demarcate the simulated Q-factor (~10,000) for the microring shown in (d). b Design of a single mode LNOI rib waveguide at 1550 nm wavelength; the top width is 650 nm, the bottom width is 840 nm and the waveguide height is 350 nm. Scanning electron microscope pictures: c cross-section taken by FIB slicing and SEM imaging; d an etched 30 μm radius ring with a 300 nm gap between the bus waveguide and the ring prior to PECVD SiO2 cladding; e false-color image of the coupling region after the lift-off process and prior to etching; the false-red highlights the metal etch mask (Krasnokutska et al. 2019) 152 3 Materials, Fabrication and Characterization Methods Fig. 3.111 a Simulation of Q-factor as a function of the coupling region gap for a 30 μm radius microring—the light red dashed lines demarcate the simulated Q-factor (~10,000) for the microring. b Measured Q-factors of the ring resonators versus their radius for the TE and TM modes. The blue curve corresponds to the TE mode and the red curve corresponds to the TM mode. c Spectral response of the ring with radius 30 μm for TM mode. d Spectral response of the ring with radius 90 μm for TE mode (Krasnokutska et al. 2019) 3.9 Lithium Niobate and Hybrid Solutions 153 Fig. 3.112 a Measured FSR as the function of a microring resonator radius for the TE mode and d for TM mode; the blue circles are measured values, whilst red line is theoretically predicted dependence of FSR on microring resonator radius; b the simulated electrical field distribution for the TE mode and (e) for the TM mode; c measured optical power distribution at the output of the chip for the TE mode and f for the TM mode, where black lines schematically show the actual waveguide dimensions (Krasnokutska et al. 2019) a separation gap of 3 μm to prevent optical loss. The bottom electrode, serving as a ground plane, is made from Cr (10 nm), Au (100 nm) and Cr (10 nm) respectively. By applying a DC voltage inn the range [0; −55] V across the top and bottom electrodes of the microring resonators, the resonance shifts with the applied voltage have been determined with an average EO tunability of 3 ± 0.04 pm/V. Microrings with radii ≥60 μm experience a DC voltage bias offset meanwhile, rings with radii ≤50 μm have a constant tunability of ~3 pm/V even at lower voltages (<10 V) (Fig. 3.113). The microring design was tailored depending on the radius: in the case of 30 μm microring resonator small bending loss were needed requiring high-index contrast single mode waveguides at 1550 nm. To obtain wide bandwidth resonances, a geometry with a 300 nm gap was chosen and get high overcoupling conditions in the rings. This is a strategy commonly used to relax the need of a very fine wavelength tuning. In the particular case they obtained a 3 dB resonance badwidth. The Q-factor measurements have shown that it is possible to achieve small and high performance microring Fig. 3.113 a Simulation results of electrical field. b Spectrum of the optical resonances of a 70 μm when voltage from −55 to 0 V is applied. c Shift in resonance of a 50 μm microring resonator when −10 V is applied (Krasnokutska et al. 2019) 154 3 Materials, Fabrication and Characterization Methods resonators for the TM mode—critical for electro-optic and nonlinear applications. On the contrary, the TE mode bending losses can significantly limit the Q-factor of the smaller radius microring resonators. In this case in fact the index contrast of the TE fundamental mode is lower than that of the TM fundamental mode. It is important to underline that in this type of microring resonator Voltage bias offsets can be present, even as high as 50 V in microring resonator with radius close to 50 μm. Respect other polymers, BCB has been played the role of a key factor: apart from his low refractive index (n ≈ 1.55), high transparency in the visible and infrared region, it presented excellent adhesion and easiness to be flatted. Recent results obtained by the group of Loncar at the Harvard University demonstrated quality factors of up to 107 , thanks to Ar+ plasma etching to physically sculpt micro-resonators from lithium niobate films that were 600 nm thick and grown on a 2 μm-thick SiO2 wafer. By etching a total of 350 nm of lithium niobate they left behind a 250 nm-thin lithium niobate slab and were able to prepare an integrated waveguide-coupled micro-ring and racetrack resonators with a bending radius of 80 μm and various “straight arm” lengths and waveguide widths. The optical Qfactors of this devices using a tuneable telecom external cavity diode laser and the propagation losses of less than 3 dB/m allows light to propagate across a metre-length path while only losing about half their optical power. The advances obtained respect the previous lithium niobate devices is definitively significant because the previous ones lost more than 99% over the same distance. This opens up a wide range of applications, including ultralow-loss quantum photonics, coherent microwave-to-optical conversion and active topological photonics (Zhang et al. 2017). Finally even the laser writing technique has very recently demonstrated suitable to design an integrated optical ring resonator to be implemented in LiNbO3 with a 2.5 mm radius and an operating wavelength of 1550 nm (Pagano et al. 2020). A free spectral range of 71.54 pm and a quality factor of ~5 × 105 were achieved. In this sense, the suitable determination of a splice angle (in this case 1.44°), shape and length for segments demonstrated to be key parameters in the ring design. For this purpose, an ad hoc software was implemented and in summary, a 250 sided polygon side showed a suitable coupling performance and established a new layout approach for middle range rings. It is worth mentioning that the so called self-suspended micro-resonators patterned in Z-cut lithium niobate on insulator substrates have been also proposed as hybrid configuration. In this case the fabrication technique consists of two single steps, focused ion beam milling for the micro- and nano-structuring and subsequent SiO2 etching for the realization of thin self-suspended membranes. The fabrication process of a free-standing photonic crystal cavity and a suspended micro-disk is described and the linear and nonlinear optical properties of the micro-resonators are investigated at telecommunication wavelengths. The whispering gallery modes of the micro-disk are measured experimentally and compared to an analytical model. The fundamental transverse-electric polarized mode of the photonic crystal cavity is measured and compared to three dimensional finite difference time domain simulations. Second harmonic generation enhancement due to the field confinement in the cavity mode is demonstrated. These results are promising for the use of Z-cut lithium niobate 3.9 Lithium Niobate and Hybrid Solutions 155 Table 3.9 Comparison between different types of tunable rings (Krasnokutska et al. 2019) Material Radius of a ring (μm) FSR (nm) EO tuning (pm/V) SOI PN junction30 7.5 8000 12.6 26 SOI on LN with integrated electrodes31 15 11,500 7.15 12.5 SOI on LN32 15 14,000 7.15 3.3 A1N33 60 500,000 n.a. 0.18 X-cut LNOI34 n.a. 50,000 n.a. 7 Z-cut LNOI35 100 4000 1.66 1.05 Z-cut LNOI36 Q-factor 50 2800 3.2 2.15 Z-cut LNOI (this work) 70 7500 2.5 3 self-suspended membranes as platforms for highly efficient miniaturized photonic devices for telecommunication applications. In Table 3.9 a comparison between microring resonator achieved in LNOI on both X and Z cut microring resonators is reported respect other technologies. Although silicon has reported very high tuning with large FSR, it is worth mentioning that the optical transparency for this material prevents its application in some spectral ranges. Recent works in hybrid Si on LN have been proposed to solve this problem but still requires extra fabrication steps that complicate the fabrication procedures. For these reasons LNOI photonics presents a promising alternative for getting tunable ring resonators as complementary tools to silicon based devices. Further refinements have been achieved developing new receipts. Either advance plasma etching combinations techniques as well as femtosecond laser have been successfully implemented. Despite the more complicated receipts they optimized the final results especially to face the know limitation of ion beam etching. It can inherently leave behind a surface roughness on the order of a few nanometers, which can limit the final Q-factor of a freestanding LN microdisk to ~106 recently been It has been proposed to proceed with a first patterning a chromium (Cr) thin film coated on the top surface of LNOI into a hard mask with a femtosecond laser, followed by the chemo-mechanical polish (CMP) for structuring the LNOI into the microdisk (Wu et al. 2018). The CMP lithography (CMPL) can enable ultrahigh performance LNOI photonic structures, opening the venue toward large scale, low loss, reconfigurable PICs for numerous applications. The performance of on-chip integrated photonic structures has approached that of the bulk optics fabricated in traditional ways such as polishing and coating (Wu et al. 2018) (Fig. 3.114). 156 3 Materials, Fabrication and Characterization Methods Fig. 3.114 Schematic of the fabrication flow of the chemo-mechanical polish lithography. a Depositing a thin layer of Cr on the top of the lithium-niobate-on-insulator (LNOI) wafer. b Patterning the Cr layer by femtosecond laser ablation to form a hard mask. c Conducting chemomechanical polishing (CMP) on the sample to transfer the pattern from the Cr mask to the LNOI. d Chemically removing the remaining Cr mask and performing a secondary CMP to further smooth the sidewall near the top surface. e Schematic illustration of the CMP principle and the instrument (Wu et al. 2018) 3.9.3 Ring Resonators Based on Lithium Niobate on Insulators in Hybrid Configuration with Nitrides and Semiconductors Hybrid configurations to couple semiconductors, glass compounds, polymers and other crystals such as lithium niobate have proven to be extremely advantageous to overcome some specific problems that are material-dependent. Among those solutions free standing microrings BCB bonded LNOI with nitrides stacks have been proposed (Poberaj et al. 2012). As a matter of fact thin-film LiNbO3 on insulator has recently proved as a promising alternative to achieve lower mode areas boosting the electro-optic efficiency. In this frame of reference, monolithic LN nanophotonic circuit has been addressed as the new challenge of high-speed modern telecommunication and in hybrid platforms where an easy-to-etch material (e.g. Si and SiN) is used as a device layer bonded to non-etched thin LN films. These heterogeneous platforms are very promising and for this reason great efforts are currently made to optimize them in order to get the best compromise between electro-optic bandwidth, modulation efficiency, optical confinement and operating wavelengths respectively. 3.9 Lithium Niobate and Hybrid Solutions 157 LN Hybrids with Nitrides Starting from the BCB bonding procedures already presented in the previous section, hybrid solutions have been realized coupling LN rings to nitrides. In this case LN rings have been obtained by fully etching BCB/LN structures until the BCB layer interface. In this way isolated microrings have been obtained, laying on the top of the substrate free to be moved and transferred onto any other host substrate. They have been therefore placed and aligned with high accuracy and precision using submicrometer positioning actuators. By using this approach LiNbO3 microrings coupled to gallium nitride (GaN) have been achieved with small radius (close to 20 μm). GaN has been chosen because its low absorption in the near infrared wavelength range and a good refractive index matching with LiNbO3 respectively. The vertical structure LN/GaN showed a good refractive index match, optimized by using a sapphire substrate covered with a 100nm thick layer of SiN and waveguides (Koechlin et al. 2010). Koechlin and coworkers (2010) have demonstrated that free-standing LiNbO3 microring with a radius of 20 μm, positioned on a straight GaN waveguide can be achieved. The widths of the coupling waveguide and of the microring have been settled to 1.1 μm and 3.0 μm, respectively, both structures having a height of 600 nm (Kochlin et al. 2010). These authors characterized the polarized transmission. The transmission spectrum has shown as sharp resonance dips with a linewidth of 0.15 nm FWHM and an extinction ratio of up to 18 dB, separated by a FSR = 7.9 nm at 1.55 μm respectively. These types of structures have demonstrated to have a finesse close to 53 and quality factor Q 10,000 and propagation losses close to 17 dB/cm for the zero-order TE mode in the LiNbO3 microring. The measured resonance dip was found at 1555.28 nm with a linewidth of 0.15 nm FWHM and an extinction ratio of 18 dB. Both standalone and other hybrid LiNbO3 platforms such as Si-LiNbO3 , Si3 N4 LiNbO3 ) have been also demonstrated to be very active (Boes et al. 2018). Si3 N4 LiNbO3 have attracted great attention because of good index matching, high mode confinement inside LiNbO3 (Jin et al. 2016; Zhang et al. 2017) as well as ultralow propagation loss of Si3 N4 , high power handling capabilities. Last but not least, Si3 N4 has insulating properties, and a wide optical transparency window. Passive devices have been optimized in Si3 N4 -LiNbO3 -based structures made low loss optical waveguides and vertical mode transition structures from Si3 N4 to LiNbO3 material and push–pull Mach-Zehnder interferometer (MZI) modulation. As far as microring resonators, recent advances have been confirmed with the first hybrid Si3 N4 -LiNbO3 based tunable microring resonator where the waveguide has been formed by loading a Si3 N4 strip on an electro-optic (EO) material of X-cut thin-film LiNbO3 (Ahmed et al. 2019). A sketch of the realized structure is reported in Fig. 3.115. The hybrid Si3 N4 -LiNbO3 microring exhibited a high intrinsic quality factor of 1.85 × 105 , with a ring propagation loss of 0.32 dB/cm, resulting in a spectral linewidth of 13 pm, and a resonance extinction ratio of ~27 dB within the optical C-band for the transverse electric mode. Using the electro-optic effect of LiNbO3 , a 1.78 pm/V resonance tunability near 1550 nm wavelength has been finally demonstrated. In Fig. 3.116 a sketch of the preparation procedure is reported. 158 3 Materials, Fabrication and Characterization Methods Fig. 3.115 a Schematic of the tunable hybrid Si3 N4 -LiNbO3 micro-ring resonator with integrated electrodes (not drawn in scale). b Simulated TE mode field profile of a hybrid Si3 N4 -LiNbO3 waveguide formed by a 200 nm × 1.2 μm Si3 N4 loading strip at 1550 nm. c Simulated bending loss as a function of bending radius for the TE mode. The bending loss is presented as decibel (dB) per 90° bend (Ahmed et al. 2019) Fig. 3.116 a SEM image of the bilayer lift-off process. b SEM image of the microring coupling section. c SEM image of a hybrid Si3 N4 -LiNbO3 microring with a bending radius of 300 μm, waveguide thickness of 200 nm, and waveguide width of 1.2 μm. The inset shows the zoomed section of the boxed region (Ahmed et al. 2019) 3.9 Lithium Niobate and Hybrid Solutions 159 Fig. 3.117 Hybrid microring resonator characterization. a The measured transmission spectrum of the passive microring at the through port for TE mode using a tunable laser near the 1550 nm. The free spectral range is 0.58 nm, and the resonance extinction ratios are up to 27 dB. b The Lorentz fitting (red curve) of the resonance dip at 5 1551.98 nm, which corresponds to an intrinsic Q of 1.83 × 10. c The resonant spectra as a function of the applied voltage for TE mode at wavelengths near 1551.410 nm (black curve) of a micro-ring resonator; the red and blue curves are the corresponding electro-optically shifted curves by applying a voltage of −50 V and 50 V to the device electrodes, respectively. The measured tunability is 1.78 pm/V. d The resonant wavelength shift as a function of the applied DC voltage (Ahmed et al. 2019) Some results of this integrated microring resonator is depicted in Fig. 3.117. In this case the measured transmission spectrum of the passive microring at the through port for TE mode using a tunable laser near the 1550 nm is shown. The free spectral range is 0.58 nm, and the resonance extinction ratios are up to 27 dB. The resonant spectra as a function of the applied voltage for TE mode at wavelengths near 1551.410 nm are presented together with the corresponding electro-optically shifted curves by applying a voltage of −50 V and 50 V to the device electrodes, respectively. LN Hybrids with Semiconductors As already pointed put in the previous sections, the crucial technological step to realize an Integrated Optics Circuit and in LNOI and photonic devices in general relies on the way used to pattern LiNbO3 thin films. Recent advances on this topic come mainly on the exploitation of optimized techniques and protocols to achieve a better resolution, an improved surface and cut edge quality. On this framework 160 3 Materials, Fabrication and Characterization Methods of reference, femtosecond laser, chemo-mechanical polishing for patterning waveguides have recently demonstrated to provide better results in the LNOI realization. To this aim even Si-LN and Si/LNOI structures have been proposed to improve integrated ring resonators. In particular Hybrid silicon and LiNbO3 electro-optical ring modulator operating at gigahertz frequencies consisting of a 15 μm radius silicon microring and an ion-sliced LiNbO3 thin film bonded together via benzocyclobutene has been successfully achieved (Chen et al. 2014). A sketch of the proposed device is reported in Fig. 3.118. A Scanning electron micrograph of the silicon microring resonator after slab patterning and doping is reported in Fig. 3.119. These devices have been operating in the TE optical mode and exhibited an optical loaded quality factor of 14,000 and a resonance tuning of 3.3 pm/V respectively (Chen et al. 2014). In particular an electrical-to-optical 3 dB bandwidth has been measured to be 5 GHz together with a digital modulation with an extinction ratio greater than 3 dB demonstrated up to 9 Gb/s. High-speed and low-tuning-power chip-scale modulators that exploit the high-index contrast of silicon with the second-order susceptibility of LiNbO3 have therefore achievable. Optical transmission measurements were carried out to characterize the electrical tuning of optical resonances. TE-mode light from Fig. 3.118 Schematic of the hybrid silicon and LiNbO3 ring modulator (Chen et al. 2014) Fig. 3.119 a Scanning electron micrograph of the silicon microring resonator after slab patterning and doping; b top-view optical micrograph of the fabricated device (Chen et al. 2014) 3.9 Lithium Niobate and Hybrid Solutions 161 Fig. 3.120 Measured optical transmission of a single resonance as a function of applied voltage (Chen et al. 2014) a tunable infrared continuous-wave laser source has been therefore coupled through the input and output fiber-to-chip cantilever couplers of the modulator. DC voltage was consequently applied to the top electrode of the modulator while the bottom electrode is grounded. An example of the measured optical transmission of a single resonance as a function of applied voltage is reported in Fig. 3.120. The total optical insertion loss were found to be close to 4.3 dB. The resonance shift is 66 pm for a change in DC bias from −10 to 10 V can be there seen indicating 3.3 pm/V tuning, which is equivalent to a V π L of 9.1 V cm. The measured quality factor is 14,000, the FWHM is 13.7 GHz, and the group index is 4.0. At 1551.856 nm, the optical transmission intensity varies by 5.2 dB with a −5 to 5 V voltage swing, as indicated by the dashed arrow (Chen et al. 2014). 3.9.4 Microring Modulators Based on Lithium Niobate and Chalcogenide Glasses on Silicon Chalcogenide glasses are amorphous materials containing at least one of the chalcogen elements such as Se, Te and S. Although they have been mainly used in optical memories and IR lens systems thanks to their thermal stability, and transparency to a large range of wavelengths. Waveguide structures in chalcogenides have been already been demonstrated as well as applications in nonlinear optics. Although some constraints in achieving high confinement has been initially evidenced in the past due to the low refractive index, chalcogenide glasses appeared to be attractive to create hybrid solutions. In this frame of reference, the first feedback optical filter fabricated in ring shaped As2 S3 on LN crystals has been proposed. Vertically integrate waveguides with a core material of As2 S3 , a chalcogenide glass with a refractive index of 2.4 compared with 2.2 for LN have been therefore obtained with low-loss bend radii of the order of 100 μm by Solmaz and coworkers. The mode confinement has 162 3 Materials, Fabrication and Characterization Methods been adjusted between the As2 S3 and the LN materials by varying the As2 S3 waveguide thickness and width (Solmaz et al. 2009). Lithography and reactive-ion etching have been exploited to design the final configuration, where standard Ti-indiffused waveguides have been deposited with 470 nm thick As2 S3 by RF magnetron sputtering. The fiber-to-fiber insertion loss of a typical waveguide is 2.5 ± 0.5 dB. A protective layer of SiO2 and Ti is covered on the chalcogenide thin film to prevent dissolution of As2 S3 in photoresist developer. Contact photolithography has been used to pattern on the titanium and a subsequent reactive-ion etching step forms the As2 S3 ring structure. The taper design helps to reduce the effective index mismatch between the Ti-diffused and the As2 S3 waveguides and thereby increase the coupling into the ring. The taper length of 750 μm together with a ring diameter of 581.6 μm together generated a final circumference of 4.827 mm and free-spectral range (FSR) of approximately close to 25.4 GHz, with a calculated power coupling ratio and roundtrip loss are 10.6% and 2.08 dB, respectively, for TM polarization respectively. Other heterogeneous microring modulators based on lithium niobate and chalcogenide glasses on silicon have been realized by bonding on silicon substrates and rib-loaded with a chalcogenide glass Ge23 Sb7 S70 . Single-mode submicron waveguides and microring modulators in the telecom C band have been made by using 400-nm-thick film of Y-cut LN bonded to a 2 μm thick layer of SiO2 on a Si substrate to form the slab region of the ridge optical waveguide. The LN thin films were then rib-loaded with a 0.35 μm × 1.3 μm strip of index-matched chalcogenide to get a single-mode waveguides at 1550 nm wavelength. Bending losses could be considered negligible in this geometry thanks to the high radius of the microring modulator. The crystal orientation of the lithium niobate thin film has been chosen to utilize the highest electrooptic coefficient of LN, r 33 = 31 pm/V: the microring modulator have been designed for a tunability of 3.8 pm/V. A final performance of 1.2 dB/cm waveguide propagation with quality factor close to 1.2 × 105 has been achieved, with a tuning rate equal to 0.4 GHz/V and 13 dB extinction ratio respectively. A scheme of the realized structures is depicted in Fig. 3.121 (Rao et al. 2015), together with the section of the device. Fig. 3.121 Schematic of the new platform depicting the chalcogenide (ChG) rib, lithium niobate (LN) core slab, lower optical cladding of silicon dioxide (SiO2), silicon substrate (Si), and the gold metal electrodes for: a microring modulators; b optical TE mode profile at 1550 nm—the thin gold stripes are the 100-nm-thick regions of the gold electrodes (Rao et al. 2015) 3.9 Lithium Niobate and Hybrid Solutions 163 Fig. 3.122 a Measured transmission spectrum (blue) around one under-coupled microring resonance, and the corresponding theoretical fit (red). b Measured transmission spectrum (blue) around one critically coupled MRM resonance and the corresponding theoretical fit (red). c Measured transmission power spectrum of the critically-coupled MRM devices. d Optical modulation (green) following the electrical drive signal (blue) at sub-kHz frequencies. The drive signal clipping observed is a measurement artefact from the limitation of the measurement range of the oscilloscope used, and doesn’t affect the extraction of any parameters from the measured data (Rao et al. 2015) These responses have been obtained at wavelength in the range 1530–1565 nm: in the case of 200 μm radius, these devices were under-coupled to minimize the coupling loss. It is worth mentioning that the propagation loss of 1.2 dB/cm in the LN waveguides rib-loaded with ChG is significantly lower than those observed on Ta2 O5 microring modulators that showed instead loss of 5 dB/cm (Rabiei et al. 2013). The critically-coupled microring modulators have a lower loaded Q of 8.6 × 104 , an unloaded Q of 1.26 × 105 , and a maximum potential extinction ratio of over 15 dB. The measured transmission spectrum under-coupled microring resonance as well as around one critically coupled MRM resonance are reported together wit the optical modulation in Fig. 3.122. 3.10 Microring Modulators in LN, LNOI and Hybrids: Limits and Improvements The optimization of the final performances needs to look after every constraint and verify what can be improved and what instead represents and intrinsic limit. Several studies have been made on this topic, the most comprehensive has been very recently made by Bahadori et al. (2020). In a microring resonator, it is expected a high impact 164 3 Materials, Fabrication and Characterization Methods of the curvature of microring/race-track resonators on the electro-optic tuning with a coefficient so-called the filling factor. Bahadori and coworkers have calculated this contribute depending on the crystal cut. By referring to Fig. 3.123 for the reference system and geometries therein considered, the electro-optic perturbation under rotation is summarized in Table 3.10. In Fig. 3.123 in fact it is shown the rotation a straight waveguide and its side electrodes by an angle ϕ respect the crystal axis (in this case Y-axis). It results that the applied lateral DC field still strongly interacts with the transverse electric (TE) Fig. 3.123 Schematic of a straight LN waveguide with two electrodes on the side. The applied DC field between the two electrodes is exactly in the extraordinary direction of the crystal. Under the rotation, the applied DC field is no longer in the extraordinary direction. The 1, 2, 3 axes are aligned with the LN crystal coordinate system such that axis 3 is the extraordinary direction (optic axis). The axes under rotation by ϕ are denoted by 1 , 2 , 3 (Bahadori et al. 2020) Table 3.10 Derived relations for the electro-optic perturbation under rotation for the LN crystals Electro-optic perturbation under rotationa (0) Crystal n eff (φ)/n eff X-cut cos3 φ + 2 22 2 33 r22 r33 sin φ + Y-cut cos2 φ + 2 11 2 33 r13 r33 cos φ sin2 φ Z-cut 1 r23 r33 cos φ sin2 φ It is worth noting that in this derivation the impact of rotation of the DC [ε] tensor on the applied DC field inside the LN waveguide has been ignored. DC field is exactly aligned with the Z-axis, the dielectric tensor [ε] corresponds to the dielectric perturbation tensor [ε] (Bahadori et al. 2020) a 11 = 22 = 4.889 = o (ordinary, optical). 33 = 4.569 = e (extraordinary, optical). r13 = r23 = 8.6 pm/V, r22 = 3.4 pm/V, r33 = 30.8 pm/V Z-cut assumes a vertical DC field 3.10 Microring Modulators in LN, LNOI and Hybrids: Limits and Improvements 165 mode of the waveguide although the r 33 coefficient cannot be fully harnessed to produce maximum net electro-optic effect. It clearly emerges that electrodes are closer to the waveguide, guaranteeing a higher optical confinement of the TE mode and the reinforcement of the interaction between the TE optical mode and the lateral DC electric field respectively (Bahadori et al. 2020). This configuration has proven to have a significant impact when X and Y cut LN based microring resonators devices because of the stronger electrooptic perturbation effects under the same applied voltages. Instead, the electro-optic performances of Z-cut waveguides are not improved by the rotation of the waveguide and the electrodes. It is worth mentioning that in Z-cut waveguides TM modes are commonly used to achieve high electro-optic effect. In this case electrodes are placed at higher vertical distance above the waveguide hence limiting the strength of this perturbation due to the lower optical confinement of TM modes (Bahadori et al. 2020). Their work has shown also that the upper bound of the filling factor for a singlepair electrode arrangement in a microring modulator is ~0.25 which is achieved when the electrodes are symmetrically extended by 90° about the extraordinary direction. In general, a microring modulators have shown to present an upper bound on their electro-optic performance (~50% filling factor) corresponding to a specific arrangement of metal electrodes surrounding the microring. In the case of lithium niobate, it yields nearly identical results for X-cut and Y-cut designs although this limitation does not exist (i.e., 100% filling factor is possible) with Z-cut microring modulators. It is worth mentioning that filling factor ~100% is achievable in Xcut and Y-cut modulators provided that a race-track configuration with segmented electrodes is set-up. By exploiting the crystal properties of the material, it is possible to optimize the design and consider the effect of the so-called rotated configuration. These effects of the electro-optic performances are impacting on the final microring response but can be overcome by a suitable tailoring of the resonator design. Some studies have been performed to propose new configurations, as depicted in Fig. 3.124 (Bahadori et al. 2020). In this case of a microring resonator with one electrode inside and another electrode outside of the ring is reported. The tuning efficiency can be estimated by quantifying the shift in the resonance λres , that in this case is given by: λres = EO · FSRnm 2π (3.20) where is the variation in the phase shift (λ), and EO stands for Electro-Optic. Due to the curvature of the microring resonator and electrodes (in Fig. 3.125a) it is clear that the applied DC field inside the ring deviates from the extraordinary direction when moving along the ring from the angle ϕ = 0. As reported in Bahadori et al. (2020), the total induced electro-optic phase shift is given by EO 2π ·R = λ φ1 n eff (φ)dφ φ0 (3.21) 166 3 Materials, Fabrication and Characterization Methods Fig. 3.124 a Schematic of a microring resonator in Y-cut LN. The curvature of the ring and electrodes causes the applied DC field inside the LN waveguide to deviate from the extraordinary direction (3 axis). b Electrode arrangements for X-cut or Y-cut microring modulators with arbitrary extent originated from the extraordinary axis, and c its filling factor (Bahadori et al. 2020) That corresponds to a tuning efficiency: λres = VDC λres n (0) eff · ng VDC · ff (3.22) It is worth mentioning that, as underlined by Bahadori et al. (2020), the term in parentheses is equivalent to a uniform electro-optic perturbation in the extraordinary direction. λres n (0) eff · (3.23) pEO = ng VDC Similarly to a straight waveguide at the state of zero where: rotation, this term represents the impact of the curvature of microring/electrodes. The so-called filling extent of the electrodes (i.e., the fraction of the microring exposed to electro-optic perturbation) is given by: 3.10 Microring Modulators in LN, LNOI and Hybrids: Limits and Improvements 167 Fig. 3.125 a Symmetric extension of electrodes about the ordinary axis and b its filling factor. c Symmetric extension about the extraordinary axis, and d its filling factor 1 f f (φ0 , φ1 ) = 2π φ0 φ0 n eff (φ) n (0) eff dφ (3.24) By taking in to account these equations and the results summarized in Table 3.11. The filling factors for X and Y configuration can be estimated in function of θ. It results that the maximum possible value for the filling factor is 0.253 for X-cut and 0.246 for Y-cut (Bahadori et al. 2020). This result fixes a basic constraint in the curvature of the microring resonators and the relative electro-optic performance in X-cut or Y-cut thin-film LN platform respectively. In Table 3.11 a summary of performances in terms of tunability actually achievable by microring modulators based on thin-film lithium niobate have also been quoted in Bahadori et al. (2020). Although the X-cut and Y-cut modulators showed to suffer from rotation effects as previously quoted, they provide higher electrooptic tunability for the resonance respect other microring configurations. In the case of Z-cut structures, only hybrid systems have been suitable alternatives for a good tunability. 168 3 Materials, Fabrication and Characterization Methods Table 3.11 Literature review on the demonstrated tunability of X-cut, Y-cut, and Z-cut microring modulator (Bahadori et al. 2020) Author Structure type LN type Mode Tunability (pm/V) Ahmed et al. [23] Hybrid LN/SiN Zhang et al. [24] Partially etched LN X-cut TE 2.8 X-cut TE Rabiei et al. [16] Hybrid LN/Ta2 O5 X-cut 4 TE 4.5 Chen et al. [25] Hybrid LN/Si X-cut TE 3.3 Wang et al. [4] Partially etched LN X-cut TE 2.4 Wang et al. [10] Partially etched LN X-cut TE 7 Ahmed et al. [26] Hybrid LN/SiN X-cut TE 1.78 Rao et al. [9] Hybrid LN/Sia Y-cut TE 3.2 Mahmoud et al. [15] Partially etched LN Y-cut TE 0.32 Chen et al. [21] Hybrid LN/Si Z-cut TM 12.5 Wang et al. [27] Partially etched LN Z-cut TM 1.565 Guarino et al. [20] Partially etched LN Z-cut TM 1.05 Lee et al. [7] Hybrid LN/Si Z-cut TE 2 Siew et al. [28] Partially etched LN Z-cut TM 2.15 Krasnokutska et al. [19] Partially etched LN Z-cut TM 3 Reprinted under Common Creative License a With chalcogenide glass Examples of devices that can be therefore obtained and provide for excellent compromises are reported in Figs. 3.126 and 3.127. In the first case a modal electrooptic efficiency of about 2.26 × 10−5 V−1 and pEO close to 15.64 pm/V. The following chapter deals with the building blocks of ring resonator devices which include bends and couplers. 3.10 Microring Modulators in LN, LNOI and Hybrids: Limits and Improvements 169 Fig. 3.126 a Cross-section of the LN waveguide with its dimensions listed in the inset table. b Electrode arrangement used in the X-cut microring structure. The two pairs of electrodes have reverse polarity; hence each pair contributes a filling factor of ~0.24 and the overall filling factor is ~0.48. c COMSOL simulation for the DC E-field distribution for V DC = 1 V. 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Express 14(15), 6851–6857 (2006) Chapter 4 Building Blocks of Ring Resonator Devices Ring resonator devices comprise a bus waveguide and a ring which is made out of bend waveguides in the basic configuration. The material used for realizing the ring resonator filter already imposes restrictions onto the waveguide type and thus on the performance of the ring resonator. It is therefore important to analyze the building blocks of the envisaged ring resonator with respect to the wanted performance of the filter in advance once the material has been chosen. The part where the bus and the ring come close to one another can be regarded as a coupler, also in the basic configuration, where the interaction path (coupler length) of the optical field in ring and coupler is extremely short. The performance of the ring resonator depends on the power coupling factor as one parameter besides several other factors already discussed in previous chapters. Several coupling schemes can be applied including vertical couplers, directional couplers, MMI couplers and Ycouplers. A detailed summary of the simulation and design of directional couplers and MMI couplers also with respect to polarization dependence is presented in Darmawan et al. (2005). In order to fabricate ring resonators with low loss, it is essential to know the bending loss of the waveguides which depends directly on the used bending radius, which supplies the FSR of the ring resonator filter if this type of waveguide is used for fabricating the ring. A fact which should be taken into account in the designing stage is the coupling of the bus waveguides to the outside world. Here several concepts exist like tapering the waveguides in vertical, horizontal (or both) directions to match the mode field profile of the bus waveguides to an optical fiber. This chapter provides an introduction into the various building blocks making up a ring resonator filter. © Springer Nature Switzerland AG 2020 D. G. Rabus and C. Sada, Integrated Ring Resonators, Springer Series in Optical Sciences 127, https://doi.org/10.1007/978-3-030-60131-7_4 179 180 4 Building Blocks of Ring Resonator Devices 4.1 Couplers 4.1.1 Directional Couplers An important device used to couple light into and from ring resonators is the directional coupler. This type of coupler is preferably used to realize splitting ratios other than 3 dB. One of the first papers to deal with directional integrated optical couplers is presented in Marcatili (1969b). Directional couplers have been studied extensively in the past and have found their way into many integrated optical devices like for example optical switches (Forber and Marom 1986) and vertical coupler beam splitters (Raburn et al. 2000). The well-known equations which describe the input and output field of the coupler shown in Fig. 4.1 are given by E3 E4 1 = (1 − γ ) 2 √ √ 1 − κ −j κ E1 √ √ . · E2 −j κ 1 − κ (4.1) The relation between the in- and output intensity of a symmetrical directional coupler is given using I3 I4 1−κ κ I = (1 − γ ) · 1 , I2 κ 1−κ (4.2) where γ is the power loss coefficient, κ is the power coupling factor. If both waveguides have the same propagation constant which is the case in this configuration and the light is inserted into input port 1, then after a length L c the energy will have coupled into the other waveguide and can be detected at output port 4. The coupling behavior dependent on L c for light inserted at input port 1 is expressed by π x , 2L c 1 π E 4 (x) = j E 1 (1 − γ ) 2 sin x , 2L c 1 E 3 (x) = E 1 (1 − γ ) 2 cos I3 (x) = E 3 (x) · E 3 (x) and I4 (x) = E 4 (x) · E 4 (x). Fig. 4.1 The directional coupler (4.3) (4.4) (4.5) 4.1 Couplers 181 Fig. 4.2 Coupling behavior of a symmetrical directional coupler The coupling behavior for a coupler with L c = 450 μm, E 1 = 1, E 2 = 0 is shown in Fig. 4.2. The intensity at both output ports is normalized to the sum of the output intensities Intensity at output port 3 = I3 I3 + I4 (4.6) Intensity at output port 4 = I4 I3 + I4 (4.7) The power coupling factor κ is taken from the diagram (Fig. 4.2) for a specific coupling length x. For example, the power coupling factor κ is equal to κ = 0.9 for a coupler with a length of 360 μm. The separation between the waveguides in the directional coupler is the critical element regarding the fabrication. The resolution of the photolithography used (standard photolithography using a quartz/chromium mask, electron beam lithography, etc.) defines the minimum coupling gap. The fabrication of the gap depends mainly on the waveguide width and the etch depth in the gap. An example of a fabricated coupler is shown in Fig. 4.3. The etch depth in the gap is lower in this example than on the outer side of the coupler waveguides, which is due to the lower etch rate in the gap. The dry etching process is strongly dependent on the etch gases and conditions used and has to be modified if performed with other RIE systems to achieve similar results. Integrated optical devices require directional couplers to provide the desired power splitting ratio, independent of wavelength or polarization. In wavelength division multiplexing systems, where ring resonator add drop filters are deployed, it is necessary to achieve a constant splitting ratio for all used wavelength channels. It is often impossible to achieve broadband polarization-insensitive performance, especially in planar integrated devices, unless several design consideration are incorporated and tradeoffs taken into account as is explained in Sect. 3.7. A wavelength- and polarization-insensitive directional coupler configuration is demonstrated in Little 182 4 Building Blocks of Ring Resonator Devices Fig. 4.3 SEM photograph of the input region of a directional coupler, gap = 0.8 μm and Murphy (1997) and Murphy et al. (1999). Design rules towards polarization insensitive directional couplers employed in ring resonator filters are discussed and presented in Chin (2003). 4.1.2 Multimode Interference Couplers A multimode interference (MMI) coupler consists of a broad center waveguide which supports several modes depending on the width and the layer sequence of the waveguide (Fig. 4.4). The self-imaging principle is used in MMI couplers for realizing various coupler configurations including a 2 × 2 coupler to be used in ring resonator devices. Self-imaging is a property of multimode waveguides by which an input field profile is reproduced in single or multiple images at periodic intervals along the propagation direction of the guide (Soldano and Pennings 1995). Between these intervals, the input field is reproduced with only a fraction of the input intensity, divided symmetrically in the multimode section. A SEM photograph of the input region of a 2 ×2 MMI coupler is shown in Fig. 4.5. An atomic force microscope (AFM) photograph of the input region of an MMI coupler is shown in Fig. 4.6 (Rabus 2002). The gap between the two input waveguides is 2.4 μm. The main advantage of MMI couplers compared to directional couplers is the fabrication tolerance with respect to the splitting ratio which can be for example 3-dB in the case of 2 ×2 couplers used in ring resonators. If other coupling ratios Fig. 4.4 Top view of an MMI coupler 4.1 Couplers 183 Fig. 4.5 SEM photograph of the input region of a 2 ×2 coupler Fig. 4.6 AFM picture of the input region of an MMI coupler (Rabus 2002) are required, directional couplers are favored. The multimode section should support more than three modes to assure an appropriate interference signal of the input mode. Finite difference time domain or beam propagation tools (Weinert and Agrawal 1995) are needed to calculate the behavior of MMI couplers which are commercially available. The fundamental beat length of MMI is related to the waveguide parameters (step-index MMI section) by Soldano and Pennings (1995): Lπ = π 4n eff · w2 ∼ , = β0 − β1 3λ0 (4.8) 184 4 Building Blocks of Ring Resonator Devices where β 0 and β 1 are the propagation constants of the fundamental and first order lateral modes, respectively, λ0 is the wavelength, neff is the effective index and w is the width of the multimode section. The 3 dB length of MMI couplers can also be approximated by the formula given in van Roijen et al. (1994): L 3 dB = λ0 3 n eff · w2 ≈2 , 4 n eff0 − n eff1 λ0 (4.9) where λ0 is the wavelength, neff0 and neff1 are the effective indices of the fundamental and first order mode. The usage of short couplers with defined splitting ratio is essential in ring resonators for achieving a high FSR due to a short roundtrip length. One of the first fabricated MMI couplers on InP having the shortest length at that time of only 107 μm for a 3 dB coupler are demonstrated in Spiekman et al. (1994). The width of the MMI is only 9 μm. A ridge waveguide design is used with an InGaAsP core with a bandgap wavelength of 1.3 μm and a thickness of 600 nm. An InP cap having a thickness of 300 nm is grown on top. Extremely short InP–InGaAsP MMI 3-dB couplers with lengths between 15 and 50 μm are presented in Ma et al. (2000b). Ring resonators ideally require a tunable coupler in order to adjust the coupling factor to the roundtrip loss in the case of passive resonators and to realize specific filter characteristics in the case of multiple coupled ring resonators. MMI couplers with a tunable splitting ratio are demonstrated in Nagai et al. (1999), Leuthold and Joyner (2000, 2001) and Jiang et al. (2005). MMI couplers are usually fabricated in semiconductor materials which enable the realization of strong guiding waveguides. Recently MMI couplers are proposed using weak guiding structures (West and Honkanen 2005) and fabricated in polymer materials (Mule’ et al. 2004; Rabus et al. 2005b). 4.1.3 Y-Couplers Y-couplers are a well-known class of integrated optical devices and have been used in several integrated systems to guide and manipulate light. Quite a lot of research has been performed on digital optical switches (DOS) in polymers using cascaded Y-couplers to create integrated 1 × N splitters (Bernhard 2002; Hauffe 2002). An example of a Y-coupler is shown in the schematic in Fig. 4.7. This example of a Y-coupler comprises single mode waveguides for in- and out coupling with width w, a taper and a coupling region. The taper region is designed in such a way, that the width at the end is slightly less than 2 times the width of a single mode waveguide. This assures, that only the fundamental mode is allowed to propagate in the beginning of the taper and in the end into the two output waveguides and not the next higher mode which would cause additional losses, as it is not 4.1 Couplers 185 Fig. 4.7 Schematic of a symmetric Y-coupler supported by the geometry of the single mode waveguides. In the coupling region, both output waveguides have to be treated using coupled mode theory to describe their behavior. This region is of importance when it comes to design a symmetric Y-coupler with equal power splitting in both output arms. If the angle α is chosen too small, power from one arm is able to couple to the other one being the cause for a different splitting ratio than intended. On the other hand making the angle too large causes additional losses. Therefore, a tradeoff has to be found for realizing a specific Y-coupler. Usually S-bends are used to separate the output arms and realize a certain distance between them. Due to manufacturing tolerances like proximity effect and etching, a sharp branching angle is not achieved in most cases and a compromise has to be made to find the optimum angle. An example of a fabricated Y-coupler in polymers is shown in Fig. 4.8 (Rabus et al. 2005b). Y-couplers have found their way into ring resonators for example in ring lasers, where they have been specially designed to increase the output power. An example of an improved Y-junction splitter used in ring resonator lasers can be found in Burton et al. (1994). The design uses only rectangular sections which make it similar to an MMI coupler avoiding sharp tips at waveguide intersections, which are a challenge to fabricate. For more details on ring resonator lasers, see Sect. 5.6. Due to the fact that Y-couplers can be regarded as standard optical components which can be simulated Fig. 4.8 Polymer Y-coupler 186 4 Building Blocks of Ring Resonator Devices with several commercially available BPM and FDTD software, further treatment of these devices will not be given. 4.2 Bends Bends are inevitable building blocks of state-of-the-art integrated optical circuits and have therefore been always of interest in the optics community. One of the first papers dealing with the analysis of bends is described in Marcatili (1969a). Since then, many methods have been proposed and developed to describe the behavior of the mode field and lower the losses in bends for example, Neumann and Richter (1983), Bienstman et al. (2002), and Melloni et al. (2001). One method of describing a waveguide bend is to use a conformal transformation which is presented in Heiblum and Harris (1975). The curved waveguide is translated into an equivalent straight waveguide with a transformed index profile. By using a cylindrical coordinate system (x, ρ, φ), propagation of light in circularly curved waveguides can be described in terms of modal propagation (Fig. 4.9). A mode in such a structure is given by Smit et al. (1993): E Circ = Uγ (r )e±γφ φ . (4.10) This mode has as an equi-phase front which propagates in the angular direction φ. γ φ is regarded as a complex angular propagation constant and is described as: γφ = αφ + jβφ , (4.11) where α φ is the attenuation coefficient, this time in angular direction, and β φ is the real angular propagation constant in rad−1 . Fig. 4.9 Curved waveguide transferred to a straight waveguide using conformal transformation. Curved waveguide with real index profile (left). Equivalent straight waveguide with transformed index profile (right) 4.2 Bends 187 Using a conformal mapping technique (see also Chin and Ho 1998), the problem of solving the wave equation in cylindrical coordinates can be transformed to rectangular coordinates by performing the following steps (Heiblum and Harris 1975; Smit et al. 1993): u = Rt ln r Rt (4.12) with Rt a freely selectable reference radius. Equation (4.10) can then be written as ∂2 2 2 2 + {k n (u) − γ } Ut (u) = 0, t t ∂u 2 (4.13) where u n t (u) = n{r (u)}e Rt γt = γφ Rt (4.14) (4.15) u r (u) = Rt e Rt (4.16) The angular propagation and attenuation constants can now be derived using (4.15) as follows: βφ = βt Rt , (4.17) αφ = αt Rt . (4.18) The radiation loss can then be expressed by −α π φ = 10π αφ log10 e. Aφ = −20 log10 e 2 (4.19) With this transformation an ordinary straight waveguide problem is obtained, which can be solved with the effective index method by using a staircase approximation for the transformed index profile in the u-direction (Fig. 4.9 right). The index profile n(r) is transformed into an index profile nt (u). The shape of the transformed profile can be qualitatively understood by considering that the longer path length of the light travelling in the outside bend has to turn up in the straight waveguide problem as a slower phase velocity, hence the higher index there. The center of gravity of the mode profile in a curved waveguide moves outward, an effect that increases by decreasing the radius of the bend. 188 4 Building Blocks of Ring Resonator Devices An approximation can be made when Rt is chosen to be equal to the outer edge of the waveguide and u/Rt 1 in the vicinity of the waveguide, then r∼ = Rt + u, (4.20) which leads to a transformed index profile u ∼ . n t (u) = n(Rt + u) 1 + Rt (4.21) A simple method for estimating bend radii of deeply etched rib waveguides (Fig. 4.9) is presented in Pennings et al. (1991). This method can be used for rib waveguides, where the rib is etched completely through the guiding layer. The effective index method (EIM) is used in this reference to describe the rib waveguide by a one dimensional refractive index profile with an effective index nrib under the rib and an effective index of 1 next to the rib (air). This one dimensional refractive index profile can now be treated as a straight slab waveguide with a propagation constant of β = kn straight· (4.22) All modes with a refractive index nstraigth smaller than the refractive index of the substrate nsubstrate are treated as below the cut of wavelength and are lost into the substrate. The straight waveguide problem is solved again by applying the conformal transformation method as discussed before with the refractive index of the bend nbend related to the angular propagation constant γ by n bend = αφ Re(γφ ) = . kR kR (4.23) The imaginary part of the angular propagation has been neglected due to the high index contrast between the waveguide and the surrounding air, which leads to a strong confinement of the mode in the waveguide and results in low radiation losses in the bend. The radius R is defined as being the length up to the outer side of the waveguide bend. Using the cutoff condition R = Rco when nbend = nsubstrate and the approximation n straight − n bend = w 1 n rib 2 R (4.24) leads to the equation for the cutoff radius, which depends only on parameters of the straight waveguide Rco = w · n rib . 2(n straight − n bend ) (4.25) 4.2 Bends 189 Fig. 4.10 Architectures of waveguide bends The main cause for losses in bends is of course the bending losses themselves (4.19). One way to minimize the bending loss is by increasing the radius. This is of course limited when designing ring resonators with certain parameters and a specified filter performance. Therefore one way to reduce the bending loss is by changing the refractive index of the material on the outer side of the waveguide. This can also mean the complete removal of the material on the outer side of the waveguide and forming a trench. An analysis of this idea is presented in Neumann (1982b) and Seo and Chen (1996). Schematics of proposed waveguide geometries are shown in Fig. 4.10. Seo et al. not only suggested to use trenches on the outer side of the curved waveguide to reduce the bending losses, but analyzed also the slope of the rib with regard to the transition losses which can be lowered this way. Another type of loss which is especially important when it comes to the design of racetrack shaped ring resonators is the transition loss which occurs at the interface between a straight waveguide and a bend. One of the first publications dealing with the reduction of these transition losses is (Neumann 1982a). As described earlier, the center of the mode field in the curvature shifts with increasing radius to the outer side of the waveguide in the bend. This distance d of the mode shift in a waveguide having a width w1 can be described by the following equation: d= π 2 n 2eff w . λ2 R (4.26) One method of reducing the transition losses is therefore to apply an offset between the curved and the straight waveguide sections which is equal to a distance d. A schematic of a racetrack shaped ring resonator employing offsets at the respective interfaces is shown in Fig. 4.11. A fabricated racetrack shaped ring resonator in the material system GaAs–AlGaAs (Fig. 4.12) employing such offsets is presented in Van et al. (2001). Here, fabricated racetrack shaped ring resonators with offsets up to 0.08 μm are demonstrated. The parameters for the racetrack shaped ring resonators are a waveguide width of 0.52 μm, a coupling gap of 0.2 μm, an average bending radius of 4.7 μm, and straight-section length of 10.24 μm. The transmission from a straight to a curved waveguide for the case of rib channel waveguides is given by Subramaniam et al. (1997) 1 Note that w can either be the actual width of the waveguide or the width of the mode, depending on the type of waveguide used. 190 4 Building Blocks of Ring Resonator Devices Fig. 4.11 Schematic of a racetrack shaped ring resonator with offsets between the curved and straight waveguide junctions Fig. 4.12 Racetrack shaped ring resonator with lateral offsets between curved and straight waveguide sections Van et al. (2001) −d 2 2 d e 2w2 1 + (k·n·w) 2R TSC (d) = 4 w2 1 + (k·n·w) 2R 2 2 , (4.27) where w represents the mode width and n the effective refractive index of the rib in the center of the waveguide. Minimum transition loss is achieved when: (a) The amplitude distributions of the two modes are matched (b) The phase distributions are matched. Condition (b) is satisfied, condition (a) is a cause for the transition losses which can be evaluated using (4.27) or can be approximated by Neumann (1982a) αSC-losses = 4.343 d 2 w (dB) where w is either the width of the waveguide or the width of the mode. These transition losses can be lowered by choosing the appropriate offset, trench or different material with a lower refractive index on the outer side of the waveguide 4.2 Bends 191 in the bend and in addition selecting the right widths of both the straight and the bend waveguides (Smit et al. 1993). Bends are not only used as “connecting” elements in integrated optics, but can also serve themselves as polarization rotators. An analysis of polarization rotation in bends is presented in Lui et al. (1998) and Obayya et al. (2001). A compact polarization converter based on bends is demonstrated in van Dam et al. (1996). Polarization rotation can be of importance when designing ring resonator filters and depends on several influencing factors like type of material used, waveguide geometry and ring radius. 4.3 Spot Size Converters for Light in- and Outcoupling Spot size converters are used to reduce the fiber–chip coupling losses when single mode fibers are butt coupled to an integrated waveguide structure or to a laser diode. The efficiency of the spot size converter depends again on the type of material used for realizing the integrated waveguide based device which results in possible waveguide parameters. Therefore in choosing an appropriate material for the fabrication of a ring resonator filter for example and with it a waveguide geometry, already sets the boundary conditions for the spot size converter. It is therefore important to design a photonic device taking into account not only fabrication aspects, but also the connections to the outside world. An established way to realize a spot size converter is by incorporating tapered structures operating close to the mode cutoff, which expands their spot size area to enhance the optical coupling efficiency without deteriorating alignment tolerances. The use of these designs has improved the coupling efficiency and at the same time has enabled a more relaxed alignment tolerance of the fiber to the chip. Several taper designs have been demonstrated, such as lateral tapers (Kasaya et al. 1993), vertical tapers, or combinations of either lateral and vertical tapers (Yan et al. 2002) or waveguide configurations (Hamacher et al. 2000). An example of a spot size converter consisting of a lateral taper and a vertical coupling to a waveguide underneath is shown in Fig. 4.13. Here an approach is applied which relies on an adiabatic coupling between a strong confined waveguide mode and a weak waveguide mode in a guiding layer 1 μm beneath the actual waveguide. The rib of the waveguide is laterally tapered down from 2 to 0.5 μm forcing the light to couple between the two modes. For a better lateral confinement of the weakly guided mode a second rib is etched in the tapered region only. An example of the integration of this spot size converter with a ring resonator is shown in Fig. 4.14. A tradeoff between overall chip size and length of the taper region on both sides has to be found. A longer taper with a gradual enough taper slope will of course exhibit a lower loss. An optimization of compact lateral, vertical, and combined tapered spot size converters using the beam-propagation method is presented in Haxha et al. (2006). 192 4 Building Blocks of Ring Resonator Devices Fig. 4.13 Schematic of a spot size converter (Hamacher et al. 2000) Fig. 4.14 Ring resonator with integrated SOA and spot size converter 4.4 Gratings for Light in- and Outcoupling In integrated optics based devices, such as those here presented in this book, the optical coupling efficiency is a key parameter to optimize the final device performance. In order to decrease the insertion losses, several designs have ben proposed, especially to match the external laser output, normally in the form of single optical fibers, to the integrated optical waveguides in the device. Among the others, grating coupling has been demonstrated a very promising method to allow efficient optical coupling, now implementable thanks to the advanced technologies available. This is particular interesting when SOI or LNOI optical waveguides in microring resonators devices are considered: grating coupling provides high alignment tolerance without requiring cleavage and can be improved in coupling efficiency by inserting a reflectors under the buried oxide layer or silicon. It is clear that the more complex the final 4.4 Gratings for Light in- and Outcoupling 193 stuck structure is the more expensive it will be due to the need of implementing several process steps to integrate different layers together. For these reasons, the simplest way is always the most preferred one, not only because it is currently cheaper but because it results to be more controllable and reproducible. An example of a compact uniform grating structure without bottom reflector element or silicon overlay is provided in (Nambiar et al. 2018). In one step etching process they have achieved a relatively high efficiency. Nambiar et al. have in fact reported a theoretical CE over 75% at a wavelength of 1550 nm and a measured Coupling Efficiency (CE) of 47.2% at 1562 nm was obtained for a 12.4 × 12-μm2 grating coupler on silicon-on-insulator (SOI). The sketch of the device that they have implemented is reported in Fig. 4.15. In the case of close vertical coupling between the standard optical fiber and the wire waveguide, an adiabatic taper has been designed by these authors to adjust the optical mode (Nambiar et al. 2018). The final structure built is showed in Fig. 4.16, for both TE and TM fundamental mode coupling, together with the simulated and characterization results of the Coupling efficiency in Fig. 4.17. Nambiar et al. (2018) has provided also a detailed summary of various Silicon-onInsulator (SOI) based fiber to chip grating couplers in Table 4.1 that include uniform as well as non-uniform (apodized) designs. Various Adiabatic and Non-Adiabatic Tapers on SOI proposed in literature. Features and performances are listed in Table 4.2. Performance comparison of various SOI based polarization splitting grating couplers (PSGCs). Columns 3 and 4 pertain to the polarization state of the coupled waveguide modes are reported in Table 4.3. PDL denotes the minimum polarization dependent loss. Fig. 4.15 a Three dimensional (3-D) schematic of a Silicon-on-Insulator (SOI) based fiber to chip surface grating coupler with adiabatic tapers; b k-space representation of the grating phase matching condition k fr nsup corresponds propagation constant of superstrate and k fr nsup of substrate and G is the grating reciprocal lattice. Reprinted with permission under CC license from Nambiar et al. (2018) 194 4 Building Blocks of Ring Resonator Devices Fig. 4.16 Top down SEM image fabricated of focusing gratings for a transverse electric (TE); b transverse magnetic (TM) fundamental mode coupling (Nambiar et al. 2018) Fig. 4.17 Simulated and characterization results for a TE gratings with 640 nm period. Experimental results are for 24 μm focal length and b TM couplers with 980 nm period with optimum focal length of gratings used in experiments being 20 μm. Reprinted with permission under CC license from Nambiar et al. (2018) In the previous chapters, simulation, fabrication, and building blocks of ring resonator devices have been described. The following chapter presents applications of ring resonator devices fabricated in different material systems using different architectures and building blocks. 4.4 Gratings for Light in- and Outcoupling 195 Table 4.1 Summary of various silicon-on-insulator (SOI) based fiber to chip grating couplers (Nambiar et al. 2018) SOI coupler Max CE (−dB) Bandwidth 3 dB (nm) λmax (m) Uniform (U)/apodized (A) [26] 3 58 1.31 [27] 2 50 1.302 [28] 1.9 23 (1 dB) [29] 1.05 50 [11] 1.6 [10] 1.6 [15] Fiber tilt angle (θ) Etch type Bottom reflector U 12 Shallow N A 17 Double-etch N 1.31 A 10 Double-etch N 1.551 A 8 Shallow N 63 1.515 U 10 Shallow Y 60 1.54 U – Shallow Y 1.6 80 1.53 U 13 Shallow N [17] 1.9 43 (1 dB) 1.524 A 15 Shallow N [18] 1.2 45 1.533 A 10 Shallow N [13] 1.08 42 (1 dB) 1.551 U 9 Shallow Y [13] 0.62 40 (1 dB) 1.531 A 11 Shallow Y [30] 2.5 – 1.325 A 33 Full N [31] 3.2 36 (1 dB) 1.59 A −31 Full N [19] 2.16 64 1.543 A 27 Full N [25] 0.58 71 1.56 A 13 Full Y Full etch signifies SWG couplers. CE refers to the coupling efficiency Reprinted with permission under CC license from Nambiar et al. (2018). https://doi.org/10.3390/ app8071142 Table 4.2 Summary of the features o silicon-on-insulator (SOI) based fiber to chip grating couplers, depending on the taper design (Nambiar et al. 2018) Taper designs Adiabatic taper Linear [39] Exponential [40] Length (m) Initial width (m)–final width (m) Coupling efficiency theoretical Remarks 150–500 10–0.5 65–99% 200 10–0.5 70 Tradeoff between the taper length and coupling efficiency due to the adiabatic transition (continued) 196 4 Building Blocks of Ring Resonator Devices Table 4.2 (continued) Taper designs Non-adiabatic Length (m) Initial width (m)–final width (m) Coupling efficiency theoretical Parabolic [41] 200 10–0.5 80 Efficient adiabatic [42] 120 10–0.5 98.3 Complex non-adiabatic [43] 15.4 10–0.56 70 Lens-assisted [44] 20 10–0.45 −1 dB (TE) −5 dB (TM) Expt. Discontinuous [45] – 10–0.45 90% Compact taper [46–48] 15 10–0.5 92% Remarks Complexity in Fabrication Robust to fabrication errors, broadband, efficient Reprinted with permission under CC license from Nambiar et al. (2018). https://doi.org/10.3390/ app8071142 Table 4.3 Performance comparison of various SOI based polarization splitting grating couplers (PSGCs) (Nambiar et al. 2018) SOI coupler Max CE (−dB) Polarization 1 (λ1 ) (m) Polarization 2 (λ2 ) (m) Type (1D, 2D) focusing/non-focusing PDL (−dB) [50] 2 TE0 (1.559) TM0 (1.551) 1D non-focusing High [51] 5.8 TE0 (1.54) TE0 (1.535) 2D non-focusing 0.2 [53] 5.6 TE0 (1.54) TE0 (1.53) 2D focusing 0.4 [54] 3.2 TE0 (1.492) TE0 (1.492) 2D focusing 0 Reprinted with permission under CC license from Nambiar et al. (2018). https://doi.org/10.3390/ app8071142 References Bernhard, W.: Digitale thermo-optische Schalter mit integrierten Modulatoren zur Erhoehung der Uebersprechdaempfung. 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Lett. 7, 529–531 (1995) West, B.R., Honkanen, S.: MMI devices with weak guiding designed in three dimensions using a genetic algorithm. Opt. Express 12, 2716–2722 (2005) Yan, X., Masanovic, M.L., Skogen, E.J., Hu, Z., Blumenthal, D.J., Coldren, L.A.: Optical mode converter integration with InP-InGaAsP active and passive waveguides using a single regrowth process. IEEE Photonics Technol. Lett. 14, 1249–1251 (2002) Chapter 5 Devices This chapter is entirely devoted to highlighting the various applications of ring resonator devices developed to date using examples presented by the ring resonator community. Some ring resonators have already been described in Chap. 3, therefore only performance parameters like the free spectral range (FSR), the full width at half maximum (FWHM), the quality factor Q and the finesse F will be given in this chapter for selected devices. Ring resonators have been primarily investigated to be implemented as optical add–drop filters in optical networks. Several optical filter designs have been proposed and realized in semiconductors and polymers, purely passive devices, ring resonators with integrated gain sections and devices made out of active material. Optical filters need to be tunable in order to be deployed in optical networks. This fact is even more important, when it comes to ring resonators, as the resonances of the ring resonator filter have to be aligned exactly to the required optical channel. Wavelength tuning and center wavelength trimming methods will be explained in this chapter. Ring resonators can be used for flexible dispersion compensation and several fabricated devices will be explained. In wavelength division multiplexing (WDM) applications, a square spectrum response is desirable. Periodic multiplexers and demultiplexers, which have a flat passband and a wide rejection region, can be realized integrating a modified Mach–Zehnder interferometer (MZI) with a ring resonator. The application of ring resonators as lasers has been demonstrated already some time ago. It has gained attention again recently with the fact that combining ring resonators can enhance the tunability of ring lasers. Novel concepts have been proposed and realized using all active ring lasers and passive ring resonator coupled configurations with integrated semiconductor optical amplifiers (SOAs). Due to the advancing state of the art in fabrication technology, ring resonators with very small radii have been built which opens up the possibility to use these elements as modulators and in optical signal processing systems as logic gates and as switching devices. © Springer Nature Switzerland AG 2020 D. G. Rabus and C. Sada, Integrated Ring Resonators, Springer Series in Optical Sciences 127, https://doi.org/10.1007/978-3-030-60131-7_5 199 200 5 Devices As equally important as creating a wavelength with ring lasers and filtering out a specific wavelength, wavelength conversion has been found to be possible using ring resonator devices. Finally as a new technology trend is emerging which is currently known as biophotonics, ring resonators have again found their way into this new field in the form of sensors. 5.1 Filters Ring resonator filters have been fabricated in many material systems as is described in Chap. 3. State-of-the-art manufacturing technologies have enabled the demonstration of filter characteristics and parameters useful for optical networks. The advantages of using ring resonator filters are obvious. Ring resonators can be integrated with other components such as lasers or SOAs to form complex photonic integrated circuits. Ring resonators do not require facets or gratings for optical feedback and can have very small dimensions which enables the realization of large scale photonic integrated circuits. Several examples will be presented in this chapter highlighting various results achieved for ring resonator filters with different geometries and materials. 5.1.1 Passive Devices Single Ring Filters One of the first passive single ring resonator add–drop filter with integrated throughput and drop–port is presented in Haavisto and Pajer (1980). A thin film of PMMA is used to fabricate the waveguides. The radius of the ring is 4.5 cm. The waveguide widths are 10 μm, with a 17.5 μm separation from center to center. A coupling strength of 2% is achieved. Prism coupling is used to couple in and out of the bus waveguides. A finesse of 16 is measured. The loss in the ring is found to be 0.05 dB cm−1 , which includes coupling and radiation losses. Due to the large circumference of the ring, these ring resonator filters are limited in their use as channel dropping filters. Improvement of fabrication methods and the coming up of new material systems (for example III–Vs) has made it possible to fabricate ring resonators with radii far below 100 μm. One of these first ring resonators is demonstrated in Rafizadeh et al. (1997b). Ring and disk resonators in the material system AlGaAs/GaAs with diameters of 10.5 μm (Fig. 5.1) and 20.5 μm are presented. An FSR of 21.6 nm and an FWHM of 0.18 nm is measured for the disk resonator with a diameter of 10.5 μm, leading to a finesse of 120, and a cavity quality factor Q greater than 8500. In the case of the ring resonator with a diameter of 10.5 μm, an FSR of 20.6 nm and an FWHM of 0.43 nm is measured, leading to a finesse of 5.1 Filters 201 Fig. 5.1 SEM images of a 10.5-mm-diameter a disk and b ring (Rafizadeh et al. 1997b) 48 and a Q-factor greater than 3500. The FSR and the FWHM for the ring and disk resonators with a diameter of 20.5 μm are 10.2 nm/10.7 nm and 0.54 nm/0.12 nm, respectively. The FWHM is broader in the case of the ring resonator due to the loss caused by the additional sidewall. Similar ring resonators in glass, vertically coupled to the bus waveguides with radii of 10 μm are presented in Little et al. (1999). An FSR of 20 nm and an FWHM of 5.2 nm are measured, leading to a finesse of 4 and a quality factor of 300. The low Q factor compared to the high Q factor for the similar AlGaAs/GaAs is due to a stronger coupling, leading to a broader FWHM and therefore to a lower Q factor. The transmission spectrum from both the throughput and the drop–port is shown in Fig. 5.2. These ring resonators are used as building blocks in an 8 channel add–drop filter (Chu et al. 1999c). The ring resonators are connected in parallel to form a multichannel add–drop filter. Each ring resonator in the device has a different radius and thus a different resonance wavelength. In the fabricated device, the first ring resonator has a radius of 10.35 μm, while the remaining ring resonators decrease in radius by increments of 50 nm. The parallel drop–port waveguides are separated by 250 μm. A schematic of the 8-channel ring resonator add–drop filter is depicted in Fig. 5.3. The transmission spectrum of the eight channel add–drop filter is polarization dependent. The FWHMs of the resonances for TE and TM polarization, from shortest to longest wavelengths, are 0.53, 0.63, 0.64, 0.71, and 0.92, 1, 1.06, 1.16 nm, respectively, leading to Q factors of 2500 and 1500. The average FSRs of the array is 20.1 nm and 20.2 nm for TE and TM, respectively. A junction induced crosstalk lower than −30 dB is achieved. The channel spacing achieved with this architecture is approximately 5.7 nm. The channel spacing can be adjusted to the required parameter by either changing the ring radius or the width of the waveguide, which results in a different propagation constant. 202 5 Devices Fig. 5.2 TE polarized wavelength response of a 10 μm radius ring resonator (Little et al. 1999) Fig. 5.3 8-Channel add–drop filter Vertically coupled ring resonators have not only been used in a parallel cascade to form a channel dropping filter, but have also been used in a 2 × 2 cross grid array for crosstalk reduction and spectrum cleanup in Chu et al. (1999a). A schematic of the 2 × 2 array consisting of three ring resonators is shown in Fig. 5.4. The three ring resonators have the same parameters and therefore filter out the same wavelength. Resonator 1 is the first filter along the input bus waveguide. Resonator 2 having the same resonance wavelength as resonator 1 sends the filtered wavelength to the drop–port which increases the out-of-band signal rejection. This ring resonator configuration corresponds to a double ring resonator leading to a steeper roll off of the filter spectrum and consequently to a larger out-of-band rejection. Resonator 2 therefore, cleans up the drop–port spectrum. Signal power at the resonance wavelength that is not completely filtered out by resonator 1 is filtered out a second time by resonator 3. Resonator 3 therefore, cleans up the throughput spectrum. The add port which does not have a path to the drop–port is cross connected to the input and throughput bus waveguide by resonator 3. 5.1 Filters 203 Fig. 5.4 2 × 2 ring resonator add–drop node Finally, the vertically coupled glass ring resonators have been used to realize an 8 × 8 cross grid array (Little et al. 2000). A photograph of the array is shown in Fig. 5.5. The height of the waveguide in the ring resonators is 1.5 μm, and the waveguide widths vary from 1 to 1.7 μm in increments of 100 nm. The ring resonators are identical along upward directed diagonals in the array. The spacing between the bus waveguides is 250 μm. Vertically coupled ring resonators consisting of a dielectric material core (Ta2 O5 – SiO2 compound glass with n = 1.8, or SiN with n = 2) and an air cladding have been proposed, designed and fabricated by the group of Kokubun. A summary of the work can be found in Kokubun (2005). Ring resonators with radii between 10 and 20 μm, resulting in an FSR of 10–25 nm and an FWHM 0.1–1.0 nm have been Fig. 5.5 Photograph of a portion of the 8 × 8 cross-grid vertically coupled glass ring resonator array (Little et al. 2000) 204 5 Devices demonstrated. These device parameters lead to high Q values between 1500 and 15,000. Kokubun’s group have pushed ring resonator technology not only in terms of ring size, but have also demonstrated polarization insensitive and tunable (center wavelength tuning and resonance tuning) ring resonators which are addressed in the relevant chapters of this book. Laterally coupled ring resonators and vertically coupled disk resonators, with PMMA cladding and without cladding have been designed and realized in Si3 N4 on SiO2 in Klunder et al. (2001). A finesse of 136 has been achieved for a laterally coupled ring resonator without cladding and with a radius of 25 μm with a coupling gap of 750 nm. A finesse of 61 has been measured for a ring resonator with PMMA cladding. TE polarized light is used for the characterization of the devices at a wavelength of 1.55 μm. Vertically coupled disk resonators with a radius of 15 μm have been fabricated. The vertically coupled disk resonators are characterized using a wavelength of 640 nm. An FSR of 2.2 nm is measured which results in a finesse of 31. The finesse is limited by the linewidth of the laser used for characterizing the devices. A detailed analysis of the device performance of laterally coupled ring resonators in the same material system is presented by the group in Klunder et al. (2003). Here ring resonators with coupling gaps of 0.5 (not completely open, due to fabrication imperfections), 0.75 and 1 μm have been fabricated and characterized. A photograph of a ring resonator with a coupling gap of 0.75 μm is shown in Fig. 5.6. An FSR of 8 nm at a wavelength of 1530 nm and a finesse of 120 are obtained for a ring resonator with a coupling gap of 0.75 μm and air cladding. A finesse of 22 is measured for the resonator with a coupling gap of 0.5 μm with air cladding. The values for the finesse of ring resonators with PMMA cladding are 61 and 25, respectively. As has been mentioned in Chap. 3, recently several groups have demonstrated ring resonators not only in silicon, but also in GaAs and InP. One of the first racetrack shaped laterally coupled ring resonators in the material system AlGaAs with a cavity length of 31 μm (length of the straight sections is 6 and 4 μm) is presented in Chin et al. (1999). A photograph of a racetrack shaped ring resonator is shown in Fig. 5.7. Fig. 5.6 Laterally coupled ring resonator in SiON with a radius of 25 μm and a coupling gap of 0.75 μm Klunder et al. (2003) 5.1 Filters 205 Fig. 5.7 Racetrack shaped ring resonator Chin et al. (1999) A gap between the bus waveguides and the racetrack of 200 nm is used. An FSR of 20 nm and an FWHM of 1 nm is achieved in the case of the 6 μm long straight sections, leading to a finesse of 20. An FWHM of 0.2 nm and a finesse of 100 are obtained in the case of the 4 μm long straight sections. The racetrack shaped ring resonators are surrounded by etched trenches which are 2.5 μm deep and 1 μm wide. The waveguide width is 0.4 μm and is tapered to 2 μm at the facets for easier fiber chip coupling. Disk resonators with diameters of 5 and 10 μm in the material system GaInAsP are presented in Ma et al. (2000). The disk resonators are vertically coupled using polymer (BCB) wafer bonding. The measured FSR of the disk resonators is nearly the same as for the devices described in this chapter, namely 38 nm for the disk with a diameter of 5 μm and 21 nm/20 nm for the disk with a diameter of 10 μm. The two values for the FSR for the 10 μm disk are due to the polarization dependence in this disk which is also visible in the transmission spectrum having two sets of resonance peaks. The FWHM is, as expected, therefore also polarization dependent which leads to values of 0.25 and 0.22 nm. In the case of the 5 μm disk, the FWHM is measured to be 0.6 nm. Vertically coupled disk resonators also in the material system GaInAsP fabricated by wafer bonding with radii ranging from 4 to 12 μm are presented in Dapkus et al. (2001) and Djordjev (2002). The parameters for a disk with radius of 12 μm are: an FSR of 10 nm, an FWHM of 0.22 nm leading to a Q factor of more than 7000. The details of the fabrication method have been described in Chap. 3. Photographs of bus waveguides and a disk resonator are shown in Figs. 5.8 and 5.9. One of the smallest racetrack shaped ring resonator notch filters in InP is demonstrated in Grover et al. (2003). A radius of 2.25 μm is realized. The straight waveguides have a length of 10 μm. An FSR of 19 nm at a wavelength of 1550 nm is measured. A photograph of a ring resonator notch filter is shown in Fig. 5.10. The values for the finesse and the Q factor are 6 and 500. A transmission spectrum of a notch filter is shown in Fig. 5.11. 206 5 Devices Fig. 5.8 Bus waveguides at the bonded interface and the remaining transparent InP layer after the etch of the microdisk mesa Djordjev (2002) Fig. 5.9 A smooth 2.3 μm deep microdisk mesa formed by CH4 based RIE etch. The bus waveguides are below the remaining thin membrane of InP Djordjev (2002) A racetrack shaped ring resonator notch filter employing multimode interference couplers is presented in Rabus and Hamacher (2001). The curved sections have a rather large radius of 100 μm when compared to the previous examples. The length of the used MMI coupler is 150 μm. A photograph of a ring resonator and the transmission spectrum are shown in Figs. 5.12 and 5.13. An FSR of 0.8 nm (corresponding to 100 GHz in the frequency domain at a wavelength of 1.55 μm) and a finesse of 6 are measured. Single ring resonator notch or add–drop filters have been studied extensively in the past and have been realized in major material systems as was demonstrated in this section. The use of single ring resonator devices as filters in optical networks is limited by the Lorentzian like function of the transfer function. Filters employed in optical networks require a rectangular, box-like passband shape. Multiple coupled ring resonator devices fulfill this request and have been fabricated in several material systems. 5.1 Filters Fig. 5.10 One of the smallest ring resonator notch filters in InP Grover et al. (2003) Fig. 5.11 Spectral behavior of InP racetrack shaped ring resonator notch filter. The solid line is experimental data, and the dashed line is a curve-fit Grover et al. (2003) 207 208 5 Devices Fig. 5.12 MMI coupled racetrack shaped ring resonators Fig. 5.13 Transmission spectrum of an MMI coupled racetrack shaped ring resonator with a radius of 100 μm Double Ring Filters One of the first integrated double ring resonator filters in silicon which is also used in a frequency-shift keying (FSK) optical transmission experiment is presented in Oda et al. (1994). The group had previously demonstrated a double ring resonator with an overall FSR of 40 GHz in Oda et al. (1991). In Oda et al. (1994) a double ring resonator consisting of ring resonators with different radii is used. The use of two ring resonators with different radius (3.33 and 3.82 mm in this case) opens up the possibility to increase the FSR [see (2.77)]. The FSRs of the ring resonators are 14.29 and 12.50 GHz at a wavelength of 1550 nm, leading to an overall FSR of 100 GHz or 0.8 nm. The finesse achieved is 200 for this configuration. A 10 GHz spaced, 8-channel, 622 MB s−1 FSK direct detection distribution experiment over 40 km is demonstrated using this double ring resonator configuration. A similar double ring resonator consisting again of two ring resonators with different radius is presented by the same group in Suzuki et al. (1995). The double ring resonators consist of two ring resonators with FSR’s of 12.5 and 14.29 GHz, whose ring radii are 1.75 and 2.0 mm, respectively. The designed overall achieved FSR is again 100 GHz (98 GHz measured). The finesse is 138. In these two ring resonator experiments thin film heaters are integrated to be able to match the resonances of the two rings. Matching 5.1 Filters 209 of the resonances in multiple coupled ring resonators is of utmost importance to achieve an optimum device performance and to realize the designed filter response. The tuning of the resonances and the center wavelength of ring resonator devices will be addressed in Sect. 5.2. A double ring resonator where the ring resonators and the bus waveguides are coupled to one another by multimode interference couplers is presented in Rabus and Hamacher (2001). The radius of the curved sections is 100 μm. The length pf the MMI coupler is 150 μm, leading to an FSR of 0.8 nm at a wavelength of 1550 nm. A photograph of an MMI coupled double ring resonator is shown in Fig. 5.14. Vertically coupled double ring resonators in the material system Ta2 O5 –SiO2 are presented in Kokubun et al. (2002). Double ring resonators with a finesse of 39.8, an FSR of 16.7 nm and an FWHM of 0.42 nm have been designed, fabricated and characterized. Due to the double ring resonator structure, a box-like filter response is obtained. The design and characterization of a polarization independent double ring resonator filter with a designed FSR of 50 GHz (47.6 GHz measured) at a wavelength of 1550 nm by use of SiOx Ny technology is presented in Melloni et al. (2003a). The photograph of a double ring resonator is shown in Fig. 5.15. The coupling between the ring resonators is realized by directional couplers with coupling coefficients of 0.4, 0.28, and 0.4 for realizing a Butterworth type filter response. A 15 dB extinction ratio and a bandwidth at −1 dB of 7.4 GHz are measured. The transmission spectrum of a double ring resonator filter is shown in Fig. 5.16. Double ring resonator filters are a first step to enable the realization of box-like filter functions. Using double ring resonators as was demonstrated by the examples in this chapter also makes enlargement of the FSR possible. In order to improve the roll-off and out-of-band rejection, multiple coupled ring resonator filters are required. Fig. 5.14 MMI coupled double ring resonator 210 5 Devices Fig. 5.15 Photograph of a double ring resonator filter Melloni et al. (2003a) Fig. 5.16 Drop–port TE (solid curves) and TM (dashed curves) measured spectral responses of the double-ring filter. a Response over a 4-nm span and b detail of the response centered at 1551.2 nm. The dotted curve in (b) is the theoretical response Melloni et al. (2003a) Multiple Coupled Ring Filters Serially coupled, racetrack shaped, AlGaAs–GaAs triple ring resonators with radii of 4.5 μm and straight sections with lengths between 0 and 10 μm are demonstrated in Hryniewicz et al. (2000). A photograph of a triple ring resonator is shown in Fig. 5.17. The waveguide width, bus waveguide–ring resonator gap and inter ring resonator coupling gap is between 0.18 and 0.32 μm. The box-like filter response of a triple ring resonator is shown in Fig. 5.18. Parallel cascaded third- and fifth-order disk resonators in the material system GaInAsP/InP are presented in Ma et al. (2001). Photographs of the realized devices are shown in Fig. 5.19. The disks have diameters of 10 μm and are only coupled to the bus waveguides and not to each other. The coupling gap between the bus waveguide and the disk resonator is about 0.15 μm. The distance between two adjacent resonators is 23.85 μm, leading to a π /2 phase shift. The chosen distance between the resonators introduces in-phase 5.1 Filters 211 Fig. 5.17 Serially coupled triple ring resonator Hryniewicz et al. (2000) Fig. 5.18 Transmission spectrum at drop–port of triple resonator filter Hryniewicz et al. (2000) responses among the parallel cascaded disk resonators. A box like filter response is obtained due to the constructive interference formed at the drop–port which can be seen in the spectral response of a fifth-order disk filter in the measurement of the drop–port in Fig. 5.20. The FSR of the fifth-order filter is about 20 nm and the FWHM is approximately 3.5 nm. Parallel, vertically coupled triple ring resonators in the material systems GaAs– AlGaAs and GaInAsP–InP are demonstrated in Grover et al. (2002). A photograph of a triple ring resonator is shown in Fig. 5.21. The width of the single mode waveguides is 0.8 μm. The waveguides are tapered to a width of 2 μm at the facets to improve fiber chip coupling. The radius of the rings is 9.55 μm. The distance between the rings is chosen to be 20 μm (center-to-center). The achieved overall FSR of the triple ring resonator is 34 nm. The transmission spectrum of the GaAs–AlGaAs ring resonator is shown in Fig. 5.22. 212 Fig. 5.19 Photograph of third- and fifth-order disk resonators Ma et al. (2001) Fig. 5.20 Measured filter responses of fifth-order cascaded microdisk resonator filter for TM polarization Ma et al. (2001) Fig. 5.21 Photograph of a vertically coupled triple ring resonator filter. The ring resonators are on the lower level Grover et al. (2002) 5 Devices 5.1 Filters 213 Fig. 5.22 Response of the drop–port of a parallel, vertically coupled triple ring resonator Grover et al. (2002) The increase in the FSR in the case of the third-order ring resonator filter compared to a single ring resonator device is due to the Vernier effect (see Sect. 2.2.2). The cavities which interfere with one another are each of the ring resonators and part of the ring resonators with the bus waveguides. Fabrication tolerances can introduce an unwanted Vernier effect also and have an influence on the device performance. A difference in the radius of the rings of 0.04% is reported for this device. Vertically, serially coupled triple ring resonators are presented in Yanagase et al. (2002). The ring resonators are fabricated in the material system Ta2 O5 –SiO2 . A photograph of a triple ring resonator is shown in Fig. 5.23. The bus waveguides and ring resonator 2 are in the lower layer and ring resonators 1 and 3 are located in the upper layer. The coupling strength between the resonators and the resonators with the bus waveguides is controlled by the thickness of the buffer layer. This is one of the advantages of using a vertically coupled ring resonator configuration. One triple ring resonator configuration presented by the authors has the following parameters: the radius of ring resonator 1 and 3 is 22.78 μm resulting in an FSR of 10 nm, the radius of ring resonator 2 is 39.32 μm leading to an FSR of 6 nm. The measured overall FSR expanded to 25.8 nm (theoretical value: 30 nm), which is larger than the FSR of each of the ring resonators. In determining the value for the overall FSR, one has to take into account different values for the propagation constant in the buried ring resonator and the ring resonators on top. A transmission spectrum of the response of the drop–port of a single resonance is shown in Fig. 5.24. The mentioned shape factor is defined here as the width of the bandwidth at −1 dB divided by the width of the bandwidth at −10 dB. 214 5 Devices Fig. 5.23 Vertically coupled triple ring resonator (Yanagase et al. 2002) Fig. 5.24 Measured filter response of a triple ring resonator with radii of 28.52 μm for resonators 1 and 3 and 39.32 μm for resonator 2 (Yanagase et al. 2002) One of the first and so far only demonstration of 6 and 11 serially coupled ring resonator filters using the material HydexTM1 which is a glass based material, is presented in Little et al. (2004). The ring resonators are laterally coupled to each other. The outer rings are vertically coupled to the bus waveguides. A photograph of a serially coupled sixth-order ring resonator is shown in Fig. 5.25. The width and thickness of the cores of the waveguides are approximately 1.5 μm. The vertical gap 1 See www.nomadics.com for more information. 5.1 Filters 215 Fig. 5.25 Example of a sixth-order ring resonator filter fabricated with 17% index contrast Hydex Little et al. (2004) between the bus waveguides and the outer ring resonators varies from 200 to over 1000 nm depending on the desired filter linewidth. The gaps between the laterally coupled ring resonators vary from 500 to 1400 nm depending again on the application. The drop–port response of first-, third-, and 11th-order ring resonator filters is shown in Fig. 5.26. Filters with high quality factor and large out of band rejecFig. 5.26 Measured response for first-, third-, and 11th-order ring resonator filters similar in fabrication to the device shown in Fig. 5.25. The responses have been normalized to their 3-dB bandwidths. The dashed curve is the theoretical fit to the 11th-order filter Little et al. (2004) 216 5 Devices tion have been realized. As can be seen, maximal flatness of the filters response is obtained by increasing the number of coupled ring resonators. Polarization independent resonances can be achieved by this technology by choosing the correct aspect ratio for the waveguides. The examples in this section have demonstrated that fabrication methods of ring resonator filters in several material systems are available for realizing devices with adjustable performance parameters suitable for implementation in future all-optical networks. In order to increase the device functionality of ring resonator filters, gain can be introduced into the cavity. Examples of devices with gain inside the ring resonator are presented in the following section. 5.1.2 Devices with Gain Section Ring resonator lasers have of course been around quite some time and examples will be presented in Sect. 5.6. This chapter focuses on ring resonator filters with integrated gain sections for realizing improved and loss reduced filter functions. One of the first devices with gain inside the resonator is presented in Djordjev et al. (2002b). Disk resonators with gain region, vertically coupled to the bus waveguides are used to demonstrate gain trimming of the resonant response. The fabrication of the devices has been described in Sect. 3.4.7. The response from the throughput port of a disk with a radius of 10 μm is shown in Fig. 5.27. The device has an FSR of 10 nm. A quality factor of 5700 and a finesse of 40 are measured. The coupling coefficient is estimated to be 3.6%. As can be seen in Fig. 5.27 it is possible with active devices to adjust the response of the disk resonator. When the applied current supplies enough gain inside the resonator to equal the Fig. 5.27 Gain trimming of the transmission response of a disk with radius 10 μm Djordjev et al. (2002b) 5.1 Filters 217 internal losses, the resonator becomes lossless and the obtained filter spectrum is ideal. Racetrack shaped ring resonators with integrated SOAs are presented in Rabus et al. (2002c). A minimum radius of 100 μm which is one magnitude larger than the ones presented in the previous paragraph is used. Single, double and triple serially coupled ring resonator add–drop filters with integrated SOAs are demonstrated. The fabrication details and the layer sequence of the devices have been described in Sect. 3.4.7. A photograph of a serially coupled triple ring resonator with SOAs is shown in Fig. 5.28. The output port is transferred to the right side of the chip via another half circle for a better accessibility when measuring the transfer response. The devices realized have FSRs of 12.5, 25, and 50 GHz at a wavelength of 1550 nm. The lossless filter response of a single ring resonator with an FSR of 25 GHz is shown in Fig. 5.29. The radius of the ring resonator is 363 μm and the length of the SOA is 400 μm. The length of the couplers is 200 μm (gap = 0.9 μm), which results in power coupling factors of 0.17. The y-axis has been normalized to the fiber–chip coupling loss. The on–off ratio is measured to be more than 22 dB. The FWHM is determined to be 0.012 nm. The finesse of the ring resonator is F = 17, leading to a Q factor of more than 130,000. The filter response is measured by sweeping the external cavity laser (ECL) signal with a resolution of 4 pm. The SOA is operated at a current of 90 mA Fig. 5.28 Serially coupled triple ring resonator with integrated SOAs 218 5 Devices Fig. 5.29 Single ring resonator with two straight input/output waveguides and directional couplers (length = 200 μm, gap = 0.9 μm), r = 363 μm, gain length = 400 μm, FSR = 25 GHz which provides lossless operation of the ring resonator as is seen in the transmission spectrum. The response from the drop–port on resonance is as high as the response from the throughput port off-resonance. The response from the drop–port of a double ring resonator with integrated SOAs is shown in Fig. 5.30. The double ring resonator is made up of two straight input/output waveguides, two 3 dB MMI couplers for the outer couplers (length = 150 μm, width = 6 μm) and a directional coupler in the center (length = 150 μm, gap = 1 μm), r = 347 μm, SOA length = 500 μm which results in an FSR of 25 GHz. The driving current for each SOA is 50 mA. The shape factor which is defined in this case as L 1 divided by L 2 , achieved for this configuration is 0.5. The FWHM is measured to be 0.04 nm, leading to a finesse of 5. The drop–port response of a triple serially coupled ring resonator is shown in Fig. 5.31. The measured triple ring resonator has a radius of 323 μm. The length of an SOA is 400 μm. The length of the couplers is 325 μm with a gap of 0.8 μm for the outer couplers and 1 μm for the couplers in the center. The achieved FSR is 25 GHz. The driving current for each of the three SOAs is 50 mA. The steep roll-off can be seen from the measurement. The two ripples result from a slight resonance mismatch between the three ring resonators. The on–off ratio for the fabricated triple ring resonator is more than 18 dB including the ripples. Ring resonators integrated with SOAs have not only been fabricated in the serially coupled configuration, but have also been demonstrated in the parallel architecture. The photograph of a parallel coupled triple ring resonator is shown in Fig. 5.32. 5.1 Filters 219 Fig. 5.30 Drop–port response from a double ring resonator with two straight input/output waveguides, two MMI couplers and a directional coupler (length = 150 μm, gap = 1 μm), r = 347 μm, SOA length = 500 μm, FSR = 25 GHz Fig. 5.31 Filter response of the drop–port of a triple ring resonator with r = 323 μm, length of the couplers = 325 μm, gain length = 400 μm, FSR = 25 GHz 220 5 Devices Fig. 5.32 Photograph of a fabricated triple coupled ring resonator in a parallel configuration The ring resonators have a radius of 117 μm, a coupler length of 200 μm (gap = 0.9 μm) and a gain length of 300 μm. An FSR of 50 GHz is realized. The driving current for each SOA is 50 mA. The distance between the resonators was chosen to be equal to half of the circumference of a single ring resonator. The filter characteristic of the drop–port of the parallel, triple coupled ring resonator is shown in Fig. 5.33. The ripples are due to a slight resonance mismatch due to fabrication tolerances. The resonances can be matched when integrated platinum resistors (see Sect. 5.2) in the ring resonators or adjusted SOA currents are used. Another example of the integration of ring resonators with SOAs is presented in Menon et al. (2004). In this example, a vertically stacked asymmetric twin waveguide structure is used to integrate the SOA with the passive waveguides. The ring resonator is racetrack shaped and is designed as a notch filter with only one input/output bus waveguide. A photograph of the fabricated chip as well as a schematic of the design Fig. 5.33 Drop–port response of a parallel coupled triple ring resonator with integrated SOA, length of the couplers = 200 μm, r = 117 μm, gain length = 300 μm, FSR = 50 GHz 5.1 Filters 221 Fig. 5.34 Schematic of the microring resonator with integrated SOAs at the input and in the ring. Upper left inset: Scanning electron microscope image of the fabricated devices with and without an SOA in the ring. Lower right inset: Refractive index profile and layer structure of the ring resonator with integrated SOA Menon et al. (2004) is shown in Fig. 5.34. In addition to the SOA in the resonator, another SOA has been integrated on the side of the input port. Details on the fabrication have been described in Sect. 3.4.7. The racetrack shaped ring resonator has an FSR of 0.25 nm. A multimode interference coupler is used as in the previous example to couple into and from the ring. The length of the MMI is 685 μm and the width is 12 μm. The length of SOA1 is 1000 μm and the length of SOA2 is 500 μm. The overall length of the resonator is 3020 μm. The availability of an SOA inside a ring cavity enables the tuning of parameters of the resonator like the FWHM, the extinction ratio and thus also the Q factor and the finesse. The tuning of these parameters is shown in Fig. 5.35. A fabricated ring resonator employing an SOA, an MMI and total internal reflection (TIR) mirrors is demonstrated in Kim et al. (2005). Details on the layout and a photograph of a TIR based ring resonator are shown in Fig. 5.36. An FSR of 2 nm at a wavelength of 1568 nm is obtained. The on–off ratio achieved is 14 dB, an FWHM of 0.3 nm is measured leading to a finesse of more than 6, and a Q factor of more than 4900. The length achieved for the MMI coupler is one of the shortest reported. The SOA current dependable tunability of the resonance characteristic of the device is shown in Fig. 5.37. All integration schemes have in common that they require temperature stabilization. Another effect which takes place is the resonance shift due to increase in SOA current. This is due to the current dependency of the refractive index of the SOA. Despite these unwanted effects, SOAs inside ring resonators offer tunability of 222 5 Devices Fig. 5.35 Measured extinction ratio and FWHM as a function of the ring SOA2 current Menon et al. (2004) Fig. 5.36 Total internal reflection mirror-based GaInAsP ring resonators integrated with optical amplifiers Kim et al. (2005) essential parameters and enable lossless switching devices, which can also be used for lasers, wavelength converters and nonlinear operation. Examples will be given later on in this chapter. 5.2 Tunability Methods 223 Fig. 5.37 Tuning of the resonator extinction ratio via the SOA current Kim et al. (2005) 5.2 Tunability Methods Tunability is essential for the system application of optical filters. In the case of periodic filters, like ring resonators, it is important to fit the transmission curve to the defined channel spacing (e.g., ITU-Grid). Several tunability methods exist either for trimming the center wavelength of the filter after processing or for tuning the resonance wavelength when the ring resonator add–drop filter is in operation. These methods including examples are briefly explained in the following chapters. The physical mechanisms behind these methods are: Thermo-optic tuning. Thermo-optic tuning is realized by heating the component for example by fabricating a metal heater on top of the waveguide in the ring resonator. The refractive index of the material is changed through the heat which in turn shifts the resonances. The heating process is fairly slow but can be used to trim resonances in for example a double ring resonator because it is very difficult to fabricate ring resonator devices with exactly the same resonant wavelength. By adding heating elements and using the same, negligible additional loss is obtained. On the other hand, using heaters, limits the density of devices to maintain thermal isolation, and requires significant power consumption to maintain the tuned status. Another used tuning mechanism is electro-optic tuning. Here an electric field is applied to change the properties of the material, which means either the refractive index or the absorption. Changes in the refractive index are realized by using a bandgap wavelength of the material which is far away from the signal wavelength so as not to interfere with it. This effect is quite small compared to the effect produced by the heating elements. The refractive index increase is maximized when ring resonators with narrow peaks and low losses are used. The change in the refractive index by using the electro-optic effect is weak in III–V materials like InP, but has the advantage of being fast compared to the thermo-optic effect described before. One has to be careful when applying higher voltages which lead to significant losses. Changes in the absorption of the material are obtained, when the bandgap wavelength 224 5 Devices is closer to the signal wavelength. Only a small electric field is necessary to induce a large loss. This can be used advantageously in switching devices which shall be explained in the following chapter. Carrier injection (or free carrier injection for example in InP) is another means of changing the refractive index, absorption or gain. Introducing gain in ring resonators is an advantage of using carrier injection. As is and will be demonstrated in the following chapters, gain can be used to change the response of ring resonators, the extinction ratio, the Q factor and the maximum transmission. Ring resonators can be switched between dropping and transmitting a signal by changing the loss/gain inside the cavity. When gain is introduced into the ring resonator, attention has to be paid to design and fabricate a heat sink which is necessary to suppress the unwanted thermo-optic effect. 5.2.1 Wavelength Tuning Wavelength tuning is essential for realizing optical filters to be implemented in optical network. Tunability offers the network suppliers flexibility when designing and operating a network. Thermo-Optic Tuning A common and well-known method of tuning semiconductor and polymer based integrated optical devices is by using temperature. The simplest way is to heat the entire device and thus change the resonance spectrum in the case of ring resonators. This method is of course only useful for materials with a large temperature coefficient. A more effective way is to use local heating elements on top of the waveguides in the ring resonator for changing the refractive index and so for changing the resonance wavelength of the device. A detailed theoretical analysis with implementation on thermal tuning in ring resonators is described in Geuzebroek (2005). One of the first papers dealing with the integration of such heating elements in ring resonators made in silicon is presented in Katila et al. (1996) and Heimala et al. (1996). The ring resonator is made out of silicon nitride (Si3 N4 ) rib waveguides with a height of 40 nm. The silica undercladding layer and the silicon nitride layer thicknesses are 3 μm and 300 nm, respectively. The diameter of the ring is 2 mm. The resistors are made out of a phosphorous doped polysilicon layer. Aluminum with a thickness of 900 nm is used to create the bondbads. The layout and the layer sequence are shown in Fig. 5.38. Temperature tuning of the entire chip is used in Rafizadeh et al. (1997a) to tune a disk resonator. A temperature tuning of 1.3 nm per 10 °C is obtained. An overall tuning range of 6.3 nm over a temperature range of 50 °C is demonstrated. The tunability is mainly due to physical thermal expansion of the cavity. Triple ring resonators incorporating thermo-optic phase shifters for wavelength and passband shape tuning are demonstrated in Madsen and Zhao (1997) and Coppinger et al. (1999). In Madsen and Zhao (1997), double and triple serially 5.2 Tunability Methods 225 Fig. 5.38 a The schematic layout and b the cross-section (A–A) of the temperature-controlled ring resonator Katila et al. (1996) coupled ring resonator filters in silicon with chromium heating elements inside the ring resonators are presented. A minimum bend radius of 4 mm is achieved leading to an FSR of 0.066 nm. The response of the filter is adjusted by the integrated heating elements and is analyzed by a developed algorithm. Triple serially coupled ring resonators integrated in a silica waveguide technology with diameters of 8.5 mm are presented in Coppinger et al. (1999). The FSR of the filter is 7.5 GHz and a bandwidth of 1.5 GHz is measured. The application of this rather large ring resonator filter is the filtering of microwave signals to obtain a microwave transfer function. The integrated phase shifters (heating elements) cover part of the waveguide in the ring. As will be explained in the following paragraph in more detail using another ring resonator example, these heating elements are used to match the resonances of each ring to one another which leads to an improved pass-band of the filter. Once the desired passband characteristic is achieved, the power of the heating elements is increased by the same amount which enables wavelength tuning of the entire filter. Another method applied successfully to achieve wavelength tuning is by using platinum as a heating element inside a GaInAsP/InP based ring resonator (Rabus 226 5 Devices et al. 2002b). The platinum layer which enables the local heating of waveguide segments of the ring resonators via the thermo-optic effect is deposited directly on the waveguides. Before the platinum is deposited, the entire device is covered with a SiNx layer. This layer assures that no metal will diffuse into the waveguide material and no waveguide mode couples to the metal and increases the propagation losses. A photograph of a part of a Pt-resistor in a ring resonator is shown in Fig. 5.39. The pads for contacting the Pt-resistor are composed of layers of titanium, platinum and gold. A triple ring resonator with integrated Pt-resistors is shown in Fig. 5.40. The Pt-resistors have two functions. The first function is the tuning to specific wavelengths. The second function is the resonance matching of multiple coupled ring resonators to each other. A demonstration of resonance matching of a double ring resonator is shown in Rabus et al. (2002a). The tunability of a single ring resonator notch filter is shown in Fig. 5.41. The Pt-resistors enable a finer tuning to a specific wavelength and so an improved on–off ratio is obtained. The second feature of the Pt-resistors, the resonance matching, is demonstrated with a double ring resonator (r = 200 μm, upper and lower coupling factors κ 0,2 = 0.5, middle coupling factor κ 1 = 0.055, coupler lengths = 150 μm). The unmatched transmission spectrum of the double ring resonator is shown in Fig. 5.42. The upper curve shows the response of the throughput port and the lower curve that of the drop–port. This device has not been antireflection coated, which leads to Fabry–Perot resonances in the straight waveguides. The resonances are visible in the transmission spectrum of the throughput port. The typical filter characteristic of the double ring resonator is not disturbed despite the Fabry–Perot resonances. It depends on the application, if antireflection coating is required. The contrast of the throughput port is 16 dB and that of the drop–port 13 dB. The simulated filter response reveals a difference of the effective refractive index of about 0.0003, which is also the origin of the different contrast values. According to the calculation, the refractive index is lower in the upper ring. This is mainly due to fabrication tolerances which occur during the deep etching on the outer side of the waveguide in the curvatures. The physical lengths of the resonators are the same. In order to match the resonance frequency in both ring resonators, the upper Pt-resistors are used. A voltage of 0.5 V Fig. 5.39 SEM picture of waveguide with platinum layer 5.2 Tunability Methods 227 Fig. 5.40 Triple ring resonator with integrated platinum heaters on top of the waveguides in the curvatures and adjacent contact pads Fig. 5.41 Tunability of a single ring resonator notch filter with Pt resistors 228 5 Devices Fig. 5.42 Unmatched transmission spectrum of a double ring resonator. Dotted line—simulation, solid line—measurement is applied to match the resonance frequency. The temperature coefficient of InP can be approximated in this example to (see Sect. 3.4): dn ≈ 0.0001 K−1 dT (5.1) The local temperature increase is therefore approximately 3 K. The result of the resonance matched double ring resonator is shown in Fig. 5.43. The tuning to a specific wavelength can be performed after the frequency matching in such a way, that both of the Pt-resistors in the two rings are used. The driving voltage of the Pt-resistors is different in both ring resonators due to the previous frequency Fig. 5.43 Resonance matched double ring resonator. Dotted line—simulation, solid line—measurement 5.2 Tunability Methods 229 matching but has to be increased by the same amount in order to shift to a specific wavelength. A tunable racetrack shaped ring resonator notch filter in SOI is demonstrated in Kiyat et al. (2006). Details of the ring resonator and the used waveguide are shown in Fig. 5.44. A directional coupler with a coupling gap of 0.8 μm and a length of 48 μm is used, which results in a coupling factor of 0.45. The FSR of the ring resonator is determined to be 248 pm. The FWHM is measured to be 40 pm leading to a Q-factor of 38,000 and a finesse of 6.2. A heater electrode made out of nickel is used for tuning the resonance wavelengths of the filter. The electrode covers part of the waveguide in the curvature as in the previous example where platinum is used as the electrode material. The resistance of the heating element including the bond pads is 170 . The tuning of the resonance wavelength against power consumption is shown in Fig. 5.45. Electro-optic Tuning Fig. 5.44 Schematic views showing critical dimensions. a Top view of SOI resonator and b crosssectional view of SOI rib waveguide Kiyat et al. (2006) Fig. 5.45 Shift in resonance wavelength as function of applied power (dotted line with arrows indicate the tuning parameters for reaching the FSR) Kiyat et al. (2006) 230 5 Devices As already cited in Chap. 3, the electro-optic effect can be used to tune the resonance wavelength by tailoring the refractive index. In materials such as Lithium Niobate, high efficiency can be achieved. As far as semiconductors based ring resonators, one of the first electro-optic tunable, racetrack-shaped ring resonator notch filters in GaInAsP/InP is presented in Grover et al. (2004). The racetrack shaped ring resonator filter is also one of the smallest reported, with a radius of curvature of 2.25 μm and straight sections with a length of 1 μm leading to an FSR larger than 30 nm. The electrodes are made on top of a BCB layer which is used to planarize the device after the waveguides have been etched. The top contact (p-side) is made out of deposited Ti–Pt-Au. The bottom contact is made out of deposited Pd-Sn-Au-Pd-Au after the chip has been thinned. The change of the refractive index and the tuning of the resonance wavelength of the ring resonator filter with applied electric field are shown in Fig. 5.46. The quadratic electro-optic coefficient can be calculated from the measurement and is determined to be −9.8 × 10−1 cm2 V−2 . A tuning range of 0.8 nm which corresponds to 100 GHz at a wavelength of 1550 nm is realized. A narrowband, widely electro-optically tunable filter based on a whispering gallery mode cavity using LiNbO3 is demonstrated in Savchenkov et al. (2003). The device has an FSR of 10 GHz and can be used in microwave photonics communication systems. The obtained tuning speed of the filter is approximately 10 ns. The actual spectrum shifting time is determined by the 30 MHz bandwidth of the filter and does not exceed 30 ms. A channel crosstalk suppression of −20 dB for a 50 MHz channel spacing is measured. Fig. 5.46 Effective refractive index versus electric field, assuming all the bias appears across the core. Corresponding value of the resonance wavelength is shown on the right side. Refractive index in the absence of electric field is obtained from simulations. Quadratic fit provides us the quadratic electro-optic coefficient for the waveguide. Value of the coefficient for the waveguide is a lower bound for the quadratic electro-optic coefficient of the core Grover et al. (2004) 5.2 Tunability Methods 231 Carrier Injection Tuning One of the first vertically coupled disk resonators with a radius of 10 μm using carrier injection for increasing the refractive index and tuning the resonance of the resonator is demonstrated in Djordjev et al. (2002b). The device has an FSR of 10 nm and a Q value of 5500. The fabrication of the device has been explained in Sect. 3.4.7. The tunability of the device is 1.1 nm (mA)−1 . The refractive index change is n = −2.1 × 10−3 . The linewidth of the resonances is 0.28 nm. A transmission measurement of the tuning of the disk resonator is shown in Fig. 5.47. The vertically coupled disk resonator can also be used as an on/off switch. A demonstration of the switching behavior is shown in Fig. 5.48. The switch is operated by changing the drive current from 200 to 400 μA requiring a voltage of only 0.1 V. A contrast between the on and off state of 10 dB is achieved. Fig. 5.47 The free carriers injected into the disk resonator change the modal refractive index, which blue-shifts the resonant wavelengths Djordjev et al. (2002b) Fig. 5.48 Switching behavior of a disk at a wavelength of 1598 nm. Change in the drive current by I = 200 μA is enough to toggle the switch from the off to the on state. The voltage change required for this transition is V = 0.1 V Djordjev et al. (2002b) 232 5 Devices Fig. 5.49 Schematic drawings and SEM images of: a a disk vertically coupled to a single air-guided bus waveguide, type 1, and b a disk built on a buried bus line, type 2, respectively. The SEM image in (b) shows a stain-etched cross-sectional view of a buried bus waveguide section Choi et al. (2004) Two different types of tunable disk resonators vertically coupled to bus waveguides are presented in Choi et al. (2004): a disk resonator coupled to air-guided rib bus waveguides and another one fabricated on buried hetero-structure bus waveguides. Diagrams and SEM photographs of both types of resonators are shown in Fig. 5.49. The disk resonators have a radius of 12 μm. The two types of disk resonators have Q values of 8000 and 3000, respectively. A tunability of 1.5 and 2.1 nm is demonstrated at a current of 3 mA due to free carrier injection. 5.2.2 Center Wavelength Trimming In the previous chapter, examples of tuning mechanisms have been presented which enable the selection of resonance frequencies inside a ring resonator filter. Postfabrication methods which enable the permanent fitting of the entire resonance spectrum to a desired resonance frequency grid are explained in this chapter. 5.2 Tunability Methods 233 Ring resonators once fabricated offer practically no way to change the resonance spectrum besides heating the entire sample and thus changing the refractive index which in turn shifts the resonance spectrum. Therefore it is highly desirable to have methods which can be applied after the ring resonator filters have been fabricated to change the resonance spectrum. One way is to use a UV sensitive polymer overlay to change the resonance spectrum (Chu et al. 1999c). Polysilane is used as a polymer overlay to change the resonance spectrum of vertically coupled glass ring resonators with a radius of 19 μm. The FSR of the device before UV exposure for TE and TM polarized input light is 10.54 and 10.56 nm, respectively. Dip coating of the resonator is used which results in a thickness of the polymer of 2 μm. An Hg-lamp UV source (Toshiba Lightec TOSCURE 251), having a center wavelength of 370 nm and an irradiance of 38 mW cm−2 is used for the UV exposure. The trimming of one resonance using TM polarized input light is shown in Fig. 5.50. The wavelength shifts obtained for the resonances are 7.62 and 9.14 nm for TE and TM polarized input light. No change has been observed to a device after UV exposure which was measured again after one month. A similar polysilane UV trimming technique has been used in Suzuki et al. (2002) to trim the resonance wavelengths of a vertically coupled 1 × 8 filter array. A radius of 15 μm is used for all rings in the array. The ring resonators are made on a SiO2 substrate. The ring and bus waveguides are made out of Ta2 O5 / SiO2 compound glass. The cores of the ring resonator waveguides are covered by polysilane with a thickness of 10 μm using dip coating. The change of the refractive index of polysilane versus UV exposure time is shown in Fig. 5.51. The authors report, that the center wavelength change which is caused by the index change of the polysilane overcladding is due to the effect of oxidation or humidity Fig. 5.50 The detailed TM spectra around one resonance after three different UV time exposures (Chu et al. 1999c) 234 5 Devices Fig. 5.51 Measured refractive index change of polysilane versus UV exposure time Suzuki et al. (2002) absorption during UV exposure of the polysilane. The authors also report on an aging effect which makes hermetic packaging of the device after UV trimming necessary. A polysilane overcladding has also been used in Sparacin et al. (2005) to trim the resonance spectrum of Si3 N4 ring resonators fabricated on a 3 μm SiO2 undercladding layer on a (100) silicon substrate with a diameter of 100 μm. The ring resonators are designed for a wavelength of λ = 1550 nm. The difference to the aforementioned polysilane trimming method which utilizes dip coating is that the used polysilane is brought on to the ring resonators using a vapor phase technique. The polysilane used is (PECVD 6M2S). The UV exposure is carried out with a MINERALIGHT® handheld lamp (model UVGL-25) emitting at a wavelength of λ = 254 nm at an intensity of 1.7 μW cm−2 . The refractive index decreased exponentially by ~4%, from 1.52 to 1.46 at a wavelength of λ = 1550 nm. The overall spectrum shift obtained is 12.8 nm for the TE mode and 23.5 nm for the TM mode. Another UV trimming method is presented in Haeiwa et al. (2004) where the refractive index of the waveguide material SiN is exposed to UV light which imposes a refractive index change in the material. The refractive index change of an SiN film versus UV exposure time is shown in Fig. 5.52. The UV light source used is an Ar ion second harmonic generation laser with a wavelength of 244 nm and an output power of 100 mW. Details on the used ring resonator can be taken from the inset in Fig. 5.52. The maximum refractive index change is n = −1.3 × 10−2 , leading to a center wavelength shift of −11.4 nm. This UV induced index change is reported to be stable for more than 1200 h without any further treatment. A side effect of the UV induced index change is that coupling strength and loss inside the ring resonator are affected due to the absorption of UV radiation, changing the performance of the ring resonator 5.2 Tunability Methods 235 Fig. 5.52 Refractive index change of SiN film by UV irradiation and calculated center wavelength shift Haeiwa et al. (2004) filter. The FWHM in the presented example changed from an initial value of 0.34 to 1.02 nm after UV irradiation for 24 h. A different approach of trimming the resonance spectrum of SiN ring resonators is demonstrated in Wang et al. (2005). Oxygen plasma treatment is used to convert the ring resonator material into SiOx Ny changing the refractive index and thus affecting the resonance spectrum. The refractive index of SiOx Ny depends on the amount of oxygen incorporated in the SiN layer and can be tuned over a large range between 1.45 (SiO2 ) and 2.0 (Si3 N4 ). A schematic of the used ring resonators is shown in Fig. 5.53. The radius of the ring resonator filter is r = 25 μm. The length of the zero-gap coupler is 4 μm. The waveguide width is 1 μm for the bus waveguides and 2.5 μm for the ring resonator waveguides. An overall change in the resonance wavelength of 8.9 nm is demonstrated. In the previous examples, tuning of semiconductor based ring resonators has been addressed. In the following example, a polymer ring resonator notch filter fabricated by soft lithography (Poon et al. 2004) is tuned via a photo-bleaching technique of CLD-1 chromophores. The radius of the ring resonator is 207 μm, and the height and width of the waveguides are approximately 1.6 and 1.4 μm, respectively. The coupling gap is 430 nm wide. The trimming is performed using a visible broadband light source which is focused on one part of the ring resonator. The wavelength shift achieved is 8.73 nm after an exposure time of 1.75 h. The stability of chromophores, as it is well known, can degrade the performance of this material by the presence of oxygen. Therefore hermetic sealing and an inert gas atmosphere are needed for practical applications. Tunability of the resonance spectrum of ring resonators by changing the refractive index with different methods has been presented, highlighting several practical examples. These methods have only affected the FSR and have had sometimes as a side effect, changed the shape of the resonances which is seen by an increase/decrease of the FWHM. A way of definite tuning of the resonance shape is by implementation of tunable couplers. 236 5 Devices Fig. 5.53 Ring resonator filter [inset: (upper-left) SiN waveguide structure; (upper-right) photograph of fabricated ring resonator filter] Wang et al. (2005) 5.2.3 Tunable Couplers in Ring Resonators Tunable couplers have been fabricated and demonstrated as has been described in Sect. 4.1. Their implementation in ring resonators is so far limited by the size and technologies used. A widely used technique for realizing tunable couplers in ring resonator filters is by applying heaters on top of the waveguides in the coupling region. This also affects the resonance spectrum which is also shifted and has to be compensated with another heater inside the ring cavity. Tunable couplers enable the exact matching of the coupling coefficient to the loss inside ring resonator filters realizing a critically coupled state with maximum on–off ratio. One of the first disk resonators on an SOI platform, employing tunable couplers is presented in Lee and Wu (2005). Micro-electromechanical system (MEMS) actuated deformable waveguides are used to tune the shape of the resonance. The layout and an SEM photograph of the MEMS disk is shown in Figs. 5.54 and 5.55, respectively. The disk has a radius of 10 μm and the gap is 1.4 μm wide when no voltage is applied. A voltage of 70 V is needed to obtain a zero-gap coupler. One advantage of using MEMS couplers is the elimination of electron beam lithography to define the coupling gaps smaller than 500 nm. In this example a single standard lithographic step is required to pattern both the disk and the bus waveguides simultaneously. Another MEMS approach is described and demonstrated in Nielson et al. (2004), where a MEMS parallel plate structure is placed above the ring resonator enabling switching by lowering the plate and elevating it thus creating a change in the effective 5.2 Tunability Methods 237 Fig. 5.54 Schematic structure of the disk resonator with deformable waveguides. a At zero bias, the disk is completely uncoupled since the suspended waveguides are far away from the disk. b With voltage applied on the electrodes, the waveguides are bent toward the disk, increasing the coupling between the waveguides and the disk Lee and Wu (2005) Fig. 5.55 SEM photograph of MEMS actuated disk resonator Lee and Wu (2005) refractive index and a change in resonance wavelength. A detailed theoretical analysis of tunable couplers in ring resonators is presented in Kaplan (2006). Tunable couplers are one possibility of realizing perfectly matched ring resonator filters apart from gain implementation inside the ring cavity as was described in Sect. 5.1.2. Due to the advancing state-of-the-art of manufacturing technologies, it will only be a matter of time until tunable couplers are widely incorporated in ring resonator filters realizing various types of devices. 238 5 Devices 5.3 Dispersion Compensators In classical optics, “dispersion” is used to denote the wavelength dependence of the refractive index in matter (dn/dλ, where n is the refractive index and λ is the wavelength) caused by interaction between matter and light. In communication technology, “dispersion” is used to describe any process by which an electromagnetic signal propagating in a physical medium is degraded because the various wave components (i.e., frequencies) of the signal have different propagation velocities within the physical medium. Material dispersion causes different wavelengths to travel at different speeds due to the variation of the refractive index of the fiber core with wavelength. However, part of the light also travels in the cladding of the fiber, which has a different refractive index. This portion of the light propagates therefore right through the cladding at different speeds to the core—an effect known as waveguide dispersion. Material and waveguide dispersion are combined to give an overall effect called “chromatic dispersion.” Chromatic dispersion is caused by a variation in the group velocity of light traveling within a fiber with changes in optical frequency. A data pulse always contains a spectrum of wavelengths. As the pulse travels along the fiber, the shorter wavelength components travel faster (negative dispersion) than the longer wavelength components (positive dispersion). This effect broadens the pulse and causes it to interfere with neighboring pulses and distort the transmission signal. The allowed chromatic dispersion in an optical network is inversely proportional to the square of the transmitted bit rate, so as data rates increase, dispersion tolerances decrease dramatically. While 2.5 Gbit s−1 networks can tolerate 16,000 ps nm−1 of dispersion, 10 Gbit s−1 networks can tolerate only 1200 ps nm−1 and in 40 Gbit s−1 networks, the tolerance drops to only 60 ps nm−1 of dispersion. In addition, 40 Gbit s−1 systems require a wider modulation spectrum. A 12 GHz wide spectrum is typical for 10 Gbit s−1 , for 40 Gbit s−1 , it can be as high as 50 GHz, which means the total dispersion per channel is higher. Chromatic dispersion has a fixed, stable component in addition to a dynamic one. Most of the fixed dispersion is caused by the fiber and is predictable as a function of the type of fiber and the distance. In addition, the optical components present in the optical path add a smaller, fixed contribution. A dynamic contribution must be added to the fixed one. Since many passive components do not have a simple flat or linear dispersion curve, laser drift (caused by aging or temperature change) can lead to dispersion fluctuations that are nonlinear and hard to predict. Another important type of dispersion is the polarization mode dispersion (PMD). PMD is caused by light traveling faster in one polarization plane compared to another. Fundamentally, it is caused by the core of the fiber not being perfectly round in cross-section and by birefringence which is introduced by mechanical forces. As a result, the optical thickness is not absolutely identical on every possible axis. PMD is a special case for modal dispersion or intermodal dispersion, which is caused by multimode propagation of light. Each mode travels with a different group velocity. The modes can be higher order modes of the same polarization, or modes of different 5.3 Dispersion Compensators 239 polarization, as is it is the case for PMD. Intermodal dispersion is of no concern under single mode operation. Finally, there is structural dispersion also known as quadratic dispersion which is effectively the second derivative of the transmission phase with respect to frequency. Structural dispersion is determined by the architecture and layout of the photonic integrated circuit. Ring resonators can be used as dispersion compensators and examples presented in literature will be highlighted in this chapter. Practical dispersion compensators should have a limited tunability, uniform insertion loss upon tuning of dispersion and should enable the operation at multiple wavelengths. Ring resonators can be used to enhance the physical length by forcing the light to traverse the physical distance many times. Resonant enhancement, however, comes at the price of finite bandwidth. A large enhancement results in a narrower bandwidth. Ring resonators allow large compensation for multiple wavelengths simultaneously in a so far limited frequency range. The building block of a multistage dispersion compensator using ring resonators is shown in Fig. 5.56. The group delay of a ring resonator follows a periodic curve. Cascading multiple loops enables synthesization of various delay curves. A tutorial overview on ring resonators used as dispersion compensators highlighting various configurations is given in Schwelb (2004). Dispersion compensators utilizing ring resonator architectures have been investigated by Madsen and coworkers extensively and some examples will be given in the following section. One filter type is of special interest, the optical all pass filter (APF). APF’s are devices that allow phase correction or equalization without introducing any amplitude distortion (Lenz and Madsen 1999). One of the first experimental demonstration of a multistage all pass filter dispersion compensator that uses ring resonators in planar waveguides is demonstrated in Madsen et al. (1999). A two stage optical filter consisting of two parallel coupled ring resonator notch filters with a bend radius of 2.2 mm is realized. Ge-doped silica waveguides on a silicon substrate are used for the waveguides. A coupling gap of 3 μm is used for the directional couplers. The phase shifter inside the ring resonators is made out of chrome with a resistance of 55 , which is deposited on the upper cladding of each ring. The FSR of the device is 12.5 GHz. The parameters of the filter are: D = 4200 ps nm−1 , ±5 ps group delay ripple, <3 dB loss, and a 4.5 GHz passband width. The filter is used in a transmission experiment using 320 km of fiber. The filter is capable of compensating negative and positive dispersion. Due to the birefringence of the used waveguides, the filter Fig. 5.56 Single ring resonator filter building block of multistage dispersion compensator 240 5 Devices is polarization dependent and therefore to avoid PMD, either TE or TM polarized input light is used. Four stage ring resonator dispersion compensating filters are presented in Horst et al. (2000). Ring resonators with an FSR of 25, 33, and 50 GHz are fabricated in SiON technology. Metal heaters are deposited on top of the waveguides to allow for tunable phase shifting. A dispersion of −415 ps nm−1 over a usable bandwidth of 22 GHz for a filter with an FSR of 50 GHz is obtained. The filter is as the previous example polarization dependent which means that accurate polarization control has to be maintained. A new architecture combining ring resonators and MZIs to be used for dispersion compensation is presented in Madsen et al. (1999). A schematic of a single stage ring resonator filter with an MZI design is shown in Fig. 5.57. The MZI design enables a tunable APF by incorporating phase shifters in the ring and the MZI. The phase shifter in the MZI enables a tunable coupling ratio while the phase shifter in the ring resonator is for resonance tuning. Four stages of the ring resonator/Mach–Zehnder combination are cascaded yielding a dispersion of 1800 ps nm−1 and a passband of 14 GHz, which is greater than 50% of the FSR. A low group delay ripple of 15 ps peak is achieved. The device is realized in Ge-doped silica planar waveguides. The directional coupler lengths are 477 μm. The radius used is 1 mm, and the FSR of the filter is 25 GHz (at 1490 nm). A device consisting of ring resonators coupled to arms of an MZI are used in Madsen et al. (2004) to compensate and emulate PMD. A photograph of a similar realized device is shown in Fig. 5.58. The device which is used for PMD measurements consists of a directional coupler, which is fed into an MZI which has ring resonators attached at each arm. A schematic of the used configuration is shown in Fig. 5.59. The experimental device based on Ge-doped silica waveguides is a four stage all pass filter. The radius of the ring resonators used is 350 μm, leading to an FSR of 74.4 GHz. A discrete polarization beam splitter (PBS) on the output side and a linearly polarized input signal with the polarization aligned to either the TE or TM axis is used in the measurement setup. The authors demonstrate a differential group delay (DGD) tuning range over 100 ps for 10 Gbit s−1 and 25 ps for 40 Gbit s−1 Fig. 5.57 Ring resonator with asymmetric Mach–Zehnder interferometer 5.3 Dispersion Compensators 241 Fig. 5.58 A two-section planar waveguide chip with three-stage all-pass filters in the upper and lower arms of each section Madsen et al. (2004) Fig. 5.59 Experimental device Madsen et al. (2004) data. Second order PMD with a tuning range of 255 ps2 and third order PMD with a range of 2430 ps3 are also demonstrated. Ring resonators combined with MZIs can not only be used for dispersion compensating optical devices. Other applications will be addressed in the following chapter. 5.4 Mach–Zehnder Interferometers Combined with Ring Resonators MZIs are well known and have found their way into integrated optics. A basic MZI consist of two waveguides of different lengths, which are joined at both ends using 3 dB couplers. A schematic is shown in Fig. 5.60. The transfer characteristic has a periodic sin2 shape over wavelength assuming that the two 3 dB couplers are wavelength independent regarding their coupling behavior. The distance between the minima and maxima in terms of wavelength depend on the length difference in both arms of the MZI. The 3 dB bandwidth of the filter in the frequency domain is given by 242 5 Devices Fig. 5.60 Layout of a basic MZI f = c0 2n eff L (5.2) where L is the length difference between both arms. Optical filters deployed in optical networks are required to have a “box-like” filter response as was described earlier. One way to do this is by using multiple coupled ring resonators. MZIs can also be modified to realize a more rectangular transfer function by introducing a ring resonator into one of the arms. A ring resonator has one 2π phase shift per FSR. In order to obtain passband flattening of the transfer characteristic of the MZI, two ring resonator phase shifts per FSR of the MZI are required. This means that the FSR of the ring resonator has to be half of the FSR of the MZI. Translated into length requires the circumference of the ring to be twice as large as the delay length of the MZI. A periodic multi/demultiplexer with a square spectrum response having an FSR of 200 GHz is presented in Kohtoku et al. (2000). A schematic of the device layout including design parameters is shown in Fig. 5.61. The device is fabricated on an InP substrate. MMI couplers are used in the device which enables lower manufacturing tolerances regarding the splitting ratio. The circumference of the ring resonator is 876.6 μm leading to an FSR of 100 GHz which is half of the FSR of the MZI. Fig. 5.61 Configuration of the periodic multi/demultiplexer with a ring resonator Kohtoku et al. (2000) 5.4 Mach–Zehnder Interferometers Combined with Ring Resonators 243 A suitable coupling ratio for the coupler in the ring resonator has to be chosen to obtain a rectangular transfer characteristic with a large rejection bandwidth and a high extinction ratio. The MMI coupler in the ring resonator has a splitting ratio of 15:85. The transmission characteristic of the device is shown in Fig. 5.62. In the following example, a balanced MZI with one arm coupled to a ring resonator in AlGaAs-GaAs is presented (Absil et al. 2000b). The motivation in using a balanced MZI is by realizing a notch filter and thus introducing a zero pole filter when speaking in terms of the Z-transformation (see Chap. 2). When the round-trip loss in the ring resonator is small compared to the waveguide coupling strength, the ring resonator introduces a phase shift of π at resonance. The resonant phase shift is independent of the coupling coefficient, and minimum transmission occurs. A photograph of the device is shown in Fig. 5.63. The amplitude transfer response of this kind of device is given by Absil et al. (2000b): t − e−(α+ jβ)2π R − jφ 1 , 1+ e T = 2 1 − te−(α+ jβ)2π R t = 1 − κ 2, (5.3) where φ is the phase imbalance between the two arms of the MZI. The Y-splitters are assumed of having a 3 dB splitting ratio with a wavelength independent loss. The device has only one input and one output port coupled to 3 dB Y-splitters. The transfer spectrum obtained is slightly deviated from the theoretical notch filter response due to an imbalance in the arms of the MZI of only 110 nm. The spectrum is shown in Fig. 5.64. Fig. 5.62 Transmission spectra of the fabricated device with 200 GHz FSR. The solid line indicates ports 1–3. The dashed line indicates ports 1–4. The dotted line indicates the reference waveguide Kohtoku et al. (2000) 244 5 Devices Fig. 5.63 SEM micrograph of the fabricated MZI in GaAs–AlGaAs (Absil et al. 2000b) Fig. 5.64 Measured Mach–Zehnder transmission spectrum and analytical fit showing imbalanced arms (Absil et al. 2000b) These two examples show how different transfer functions can be realized with a ring resonator coupled to one arm of an MZI. The response depends on the length of the arms (balanced/unbalanced), on the type of response desired and on the coupling coefficient from one arm to the ring resonator. Recently a novel geometry for ring resonators coupled to an MZI has been demonstrated in polymer in Paloczi et al. (2003). A photograph of the proposed and fabricated device is shown in Fig. 5.65. The device is realized in SU-8. The ring resonators are racetrack shaped and have a bending radius of 100 μm. The straight coupling sections have a length of 50 μm. The designed coupling gap is 750 nm. The ring resonators have an FSR of 2.2 nm for TE polarized light at a wavelength 5.4 Mach–Zehnder Interferometers Combined with Ring Resonators 245 Fig. 5.65 Novel design of ring resonators coupled to an MZI. The size of the device is approximately 1.2 mm Paloczi et al. (2003) Fig. 5.66 Experimental data (dotted) and the theoretical fit (line). The fitting parameters used for the fit were: polarization 93% TE and 7% TM, effective indices 1.48475 for TE and 1.48555 for TM, power coupling coefficients 0.46 for TE and 0.85 for TM, and waveguide loss of 30 dB cm−1 Paloczi et al. (2003) of 1550 nm. Complicated phase properties and a periodic spectral response of the absolute field amplitude are observed. The transmission spectrum of the device is shown in Fig. 5.66. MZIs with ring resonators have also been demonstrated to be used for all optical switching (Heebner et al. 2004). Optical switching in ring resonators will be described in Sect. 5.8. Ring resonators coupled to MZIs have also been investigated for implementation as modulators Tazawa and Steier (2005). The properties of ring resonator modulators are addressed in the following chapter. 5.5 Modulators Wavelength division multiplexing (WDM) and dense WDM systems require modulators to generate the required optical signals to be transmitted. Electro-optic (EO) modulators based on an MZI are used for fulfilling this task so far. Resonator based modulators are of increasing interest as they can be operated in principle with a 246 5 Devices lower driving voltage and have a more compact design which is a prerequisite for integrated devices. One of the earliest resonator based modulators is of course the Fabry–Perot resonator. Ring resonator modulators have recently gained attention due to the improvement of fabrication technologies which enable very small devices as was demonstrated in previous chapters, and due to improved and novel material properties. In contrast to MZI based EO devices, ring resonator modulators have a rather small bandwidth which limits their applications so far to systems requiring a modest radio frequency (RF) bandwidth but operate at high carrier frequencies. A single wavelength is used as the input signal for a ring resonator modulator. The operating wavelength of the ring resonator modulator is tuned, so that the steepest slope of one of the resonances in the throughput port spectrum is used. Applying a voltage through an electrical field in the ring resonator induces a shift in the position of the resonance peak, resulting in an intensity change at the throughput port. The main bandwidth limitation is the time which is needed to build up the optical field in the ring resonator. The time of one roundtrip in the resonator is given by (see also Chap. 2): τRoundtrip = 2π Rn g c0 (5.4) The total time needed for a ring resonator to build up a resonance (also referred to as cavity ring-down time) is given by τCav = m · 2π Rng c0 (5.5) The cavity ring-down time can be related to the quality factor Q of a ring resonator by Leinse (2005) τCav = λQ 2π c0 (5.6) The cavity ring-down time can also be written in terms of the finesse F of the ring resonator using (2.31) to: τCav = F Rn g c0 (5.7) Instead of using the group refractive index, the effective refractive index can also be used. The group refractive index takes into account the wavelength dependency of the effective refractive index and therefore a more accurate value for the cavity ring-down time is obtained. The relationship between the bandwidth of the filter spectrum response and the maximum transmission capacity is analyzed theoretically and experimentally in Suzuki et al. (2001). A vertically coupled ring resonator add– drop filter with a radius of 20 μm is used for the experiment. An FWHM of 0.75 nm is 5.5 Modulators 247 obtained. A pulsewidth of 3.4 ps is measured at the output port of the ring resonator, when an input pulse of 1.2 ps with a sech pulse shape from a fiber laser is inserted at the input port. A maximum transmission capacity of 50 Gbit s−1 is estimated for this type of ring resonator filter. Linear and nonlinear pulse propagation in ring resonator filters is analyzed theoretically in Melloni et al. (2003b). In particular, the so-called slow wave structures consisting of a chain of directly coupled ring resonators are investigated. In the following paragraph a relationship between the bandwidth and the driving voltage based on Rabiei et al. (2002a) is given. Since the traditional switching voltage V π in MZI based modulators cannot be used for a ring resonator modulator a switching voltage of V fwhm is defined, which is the voltage required to shift the resonant wavelength by the FWHM. Sometimes other definitions are used which define the voltage needed for a specific extinction ratio (e.g., V 10 dB or V 20 dB). The modulation bandwidth BW of a ring resonator is given by BW = 1 2π τLifetime , (5.8) where τ Lifetime is the finite lifetime for the photons in the resonator. Using the frequency relationship for the FWHM ωFWHM = 1 . τLifetime (5.9) The bandwidth can be rewritten as BW = vFWHM (5.10) The index change neff required to shift the resonance by vfwhm is given by n eff vFWHM , = n eff v (5.11) where neff is the effective refractive index of the ring resonator and v is the optical frequency. The index change relation for EO materials is given by n ef = V 1 K n 3EOr33 , 2 d (5.12) where K is the confinement factor, V is the applied voltage, nEO is the refractive index of the EO material, and d is the distance between the electrodes. Using these equations, the relationship between the bandwidth and the driving voltage is obtained, yielding the fundamental limitations of these kind of modulators: 248 5 Devices BW K vn 3EOr33 . = VFWHM 2n eff d (5.13) The polymer based ring resonator modulator presented in Rabiei et al. (2002a) has a bandwidth of 2 GHz and a transmission experiment has been carried out demonstrating an open eye diagram at 1 Gbit s−1 . Detailed expressions for the modulation bandwidth and drive voltage for optical resonator based modulators can be found in Gheorma and Osgood (2002). Ring resonator-based travelling wave modulators are also analyzed theoretically in Tazawa and Steier (2006). Theory on ring resonator modulators, device design, and characterization is presented in Rabiei (2003) and Leinse (2005). In Leinse (2005), modulators consisting of a ring resonator coupled to an MZI are also demonstrated. Polymer ring resonator modulators with diameters of 50, 70, and 150 μm are demonstrated in Rabiei et al. (2002b). The modulators have FSRs of 1100, 770, and 300 GHz at a wavelength of 1330 nm. The fabrication and layer sequence of the ring resonators has been described in Sect. 3.5.1. The bandwidth of the devices is 18, 16, and 12 GHz, respectively. The authors propose a multiwavelength ring resonator modulator and filter configuration for implementation in WDM systems shown in Fig. 5.67. In order for the system to be realized, the FSRs of each of the ring resonator modulators and filters have to be greater than the wavelength spectrum used in the WDM system. Each ring resonator has to be frequency hence wavelength stabilized to modulate or filter out the correct wavelength with high extinction ratio. The device consisting of several ring resonators is feasible with current state-of-the-art manufacturing methods and as was described in a previous chapter, wavelength stabilization can be performed with several methods. Modulators based on ring resonators on silicon on insulator are presented in Pradhan et al. (2005) and Xu et al. (2005). A ring resonator notch filter is used with a rib waveguide structure. Photographs of the ring resonator and the metal contacts are shown in Fig. 5.68. Electro-optic modulation of the refractive index is achieved by a p–i–n junction integrated with the ring resonator. The p- and n-doped regions are on the inner and outer side of the ring waveguide having a concentration of 1019 cm−3 . The width and height of the ring and bus waveguides are 450 and 250 nm, respectively. A coupling Fig. 5.67 Integrated WDM system using microring modulators and filters Rabiei et al. (2002b) 5.5 Modulators 249 Fig. 5.68 SEM and microscope images of the fabricated device. a Top view SEM image of the ring coupled to the waveguide with a close-up view of the coupling region. b Top view microscope image of the ring resonator after the metal contacts are formed. The metal contact on the central p doped region of the ring goes over the ring with a 1 μm thick silicon dioxide layer between the metal and the ring Xu et al. (2005) gap of 200 nm is realized. The diameter of the ring resonator is 12 μm leading to an FSR of 15 nm. The FWHM of a resonance around 1550 nm is measured to be 0.04 nm. The cavity ring down time for this type of modulator using (5.6) is calculated to be τ cav = 33 ps. The performance of the device is demonstrated using a nonreturn-to-zero (RZ) signal at 0.4 Gbit s−1 and an RZ signal at 1.5 Gbit s−1 . Vertically coupled disk modulators on InP are demonstrated in Sadogopan et al. (2005). The operation of the device is based on a depletion width translation mechanism which involves the transfer of optical energy between two waveguides at the resonance of a ring or disk resonator that couples the two waveguides. A photograph of a fabricated ring modulator as well as a sketch of the cross-section is shown in Fig. 5.69. The fabricated device has an outer radius of 12 μm and an inner radius of 8.5 μm. The 3 dB modulation BW of the device is 8 GHz. A wavelength shift of 0.2 nm at a driving voltage of 0.9 V leads to an extinction of the signal wavelength of 10 dB. The device shows open eye diagrams at 10 Gbit s−1 which demonstrates the functionality at these speeds. Ring and disk resonators with a high Q-factor enhance the coupling between waveguides, thus a low voltage modulation of the resonator Q can modulate the power transfer, enabling high speed operation. Examples of techniques for fabricating ring and disk resonators modulator circuits have been demonstrated in this chapter and ongoing research will enable faster and smaller devices. High-speed modulation of a compact silicon ring resonator based on a reversebiased pn diode is demonstrated in Gardes et al. (2009), where a high speed ring resonator modulator based on the carrier depletion effect in an asymmetric pn diode structure is fabricated and characterized. The modulator exhibits a DC on/off ratio of 5 dB at −10 V, and a 3 dB bandwidth of 19 GHz. 250 5 Devices Fig. 5.69 SEM photograph of fabricated ring modulator. The cross-section of the device shows the three-dimensional coupling which is necessary for the depletion mechanism Sadogopan et al. (2005) One of the first experimental demonstration of interdigitated PN silicon modulator integrated in a ring resonator is presented in Ziebell et al. (2011). Here, to increase the modulation efficiency, an alternative solution is used to change the orientation of the diode and consequently to use interdigitated PN junctions orthogonally oriented to the direction of light propagation (i.e. waveguide direction). In such configuration, the optical mode propagates through successive depleted regions, which maximizes the interaction between the light and the regions where refractive index variation occurs. The structure was integrated in a ring resonator with a radius of 50 μm. High modulation was obtained in both TE and TM polarizations, with a DC extinction ratio larger than 10 dB. V π L π as low as 2.5 V × cm was obtained in both TE and TM polarizations. Excess optical loss lower than 1 dB were measured. Finally, high-speed operation was analyzed thanks to 10 Gbit s−1 eye diagram measurements. A clear open eye diagram was obtained, with 4 dB extinction ratio using 5 V peak-to-peak RF signal. High speed coupling-modulation of a ring resonator is demonstrated by Li et al. (2011), showing that an extinction ratio improvement from <1 to >20 dB with 40 Gb/s non-return-to-zero (NRZ) signals can be achieved utilizing a 25 times smaller driving voltage. The obtained tolerance to active ring propagation loss is increased from 5.5 Modulators 251 5 dB cm−1 to more than 25 dB cm−1 with less than 5% modulation bandwidth reduction. The authors convincingly describe of obtaining 160 Gb/s NRZ signal with approximately 4 V drive voltage and less than 5 dB insertion loss in optimizing their structure. Hagan et al. (2020) present high-speed performance of a thulium doped fiber amplifier(TDFA)-band ring resonator modulator and detector. The authors present steady-state measurements of the defect-mediated (DM) detector showing 1.97 μm wavelength responsivities of 0.04 and 0.14 A/W at −15 and −30 V, respectively. The DM detector exhibits a maximum electrical bandwidth of 16 GHz at −15 V and about half of this at −30 V. The authors have demonstrated high-speed operation of a mid-infrared (MIR) SOI-based MRR modulator operating without an integrated modulation driver at a detector-limited bandwidth of 12.5 GHz. Combined in an optical link with a transfer-impedance-amplifier (TIA)-less high-speed detector operating with a maximum bandwidth of 16 GHz, open eye-diagrams up to 12.5 Gbps have been demonstrated. These examples clearly demonstrate the potential of using integrated ring resonators as elements for telecom applications highly needed to massively increase the bandwidth of current optical networks. 5.6 Lasers Semiconductor ring lasers have been investigated in the past and have recently gained attention again because they can be readily integrated with other optoelectronic devices and do not require gratings or facets for optical feedback. Ring lasers avoid spatial hole burning by traveling wave operation, which results in single mode operation and reduced sensitivity to feedback. Different types of active and passive coupling configurations have been used in ring resonator lasers including Y-splitters, directional couplers and multimode interference couplers. MMI couplers have attracted widespread attention, because they allow increased fabrication tolerances compared to directional couplers as has been described in Chap. 4. Ring lasers have been described in detail in literature, therefore only brief highlights will be given and different types of laser configuration will be discussed in the following chapter. 5.6.1 All Active Lasers In this chapter ring resonator-based lasers fabricated using gain material for realizing ring and bus waveguides are described. These ring lasers will be referred to as all active ring lasers. 252 5 Devices One of the first demonstrations of the principle of a ring resonator laser is presented in Weber and Ulrich (1971). A rhodamine 6G2 doped polyurethane film which serves as the waveguide is coated on the surface of a cylindrical glass rod with a diameter of 5 mm providing the ring resonator geometry. This film is pumped with a N2 laser having a wavelength of 337 nm emitting a beam with a sheet like output characteristic, enabling the pumping of only a short width of approximately 0.2 mm of the film coated glass rod. In using this pump method, a ring resonator laser is obtained. A prism coupler is used to couple light out of the ring resonator. One of the first integrated ring resonator lasers is presented in Liao and Wang (1980). The ring laser is made in the material system GaAs–GaAlAs and has a straight branching waveguide serving as the output. The output waveguide is in principle a Y-splitter. A ring radius of 100 μm is realized. The lasing wavelength observed is around 873 nm under pulse operation. The threshold of the laser is above 300 mA. In order to prevent the output waveguide from acting as a second cavity, it was made 3 mm long and the facets have been scratched to lower or eliminate the reflectivity. One of the first continuous wave (cw) operating integrated disk resonator lasers in the GaAs material system with integrated Y-splitter for output coupling is presented in Krauss et al. (1990). The disk has a diameter of 84 μm and a threshold current of 24 mA. The low threshold current is achieved by only depositing a metal contact layer on the outer side of the disk with a width of 4 μm, forming a metal ring and isolating the inner disk with a poly-imide layer. One of the first integrated ring resonator lasers in GaAs/AlGaAs with a radius of 150 μm and a threshold current of 72 mA is demonstrated in Hohimer et al. (1991). A Y-splitter is used to couple out of the ring resonator. The width of the used waveguide is 8 μm. A side mode rejection ratio of 22 dB is measured for current values greater than 50 mA, which was one of the highest side mode rejection ratios at that time. The laser emits at a wavelength of 852 nm. The output power has been increased significantly for similar ring laser devices in Hohimer et al. (1992) by tilting the output waveguide (tilt angle = 5°, 10°), eliminating a back reflection of modes which compete with the laser mode for gain. Controlled back reflection is also investigated for unidirectional lasing in ring resonator lasers suppressing the counter propagating wave. Ring lasers in GaAs– AlGaAs having Y-splitters as output couplers with tilted output waveguides are also presented in Tsai et al. (1998). Tilt angles from 0° to 15° between the waveguide orientation and the normal of the cleaved facet are realized. Ring lasers having a radius of 200 and 300 μm are demonstrated. Unidirectional ring lasers using racetrack geometry are presented in Hohimer and Vawter (1993). Inside the racetrack cavity is an equal-radius crossover S-waveguide that is independently electrically contacted. This S bend waveguide enables unidirectional lasing. Single mode operation at wavelengths around 870 nm with an output power greater than 10 mW is reported. This group around Hohimer has performed extensive research on ring resonator lasers and has published numerous papers on the subject. Therefore only an excerpt of relevant publications from this group is presented in this chapter. 2 Formula: C28 H31 N2 O3 Cl. 5.6 Lasers 253 One of the first ring resonator lasers in the material system GaInAsP is demonstrated in Hansen et al. (1992). The ring resonator laser has a diameter of 3 mm and emits at a wavelength of 1.54 μm. The threshold current is measured to be 157 mA. The ring laser is coupled to a straight waveguide with a gap of 1.5 μm. The ring laser is fabricated using buried passive rib waveguides and two buried heterostructure active sections with multiple quantum wells. The length of the active sections is 500 μm each, placed on opposite sites of the ring laser. Continuous wave operation is achieved with a side mode suppression of 28 dB. InP-based ring lasers employing MMI couplers are presented and analyzed in detail in Pennings et al. (1993, 1994) and van Roijen et al. (1994). An output power of 9 mW under cw operation at a wavelength around 1.6 μm with a side mode suppression of 35 dB is obtained. Two types of ring resonator geometries are analyzed and fabricated. A schematic of the devices is shown in Fig. 5.70. Completely active ring resonators are fabricated. Two types of MMI couplers are used, output couplers with a width of 7 μm with lengths between 185 and 233 μm and combiners with a width of 8 μm and lengths between 61 and 75 μm. The use of MMI couplers in ring resonator lasers has also been investigated and demonstrated in Krauss et al. (1994, 1995b). Racetrack shaped ring resonators in the GaAs/AlGaAs material system with a radius of 400 μm and a length of 320 μm for the straight section and the 3 dB MMI coupler are used. The device has a threshold current of 140 mA and emits at wavelengths around 870 nm. Ring lasers having directional couplers, MMI couplers and Y-splitters as output configurations are analyzed, fabricated and compared in Krauss et al. (1995a). A square ring resonator laser in GaAs–AlGaAs with an MMI output coupler is presented in Kim et al. (1997). A schematic of the laser is shown in Fig. 5.71. The round-trip length of the square ring resonator laser is determined by the width of the used waveguide. A waveguide width of 6 μm results in a 3 dB coupling length of 283 μm and for a waveguide width of 8 μm, a 3 dB coupling length of 509 μm Fig. 5.70 Ring laser employing MMI couplers—design 254 5 Devices Fig. 5.71 Layout of square ring resonator laser is determined. The width of the coupling waveguide is 2 μm for the 6 μm ring waveguide and 3 μm for the 8 μm ring waveguide. Threshold currents of 200 mA and 250 mA are measured at lasing wavelengths around 800 nm. A ring laser with a triangular shape in InP–GaInAsP is presented in Ji et al. (1997). A photograph of the device is shown in Fig. 5.72. The lasing wavelength of a presented device is around 1.26 μm with a threshold current of 64 mA (θ = 25°) under pulsed operation (100 ns pulsewidth, and 20 μs period). A side mode suppression ratio of 25 dB is achieved. The width of the waveguide is 4 μm and the cavity length is 300 μm. The Q of the cavity is determined by the so called structural angle θ which defines the output angle φ. The dependence of these angles on the output power is investigated experimentally. Fig. 5.72 SEM fabricated triangular ring laser, cavity length 300 μm, structural angle θ and light output angle φ are defined in the diagram Ji et al. (1997) 5.6 Lasers 255 Fig. 5.73 Schematic of photonic integrated circuit Vawter et al. (1997) One of the first photonic integrated circuits in GaAs–AlGaAs comprising a modelocked ring laser, an optical amplifier, and a high speed photodetector is fabricated and demonstrated in Vawter et al. (1997). A schematic of the device is shown in Fig. 5.73. The device is used to generate mm wave signals at frequencies of 30, 60, and 90 GHz depending on the radius of the ring laser. The radii of the used ring lasers are 860, 430, 290 μm, respectively. Passive mode locking of the ring laser is realized by a saturable absorber, generating pulses between 1 and 10 ps. Mode locking in ring lasers is investigated both theoretically and experimentally in Yu et al. (1998) with respect to different configurations of intra-cavity saturable absorbers. A schematic of the designs analyzed is shown in Fig. 5.74. Low-threshold GaInAsP all active ring lasers are presented in Griffel et al. (2000). The layer sequence has already been described in Chap. 3. The threshold current of the cw operated ring laser is 66 mA with a side mode suppression ratio of 26 dB at wavelengths around 1.6 μm. Unidirectional bistability in circular waveguide InGaAs/GaInAsP semiconductor lasers has been observed and demonstrated in Sorel et al. (2002). A ring diameter of 1.2 mm is used for the cw ring laser having a threshold current of 125 mA. The FSR obtained is 0.166 nm. Three operating regimes regarding the clockwise and counter clockwise propagating modes are observed. Operation regime one is between 125 and Fig. 5.74 Configurations: a symmetric, b asymmetric and c dual absorber 256 5 Devices 135 mA, and both modes oscillate. Operation regime two is between 135 and 220 mA, unidirectional operation is observed, either in one or the other direction, depending on the driving current. The extinction ratio between the lasing and nonlasing output is measured to be more than 30 dB. Operation regime three is above 220 mA, here the modes randomly switch to the output ports. Bistability is imposed by two electrodes (see Fig. 5.75), each on one side of the output waveguide. For example by applying a short pulse to either of the two electrodes when the ring laser is operated in regime two, changes the direction of the mode in the ring laser. Operating regimes of ring laser in the material system GaAs–AlGaAs are also investigated by this group in Sorel et al. (2003). A photograph of a ring laser where the contact layout can be seen which was also used for the InP based devices is shown in Fig. 5.75. The presented ring laser is integrated together with three photodiodes (PD) realized in a simple manner by placing contacts on top of the active waveguides. Their position can be taken from the photograph. The radius of the ring lasers investigated is 1 mm. A directional coupler with a coupling gap of 1 μm is used to couple light out of the ring. The output waveguide is tilted at an angle of 5° to reduce back reflection of the light from the cleaved facets below a reflectivity of 0.5%. Different operating regimes are analyzed both theoretically and experimentally. In addition to the operating regimes described previously, a Fig. 5.75 Ring laser with contact pad layout Sorel et al. (2003) 5.6 Lasers 257 bidirectional regime is observed, where the two counterpropagating modes undergo harmonic alternate oscillations. Defined mixing of clockwise and counterclockwise ring laser modes of two ring lasers fabricated in InGaAs/GaAs/AlGaAs is used in Cao et al. (2005) to obtain frequency beating. The application of such integrated circuits is in ring laser gyros and optical rotation sensors. The ring lasers in the form of racetracks have a radius of 1 mm and a straight section length of 2 mm. Clockwise and counterclockwise operation is achieved by integrated absorbing spiral elements coupled to the ring waveguide located inside one ring and on the outside of the other ring. Tunability of the lasing wavelength of each ring is realized by integrated heaters. Single mode ring resonator laser operation using two coupled active ring lasers is demonstrated in Hamacher et al. (2003). The ring lasers are fabricated in the GaInAsP/InP material system. A photograph of the device is shown in Fig. 5.76. The ring laser consists of two coupled ring resonators having a radius of 50 μm. The ring resonators, the couplers and the bus waveguides can be driven independently by separate electrical contacts. Each ring resonator laser generates an individual slightly shifted comb like laser spectrum with respect to the driving current. Wavelength tuning to specific single mode emission is achieved using the Vernier effect. A measured single mode spectrum of the double ring laser configuration is shown in Fig. 5.77. A high side mode suppression ratio of >40 dB and a maximum output power of 6.5 mW per facet at a driving current of 250 mA is obtained. A single mode ridge waveguide (RW) laser coupled to two ring resonators using MMI couplers also in the material system GaInAsP/InP has been realized and demonstrated in Bach et al. (2003). The layout of the device is shown in Fig. 5.78. The diameter D1 and D2 of the ring resonators is 50 μm and 60 μm, respectively, leading to an overall FSR of 18 nm. The FSR of the ridge waveguide Fabry–Perot cavity is 0.5 nm and is small compared to the FSR of each of the ring resonators. Therefore only the FSRs of the ring resonators will contribute to the mode selection. The width w of the ridge waveguide is 4 μm. The facet width e inside the ring resonators is given by Fig. 5.76 Single mode operating double ring laser 258 5 Devices Fig. 5.77 Single mode output spectrum of a double ring laser Fig. 5.78 Layout of double ring laser. The ring resonators are also covered with BCB which is left out for illustration purposes Bach et al. (2003) e= √ 2 · w. (5.14) The ring resonators are not metal contacted and are only pumped through the straight ridge waveguide by a lateral carrier flow over the cap layer. A measured spectrum of such a double ring resonator laser is given in Fig. 5.79. Ring lasers have been made with deeply etched structures to provide a stronger confinement of the optical mode in the waveguide. This, however, comes at the price of higher threshold currents due to surface recombination and scattering losses. Another drawback is the fact that deeply etched structures lase in multiple lateral modes because of the large index step. Other types of waveguide designs used for realizing ring lasers like ridge waveguides or buried heterostructures with small index 5.6 Lasers 259 Fig. 5.79 cw laser characteristics at room temperature of a 700 μm long device with 50 and 60 μm ring resonators. The inset shows the emission spectrum at a drive current of 450 mA Bach et al. (2003) steps exhibit a better lateral mode confinement and have lower threshold currents. A detailed analysis of the lateral and longitudinal mode discrimination of ring lasers is presented in Nabiev et al. (1993). Ring lasers with different architectures (circular, square, and triangular ring cavities) and waveguide designs having a radius down to 50 μm have been described in this chapter. A theoretical comparison of photon recycling in circular, square, and triangular ring laser cavities is given in Numai (2000). Smaller devices have been fabricated by several groups and examples are given in Sect. 5.6.3. 5.6.2 Devices with Gain Section Merits of integrated ring resonators have been pointed out throughout this book. This chapter demonstrates again some of them, like the integration capability with active sections to enhance the characteristics of ring lasers. One of the first integration of an SOA with passive silica waveguides and coupler is demonstrated in Hibino et al. (1992). The gain in the ring resonator consists of a GaInAsP buried heterostructure SOA. The facets of the SOA are coated with antireflecting films made from SiO. Both facets of the SOA are coupled to lensed optical fibers with a lens radius of 7 μm. The SOA module is inserted into the passive integrated silica ring resonator using etched fiber grooves. The size of the module is 1.2 mm × 1.2 mm × 3 mm. The fibers are fixed to the passive waveguides using an 260 5 Devices UV curable resin. The total resonator length is 10.2 cm leading to an FSR of 2 GHz at a wavelength of 1.3 μm. A comb like lasing spectrum is obtained with a threshold current of only 17 mA. The device is temperature stabilized with a Peltier cooler. An active resonator with passive Y-coupler and outcoupling waveguides has been realized in the material system InGaAs-GaAs in Cockerill et al. (1994). The ring laser is made out of strained-layer InGaAs–GaAs buried heterostructure waveguides. The integration of the passive Y-coupler is made by selective area growth. The radius of the ring laser is 200 μm. The facets are antireflection coated to avoid back reflections. The laser operates at a wavelength around 1 μm with a threshold current of 25 mA. A side mode suppression of 24 dB is achieved. Passive circular sections, an SOA and a saturable absorber in the material system GaInAsP are used in Ohno et al. (2002) to fabricate a modelocked ring laser. The radius of the curved sections is 100 μm. Modelocking at frequencies of 29.5, 41.2, and 61.7 GHz is obtained for three different devices with corresponding SOA lengths of 1000, 650, and 300 μm and saturable absorber lengths of 30, 20, and 20 μm, respectively. An MMI coupler is used for output coupling. Ring lasers with MMI output couplers have been showed to have superior operation characteristics to devices with Y-junction couplers (examples have been given in this chapter and in the previous chapter for both coupling versions). A further improvement in performance of MMI coupled ring lasers as suggested in Pennings et al. (1994) is by the use of a single active gain section in the ring, and making the MMI coupler and outcoupling waveguides of passive waveguide material. The realization of a racetrack shaped ring resonator laser employing an SOA as the gain element, where the input and output waveguides, the MMI coupler and the curved ring sections are made out of passive material is described in the following paragraph. The passive waveguide is made from quaternary GaInAsP with a bandgap wavelength of 1.06 μm. The ring radius is 117 μm. The length of the MMI coupler is 150 μm. The fabrication details and the layer sequence of the passive waveguide have already been described in Chap. 3. A photograph of the ring laser with integrated SOA is shown in Fig. 5.80. Fig. 5.80 Photograph of a ring resonator laser with integrated SOA 5.6 Lasers 261 A standard ridge waveguide laser structure was used for the 500 μm long SOA section, which required an additional epitaxial growth step. The SOA is butt-coupled to the passive waveguide using a self-alignment process. The detail of the SOA as well as the fabrication process has been described in detail in Chap. 3.4.7. The butt coupling losses have been determined to be <2 dB each. The facets of the input and output waveguides have been antireflection coated. The ring laser has been designed to have an FSR of 50 GHz. The ring laser is operated at T = 17 °C. The lasing spectrum was measured using a tapered fiber and an optical spectrum analyzer. The relationship between the lasing power in the fiber and the injection current in the SOA is shown in Fig. 5.81. The threshold current is as can be seen from the diagram as low as 25 mA. The kinks in the L–I curve of the ring laser are accompanied by mode-hops and can be explained by coupled cavity effects, the second cavity being formed by the output path which includes the MMI coupler (Krauss et al. 1995a). The kinks have also been observed for fabricated ring lasers which do not have an antireflection coating on the facets of the outcoupling waveguides. The SOA does not form a cavity with the butt-joints. This has been verified by using a straight waveguide with integrated SOA (Fig. 5.82) where the input and output waveguides have been antireflection coated. Fig. 5.81 Output power characteristic of a racetrack laser Fig. 5.82 Photograph of a straight passive waveguide with integrated SOA 262 5 Devices No lasing has been observed in such a device with a 500 μm SOA. An interesting feature observed was that the same threshold current of 25 mA is obtained for a device which was not antireflection coated (Fig. 5.83). The measurement has been performed monitoring the output power directly using a photodiode. If Fig. 5.83 is compared to the output power characteristic of the ring laser (Fig. 5.81), the fiber– chip coupling loss which has been determined to be ~5 dB, has to be improved. This can be done for example by using a vertical taper. In the output power characteristic there are no kinks visible which leads to the assumption, that the kinks in the ring laser L–I curve are mainly attributed to the output path which includes the passive waveguides and the MMI coupler. This also indicates that the threshold current is only dependent on the butt-joint losses. The curved waveguide sections have negligible bending losses. The lasing spectrum of the racetrack laser at a drive current of 162 mA is shown in Fig. 5.84. An Advantest optical spectrum analyzer Q8384 with a maximum resolution of 10 pm in this wavelength range is used. The measured FWHM is therefore smaller than 1.25 GHz. The total power in the fiber is 0.6 mW per facet. As can bee seen from the lasing spectra, the side mode suppression ratio (SMSR) is 45 dB. The spectrum shows the designed FSR of 50 GHz of the ring resonator. The lasing spectra covering the entire 50 nm gain spectrum is shown in Fig. 5.85. It can be clearly seen that there is only one lasing mode. Ring lasers fabricated by a combination of active and passive waveguide sections enable the lowering of the threshold current as compared to all active devices, where the whole structure needs to be electrically contacted. Special attention has to be made Fig. 5.83 Output power characteristic of a straight waveguide with integrated SOA without antireflection coated input and output passive waveguides 5.6 Lasers 263 Fig. 5.84 Lasing spectra of a racetrack laser at a drive current of 162 mA, showing single mode operation with SMSR = 45 dB Fig. 5.85 Lasing spectrum of a racetrack laser showing single mode operation over a 50 nm gain spectrum when joining active and passive elements. Mode field profiles of both waveguides have to match as close as possible to minimize transition losses. 264 5 Devices 5.6.3 Passive Ring Resonator Coupled Lasers Ring resonator coupled lasers are different from the ring lasers in the previous chapter as the gain medium is placed outside the ring resonator cavity. Passive ring resonators serve as optical filters which enable single mode operation and tunability of the laser. Several examples including different architectures are described in this chapter. Ring resonator coupled lasers offer many promising advantages over conventional tunable lasers, including ultra wide wavelength tuning range, high side mode suppression ratio, uniform threshold and efficiency, narrow linewidth, and low frequency chirp. The integration of active gain sections, passive waveguides and ring resonators forming a ring resonator coupled laser has recently been proposed and analyzed in Liu et al. (2001). A schematic of the two proposed architectures is shown in Fig. 5.86. A detailed analysis of a single passive ring resonator coupled laser having a design like the one shown in Fig. 5.86b, with only one gain region as the output waveguide (the other waveguide is also passive like the ring) is given in Bian et al. (2003). One of the first fabricated passive single ring resonator coupled lasers is presented in Park et al. (2002a, b). A schematic of the layout of the device is shown in Fig. 5.87. One material is used for the ring coupled laser. The ring is operated in a transparent Fig. 5.86 Examples of passive ring resonator coupled lasers Fig. 5.87 Ring resonator coupled laser 5.6 Lasers 265 mode. Only the waveguides at the facets introduce gain into the device. The waveguides not leading to the facets act as absorbers. The ring coupled laser is made using the material system GaInAsP on InP. Three types of devices having a radius of 5, 10 and 20 μm are fabricated. The width of the waveguides is 0.4 μm. Directional couplers with a coupling gap of 0.2 μm are used. The bus waveguides are tapered to a width of 2 μm having a taper length of 200 μm. The FSR of the ring resonator is chosen large enough that a resonance is in the middle of the gain spectrum to achieve single mode operation. The threshold of the laser is 70 mA under pulsed operation. The lasing wavelength is measured to be 1.549 μm. In order to achieve single mode operation, the radius of the ring resonator has to be small, in the order of 10–20 μm. Another way to achieve single mode operation using passive coupled ring resonators is by using a double ring architecture. The ring resonators have slightly different radii which leads to an increase of the overall FSR as was described in Chap. 2. Passive double ring resonator coupled lasers (DR-RCLs) are analyzed theoretically in Liu et al. (2002). A double ring coupled laser is demonstrated in Rabiei and Steier (2003) using an integrated tunable polymer double ring filter, fiber coupled to an erbium-doped fiber amplifier, serving as the gain medium. Thermo-optic and electro-optic tunable devices are presented. The layer sequence of the device as well as the fabrication is similar to the ones described in Chap. 3. The radius of the ring resonators is 240 and 246 μm. The overall obtained FSR is approximately 39 nm at a wavelength of 1550 nm. A layout of the double ring resonator structure is shown in Fig. 5.88. One of several advantages of using a double ring resonator is the possibility of a higher tuning enhancement factor using the Vernier effect. The tuning enhancement factor is given by T = 1 1− L1 L2 = R2 , R2 − R1 (5.15) where L 1 and L 2 are the cavity lengths of each ring and R1 and R2 the radius, respectively. The tuning range of a double ring resonator is T times the tuning range of a Fig. 5.88 Layout of double ring resonator structure 266 5 Devices single ring. The polymer double ring resonator configuration has a tuning enhancement factor of 40. The transmission experiments are performed using TM polarized input light, fed to the input port of the double ring resonator from an erbium doped fiber amplifier which serves as the gain medium. An output power of 1 mW and a side mode suppression ratio of 30 dB are measured for both the thermo-optic and the electro-optic device. One of the first integrated double ring resonator coupled lasers in GaInAsP combining passive ring resonators with integrated SOAs is presented in Rabus et al. (2005). A photograph of a DR-RCL is shown in Fig. 5.89. The layer sequence and the dimensions of the waveguides are the same as is described in Chap. 3 for the passive ring resonator and the integration of an SOA into the ring cavity. Two configurations of DR-RCLs are investigated and the radii of the rings are 100 and 108 μm for the first configuration and 100 and 104 μm for the second configuration. An FSR of approximately 15 and 30 nm is obtained respectively. The coupling between the bus waveguides and the ring resonators is realized by a codirectional coupler with a length of 500 μm and a coupling gap of 1 μm. The coupling from the bus waveguide to the ring depends critically on the separation. The achieved splitting ratio is 3 dB. The laser cavity consists of SOA1 and SOA2 (see Fig. 5.89) which have a length of 500 μm each and the two ring resonators. The chip length is 2 mm. The remaining SOAs are not biased and they are used as absorbers to suppress the lasing of sub cavity modes. The end facets of the chip are as cleaved and are uncoated, which could be improved to increase the performance in the future. The output of the DR-RCL is collected using a tapered fiber at SOA2. The spectrum of the DR-RCL with an FSR of 15 nm is shown in Fig. 5.90, when the driving currents for SOA1 and SOA2 are 110 and 90 mA, respectively. Due to the fact that the FSR of the double ring resonator does not cover the entire gain spectrum, another lasing mode is present. The power difference between the two lasing modes is 13 dB. The threshold of the DR-RCL is about 30 mA when SOA1 is biased above 40 mA. The spectrum of the DR-RCL with an FSR of 30 nm is shown in Fig. 5.91. A side mode suppression ratio of >35 dB is obtained which is limited by the dynamic range (−35 dB) of the used optical spectrum analyzer (OSA). The linewidth of the Fig. 5.89 Photograph of a DR-RCL 5.6 Lasers 267 Fig. 5.90 Spectrum of a DR-RCL with an FSR of 15 nm Fig. 5.91 Spectrum of a DR-RCL with an FSR of 30 nm lasing wavelength is also limited by the bandwidth of the OSA which is 0.06 nm. From calculations, the linewidth is estimated to be <2 MHz. The driving currents for SOA1 and SOA2 are 100 and 90 mA, respectively. The output power varies with the currents supplied to SOA1 and SOA2 (Fig. 5.92). The threshold of the DR-RCL is about 25 mA when SOA1 is biased above 40 mA. An output power exceeding 1 mW is demonstrated in Bian et al. (2006). The resonance wavelength of the rings can be tuned by the integrated platinum resistors on top of the passive waveguides in the ring resonators. Varying the current of one heater results in a shift of resonance wavelength of the corresponding ring resonator due to the thermo-optic effect and the lasing can jump from one mode to the next one where the transmission peaks of the double ring resonators overlap. Figure 5.93 268 5 Devices Fig. 5.92 PI-curve of the DR-RCL with an FSR of 30 nm changing the current at SOA2 Fig. 5.93 Wavelength tuning by applying a current between 0 and 30 mA to the integrated Platinum heater shows a series of lasing spectra when varying the heater current between 0 and 30 mA. When the current of the integrated heater is changed, the laser produces 20 different modes, which are spread uniformly over a 17 nm wavelength range. Another architecture for a double ring resonator coupled laser is analyzed theoretically in Chung et al. (2005). The device consists of a coupled ring reflector and an active straight waveguide providing lasing activity. A schematic of the proposed device is shown in Fig. 5.94. The properties and formulas describing the behavior of coupled ring reflectors have been addressed in Chap. 2. The radius of the ring resonators is chosen to be different enabling a larger FSR for the coupled device utilizing the Vernier effect. 5.6 Lasers 269 Fig. 5.94 Schematic of a ring resonator reflector coupled laser Two different ring radii enable an enhanced tuning factor as is described in this chapter. The reflective properties are obtained by allowing inter ring coupling. A tunable laser based on a coupled ring reflector laser is fabricated and demonstrated in Choi et al. (2005). The device is fabricated by using a buried heterostructure waveguide design in the material system GaInAsP/InP. A photograph of the device is shown in Fig. 5.95. The radius of the used ring resonators is 130 and 140 μm, giving an FSR for each of the rings of 0.8 nm and 0.75 nm. The overall FSR is determined to be 12 nm. Tuning of the device is realized through the free carrier injection (FCI) method which shifts the resonance wavelengths by the free carrier plasma effect. The tunability of the device is shown in Fig. 5.96. Carriers are injected into the ring resonator having an FSR of 0.75 nm leading to a shift of the resonance wavelength of 0.8 nm which corresponds to 100 GHz at a wavelength of 1550 nm. Examples of ring resonator coupled lasers with different architectures have been presented in this chapter and due to this relative new research field, an improvement of the device parameters is expected in the coming years. Technological progress will also add to advancement in device performance. Ring resonator based devices both active and passive can be used for wavelength conversion as will be demonstrated in the following section. Fig. 5.95 Photograph of a fabricated coupled ring reflector laser. Photograph courtesy of Prof. Dapkus, University of Southern California, Department of Electrical Engineering—Electrophysics, VHE 314, Vivian Hall of Engineering, Los Angeles, CA 90089, USA 270 5 Devices Fig. 5.96 Measured tuning characteristics. Photograph courtesy of Prof. Dapkus 5.7 Wavelength Converters The four wave mixing (FWM) effect can be applied to passive and active ring resonators, enabling efficient wavelength conversion for all-optical communication systems. Ring resonators based on GaAs or InP combine both advantages of a high nonlinear susceptibility and a high linear gain. In contrast to other active resonant structures like distributed feedback (DFB) lasers or SOAs, ring resonators enhance both, the optical power of the signal wavelength at frequency ωS and that of the converted wavelength at ωC . Maximum conversion efficiency is achieved, when ωS and ωC fit one of the resonance wavelengths of the ring resonator. No stop-band has to be taken into account. Operating at wavelengths not being one of the resonance wavelengths of the ring resonator results in a reduced conversion efficiency. The internal optical field enhancement and the FSR can be designed by the radius and the power coupling ratio between the ring resonator and the bus waveguides. A passive GaAs racetrack shaped ring resonator is used in Absil et al. (2000a) to demonstrate wavelength conversion by four wave mixing with an improved conversion efficiency compared to a straight waveguide. A photograph of the device is shown in Fig. 5.97. The increase in efficiency is attributed to the increase of the interaction length and the enhancement of optical power inside the ring resonator cavity. Optical propagation losses limit so far the overall performance. A spectrum of the FWM measurement is shown in Fig. 5.98. The ring resonator used in the experiment has a radius of 4.2 μm. A coupling strength of 0.27 is obtained for the directional coupler. The properties of an all-optical wavelength converter with reshaping characteristics, based on FWM in a passive GaAs–AlGaAs ring resonator notch filter are investigated in Mikroulis et al. (2004). A detailed theoretical analysis of the static and dynamic reshaping characteristics of the wavelength converter is carried out. 5.7 Wavelength Converters 271 Fig. 5.97 Optical micrograph of a racetrack-shaped resonator with defined ports Absil et al. (2000a) Fig. 5.98 Optical spectra for on-resonance (solid curve) and off-resonance (dotted curve) cases Absil et al. (2000a) Improved conversion efficiency is expected in ring resonators fabricated as allactive ring resonators. An active ring resonator architecture used for wavelength conversion is demonstrated in Hamacher et al. (2003). A photograph of an electrically contacted ring resonator is shown in Fig. 5.99. The ring resonator has a radius of 182 μm including two 160 μm long MMI couplers which can be electrically driven separately to couple the light from the straight bus waveguide into the ring and vice versa. In analogy to FWM in DFB lasers the ring cavity itself can be used as the pump signal source. A proper choice of the driving currents provides a sufficient side mode suppression ratio of greater than 35 dB. An ECL acting as a cw signal source is used in the FWM experiment. The result of this experiment with a cw output power of 2 dB m measured in the feeding fiber is shown in Fig. 5.100. A conversion efficiency 272 5 Devices Fig. 5.99 All active ring resonator Fig. 5.100 Optical cw spectrum measured at the throughput port exhibiting a conversion efficiency of − 5 dB (relation of the intensities in the feeding fibers) of −5 dB is derived from the measurement of the output power. Taking into account that the input signal will be increased due to the high power enhancement of the active ring structure, the conversion efficiency can be corrected by a factor of 8 dB, resulting in an “effective” conversion efficiency of 3 dB. Instead of selecting a single mode laser spectrum by using a ring resonator with a small radius and/or a proper choice of driving currents as mentioned in the previous example, it is also feasible to obtain a mode selection by injection locking. If the frequency of the master laser (in the test set-up a second ECL, amplified by an erbium-doped fiber amplifier) is close enough to the ring resonator’s free-running frequency and the signal amplitude is large enough, the device is locked to the master frequency over a certain bandwidth. This approach may be favored for practical use in a real system in order to realize a well controlled resonator of specified FSR for FWM and to control the pump signal by injection locking in a separate device (master laser). 5.7 Wavelength Converters 273 To demonstrate the FWM capabilities of an all active device, an all-optical cw channel switching experiment is performed. In this experiment the cw signal at ωS is kept fixed at a resonance wavelength of the ring resonator of 1567.9 nm. For maximum conversion efficiency the injection locked pump wavelength ωP is chosen to fit one of the resonances of the ring resonator. When the detuning of the pump wavelength is changed stepwise by multiples of the FSR, the converted signals at ωC = 2ωP − ωS fit the resonances of the ring resonator as well. In this way the conversion efficiency can be kept at a maximum level over a tuning range of multiples of the FSR, which is verified in the experiment. Due to a high coupling factor of 0.7, the enhancement effect of the ring is limited and a conversion efficiency of approximately −20 dB is obtained. The result of the measurement is shown in Fig. 5.101, where λC is the converted wavelength, λP is the pump wavelength and λS is the signal wavelength. Wavelength conversion can also be performed using passive ring resonators with integrated SOAs (Fig. 5.80) as the pump laser and inserting a signal wavelength Fig. 5.101 All optical channel switching experiment in cw operation using injection locking. The signal wavelength is fixed and the pump wavelength routes the conjugated signal 274 5 Devices into the bus waveguide placed on a resonance of the ring resonator. A spectrum of the ring resonator operating as a laser without signal and pump wavelength is shown in Fig. 5.102. The result of an FWM experiment using this racetrack shaped ring resonator with integrated SOA is shown in Fig. 5.103. The ring resonator has a radius of 117 μm. A directional coupler with a gap of 1 μm and a length of 150 μm is used for coupling into and from the resonator. The overall FSR is 0.4 nm which corresponds to 50 GHz at a wavelength of 1550 nm. A conversion efficiency of approximately —6 dBm is achieved. The driving current for the SOA is 119 mA. The Fig. 5.102 Passive ring resonator with integrated SOA in laser operation Fig. 5.103 FWM in a ring resonator with integrated SOA 5.7 Wavelength Converters 275 signal wavelength is inserted into the ring resonator from an ECL which is amplified by an erbium doped fiber amplifier (EDFA) to a total signal power of 3 mW. Wavelength conversion using integrated ring resonators is a relative novel research direction as it requires either low loss passive ring resonators or active devices to achieve comparable conversion efficiencies as if using straight SOAs for example. This chapter proves again the versatility of ring resonator devices. In the following chapter, an emerging field will be introduced with several practical examples: optical signal processing using ring resonators. 5.8 Optical Signal Processing Optical signal processing (OSP) is one of the research areas which are receiving an increasing amount of interest from the all-optical network community. In OSP, light is used to influence, switch and control light. OSP has several advantages compared to electrical signal processing. One of them is the higher processing speed, which has been demonstrated to be as high as 100 Gbit s−1 . Elements used for OSP can be fabricated with current state-of-the-art technologies and are easier to be realized than compared to similar solutions in electrical signal processing. Several books can be found dealing with the fundamentals of OSP. The focus in this chapter is on integrated ring resonators in optical signal processing. Ring resonators can be used for realizing all-optical switches, multiplexers, and logic gates. 5.8.1 Logic Gates All-optical logic gates have evolved in the last couple of years and have received considerable attention. Examples of potential applications in optical signal processing systems are optical bit-pattern recognition, bit-error rate monitoring, payload separation and all-optical packet addressing. One of the most obvious applications of ring resonators in connection with logic gates is the use as optical delay lines. In optical logic gates, control signals need to be overlapped in time with incoming data signals. As was shown in an earlier chapter, ring resonators used as all pass filters can address this application. Optical delay lines can also serve as an optical buffer to delay signals until the system is ready to process them. A detailed analysis of all pass filters used as optical delay lines is given in Lenz et al. (2001). Multiple coupled all pass filters are investigated theoretically in Azaña and Chen (2002) for optical signal processing applications, especially for real-time Fourier transformation (RTFT) and pulse repetition rate multiplication (PRRM). Optical signal processing using fabricated nonlinear integrated ring resonators is presented in Van et al. (2002a). Applications of the ring resonators to switching, timedivision demultiplexing, pulse routing, and wavelength conversion (see Sect. 5.7) 276 5 Devices using four wave mixing are demonstrated. The authors also propose architectures for realizing OR, AND, and XNOR optical logic gates with ring resonators. A schematic of the proposed logic gates is shown in Fig. 5.104. The used input signals A, B, and C are tuned to resonances of the ring resonator. Signal C can be regarded as a constant bias to the gate in the case of asynchronous operation, or as a clock in the case of synchronous operation. In the case of the OR and AND gate, the signal wavelength C is not detected at the output D when signals A and B are not inserted. In the XNOR configuration, the MZI is balanced only when signal C is present, leading to a signal at output D. In all three configurations, a bandpass filter (BPF) only allows the wavelength λout to pass through. In the OR configuration, signal C is brought off-resonance by either signal A or B which can then be detected at output port D. In the AND configuration, both signals A and B need to be present for signal C to be off-resonance so that it can be detected at output port D. In the case of the XNOR gate, signal C will be off-resonance either by the presence of signal A or B, inducing a π phase shift in the MZI and thus leading to destructive interference at output port D which means no signal is detected. A signal at output port D is detected on the other hand if both signals A and B are inserted into the gate, signal C is off-resonance, the MZI is balanced and signal C can be detected Fig. 5.104 Optical logic gates using ring resonators. Signals A and B are tuned to resonance wavelength λin ; signals C and D are at resonance wavelength λout ; BPF: bandpass filter Van et al. (2002a) 5.8 Optical Signal Processing 277 Fig. 5.105 Signal paths leading to AND/NAND operation in a racetrack shaped ring resonator filter at output D. As described in Sect. 5.5, the speed of operation depends on the cavity ring-down time of the ring resonators. All optical AND and NAND logic gates are demonstrated experimentally in Ibrahim et al. (2003b). The nonlinear effect used in the experiment is the change in refractive index from free carriers generated by two-photon absorption. InP and GaAs-based racetrack shaped notch filters are used. The InP device has a radius of 10 μm and a 3 μm long straight section. A schematic of the signal paths is shown in Fig. 5.105. The intensity of the pump beams A and B are alone not strong enough to induce switching of the probe beam. The probe signal which is initially tuned to one of the resonance wavelengths of the ring resonator leading to a “0,” is detected at the receiver when both input signals A and B are fed into the ring resonator corresponding to a “1.” When the probe beam is slightly “blue” shifted and out of resonance obtaining a “1,” NAND gate operation is achieved when both input signals A and B are fed into the ring resonator leading to a shift of the probe beam into a resonance wavelength resulting in a “0” at the receiver. The experiment using the InP device is performed with a mode-locked laser at 5.6 GHz, externally modulated at 140 MHz. The pump pulse has a pulsewidth of 35 ps and energy of 20 pJ. The result of the measurement demonstrating AND logic gate operation is shown in Fig. 5.106. The GaAs sample, similar to the InP device, exhibits an FSR of 11 nm. A gainswitched laser diode at 8.4 GHz and externally modulated at 140 MHz, is used for the data source. The pump pulse energies of 80 pJ per pulse are inserted into the input port of the device. The measurement of the device showing AND/NAND operation is given in Fig. 5.107. An all optical AND logic gate based on the four wave mixing (FWM) effect is theoretically analyzed in Mikroulis et al. (2005). A GaInAsP ring resonator notch filter is used for the calculation with a cavity length of 69 μm. Optical logic gates realized with ring resonator filters are a promising approach which has room for improvement in the future as smaller devices and material configurations are fabricated and investigated. 278 5 Devices Fig. 5.106 Time traces showing an AND logic gate using the InP ring resonator: a “A” and b “B” are the two input pumps tuned to the resonance at 1550 nm and c “F = A • B” is the output probe signal tuned to the next higher resonance at 1560 nm Ibrahim et al. (2003b) 5.8.2 Switching All optical switches rely on the control of light by light (the principle of optical signal processing) as was shown in the previous section for logic gates. In order to induce switching, an optical control signal is used to change the optical properties of a nonlinear medium. The device, in this case the ring resonator, then switches the data signal, which experiences the changed transmission properties when it passes through. In all-optical switches MZIs with SOAs have been used so far where the SOAs provide the nonlinear media. In the case of ring resonators, material systems providing nonlinearity are required which does not necessarily mean to introduce electrically contacted gain into the cavity. Ring resonators are ideal for optical switching as they have a high Q-factor and can be monolithically integrated. A high field enhancement and finesse in the ring can lower the switching threshold significantly. One of the first experimental demonstrations of all optical switching in GaAs ring resonators is given in Van et al. (2002b). Switching is accomplished by a refractive index change in the ring resonator due to free carriers generated by two-photon absorption. This switches the probe wavelength in and out of resonance. The radius 5.8 Optical Signal Processing 279 Fig. 5.107 Time traces showing logic operation using the GaAs resonator: a and b are the inputs “A” and “B” tuned to the resonance at 1548 nm; c output “F” when the probe was initially in resonance at 1559 nm; and d output “F” when the probe was initially blue tuned out of resonance at 1558.6 nm Ibrahim et al. (2003b) of the used vertically coupled ring resonator notch filter is 10 μm. The parameters of the device are as follows: FWHM = 0.16 nm, Q-factor = 9, 800, F = 70, calculated field enhancement factor = 7.3, calculated cavity lifetime = 40 ps. The switching experiment is carried out using an externally modulated laser diode, producing a 300 ps pump pulse signal with a 20 MHz repetition rate with an average input power of 10 mW. A 3 mW cw signal is used for the probe wavelength. The pump wavelength is slightly out of resonance whereas the probe signal is placed on a resonance of the ring resonator. The result from the experiment is shown in Fig. 5.108. Both pump and probe beams are inserted at the input port of the ring resonator via a fiber coupler. After passing through the ring resonator notch filter, the pump and probe beams are amplified and separated by a bandpass filter. Switching times of the probe beam of approximately 100 ps is observed. A similar ring resonator geometry is used in Ibrahim et al. (2002) to demonstrate all-optical time division demultiplexing and spatial pulse routing. The radius of the ring resonator add–drop filter is 10 μm. The cavity lifetime of the ring is measured to be approximately 30 ps. Switching is again accomplished by a refractive index change 280 5 Devices Fig. 5.108 Measured time traces of the pump-and-probe beam intensities with a probe beam initially on resonance (low transmission) and b probe beam initially off-resonance (high transmission). The transmitted probe intensity is normalized with respect to the maximum transmittance at resonance Van et al. (2002b) induced by two-photon absorption. A data pulse inserted into the ring resonator is demultiplexed and collected at the drop–port of the ring resonator filter. An on–off contrast ratio of 8 dB is achieved. A detailed theoretical analysis of the nonlinear transfer functions of ring resonators is given in Blair et al. (2002). Ring resonators are compared to straight nonlinear sections of different lengths. Ring resonators are demonstrated to have a higher nonlinear phase shift induced by linear and two-photon absorption when compared to nonlinear straight devices. Based on the simulated results, a design for an MZI with integrated ring resonator is presented. One of the first disk resonators with an electro-absorptive active region is presented in Djordjev et al. (2002f). The disk uses the quantum confined Stark effect (QCSE) to loss trim the frequency response of the resonator cavity. The disk vertically coupled to two bus waveguides has a radius of 10 μm, an FSR of 10.5 nm, a Q-factor of 5700 and an F of 40. The transmission and dropped coefficients can be changed by introducing additional loss into the cavity at a particular wavelength. One advantage of using electro-absorptive ring or disk resonators is that the light is not absorbed as strongly as it would be in an MZI configuration. Switching in ring or disk resonators is done by changing the resonance characteristics which directs the light to the drop–port for example. All-optical switching in a racetrack shaped laterally coupled ring resonator add– drop filter by carrier injection induced by single photon absorption is demonstrated in Ibrahim et al. (2003a). Single photon absorption is achieved by optically pumping the used material above its bandgap energy, generating electron–hole pairs, which in turn alter the gain–loss coefficient and the refractive index. In comparison to two photon absorption, the pump beam does not need to be located on a resonance of the ring resonator, reducing the cavity ring-down time leading to a reduction in the switching 5.8 Optical Signal Processing 281 time. The parameters of the used ring resonator add–drop filter is: FWHM = 1.3 nm, Q = 1, 200, FSR = 18 nm, and a finesse of 14. In the experiment, the ring resonator is pumped from the top with a Ti:Sapphire laser with a wavelength of 800 nm. A switching window of 20 ps is obtained. Two switching schemes are demonstrated. In the first, the inserted wavelength is located near a resonance causing it to be on a resonance when the ring resonator is pumped. The signal is then switched to the drop–port. In the other scheme the signal is tuned to a resonance and by pumping the ring, the signal is switched to the throughput port. In this way, a modulator is implemented. A switching contrast of approximately 7 dB is achieved. A switching time of only 20 ps is demonstrated in Hill et al. (2004) using integrated ring lasers in GaInAsP/InP having radii of 8 μm. A photograph of the fabricated device is shown in Fig. 5.109. The width of the waveguides is 2 μm. The lasers are operated at 281 K in pulsed mode, with current pulses of 80 ns duration every 13.5 ms. The threshold current is approximately 30 mA. The double ring laser device can have two stable states. In one state, light from ring laser A injection locks ring laser B, forcing it to lase only in the clockwise direction. In the second state, ring laser B injection locks ring laser A, forcing it to lase only in the anticlockwise direction. Pulses of light at the chosen input can set the system in the corresponding state. Optical signal processing using ring resonators is a useful alternative to for example MZIs and progress in research on the switching behavior of these devices will eventually lead to an implementation in all-optical networks. Fig. 5.109 A memory element formed by two 16 mm diameter microring lasers coupled via a waveguide on an InP/GaInAsP photonic integrated circuit. Scale bar, 10 mm. The microring lasers were fabricated in active areas of the integrated circuit containing bulk 1.55 mm bandgap GaInAsP in the light guiding layer. Separate electrical contacts allowed each laser’s wavelength to be individually tuned by adjusting the laser current. Passive waveguides connected the microring lasers to the integrated circuit edges Hill et al. (2004) 282 5 Devices 5.8.3 Telecom Operations Optical networks consisting of fiber optics are the standard in telecom networks carrying the highest data rate capacity. Especially now in the digitization and internet age, optical networking topologies have evolved and more than ever single optical components are required to handle the vast amount of data traffic in terms of wavelength channels. More information on the topology of different optical networks can be found in Robertazzi (2017) and Bianco et al. (2012). Ring resonators as described in several chapters in this book are ideal building blocks for such all optical networks of the future as they can be used as optical switching elements (SE) which are the key components of all optical networks. Another important building block is a ring resonator enabling wavelength conversion via four wave mixing. This topic has been addressed as well in this book with practical examples. Four wave mixing or wavelength conversion is necessary in all optical networks to change the wavelength of a data channel without the need of optical to electrical conversion. It is beyond the scope of this book to treat the Four wave mixing, that has been treated in details in other publications (Martini and Politi 2017) and references therein quoted. Ring resonators have the advantage of being able to be integrated with other optical components like detectors, so that optical switches based on ring resonators can be integrated together with optical detectors on a chip, thus enabling large scale matrices with detectors for high speed all optical networking. In addition to optical switches, optical modulators are the other work horses of all optical networks which have been addressed in another section of this book. In classical interconnection networks, it is known that input signals suffer power losses independent of the state of the SEs in interconnection networks. On the contrary, microring resonator SEs based systems show an intrinsic asymmetric statedependent behavior: as a matter of fact, because optical signals coupled/not coupled to the ring undergo to different power degradation, depending on the specific microring design. From a general point of view, as described in details by Garrich and Neri (2009), the ring resonator has a transfer function identical to that of a Fabry–Perot cavity. It represents a relatively small free spectral range (FSR) that corresponds to the wavelength spacing used in dense-WDM (0.8 nm). Since a microring can be tuned by several methods for example, carrier injection, electro-optic effect or thermal tuning, it is possible to shift the transfer function. Two possible states of the 1 × 2 microring based switching element are therefore possible: untuned and the tuned stated respectively. In the untuned state, the signal enters the input port and goes out by the throughput port. In this state, the signal wavelength matches with the maximum signal through in the transfer function and therefore the signal undergoes negligible losses 0.1 dB (power through ON). At the same time, a small part of the useful signal is deflected to the drop port and therefore a power leakage is observed (called power drop OFF) (Garrich and Neri 2009). In the tuned state, the signal wavelength matches with the maximum signal of the drop port curve in the transfer function (Garrich and Neri 5.8 Optical Signal Processing 283 Fig. 5.110 Elementary microring-based switching elements (Bianco et al. 2012) 2009). In this case the useful power is obtained at the drop port (called power drop ON) that is lower than the previously power through ON. Experimental measurements report that coupling the ring in order to reach the drop port brings a non negligible attenuation 2.3 dB (Garrich and Neri 2009). At the same time, a higher value of power leakage is obtained at the through port (called Power through OFF) since the signal does not couple into the ring (Garrich and Neri 2009). Starting from this simple description, optical switches based on ring resonators can have the following configurations (Bianco et al. 2012) depicted in Fig. 5.110. Different architectures can be built from this exploitation. In a microring resonator OS (for example, Fig. 5.110a), an incoming optical signal can be either coupled to the ring or it can continue along its path: the first case is achieved when the input signal wavelength is matching to the resonance wavelength of the microring, the second if the input signal wavelength is different from the resonance wavelength respectively. The classical ring resonator switching configuration where a wavelength channel is either “dropped” at the drop port from the input port or passed through to the “throughput” port. This single element can be cascaded to create a switching matrix consisting of several hundred switches, enabling all optical switches in real time without any need for optical-electrical conversion and thus no data transmission speed loss. This behavior is at the basic one to switch an incoming signal to a different output port, depending on the ring resonance wavelength. In order to provide the architecture scalability, it is important to minimize the power degradation through the interconnection network. To this aim, many efforts have been made to propose architecture designs and suitable algorithms to control the OS configuration that will not be treated here since beyond the scope of this book. The other two configurations depicted in Fig. 5.110b and c are starting configurations for large scale optical switching matrices and the reader is advised to consult the corresponding publication for further details. It is however useful to recall that microring-based switching elements 1B-SEs present an asymmetric power degradation depending on the switching state. As a consequence, as summarized in Bianco et al. (2012) the design of the microring resonator is based on a tradeoff between different figures of merit. As a consequence 284 5 Devices a large coupling coefficient between a microring and adjacent waveguides leads to low power degradation in signals deflected to the drop port but high degradation to signals sent towards the through port respectively. On the contrary, a small coupling coefficient between a microring and adjacent waveguides leads to high degradation in signals deflected to the drop port but low degradation to signals sent. In the microrings controlled by laser pumps, input signals sent to the drop port undergo to higher power losses (around 1.5 dB) than signals routed to the through port (with negligible losses). As a matter of fact, there is a small coupling coefficient between the microring and the drop/through waveguides. In this case the loss behavior of the 1B-ES with a simplified model based on two loss states, assuming either a high-loss state (HLS) or a low-loss state (LLS). In general these are the basic architectures for interconnection networks mostly used: crossbars, Clos networks, and Benes networks respectively. Hybrid configurations are possible, to optimize the final performance in terms of degradation index and area. Crossbars Network Crossbars can be built exploiting the 1B-SE switching element configuration, as depicted in Fig. 5.111: column waveguides are connected to the input ports and row waveguides to the outputs (Bianco et al. 2012). The crossbar exhibits the best Fig. 5.111 4 × 4 microring-based crossbar connecting 1 → 4, 2 → 2, 3 → 1, and 4 → 3 (Bianco et al. 2012) 5.8 Optical Signal Processing 285 Fig. 5.112 Rearrangeable non-blocking Clos network (Bianco et al. 2012) scalability in terms of degradation index: although routing is easily achievable, they exhibit the worst scalability in terms of area. Clos Network When a lower number of switching elements (SEs) than the crossbar are used, a multistage interconnection networks, like the well-known Clos networks is created. Figure 5.112 reports a symmetric three-stage Clos network as example. In this case each switching module (SM) of the first stage and of the third stage is connected with all the SMs of the middle stage (Bianco et al. 2012). As a consequence, the first design parameter is the number of SMs in the first and the third stage, respectively, denoted by k. The second design parameter is the number of SMs in the second stage, influencing the blocking property. In the case that n = N/k SMs in the middle stage, this is the minimum n value that guarantees a non-blocking rearrangeable network. As a consequence, the first-stage and third-stage SMs are of size n × n, and the second-stage SMs are of size k × k. Benes Network Benes networks are basically Clos networks recursively constructed with basic SMs of size 2 × 2. In this way N = 2h for some integer h. They present the best scalability, being asymptotically optimal. It is worth mentioning that an N × N Benes network has a number of stages (columns of 2B-SEs) equal to 2log2 N − 1, each stage including N/2 basic 2B-SEs. 286 5 Devices References Absil, P.P., Hryniewicz, J.V., Little, B.E., Wilson, R.A., Joneckis, L.G., Ho, P.T.: Compact microring notch filters. IEEE Photonics Technol. 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Integrated waveguide-based sensors have gained attention since the downturn of the telecommunication industry left several research groups looking for other fields of application. But this is not the only cause. The focus of research has turned more and more towards biology where single molecule and single cell detection are the envisaged goal. This chapter provides an overview of sensors based on integrated ring resonators in microfluidics, optofluidics and special focus on biosensors. The following examples demonstrate the wide range of application of integrated ring resonators which has grown tremendously in the last 20 years. In Table 6.1 a comparison among the most used sensor configuration is provided together with some key sensing parameters such as bulk sensitivity, system detection limits and intrinsic detection limits depending on the sensor configuration. He values therein reported should be considered as a order of magnitude of what currently available, destinated to improve in time thanks to the constant optimization of technologies and the advent of new ones. Sensors for Measuring Optical Properties of Waveguides A silicon based integrated ring resonator notch filter with a radius of 3 cm is used in Adar et al. (1991) to measure the loss in phosphorus-doped silica on silicon waveguides. The finesse of the resonator is 45. The measuring principle used is the fact that waveguide loss is related to the width of the resonances (see Chap. 2). The ring resonator is placed on a temperature controlled surface. An ECL kept at a constant wavelength, with a linewidth smaller than the width of the resonances of the ring resonator is used as the input source. The temperature is changed and the response of the ring resonator is measured, revealing the filter function characteristic for ring resonator notch filters. As the FSR is known from the parameters of the ring © Springer Nature Switzerland AG 2020 D. G. Rabus and C. Sada, Integrated Ring Resonators, Springer Series in Optical Sciences 127, https://doi.org/10.1007/978-3-030-60131-7_6 293 Sensor configuration MZI Ring Sensor type Interferometer Microcavity TM TE TE TE TE TM TE TM TM TM TE TM Vernier Vernier Slot/critical coupling Multi-box SWG SWG SWG Slot Suspended Thin WG N/A Thin WG 1.31 μm Wvl TE N/A TM TM N/A Vernier/suspended TE TE 1.31 μm Wvl TE Suspended Slot TE Optical mode Vernier Strategy 33.5 24 10.1 4.5 12 0.33 9.8 7 2.6 6 20 15 N/A N/A N/A N/A N/A N/A N/A Q-factor (×103 ) nm 113 nm 133 nm 200 nm 270 nm 290 nm 298 nm 429 nm 490 nm 580 nm 1.3 × 103 nm 1.3 × 103 nm 2.43 × N/A 4.6 × 105 nm 104 N/A N/A 300 × 2π rad N/A N/A N/A N/A N/A (continued) 1.49 × 10−3 5 × 10−4 7.5 × 10−4 1.2 × 10−3 N/A 1.59 × 10−2 4.2 × 10−5 5.5 × 10−4 1.02 × 10−3 3.71 × 10−4 10−6 N/A 2× N/A <10−4 N/A 5.05 × 10−4 N/A N/A N/A 4.8 × 10−6 N/A [44] 3.3 × 10−5 460 × 2π rad N/A N/A 1.29 × 4 × 10−5 N/A 1730 × 2π rad 10−5 N/A Intrinsic detection limit (RIU) 540 × 2π rad N/A N/A 2.15 × 104 nm 740 nm System detection limit (RIU) Bulk sensitivity (RIU−1 ) Table 6.1 Comparison among the most used sensor configuration is provided together with some key sensing parameters, WG, waveguide; Wvl, wavelength, 1.55 μm where not specified (Luan et al. 2019) and references therin quoted 294 6 Sensors Uniform Phase-shifted 1D 2D Disk Sensor configuration TM TE 1.31 μm Wvl N/A TE TE Slot N/A TE Multi-box SWG TE N/A TE Ring-slot TE TE N/A Slot TE TE N/A Slot TM Suspended TE N/A TM TE 1.31 μm Wvl N/A Optical mode Strategy Reprinted under Creative Commons Attribution (CC BY) license Bragg grating Photonic crystal Sensor type Table 6.1 (continued) N/A 27.6 76 15 6.2 3 174 11.5 0.4 50 33 0.1 16 15 9.8 Q-factor (×103 ) 103 182 nm 59 nm 106 nm 340 nm 610 nm 130 nm 815 nm 160 nm 200 nm 1.5 × 26 nm 130 nm 142 nm 38 nm 91 nm nm Bulk sensitivity (RIU−1 ) N/A N/A N/A N/A N/A 7× N/A N/A 2× 10−5 10−3 10−6 10−4 7.8 × N/A 8× N/A N/A N/A System detection limit (RIU) N/A 9.3 × 10−4 1.6 × 10−4 3 × 10−4 4 × 10−4 4 × 10−3 1 × 10−5 8.75 × 10−5 1.88 × 10−2 2.07 × 10−5 1.8 × 10−3 1.18 × 10−1 6.8 × 10−4 2.7 × 10−3 3.5 × 10−4 Intrinsic detection limit (RIU) 6 Sensors 295 296 6 Sensors Fig. 6.1 Integrated microring resonator displacement sensor for scanning probe microscopies resonator, the width of the resonances can be taken directly from the transmission experiment leading to the waveguide loss. An integrated ring resonator sensor is analyzed theoretically in Kiyat et al. (2004) to be implemented in a setup to measure the displacement in scanning probe microscopy. A schematic of the proposed device is shown in Fig. 6.1. The displacement of the cantilever changes the refractive index of the ring resonator which changes the transmission spectrum. Several designs including racetrack-shaped ring resonators are simulated and compared. The highest sensitivity is obtained for a racetrack-shaped ring resonator. Sensitivities as high as 10−4 Å−1 are calculated. Waveguide birefringence is measured in Carriere et al. (2004) by using an integrated ring resonator with a radius of 14 mm, fabricated by ion exchange in glass. The waveguide birefringence is defined as the difference between the effective refractive indexes of transverse electric and transverse magnetic modes. The birefringence nBi ; is calculated using the FSR of a ring resonator as follows (Carriere et al. 2004). Using (2.21) where the group refractive index is used, the shift in wavelength between the two polarization states seen in the FSRs is given by FSRBi = FSRTM − FSRTE 1 λ2 1 . = − L n gTM n gTE (6.1) The waveguide birefringence is defined as n Bi = n eff, TE − n eff, TM . (6.2) Using (2.20), the waveguide birefringence in terms of the FSRs is given by n Bi = FSRBi λ2 · . L FSR(FSR − FSRBi ) (6.3) 6 Sensors 297 Fig. 6.2 Cross-section and photograph of the polymer ring resonator used for the strain sensor. Dimensions are in μm Bhola et al. (2005) Fig. 6.3 Application of controlled strain using a micrometer stage. E is the strain and R the radius of the bend Bhola et al. (2005) This equation is straight forward and the birefringence is easily calculated from the measurement of the FSRs. In order to differentiate the birefringence induced by the curved sections of a ring resonator, racetrack-shaped and full circle resonators can be compared in terms of their birefringence. The difference is only due to the contribution of the straight waveguide sections. Sensors of Strain Ring resonators are not only used for measuring birefringence in waveguides, but can also be applied to determine strain. In Bhola et al. (2005) a polymer ring resonator strain sensor is demonstrated. A photograph and a cross-section of the fabricated device are shown in Fig. 6.2. A sketch and a photograph of the strain sensor attached to a micrometer stage are shown in Fig. 6.3. An advantage of using ring resonators as strain sensors is that the direction of the strain does not matter due to the ring geometry. The sensitivity can be increased by using a racetrack shaped ring resonator. In this case two racetrack-shaped ring resonators perpendicular to one another can be used to determine the direction of the strain. 298 6 Sensors Fig. 6.4 Layer sequence of waveguide in a ring resonator gas sensor These examples demonstrate a small variety of sensors realized with integrated ring resonators in different materials. Lately biosensors have attracted a lot of attention and ring resonators are again focus of research in this new emerging field. Sensors of Gas So far solids or liquids are detected with ring resonators. A gas sensor is fabricated and demonstrated in Ksendzov et al. (2004) which utilizes a polymer sensing layer. The racetrack-shaped ring resonator add–drop filter has a radius of 1.5 mm. The straight sections have a length of 0.1 mm with a coupling gap of 2 μm. The layer sequence of the waveguide used is shown in Fig. 6.4. The polymer swells in the presence of the analyte and changes its refractive index due to chemical permeating. The resonance wavelength is monitored with a tunable laser and the shift is detected in dependence of the concentration of the analyte. The fabricated ring resonator is brought into a sealed chamber and a controlled mixture of air, water vapor, and isopropanol is inserted. Sensitivity to isopropanol of 50 ppm is shown experimentally. Sensors of Temperature The optical path length of the ring waveguide changes when thermally-induced effects act to modify the effective refractive index. Consequently, a shift of the resonance wavelength occurs that can be probed and monitored by a tunable laser or spectrometer (Kwon and Steier 2008; Kim et al. 2010; Xu et al. 2014). In these works, it has been reported that in SOI ring resonators a temperature sensitivity close to ~80 pm/°C can be achieved. Apart from the sensitivity, the temperature detection limit (otherwise often addressed as temperature resolution) and the sensing range are of key importance. Whilst the temperature resolution it is related to the sensor resolution and sensitivity and of the performances of the linewidth tunable laser and/or spectral analyzer used, the sensing range is determined by the free spectral range (FSR) of the ring resonator. The last corresponds to the temperature change able to induce the resonance wavelength shift to a full FSR. In order to increase the sensing 6 Sensors 299 range the easy way is to increasing the FSR, feasible by coherently reducing the ring size. There are several devices that have been demonstrated: the most known are a sensing range of 120 °C have been realized by a 9.2 μm-radius ring resonator, whilst a 280 °C of sensing range by a 4 μm-radius ring resonator respectively. Many efforts have been devoted to improve the temperature sensing performances of ring resonators employing different ring resonator configurations. Among those sure it deserves to cite: cascaded ring resonators (CRR) (Dai 2009; Zamora et al. 2013) for realizing the Vernier effect and get higher sensitivity-finesse and FSR, vertically stacked ring resonators for obtaining resonance splitting (Campanella et al. 2014), and Bragg grating ring resonators for achieving resonance splitting and Fano resonance (De Leonardis et al. 2014) and get enhanced sensor resolution. As reported in Kim (2016), in a conventional CRR sensor configuration two ring resonators are exploited in which one acts as reference resonator and the second ad sensor resonator respectively. They are designed to have slightly different FSRs (FSR1 and FSR2 , respectively) and to respond differently to a given sensing input: the resonance wavelength of the sensor resonator shifts whilst the reference resonator provides unchanged resonance wavelength. In case that the dispersion is neglected, the FSR of the CRR is therefore given by Claes et al. (2010) FSRCRR = FSR1 · FSR2 /(FSR1 − FSR2 ) (6.4) so that the CRR sensitivity is magnified by a factor of FSR · CRR/FSR2 . On the contrary the sensing range is determined by the FSR of the sensor resonator and does not benefit of amplification. Although extremely convenient, the CRR configuration is not trivial to be achieved because it requires that the reference resonator is isolated from a temperature change. Alternatives have been proposed such as depositing a cladding layer with negative thermo-optic coefficient such as polymer or TiO2 (Ye et al. 2008; Guha et al. 2013) on the reference resonator to prevent its temperature sensitivity. Polymers are not CMOS compatible and therefore present several drawbacks whilst and the selective deposition of a negative thermo-optic cladding layer is quite expensive requiring several steps made procedures. To solve this problem, Kim (2016) realized two micro ring resonators with different temperature sensitivities and different free spectral ranges (FSRs) by tailoring the in-plane geometric parameters of the two ring resonators respectively. A scheme of the final device is reported in Fig. 6.5. The CRR temperature sensor was therefore prepared by using a singlemask complementary metal–oxide–semiconductor (CMOS)-compatible process. A temperature sensitivity of 293.9 pm/°C has been demonstrated and a temperature sensing range increased by a factor 5.3 times. A sketch of the CRR temperature sensor operation is shown in Fig. 6.6 where a cascaded configuration of Rings 1 and 2 is reported together with the Transmission spectra at the drop ports of the two ring resonators, and at the output of the CRR respectively. Finally, the derivative of the effective refractive index neff respect the temperature as well as the temperature sensitivity of a ring resonator as a function of waveguide 300 6 Sensors Fig. 6.5 a Optical microscope image of the fabricated CRR temperature sensor. SEM images of the ring and bus waveguides in the coupling region for b Ring 1 and c Ring 2 (Kim and Yu 2016). Reprinted under Common Creative License CC BY Fig. 6.6 Schematic of the CRR temperature sensor operation. a Cascaded configuration of Rings 1 and 2. Transmission spectra b at the drop ports of the two ring resonators, and c at the output of the CRR. d Power output at the drop port of a single ring resonator as a function of wavelength and temperature (Kim and Yu 2016) 6 Sensors 301 Fig. 6.7 a ∂neff /∂T, ng , and b temperature sensitivity of a ring resonator as a function of waveguide width. c FSR and d TP as a function of ring radius with 350 nm and 450 wide waveguides at the quasi-TM mode. FDTD simulation and analytical calculation were performed at 1550 nm. The waveguide thickness is 210 nm (Kim and Yu 2016) width are plotted in Fig. 6.7. FSR and TP as a function of ring radius with 350 and 450 nm wide waveguides at the quasi-TM mode are added for completeness. FDTD simulation and analytical calculation were performed at 1550 nm, using a waveguide thickness is 210 nm. Optical Sensor This section includes the well received contribution on optical sensors by Patrick Steglich (Leibniz-Institute for Innovative Microelectronics), which is highly acknowledged with thanks by the authors. Optical sensors in photonic integrated circuit (PIC) technology have great potential for cost-effective disposable sensors with various applications in environmental monitoring, food analysis and point-of-care-testing (Steglich et al. 2019a, b). Such sensors have the potential for the simultaneous analysis of various substances (Wang et al. 2020) and physical parameters such as temperature (Steglich 2020; Steglich et al. 2020) and stress (Lu and Lee 2009). Further, they provide rapid results within minutes 302 6 Sensors and the direct translation of the optical into an electrical signal by using a chipintegrated photodiode allows reliable and secure data transfer, employing modern communication protocols. One main advantage, however, is the miniaturization of the complete sensor system. This includes the light source, sensor element and electronic readout, which gives perspectives to mobile and lab-on-a-chip applications. The working principle of micro-ring resonators as optical sensor is based on a refractive index change. At this point, we should distinguish between two cases. First, if the refractive index of the surrounding material changes, we speak about refractive index sensing in bulk material or surface sensing in case of specific detection of molecules at the surface of the waveguide. Second, if the refractive index of the optical waveguide is changed, we speak about thermal or stress sensing, depending on either the refractive index change originates from a temperature change or from the applied stress inside the silicon waveguide, respectively. Temperature sensing is highly efficient in silicon-based PICs due to its large thermo-optical effect (Weituschat et al. 2020). In all aforementioned cases, the detection principle relies on the change of the effective refractive index of the optical waveguide which causes a change of the resonance condition: λ = λres n clad ng (6.5) Here, λres refers to the resonance wavelength, n clad represents the cladding refractive index change which is similar to the refractive index change of the fluid. It is useful to distinguish between the waveguide sensitivity and the ring resonator sensitivity. The former describes the interaction of the guided light with the surrounding medium. It takes into account that the effective refractive index is altered if the cladding refractive index is changed. The waveguide sensitivity is given by: Swg = n eff n clad (6.6) where n eff represents the effective refractive index change. Such a definition is useful for waveguide optimization through simulation studies. However, the ring resonator sensitivity depends not only on the waveguide geometry and, therefore, a second definition defining the ring resonator sensitivity is given by Srr = λ n eff (6.7) Taken both definitions into account, we get the overall photonic device sensitivity defined by S = Swg Srr = n eff λ λ = n clad n eff n clad (6.8) 6 Sensors 303 The unit the definition reported in (6.8) is often written as nm/RIU, where RIU denotes the refractive index unit. The refractive index change n clad can be detected by tracking the resonance peak position or by measuring the intensity at a fixed wavelength, as shown in Fig. 6.15. The peak position is usually tracked by using a broad light source in combination with an optical spectrum analyser, while the intensity can be measured by employing a tunable laser with a chip-integrated photodiode. 6.1 Microfluidics Similar to the technological advances in integrated ring resonator devices, microfluidics developed accordingly and basically started off in the 1990s. Although one could say that the origin of ring resonators and microfluidics can both be related back to the advent of MEMS in general. The aim of this short chapter is to provide you with a brief overview of the possibilities in such a way, that you can directly start to work on your dedicated project and run your application so that you can focus on your expertise. The last years, with growing technological fabrication advanced, have given ring resonators and microfluidics a huge boost, leading to more and more applications and products and as such, a variety of specialized technologies exist which will be described in the following. The question nowadays is not anymore if microfluidic devices can be realized but rather what are the requirements for the application and then what follows is merely a matter of fabrication and system approach and perspective. For example, if you need to create your microfluidic chip, companies offer a large variety of readily available configurations and even customized chips are commercially available. 3D printing has boosted microfluidic applications tremendously. The result is more than visible in the number of publications in this field, just to mention as an example the recently published book on 3D Printed Microfluidic Devices by Tasoglu and Folch (2019). Several available technologies for realizing microfluidics are available for example in realizing small scale devices in polymeric materials with state of the art two photons polymerization techniques. Salvatore Puce et al. (2019) demonstrated what is also known as 4D lithography to combine polymer and metallic structures for future integration of 3D MEMS multi-material sensing possibilities (Figs. 6.8 and 6.9). Another possibility to fabricate arbitrary three-dimensional suspended hollow microstructures in transparent fused silica glass are described in Kotz et al. (2019). The fabrication of suspended hollow microstructures in fused silica glass steps and results are reported in Fig. 6.10. Structures templates produced by direct laser writing and the resulting microfluidic spiral channels in fused silica glass with a channel width of 74 μm are reported in Fig. 6.11 with the relative characterization in Fig. 6.12. 304 6 Sensors Fig. 6.8 a Schematic representation of a silicon-on-insulator ring resonator. According to the resonance condition, only selected wavelengths can propagate in the ring and distinct resonance peaks appear in the output spectrum. b Molecular binding takes place if a sample of the analyte gets in touch with the adsorbed layer on top of the silicon waveguide leading to a resonance wavelength shift (Steglich et al. 2019a, b) Fig. 6.9 Fabrication process flow. (i) Spin coating of bottom resist and drop casting of the top resist. (ii) 2PP writing process of Sacrificial Stencil Mask and pedestal in one single step. Exclusive development of the top layer (iii) followed by the metal evaporation step (iv). After the bottom resist development (v), the structure is fabricated (Puce et al. 2019). Reprinted under Common Creative license Printing your own microfluidic device with overlay functionality and integration of MEMS sensors is also possible today with state-of-the-art equipment. Microfluidic systems with valves and dosing units or micropumps are possible as well using commercially available devices. These are just a few examples to highlight the endless possibilities established in the last couple of years in the microfluidics field, enabling a steady and fundamental growth of this exciting field. The authors believe that future research is geared towards the combination of disciplines and the system and application aspect is brought into focus resulting in even further interdisciplinary work- and research groups. 6.1 Microfluidics 305 Fig. 6.10 Double layer resists deposition i. Diffusion of the top resist into the bottom one ii. Floodexposure prevents the diffusion of the two resists (Puce et al. 2019). Reprinted under the permissions of Elsevier Common Creative license An example of an integrated ring resonator in a microfluidic setting is presented by Geidel et al. (2016) where a ring resonator biosensor is embedded into a microfluidic cartridge (see Fig. 6.13). The design of the ring resonator is shown in Fig. 6.14 including the integration into the microfluidic environment (Fig. 6.15). This is a perfect example of what is already possible today with state-of-the-art technology thus enabling the further extension of the research boundaries. Having said this, the authors encourage the scientific community to again focus on the main interest of their research and using existing readily available technology and scientific interdisciplinary collaborations to proof the system aspect of their research for enabling a faster demonstration of the application. 6.2 Optofluidic Resonators A promising strategy for improving the light– matter interaction is to increase as much as possible the interaction time between the probe and the probed target. For this reasons ring resonators, and especially integrated microring ones, have attracted great attention. As defined in Li (2015), optofluidic resonators are optical microcavities that are partially or completely made of liquids: they confine light both spatially and temporally in some structurally defined resonance modes. Classified into liquidcore, liquid-cladding, and all-liquid resonators, the most common cavity types are whispering gallery mode (WGM) cavities, photonic crystal or DFB type cavities and Fabry–Perot type cavities respectively. Among the others, WGM cavities normally 306 6 Sensors Fig. 6.11 Fabrication of suspended hollow microstructures in fused silica glass. a Polymeric filaments are embedded in an amorphous silica nanocomposite. The polymerized nanocomposite is turned into fused silica glass via thermal debinding and sintering. The polymeric template is removed during the thermal debinding process and leaves the according hollow cavity. b Microfluidic fused silica chip fabricated by embedding a nylon thread (scale bar: 9 mm). c Microfluidic meander fabricated by embedding polymerized PEGDA structured by microlithography (scale bar: 11 mm). d A mesh structure made from poly(ε-caprolactone) using melt electrowriting (scale bar: 5 mm). The inset shows the microscopy image of the mesh with a fiber diameter of 25.0 μm (scale bar: 100 μm). e Inverse hollow mesh structure in fused silica glass (scale bar: 4.5 mm). Inset shows the microcavities with a width of around 18.4 μm (scale bar: 100 μm) (Kotz et al. 2019). Reprinted under Common Creative License present ultrahigh quality (Q) factors providing very narrow linewidth cavity resonances favorable for low-threshold lasing and ultrasensitive sensing applications. Photonic crystal or DFB cavities are instead are more suited for on-chip integration with microfluidics. Microfluidic channels can be combined in the fabrication process with the optofluidic cavity structure to get on-chip microfluidic tuning and sample introduction. Fabry–Perot cavity is instead well suited for intracavity sensing and spectroscopy applications because the ease of access to its intracavity space. Optofluidic resonators offer tunable optical resonances with extremely large tuning range (refractive index change can be as high as 0.5 compared with <0.01 in most solid-state materials) by liquid filling, mixing, or replacement. By placing the target inside an optical cavity with a high-quality factor Q, in fact, a high gain can be achieved (Minzioni et al. 2017). Integrated optofluidic resonators in the form of a 6.2 Optofluidic Resonators 307 Fig. 6.12 STR using templates produced by direct laser writing. a Polymeric DNA double-helix (scale: 500 μm). b Inverse structure in fused silica glass (scale: 400 μm). The smallest channel size is 20 μm. c Intertwined spirals (scale: 900 μm). d Resulting intertwined microfluidic spiral channels in fused silica glass with a channel width of 74 μm. The channels were filled with dyes (see inset, scale: 140 μm). e Polymeric microstructures of an out-of-plane mixer structure (scale: 600 μm). f Microfluidic mixer structure in fused silica glass with a channel width of 74 μm (scale bar: 280 μm). As can be seen the 3D structures can be replicated with high fidelity and no deformations (Kotz et al. 2019). Reprinted under Common Creative License planar ring have been obtained using slot waveguides (SWs), Bragg waveguides (BWs) or antiresonant reflection optical waveguides (ARROWs). Towards disposable optical sensor chips, the use of a single wavelength light source in combination with a chip-integrated photodiode is preferable since optical spectrum analyser are expensive and cannot be miniaturized currently. Such a configuration can be used for intensity measurements. However, the main drawback of intensity measurement is the small detection range. Currently, approaches to track the peak position with a laser and photodiode is realized with a tunable laser, which is expensive and requires 308 6 Sensors Fig. 6.13 Characterization of suspended hollow microstructures in fused silica. a, b SEM of rectangular channel cross-section with an aspect ratio of 0.1 and 10 (scale: 100 μm). c–f SEM of spherical, triangular, trapezoidal, and rectangular channel cross-sections (scale: 10 μm). All templates were fabricated using direct laser writing. The flattened side of the “spherical” channel cross-section is due to the 2-photon polymerization 3D printing process of the template. Structures are printed on glass slides and a certain contact area is required to prevent the structure from detaching from the glass. g, h SEM and white light interferometry of the channel structure from a with a mean roughness of Ra ~ 20 nm (scale: 10 μm) (Kotz et al. 2019) much space. To avoid this, a tunable optical filter is placed in front of the optical sensor (Moldenhauer et al. 2017). In this way, a broadband light source such as a superluminescent diode can be used because only certain wavelengths with sharp linewidth can pass the optical filter. The transmitted center wavelength can be tuned, so that the working principle of a tunable laser is achieved. The advantage of a tunable filter is mainly referred to the fact that it can be realized by integrating an additional add-drop ring resonator that is thermally tuned using the relatively large thermo-optical effect in silicon. Metal plates in the back-end of line can be employed as heaters. Another bottleneck is related to the light coupling from the external light source into the chip. Single mode optical fiber having a mode field diameter of 10.4 μm and a numeric aperture of 0.14 are typically used. Due to these characteristics, the optical fiber needs to be placed above chip with a distance of about 3 μm, making the fiber alignment challenging. Therefore, precision 3D translational stages are used. 6.2 Optofluidic Resonators 309 Fig. 6.14 The picture of the newly-designed cartridge shows the reservoirs filled with colored water except the sample reservoirs. The sample is filled into the corresponding reservoirs using an external manipulator through tubing’s connected to a port with high performance liquid chromatography (HPLC)-fitting compatible threadings. The PIC is not shown here presented (Geidel et al. 2016) However, the alignment procedure is too time consuming and the tolerance against misalignment is too small. Current research is focused on the development of costeffective fiber-to-chip packaging methods to overcome this issue (Wan et al. 2019; Nauriyal et al. 2019). The optical sensor elements can be co-integrated with light-sources and photodetectors. Even a monolithic integration with electronic devices is possible by using an electronic-photonic-integrated circuit (EPIC) technology. However, PIC technology has a higher potential for disposable sensor applications since the fabrication is significant cheaper than EPIC. The main bottleneck is still the integration of a light sources. Therefore, optical fiber coupling using on-chip grating coupler is still required. In summary the main bottleneck for cost-effective and reliable sensor integration is the co-integration of light-source (optical fiber), electrical signal supply and micro-fluidic from same interface. From Fig. 6.16 it is apparent that the optical fiber coupling, the micro-fluidic and the electric contacts obstruct each other mutually. As a consequence, cost-efficient mass-production of optofluidic silicon photonic biosensors for disposable sensor applications is not yet realized. A novel integration concept is based on a wafer backside release procedure that enables a separation of sensing area and, hence, the microfluidic from the optical fiber and electrical contacts (Steglich 2020; Steglich et al. 2020). In principle, the photonic sensor is released by a local backside dry-etch followed by a combination of different chemical wet etch processes. A schematic is shown in Fig. 6.16: a second major advantage of this approach is the improved compatibility to the baseline CMOSprocess, i.e., the complete back-end of line can be fabricated in a similar way as in 310 6 Sensors Fig. 6.15 Design of the photonic sensor: a microscope image of a part of the photonic sensor with optical ring resonators (a1), optical waveguides (a2), and optical interfaces on the right (a3); b drawing of the whole circuit’s layout with an array of optical grating couplers on the left (b1) and on the right (b3) connected by a waveguide (b2). Optical ring resonators are located in the middle of the chip (b5). The black frame (b4) is not a part of the chip. It marks the area where the liquids will be pumped through; c detailed design of an optical ring resonator within the photonic sensor. An optical waveguide (c1) passes the optical ring resonator (c3) at a small area (c2); and d a schematic sketch of the fluidic connection of a polymer based cartridge (d8) and a silicon chip d4 using an elastomer sealing ring (d6). The direction of the pumped liquids is visualized by arrows (Geidel et al. 2016) the standard process. Only the passivation layer of the bondpads needs to be adjusted, as we have reported in Steglich et al. (2019a, b). The fabrication can be done by utilizing a PIC-technology (Steglich 2020). Such technology employs 200 mm silicon-on-insulator wafer having a 2 μm buried oxide and a 220 nm crystalline silicon layer on top. A 248 nm DUV optical lithography is used to define the waveguide structures. Then, the chip is fabricated, including all five metal stacks in the back-end of line. As mentioned before, the passivation module has been adjusted (Steglich et al. 2019a, b). This is required because the ring resonator is released by a deep silicon etch followed by a chemical wet etch. As a consequence, the wet etch would underetch the standard passivation and, hence, destroy the metal pads. The adjusted passivation based on a flattened silicon nitride layer has been proven to protect the back-end of line (Steglich et al. 2019a, b). A 6.2 Optofluidic Resonators 311 Fig. 6.16 Current status of optical sensors in a photonic integrated circuit technology. The optical light coupling, connection with micro-fluidics and wafer-level packaging are identified bottlenecks that hinder a mass-production detailed description of the fabrication process with focus on the back-side release process is provided in Steglich (2020) and Steglich et al. (2020). 6.3 Biosensors The motivation to use integrated ring resonators as biosensors is apparently obvious by now as we are making use of the resonance wavelength shift which is induced by changing the effective refractive index the evanescent light field is seeing when making round trips inside the ring resonator. In a microcavity resonator structure, the most common configuration starts from the coupling of the incident light propagating in an input waveguide (or tapered fiber) the microcavity via the evanescent field. When whispering gallery modes (WGMs) or circulating waveguide modes with multiple round-trips are created (see also Chap. 7), optical interference occurs at specific wavelengths of light, λ= 2πr n eff m (6.1) where λ is the resonant wavelength, r is the radius of the resonator, neff is the resonator effective refractive index, and m is an integer respectively. The positions of resonant peaks are related to the refractive index close to the resonator surface whilst the 312 6 Sensors Fig. 6.17 Conceptual illustrations of an optical ring resonator sensor. The resonant light circulates along the resonator and its evanescent field is present in the surrounding medium outside (a) or inside (b) the ring resonator, interacting with the analyte on the ring resonator exterior surface (a) or interior surface (b) and in the surrounding medium (Sun and Fan 2011) shift is due to the change of neff . It is clear that it can be monitored by scanning the wavelength or by measuring the intensity at a single wavelength (Luan et al. 2019). As depicted in Fig. 6.17, it is clear that in order to change the effective refractive index, the evanescent field is interacting with an analyte which is hooked up to the ring resonator by bio-chemical binding processes Sun and Fan (2011). The principle of how a ring resonator biosensor detects the binding of analyte to the surface is reported in Fig. 6.18. In this case a tunable laser is coupled to the ring resonator: at the laser resonance with the resonant mode in the resonator, a spectral dip is shown at the detector to indicate the spectral position. The quality factor is the one of the most important parameter to have performant sensors: higher Q-factor corresponds to longer interactions of the light with the analyte. Moreover, White et al. proved that a high Q-factor reduces the sensor noise and further improves the Detection Limit (DL) (White and Fan 2008). In general the DL (or sDL) depends on the measurement system including curve fitting methods and limitations from light sources or detectors: this is why it is not so common to clear comparison between sensors. In order to solve this problem, often the so-called intrinsic detection limit (iDL) is used in for resonant sensors. It depends on intrinsic characteristics, such as the resonance linewidth, and defined by: iDL = λ QS (6.1) where λ, Q, and S are the sensor’s resonant wavelength, quality factor, and sensitivity, respectively. Up to now, several types of planar resonant microcavity-based configurations have been realized for biosensing applications such as microring (MRR), microdisk and microtoroid shaped resonators. A review on this topic has been also being treated by Luan et al. (2019): as it is there summarized, although resonator-based biosensors enable dense on-chip integration and offer a similar DL of 10−5 to 10−7 RIU, their 6.3 Biosensors 313 Fig. 6.18 a Illustration of a ring resonator biosensor that detects the binding of analyte to the surface. A tunable laser is coupled to the ring resonator. When the laser is in resonance with the resonant mode in the resonator, a spectral dip is shown at the detector to indicate the spectral position. b The resonant mode shifts in response to the local RI change induced by the molecular binding. c A sensorgram can be obtained by monitoring the spectral shift in real time (Sun and Fan 2011) Q-factors (except toroid resonators) are relatively low. As alternatives microspherebased ring resonators and capillary-based opto-fluidic ring resonators (OFRR) have been recently proposed because characterized by higher Q-factors (>106 ) and DLs of the order of 10−7 RIU for pesticide, cancer and bacteria. However, due to threedimensional architectures, these devices are not suitable for on-chip fabrication as well as microfluidics integration. Fig. 6.19 describes a planar ring resonator for vapor sensing. Its surface is coated with a layer of vapor-sensitive material such as a polymer. The particular case of a capillary-based ring resonator for vapor sensing is shown: its inner surface is coated with a layer of polymer for vapor separation and detection. A biosensor based on a disk resonator is proposed and analyzed in Boyd and Heebner (2001). The disk is weakly coupled to a bus waveguide which allows the field to build up to high values in the disk resonator which is necessary for sensing. The device designed has the following parameters: a waveguide width of 0.4 μm, a coupling gap of 0.25 μm and a disk radius of 2.54 μm. The device is operated in TM polarization. A dielectric constant of the device of 4 is assumed. The achieved simulated sensitivity is expected to be approximately 100 molecules. 314 6 Sensors Fig. 6.19 a Planar ring resonator for vapor sensing. Its surface is coated with a layer of vaporsensitive material, for example polymer. Upper figure: cross-sectional view. Lower figure: top view. b Capillary-based ring resonator for vapor sensing. Its inner surface is coated with a layer of polymer for vapor separation and detection. c Schematic diagram of capillary ring resonator-based vapor separation and detection. d Sensing signal is generated when each analyte arrives at the detection position defined in (c) (Sun and Fan 2011). Reprinted with permission from Springer Nature A sensor using a disk resonator vertically coupled to a bus waveguides is fabricated and demonstrated in Krioukov et al. (2002). The layer sequence and layout of the device is shown in Fig. 6.20. Similar to the previous simulated example, the disk resonator is weakly coupled to the underlying bus waveguide, allowing modes in resonance with the disk to build up. The response from the disk is measured using water, ethanol and a mixture of water and glucose in different concentrations as cladding. A shift in the resonance wavelength indicates the different solutions. A glucose concentration sensor is realized in Chao and Guo (2003) using polymer nanoimprinting. The racetrack shaped ring resonator notch filter includes partially reflecting junctions in the bus waveguide creating so called Fano resonances (Fan 2002). A schematic of the devices is shown in Fig. 6.21. Details on the fabrication have been described in Chap. 3 where a similar device is realized. The measurement is performed by tuning a laser near one of the resonances of the ring and detecting the change in the spectra. The ring resonator is placed in different glucose concentrations. A minimum detectable concentration 6.3 Biosensors 315 Fig. 6.20 Cross-section and view of an integrated optical MC sensor. Light from a tunable laser is coupled into the excitation waveguide, and the scattering is measured from the top of the MC as a function of the wavelength with various solutions in the sensing area. Dotted line, localization of a high-Q whispering-gallery mode; its propagation direction is shown by an arrow around the circumference. Device parameters: R = 15 μm, hc = 255 nm, he = 150 mm Krioukov et al. (2002) Fig. 6.21 Racetrack-shaped ring resonator with partially reflecting waveguide junctions 316 6 Sensors change of glucose solution is estimated to be 0.024%, or 24 mg (dl)−1 . Since the Q-f actor is proportional to the sensitivity, an increase in the Q-factor of the ring resonator will also enhance the sensitivity. The shift in the resonance wavelength is linear with increasing glucose concentration. A detailed analysis of resonantenhanced evanescent-wave fluorescence biosensing in ring and disk resonators is presented in Blair and Chen (2001). Design layouts are given and the sensitivity and the enhancement factor are derived. Another demonstration of a ring resonator used for sensing bio-molecules is given in Yalcın et al. (2006). The functionality of the device is proven by using avidin–biotin binding on the surface of a vertically coupled glass ring resonator. The radius of the ring resonator is 60 μm. The penetration depth of the mode into the medium (deionized water) is calculated to be approximately 360 nm at a wavelength of 1550 nm assuming an effective refractive index of the waveguide of 1.5. The ring resonator parameters are as follows: FSR = 4.2 nm, FWHM = 0.126 nm, F = 33, Q = 12,000. The measurement principle is again the monitoring of the resonance shift due to a change in the refractive index caused by the binding of biomolecules. The refractive index sensitivity of the system is 1.8 × 10–5 . Some examples of application and selection of biomolecules that have been detected by integrated photonic biosensors based on SOI ring resonators, as reported in Table 6.2 by Steglich et al. (2019a, b). The comparison between sensor performances results cin the field of silicon photonic biosensors is presented in Table 6.3 as provided by Luan et al. (2019): different architectures as well as strategies to improve the S and DL values are summarized. As reported by Luan et al. (2019), bulk sensitivities in the unit of wavelength (or phase) shift per refractive index change are reported such as light polarization and wavelength, system and intrinsic detection limits, and Q-factor respectively. Table 6.2 Examples of application and selection of biomolecules that have been detected by integrated photonic biosensors based on SOI ring resonators (by Steglich et al. 2019a, b) Application Analyte/biomarker Receptor/target Detection limit Acute inflammation C-reactive protein (CRP) Anti-CRP 6.5 pM Acute inflammation Interleukin 2,4,5 Anti-CRP 6–100 pM HIV Human immunoglobulin (Hu-IgG) Anti-Hu-lgG 1 ng Hepatitis Human serum albumin Anti-albumin 3.4 pg Meningitis tmRNA DNA 0.524 nM Prostate cancer Prostate specific antigen (PSA) Anti-PSA 0.4 nM Liver cancer α-fetoprotein (AFP) Anti-AFP 100 pM Bowel cancer Carcinoembrionic antigen (CEA) Anti-CEA 10 pM Bladder cancer Tumor necrosis factor (TNF) Antibody 100 pM Model system Green fluorescent protein (GFP) Antibody 0.1 mg/mL Model system Streptavidin Biotin 60–150 fM Food monitoring Bean pod mottle virus Antibody 1.43 pM Reprinted under Common Creative license Sensor configuration MZI Ring Sensor type Interferometer Microcavity TE TE TE TE TM TE TM TM TM TE TM TE Slot/critical coupling Multi-box SWG 5WG swc Slot Suspended Thin WG N/A Thin WG 1.31 μm Wvl 1.31 μm Wvl TE N/A Vernier TM N/A TM TE 1.31 μm Wvl Vernier TE Slot TM TE Suspended Vernier/suspended TE Optical made Vernier Strategy 9.8 33.5 24 10.1 4.5 12 0.33 9.8 7 2.6 6 20 15 N/A N/A N/A N/A N/A N/A N/A Q-factor (×103 ) N/A 91 nm 113 nm 133 nm 200 nm 270 nm 290 nm 298 nm 429 nm 490 nm 580 nm N/A N/A N/A N/A N/A N/A 10–5 10–6 4.2 × N/A 2× N/A N/A 5.05 × nm 13 × 103 nm 13 × N/A N/A 2.43 × 104 nm 10–4 N/A 103 N/A 300 × 2π rad 4.6 × 105 nm (continued) 3.5 × 10–4 1.49 × 10–3 5 × 10–4 [142] 7.5 × 10–4 1.2 × 10–3 N/A 1.59 × 10–2 3.71 × 10–4 5.5 × 10–4 1.02 × 10–3 <10–4 4.8 × 10–6 N/A N/A 3.3 × 10–5 460 × 2π red N/A N/A N/A 4 × 10–5 N/A Intrinsic detection limit (RIU) 540 × 2π rad 1.29 × 10–5 1730 × 2π rad N/A N/A 2.15 × 104 nm 740 nm System detection limit (RIU) Bulk sensitivity (RIU−1 ) Table 6.3 Performance metrics comparison of selected optical biosensors (WG, waveguide; Wvl, wavelength, 1.55 μm where not specified) 6.3 Biosensors 317 Uniform Phase-shifted ID 2D Disk Sensor configuration TM TE 1.31 μm Wvl N/A TE TE Slot N/A TE TE N/A Multi-box SWG TE TE Ring-slot Slot TE N/A TE N/A TE TM Suspended Slot TM TE N/A N/A Optical made Strategy Reprinted under CC license from Luan et al. (2019) Bragg grating Photonic crystal Sensor type Table 6.3 (continued) N/A 27.6 76 15 6.2 3 174 11.5 0.4 50 33 0.1 16 15 Q-factor (×103 ) 182 nm 59 nm 106 nm 340 nm 610 nm 130 nm 815 nm 160 nm 200 nm N/A N/A N/A N/A N/A 7× N/A N/A 2× 10–5 10–3 7.8 × 10–6 1.5 × 103 nm 10–6 N/A 8× N/A N/A System detection limit (RIU) 26 nm 130 nm 142 nm 38 nm Bulk sensitivity (RIU−1 ) N/A 9.3 × 10–4 1.6 × 10–4 3 × 10–4 4 × 10–4 4 × 10–3 1 × 10–5 8.75 × 10–5 1.88 × 10–2 2.07 × 10–5 1.8 × 10–3 1.18 × 10–1 6.8 × 10–4 2.7 × 10–3 Intrinsic detection limit (RIU) 318 6 Sensors 6.3 Biosensors 319 An overview of target analytes has been reported by the same authors arranged in descending molecular weight, with privilege to those that use label-free SOIbased biosensors. As therein reported, SOI-based optical biosensors present a wide detection range for analytes. It is worth mentioning that larger molecules such as micrometer-sized cells and bacteria may exceed the evanescent field range limiting in this case the sensor use. On the other hand, small molecules are difficult to be detected especially when in low concentrations: the relative low sensitivity and/or high noise level of SOI-based sensors is in this case a unable to circumvent the detection problem. An overview of selected biomolecules that have been detected by optical sensors using label-free method is instead reported in Table 6.4. An example of a split ring resonator (SRR) fabricated and integrated with a microfluidic chamber for biosensing is reported by Jaruwongrungsee et al. (2015). The authors produced it on a microwave printed circuit board while the microfluidic chamber has been realized by casting of polydimethylsiloxane (PDMS). In particular SRR has been immobilized with Anti-Immunoglobulin G (IgG) for IgG detection by a standard covalent immobilization using Cystamine. Jaruwongrungsee et al. (2015) aligned the PDMS chamber was aligned on the circuit board so that to monitor the response of the SRR sensor continuously: they have demonstrated that the reaction of Immunoglobulin G (IgG) and Anti-IgG results in a shift of resonance frequency, sensitive to the IgG concentrations. Their SRR integrated device with the PDMS chamber is reported in Fig. 6.22 whilst the working principle of SRR electrode with immobilized antibody in microfluidic flow channel before and after binding under analyte flow ire reported in Fig. 6.23. The Measured real-time frequency response of a SRR sensor under different loading conditions are presented in Fig. 6.24. Other sensing applications have been demonstrated in Human-IgG (Human Immunoglobulin G) and PA (Staphylococcal protein A) respectively (Ren et al. 2013). The biosensing devices have been achieved by combining the so-called “stamp-andstick” method (Satyanarayana et al. 2005) where a PDMS fluidics channel is mounted on top of the microring resonator chip, as sketched in Fig. 6.25. The signals of the PA-coated polymer sensors to specific and nonspecific interactions has been reported: the wavelength shift is due to the interaction with human IgG (50 and 5 μg/mL) and with BSA (50 μg/mL) respectively (Ren et al. 2013). A systematic work on the development of optical biosensors built on a novel polymer platform named PSQ-Ls has been studied by Wang et al. (2012). This material has ben demonstrated to be very flexible and cheap to get optical devices with high performances made by UV-based soft imprint lithography technique. Ring resonators with Q value as high as 5 × 104 and 2.7 × 104 have been achieved and tested after protein A molecules functionalization by physical immobilization. Surface binding sensing have been measured with a flow speed of 10 μL/min, deionized water and 0.01 × phosphate buffer solution (PBS), Human-IgG with a concentration of 50 μg/mL and 0.01 × PBS injected into the fluidics channel consecutively. A wavelength shift of about 230 pm has been induced by the affinity of Human-IgG for the protein A molecules immobilized on the chip surface as bio-receptors. The Ring biosensor activity has been tested at different concentrations of Human-IgG 320 6 Sensors Table 6.4 Overview of selected biomolecules that have been detected by optical sensors using label-free method (CFU, colony-forming unit; HAU, hemagglutination unit; VP, viral particle) Biological material Target Weight Sensor type Waveguide material Detection limit Cell E. coli O157:H7 1 pg MRR Hydex 105 CFU/mL MRR Si 108 CFU/mL Virus Protein Avian influenza virus 542 MDa MZI Si3 N4 5 × 10–4 HAU/mL Herpes simplex virus 96 MDa YI Si3 N4 850 VP/mL Bean pod mottle virus 7 MDa MRR Si 1.43 Pm Human papilloma virus 5 MDa PhC Si 1.4 nM Immunoglobulin G 150 kDa PhC Si 1 ng/mm2 MZI Polymer 3.1 nM Vernier MRR Si 47.3 nM MZI SiOx Ny 2.14π/nm PhC Si 2.5 fg PhC Si 344 Pm/nm Slot MZI Si3 N4 18 fM PhC Si 49 fM MRR Si 60 fM MRR-MZI Si 20 pM MRR SiO2 /Six Ny 0.1 nM MRR Si 0.15 nM (Strept)avidin 55–68 kDa Human serum albumins 67 kDa Prostate specific antigen 28 kDa C-reactive protein 25 kDa Nucleic acid RNA DNA 7–40 kDa 7–12 kDa Slot disk SiNx 0.55 nM YI Si3 N4 20 fg/mm2 MRR Si 3.4 pg/mm2 MRR Si 0.4 Nm Slot MRR SiN 1.79 nM MZI Six Ny 84 fM MRR Si 0.4 nM MZI SiN 0.78 nM MRR Si 53 fM MRR Si 15 fM Slot MZI Si3 N4 1 nM MZI Si3 N4 300 pM Slot MZI Si3 N4 1 nM (continued) 6.3 Biosensors 321 Table 6.4 (continued) Biological material Small molecule Target Weight Sensor type Waveguide material Detection limit MRR Si 1.95 nM PhC Si 19.8 nM MRR Hydex 100 nM Gentamicin 478 Da PhC Si 0.1 nM Biphenyl-4-thiol 186 Da PhC Si3 N4 N/A Reprinted under CC license from Luan et al. (2019) Fig. 6.22 The photographs of microstrip-coupled SRR integrated with PDMS microchamber detection (Jaruwongrungsee et al. 2015) Fig. 6.23 The diagram illustration of SRR electrode with immobilized antibody in microfluidic flow channel a before and b after binding under analyte flow thorugh a channel detection (Jaruwongrungsee et al. 2015) 322 6 Sensors Fig. 6.24 Measured real-time frequency response of a SRR sensor under a different loading conditions and b due to various stages of Anti-IgG immobilization and 100 μg/ml IgG detection (Jaruwongrungsee et al. 2015) Fig. 6.25 Sketch of the biosensing process exploiting the PA/IgG affinity couple: a schematic of the biosensing process using PA/IgG affinity couple; b SEM pictures of the ring resonator fabricated by UV-based soft imprint lithography technique; c response signals of the PA-coated polymer sensors to specific and nonspecific interactions. Wavelength shift obtained due to the interaction with human IgG (50 and 5 μg/mL) and with BSA (50 μg/mL). Every curve corresponds to a different experiment on a different chip. The time point of the loading of protein samples is shown in the figure (Ren et al. 2013) 6.3 Biosensors 323 Fig. 6.26 The responsivities of the PA surface functionalized photonic biosensor to specific and nonspecific interactions. Resonant wavelength shift induced by the interaction with human IgG (50 and 5 μg/mL) and with BSA (50 μg/mL) (Han et al. 2018) solutions showing different dynamic responsivities to the antibody concentrations, with a detected concentration of Human-IgG as low as 5 μg/mL. As reported in Han et al. (2018), the nonspecific binding is another key factor for a label-free photonic biosensor. To test the response of polymer-based photonic biosensor toward nontargeted biomolecules, Ren et al. (2013) used Bovine Serum Albumin (BSA) control protein in a the PA-coated microring surface. In this case the concentration of the BSA for the test was 50 μg/mL (in 0.01 mol PBS, pH 7.4). In Fig. 6.26 the resonance shift therefore induced has been measured to be close to 40 pm due to the nonspecific binding of the BSA molecules. A resonant wavelength shift of 90 pm using the specific binding of the Human-IgG with a concentration of 5 μg/mL was also observed, validating the recognition ability of the PA-coated microring biosensors. Ring resonators are ideal for use in sensing biomolecules or even cells, as only a few molecules are required to induce a change in the resonance wavelength. Going into the direction of single molecule detection requires so called whispering gallery mode resonators which will be briefly described in the following chapter. References Adar, R., Shani, Y., Henry, C.H., Kistler, R.C., Blonder, G.E., Olsson, N.A.: Measurement of very low-loss silica on silicon waveguides with a ring resonator. Appl. Phys. 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Lett. 20(11), 885–887 (2008) Zamora, V., Lützow, P., Weiland, M., Pergande, D.: Investigation of cascaded SiN microring resonators at 1.3 μm and 1.5 μm. Opt. Express 21(23), 27550–27557 (2013) Chapter 7 Whispering Gallery Mode Devices Whispering gallery mode (WGM) resonators and lately photonic crystal resonator based devices are attractive due to their potential applications in photonics and recently in biophotonics as is described in the previous chapter. Applications which have been realized include for example lasers, filters, optical switches and biosensors. This chapter introduces WGM devices, although some examples which have been given in this book have dimensions of whispering gallery mode resonators. This chapter serves as a brief introduction into the topic as a significant number of books and other publications exist on this subject (for example Vahala 2003, 2004). 7.1 Whispering Gallery Modes (WGM) Whispering gallery modes (WGMs) are named after the whispering gallery at St. Paul’s Cathedral in London and have been studied by Lord Raleigh in 1910 (Rayleigh 1910, 1912). Whispering gallery modes occur at particular resonant wavelengths depending on the size of the resonator. At these particular wavelengths, light undergoes total internal reflection at the surface of the resonator creating resonances in the transmission spectrum of the resonator. Whispering gallery resonators are dielectric structures in which light waves are confined by continuous total internal reflection. WGMs can be observed in droplets and glass spheres for example. In this chapter, examples are limited to planar integrated WGM resonators. The light in WGM resonators is concentrated near the circumference of the device and is assigned a mode number and a mode order. The mode number, mn , reveals the number of wavelengths around the circumference, and the mode order, mo , reveals the number of maxima in the radial dependence of the electromagnetic field within the resonator. These modes can have very high Q factors if the losses due to reflection at the surface of the resonator are low. In addition to high Q values, a high finesse is also obtained. The high Q factor makes these resonators very attractive to be used as lasers. In order to couple light in or out of these resonators, the evanescent field of the © Springer Nature Switzerland AG 2020 D. G. Rabus and C. Sada, Integrated Ring Resonators, Springer Series in Optical Sciences 127, https://doi.org/10.1007/978-3-030-60131-7_7 327 328 7 Whispering Gallery Mode Devices whispering gallery modes has to overlap with the evanescent field of a phase-matched optical bus waveguide. This in and out coupling of WGM resonators is one of the major technological challenges and was only recently achieved due to the advance of fabrication technology, as was demonstrated in several examples in this book. A review of the basic properties of WGM resonators is presented in Matsko and Ilchenko (2006a, b). 7.2 WGM Filters Optical filters are one of the first applications when considering optical devices having wavelength dependent resonances. As in ring resonators, WGM resonators have a wavelength dependent resonance spectrum. Due to the small size of WGM resonators, they have large FSRs, high Q factors and high finesse. A review paper presenting applications of both WGM and ring resonators is given in Matsko and Ilchenko (2006a, b). One of the challenging research tasks is to achieve in and output coupling of these very small (diameter <10 µm) WGM resonators. Several groups have and are working on this subject. Before being able to couple in and out of a WGM device, WGM modes must circulate in the device to build up a resonance spectrum. This is only achieved when the WGM device has sufficiently low internal losses, especially a low surface roughness. Both of these aspects are theoretically investigated in Little and Chu (1996). The coupling between a WGM disk resonator and a bus waveguide is simulated in Dehmubed and Diament (1998). Design and fabrication of laterally coupled ring and WGM disk resonators in the material system AlGaAs/GaAs is presented in Hagness et al. (1997) and Rafizadeh et al. (1998). The layer sequence of the device has been described in Chap. 3. Photographs of the fabricated ring and WGM disk resonator are shown in Fig. 7.1. The diameter of the ring and disk resonator is 10.5 µm. A waveguide width of 0.5 µm is used. The coupling gap between the bus waveguide and the ring and disk is 0.1 µm. A trench is fabricated around the waveguides with a width of 1 µm. A detailed description of cylindrical WGM multimode resonators verified by experimental results realized in silicon oxynitride technology is presented in Klunder et al. (2002a, b, 2003). The layer sequence of the fabricated cylindrical WGM resonator is shown in Fig. 7.2. The intensity distribution inside the WGM resonator is analyzed using photon scanning tunneling microscope (PSTM) and effects like polarization conversion and counter propagation is detected. A simulation model is derived for calculating the finesse, bending losses and FSRs of fundamental quasi guided modes in this cylindrical WGM resonator. Another form of WGM resonator is designed and analyzed in detail in Maolatou et al. (1999) and Hammer (2002). The WGM resonator is in the shape of a rectangle coupled to bus waveguides. A schematic of the rectangular WGM resonator is shown in Fig. 7.3. Rectangular shaped resonators are slightly different 7.2 WGM Filters 329 Fig. 7.1 SEM images of a 10.5 µm diameter GaAs/AlGaAs microcavity ring and disk resonator coupled to 0.5 µm-wide waveguides Hagness et al. (1997) Fig. 7.2 Layer sequence of cylindrical WGM resonator Fig. 7.3 Rectangular WGM resonator from ring or disk resonators treated so far in this book with respect to the intensity distribution at the output ports. As can be seen from Fig. 7.3, some of the input power is reflected back to the same port and dropped at all the remaining ports. This is in contrast to ring or disk resonators, where there is a preferred direction of the light passing the resonator in the on or off resonance state, leading to only one drop and one throughput port. Several configurations have been simulated in Hammer (2002) using an operation wavelength of 1.55 µm. The length L and width W of the rectangular WGM resonator is varied between 0.81–6.902 µm and 0.81–3.696 µm, respectively. The width of 330 7 Whispering Gallery Mode Devices Fig. 7.4 Grating assisted rectangular WGM resonator the bus waveguides and the coupling gap is varied between 0.035–0.13 µm and 0.32–0.49 µm, respectively. The refractive index of the WGM resonator and the bus waveguides is assumed to be 3.4, whereas the surrounding refractive index is defined to be 1.45. This type of resonator is coupled to gratings on either side of the WGM resonator which leads to a superior add-drop filter characteristic. The device design is presented in Hammer et al. (2004). A schematic of the proposed device is shown in Fig. 7.4. The fabrication of WGM resonators has only been possible recently due to an advance in nanofabrication technologies. Especially in the case of WGM resonator filters, in and out coupling is the greatest technological challenge. When these tasks are overcome, tunability of WGM resonators is the next goal. Tuning of WGM resonators is addressed in Boriskina et al. (2003). Filter tuning is proposed by changing the shape of the resonator from circular to elliptic, which reduces the dependence of the coupling efficiency on the width of the air gap. The elliptic shape can be compared to a racetrack shaped ring resonator, where the effect in increasing the coupling length is the same. Two alternative coupling designs are suggested for monolithic and hybrid integration technologies. The first one is based on increasing the coupling length. The other makes use of the field concentration at the increased curvature portion of the deformed WGM resonator. Another method of tunability (either wavelength or filter shape) in resonators is be introducing gain into the resonator as described in Chaps. 3 and 5. Active disk resonators are simulated and designed in Djordjev et al. (2002) for use as modulators, switches and wavelength routers. Totally active devices can of course be used as lasers. WGM lasers have been investigated and demonstrated earlier than WGM resonator filters, which is obvious, because light only needs to be collected from the WGM resonator and not coupled into it for detecting the spectrum. In the following chapter, a brief introduction is given with examples of fabricated WGM lasers. 7.3 WGM Lasers WGM lasers are expected to be the light sources of future photonic integrated circuits and optical computer boards due to their extremely small size. Other advantages are similar to ring and disk resonators and include their compactness and their integration ability. Further more, no grating or facet is required for optical feedback which is the 7.3 WGM Lasers 331 main advantage when thinking of several WGM lasers on a chip placed at different locations on the chip. Some examples described in Sect. 5.6.1 can be regarded as WGM resonator lasers and are therefore not addressed in this chapter. WGM lasers having diameters of 3, 5 and 10 µm are fabricated in the material system GaInAsP/InP and demonstrated in McCall et al. (1992). Optically pumped InGaAs quantum wells are used to achieve lasing at wavelengths of 1.3 and 1.5 µm. The WGM lasers have the shape of a “mushroom” with an InP pedestal holding the disk with the quantum well layers. The thickness of the InGaAs quantum wells is 10 nm, the thickness of the GaInAsP barriers is 10 nm as well. The GaInAsP end caps have a thickness of 20 nm. The mushroom like shape is achieved by selective chemical etching of the InP below and around the quantum wells, resulting in a disk on a pedestal. Even smaller WGM disk lasers are presented in Slusher et al. (1993). Disks with a diameter of 2.2 and 5 µm in the same material as the previous ones are fabricated. Six quantum wells with a thickness of 10 nm of the material In0.53 Ga0.47 As are used together with five 10 nm thick GaInAsP barriers. The bandgap wavelength of the GaInAsP material is 1.1 eV at room temperature. The disks are optically pumped with a HeNe laser at a wavelength of 633 nm. A mode spacing of 87 nm is obtained for the small disk and 37 nm for the larger disk. Q values of 260 and 500 are measured at pump powers below threshold. A “submicron” WGM disk laser is presented in Levi (1994) having a radius of 0.8 µm and a thickness of 0.18 µm. The disk consists of six 12 nm thick InGaAs quantum wells separated by five 12 nm thick GaInAsP barriers. The disk is optically pumped with a diode laser having a wavelength of 850 nm. Pulses with a length of 8 ns and a repetition period of 100 ns are used for the pumping. A conformal mapping technique is used in Frateschi and Levi (1995) to determine the radial and azimuthal eigenvalues and eigenvectors of leaky optical modes of this WGM disk laser. Quantum cascade (QC) WGM disk lasers with an emission wavelength at 5 µm are fabricated and demonstrated in Faist et al. (1996). A mushroom like device structure is again used. A photograph of a fabricated QC disk laser is shown in Fig. 7.5. The layer sequence of the device is shown in Fig. 7.6. Disks with diameters of 17, 25, 45, 80, and 125 µm are fabricated. The measurement of the devices is done at a temperature of 15 K. The disks are contacted from top and are operated using 50 ns pulses. A threshold current of 2.85 mA is measured for the QC disk with a diameter of 17 µm. QC WGM disk lasers in the material system InGaAs/AlInAs, emitting at a wavelength of 16 µm, being one of the longest wavelengths reported for disk lasers, are presented in Tredicucci et al. (2000). The disk lasers are electrically contacted and operated in pulsed mode. Measurements are performed at temperatures of 10 K. Electrically pumped GaInAsP–InP strained quantum well WGM disk injection lasers with diameter between 2 and 10 µm are presented in Baba (1997) and Baba et al. (1997). A photograph of WGM disk lasers with diameters of 8, 3 and 2 µm are shown in Fig. 7.7. The disks are made of compressive strained multiple quantum wells. Four quantum well layers with a thickness of 3–4 nm sandwiched between barrier layers with a 332 7 Whispering Gallery Mode Devices Fig. 7.5 Scanning electron microscope image of a 25 µm diameter QC disk laser with total height 15.5 µm Faist et al. (1996) Fig. 7.6 Layer sequence of the QC WGM disk laser Fig. 7.7 WGM disk injection lasers with diameters of 8, 3 and 2 µm (from left to right) Baba (1997) bandgap wavelength of 1.2 µm having a thickness of 10 nm. The active layers include 50 nm thick guide layers with a bandgap wavelength of 1.2 and 30 nm thick gradient index (GRIN) layers with a bandgap wavelength of 1.1 µm. The total thickness of the active layers is 0.2 µm. A threshold current of 0.2 mA is measured for the disk 7.3 WGM Lasers 333 with a diameter of 2 µm under pulsed operation at a temperature of 286 K. Lasing is achieved at wavelengths around 1.55 µm. Optically pumped disk and ring lasers in InGaAs with diameters between 3.5 and 9 µm, fabricated using substrate removal and material transfer to a glass substrate by liftoff processing are presented in Corbett et al. (1996). This process is used in Corbett (1998) to fabricate ring and disk lasers with diameters between 6 and 28 µm having a single compressively strained 3 nm, In0.7 Ga0.3 As quantum well cladded by a 20 nm GaInAsP layer having a bandgap wavelength of 1.25 µm and a 100 nm GaInAsP layer with a bandgap wavelength of 1.15 µm, lattice matched to InP with a total thickness of 245 nm. The devices are optically pumped continuous wave (cw) with the 514 nm line of an Ar–ion laser at liquid nitrogen temperatures. An optically pumped threshold of 2 µW is obtained. The lasing wavelength observed is between 1.4 and 1.55 µm. Multimode operation of the lasers is observed at wavelengths corresponding to whispering gallery modes. Determining the optical modes in WGM resonators requires a different approach as the one presented in Chap. 2 for calculating the transmission spectrum of ring resonator filters. As these WGM resonators can be extremely small as is demonstrated in this chapter, the three dimensional Maxwell equations can not be reduced to a one dimensional problem. A method for calculating optical modes in WGM disk resonators giving an eigenvalue equation for optical modes and providing the distribution of the optical field in exact forms is described in detail in Wang and Dumitrescu (1998). Based on the results of the optical modes, the emitted optical modes are determined. Disks with a radius between 0.5 and 1.5 µm having a thickness of 50, 100 and 150 nm are simulated. One of the first cw operating, current injection WGM disk lasers in the material system GaInAsP/InP is presented in Fujita et al. (1999). A schematic of a WGM disk injection laser is shown in Fig. 7.8. Whispering gallery modes travel round near the edge of the disk by total internal reflection at the semiconductor/air boundary. The current is flowed from the top contact. Carriers are injected into the active layer from the posts. Fig. 7.8 Schematic of a WGM disk injection laser Fujita et al. (1999) 334 7 Whispering Gallery Mode Devices Fig. 7.9 Laser mode peak intensity versus current characteristic and lasing spectra observed under cw condition at 298 K for a 3 µm diameter device Fujita et al. (1999) A record threshold value of 150 µA is measured for a disk with a diameter of 3 µm at a temperature of 298 K. The measurement curve is shown in Fig. 7.9. Two resonant modes are seen at a wavelength of 1.63 µm. The lasing mode has a FWHM of 0.5 nm. The non lasing mode has a FWHM of 0.7 nm. The calculated Q factors for both of them are 3300 and 2300 respectively. WGM resonators have not only been realized in GaAs or GaInAsP, but have also been demonstrated in the material system InGaN/GaN using multiple quantum wells (MQW). An example of realized WGM ring and disk resonator devices is described in Zeng et al. (1999). Both realized devices are optically pumped. A schematic diagram of the InGaN/GaN MQW WGM ring resonators is shown in Fig. 7.10. The response from a WGM disk resonator is shown in Fig. 7.11. Different fabrication techniques and material systems have been used to fabricate WGM disk and ring resonators. A wafer fusion method is described in Song et al. (2000) to fabricate optically pumped GaInAsP disk lasers on Alx Oy . Continuous wave room temperature operation is achieved for devices with a diameter of 2.2 µm. The output power and the spectrum of an optically pumped disk are shown in Fig. 7.12. Fig. 7.10 Schematic diagram of representative InGaN/GaN MQW microring fabricated by photolithography patterning and dry etching Zeng et al. (1999) 7.3 WGM Lasers 335 Fig. 7.11 Optical emission spectrum of an InGaN/GaN MQW microdisk with a diameter of 9.4 mm. Both the WG and radial modes are observed in the microdisks Zeng et al. (1999) Fig. 7.12 Output power against incident pump power for the 2.2 µm diameter microdisk laser pumped by 1064 nm Nd:YAG laser. The spectra are measured by optical spectrum analyzer (OSA) with 0.24 nm resolution Song et al. (2000) The FSR of adjacent whispering gallery modes is 110 nm. The threshold pump power is 1.13 mW, as can be seen in the measurement. So far, WGM disk and ring lasers are measured by placing an optical fiber near the edge of the disk or ring to collect the emission which is then fed to an optical spectrum analyzer. In addition to the collection of the output light, cooling of some devices and measuring in pulsed mode is required. One of the first disk lasers with a radius of 10 µm vertically coupled to underlying bus waveguides in the material system GaInAsP/InP is presented in Choi et al. (2002). The device operates cw at room temperature, has a side mode suppression ratio of 20 dB and emits at a wavelength around 1.52 µm. The layer sequence and the fabrication of the device are similar to 336 7 Whispering Gallery Mode Devices the ones described in Chap. 3. A disk laser based on the same fabrication process, vertically coupled to a single bus waveguide with a radius of 8 µm is demonstrated in Choi et al. (2003). A photograph of a vertically coupled disk and a schematic of the cross section are shown in Fig. 7.13. The width of the bus waveguide is 0.7 µm. The waveguide is anti reflection coated to avoid Fabry–Perot resonances. A spectrum of the disk laser at an operating current of 14 mA is shown in Fig. 7.14. The disk laser has a threshold current of 4.5 mA. The FSR of the disk is 13 nm and the side mode suppression ratio is greater then 30 dB as can be seen in the diagram. Q factors between 5000 and 6000 are measured for this device. These disk lasers are used in Choi et al. (2004) to fabricate an eight channel laser array. A photograph of the device is shown in Fig. 7.15. The radius of the disks varies from 10.6 to 10.95 µm with 0.05 µm difference leading to spectral spacing of the channels of 1.6 nm. The FSR of the disks is approximately 9 nm. The bus waveguide is AR coated. The output spectrum of the laser array is shown in Fig. 7.16. Fig. 7.13 SEM image (left) and schematic cross-sectional view of the microdisk vertically coupled to a bus waveguide. Picture was taken after the disk formation. A thin InP membrane remains along the edges Choi et al. (2003) Fig. 7.14 Lasing spectrum for an 8 µm radius microdisk laser measured at I = 14 mA Choi et al. (2003) 7.3 WGM Lasers 337 Fig. 7.15 Micrograph showing the top view of the fabricated eight-channel microdisk array vertically coupled to a single bus waveguide Choi et al. (2004) Fig. 7.16 The microdisks for channels 6–8 are pumped at I = 13 mA, while the current injection levels for the other disks are maintained at I = 10 mA Choi et al. (2004) A FWHM of 0.25 nm and a side mode suppression ratio of 20 dB are obtained. Different current levels are used to tune the resonance wavelength to realize a channel spacing of 1.6 nm. With increasing advance in nanofabrication and modeling, photonic crystal based devices have made it into real devices. Many applications of ring resonators presented in this book can be transferred to photonic crystal structures and some have already been demonstrated and described in several books and journal publications. Therefore only a few examples of photonic crystal based lasers will be described in the following paragraph to show the potential and possible future direction. An optically pumped two dimensional (2D) photonic crystal (PhC) laser in the material system GaInAsP/InP is fabricated and demonstrated in Painter et al. (1999). A schematic of the cross section of the 2D PhC laser is shown in Fig. 7.17. Four 0.85% compressively strained quaternary quantum wells with an emission wavelength at 1.55 µm are used as the gain source. The membrane has a thickness of 211 nm and a width of approximately 8 µm. The lattice spacing is 500 nm. The holes 338 7 Whispering Gallery Mode Devices Fig. 7.17 Illustration of a cross-section through the middle of the photonic crystal microcavity. Photons are localized to the defect region by TIR at the air/slab interface and by Bragg reflection from the 2-D photonic crystal Painter et al. (1999) have a radius of 160 nm. A SEM photograph showing a top view of the fabricated device is shown in Fig. 7.18. For measuring the properties of the cavity, a semiconductor laser with an emission wavelength of 830 nm is used. The measurement is performed under pulsed operation of the pump source. Lasing at a wavelength of 1580 nm is observed. The absorbed threshold pump power of the PhC laser is estimated to be 500 µW. An upper limit for the Q factor is derived to be approximately 600. A similar layout is used in Kim et al. (2002) for fabricating an optically pumped hexagonal PhC ring laser in GaInAsP/InP emitting around 1.55 µm. A photograph of the device is shown in Fig. 7.19. Fig. 7.18 Top view of a microfabricated 2D hexagonal array of air holes with a single central hole missing. The interhole spacing, a, is 500 nm, and the radius of the holes are approximately 160 nm Painter et al. (1999) 7.3 WGM Lasers 339 Fig. 7.19 The scanning electron microscope image of a fabricated laser sample. The photonic crystal ring cavity consists of six waveguides and six 120° bends. Thus the resonant mode has similar properties to the guided mode of photonic crystal waveguides. In this picture, lattice constant a is ~0.57 mm and the air hole radius r is ~0.36a Kim et al. (2002) The diameter of the device is 8 µm. The measurement of the device is performed using a pump laser with a wavelength of 980 nm at room temperature with pulses having a width of 10 ns. A near field photograph of the standing wave mode in the PhC ring laser is shown in Fig. 7.20. The threshold pump power of the laser is measured to be 3 mW. The wavelength of the lasing mode observed is ~1625 nm. A Q factor of more than 2000 is obtained for this PhC ring laser. A detailed analysis of the resonant modes in 2D PhC lasers is presented in Park et al. (2002). Simulations are compared with two types of fabricated devices, air based free standing (similar to the one in Fig. 6.17) and SiO2 based epoxy bonded structures. Fig. 7.20 Experimentally measured laser mode using a CCD. This laser sample has 15 air holes along the ring diameter. Lattice constant a of this laser sample is ~0.58 mm and the air hole radius r is ~0.41a. A hexagonal ring mode pattern shows that the laser is emitted mainly from the ring region Kim et al. (2002) 340 7 Whispering Gallery Mode Devices These exemplary examples have demonstrated novel types of devices which have a great potential for the future in photonic integrated circuits. Compared to the history of disk or ring resonator structures, active PhC resonator structures are on the way to being electrically contacted with the ability to connect to the outside fiber world using integrated PhC bus waveguides. Laser Spatial and temporal coherences strongly depend on the optical cavity or resonator characteristics such as the quality factor Q and mode volume V, i.e. the figure of merit (Q/V ). Since WGM microcavities can support high values of Q/V, in the recent years the efforts to improve the previously quoted configurations have been made. Ultralow threshold microlasers have been therefore demonstrated in microspheres, microdisks, microtoroids and microrings respectively and reviewed in Jiang et al. (2015). It is worth mentioning that the rotational symmetry of these WGM cavity structures, however, leads to a laser emission is usually inplane isotropic as summarized in Fig. 7.21. In general WGM configurations allow for low collection efficiency in free space and requires to use, near-field couplers such as high-index prisms, side waveguides or tapered fibers that need precise alignment of the components, high-resolution lithography to maintain the nanometer-scaled gap between the coupler and the microcavity Fig. 7.21 (online color at: www.lpr-journal.org) Typical mode distributions of the traditional microcavity (kR # 59, where k is the vacuum wavevector and R is the maximum radius of the micro-cavity) (a), microcavity with a scatterer on the surface (kR # 59) (b), deformed microcavity (kR # 72) (c), and a microcavity with a grating structure (kR # 30) (d) (Cai et al. 2012) 7.3 WGM Lasers 341 and phase matching conditions to be fulfilled. In order to overcome these limitations and to achieve inplane unidirectional laser emission, it has been proposed to break the inherent rotational symmetry of WGM microcavities either by introducing a “defect” in the modal region or by using the so-called asymmetric/deformed cavity structures. Although both solutions provided excellent alternatives, the first one benefits from a high-Q mode-enhanced scattering and high collimation of the dielectric microcavity itself: in this way the optical WGM fields can be efficiently scattered and collimated into free space. In the second solution, asymmetrical emission is realized by adequately shaping the cavity boundary. Finally, vertical emission of a WGM laser can be promoted by adding a diffraction grating along the WGM microcavity circumference. It is beyond the scope of this book to provide a deep detailed description of the recent results on this topic. However, for the shake of completeness it is mandatory to briefly remind some advances obtained in integrated ring resonators, addressing the reader to the references to gain more information on other geometries. A review on this topic has been published by (He et al. 2012) where the recent efforts devoted to optimize the WGM laser performances with a monodirectional emission have been summarized. As a matter of fact, several WGM microcavities supporting unidirectional laser emission as well as their photonics applications have been presented mainly based on three different types of WGM cavities: scatterer-induced unidirectional emission, chaos-induced unidirectional emission and grating-induced vertical emission. Whilst the spatial localization can be described in terms of divergence angle of the unidirectional emission and the mode volume of the cavity mode, the temporal localization is strongly depending by the Q factor. The mode volume is influenced by the cavity size and the wavelength, and therefore the so called kr parameter is the key feature: higher kr corresponds to higher mode volume. Divergence angle and Q factor are consequently the most important parameters for unidirectional-emission microcavities. In order to optimize both, theoretical modeling new technology approaches have been widely performed in the last ten years. In the case of unidirectionalemission cavities the performances have been improved dramatically. In Fig. 7.22 a Fig. 7.22 Experimentally demonstrated divergence angle and Q factor of the seven types of WGM cavity with unidirectional laser emission, including rounded-isosceles-triangle cavity, spiral-shaped cavity, microdisk with diffraction gratings, notched-elliptical cavity, microdisk with line defect, limacon-shaped cavity, and deformed microtoroid (Jiang et al. 2015 and references therein quoted) 342 7 Whispering Gallery Mode Devices comparison of the recent advances have been reported (Jiang et al. 2015): divergence angles smaller than 10 degrees can be achieved in the notched-elliptical cavity and the face-shaped microtoroid. As for the Q factor, most of the cavity shapes possess Q factors smaller than 104 , except for the limacon-shaped microdisks and face-shaped microtoroids. It is worth mentioning that recently, Kim et al. (2014) have reported a microdisk semiconductor laser with partially directional emission, based on the asymmetric backscattering from two Rayleigh scatterers. In this case the directionality and chirality of the laser modes have been tailored by changing some parameters such as size, shape, and relative positions of scatterers on the microcavity boundary respectively. Moreover, deformed silica microtoroids have fabricated on a silicon wafer with a 2-µm thickness silicon dioxide layer. A deformed silica toroid supported by a silicon pillar of the top diameter smaller than 10 µm have been therefore realized. This slim silicon pillar was able to reduce the silica-to-silicon loss since the chaotic modes can travel everywhere in the cavity (Wang 2015a, b; Jiang et al. 2015). Even 1.5 µm thickness erbium-doped silicon dioxide on a silicon wafer with the Er3+ ions concentration of 2 × 1019 cm−3 was used (Shao et al. 2013) to fabricate the deformed microtoroids showing unidirectional emission with divergence lower than 10°. In Fig. 7.23 an example of the achieved results is depicted. Finally, a circular symmetric microcavity, supporting high Q WGMs, can carry high orbital angular momentum (OAM), which may lead to various photonics applications. Efficient microring devices were fabricated on a silicon-on-insulator chip with a radius of 3.9 µm, which was designed with Q = 36 and a resonance wavelength in the 1550-nm wavelength band, as shown by Mahler and coworkers (Mahler et al. 2009). 7.4 WGM Microresonators in LN: Recent Advances in Dielectric Crystalline Configurations In the previous sections it has been already evidenced that in whispering-gallerymode (WGM) microresonators have been realized in various kinds of transparent materials such as liquids, polymers, glasses, semiconductors, and dielectric crystals demonstrating physical and/or optical functionalities such as lasing, filtering, nonlinear wavelength conversion, optomechanics, and cavity electrodynamics. Currently, it is of high interest to push for further on-chip integration of the WGMs with other photonic micro- and nanostructures. The platforms material that have been addressed as suitable for photonic integration application are surely semiconductors for their fabrication compatibility with the complementary metal oxide semiconductor (CMOS) approach. Recently lithium niobate on insulator (LNOI) has emerged as a valid complementary option thanks to the rapid development of innovative solutions already presented in Chap. 3 and its wide range of optical transparency. 7.4 WGM Microresonators in LN: Recent Advances … 343 Fig. 7.23 (online color at: www.lpr-journal.org) a Flow diagram of the fabrication process of ultrahigh-Q deformed microtoroid cavities. Left to right: deformed silica microdisk, first-step undercut etching of the microdisk, CO2 laser reflow and the second-step dry etching of the deformed microtoroid. b, c Top-view SEM image and its close-up view of a deformed microtoroid with R0 # 49 µm and η # 1.0. The red dashed curve plots the ideal boundary of designed ARC with η = 1.0. The black dashed curve gives the boundary of an ellipse for comparison, and the white dashed curve shows the boundary of a circle with the same diameter. The inset shows a side-view SEM image of the deformed toroid. d Experimental Q factors of various microcavities (R # 45 µm) with different deformation parameters η. e Far-0 field emission distribution for the lasing of CW, CCW and their sum at 1560.15 nm (Jiang et al. 2012) Since exterior whispering-gallery modes (WGMs) can be tailored to have mode energy mainly confined outside the microcavity, high mode overlapping with the ambient environment can be achieved as well as a strong electric field and gradient force at the surface. As a consequence highly localized WGMs in the nanoair gap of a double-layer crystalline microdisk have been obtained (Zheng et al. 2019). The geometry therein proposed is based on a horizontal slot-waveguide structure of two vertically stacked crystalline microdisks made of lithium niobate thin films. The slot WGM therefore presents a quality factor greater than 105 without metallic loss. The absorption and scattering loss have been reduced by depositing a crystalline nanofilm at sub-nm rms surface roughness. An example of the achieve structure is shown in Fig. 7.24. 344 7 Whispering Gallery Mode Devices Fig. 7.24 a Schematic of the double-layer LNOI microdisk evanescently coupled by a tapered fiber. b Top-view optical microscopy image of the microdisk. The two inner irregularly shaped circles indicate inward etching of the silica buffer layers. c SEM image of the microdisk, with enlarged false-colored images clearly showing the well-separated upper and lower LNTF layers (Zheng et al. 2019) The experimentally measured transmission spectrum for the double-layer LNOI microdisks is finally presented in Fig. 7.25. Moreover, high-Q monocrystalline LN based WGM resonators have been fabricated on a LNOI wafer by using UV-photolithography, Ar+ plasma etching, and HF etching respectively (Wang 2015a, b). The measured Q factor in 1550 nm band of LN resonators with a radius of 39.6 µm and a thickness of 500 nm are up to 1.19 × 106 . Electro-optic modulation at 1550 nm has been proved by applying an alternating voltage along the c axis of LN crystal showing a 3.0-GHz/V tuning rate of the resonance frequency of LN WGM resonators (Wang 2015a, b). A sketch of the obtained structure and relative result are reported in Figs. 7.26 and 7.27. Dielectric crystalline WGM resonators have even attracted great attention also as next generation nonlinear sources of both classical and nonclassical light because of their high nonlinear optical coefficients, low intrinsic absorption loss, and large transparent windows respectively. Advances on this fields were reported in Lin et al. (2015) with the fabrication of high-Q lithium niobate whispering-gallery-mode microresonators suspended on silica pedestals by femtosecond laser direct writing followed by focused ion beam (FIB) milling. In this case the micrometer-scale (diameter ~82 µm) LN resonator possesses a Q factor of ~2.5 × 105 around 1550 nm wavelength. The combination of femtosecond laser direct writing with FIB enables high-efficiency, high-precision nanofabrication of high-Q crystalline microresonators. In Fig. 7.28 a sketch of the preparation steps is reported. Some optimizations in the process steps have been made in the last years that allowed to reach even higher Q factor values (such as 1.46 × 107 at a wavelength of around 773 nm) (Zhang 2019). With a surface roughness to the order of Ra ~ 0.115, the major source of optical loss in the microresonator is radiative bending loss, which 7.4 WGM Microresonators in LN: Recent Advances … 345 Fig. 7.25 a Experimentally measured transmission spectrum for the double-layer LNOI microdisk. The arrows mark the theoretically predicted slot-waveguide WGMs. b Resonance of interior WGM. c Resonance of slot-waveguide WGM (Zheng et al. 2019) Fig. 7.26 Sketch of the Cr and silica removal steps (Zhang et al. 2019) 346 7 Whispering Gallery Mode Devices Fig. 7.27 a Top view scanning electron microscope (SEM) image of a fabricated LN microdisk resonator. b Close up view SEM image of the area indicated by the red box in (a). c Atomic force microscope (AFM) image of the microdisk wedge. d Optical microscope image of the microdisk resonator with different diameters (55, 85, 105, 135, 155, 185, and 205 µm) (Zhang et al. 2019) Fig. 7.28 Procedures of fabrication of a LN microresonator by water-assisted femtosecond laser ablation, followed by FIB milling, selective chemical etching, and annealing (Lin et al. 2015) 7.4 WGM Microresonators in LN: Recent Advances … 347 Fig. 7.29 a Measured Q factors of the microdisks of different diameters. b The Lorentz fitting (red curve) of a splitting mode in the microdisk with a diameter of 105 µm revealed a Q factor of 4.7 × 107 (Zhang 2019) can be reduced by increasing the diameters of the microdisks. In Fig. 7.29 an overview of the Achieved Q factor depending on the microdisk diameter and the transmission achieved at r = 105 µm. The wedge angles of the LNOI have been continuously tuned from 9° to 51° without affecting the Q factor, which is critical for nonlinear optical applications as the dispersion curve in the microdisks is a function of the wedge angle. References Baba, T.: Photonic crystals and microdisk cavities based on GaInAsP–InP system. IEEE J. Sel. Top. Quantum Electron. 3, 808–830 (1997) Baba, T., Fujita, M., Sakai, A., Kihara, M., Watanabe, R.: Lasing characteristics of GaInAsP–InP strained quantum-well microdisk injection lasers with diameter of 2–10 µm. IEEE Photonics Technol. Lett. 9, 878–880 (1997) Boriskina, S.V., Benson, T.M., Sewell, P., Nosich, A.I.: Tuning of elliptic whispering-gallery-mode microdisk waveguide filters. IEEE J. 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Express 23(18), 2307 (2015a) Wang, L., Lippolis, D., Li, Z.Y., Jiang, X.F., Gong, Q., Xiao, Y.F.: Statistics of chaotic resonances in an optical microcavity. Phys. Rev. E 93, 040201 (2015b) Zeng, K.C., Dai, L., Lin, J.Y., Jiang, H.X.: Optical resonance modes in InGaN/GaN multiplequantum-well microring cavities. Appl. Phys. Lett. 75, 2563–2565 (1999) Zhang, J., Fang, Z., Lin, J., Zhou, J., Wang, M., Wu, R., Gao, R., Cheng, Y.: Fabrication of crystalline microresonators of high quality factors with a controllable wedge angle on lithium niobate on insulator. Nanomaterials 9, 1218 (2019) Zheng, Y., Fang, Z., Liu, S., Cheng, Y., Chen, X.: High-Q exterior whispering-gallery modes in a double-layer crystalline microdisk resonator. Phys. Rev. Lett. 122, 253902 (2019) Chapter 8 Outlook Ring resonators are ideal candidates for realizing all kinds of devices ranging from optical filters to lasers for future all optical telecommunication networks to sensors including biosensors. Current developments are ongoing in the fields of quantum and neuromorphic computing, demonstrating their high versatility. Ring resonators can be integrated with other semiconductor-based devices incl. electronics putting them in the focus of current and future research. The increasing knowledge of ring resonator devices and the fast improving stateof-the-art in manufacturing technologies is leading and will lead to novel future devices with greater flexibility and higher level of integration. Miniaturization and nanofabrication technologies have already led to multiple coupled ring resonator configurations with and without integrated optical gain. State-of-the-Art design and manufacturing of ring resonators is open to fab less companies by way of multiple wafer projects (MWP) which are made available through for example ePIXfab (https://epixfab.eu/), a not-for-profit open alliance of academic and industrial organizations with a mission to promote silicon photonics science, technology and applications. In this way, access to state-of-the-art facilities is possible for realizing devices on silicon on insulator (SOI) and silicon nitride (SiN). Another joint community effort is centered around JePPIX (https://www.jep pix.eu/) which is a joint European platform for photonic integrated components and circuits, established in 2006. JePPIX provides access to design, training and MWPs on indium phosphide, silicon nitride and hybrid photonic integration. Both ePIXfab and JePPIX have their origin in EU funded projects which had the target to create a straight forward path of optoelectronic semiconductor devices from idea to high volume production. For example, one of the foundation stones of JePPIX was the EU funded project PARADIGM (Photonic Advanced Research And Development for Integrated Generic Manufacturing). Using these now established manufacturing paths, focus on the enhancement of device performance is more than ever possible in ring resonators research and development, thus ring resonators developers can target the applications in a faster and concrete way. © Springer Nature Switzerland AG 2020 D. G. Rabus and C. Sada, Integrated Ring Resonators, Springer Series in Optical Sciences 127, https://doi.org/10.1007/978-3-030-60131-7_8 351 352 8 Outlook Parallel to semiconductor processing, polymer materials, and polymer manufacturing technologies like embossing or nanoimprinting will play an increasing role also due to the “bio” component of the current worldwide research direction, integrating ring resonators with microfluidics and optofluidics. This merger of technologies is the building block of future ring resonator devices increasing again their application and thus enhancing the existing portfolio of real world systems. Ring resonators will certainly not loose their attractiveness as their versatility will increase rather than decrease which is also demonstrated by several examples given in this book and also just by the simple fact that their existence spans already more than just two decades. 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Lett. 122, 253902 (2019) Index A Add-drop filter, 6 Apodization, 38, 40 B Bandpass, 31 Birefringence, 296 Box like, 19 Buildup factor, 11 Buried heterostructure, 260, 269 Butterworth, 28, 31 C Cavity ring-down time, 246, 247, 276 Chain matrix, 16, 29 Characteristic matrix, 29, 32 Chebyshev, 28, 31, 32 Chebyshev type I, 28 Chebyshev type II, 28 Conformal transformation, 188 Coupling asymmetrical coupling, 58 critical coupling, 6 cut-back, 118, 119 symmetric coupling, 8 D Delay lines, 276 Differential group delay, 242 Dispersion, 238 chromatic dispersion, 238, 239 dispersion compensation, 199 intermodal dispersion, 239 material dispersion, 238 modal dispersion, 239 negative dispersion, 238, 240 polarization mode dispersion, 239 positive dispersion, 238, 240 quadratic dispersion, 239 structural dispersion, 239 waveguide dispersion, 238 E Etching, 55 anisotropic, 55, 56 isotropic, 55 F Fabry–Perot method, 119 Filters, 200 Finesse F, 10 Four wave mixing, 270 Free carrier plasma effect, 269 Free Spectral Range (FSR), 9 Frequency beating, 257 Full-width at Half-Maximum (FWHM), 9 G Grating, 25 Group velocity, 13 Group-velocity dispersion, 42 Group-velocity reduction, 42 I Intensity enhancement factor, 11 Ion beam milling, 139, 154, 344 Ion implanted waveguide, 129, 131, 132, 135 © Springer Nature Switzerland AG 2020 D. G. Rabus and C. Sada, Integrated Ring Resonators, Springer Series in Optical Sciences 127, https://doi.org/10.1007/978-3-030-60131-7 359 360 L Label-free optical biosensor, 319, 320, 323 Lateral coupling, 47 Lithium niobate, 44, 51, 127–133, 135, 136, 138–142, 144, 146, 147, 154, 156, 161, 162, 165, 167, 230, 342, 343, 344 Lithium Niobate on Insulator (LNOI), 133, 134, 136, 146, 149–151, 154–156, 159, 160, 163, 165, 192, 342, 344, 345, 347 Lorentzian function, 206 N Notch filter, 3 P Polarization, 114, 115 Proton exchange, 128, 130, 131, 141, 142, 146 Q Quality factor Q, 10 Quantum cascade laser, 331 Quantum confined Stark effect, 281 R Racetrack, 17 Ridge waveguides, 69, 83, 84, 132, 133, 135, 138, 139, 142, 144, 184, 257, 258, 261 S Saturable absorber, 260 Scattering matrix, 16 Shape factor, 214 Silicon on Insulator (SOI), 51, 56, 57, 59, 60, 116, 136, 155, 192, 193, 195, 196, Index 229, 236, 248, 251, 298, 304, 310, 316, 319, 342, 351 Single photon absorption, 281 Smart cut, 132, 135–138, 150 T Taylor series expansion, 15 Ti-indiffusion, 129, 131, 132, 146 Time dependent relations, 12 decay time-constant, 13 Total internal reflection, 90, 222, 327 Transfer matrix, 16, 29 Tuning carrier injection, 224, 231 electro-optic tuning, 224, 229 free carrier injection, 224, 269 photobleaching technique, 236 thermo-optic tuning, 224 Tuning enhancement factor, 266 Two-photon absorption, 276, 280 V Vernier effect, 213, 257, 266, 269 Vertical coupling, 47 W Wafer bonding, 51 adhesion bonding, 51 anodic bonding, 53 electrostatic bonding, 53 eutectic bonding, 52 fusion bonding, 52 hydrophobic bonding, 52 Wavelength reflective filter, 25 reflector, 35, 268 Z Z-transformation, 14