Hawassa University School of Postgraduate Studies Department of Chemistry Chemical Instrumentation (Chem. 572) Review Exercises 1) Discuss how each of the following transducers are used in chemical instruments Photomultipliers (Phototransducer) Charge-transfer transducers Thermocouples Pyroelectric transducers 2) What is a data domain? 3) What is a transfer function of the transducer? 4) Give examples of analog and time domain signals 5. The circuit that follows is for a laboratory potentiometer for measuring unknown voltages Vx. Assume the resistor AB is a slide wire whose resistance is directly proportional to its length. With the standard Weston cell (1.018 V) in the circuit a null point was observed when contact C was moved to a position 84.3 cm from point A. When the Weston cell was replaced with a cell of an unknown voltage Vx, a null was observed at 44.3 cm. Find the value of Vx. 6. What are the ideal characteristics of OP AMPs? 7. Draw the symbol of OP AMP? 8. Using appropriate circuit elements and symbols draw circuit diagram for each of the following and suggest their applications in chemical instruments. a) Voltage divider b) Current divider c) The inverting amplifier d) The noninverting amplifier e) The voltage follower 1 f) The current follower g) The summing amplifier h) The difference amplifier i) The cascaded amplifier 9. Figure below shows an operational difference amplifier measuring the output voltage of a pair of thermocouples. Show that the output voltage (Vo) is given by: š šš = š (š2 − š1 ) š š 10. By means of a derivation, show that the output voltage Vo, and the input voltage Vi for the following circuit are related by š 1 + š 2 šš = ( )šš š 1 11. For the circuit shown below find an expression for the output voltage. 2 12. Find an expression for the output voltage in in terms of the resistance and input voltages for the differential amplifier shown in below. 13. Assume the op amps are ideal, find the voltage gain (v0/ vi) of the following circuits. 14. Design an inverting amplifier with a gain of -15. 3 15. Design a noninverting amplifier with a gain of 10 16. Design an op amp circuit to perform the following operation: Vo = 3V1-2V2 All resistances must be ļ£ 100 kļ 17. Design a difference amplifier to have a gain of 2 and a common mode input resistance of 10 kļ at each input. 18. Design a circuit having an output given by −šš = 3š1 + 5š2 − 6š3 19. Design a circuit to perform the following calculation: 1 −šš = 10(5š1 + 3š2 20. What types of noise are frequency dependent? Frequency independent? 21. Name the type or types of noise that can be reduced by (a) decreasing the temperature of a measurement. (b) decreasing the frequency used for the measurement. (c) decreasing the bandwidth of the measurement. 22. Suggest a frequency range that is well suited for noise minimization. Explain. 23. Why is shielding vital in the design of glass electrodes that have an internal resistance of 106 Ohms or more? 24. Source: 1) Douglas A. Skoog et al. 6th Ed. 2007. Principles of Instrumental Analysis 2) Electronic material, Chapter 5. Operational Amplifiers 4