A P P E N D I X A THE INTERNATIONAL SYSTEM OF UNITS (SI)* Table 1 The SI Base Units Quantity Name Symbol length meter m mass kilogram kg time second s electric current ampere A thermodynamic temperature kelvin K amount of substance mole mol luminous intensity candela cd Definition “. . . the length of the path traveled by light in vacuum in 1/299,792,458 of a second.” (1983) “. . . this prototype [a certain platinum – iridium cylinder] shall henceforth be considered to be the unit of mass.” (1889) “. . . the duration of 9,192,631,770 periods of the radiation corresponding to the transition between the two hyperfine levels of the ground state of the cesium-133 atom.” (1967) “. . . that constant current which, if maintained in two straight parallel conductors of infinite length, of negligible circular cross section, and placed 1 meter apart in vacuum, would produce between these conductors a force equal to 2 107 newton per meter of length.” (1946) “. . . the fraction 1/273.16 of the thermodynamic temperature of the triple point of water.” (1967) “. . . the amount of substance of a system which contains as many elementary entities as there are atoms in 0.012 kilogram of carbon-12.” (1971) “. . . the luminous intensity, in a given direction, of a source that emits monochromatic radiation of frequency 540 10 12 hertz and that has a radiant intensity in that direction of 1/683 watt per steradian.” (1979) *Adapted from “The International System of Units (SI),” National Bureau of Standards Special Publication 330, 1972 edition. The definitions above were adopted by the General Conference of Weights and Measures, an international body, on the dates shown. In this book we do not use the candela. A-1 A-2 APPE N DIX A TH E I NTE R NATIONAL SYSTE M OF U N ITS (SI) Table 2 Some SI Derived Units Quantity Name of Unit Symbol area volume frequency mass density (density) speed, velocity square meter cubic meter hertz kilogram per cubic meter meter per second m2 m3 Hz kg/m3 m/s angular velocity acceleration angular acceleration force pressure radian per second meter per second per second radian per second per second newton pascal rad/s m/s2 rad/s2 N Pa kg m/s2 N/m2 work, energy, quantity of heat power quantity of electric charge potential difference, electromotive force electric field strength joule watt coulomb volt volt per meter (or newton per coulomb) J W C V V/m N m J/s A s W/A N/C electric resistance capacitance magnetic flux inductance magnetic flux density ohm farad weber henry tesla F Wb H T V/A A s/V V s V s/A Wb/m2 magnetic field strength entropy specific heat thermal conductivity radiant intensity ampere per meter joule per kelvin joule per kilogram kelvin watt per meter kelvin watt per steradian A/m J/K J/(kg K) W/(m K) W/sr Table 3 The SI Supplementary Units Quantity Name of Unit Symbol plane angle solid angle radian steradian rad sr s1 A P P E N D I X B SOME FUNDAMENTAL CONSTANTS OF PHYSICS* Best (1998) Value Constant Symbol Valuea Computational Value Uncertaintyb Speed of light in a vacuum Elementary charge Gravitational constant Universal gas constant Avogadro constant Boltzmann constant Stefan – Boltzmann constant Molar volume of ideal gas at STPd Permittivity constant Permeability constant Planck constant c e G R NA k s Vm e0 m0 h 3.00 10 8 m/s 1.60 10 19 C 6.67 10 11 m3/s2 kg 8.31 J/mol K 6.02 10 23 mol1 1.38 10 23 J/K 5.67 10 8 W/m2 K4 2.27 10 2 m3/mol 8.85 10 12 F/m 1.26 10 6 H/m 6.63 10 34 J s 2.997 924 58 1.602 176 487 6.674 28 8.314 472 6.022 141 79 1.380 650 4 5.670 400 2.271 098 1 8.854 187 817 62 1.256 637 061 43 6.626 068 96 exact 0.025 100 1.7 0.050 1.7 7.0 1.7 exact exact 0.050 Electron massc me Proton massc mp Ratio of proton mass to electron mass Electron charge-to-mass ratio Neutron massc mp/me e/me mn Hydrogen atom massc Deuterium atom massc Helium atom massc Muon mass m1H m2H m4He mm 9.11 10 31 kg 5.49 10 4 u 1.67 10 27 kg 1.0073 u 1840 1.76 10 11 C/kg 1.68 10 27 kg 1.0087 u 1.0078 u 2.0136 u 4.0026 u 1.88 10 28 kg 9.109 382 15 5.485 799 094 3 1.672 621 637 1.007 276 466 77 1836.152 672 47 1.758 820 150 1.674 927 211 1.008 664 915 97 1.007 825 031 6 2.013 553 212 724 4.002 603 2 1.883 531 30 0.050 4.2 10 4 0.050 1.0 10 4 4.3 10 4 0.025 0.050 4.3 10 4 0.0005 3.9 10 5 0.067 0.056 Electron magnetic moment Proton magnetic moment Bohr magneton Nuclear magneton Bohr radius Rydberg constant Electron Compton wavelength me mp mB mN a R lC 9.28 1024 J/T 1.41 1026 J/T 9.27 1024 J/T 5.05 1027 J/T 5.29 1011 m 1.10 10 7 m1 2.43 1012 m 9.284 763 77 1.410 606 662 9.274 009 15 5.050 783 24 5.291 772 085 9 1.097 373 156 852 7 2.426 310 217 5 0.025 0.026 0.025 0.025 6.8 10 4 6.6 10 6 0.0014 a Values given in this column should be given the same unit and power of 10 as the computational value. b Parts per million. Masses given in u are in unified atomic mass units, where 1 u 1.660 538 782 10 27 kg. c d STP means standard temperature and pressure: 0#C and 1.0 atm (0.1 MPa). *The values in this table were selected from the 1998 CODATA recommended values (www.physics.nist.gov). A-3 A P P E N D I X C SOME ASTRONOMICAL DATA Some Distances from Earth 3.82 10 8 m 1.50 10 11 m 4.04 10 16 m To the Moon* To the Sun* To the nearest star (Proxima Centauri) 2.2 10 20 m 2.1 10 22 m 10 26 m To the center of our galaxy To the Andromeda Galaxy To the edge of the observable universe *Mean distance. The Sun, Earth, and the Moon Property Unit Mass Mean radius Mean density Free-fall acceleration at the surface Escape velocity Period of rotationa Radiation powerc kg m kg/m3 m/s2 km/s — W Sun 1.99 10 30 6.96 10 8 1410 274 618 37 d at poles b 26 d at equator b 3.90 10 26 Earth Moon 5.98 10 24 6.37 10 6 5520 9.81 11.2 23 h 56 min 7.36 10 22 1.74 10 6 3340 1.67 2.38 27.3 d a Measured with respect to the distant stars. The Sun, a ball of gas, does not rotate as a rigid body. c Just outside Earth’s atmosphere solar energy is received, assuming normal incidence, at the rate of 1340 W/m2. b Some Properties of the Planets Mercury Venus Earth Mars Jupiter Saturn Uranus Neptune Plutod Mean distance from Sun, 106 km 57.9 108 150 228 778 1430 2870 4500 5900 Period of revolution, y 0.241 0.615 1.00 1.88 11.9 29.5 84.0 165 248 Period of rotation,a d 58.7 243b 0.997 1.03 0.409 0.426 0.451b 0.658 6.39 Orbital speed, km/s 47.9 35.0 29.8 24.1 13.1 9.64 6.81 5.43 4.74 Inclination of axis to orbit 28# 3# 23.4# 25.0# 3.08# 26.7# 97.9# 29.6# 57.5# Inclination of orbit to Earth’s orbit 7.00# 3.39# 1.85# 1.30# 2.49# 0.77# 1.77# 17.2# Eccentricity of orbit 0.206 0.0068 0.0167 0.0934 0.0485 0.0556 0.0472 0.0086 0.250 Equatorial diameter, km 4880 12 100 12 800 6790 143 000 120 000 51 800 49 500 2300 Mass (Earth 1) 0.0558 0.815 1.000 0.107 318 95.1 14.5 17.2 0.002 Density (water 1) 5.60 5.20 5.52 3.95 1.31 0.704 1.21 1.67 2.03 Surface value of g,c m/s2 3.78 8.60 9.78 3.72 22.9 9.05 7.77 11.0 0.5 Escape velocity,c km/s 4.3 10.3 11.2 5.0 59.5 35.6 21.2 23.6 1.3 Known satellites 0 0 1 2 67 ring 62 rings 27 rings 13 rings 4 a Measured with respect to the distant stars. Venus and Uranus rotate opposite their orbital motion. c Gravitational acceleration measured at the planet’s equator. d Pluto is now classified as a dwarf planet. b A-4 A P P E N D I X D CONVERSION FACTORS Conversion factors may be read directly from these tables. For example, 1 degree 2.778 10 3 revolutions, so 16.7# 16.7 2.778 10 3 rev. The SI units are fully capitalized. Adapted in part from G. Shortley and D. Williams, Elements of Physics, 1971, Prentice-Hall, Englewood Cliffs, NJ. Plane Angle $ RADIAN rev 60 1 1.667 10 2 3438 2.16 10 4 3600 60 1 2.063 10 5 1.296 10 6 1.745 10 2 2.909 10 4 4.848 10 6 1 6.283 2.778 10 3 4.630 10 5 7.716 10 7 0.1592 1 ° 1 degree 1 1 minute 1.667 10 2 1 second 2.778 10 4 1 RADIAN 57.30 1 revolution 360 Solid Angle 1 sphere 4p steradians 12.57 steradians Length cm 1 centimeter 1 1 METER 100 1 kilometer 10 5 1 inch 2.540 1 foot 30.48 1 mile 1.609 10 5 1 angström 10 10 m 1 nautical mile 1852 m 1.151 miles 6076 ft METER km in. ft mi 10 2 1 1000 2.540 10 2 0.3048 1609 10 5 10 3 1 2.540 10 5 3.048 10 4 1.609 0.3937 39.37 3.937 10 4 1 12 6.336 10 4 3.281 10 2 3.281 3281 8.333 10 2 1 5280 6.214 10 6 6.214 10 4 0.6214 1.578 10 5 1.894 10 4 1 1 fermi 10 15 m 1 light-year 9.461 10 12 km 1 fathom 6 ft 1 rod 16.5 ft 1 Bohr radius 5.292 10 11 m 1 mil 10 3 in. 1 parsec 3.084 10 km 1 yard 3 ft 1 nm 10 9 m 13 Area METER2 1 SQUARE METER 1 1 square centimeter 10 4 1 square foot 9.290 10 2 1 square inch 6.452 10 4 cm2 ft2 in.2 10 4 1 929.0 6.452 10.76 1.076 10 3 1 6.944 10 3 1550 0.1550 144 1 1 square mile 2.788 10 7 ft2 640 acres 1 acre 43 560 ft 2 1 barn 10 28 m2 1 hectare 10 4 m2 2.471 acres A-5 A-6 APPE N DIX D CONVE RSION FACTORS Volume METER3 1 CUBIC METER 1 1 cubic centimeter 10 6 1 liter 1.000 10 3 1 cubic foot 2.832 10 2 1 cubic inch 1.639 10 5 cm3 L ft3 in.3 10 6 1 1000 2.832 10 4 16.39 1000 1.000 10 3 1 28.32 1.639 10 2 35.31 3.531 10 5 3.531 10 2 1 5.787 10 4 6.102 10 4 6.102 10 2 61.02 1728 1 1 U.S. fluid gallon 4 U.S. fluid quarts 8 U.S. pints 128 U.S. fluid ounces 231 in.3 1 British imperial gallon 277.4 in.3 1.201 U.S. fluid gallons Mass Quantities in the colored areas are not mass units but are often used as such. For example, when we write 1 kg “” 2.205 lb, this means that a kilogram is a mass that weighs 2.205 pounds at a location where g has the standard value of 9.80665 m/s2. g KILOGRAM 1 gram 1 1 KILOGRAM 1000 1 slug 1.459 10 4 1 atomic mass unit 1.661 10 24 1 ounce 28.35 1 pound 453.6 1 ton 9.072 10 5 slug u oz lb ton 0.001 1 14.59 6.852 10 5 6.852 10 2 1 6.022 10 23 6.022 10 26 8.786 10 27 3.527 10 2 35.27 514.8 2.205 10 3 2.205 32.17 1.102 10 6 1.102 10 3 1.609 10 2 1.661 10 27 2.835 10 2 0.4536 907.2 1.138 10 28 1.943 10 3 3.108 10 2 62.16 1 1.718 10 25 2.732 10 26 5.463 10 29 5.857 10 26 1 16 3.2 10 4 3.662 10 27 6.250 10 2 1 2000 1.830 10 30 3.125 10 5 0.0005 1 1 metric ton 1000 kg Density Quantities in the colored areas are weight densities and, as such, are dimensionally different from mass densities. See the note for the mass table. KILOGRAM/ METER3 slug/ft3 1 slug per foot3 1 1 KILOGRAM per METER3 1.940 10 3 1 gram per centimeter3 1.940 1 pound per foot3 3.108 10 2 1 pound per inch3 53.71 g/cm3 lb/ft3 515.4 0.5154 32.17 1.862 10 2 1 1000 16.02 2.768 10 4 0.001 1 16.02 10 2 27.68 6.243 10 2 62.43 1 1728 3.613 10 5 3.613 10 2 5.787 10 4 1 T ime Time y 1 year 1 1 day 2.738 10 3 1 hour 1.141 10 4 1 minute 1.901 10 6 1 SECOND 3.169 10 8 lb/in.3 d h min SECOND 365.25 1 4.167 10 2 6.944 10 4 1.157 10 5 8.766 10 3 24 1 1.667 10 2 2.778 10 4 5.259 10 5 1440 60 1 1.667 10 2 3.156 10 7 8.640 10 4 3600 60 1 APPE N DIX D CONVE RSION FACTORS Speed ft/s 1 foot per second 1 1 kilometer per hour 0.9113 1 METER per SECOND 3.281 1 mile per hour 1.467 1 centimeter per second 3.281 10 2 1 knot 1 nautical mi/h 1.688 ft/s km/h METER/SECOND mi/h cm/s 1.097 1 3.6 1.609 3.6 10 2 0.3048 0.2778 1 0.4470 0.01 0.6818 0.6214 2.237 1 2.237 10 2 30.48 27.78 100 44.70 1 1 mi/min 88.00 ft/s 60.00 mi/h Force Force units in the colored areas are now little used. To clarify: 1 gram-force ( 1 gf) is the force of gravity that would act on an object whose mass is 1 gram at a location where g has the standard value of 9.80665 m/s2. dyne 1 dyne 1 1 NEWTON 10 5 1 pound 4.448 10 5 1 poundal 1.383 10 4 1 gram-force 980.7 1 kilogram-force 9.807 10 5 NEWTON lb pdl gf 10 5 1 4.448 0.1383 9.807 10 3 9.807 2.248 10 6 0.2248 1 3.108 10 2 2.205 10 3 2.205 7.233 10 5 7.233 32.17 1 7.093 10 2 70.93 1.020 10 3 102.0 453.6 14.10 1 1000 kgf 1.020 10 6 0.1020 0.4536 1.410 10 2 0.001 1 1 ton 2000 lb Pressure atm 1 atmosphere 1 1 dyne per centimeter2 9.869 10 7 1 inch of watera at 4°C 2.458 10 3 1 centimeter of mercurya at 0°C 1.316 10 2 1 PASCAL 9.869 10 6 1 pound per inch2 6.805 10 2 1 pound per foot2 4.725 10 4 dyne/cm2 inch of water cm Hg PASCAL lb/in.2 lb/ft2 1.013 10 6 406.8 76 1.013 10 5 14.70 2116 1 4.015 10 4 7.501 10 5 0.1 1.405 10 5 2.089 10 3 2491 1 0.1868 249.1 3.613 10 2 5.202 1.333 10 4 10 6.895 10 4 478.8 5.353 4.015 10 3 27.68 0.1922 1 7.501 10 4 5.171 3.591 10 2 1333 1 6.895 10 3 47.88 0.1934 1.450 10 4 1 6.944 10 3 27.85 2.089 10 2 144 1 a Where the acceleration of gravity has the standard value of 9.80665 m/s2. 1 bar 10 6 dyne/cm2 0.1 MPa 1 millibar 10 3 dyne/cm2 10 2 Pa 1 torr 1 mm Hg A-7 A-8 APPE N DIX D CONVE RSION FACTORS Energy, Work, Heat Quantities in the colored areas are not energy units but are included for convenience. They arise from the relativistic mass – energy equivalence formula E mc2 and represent the energy released if a kilogram or unified atomic mass unit (u) is completely converted to energy (bottom two rows) or the mass that would be completely converted to one unit of energy (rightmost two columns). Btu 1 British thermal unit 1 9.481 1 erg 10 11 1.285 1 foot-pound 10 3 1 horsepowerhour 2545 9.481 1 JOULE 10 4 3.968 1 calorie 10 3 1 kilowatthour 3413 1.519 1 electron-volt 10 22 1 million 1.519 electron-volts 10 16 8.521 1 kilogram 10 13 1 unified atomic mass 1.415 unit 10 13 ft lb erg 1.055 10 10 1 1.356 10 7 2.685 10 13 777.9 7.376 10 8 1 1.980 10 6 hp h 3.929 10 4 3.725 10 14 5.051 10 7 1 3.725 10 7 1.560 10 6 JOULE 1055 252.0 10 7 2.389 10 8 1.356 2.685 10 6 0.3238 6.413 10 5 1 0.2389 1 8.600 10 5 3.827 10 20 3.827 10 14 2.146 10 16 3.564 10 11 107 4.1868 10 7 3.600 10 13 1.602 10 12 1.602 10 6 8.987 10 23 3.088 2.655 10 6 1.182 10 19 1.182 10 13 6.629 10 16 1.341 5.967 10 26 5.967 10 20 3.348 10 10 4.1868 3.600 10 6 1.602 10 19 1.602 10 13 8.987 10 16 1.492 10 3 1.101 10 10 5.559 10 17 1.492 10 10 0.7376 kW h eV MeV kg 2.930 10 4 2.778 10 14 3.766 10 7 6.585 10 21 6.242 10 11 8.464 10 18 1.676 10 25 6.242 10 18 2.613 10 19 2.247 10 25 6.585 10 15 6.242 10 5 8.464 10 12 1.676 10 19 6.242 10 12 2.613 10 13 2.247 10 19 1 10 6 106 5.610 10 35 1 5.610 10 29 1.174 10 14 1.113 10 24 1.509 10 17 2.988 10 11 1.113 10 17 4.660 10 17 4.007 10 11 1.783 10 36 1.783 10 30 1 9.320 10 8 932.0 cal 0.7457 2.778 10 7 1.163 10 6 1 4.450 10 26 4.450 10 20 2.497 10 10 4.146 10 17 1.661 10 27 u 7.070 10 12 670.2 9.037 10 9 1.799 10 16 6.702 10 9 2.806 10 10 2.413 10 16 1.074 10 9 1.074 10 3 6.022 10 26 1 Power Btu/h ft lb/s hp cal/s kW WATT 1 British thermal unit per hour 1 1 foot-pound per second 4.628 1 horsepower 2545 1 calorie per second 14.29 1 kilowatt 3413 1 WATT 3.413 0.2161 1 550 3.088 737.6 0.7376 3.929 10 4 1.818 10 3 1 5.615 10 3 1.341 1.341 10 3 6.998 10 2 0.3239 178.1 1 238.9 0.2389 2.930 10 4 1.356 10 3 0.7457 4.186 10 3 1 0.001 0.2930 1.356 745.7 4.186 1000 1 Magnetic Field gauss 1 gauss 1 1 TESLA 10 4 1 milligauss 0.001 1 tesla 1 weber/meter2 Magnetic Flux TESLA milligauss 10 4 1 10 7 1000 10 7 1 maxwell 1 maxwell 1 1 WEBER 10 8 WEBER 10 8 1 A P P E N D I X E MATHEMATICAL FORMULAS Geometry ⬆ is not equal to Circle of radius r: circumference 2pr; area pr2. Sphere of radius r: area 4pr 2; volume 43pr3. Right circular cylinder of radius r and height h: area 2pr 2 2prh; volume pr 2h. Triangle of base a and altitude h: area 12ah. is identical to, is defined as is greater than (% is much greater than) is less than ( is much less than) is greater than or equal to (or, is no less than) is less than or equal to (or, is no more than) plus or minus Quadratic Formula If ax bx c 0, then x 2 & is proportional to 1b2 4ac . 2a b the sum of xavg the average value of x Trigonometric Functions of Angle u sin u y r cos u x r tan u y x cot u x y sec u r x csc u Trigonometric Identities y axis sin(90# u) cos u cos(90# u) sin u sin u/cos u tan u r r y θ x axis x 0 sin2 u cos2 u 1 y csc2 u cot2 u 1 Pythagorean Theorem sin 2u 2 sin u cos u In this right triangle, a2 b2 c2 c cos 2u cos2 u sin2 u 2 cos2 u 1 1 2 sin2 u a b Triangles Angles are A, B, C Opposite sides are a, b, c Angles A B C 180# sin B sin C sin A a b c 2 2 2 c a b 2ab cos C Exterior angle D A C sec2 u tan2 u 1 C b B equals approximately is the order of magnitude of cos a sin b cos(a b) cos a cos b ' sin a sin b tan(a b) tan a tan b 1 ' tan a tan b sin b 2 sin 12(a b) cos 12(a ' b) cos a cos b 2 cos 12(a b) cos 12(a b) D cos a cos b 2 sin 12(a b) sin 12(a b) c Mathematical Signs and Symbols equals b) sin a cos b sin a a A sin(a Binomial Theorem (1 x)n 1 n(n 1)x2 nx 1! 2! (x2 1) Exponential Expansion ex 1 x x2 x3 2! 3! A-9 A-10 APPE N DIX E MATH E MATICAL FOR M U L AS Logarithmic Expansion Products of Vectors ln(1 x) x 12 x2 13 x3 (|x| 1) Let î, ĵ , and k̂ be unit vectors in the x, y, and z directions. Then î î ĵ ĵ k̂ k̂ 1, Trigonometric Expansions (u in radians) î î ĵ ĵ k̂ k̂ 0, u5 u3 sin u u 3! 5! u4 u2 2! 4! cos u 1 u3 2u 5 tan u u 3 15 î ĵ k̂, k̂ î ĵ : a ax î ay ĵ azk̂. : Let : c be arbitrary vectors with magnitudes a, a , b , and : b, and c.Then : : : : : c ) (a b ) (a : c) a (b : : : : : : (sa )b: a (sb ) s(a b) Two simultaneous equations in unknowns x and y, a1x b1 y c1 and a2x b2 y c2, have the solutions a1c2 a2c1 . a1b2 a2b1 c1 c2 b1 b2 a1 a2 b1 b2 a1 a2 c1 c2 a1 a2 b1 b2 c1b2 c2b1 a1b2 a2b1 (s a scalar). Let u be the smaller of the two angles between : a and b . Then : : : : ab b: a axbx ayby azbz ab cos î a b b a ax bx : : : î and y ĵ k̂ î, Any vector : a with components ax, ay, and az along the x, y, and z axes can be written as Cramer’s Rule x î ĵ ĵ k̂ k̂ î 0, ay by : ĵ ay by k̂ az bz az a az a ĵ x k̂ x bz bx bz bx (aybz by az)î (azbx bzax)ĵ (axby bxay)k̂ : : b | ab sin u |a : : : : : a (b : c ) b ( : c : a) : c (a b) : : : : : : : a (b : c ) (a c )b (a b): c ay by APPE N DIX E MATH E MATICAL FOR M U L AS Derivatives and Integrals In what follows, the letters u and v stand for any functions of x, and a and m are constants. To each of the indefinite integrals should be added an arbitrary constant of integration. The Handbook of Chemistry and Physics (CRC Press Inc.) gives a more extensive tabulation. 1. 2. 3. 1. dx 1 dx 4. 2. du d (au) a dx dx 5. d du dv (u v) dx dx dx 6. 3. 4. d m x mxm1 dx d 1 5. ln x dx x 7. 8. 6. dv du d (uv) u v dx dx dx 7. d x e ex dx 8. d sin x cos x dx 10. 9. d cos x sin x dx 11. 10. d tan x sec2 x dx 12. 11. d cot x csc2 x dx 13. 12. d sec x tan x sec x dx 14. 13. d csc x cot x csc x dx 15. du d u 14. e eu dx dx du d 15. sin u cos u dx dx d du 16. cos u sin u dx dx 9. dx x au dx a u dx xm dx dx ln |x| x u dv dx uv dx 18. 19. 20. 0 21. v dx v du dx dx ex dx ex sin x dx cos x cos x dx sin x tan x dx ln |sec x| sin2 x dx 12 x 14 sin 2x eax dx 1 ax e a 1 (ax 1) eax a2 xeax dx x2eax dx xneax dx x2neax dx 2 0 17. u dx xm1 ( m ( 1) m1 0 16. (u v) dx 1 (a2x2 2ax 2)eax a3 n! an1 p 13 5 (2n 1) n1 n 2 a A a dx ln(x 2x2 a2) 2x2 a2 1 x dx 2 (x2 a2)3/2 (x a2)1/2 dx x 2 2 2 3/2 (x a ) a (x a2)1/2 2 x2n1 eax dx 2 n! (a 0) 2an1 x dx x d ln(x d) xd A-11 A P P E N D I X F PROPERTIES OF THE ELEMENTS All physical properties are for a pressure of 1 atm unless otherwise specified. Element Symbol Atomic Number Z Actinium Aluminum Americium Antimony Argon Arsenic Astatine Barium Berkelium Beryllium Bismuth Bohrium Boron Bromine Cadmium Calcium Californium Carbon Cerium Cesium Chlorine Chromium Cobalt Copernicium Copper Curium Darmstadtium Dubnium Dysprosium Einsteinium Erbium Europium Fermium Flerovium* Fluorine Francium Gadolinium Gallium Germanium Gold Ac Al Am Sb Ar As At Ba Bk Be Bi Bh B Br Cd Ca Cf C Ce Cs Cl Cr Co Cn Cu Cm Ds Db Dy Es Er Eu Fm Fl F Fr Gd Ga Ge Au 89 13 95 51 18 33 85 56 97 4 83 107 5 35 48 20 98 6 58 55 17 24 27 112 29 96 110 105 66 99 68 63 100 114 9 87 64 31 32 79 A-12 Molar Mass, g/mol (227) 26.9815 (243) 121.75 39.948 74.9216 (210) 137.34 (247) 9.0122 208.980 262.12 10.811 79.909 112.40 40.08 (251) 12.01115 140.12 132.905 35.453 51.996 58.9332 (285) 63.54 (247) (271) 262.114 162.50 (254) 167.26 151.96 (237) (289) 18.9984 (223) 157.25 69.72 72.59 196.967 Density, g/cm3 at 20#C 10.06 2.699 13.67 6.691 1.6626 10 3 5.78 — 3.594 14.79 1.848 9.747 — 2.34 3.12 (liquid) 8.65 1.55 — 2.26 6.768 1.873 3.214 10 3 (0#C) 7.19 8.85 — 8.96 13.3 — — 8.55 — 9.15 5.243 — — 1.696 10 3 (0#C) — 7.90 5.907 5.323 19.32 Melting Point, #C 1323 660 1541 630.5 189.4 817 (28 atm) (302) 729 — 1287 271.37 — 2030 7.2 321.03 838 — 3727 804 28.40 101 1857 1495 — 1083.40 — — — 1409 — 1522 817 — — 219.6 (27) 1312 29.75 937.25 1064.43 Boiling Point, #C Specific Heat, J/(g #C) at 25#C (3473) 2450 — 1380 185.8 613 — 1640 — 2770 1560 — — 58 765 1440 — 4830 3470 690 34.7 2665 2900 — 2595 — — — 2330 — 2630 1490 — — 188.2 — 2730 2237 2830 2970 0.092 0.900 — 0.205 0.523 0.331 — 0.205 — 1.83 0.122 — 1.11 0.293 0.226 0.624 — 0.691 0.188 0.243 0.486 0.448 0.423 — 0.385 — — — 0.172 — 0.167 0.163 — — 0.753 — 0.234 0.377 0.322 0.131 APPE N DIX F PROPE RTI ES OF TH E E LE M E NTS Element Symbol Atomic Number Z Hafnium Hassium Helium Holmium Hydrogen Indium Iodine Iridium Iron Krypton Lanthanum Lawrencium Lead Lithium Livermorium* Lutetium Magnesium Manganese Meitnerium Mendelevium Mercury Molybdenum Neodymium Neon Neptunium Nickel Niobium Nitrogen Nobelium Osmium Oxygen Palladium Phosphorus Platinum Plutonium Polonium Potassium Praseodymium Promethium Protactinium Radium Radon Rhenium Rhodium Roentgenium Rubidium Ruthenium Rutherfordium Hf Hs He Ho H In I Ir Fe Kr La Lr Pb Li Lv Lu Mg Mn Mt Md Hg Mo Nd Ne Np Ni Nb N No Os O Pd P Pt Pu Po K Pr Pm Pa Ra Rn Re Rh Rg Rb Ru Rf 72 108 2 67 1 49 53 77 26 36 57 103 82 3 116 71 12 25 109 101 80 42 60 10 93 28 41 7 102 76 8 46 15 78 94 84 19 59 61 91 88 86 75 45 111 37 44 104 Molar Mass, g/mol Density, g/cm3 at 20#C 178.49 (265) 4.0026 164.930 1.00797 114.82 126.9044 192.2 55.847 83.80 138.91 (257) 207.19 6.939 (293) 174.97 24.312 54.9380 (266) (256) 200.59 95.94 144.24 20.183 (237) 58.71 92.906 14.0067 (255) 190.2 15.9994 106.4 30.9738 195.09 (244) (210) 39.102 140.907 (145) (231) (226) (222) 186.2 102.905 (280) 85.47 101.107 261.11 13.31 — 0.1664 10 3 8.79 0.08375 10 3 7.31 4.93 22.5 7.874 3.488 10 3 6.189 — 11.35 0.534 — 9.849 1.738 7.44 — — 13.55 10.22 7.007 0.8387 10 3 20.25 8.902 8.57 1.1649 10 3 — 22.59 1.3318 10 3 12.02 1.83 21.45 19.8 9.32 0.862 6.773 7.22 15.37 (estimated) 5.0 9.96 10 3 (0#C) 21.02 12.41 — 1.532 12.37 — Melting Point, #C 2227 — 269.7 1470 259.19 156.634 113.7 2447 1536.5 157.37 920 — 327.45 180.55 — 1663 650 1244 — — 38.87 2617 1016 248.597 637 1453 2468 210 — 3027 218.80 1552 44.25 1769 640 254 63.20 931 (1027) (1230) 700 (71) 3180 1963 — 39.49 2250 — Boiling Point, #C Specific Heat, J/(g #C) at 25#C 5400 — 268.9 2330 252.7 2000 183 (5300) 3000 152 3470 — 1725 1300 — 1930 1107 2150 — — 357 5560 3180 246.0 — 2730 4927 195.8 — 5500 183.0 3980 280 4530 3235 — 760 3020 — — — 61.8 5900 4500 — 688 4900 — 0.144 — 5.23 0.165 14.4 0.233 0.218 0.130 0.447 0.247 0.195 — 0.129 3.58 — 0.155 1.03 0.481 — — 0.138 0.251 0.188 1.03 1.26 0.444 0.264 1.03 — 0.130 0.913 0.243 0.741 0.134 0.130 — 0.758 0.197 — — — 0.092 0.134 0.243 — 0.364 0.239 — A-13 A-14 APPE N DIX F PROPE RTI ES OF TH E E LE M E NTS Element Samarium Scandium Seaborgium Selenium Silicon Silver Sodium Strontium Sulfur Tantalum Technetium Tellurium Terbium Thallium Thorium Thulium Tin Titanium Tungsten Unnamed Unnamed Unnamed Unnamed Uranium Vanadium Xenon Ytterbium Yttrium Zinc Zirconium Symbol Atomic Number Z Molar Mass, g/mol Sm Sc Sg Se Si Ag Na Sr S Ta Tc Te Tb Tl Th Tm Sn Ti W Uut Uup Uus Uuo U V Xe Yb Y Zn Zr 62 21 106 34 14 47 11 38 16 73 43 52 65 81 90 69 50 22 74 113 115 117 118 92 23 54 70 39 30 40 150.35 44.956 263.118 78.96 28.086 107.870 22.9898 87.62 32.064 180.948 (99) 127.60 158.924 204.37 (232) 168.934 118.69 47.90 183.85 (284) (288) — (294) (238) 50.942 131.30 173.04 88.905 65.37 91.22 Density, g/cm3 at 20#C 7.52 2.99 — 4.79 2.33 10.49 0.9712 2.54 2.07 16.6 11.46 6.24 8.229 11.85 11.72 9.32 7.2984 4.54 19.3 — — — — 18.95 6.11 5.495 10 3 6.965 4.469 7.133 6.506 Melting Point, #C 1072 1539 — 221 1412 960.8 97.85 768 119.0 3014 2200 449.5 1357 304 1755 1545 231.868 1670 3380 — — — — 1132 1902 111.79 824 1526 419.58 1852 Boiling Point, #C Specific Heat, J/(g #C) at 25#C 1630 2730 — 685 2680 2210 892 1380 444.6 5425 — 990 2530 1457 (3850) 1720 2270 3260 5930 — — — — 3818 3400 108 1530 3030 906 3580 0.197 0.569 — 0.318 0.712 0.234 1.23 0.737 0.707 0.138 0.209 0.201 0.180 0.130 0.117 0.159 0.226 0.523 0.134 — — — — 0.117 0.490 0.159 0.155 0.297 0.389 0.276 The values in parentheses in the column of molar masses are the mass numbers of the longest-lived isotopes of those elements that are radioactive. Melting points and boiling points in parentheses are uncertain. The data for gases are valid only when these are in their usual molecular state, such as H2, He, O2, Ne, etc. The specific heats of the gases are the values at constant pressure. Source: Adapted from J. Emsley, The Elements, 3rd ed., 1998, Clarendon Press, Oxford. See also www.webelements.com for the latest values and newest elements. *The names and symbols for elements 114 (Flerovium, Fl) and 116 (Livermorium, Lv) have been suggested but are not official.