This document is not an API Standard; it is under consideration within an API technical committee but has not received all approvals required to become an API Standard. It shall not be reproduced or circulated or quoted, in whole or in part, outside of API committee activities except with the approval of the Chairman of the committee having jurisdiction and staff of the API Standards Dept. Copyright API. All rights reserved. Manual of Petroleum Measurement Standards Chapter 12 — Calculation of Petroleum Quantities Section 1 — Calculation of Static Petroleum Quantities Part 2 — Calculation Procedures for Tank Cars SECOND EDITION, XXXX, 2016 SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS Introduction This Chapter of the Manual of Petroleum Measurement Standards describes the standardized method for calculating target loading quantities and actual loaded quantities of liquids in tank cars. Also addressed within this chapter is an explanation of the factors required for the calculations. 1 Chapter 12 — Calculation of Petroleum Quantities Section 1 — Calculation of Static Petroleum Quantities Part 2 — Calculation Procedures for Tank Cars 1. Scope This Chapter is applicable to all crude oils, petroleum products, and petrochemicals (including LPGs and other liquefied gases) transported by rail tank car. It does not cover any products loaded or measured as solids. It defines the terms required to understand the calculations, and provides instructions for their use. The cars are assumed to be on level ground. 2 Normative References The following referenced documents are indispensable for the application of this document. For dated references, only edition cited applies. For undated references, the latest edition of the referenced document applies (including any addenda / errata). API Manual of Petroleum Measurement Standards (MPMS) Chapter 1, Vocabulary API Manual of Petroleum Measurement Standards (MPMS) Chapter 3.2, Tank Car Measurement API Manual of Petroleum Measurement Standards (MPMS) Chapter 10, Sediment and Water API Manual of Petroleum Measurement Standards (MPMS) Chapter 11.2.4, Temperature Correction for the Volume of NGL and LPG, Tables 23E, 24E, 53E, 54E, 59E, and 60E API Manual of Petroleum Measurement Standards (MPMS) Chapter 11.2.5, A Simplified Vapor Pressure Correlation for Commercial NGLs API Manual of Petroleum Measurement Standards (MPMS) Chapter 12.2, Calculation of Petroleum Quantities Using Dynamic Measurement Methods and Volumetric Correction Factors ASTM D15551, Standard Test Method for Calculation of Volume and Weight of Industrial Aromatic Hydrocarbons and Cyclohexane 3. Terms, Definitions, Acronyms, and Abbreviations For the purposes of this document, the following terms and definitions apply. Terms of more general use (i.e., API Gravity, Density, etc.) may be found in API MPMS Chapter 1. 3.1 General 3.1.1 capacity table adjustment factor CTAF Correction applied to capacity table volumes. 3.1.2 closed loading/unloading The manway remains closed or covered during loading/unloading. 3.1.3 compartment car A car with two or more independent (no common walls) tanks, each with its own manway, reference point, and capacity table. 1 2 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES 3.1.4 correction, pressure, liquid CPL Correction for the compressibility effect of pressure on a liquid. 3.1.5 correction, pressure, shell CPS Correction factor for the effect of pressure on a steel container. 3.1.6 correction, sediment & water CSW Corrects a volume, usually at standard temperature, for the effects of suspended sediment and water (S&W) 3.1.7 correction, temperature, liquid CTL Compensates for the effect of temperature on a liquid. 3.1.8 correction, temperature, shell CTSh The correction factor for the effect of the temperature, both ambient and liquid, on the shell of the tank. 3.1.9 custody transfer measurement The measurements specific to a change in ownership and/or a change in responsibility for commodities. 3.1.10 DOT filling limit The minimum outage (vapor) volume required at statutory temperature, expressed as percentage of the total capacity of a tank car, required by DOT regulations (49 CFR 173.24b or 173.314 as of this printing). 3.1.11 funnel flow cars Tank cars that have a slight “V” shape to allow drainage. 3.1.12 general purpose tank car A non-pressure tank car designed and constructed under DOT regulations to transport liquids of relatively low volatility, such as asphalts, crude oils, fuel oils, solvents, specialty chemicals, etc. 3.1.13 gross observed volume GOV The total observe volume (TOV) of all petroleum or chemical liquids and sediment and water (S&W), excluding free water (FW), at observed temperature and pressure. 3.1.14 gross standard volume GSV The gross volume (GV) or gross observed volume (GOV) corrected to base temperature and pressure conditions. SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 3 3.1.15 heel The amount of product liquid and vapor present in a car before loading, or left in a car after unloading. 3.1.16 innage gauge The depth of liquid in a tank measured from the datum plate or tank bottom up to the surface of the liquid. 3.1.17 interior lining The surface coating applied to the interior of a tank car shell to prevent the contents from contacting the metal shell. 3.1.18 light weight tare The number painted on the sides of a [rail] tank car near its ends indicating the empty weight of the car. 3.1.19 liquefied gas A generic term referring to gases (such as ammonia, butylene, propylene, ethylene oxide, propylene oxide, etc.) stored and transported under pressure as a liquid. 3.1.20 liquefied petroleum gas LPG A hydrocarbon gas maintained in a liquid state. 3.1.21 liquid equivalent The quantity of liquid product contained as a gas in the vapor space above the liquid surface in a pressure container. 3.1.22 [weight] load limit The number on the sides of a rail tank car near its ends indicating the maximum legal weight of its contents. 3.1.23 magnetic float gauge A gauging device employing a floating magnet to permit measuring the liquid level in a container without opening the container to the atmosphere. 3.1.24 manway [nozzle] A cylindrical opening on the top of a [rail] tank car with a hatch for [personnel] access to the interior of the car. 3.1.25 manway nozzle height The vertical distance downward from the top lip of the nozzle (hatch open) to the inside top of the car shell, measured at the point on the rim closest to the center of the car. 4 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES 3.1.26 maximum fraction of liquid allowed MFLA The DOT filling limit, expressed as a decimal fraction, of the maximum volume of liquid allowed at statutory temperature. 3.1.27 maximum fraction of liquid loaded MFLL The volume of liquid actually loaded, expressed as a decimal fraction, at statutory temperature. 3.1.28 net standard volume NSV The gross standard volume (GSV) corrected to exclude non-merchantable components such as sediment and water (S&W). 3.1.29 NIST traceable A property of a measurement result whereby the result can be traced back to NIST by an unbroken chain of calibrations. 3.1.30 open loading / unloading For a general purpose tank car, the manway hatch remains open during loading/unloading, thus sampling and temperature and level measurements generally take place through the open manway. 3.1.31 [outage] gauge The measure of the liquid level in a tank, vertically from the [rail] tank car’s reference gauge point. 3.1.32 pressure tank car A closed tank car (no direct access to the interior of the car for measurement) designed and constructed under DOT regulations to transport high volatility products and liquefied compressed gases under pressure (typically 100-200 psig for LPG). 3.1.33 reference conditions The specific physical conditions for comparison of measurements taken at other physical conditions. 3.1.34 reference pressure The specific pressure for comparison of measurements taken at other pressures. 3.1.35 reference temperature standard temperature The specific temperature for comparison of measurements taken at other temperatures. 3.1.36 slip tube A graduated hollow rod used for measuring liquid outages in a pressure car. SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 5 3.1.37 statutory outage The percentage of the total liquid capacity of a tank car reserved for vapor space set by DOT 49 CFR 173.24b or 173.314 (as of this printing) for calculating loading target outage. 3.1.38 statutory temperature Tstat The temperature set by DOT 49 CFR 173.24b or 173.314 (as of this printing) for calculating loading target outage. 3.1.39 table max volume Vtblmax The greatest volume in a capacity table. 3.1.40 tank car capacity stenciled capacity stenciled volume Vs The number painted onto the ends of a [rail] tank car indicating its shell-full capacity. 3.1.41 tank capacity table Table showing the liquid volume capacities, on an innage or ullage (outage) basis, or the corresponding vapor space capacities, in a tank, tank car or vessel compartment, at various liquid levels, which are measured at the reference gauge point: from the datum up to the liquid surface level for innage gauges; or, from the reference gauge point down to the liquid surface level for ullage (outage) gauges. 3.1.42 tank car reference gauge point The point at the top edge of the manway opening along the longitudinal centerline closest to the midpoint of the tank car from which all liquid level measurements shall be taken. 3.1.43 tank car shell-full The liquid volume at the transition point where air or vapor first becomes entrapped in a location that is not in direct communication with the manway. 3.1.44 tank gauging A process for determining the height of liquid in a tank or container by measuring the vertical distance from the bottom or fixed datum up to the liquid surface level when using innage gauging, or by measuring the vertical distance from the reference gauge point down to the liquid surface level when using ullage (outage) gauging. 3.1.45 thermometer well for tank cars thermowell A metal tube, sealed at the bottom, which extends into tank cars requiring closed loading / unloading. 6 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES 3.1.46 total observed volume table TOVtbl The total measured volume of all petroleum liquids, sediment and water (S&W), and free water (FW) at observed temperature and pressure. 3.1.47 two percent marker 2% marker A metal liquid level indicator installed in tank cars, usually at the level where the car is filled to 98% of capacity, but occasionally at other levels. 3.1.48 vapor space The volume above the liquid surface. 3.2 Acronyms and Abbreviations For the purposes of this document, the following acronyms and abbreviations apply. CPL correction, pressure, liquid CPS correction, pressure, shell CSW correction, sediment & water CTAF capacity table adjustment factor CTL correction, temperature, liquid CTSh correction, temperature, shell DOT Department of Transportation FW free water GOV gross observed volume GOVtbl table gross observed volume GSV gross standard volume GV gross volume LPG liquefied petroleum gas MFLA maximum fraction of liquid allowed MFLL maximum fraction of liquid loaded NSV net standard volume NIST National Institute of Standards and Technology, formerly the National Bureau of Standards (NBS) S&W suspended sediment and water Vs: stenciled volume Vtblmax the greatest volume in a capacity table SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 7 4. Required Data Acquisition 4.1 General As with any calculation, the results are only as reliable as the data entered. It is essential that the tank car information and measurements be NIST traceable and as accurate as possible. Temperature and level measurement equipment and procedures should also be reviewed for compliance with API custody transfer standards (see API MPMS Chapter 3.2). 4.2 Tank Car Data 4.2.1 General Experience has shown that inaccurate tank car information is often used (sometimes for many years). Data obtained off the tank car should be verified to be identical to that in any industry or company data bases used. 4.2.2 Light Weight Obtained from the side of the car or industry database. 4.2.3 Load Limit Obtained from the side of the car or industry database. 4.2.4 Stenciled Volume Obtained from either end of the car or industry database. This is the amount of water in gallons and liters that the car contains at the shell-full point. For funnel flow cars, the shell-full point is at the center of the car (there will be air pockets on both sides where the liquid cannot reach), but pressure cars, which are horizontal cylinders, will include the manway volume. The stenciled volume is determined directly by metering water into the car or indirectly by strapping the car. If an interior lining is removed, replaced, or added at a later date, the stenciled volume should be redetermined. 4.2.5 Tank Car Capacity Table Obtained from the tank car owner, manufacturer, or industry database. Care must be taken to ensure that the correct capacity table is used (it is not uncommon for individual locations to have outdated or wrong tables). A car’s useful statutory life is 50 years, so there may be several different versions in use for the same car. Furthermore, as of this writing there is no industry standard format, and a manufacturer may have changed their format several times over the years. Thus, it is generally impossible to determine by observation when the table was issued and therefore whether it is more current than another table. If in doubt, contact the owner of the tank car. The table may be based on either innage or outage gauges and may indicate either liquid or vapor space gallons. These are referred to as Outage Liquid, Outage Vapor, Innage Liquid, or Innage Vapor tables. Care must also be taken to ensure that the capacity table is used properly. There may also be no indication as to what type of table it is, and thus the table may be used incorrectly. The manufacturers have developed these tables using the inside top of the shell at the center of the car, the rail car shell-full point, as a reference point. Distance increments (normally ¼ in.) are then listed from the reference point down to the liquid surface (outage) or from the bottom of the car directly below the reference point to the liquid surface (innage), and the corresponding liquid or vapor volume is calculated and inserted in the table. Using an Innage Liquid table as an Outage Vapor table (or vice versa) for a funnel flow car will introduce an error on the order of several hundred gallons as the tables are not symmetrical. Experience has shown that table misinterpretation is the most common cause of calculation error. The same capacity table may be assigned to hundreds of dimensionally similar, but not identical, tank cars. Tank cars cannot be constructed to exactly match the table, but the table may be mathematically sized to each tank car by applying the capacity table adjustment factor (CTAF), calculated by dividing the stenciled volume (Vs) by the table max volume (Vtblmax), to every gauge volume coming out of or calculated volume going into the table. 4.2.6 Manway Nozzle Height Liquid levels are most commonly determined via outage measurements, especially if the product is hot and solidifies at ambient temperature. In practice, it is difficult if not impossible to take an outage measurement from 8 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES the inside top of shell reference point unless a proper measuring device (commercially available) is at hand. Absent such a device, it is much easier to measure from the top of the open manway nozzle nearest the center point of the car. This requires measurement of the offset between the rail car reference gauge point and the shellfull point, which in most case will be the manway nozzle height. This offset must be measured with the proper instrument (also commercially available) for maximum accuracy. Absent a proper device, numerous “work arounds” (usually containing systematic errors) have been developed in the field to compensate. A manway may be ground flush with the shell at the weld, however many manways penetrate the tank car’s shell by varying depths, as much as 3 inches. This penetration is not part of the manway’s height and should not be included. Some tank cars may already have their original tables changed to incorporate the manway height at the request of the car's owner. Pressure cars have a secured hatch that usually contains thermowells, magnetic float gauges, and loading valves permanently installed. The manway height is incorporated in the magnetic float gauge rod. 4.3 Product Data 4.3.1 Traceability All measurements must be traceable to NIST reference standards. A primary standard (1st generation standard) may be purchased from the NIST. Due to their expense, these are normally purchased by manufacturers who use them to verify the accuracy of the standards that they make (2nd generation). These less expensive standards are purchased by the industry for use as field standards, which are then used to verify the accuracy of the actual equipment used in the field (3rd generation). This 3rd generation field equipment may not be used to verify other field equipment. The verification of the field equipment must be performed (and documented) periodically as required by the applicable API standards. 4.3.2 Actual Liquid Temperature Once the car is loaded, a temperature must be taken from the center of the product at the time of gauging (after motion ceases). For very hot products like asphalt, sulfur, etc., the temperature and gauge should be taken as soon as possible, as the product will quickly stratify, forming a nonlinear temperature gradient. For a pressure car, sampling and measurement must be accomplished via permanently installed thermowell. The thermowell may be filled with a heat-transferring liquid of low volatility and freeze point (usually ethylene glycol) which transmits the temperature of the tank car contents to a thermometer or thermoprobe lowered into the thermowell. 4.3.3 Liquid CTL Table An accurate CTL table or implementation procedure must be available to properly convert GOV to GSV and NSV (or the reverse). It may be an industry accepted version developed by the API or ASTM or a private version developed directly from density data, and will have a value of 1.00000 at reference temperature. Occasionally, a product’s composition may fluctuate (or have changed) enough to justify the preparation of a new table. It is critical that a product be properly sampled and stored to ensure that a sample representative of normal production be available for density measurement at different temperatures. These densities can then be converted to a CTL table via methods described elsewhere (API MPMS Chapter 11.1, for example). Multiplying a liquid’s volume by a CTL computes its volume at reference temperature. 4.3.4 Liquid Density at Reference Temperature The liquid’s density may be directly measured at ambient temperature and corrected to reference temperature. It is commonly measured in grams per cubic centimeter (g/cc), kilograms per cubic meter (kg/m3), API gravity, or specific gravity and converted to pounds per gallon (lb/gal) in vacuo. To convert density to weight in air, API MPMS Chapter 11.5 should be used. 4.3.5 Actual Liquid Pressure If a car is loaded with a liquefied gas, the car’s pressure has to be taken and recorded. 4.3.6 Liquid CPL Table Liquefied gases are kept at or above their equilibrium vapor pressure and require an accurate CPL table or implementation procedure to properly convert GOV to NSV. The table may be an industry accepted version developed by the API, ASTM, or GPA or a private version developed directly from density/pressure measurements. SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 9 4.3.7 Sediment & Water If a car is loaded with crude oil, sediment and water should be determined via API MPMS Chapter 10. 4.3.8 Liquid Gauge 4.3.8.1 General Purpose Cars Once the car is loaded, a gauge must be taken at the reference gauge point. The reference gauge point is now defined (API MPMS Chapter 3.2) as being at the top edge of the manway opening at the longitudinal centerline of the tank car at the point on the manway circumference closest to the midpoint of the tank car. Most outage capacity tables are referenced to the shell-full point, so an outage gauge whose zero point is at the manway rim will need the manway height subtracted before entry into the capacity table. An outage measurement from an instrument with zero point at the shell-full point needs no such correction. Liquid level measurement should be made at the same time an actual liquid temperature is recorded. The contents must be allowed to cease motion (some products may take as much as 15 minutes) before the gauge is taken, as any wave motion will result in an artificially low outage (or high innage) and thus the volume of liquid calculated will be overstated. The gauge may be taken: (a) as an outage gauge from the top of the manway nozzle, (b) as an outage gauge from the inside top of the shell, or (c) as an innage gauge. Two percent markers are not accurate or traceable measurement devices, and are not recommended for custody transfer measurements. If applicable, free water (FW) should also be gauged. 4.3.8.2 Pressure Cars Gauges are taken from an installed magnetic float gauge (slip tubes have been phased out due to emission concerns). These are outage gauges normally referenced to the top inside of the shell, so manway heights are not required. The device consists of a spherical toroidal float with interior magnets that moves up and down around a hollow tube (sealed to the outside) as the car’s liquid level changes. Another magnet is attached to the bottom of a graduated gauge rod located in the hollow tube and accessible from the outside. When the gauge rod is manually pulled up until the two magnets link, the liquid level’s outage may be read off the rod. The gauge will only indicate outages for the upper third of the car and cannot indicate the presence of liquid below it. Magnetic float gauge tubes should not contain so much antifreeze or similar type liquid (to prevent condensed water from freezing) as to wet the visible portion of the rod. If a tube is filled with such liquid, its buoyant force on the rod will make the gauge float higher and overstate the product level. The contents must be allowed to cease motion (some products may take as much as 15 minutes) before the gauge is taken, as any wave motion will result in an artificially low outage (or high innage) and thus the volume of liquid calculated will be overstated. An outage offset may have to be calculated if the gauge’s reference relative density (specific gravity) is different from that of the product to be measured, or if the temperature of the liquid differs substantially from reference temperature. A more dense liquid will cause the float to float higher and result in a smaller outage reading, thus indicating that there is more liquid in the car than is really there. A less dense liquid will have the opposite effect, the gauge indicating that there is less liquid than is really there. Temperature has a similar effect. Temperatures higher than reference temperature will make the liquid less dense, resulting in a larger outage as the float will float lower, so the gauge will understate the car’s contents. Temperatures less than reference temperature will have the opposite effect. The magnitude of the effect depends on the characteristics of the gauge and the magnitude of the change in relative density and temperature. Generally, calculations (see examples in Appendix D) show the gauge offset may vary from < 1/8 inch to > 3 inches, depending on specific gravity and temperature changes. Successful calculation of this effect requires knowledge of the gauge component specifications (volume of float, weight of float and rod assembly, reference relative density) which are available from the manufacturer. See Appendix D for the equations required and their derivations. 4.3.9 Tank Car Temperatures A volume correction may be made for tank car shell expansion or contraction if its temperature is high or low enough to have a significant effect. Use of this correction is optional; therefore the determination of what is 10 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES considered a “significant effect” is left to the user (Table B-1 shows a 0.1% volume increase at 114F and a 0.2% increase at 157F). For tank cars, shell temperature is equivalent to liquid temperature. When loading very hot material like asphalt (300 to 350°F) into an ambient tank car, it cannot be assumed that the shell temperature is the same as the liquid temperature. Measurements have shown that products with melting points higher than the ambient temperature will solidify and effectively insulate the shell from the bulk of the cargo. Furthermore, the product will form a nonlinear temperature gradient fairly quickly. (Measurement of a 55°F ambient asphalt car [unpublished data] one-half hour after loading at 307°F and showed a temperature of 304°F near the middle of the car, 283°F one foot lower, 183°F just above the solidified asphalt on the shell, and 140°F an inch or two into the “rind.”) Thus, a shell expansion correction should be made only when one can be sure of the shell temperature; normally this will only occur when there is no solidified material on the shell (Appendix B and Table B-1). Cars that have been steamed to melt the contents will also meet this criteria, and the temperature will be high enough to have a significant effect on the volume. 4.3.10 Tank Car Pressure A volume correction may be made for tank car shell expansion if its pressure is high enough to have a significant effect (Annex C). 5 Actual Loaded Quantity Calculations 5.1 General Once a tank car is loaded and the actual liquid gauge and loading temperature have been taken as indicated in Sections 4.3.8 and 4.3.9, calculation of the net standard volume and liquid weight is relatively straightforward. The general equations for product gross standard volume (GSV), net standard volume (NSV), and product weight (W) are: GSV = (TOVtbl) (CTAF) (CTL) (CTS) (CPL) (CPS) (1) NSV = (GSV) (CSW) = (TOVtbl) (CTAF) (CTL) (CTS) (CPL) (CPS) (CSW) (2) W = (NSV) (dref) (3) 5.2 General Purpose Cars To calculate product NSV, look up the gauge in the tank capacity table, interpolating if necessary, to find the corresponding table total observed volume (TOVtbl). If free water is present, the volume of the free water (FW) corresponding to its depth should be subtracted from the total observed volume to obtain the product table gross observed volume (GOVtbl). GOVtbl = TOVtbl - FW (4) This is then substituted for TOVtbl in equations (1) and (2) to obtain GSV, NSV, and W for just the product present. Multiply this volume first by the capacity table adjustment factor (CTAF = Vs / Vtblmax), then by the CTL at loading temperature and the correction for the temperature of the steel shell (CTS) if desired (although CTS is optional, it should not be used here unless it has been used in the Target calculations (Appendix A)). As general purpose cars are not under pressure, CPL and CPS both equal 1.00000. Finally, multiply by the correction for sediment and water (CSW), if applicable. As discussed in API MPMS Chapter 12.1.1 (refer to API MPMS Chapter 10 for S&W%): CSW = (100 – S&W%) / 100 For most refined products, CSW = 1 (no suspended sediment and water) and thus GSV = NSV. Equation 2 thus becomes Equation 5. NSV =(GOVtbl) (CTAF) (CTL) (CTS) (1) (1) (1) = (GOVtbl) (CTAF) (CTL) (CTS) (5) 5.3 Pressure Cars To calculate product NSV, look up the gauge in the tank car capacity table, interpolating if necessary, to find the corresponding table gross observed volume (TOVtbl). Free water should not be present in a liquefied gas, and in SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 11 any case is not measureable in a pressure car. Multiply this volume first by the capacity table adjustment factor (CTAF = Vs / Vtblmax), then by the CTL at loading temperature and the correction for the temperature of the steel shell (CTS) if desired (although CTS is optional, it should not be used here unless it has been used in the Target calculations (Appendix A)). As a rule, the final loaded pressure will be at equilibrium vapor pressure for nearly pure product and CPL will equal 1.00000. If the pressure is higher than equilibrium vapor pressure, lighter products or inert gases may be present (either inadvertently or by design) and CPL may be calculated for the pressure difference, but will probably have an insignificant effect. Multiply by the correction for pressure expansion of the steel shell (CPS), if desired (although CPS is optional, it should not be used here unless it has been used in the Target calculations (Appendix A)). Finally, multiply by the correction for sediment and water (CSW), if applicable. For most refined products, CSW = 1 and thus GSV = NSV. Equation 2 thus becomes Equation 6. NSV = (GOVtbl) (CTAF) (CTL) (CTS) (1) (CPS) (1) = (GOVtbl) (CTAF) (CTL) (CTS) (CPS) (6) 5.4 Vapor Space Heel Assuming no “noncompressible” or foreign gas has been introduced to offload product, liquefied gases and liquids of sufficiently high vapor pressure will also occupy the vapor phase above the liquid. While this may be insignificant when the vapor phase is a small percentage of the total volume of the car, it is a significant portion of the total product after the car has been emptied. It may be calculated (based on temperature, pressure, relative density, and composition) in liquid equivalent net gallons via GPA 8195 or any other acceptable procedure, or fixed by mutual agreement. For a loaded car, this can be added to the net liquid gallons; for an unloaded car, this may be subtracted from the net liquid gallons as a vapor heel. 5.5 Overload check A car may not be overloaded by either weight or volume. The actual loaded weight should be calculated via Equation 3 with the assumption that any free water and S&W are product, and compared to the Load Limit to assure the car is not overloaded by weight. The actual loaded volume should be calculated at the statutory temperature to make sure the outage volume (vapor space left for liquid expansion) is not less than the statutory outage volume. This is done by calculating net standard volume (Equation 6) of the total liquid in the car (use CTS and CPS only if used above) and then dividing by the CTLstat (use CTSstat and CPSstat only if CTS and CPS are used above) at statutory temperature to obtain the statutory liquid volume Vstat. Vstat = (GOVtbl) (CTAF) (CTL) (CTS) (CPS) (CTLstat) (CTSstat) (CPSstat) (7) The loaded volume at statutory temperature is then divided by the stenciled volume (Vs) to obtain the maximum fraction of liquid loaded (MFLL) at statutory temperature. This number should be equal to or less than the product’s statutory MFLA (see Appendix A). MFLL = Vstat Vs (8) The MFLL can also be expressed as the loaded vapor space percent at statutory temperature for comparison to the DOT filling limits. Vapor Space % = 100 – MFLL * 100 (9) 6 Rounding 6.1 Data Level The number of decimal places used is influenced by the source of the data. If a tank car’s capacity tables are in whole gallons, then all subsequent gallon values should be recorded accordingly. In those cases where there are no other limiting factors, the operator should be guided by Table 1. 12 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES 6.2 Rounding of Numbers Calculations shall be performed with no intermediate rounding. When a calculation result is to be rounded to a specific number of decimals, it shall always be rounded off in one step to the number of figures to be recorded, and not rounded in two or more successive steps. When the figure to the right of the last place to be retained is less than 5, the figure in the last place retained should be unchanged. Table 1 — Significant Digits Units Gallons Pounds Liters Kilograms API Gravity @ 60°F Density pounds per gallon Relative density Temperature °F Temperature °C CTAF CTL CTS CPL CPS No. of Decimals xxxxx.xx xxx.0 xxx.0 xxx.0 xxx.x xx.xxx x.xxxx xxx.x xxx.x5 x.xxxxxx x.xxxxx x.xxxxx x.xxxxx x.xxxxx SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 13 Annex A (normative) Loading Target Quantity Calculations A.1 General In order to maximize delivered quantities and minimize shipping costs, most tank cars are loaded to the maximum amount allowable. DOT regulations, railroad regulations, manufacturing standards, and company policies govern the maximum amount of material that a tank car may contain. DOT 49 CFR 179.13 (as of this printing) stipulates that no tank car used for transportation of hazardous materials and its contents may weigh more than 263,000 pounds gross weight (or 286,000 lbs with special routing) or exceed 34,500 gallons capacity; however, individual tank car construction specifications may require a smaller total weight (for example, the total weight may be limited by the size of the truck assembly). A.2 Required Data — Target Liquid Temperature A.2.1 General In addition to the requirements stated above, the following information is necessary to properly calculate target quantities: A.2.2 Cool Loading (Below Statutory Loading Temperature) DOT 49 CFR 173.24b stipulates (as of this printing) that for most hazardous materials a minimum expansion volume (vapor space) equivalent to 1% at the statutory temperature of 115°F (for uninsulated cars), 110°F (for thermally protected cars), or 105°F (for insulated cars) must be maintained. For materials deemed poisonous by inhalation (ethylene oxide, ammonia, chlorine, phosgene, allyl alcohol, bromine, hydrogen fluoride, etc.), the vapor space must be 5%. During the winter (November 1 through March 31), the statutory temperatures of 100°F, 90°F, and 85°F may be used for certain liquefied petroleum gases (LPGs, butanes, propylene, etc.) and ammonia (DOT 49 CFR 173.314). Tank cars loaded to winter limits must be shipped directly and not be stored in transit. They must be unloaded as soon as possible after March. Liquids expand as their temperature increases and contract as it decreases. Since the liquids will rarely be loaded at either 115°F, 110°F, or 105°F, the volume actually loaded at loading temperature must expand to no more than 99% (or 95% for materials deemed poisonous by inhalation) of the tank car’s capacity at the applicable statutory temperature. Thus, the lower the loading temperature the smaller the volume that can be legally loaded. Accurate liquid loading temperatures are therefore required both to optimize the amount loaded and avoid overloading. If the actual loading temperature is lower than that used for target calculations, the calculated target volume will be too high and the car will be overloaded. Conversely, if the actual loading temperature is higher than that used for target calculations, the calculated target volume will be too low and the car will be underloaded. Accurate loading temperatures are rarely obtained from the storage tank or loading line, especially when there is a large difference between liquid temperature and ambient temperature. The most accurate loading temperature can be obtained by measuring the liquid in the car during loading while the car is about two-thirds full. The final loading target outage can then be determined from this temperature. A.2.3 Hot Loading (above statutory loading temperature) There are currently no DOT regulations regarding vapor space volumes for liquids loaded at temperatures above the statutory loading temperatures. Since these liquids will cool (and may solidify) during transport, they will normally be reheated via the tank car’s steam coils. This may cause the liquid to be heated to a higher temperature than that at which it was loaded, thus expanding to a volume greater than that loaded and possibly overflowing the manway. In such cases a vapor space at loading temperature equivalent to or larger than the DOT outage limits (2% is common for most materials, 5% is normally adequate for materials poisonous by inhalation) is recommended and an accurate loading temperature is not required for target outage calculation. A.3 General Purpose Cars A.3.1 To avoid overloading a car by weight, the weight of the maximum amount of liquid allowed by volume must be determined. To calculate this amount, multiply the stenciled capacity by the DOT maximum fraction of 14 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES liquid allowed (MFLA, 0.99 in most cases), correct the liquid volume and the tank car shell volume (optional) from the statutory temperature to reference temperature, and multiply by the liquid’s density at reference temperature in pounds per gallon: Wma = Vs (MFLA) (CTLstat) (CTSstat)* (dref) Wma = weight maximum allowed by volume, pounds, Vs = stenciled volume, gallons, (A.1) where MFLA = DOT maximum fraction of liquid allowed (0.99 or 0.95, or 0.98 for hot loading), CTLstat = CTL at statutory temperature, CTSstat* = CTS at statutory temperature, dref = density at reference temperature. * = optional A.3.2 If Wma exceeds the car’s Load Limit, the Load Limit will determine the maximum volume of liquid the car can contain. To calculate this, divide the Load Limit by dref to find the reference volume. Next, divide the reference volume by the CTL and CTS (optional) at loading temperature to find the volume at loading temperature. This volume is then divided by the capacity table adjustment factor and that result is entered into the car’s capacity table to find the corresponding gauge. If there is no volume match, the next smaller liquid volume in the table is chosen. One may wish to interpolate volumes and their gauges to the nearest 1/8 inch GOV = Wll (dref) (CTL) (CTS)* (CTAF) (A.2) where GOV = volume to be looked up in capacity table, Wll = Load Limit weight, CTL = CTL at load temperature, CTS* = CTS at load temperature, CTAF = Capacity Table Adjustment Factor (stenciled volume divided by the car’s maximum capacity table volume). * = optional A.3.3 If Wma does not exceed the car’s Load Limit, the statutory outages apply (for cool loading). To calculate this, multiply the stenciled volume by the MFLA, correct the volume to 60°F by multiplying by the CTL and CTS (optional) for the statutory temperature, divide by the CTL and CTS (optional) at loading temperature, divide by the capacity table adjustment factor, and look up the corresponding (or next smaller) liquid volume in the capacity table. GOV = Vs (MFLA) (CTLstat) (CTSstat)* (CTL) (CTAF) (CTS)* = Vs (MFLA) (CTLstat) (CTSstat)* (CTL) (Vs/Vtblmax) (CTS)* = Vtblmax (MFLA) (CTLstat) (CTSstat)* (CTL) (CTS)* * = optional (A.3) SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 15 A.3.4 If the car is being loaded hot (above the statutory temperature) and Wma does not exceed the car’s Load Limit, multiply the stenciled volume by the MFLA of 0.98 (0.95 for materials deemed poisonous by inhalation), divide by the capacity table adjustment factor, and look up the gauge in the table as above. GOV = Vs (0.98) CTAF (A.4) Weight overload checks and corresponding allowable outages are performed as above, except using CTL at loading temperature in place of CTLstat to solve for Wma. A.4 Pressure Cars To avoid overloading a pressure car, the same procedures outlined above should be followed, with the addition of CPS (optional) as shown below. If the pressure is higher than equilibrium vapor pressure, lighter products or inert gases may be present and CPL may be calculated for the pressure difference, but will probably have an insignificant effect (at or close to 1.00000). Pressure cars have a substantially greater light weight compared to general purpose cars (on the order of 110,000 pounds versus about 76,000 pounds). If a pressure car is used for normal liquids (resins that need a nitrogen cap, for example), the weight limitation will apply if the density at loading temperature is above approximately 5.0 lb/gal. For liquefied gases, the statutory outages will apply as above. A.4.1 To avoid overloading a car by weight, the weight of the maximum amount of liquid allowed by volume must be determined. Wma = Vs (MFLA) (CTLstat) (CPLstat) (CTSstat)* (CPSstat)* (dref) Wma = weight maximum allowed by volume, pounds, Vs = stenciled volume, gallons, MFLA = DOT maximum fraction of liquid allowed (0.99 or 0.95, or 0.98 for hot loading), CTLstat = CTL at statutory temperature, (A.5) where = CPLstat CPL at normal final loaded pressure, CTSstat = CTS at statutory temperature, CPSstat = CPS at statutory temperature, dref = density at reference temperature. * = optional A.4.2 If Wma exceeds the car’s Load Limit, the Load Limit will determine the maximum volume of liquid the car can contain. GOV = Wll (dref) (CTL) (CPL) (CTS)* (CPS)* (CTAF) (A.6) where GOV = volume to be looked up in capacity table, Wll = Load Limit weight, CTL = CTL at load temperature, CPL = CPL at normal final loaded pressure, CTS = CTS at load temperature, CPS = CPS at normal final loaded pressure, CTAF = Capacity Table Adjustment Factor (stenciled volume divided by the car’s maximum capacity table volume). 16 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES * = optional A4.3. If Wma does not exceed the car’s Load Limit, the statutory outages apply (for cool loading). GOV = Vs (MFLA) (CTLstat) (CPLstat) (CTSstat)* (CPSstat)* (CTL) (CTAF) (CPL) (CTS)* (CPS)* = Vs (MFLA) (CTLstat) (CPLstat) (CTSstat)* (CPSstat)* (CTL) (Vs/Vtblmax) (CPL) (CTS)* (CPS)* = Vtblmax (MFLA) (CTLstat) (CPLstat) (CTSstat)* (CPSstat)* (CTL) (CPL) (CTS)* (CPS)* (A.7) * = optional Refer to Annex C for CPS calculation. Typically only loading pressure will be available, so pressure at statutory temperature must be calculated before CPSstat can be determined. As pressure is directly proportional to temperature in degrees Kelvin at constant volume, Pstat = (Pload) ((Tstat – 32)*5/9 + 273.16) / ((Tload – 32)*5/9 + 273.16) where: Pstat = pressure at statutory temperature Pload = pressure loaded temperature Tstat = statutory temp, °F Tload = loaded temp, °F SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 17 Annex B (informative) Calculation of Tank Car Shell Expansion / Contraction with Temperature The equation for the expansion of a solid rod or hollow cylinder is derived in the following manner: = linear coefficient of expansion, V = volume of cylinder, V ' = expanded volume after heating, r = radius of cylinder, r = change in radius upon heating, l = length of cylinder, l = change in length of cylinder upon heating, T = change in temperature. = 6.2 10-6 per °F for mild carbon steel, = 9.6 10-6 per °F for 304 stainless steel, = 8.83 10-6per °F for 316 stainless steel. r = * r * T l = * l * T V = * r2 * l V ' = (r + r)2 (l + l) = (r2 + 2rr + r2) (l + l) V ' = (lr2 + 2lrr + lr2 + r2l + 2rrl + r2l) V ' = (lr2 + 2lrrT + l2r2T2 + r2lT + 2r2rlT2 + 3r2lT3) V ' = V + 2VT + V2T2 + VT + 2V2T2 +V3T3 V ' = V + 3VT + 3V2T2 + V3T3 V' = 1 + 3T + 32T2 + 3T3 V V' = (1 + T)3 V CTS = B-1 V' V This is the same equation derived for a cube, rectangular block or sphere truncated to the first two terms. The third term is small and the last term is insignificant (6.64 10-6 and 3.3 10-9, respectively, at 300°F for carbon steel). The equation produces Table B-1 (using the first three terms). Table B-1 — Shell Temperature Tank Car Volume Correction Factors Temp CTS Temp CTS Temp CTS Temp CTS Temp CTS Temp CTS Temp CTS Temp CTS 18 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES 0.99888 0.99890 0.99892 0.99894 0.99896 0.99898 0.99900 0.99901 0.99903 0.99905 0.99907 0.99909 0.99911 0.99913 0.99914 0.99916 0.99918 0.99920 0.99922 0.99924 0.99926 0.99927 0.99929 0.99931 0.99933 0.99935 0.99937 0.99939 0.99940 0.99942 0.99944 0.99946 0.99948 0.99950 0.99952 0.99954 0.99955 0.99957 0.99959 0.99961 0.99963 0.99965 0.99967 0.99968 0.99970 0.99972 0.99974 0.99976 0.99978 0.99980 0.99981 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 0.99983 0.99985 0.99987 0.99989 0.99991 0.99993 0.99994 0.99996 0.99998 1.00000 1.00002 1.00004 1.00006 1.00007 1.00009 1.00011 1.00013 1.00015 1.00017 1.00019 1.00020 1.00022 1.00024 1.00026 1.00028 1.00030 1.00032 1.00033 1.00035 1.00037 1.00039 1.00041 1.00043 1.00045 1.00047 1.00048 1.00050 1.00052 1.00054 1.00056 1.00058 1.00060 1.00061 1.00063 1.00065 1.00067 1.00069 1.00071 1.00073 1.00074 1.00076 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 1.00078 1.00080 1.00082 1.00084 1.00086 1.00087 1.00089 1.00091 1.00093 1.00095 1.00097 1.00099 1.00100 1.00102 1.00104 1.00106 1.00108 1.00110 1.00112 1.00114 1.00115 1.00117 1.00119 1.00121 1.00123 1.00125 1.00127 1.00128 1.00130 1.00132 1.00134 1.00136 1.00138 1.00140 1.00141 1.00143 1.00145 1.00147 1.00149 1.00151 1.00153 1.00154 1.00156 1.00158 1.00160 1.00162 1.00164 1.00166 1.00167 1.00169 1.00171 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 1.00173 1.00175 1.00177 1.00179 1.00181 1.00182 1.00184 1.00186 1.00188 1.00190 1.00192 1.00194 1.00195 1.00197 1.00199 1.00201 1.00203 1.00205 1.00207 1.00208 1.00210 1.00212 1.00214 1.00216 1.00218 1.00220 1.00222 1.00223 1.00225 1.00227 1.00229 1.00231 1.00233 1.00235 1.00236 1.00238 1.00240 1.00242 1.00244 1.00246 1.00248 1.00249 1.00251 1.00253 1.00255 1.00257 1.00259 1.00261 1.00262 1.00264 1.00266 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 1.00268 1.00270 1.00272 1.00274 1.00276 1.00277 1.00279 1.00281 1.00283 1.00285 1.00287 1.00289 1.00290 1.00292 1.00294 1.00296 1.00298 1.00300 1.00302 1.00303 1.00305 1.00307 1.00309 1.00311 1.00313 1.00315 1.00317 1.00318 1.00320 1.00322 1.00324 1.00326 1.00328 1.00330 1.00331 1.00333 1.00335 1.00337 1.00339 1.00341 1.00343 1.00344 1.00346 1.00348 1.00350 1.00352 1.00354 1.00356 1.00358 1.00359 1.00361 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 301 302 303 304 305 1.00363 1.00365 1.00367 1.00369 1.00371 1.00372 1.00374 1.00376 1.00378 1.00380 1.00382 1.00384 1.00386 1.00387 1.00389 1.00391 1.00393 1.00395 1.00397 1.00399 1.00400 1.00402 1.00404 1.00406 1.00408 1.00410 1.00412 1.00413 1.00415 1.00417 1.00419 1.00421 1.00423 1.00425 1.00427 1.00428 1.00430 1.00432 1.00434 1.00436 1.00438 1.00440 1.00441 1.00443 1.00445 1.00447 1.00449 1.00451 1.00453 1.00455 1.00456 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340 341 342 343 344 345 346 347 348 349 350 351 352 353 354 355 356 1.00458 1.00460 1.00462 1.00464 1.00466 1.00468 1.00469 1.00471 1.00473 1.00475 1.00477 1.00479 1.00481 1.00483 1.00484 1.00486 1.00488 1.00490 1.00492 1.00494 1.00496 1.00497 1.00499 1.00501 1.00503 1.00505 1.00507 1.00509 1.00511 1.00512 1.00514 1.00516 1.00518 1.00520 1.00522 1.00524 1.00525 1.00527 1.00529 1.00531 1.00533 1.00535 1.00537 1.00539 1.00540 1.00542 1.00544 1.00546 1.00548 1.00550 1.00552 357 358 359 360 361 362 363 364 365 366 367 368 369 370 371 372 373 374 375 376 377 378 379 380 381 382 383 384 385 386 387 388 389 390 391 392 393 394 395 396 397 398 399 400 1.00553 1.00555 1.00557 1.00559 1.00561 1.00563 1.00565 1.00567 1.00568 1.00570 1.00572 1.00574 1.00576 1.00578 1.00580 1.00581 1.00583 1.00585 1.00587 1.00589 1.00591 1.00593 1.00595 1.00596 1.00598 1.00600 1.00602 1.00604 1.00606 1.00608 1.00609 1.00611 1.00613 1.00615 1.00617 1.00619 1.00621 1.00623 1.00624 1.00626 1.00628 1.00630 1.00632 1.00634 SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 19 Annex C (informative) Calculation of Tank Car Shell Expansion with Pressure The expansion due to pressure is calculated in the same manner as for meter provers (API MPMS Chapter 12.2). CPS = 1 + (P D) / (E t) C-1 where CPS = Correction factor of pressure on steel, P = tank car internal pressure, psig, D = internal diameter of car = 120 inches, t = thickness of tank car shell = 11/16 inch, E = modulus of elasticity = 30,000,000 psig (for mild steel), = 28,000,000 psig (for 304 stainless steel), = 29,000,000 psig (for 316 stainless steel). For a typical pressure car with the values for D, t, and E given above, Table C-1 may be generated. Table C-1 — Pressure Expansion Table for a Typical (D = 120 inches, t = 11/16 inch, mild steel) Pressure Car P CPS P CPS P CPS P CPS 0 1.00000 80 1.00047 155 1.00090 230 1.00134 5 1.00003 85 1.00049 160 1.00093 235 1.00137 10 1.00006 90 1.00052 165 1.00096 240 1.00140 15 1.00009 95 1.00055 170 1.00099 245 1.00143 20 1.00012 100 1.00058 175 1.00102 250 1.00145 25 1.00015 105 1.00061 180 1.00105 255 1.00148 30 1.00017 110 1.00064 185 1.00108 260 1.00151 35 1.00020 115 1.00067 190 1.00111 265 1.00154 40 1.00023 120 1.00070 195 1.00113 270 1.00157 45 1.00026 125 1.00073 200 1.00116 275 1.00160 50 1.00029 130 1.00076 205 1.00119 280 1.00163 55 1.00032 135 1.00079 210 1.00122 285 1.00166 60 1.00035 140 1.00081 215 1.00125 290 1.00169 65 1.00038 145 1.00084 220 1.00128 295 1.00172 70 1.00041 150 1.00087 225 1.00131 300 1.00175 75 1.00044 20 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES Annex D (informative) Calculation of Magnetic Gauge Offsets D.1 General A correction for use with nonreference temperatures and / or with nonreference liquids can be made. The following procedure with examples is supplied for future use for incorporation into computer programs. Databases necessary for this procedure are not presently readily available. D.2 Determination of Magnetic Gauge Data Magnetic float gauges are designed for service with a specific car and a specific product (reference specific gravity). Normally the scale will be set to read zero at shell full (unless the customer requests a specific offset from shell full). The reference gravity cannot normally be ascertained visually; one must contact the manufacturer with the serial number off the gauge flange. As at some point the gauge rod may have been damaged and unofficially replaced, one should also supply rod data (diameter, length, distance from top of magnet to zero pt. of scale, and whether aluminum or fiberglass). Figure D.1 — Magnetic Float Gauge D.3 Derivation of Depth of Immersion Equation The float consists of a sphere cut by a cylindrical hole (see Figure D.1). The volume of the immersed portion of the float is the volume of the spherical segment minus the volume of the cylindrical hole in the segment and the spherical end cap cut by the cylindrical hole (very small volume). The following data, which includes dimensions and weights for a standard installation, are required: R = radius of spherical float (normally 3.75 inches), a = radius of cylindrical hole (normally 0.8345 inch), r = radius of floating segment, h = half height of the cylindrical hole, b = depth float is sitting in liquid, b' = depth of spherical end cap segment (not shown in Figure D.1), Vd = volume of float displaced, SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 21 Weight of float = 48.5 oz. Weight of magnet = 1.55 oz. Weight of 3/8 inch 74 inches aluminum rod = 5.45 oz. The general equation for the volume of a normal spherical segment (bowl) is (see paragraph D.4 below for derivation): V b b 2 3r 2 b 2 3R b 6 3 (D.1) The volume of the cylindrical segment cut out of the spherical segment is: V ” = a2 (b – b') The height of the end cap bowl (b') is related to the sphere’s radius (R) and the cylinder’s radius (a) as follows: b' = R – h R2 = h2 + a2 2 h = 7.5 1.687 R2 a2 2 2 2 14.0625 0.71149 3.6539 in. The height of the end cap is thus: b' = R – h = 7 .5 – 3.6539 = 0.096100 inch (not quite 3/32 inch) 2 And from equation D.1, the volume of end cap cut by cylinder is (substituting b' for b, and a for r): V 2 0.096100 0.096100 2 3 1.687 6 2 = 0.10787 inch3 The volume of the displacing segment equals the whole segment minus the interior cylindrical hole minus the end cap cut by the cylinder, or Vd = V ' – V '' – V '’' Vd = b 2 (3R – b) – a2(b – 0.0961) – (0.10787) 3 3 Vd = Rb2 – b3 – a2b + a2(0.0961) – (0.10787) Vd = 11.7810 b2 – 1.04720 b3 – 2.23522 b + 0.10618 (D.2) The volume of liquid displaced by the segment is also equal to the weight of the float, magnet, and rod assembly (in pounds) divided by the liquid’s density (ρ in pounds per gallon): weight 48.5 1.55 5.45oz Vd = density 16oz / lb density 3.46875 lb 3.46875 lb 231 in.3 lb / gal (lb / gal) gal 22 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES Vd = 801.28125 lb in.3 801.28125 in.3 (lb / gal) gal density @ 60 F (D.3) Density (pounds per gallon) at 60°F is derived from relative density (RD) by: density = RD * density of water at 60°F * 8.3454 It is then multiplied by 231 inch3 / gallon to obtain pounds per inch3, and that result is divided into the weight of the gauge assembly to obtain Vd. Equation (D.3) may then be inserted into equation (D.2) and solved for b. Thus we can guess a value for b and see how close the right part of equation (D.2) is to the right part of equation (D.3). If they are not close, we can increment b up or down by a small amount and try again. By repeating this process over and over until equation (D.2) is just under or equal to equation (D.3), we can find the true value of b specific to the product. This process can be easily accomplished by a macro in a spreadsheet. D.4 Gauge Offset Calculations D.4.1 General A gauge floating in a liquid with a lower relative density than the reference will sink deeper into the liquid, thus giving a larger outage gauge (there will appear to be less liquid in the car). A gauge floating in a liquid with a higher relative density than the reference will float higher, thus giving a smaller outage gauge (there will appear to be more liquid in the car). Temperature change produces the same effect. A temperature higher than the reference temperature (normally 60°F) will lower the fluid’s relative density; conversely, a lower temperature will raise the fluid’s relative density. D.4.2 Example 1: Relative Density Offset Calculate the gauge offset at 60°F due to the difference in relative density between the gauge’s reference relative density (0.5000) and a product of relative density 1.0000 (water). The depth of the submerged part of the float (b) must be calculated for both liquids; the difference is the offset. Step 1. Calculate the immersion depth in the reference liquid. The reference liquid’s relative density of 0.5000 is equivalent to a density of 4.1686 lb/gal. The volume displaced is thus: 55.5 16 192.21831 in.3 4 . 1686 231 Vd = 11.7810 b2 – 1.04720 b3 – 2.23522 b + 0.01618 (D.4) One can set up the spreadsheet so that rough guesses can be made for b. When the right half of equation (D.4) is close to 192.21831, start the iteration in increments of 0.001 inch (one thousandth of an inch) or less. For instance: increment b = 0.001 increment b = 0.0001 Vd = 192.21152 inches3 Vd = 192.21788 inches3 b = 6.3210 inches b = 6.3213 inches This 0.0003 inch difference is insignificant when one considers the required 1/8 inch accuracy (1/8 inch = 0.125 inch, 1/16 inch = 0.0625 inch, 1/32 inch = 0.0313 inch, 1/64 inch = 0.0156 inch, 1/128 inch = 0.00781 inch, etc.). This means that the float is immersed 6.321 inches in the reference liquid at 60°F. The gauge’s scale has been adjusted to read zero inches when the liquid level at 60°F is at the shell-full point and the float is immersed 6.321 inches. Step 2. Calculate the immersion depth in the non-reference liquid. Its relative density of 1.0000 is equivalent to a density of 8.3372 pounds / gallon. The volume displaced is thus: 55.5 16 96.10916 in.3 Vd 8 . 3372 231 =11.7810 b2 – 1.04720 b3 – 2.23522 b + 0.01618 SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 23 Solving for b as in the previous example: increment b = 0.001 increment b = 0.0001 Vd = 96.09288 inches3 Vd = 96.10544 inches3 b = 3.6050 inches b = 3.6053 inches Again, the 0.0003-inch difference is insignificant. This means that the float is immersed 3.605 inches in the nonreference liquid at 60°F. Step 3. For these two extreme examples (specific gravity 0.500 and 1.000), the float sets 6.321 – 3.605 = 2.716 inches (or roughly 1/32 inch less than 2 3/4 inches) higher in the water. Thus, the gauge indicates 2.716 inches more product in the car than is actually there. D.4.3 Example 2: Temperature Offset For A Reference Relative Density Of 0.5000 Calculate the gauge offset arising from using a float for service at non-reference temperatures. The depth of the submerged part of the float (b) must be calculated at reference temperature and operating temperature; the difference is the offset. Calculate the immersion depth of the reference liquid (relative density 0.5000, 4.1686 pounds / gallon) at various non-reference temperatures. The density of the liquid in equation (D.3) at a non-reference temperature is the density at reference temperature multiplied by the liquid’s CTL. CTLs are obtained from the appropriate API / ASTM table. The volume displaced at various temperatures is thus: 55.5 16 Vd VCF4.1686 231 192.21831 in.3 11.7810 b 2 1.04720 b 3 2.23522 b 0.01618 VCF For each temperature, obtain the CTL and calculate the volume displaced at that temperature, then solve for b as above. Temp (°F) CTL b (in.) Vd for b (in.3) 20 30 40 50 60 70 80 90 1.064 1.049 1.033 1.017 1.000 0.983 0.965 0.946 5.853 5.947 6.057 6.177 6.310 6.489 6.711 7.082 180.63879 183.21619 186.07703 188.99762 192.21152 195.53639 199.18006 203.18841 b@60°F – b 0.457 0.363 0.253 0.133 0.000 – 0.179 – 0.401 – 0.772 Offset 4 /8 in. /8 in. 2 /8 in. 1 /8 in. 0 in. – 1/8 in. – 3/8 in. – 6/8 in. 3 This float assembly sinks at 92°F. Note that the float is about 87% immersed at 60°F. The offset is added or subtracted, as indicated by its sign, from the observed gauge to obtain the true liquid level. D.4.4 Example 3: Temperature Offset For A Reference Relative Density Of 1.0000 Calculate the immersion depth for a petroleum product reference liquid (relative density 1.0000, 8.3372 lb/gal, 10 API) at a various non-reference temperatures. The density of the liquid in equation (D.3) at a non-reference temperature is the density at reference temperature multiplied by the liquid’s CTL. CTLs are obtained from API Table 6B. The volume displaced at various temperatures is thus: 55.5 16 Vd VCF8.3372 231 96.1092 in.3 VCF 11.7810 b 2 1.04720 b 3 2.23522 b 0.01618 24 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES For each temperature, obtain the CTL and calculate the volume displaced at that temperature, then solve for b as above. Temp (°F) CTL 20 60 200 1.01491 1.00000 0.94683 b (in.) Vd for b (in.3) 3.571 3.605 3.734 94.66961 96.09288 101.50039 b@60° F – b 0.034 0.000 – 0.129 Offset 1 /32 in. 0 in. – 1/8 in. Note that the float is roughly half immersed at 200°F and has sunk only 1/8 inch from its position at 60°F. These two extremes (Examples 2 and 3) show that the lower the relative density, the more effect temperature has. D.5 Derivation of Volume Segment or Bowl (Equation D.1) Strategy: Offset a sphere from the origin by its radius R and add up the volume of the small circular segments of thickness, dx within it from x = 0 to x = b: Figure D.2 — Derivation of a Spherical Volume Segment or Bowl V dv y 2 dx R 2 R x dx V V b b b 0 o o b o R 2 dx b 2 R x dx 2 o b xR 2 o R 2 x x 3 Rx 3 b 2 o b3 b3 V bR 2 R 2 b Rb 2 Rb 2 3 3 b 2 3R b 3 If the radius of the segment is r, R2 = (R – b)2 + r2 R2 = R2 – 2bR + b2 + r2 R b2 r 2 2b SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS Substituting into the volume equation above, V 2 b 2 r 2 b 3 b 3 2b V b 2 b 3r 2 6 25 26 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES Annex E (informative) Tank Car Reconciliation Custody transfer measurement of tank car cargos is usually performed both at loading and at discharge, however the methods of measurement at the locations will often vary. The most accurate method is direct static weighing at the rack before and after cargo transfer with a properly calibrated scale, but that is seldom encountered on either end of a movement. Coupled-in-motion scales located at some point between the loading and unloading racks are more often used, but this more complex method is subject to more sources of uncertainty (track condition, speed, car identification, etc.), and not all such scales are of custody transfer quality. Carrier scales are intended primarily for freight weight confirmation and do not meet custody transfer measurement standards. Most rack meters are not maintained to custody transfer standards but are instead used for controlling pumps. If a meter is used for custody transfer measurement, it should conform to API MPMS standards. Custody transfer quality manual gauging and temperature measurement, as described in this standard and API MPMS Chapt 3.2, can be as accurate as static scale measurement. Figure E-1 illustrates a review of twenty-two months of butane receipts. The seller billed off calculations from manual custody transfer measurements as described in this standard and the customer verified billing via a static scale, subtracting the car’s stenciled tare weight to determine total unloaded weight. The % Difference for each sale was calculated as follows: % Difference = (customer weight – billing weight) * 100 billing weight Note that differences of + 2% were common. Industry practice is to allow a + 0.50% difference, but Figure E-1 illustrates why reconciliation of large groups of cars is more productive than attempting to reconcile individual cars. Butene Static Scale - BOL Difference Average -0.20% 10.00% 8.00% % Difference 6.00% 4.00% 2.00% 0.00% 1 7 13 19 25 31 37 43 49 55 61 67 73 79 85 91 97 -2.00% -4.00% -6.00% -8.00% Figure E-1 The – 0.20% at first appears to be a 0.20% shortage to the customer. However, scale weights are in air, while calculated weights are in vacuo. The in air vs in vacuo difference for butane is – 0.20%, making the true average SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 27 difference 0.00%. Even a long term + 0.5% gain/loss, indicating a possible measurement bias, would not always initiate a measurement investigation, depending on the parties involved and the value of the product. The observed fluctuation is in part explained by the fact that the tare weights stenciled on the side of the cars is not always accurate. The tare weights are normally obtained when the car is manufactured. Over the life of the car equipment may be added or subtracted, but due to expense and logistical concerns, the cars are seldom reweighed. Figure E-2 is the result of measurement review where random cars were cleaned and weighed statically. Six out of nineteen cleaned cars (32%) weighed statically were over +500 lbs off their stenciled light weights (2,050, 700, -1,000, 700, -700, and -950 lbs). These errors are on the order of + 0.4-0.6% of the product weight of a fully loaded car (ignoring the first point). Thirty-two percent stenciled light weight error is unacceptable, but unfortunately the reality. There have been reports that differences of 3,000 lb. have been observed. Customers using stenciled light weights and who only order a few cars per year may very well believe they are being over-billed on individual cars. However, the average scale vs stenciled difference for those 19 cars was 34 lb. This illustrates how the differences average toward zero as more cars are considered. Actual Tare minus Stenciled Wt 2,500 2,000 1,500 lbs 1,000 500 0 0 2 4 6 8 10 12 14 16 18 20 -500 -1,000 -1,500 Figure E-2 If either party wishes to initiate a loss/gain review, several steps are recommended: a. Gather billing and receiving records for as long a period as possible, plot the percent difference as in Figure E-1, and calculate the overall average percent difference. b. Decide how much product value is at stake – an investigation may cost more than the amount of product in question. c. Visit each shipping and receiving location involved and ensure that their measurement practices follow API custody transfer measurement standards. d. If applicable, ensure that each end of the movement is using the same density and CTL tables and performing the same calculations. e. If necessary, observe the loading of one or more cars, then personally manually gauge and temperature the car(s) at destination before unloading, and observe the actual measurement by receiving personnel. f. Advise patience. This type of investigation can take several months. 28 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES Annex F (informative) Calculation Examples F.1 General The following examples necessarily display rounded input data and intermediate calculation results (CTAF, CTL, CTS, CPS), therefore those rounded values have been used to obtain the final results shown. Unrounded intermediate calculations may produce a slightly different final result. F.2 Example 1: Outage Liquid Capacity Table — Loading Target Calculation — Volume Limitation A general purpose car is to be loaded with Isopropyl Alcohol. Tank Car Data Product Data Tare: 67,900 pounds Estimated Loading Temperature: 85°F Load Limit: 195,100 pounds Manway Nozzle Height: 12.500 in. Stenciled Volume: 30,168 gallons CTL Table 6C (alpha value): API 6C (0.000578) Capacity Table: Table F-1 Density at Reference Temp: 6.574 pounds / gallon Insulated? No Statutory Temp: 115°F Vtblmax 30,154 gallons MFLA 0.9900 CTSstat 1.00102 (Equat. B-1) CTLstat 0.96792 (API 6C) CTS85 1.00047 (Equat. B-1) CTL85 0.98549 (API 6C) The weight corresponding to the statutory volume limitation must be calculated using Equation (A.1). Wma = Vs (MFLA) (CTLstat) (CTSstat) (dref), = (30,168) (0.9900) (0.96792) (1.00102) (6.574), = 190,236 pounds Since this is less than the Load Limit, the car can be loaded to statutory volume limits. If the Load Limit is not available, add Wma to the Tare (67,900 + 190,236 = 258,136) and compare with the weight limitation for that particular car (263,000 pounds for this car). One must now determine the target outage (liquid level) derived from the statutory volume using Equation (A.3). GOV = Vtblmax (MFLA) (CTLstat) (CTSstat) (CTL85) (CTS85) = (30,154) (0.9900) (0.96792) (1.00102) (0.98549) (1.00047) = 29,336 gallons Looking up this volume in the capacity table, it falls between volumes representing 7.500 inches and 7.750 inches Interpolating to the nearest 1/8 inch, 7.625 inches is equal to: (29,375 – 29,334) / 2 + 29,334 = 29,355 gallons Since GOV is less than the volume corresponding to 7.625 inches, we round to the outage corresponding to a smaller liquid volume, 7.750 inches. We do not round up to the outage corresponding to a larger volume (7.625 inches). If we wish to measure only to the nearest 1/4 inch, we would choose 7.750 inches. If measuring from the top of the manway, we must add the manway nozzle height to this value. 7.750 in. + 12.500 in. = 20.250 in. or, if to the nearest 0.250 inch: SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 29 8.000 in. + 12.500 in. = 20.250 in. If corrections for the optional shell expansion due to temperature are omitted, Wma is 190,043 lbs, GOV is 29,320 gal, which is equal to a 7.875 inch outage, or 8.000 inches if rounding to the nearest 0.250 inch. F.3 Example 2: Outage Liquid Capacity Table — Actual Loaded Calculation A general purpose car is loaded with isopropyl alcohol close to the target outage determined in Example 1. Tank Car Data Product Data Tare: 67,900 pounds Loaded Temperature: 87°F Load Limit: 195,100 pounds Manway Nozzle Height: 12.500 in. Stenciled Volume: 30,168 gallons CTL Table (alpha value): API 6C (0.000578) Capacity Table: Table F-1 Density at Reference Temp: 6.574 pounds / gallon Insulated? No Statutory Temp: 115°F Vtblmax 30,154 gallons MFLA 0.9900 CTS87 1.00050 (Equat. B-1) CTLstat 0.96792 (API 6C) CTL87 0.98432 (API 6C) Outage Gauge (from top of manway): 20.625 in. %S&W 0.0% Net Standard Volume is determined with Equation (5). GOVtbl: The capacity table (Table E-1) volumes do not include a nozzle height, so one must first subtract the manway nozzle height from the outage gauge: 20.625 in. – 12.500 in. = 8.125 in. Since the capacity table is an Outage Liquid table in quarter-inch increments, one must interpolate between the entries for 8.00 inches and 8.25 inches: (29,292 – 29,250) / 2 + 29,250 = 29,271 gallons NSV = (GOVtbl) (CTAF) (CTL87) (CTS87) = (29,271) (30,168 / 30,154) (0.98432) (1.00050) = 28,840 gallons The cargo’s weight (Equation 3) is: W = NSV (dref) = 28,840 (6.574) = 189,594 pounds Overload check by volume, using Equations (8) and (9): MFLL = (GOVtbl) (CTAF) (CTL87) (CTS87) (CTSstat) (CTLstat) (Vs) = (29,271) (30,168/30,154) (0.98432) (1.00050) (1.00102) (0.96792) (30,168) = 0.9867 Vapor space % = 100 - 0.9867 * 100 = 1.33% Since the loaded liquid fraction at 115°F would be less than 0.9900 the car is not overloaded by volume. Since the vapor space at 115°F would be greater than 1.00%, the car is not overloaded by volume. Overload check by weight: 30 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES 1. Compare cargo weight calculated above to Load Limit weight. 189,594 pounds is less than 195,100 pounds, or 2. Add Tare weight to cargo weight calculated above and compare to statutory limit: 67,900 + 189,594 = 257,494 pounds, which is less than 263,000 pounds Thus, the car is not overloaded by weight. If corrections for the optional shell expansion due to temperature are omitted,, NSV is 28,825 gal, W is 189,498 lb, and the vapor space % at 115°F is 1.28%. F.4 Example 3: Outage Liquid Capacity Table — Loading Target Calculation — Weight Limitation The same general purpose car used in Examples 1 and 2 is to be loaded with Hexylene Glycol. Tank Car Data Product Data Tare: 67,900 pounds Estimated Loading Temperature: 70°F Load Limit: 195,100 pounds Manway Nozzle Height: 12.500 in. Stenciled Volume: 30,168 gallons CTL Table: Private Table Capacity Table: Table F-1 Density at Reference Temp: 7.710 pounds / gallon Insulated? No Statutory Temp: 115°F Vtblmax 30,154 gallons MFLA 0.99 CTSstat 1.00102 (Equat. B-1) CTLstat 0.97679 CTS70 1.00019 (Equat. B-1) CTL70 0. 99570 The weight corresponding to the statutory volume limitation must be calculated using Equation (A.1). Wma = Vs (MFLA) (CTLstat) (CTSstat) (dref) = (30,168) (0.99) (0.97679) (1.00102) (7.710) = 225,154 pounds Since this is greater than the Load Limit, the car cannot be loaded to statutory volume limits. If the Load Limit is not available, add Wma to the Tare (67,900 + 225,154 = 293,054) and compare with the weight limitation for that particular car (263,000 pounds for this car). One must now determine the target outage (liquid level) derived from the statutory weight using Equation (A.2). GOV = = Wll (dref) (CTL70) (CTS70) (CTAF) (263,000 – 67,900) (7.710) (0.99570) (1.00019) (30,168 / 30,154) = 25,397 gallons Looking up this volume in the capacity table, it falls between volumes representing 25.750 inches and 26.000 inches Interpolating to the nearest 1/8 inch, 25.875 inches is equal to: (25,416 – 25,350) / 2 + 25,350 = 25,383 gallons Since GOV is greater than the volume corresponding to 25.875 inches, we round to the outage corresponding to a smaller liquid volume, 25.875 inches. We do not round up to the outage corresponding to a larger volume (25.750 inches). If we wish to measure only to the nearest 1/4 inch, we would choose 26.000 inches. If measuring from the top of the manway, we must add the manway nozzle height to this value: 25.875 in. + 12.500 in. = 38.375 in. or, if to the nearest 0.250 inch: 26.000 in. + 12.500 in. = 38.500 in. SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 31 If corrections for the optional shell expansion due to temperature are omitted, Wma is 224,925 lbs, and GOV70 is 25,402 gal, giving the same outage. F.5 Example 4: Outage Liquid Capacity Table with Nozzle Height Included — Loading Target Calculation — Volume Limitation A two compartment general purpose car is to be loaded with Odorless Mineral Spirits in the first compartment. Tank Car Data Product Data Tare: 67,200 pounds Estimated Loading Temperature: 35°F Load Limit: 195,800 pounds Manway Nozzle Height: 12.500 in. Stenciled Volume: 11,348 gallons CTL Table (API gravity): API 6B (55.1) Capacity Table: Table F-3 Density at Reference Temp: 6.322 pounds / gallon Insulated? No Statutory Temp: 115°F Vtblmax 11,348 gallons MFLA 0.99 CTSstat 1.00102 (Equat. B-1) CTLstat 0.96348 CTS35 0.99954 (Equat. B-1) CTL35 1.01635 The weight corresponding to the statutory volume limitation must be calculated using Equation (A.1). Wma = Vs (MFLA) (CTLstat) (CTSstat) (dref) = (11,348) (0.99) (0.96348) (1.00102) (6.322) = 68,501 pounds Since this is less than the Load Limit, the car can be loaded to statutory volume limits if the second compartment is still empty. If the Load Limit is not available, add Wma to the Tare (67,200 + 68,501 = 135,701) and compare with the weight limitation for that particular car (263,000 pounds for this car). If the second compartment has been loaded, the cargo weight will have to be subtracted from the Load Limit (or added to the Tare weight and subtracted from the weight limitation) to get the maximum amount allowed. If the second compartment is empty, one can now determine the target outage (liquid level) derived from the statutory volume using Equation (A.3). GOV = (Vtblmax) (MFLA) (CTLstat) (CTSstat) (CTL35) (CTS35) = (11,348) (0.99) (0.96348) (1.00102) (1.01635) (0.99954) = 10,666 gallons Looking up this volume in the capacity table, it falls at the volume representing 24.25 inches and no table interpolation is needed. Since this table includes a 12.5-inches manway nozzle, we must subtract that value if using an instrument that measures from the top inside of the shell to the liquid surface. 24.250 in. – 12.500 in. = 11.750 in. If corrections for the optional shell expansion due to temperature are omitted, Wma equals 68,431 lb and GOV is 10,650 gal. Looking this up in the capacity table, it falls between volumes representing 24.25 inches and 24.5 inches. Interpolation to the nearest 1/8 inch, 24.375 in., shows: (10,666 – 10,645) / 2 + 10,645 = 10,656 gallons Rounding to the smaller liquid volume, we choose 24.500 inches. We do not round up to the outage corresponding to a larger volume (24.375 inches). If we wish to measure only to the nearest 1/4 inch, we would also choose 24.500 inches. 32 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES Since this table includes a 12.500 inch manway nozzle, we must subtract that value if using an instrument that measures from the top inside of the shell to the liquid surface. 24.500 in. – 12.500 in. = 12.000 in. If the second compartment is already loaded, one must calculate the weight corresponding to the statutory volume limitation using a different Load Limit. Assume the cargo in the second compartment weighs 66,140 pounds and the first compartment Wma is 68,501 lb as shown above. This must be compared to the new Load Limit of: 263,000 – 67,200 – 66,140 = 129,660 pounds or 195,800 – 66,140 = 129,660 pounds Since Wma is easily within this limit, we can use the statutory volume limit as above. If it were not, we would proceed as shown in Example 3. F.6 Example 5: Outage Liquid Capacity Table with Nozzle Height Included — Actual Loaded Calculation A two-compartment general purpose car is loaded with Odorless Mineral Spirits in the first compartment, close to the outage determined in Example 4. Tank Car Data Product Data Tare: 67,200 pounds Loaded Temperature: 39°F Load Limit: 195,800 pounds Manway Nozzle Height: 12.500 in. Stenciled Volume: 11,348 gallons CTL Table (API gravity): API 6B (55.1) Capacity Table: Table F-3 Density at Reference Temp: 6.322 pounds / gallon Insulated? No Statutory Temp: 115°F Vtblmax 11,348 gallons MFLA 0.99 CTS39 0.99961 (Equat. B-1) CTLstat 0.96348 CTL39 1.01375 Outage Gauge (from inside shell top): 11.875 in. %S&W 0.0% Net Standard Volume is determined with Equation (5). GOVtbl: The capacity table (Table E-3) volumes include a nozzle height, so if one is using a gauging instrument that does not include the manway, one must first add the manway nozzle height to the outage gauge: 11.875 in. + 12.500 in. = 24.375 in. Since the capacity table is an Outage Liquid table in quarter-inch increments, one must interpolate between the entries for 24.250 inches and 24.500 inches: (10,666 – 10,645) / 2 + 10,645 = 10,656 gallons NSV = GOVtbl (CTAF) (CTL39) (CTS39) = (10,656) (11,348 / 11,348) (1.01375) (0.99961) = 10,798 gallons The cargo’s weight is determined with equation (3): W = NSV (dref) = 10,798 (6.322) = 68,265 pounds Overload check by volume, using Equation (8) and (9): MFLL = (GOVtbl) (CTAF) (CTL39) (CTS39) (CTSstat) (CTLstat) (Vs) SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 33 = (10,656) (11,348 / 11,348) (1.01375) (0.99961) (1.00102) (0.96348) (11,348) = 0.9866 Vapor space % = 100 - 0.9866 * 100 = 1.34% Since the loaded liquid fraction at 115°F would be less than 0.9900 the car is not overloaded by volume. Since the vapor space at 115°F would be greater than 1.00%, the car is not overloaded by volume. We know from the Target calculations in Example 4 that we cannot overload this product in this car by weight. However, if we did not know that, we would have to again consider the loading status of the second compartment. If the second compartment is empty: 1. Compare cargo weight calculated above to Load Limit weight. 68,265 pounds is less than 195,800 pounds, or 2. Add Tare weight to cargo weight calculated above and compare to statutory limit: 67,200 + 68,265 = 135,465 pounds, which is less than 263,000 pounds. If the second compartment is filled with 66,140 pounds of product: 1. Compare the sum of the calculated weights to the Load Limit weight of 195,800 lb. 68,267 + 66,140 = 134,407 pounds, or 2. Add the Tare weight to both cargo weights and compare to the statutory limit: 67,200 + 68,265 + 66,140 = 201,605 pounds, which is less than 263,000 pounds Thus, the car is not overloaded by weight. If corrections for the optional shell expansion due to temperature are omitted, NSV is 10,803 gal, W is 68,297 lb, and the vapor space % at 115°F is 1.20%. F.7 Example 6: Outage Vapor Capacity Table — Loading Target Calculation — Volume Limitation A general purpose car is to be loaded with Light Cat Cracked Gasoline. Tank Car Data Product Data Tare: 72,700 pounds Estimated Loading Temperature: 95°F Load Limit: 190,300 pounds Manway Nozzle Height: 9.500 in. Stenciled Volume: 23,639 gallons CTL Table (API gravity): API 6B (65.0) Capacity Table: Table F-2 Density at Reference Temp: 6.004 pounds / gallon Insulated? Yes Statutory Temp: 105°F Vtblmax 23,679 gallons MFLA 0.99 CTSstat 1.00084 (Equat. B-1) CTLstat 0.96772 (API 6B) CTS95 1.00065 (Equat. B-1) CTL95 0.97494 (API 6B) The weight corresponding to the statutory volume limitation must be calculated using equation (A.1). Wma = Vs (MFLA) (CTLstat) (CTSstat) (dref) = (23,639) (0.99) (0.96772) (1.00084) (6.004) = 136,088 pounds 34 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES Since this is less than the Load Limit, the car can be loaded to statutory volume limits. If the Load Limit is not available, add Wma to the Tare (72,700 + 136,088 = 208,788) and compare with the weight limitation for that particular car (263,000 pounds for this car). One must now determine the target outage (liquid level) derived from the statutory volume using equation (A.3). GOV = Vtblmax (MFLA) (CTLstat) (CTSstat) (CTL95) (CTS95) = (23,679) (0.99) (0.96772) (1.00084) (0.97494) (1.00065) = 23,273 gallons Since the capacity table is an Outage Vapor, the volumes listed are vapor volumes. To convert GOV to its corresponding vapor volume, subtract GOV from the maximum vapor volume in the table: 23,679 – 23,273 = 406 gallons vapor Looking up this volume in the capacity table, it falls between volumes representing 3.75 inches and 4 inches. Interpolating to the nearest 1/8 inch, 3.875 inches is equal to: (381 – 412) / 2 + 412 = 397 gallons Since GOV is greater than the volume corresponding to 3.875 inches, we round to the outage corresponding to a larger vapor volume, 4.000 inches. We do not round up to the outage corresponding to a smaller vapor volume (3.875 inches). If we wish to measure only to the nearest 1/4 inch, we would choose 4.000 inches. If measuring from the top of the manway, we must add the manway nozzle height to this value: 4.000 in. + 9.500 in. = 13.500 in. If corrections for the optional shell expansion due to temperature are omitted, Wma = 135,974 lb, well within the load limit, GOV = 23,269 gal, which is 410 gal of vapor, equivalent to just over 4.0 in. as above. F.8 Example 7: Outage Vapor Capacity Table — Loading Target Calculation — Understated Loading Temperature A general purpose car is to be loaded with Light Cat Cracked Gasoline. However, here the assumed loading temperature is 60°F instead of the real 95°F as shown in Example 6. Tank Car Data Product Data Tare: 72,700 pounds Estimated Loading Temperature: 60°F Load Limit: 190,300 pounds Manway Nozzle Height: 9.250 in. Stenciled Volume: 23,639 gallons CTL Table (API gravity): API 6B (65.0) Capacity Table: Table F-2 Density at Reference Temp: 6.004 pounds / gallon Insulated? Yes Statutory Temp: 105°F Vtblmax 23,679 gallons MFLA 0.99 CTSstat 1.00084 (Equat. B-1) CTLstat 0.96772 (API 6B) CTS60 1.00000 (Equat. B-1) CTL60 1.00000 (API 6B) The weight corresponding to the statutory volume limitation must be calculated using equation (A.1). Wma = Vs (MFLA) (CTLstat) (CTSstat) (dref) = (23,639) (0.99) (0.96772) (1.00084) (6.004) = 136,088 pounds SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 35 Since this is less than the Load Limit, the car can be loaded to statutory volume limits. If the Load Limit is not available, add Wma to the Tare (72,700 + 136,088 = 208,788) and compare with the weight limitation for that particular car (263,000 pounds for this car). One must now determine the target outage (liquid level) derived from the statutory volume using equation (A.3). GOV = (Vtblmax) (MFLA) (CTLstat) (CTSstat) (CTL60) (CTS60) = (23,679) (0.99) (0.96772) (1.00084) (1.00000) (1.000000) = 22,705 gallons Since the capacity table is an Outage Vapor, the volumes listed are vapor volumes. To convert GOV to its corresponding vapor volume, subtract GOV from the maximum vapor volume in the table: 23,679 – 22,705 = 974 gallons vapor Looking up this volume in the capacity table, it falls between volumes representing 7.750 inches and 8.000 inches. Interpolating to the nearest 1/8 inch, 7.875 inches is equal to: (945 – 984) / 2 + 984 = 965 gallons Since vapor volume is more than the volume corresponding to 7.875 inches, we round to the outage corresponding to a larger vapor volume, 8.000 inches. We do not round up to the outage corresponding to a smaller vapor volume (7.875 inches). If we wish to measure only to the nearest 1/4 inch, we would still choose 8.000 inches. If measuring from the top of the manway, we must add the manway nozzle height to this value. 8.000 in. + 9.250 in. = 17.250 in. Notice, comparing Example 6 to Example 7, that by ignoring the actual loaded temperature of 95°F and using 60°F, one will underload the car by 4.000 inches, or 572 gallons. Thus, it is always best to determine the loading temperature as accurately as possible. This example also illustrates the converse – one must not overestimate the actual loading temperature or the target calculation will result in overloading the car (see Example 9). F.9 Example 8: Outage Vapor Capacity Table — Actual Loaded Calculation A general purpose car is loaded with Light Cat Cracked Gasoline close to the target outage determined in Example 6. Tank Car Data Product Data Tare: 72,700 pounds Loaded Temperature: 97°F Load Limit: 190,300 pounds Manway Nozzle Height: 9.250 in. Stenciled Volume: 23,639 gallons CTL Table (API gravity): API 6B (65.0) Capacity Table: Table F-2 Density at Reference Temp: 6.004 pounds / gallon Insulated? Yes Outage Gauge (from top of manway): 13.5 in. Vtblmax 23,639 gallons Statutory Temp: 115°F CTS97 1.00069 (Equat. B-1) MFLA 0.99 CTLstat 0.96772 CTL97 0.97350 Outage Gauge (from top of manway): 13.500 in. %S&W 0.0% Net Standard Volume is determined with equation (5). 36 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES GOVtbl: The capacity table (Table E-2) does not include a nozzle height, so one must first subtract the manway nozzle height from the outage gauge: 13.500 in. – 9.250 in. = 4.250 in. Since the capacity table is an Outage Vapor table in quarter-inch increments, one need not interpolate for 4.250 inches, but must subtract the corresponding vapor volume from the table maximum volume. The resulting liquid volume is: (23,679 – 444) = 23,235 gallons NSV = GOV (CTAF) (CTL97) (CTS97) = (23,235) (23,639 / 23,679) (0.97350) (1.00069) = 22,597 gallons The cargo’s weight is determined, as determined with equation (3), is less than the load limit: W = NSV (dref) = 22,597 (6.004) = 135,672 pounds Overload check by volume, using equations (8) and (9): MFLL = (GOVtbl) (CTAF) (CTL97) (CTS97) (CTSstat) (CTLstat) (Vs) = (23,235) (23,639 / 23,679) (0.97350) (1.00069) (1.00084) (0.96772) (23,639) = 0.9870% Vapor Space % = 100 – 0.9870 * 100 = 1.30% Since the loaded liquid fraction at 105°F would be less than 0.9900 the car is not overloaded by volume. Since the vapor space at 105°F would be greater than 1.00%, the car is not overloaded by volume. Overload check by weight: 1. Compare cargo weight calculated above to Load Limit weight. 135,672 pounds is less than 190,300 pounds, or 2. Add Tare weight to cargo weight calculated above and compare to statutory limit: 72,700 + 135,672 = 208,372 pounds, which is less than 263,000 pounds. Thus, the car is not overloaded by weight. If CTS is not included, NSV is 22,581 gallons, W is 135,672 pounds, and the vapor space % is 1.29%. F.10 Example 9: Outage Vapor Capacity Table — Actual Loaded Calculation — Overstated Target Loading Temperature Results in Overloading by Volume A general purpose car is loaded with Light Cat Cracked Gasoline close to the target outage determined in Example 6, but at a colder temperature (90°F) than that used in the target calculation (95°F). Tank Car Data Product Data Tare: 72,700 pounds Loaded Temperature: 90°F Load Limit: 190,300 pounds Manway Nozzle Height: 9.25 in. Stenciled Volume: 23,639 gallons CTL Table (API gravity): API 6B (65.0) Capacity Table: Table F-2 Density at Reference Temp: 6.004 pounds / gallon Insulated? Yes Outage Gauge (from top of manway): 13.500 in. Vtblmax 23,679 gallons Statutory Temp: 105°F CTS90 1.00056 (Equat. B-1) MFLA 0.99 CTLstat 0.96772 CTL90 0.97854 SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS %S&W 37 0.0% Net Standard Volume is determined with equation (5). GOVtbl: The capacity table (Table E-2) does not include a nozzle height, so one must first subtract the manway nozzle height from the outage gauge: 13.500 in. – 9.500 in. = 4.000 in. Since the capacity table is an Outage Vapor table in quarter-inch increments, one need not interpolate for 4.000 inches, but must subtract the corresponding vapor volume from the table maximum volume. The resulting liquid volume is: (23,679 – 412) = 23,267 gallons NSV = GOVtbl (CTAF) (CTL90) (CTS90) = (23,267) (23,639 / 23,679) (0.97854) (1.00056) = 22,742 gallons The cargo’s weight is determined with equation (3): W = NSV (dref) = 22,742 (6.004) = 136,543 pounds Overload check by volume, using equations (8) and (9): MFLL = (GOVtbl) (CTAF) (CTL90) (CTS90) (CTSstat) (CTLstat) (Vs) = (23,267) (23,639 / 23,679) (0.97854) (1.00056) (1.00084) (0.96772) (23,639) = 0.9933% Vapor Space % = 100 – 0.9933 * 100 = 0.67% Since the loaded liquid fraction at 105°F would be more than 0.9900 the car is overloaded by volume; or, since the vapor space at 105°F would be less than 1.00%, the car is overloaded by volume by: NSV = (Vs) (0.19%) (CTLstat) (CTSstat) = (23,639) (0.0019) (0.96772) (1.00084) = 44 net gallons Overload check by weight: 1. Compare cargo weight calculated above to Load Limit weight. 136,357 pounds is less than 190,300 pounds, or 2. Add Tare weight to cargo weight calculated above and compare to statutory limit: 72,700 + 136,357 = 209,057 pounds, which is less than 263,000 pounds. Thus, the car is not overloaded by weight. 38 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES F.11 Example 10: Outage Vapor Capacity Table — Pressure Car Target Loading Calculation — Summer Loading A pressure car is to be loaded with Propane in the summer. Tank Car Data Product Data Tare: 100,800 pounds Estimated Loading Temperature: 92°F Load Limit: 162,200 pounds Manway Nozzle Height: 0.00 in. Stenciled Volume: 33,648 gallons CTL Table (relative density): API Chapt 11.2.4 (0.5059) Capacity Table: Table F-4 Density at Reference Temp: 4.218 pounds/gallon Insulated? No Statutory Temp: 115°F Vtblmax 33,653 gallons MFLA 0.99 CTSstat 1.00102 (Equat. B-1) CTLstat 0.89963 (Chapt 11.2.4) CTS92 1.00060 (Equat. B-1) CTL92 0.94460 (Chapt 11.2.4) CPSstat 1.00131 (Equat. C-1) Pressure @ 92°F 165 psig CPS92 1.00096 (Equat. C-1) Pressure @ 115°F 226 psig (Chapt 11.2.5) The weight corresponding to the statutory volume limitation must be calculated using equation (A.5). Wma = Vs (MFLA) (CTLstat) (CPLstat) (CTSstat) (CPSstat) (dref) = (33,648) (0.99) (0.89963) (1.00000) (1.00102) (1.00131) (4.218) = 126,701 pounds Since this is less than the Load Limit, the car can be loaded to statutory volume limits. If the Load Limit is not available, add Wma to the Tare (100,800 + 126,701 = 227,501) and compare with the weight limitation for that particular car (263,000 pounds for this car). One must now determine the target outage (liquid level) derived from the statutory volume using equation (A.7). GOV = Vtblmax (MFLA) (CTLstat) (CPLstat) (CTSstat) (CPSstat) (CTL92) (CPL92) (CTS92) (CPS92) = (33,653) (0.99) (0.89963) (1.00000) (1.00102) (1.00131) (0.94460) (1.00000) (1.00060) (1.00096) = 31,755 gallons Since the capacity table is an Outage Vapor, the volumes listed are vapor volumes. To convert GOV to its corresponding vapor volume, subtract GOV from the maximum vapor volume in the table: 33,653 – 31,755 = 1,898 gallons vapor Looking up this volume in the capacity table, it falls between volumes representing 12.75 inches and 13.00 inches Interpolating to the nearest 1/8 inch, 12.875 inches is equal to: (1,892 – 1,947) / 2 + 1,947 = 1,920 gallons Since the vapor space corresponding to the GOV is less than the vapor volume corresponding to 12.875 inches, we round to the outage corresponding to the larger vapor volume, 12.875 inches, and load to 1920 gallons of vapor. We do not round up to the outage corresponding to a smaller vapor volume (12.75 inches). If we wish to measure only to the nearest 0.250 inch, we would choose 13.000 inches without bothering to interpolate. Because this is a pressure car, the product level is measured by an internal gauge, and the manway height is not needed. If corrections for the optional shell expansion due to temperature and pressure are omitted, Wma equals 126,405 lb and GOV will be 31,730 liquid gallons, or 1923 vapor gallons, resulting in a loading outage of 13.000 inches. SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 39 F.12 Example 11: Outage Vapor Capacity Table — Pressure Car Target Loading Calculation — Winter Loading The pressure car in Example 10 is to be loaded with propane under winter regulations. Tank Car Data Product Data Tare: 100,800 pounds Estimated Loading Temperature: 92°F Load Limit: 162,200 pounds Manway Nozzle Height: 0.00 in. Stenciled Volume: 33,648 gallons CTL Table (relative density): API Chapt 11.2.4 (0.5059) Capacity Table: Table F-4 Density at Reference Temp: 4.218 pounds/gallon Insulated? No Statutory Temp: 100°F Vtblmax 33,653 gallons MFLA 0.99 CTSstat 1.00074 (Equat. B-1) CTLstat 0.92955 (Chapt 11.2.4) CTS92 1.00060 (Equat. B-1) CTL92 0.94460 (Chapt 11.2.4) CPSstat 1.00108 (Equat. C-1) Pressure @ 92°F 165 psig CPS92 1.00096 (Equat. C-1) Pressure @ 100°F 185 psig (Chapt 11.2.5) The weight corresponding to the statutory volume limitation must be calculated using equation (A.5). Wma = Vs (MFLA) (CTLstat) (CPLstat) (CTSstat) (CPSstat) (dref) = (33,648) (0.99) (0.92955) (1.00000) (1.00074) (1.00108) (4.218) = 130,847 pounds Since this is less than the Load Limit, the car can be loaded to statutory volume limits. If the Load Limit is not available, add Wma to the Tare (100,800 + 130,847 = 231,647) and compare with the weight limitation for that particular car (263,000 pounds for this car). One must now determine the target outage (liquid level) derived from the statutory volume using equation (A.7). GOV = Vtblmax (MFLA) (CTLstat) (CPLstat) (CTSstat) (CPSstat) (CTL92) (CPL92) (CTS92) (CPS92) = (33,653 (0.99) (0.92955) (1.00000) (1.00074) (1.00108) (0.94460) (1.00000) (1.00060) (1.00096) = 32,794 gallons Since the capacity table is an Outage Vapor, the volumes listed are vapor volumes. To convert GOV to its corresponding vapor volume, subtract GOV from the maximum vapor volume in the table: 33,653 – 32,794 = 859 gallons vapor Looking up this volume in the capacity table, it falls between volumes representing 7.250 inches and 7.500 inches. Interpolating to the nearest 1/8 inch, 7.375 inches is equal to: (819 – 861) / 2 + 861 = 840 gallons Since the vapor space corresponding to the GOV is more than the volume corresponding to 7.375 inches, but less than that for 7.500 inches, we round to the outage corresponding to the larger vapor volume, 7.500 inches, and load to 861 gallons of vapor. We do not round up to the outage corresponding to a smaller vapor volume (7.375 inches). If we wish to measure only to the nearest 0.250 inch, we would choose 7.500 inches. Since this is a pressure car, the product level is measured by an internal gauge, and the manway height is not needed or used. Comparing this result to Example 10, we can load 1,059 gallons (1920 – 861) more product at 92°F (or 1002 gallons net) under winter regulations than under summer regulations. If corrections for the optional shell expansion due to temperature and pressure are omitted, Wma will be 130,609 lb and GOV 32,786 gallons, corresponding to an outage of 7.500 in. 40 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES F.13 Example 12: Outage Vapor Capacity Table — Pressure Car Actual Loaded Calculation A pressure car is loaded with Propane in the summer close to the Target outage determined in Example 10. Tank Car Data Product Data Tare: 100,800 pounds Estimated Loading Temperature: 95°F Load Limit: 162,200 pounds Manway Nozzle Height: 0.00 in. Stenciled Volume: 33,648 gallons CTL Table (relative density): API Chapt 11.2.4 (0.5059) Capacity Table: Table F-4 Density at Reference Temp: 4.218 pounds/gallon Insulated? No Statutory Temp: 115°F Vtblmax 33,653 gallons MFLA 0.99 CTSstat 1.00102 (Equat. B-1) Outage Gauge (internal): 13.000 in. CTS95 1.00065 (Equat. B-1) CTLstat 0.89963 (Chapt 11.2.4) CPSstat 1.00131 (Equat. C-1) CTL95 0.93903 (Chapt 11.2.4) CPS95 1.00100 (Equat. C-1) Pressure @ 95°F 172 psig Pressure @ 115°F 226 psig (Chapt 11.2.5) Net Standard Volume is determined with equation (6). GOVtbl: The capacity table (Table E-4) does not include a nozzle height, but since the internal gauge measures from the top inside of the car’s shell, no correction is needed and the outage can be looked up directly in the car’s capacity table. Since the capacity table is an Outage Vapor table in quarter inch increments, one need not interpolate for 13.000 inches but must subtract the corresponding vapor volume from the table maximum volume. The resulting liquid volume is: (33,653 – 1,947) = 31,706 gallons NSV = (GOVtbl) (CTAF) (CTL92) (CTS92) (CPS92) = (31,706) (33,648 / 33,653) (0.93903) (1.00065) (1.00100) = 29,788 gallons The cargo’s weight is determined with equation (2): W = (NSV) (dref) = 29,788 (4.218) = 125,646 pounds Overload check by volume, using equation (8) and (9): MFLL = (GOVtbl) (CTAF) (CTL) (CTS) (CPS) (CTSstat) (CTLstat) (CPSstat) (Vs) = (31,706) (33,648 / 33,653) (0.93903) (1.00065) (1.00100) (1.00102) (0.89963) (1.00131) (33,648) = 0.9840 Vapor Space % = 100 – 0.9840 * 100 = 1.60% Since the MFLL is less than 0.99 and the corresponding vapor space at 115°F is more than 1.00%, the car is not overloaded by volume. Overload check by weight: 1. Compare cargo weight calculated above to Load Limit weight. 125,960 pounds is less than 162,200 pounds, or 2. Add Tare weight to cargo weight calculated above, and compare to statutory limit: 100,800 + 125,646 = 226,361 pounds, which is less than 263,000 pounds. SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 41 Thus, the car is not overloaded by weight. If corrections for the optional shell expansion due to temperature and pressure are omitted, NSV will be 29,768 gallons, the MFLL 0.9834, and the % vapor space 1.66%. F.14 Example 13: Innage Liquid Capacity Table — Loading Target Calculation — Volume Limitation A general purpose car is to be loaded with p-Xylene. Tank Car Data Product Data Tare: 65,900 pounds Estimated Loading Temperature: 75°F Load Limit: 197,100 pounds Manway Nozzle Height: 13.375 in. Stenciled Volume: 26,859 gallons CTL Table: ASTM D1555 Capacity Table: Table F-5 Density at Reference Temp: 7.2151 pounds / gallon Insulated? No Statutory Temp: 115°F Vtblmax 26,838 gallons MFLA 0.99 CTSstat 1.00102 (Equat. B-1) CTLstat 0.96942 D1555) (ASTM CTS75 1.00028 (Equat. B-1) CTL75 0.99174 D1555) (ASTM The weight corresponding to the statutory volume limitation must be calculated using equation (A.1). Wma = Vs (MFLA) (CTLstat) (CTSstat) (dref) = (26,859) (0.99) (0.96942) (1.00102) (7.2151) = 186,175 pounds Since this is less than the Load Limit, the car can be loaded to statutory volume limits. If the Load Limit is not available, add Wma to the Tare (65,900 + 186,175 = 252,075) and compare with the weight limitation for that particular car (263,000 pounds for this car). One must now determine the target outage (liquid level) derived from the statutory volume using equation (A.3). GOV = Vtblmax (MFLA) (CTLstat) (CTSstat) (CTL75) (CTS75) = (26,838) (0.99) (0.96942) (1.00102) (0.99174) (1.00028) = 25, 991 gallons Since the capacity table is an Innage Liquid, the volumes listed are liquid volumes. Looking up this volume in the capacity table, it falls between volumes representing 101.250 inches and 101.500 inches. Interpolating to the nearest 1/8 inch, 101.375 inches is equal to: (25,975 – 26,018) / 2 + 25,975 = 25,997 gallons Since GOV is greater than the volume corresponding to 101.250 inches, but less than that corresponding to 101.375 inches, we round to the innage corresponding to a smaller liquid volume, 101.250 inches. We do not round up to the innage corresponding to a larger liquid volume (101.375 inches). If we wish to measure only to the nearest 1/4 inch, we would choose 101.250 inches. Since this is an innage table, we do not need the manway nozzle height if we are going to perform an innage measurement. If measuring from the top of the manway, we must add the manway nozzle height to the shell diameter (maximum value in the table), and subtract the above calculated innage to get the target outage: 108.75 in. + 13.375 in. – 101.25 in. = 20.875 in. If measuring from the top inside of the shell, the outage would be: 42 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES 108.750 in. – 101.250 in. = 7.500 in. If corrections for the optional shell expansion due to temperature are omitted, Wma = 185,986 lb (well within the load limit), and GOV = 25,972 gal, corresponding to an innage of 101.125 inches or , if rounding to the nearest quarter inch, 101 inches. SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 43 Table F-1 — Tank Car Capacity Table Tank Car: ACFX 75538 Capacity Table: ACF 1785 0.00 0.25 0.50 0.75 1.00 1.25 1.50 1.75 2.00 2.25 2.50 2.75 3.00 3.25 3.50 3.75 4.00 4.25 4.50 4.75 5.00 5.25 5.50 5.75 6.00 6.25 6.50 6.75 7.00 7.25 7.50 7.75 8.00 8.25 8.50 8.75 9.00 9.25 9.50 9.75 10.00 10.25 10.50 10.75 11.00 11.25 11.50 11.75 30,154 30,151 30,145 30,137 30,125 30,111 30,095 30,076 30,055 30,032 30,008 29,982 29,955 29,927 29,898 29,868 29,838 29,807 29,777 29,746 29,715 29,685 29,656 29,627 29,597 29,564 29,529 29,493 29,455 29,416 29,375 29,334 29,292 29,250 29,208 29,167 29,125 29,085 29,043 29,002 28,960 28,918 28,875 28,832 28,788 28,744 28,699 28,654 12.00 12.25 12.50 12.75 13.00 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 15.25 15.50 15.75 16.00 16.25 16.50 16.75 17.00 17.25 17.50 17.75 18.00 18.25 18.50 18.75 19.00 19.25 19.50 19.75 20.00 20.25 20.50 20.75 21.00 21.25 21.50 21.75 22.00 22.25 22.50 22.75 23.00 23.25 23.50 23.75 28,608 28,561 28,514 28,465 28,416 28,366 28,316 28,265 28,213 28,162 28,110 28,058 28,006 27,953 27,900 27,846 27,792 27,738 27,683 27,628 27,572 27,516 27,460 27,403 27,346 27,288 27,230 27,172 27,113 27,054 26,995 26,934 26,874 26,813 26,752 26,690 26,628 26,567 26,505 26,442 26,380 26,318 26,255 26,192 26,128 26,065 26,001 25,937 Nozzle Volume: 0 Nozzle Height: 12.5 24.00 24.25 24.50 24.75 25.00 25.25 25.50 25.75 26.00 26.25 26.50 26.75 27.00 27.25 27.50 27.75 28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50 32.75 33.00 33.25 33.50 33.75 34.00 34.25 34.50 34.75 35.00 35.25 35.50 35.75 25,873 25,808 25,744 25,679 25,613 25,548 25,482 25,416 25,350 25,283 25,216 25,149 25,082 25,014 24,946 24,878 24,809 24,739 24,670 24,600 24,531 24,461 24,392 24,323 24,255 24,186 24,117 24,047 23,978 23,907 23,837 23,766 23,695 23,623 23,551 23,479 23,406 23,333 23,259 23,185 23,111 23,036 22,962 22,887 22,813 22,740 22,667 22,593 36.00 36.25 36.50 36.75 37.00 37.25 37.50 37.75 38.00 38.25 38.50 38.75 39.00 39.25 39.50 39.75 40.00 40.25 40.50 40.75 41.00 41.25 41.50 41.75 42.00 42.25 42.50 42.75 43.00 43.25 43.50 43.75 44.00 44.25 44.50 44.75 45.00 45.25 45.50 45.75 46.00 46.25 46.50 46.75 47.00 47.25 47.50 47.75 22,519 22,444 22,368 22,291 22,214 22,137 22,060 21,983 21,906 21,829 21,753 21,676 21,599 21,522 21,445 21,368 21,291 21,213 21,136 21,059 20,982 20,905 20,827 20,750 20,672 20,595 20,517 20,440 20,362 20,284 20,206 20,128 20,050 19,971 19,893 19,815 19,736 19,657 19,578 19,499 19,420 19,341 19,261 19,182 19,102 19,023 18,943 18,863 48.00 48.25 48.50 48.75 49.00 49.25 49.50 49.75 50.00 50.25 50.50 50.75 51.00 51.25 51.50 51.75 52.00 52.25 52.50 52.75 53.00 53.25 53.50 53.75 54.00 54.25 54.50 54.75 55.00 55.25 55.50 55.75 56.00 56.25 56.50 56.75 57.00 57.25 57.50 57.75 58.00 58.25 58.50 58.75 59.00 59.25 59.50 59.75 Stencil Volume: Nozzle Height Included? 18,783 18,702 18,622 18,542 18,461 18,380 18,300 18,219 18,138 18,057 17,976 17,895 17,814 17,733 17,652 17,570 17,489 17,408 17,326 17,245 17,163 17,082 17,000 16,919 16,837 16,755 16,674 16,592 16,510 16,429 16,347 16,265 16,182 16,100 16,018 15,935 15,852 15,770 15,687 15,604 15,521 15,438 15,355 15,272 15,189 15,106 15,023 14,940 60.00 60.25 60.50 60.75 61.00 61.25 61.50 61.75 62.00 62.25 62.50 62.75 63.00 63.25 63.50 63.75 64.00 64.25 64.50 64.75 65.00 65.25 65.50 65.75 66.00 66.25 66.50 66.75 67.00 67.25 67.50 67.75 68.00 68.25 68.50 68.75 69.00 69.25 69.50 69.75 70.00 70.25 70.50 70.75 71.00 71.25 71.50 71.75 14,857 14,774 14,691 14,608 14,526 14,443 14,360 14,278 14,195 14,113 14,031 13,949 13,867 13,785 13,704 13,622 13,541 13,460 13,379 13,298 13,217 13,136 13,055 12,974 12,893 12,813 12,732 12,652 12,571 12,491 12,411 12,330 12,250 12,170 12,090 12,010 11,930 11,850 11,770 11,690 11,611 11,531 11,451 11,372 11,292 11,213 11,133 11,054 72.00 72.25 72.50 72.75 73.00 73.25 73.50 73.75 74.00 74.25 74.50 74.75 75.00 75.25 75.50 75.75 76.00 76.25 76.50 76.75 77.00 77.25 77.50 77.75 78.00 78.25 78.50 78.75 79.00 79.25 79.50 79.75 80.00 80.25 80.50 80.75 81.00 81.25 81.50 81.75 82.00 82.25 82.50 82.75 83.00 83.25 83.50 83.75 30168 No 10,975 10,895 10,816 10,737 10,658 10,579 10,500 10,421 10,343 10,264 10,185 10,107 10,028 9,950 9,871 9,793 9,715 9,636 9,558 9,430 9,402 9,324 9,246 9,168 9,090 9,012 8,934 8,857 8,779 8,701 8,624 8,546 8,468 8,391 8,313 8,235 8,158 8,080 8,003 7,925 7,848 7,770 7,696 7,621 7,548 7,475 7,402 7,328 Tare: 67900 Type: Outage Liquid 84.00 84.25 84.50 84.75 85.00 85.25 85.50 85.75 86.00 86.25 86.50 86.75 87.00 87.25 87.50 87.75 88.00 88.25 88.50 88.75 89.00 89.25 89.50 89.75 90.00 90.25 90.50 90.75 91.00 91.25 91.50 91.75 92.00 92.25 92.50 92.75 93.00 93.25 93.50 93.75 94.00 94.25 94.50 94.75 95.00 95.25 95.50 95.75 7,254 7,179 7,105 7,030 6,956 6,882 6,809 6,736 6,664 6,593 6,521 6,450 6,379 6,308 6,226 6,164 6,092 6,020 5,948 5,877 5,806 5,735 5,665 5,595 5,526 5,456 5,388 5,319 5,251 5,183 5,115 5,048 4,981 4,914 4,847 4,781 4,715 4,649 4,584 4,518 4,453 4,385 4,324 4,260 4,196 4,132 4,069 4,005 96.00 96.25 96.50 96.75 97.00 97.25 97.50 97.75 98.00 98.25 98.50 98.75 99.00 99.25 99.50 99.75 100.00 100.25 100.50 100.75 101.00 101.25 101.50 101.75 102.00 102.25 102.50 102.75 103.00 103.25 103.50 103.75 104.00 104.25 104.50 104.75 105.00 105.25 105.50 105.75 106.00 106.25 106.50 106.75 107.00 107.25 107.50 107.75 3,942 3,879 3,817 3,754 3,692 3,630 3,568 3,507 3,445 3,384 3,323 3,262 3,202 3,143 3,084 3,025 2,967 2,909 2,852 2,794 2,738 2,681 2,625 2,565 2,513 2,458 2,403 2,349 2,294 2,240 2,187 2,133 2,080 2,027 1,974 1,921 1,869 1,817 1,765 1,714 1,663 1,613 1,564 1,514 1,465 1,416 1,368 1,320 108.00 108.25 108.50 108.75 109.00 109.25 109.50 109.75 110.00 110.25 110.50 110.75 111.00 111.25 111.50 111.75 112.00 112.25 112.50 112.75 113.00 113.25 113.50 113.75 114.00 114.25 114.5 114.75 115.00 115.25 115.50 115.75 116.00 116.25 116.50 116.75 117.00 117.25 117.50 117.75 118.00 118.25 118.50 1,272 1,226 1,180 1,136 1,093 1,051 1,008 966 925 884 844 805 766 728 696 656 621 587 555 524 493 462 433 404 375 347 319 292 265 239 212 187 161 136 111 87 62 38 20 9 3 1 0 44 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES Table F-2 — Tank Car Capacity Table Tank Car: GATX 3741 Capacity Table: GAT 8582 0.25 0.50 0.75 1.00 1.25 1.50 1.75 2.00 2.25 2.50 2.75 3.00 3.25 3.50 3.75 4.00 4.25 4.50 4.75 5.00 5.25 5.50 5.75 6.00 6.25 6.50 6.75 7.00 7.25 7.50 7.75 8.00 8.25 8.50 8.75 9.00 9.25 9.50 9.75 10.00 10.50 11.00 11.50 12.00 12.50 13.00 13.50 14.00 14.50 15.00 15.50 16.00 16.50 17.00 17.50 18.00 18.50 19.00 19.50 19 40 61 83 107 131 156 182 208 235 263 291 321 350 381 412 444 476 509 542 576 611 646 682 718 755 792 829 867 906 945 984 1,024 1,064 1,105 1,146 1,188 1,230 1,272 1,315 1,402 1,490 1,580 1,671 1,764 1,857 1,953 2,050 2,147 2,247 2,347 2,448 2,551 2,655 2,760 2,866 2,973 3,081 3,191 Nozzle Volume: 0 Nozzle Height: 9.5 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 3,301 3,524 3,751 3,981 4,215 4,452 4,692 4,935 5,181 5,430 5,681 5,934 6,190 6,448 6,707 6,969 7,233 7,498 7,765 8,033 8,303 8,574 8,846 9,119 9,394 9,669 9,944 10,221 10,498 10,775 11,053 11,331 11,609 11,887 12,165 12,443 12,721 12,998 13,275 13,552 13,827 14,102 14,376 14,650 14,922 15,193 15,463 15,731 15,998 16,263 16,527 16,789 17,049 17,307 17,563 17,816 18,067 18,316 18,562 Stencil Volume: Nozzle Height Included? 79.00 80.00 81.00 82.00 83.00 84.00 85.00 86.00 87.00 88.00 89.00 90.00 91.00 91.50 92.00 92.50 93.00 93.50 94.00 94.50 95.00 95.50 96.00 96.50 97.00 97.50 98.00 98.50 99.00 99.50 100.00 100.50 100.75 101.00 101.25 101.50 101.75 102.00 102.25 102.50 102.75 103.00 103.25 103.50 103.75 104.00 104.25 104.50 104.75 105.00 105.25 105.50 105.75 106.00 106.25 106.50 106.75 107.00 107.25 18,805 19,045 19,282 19,516 19,747 19,974 20,197 20,416 20,632 20,843 21,050 21,252 21,449 21,546 21,642 21,736 21,829 21,920 22,010 22,098 22,185 22,271 22,354 22,436 22,517 22,595 22,672 22,747 22,820 22,891 22,960 23,027 23,059 23,091 23,123 23,154 23,184 23,213 23,242 23,270 23,298 23,325 23,351 23,376 23,401 23,425 23,448 23,470 23,491 23,511 23,530 23,548 23,564 23,579 23,593 23,606 23,618 23,628 23,637 23639 No Tare: 72700 Type: Outage Vapor 107.50 107.75 108.00 108.25 108.50 108.75 109.00 109.25 109.50 109.75 110.25 23,645 23,652 23,658 23,664 23,668 23,671 23,674 23,676 23,677 23,678 23,679 SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 45 Table F-3 — Tank Car Capacity Table Tank Car: SCMX 2197 1 Capacity Table: SCM 922197 12.50 12.75 13.00 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 15.25 15.50 15.75 16.00 16.25 16.50 16.75 17.00 17.25 17.50 17.75 18.00 18.25 18.50 18.75 19.00 19.25 19.50 19.75 20.00 20.25 20.50 20.75 21.00 21.25 21.50 21.75 22.00 22.25 22.50 22.75 23.00 23.25 23.50 23.75 24.00 24.25 24.50 24.75 25.00 25.25 25.50 25.75 26.00 26.25 26.50 26.75 27.00 27.25 27.50 27.75 28.00 28.25 11,348 11,345 11,342 11,336 11,329 11,323 11,317 11,307 11,297 11,287 11,277 11,267 11,256 11,245 11,234 11,222 11,210 11,197 11,183 11,170 11,157 11,143 11,130 11,117 11,100 11,083 11,067 11,050 11,033 11,017 10,998 10,980 10,962 10,944 10,925 10,907 10,889 10,871 10,853 10,834 10,816 10,795 10,773 10,752 10,730 10,709 10,687 10,666 10,645 10,623 10,602 10,580 10,559 10,537 10,516 10,493 10,470 10,446 10,423 10,400 10,377 10,354 10,331 10,308 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50 32.75 33.00 33.25 33.50 33.75 34.00 34.25 34.50 34.75 35.00 35.25 35.50 35.75 36.00 36.25 36.50 36.75 37.00 37.25 37.50 37.75 38.00 38.25 38.50 38.75 39.00 39.25 39.50 39.75 40.00 40.25 40.50 40.75 41.00 41.25 41.50 41.75 42.00 42.25 42.50 42.75 43.00 43.25 43.50 43.75 44.00 44.25 Nozzle Volume: 0 Nozzle Height: 12.5 10,285 10,262 10,238 10,215 10,189 10,162 10,135 10,108 10,082 10,055 10,028 10,002 9,975 9,948 9,922 9,895 9,868 9,841 9,815 9,787 9,759 9,732 9,704 9,677 9,649 9,621 9,594 9,566 9,538 9,511 9,483 9,456 9,428 9,399 9,370 9,340 9,310 9,281 9,251 9,221 9,192 9,162 9,132 9,103 9,073 9,043 9,014 8,982 8,951 8,920 8,888 8,857 8,826 8,794 8,763 8,732 8,701 8,669 8,638 8,607 8,575 8,544 8,513 8,480 44.50 44.75 45.00 45.20 45.50 45.75 46.00 46.25 46.50 46.75 47.00 47.25 47.50 47.75 48.00 48.25 48.50 48.75 49.00 49.25 49.50 49.75 50.00 50.25 50.50 50.75 51.00 51.25 51.50 51.75 52.00 52.25 52.50 52.75 53.00 53.25 53.50 53.75 54.00 54.25 54.50 54.75 55.00 55.25 55.50 55.75 56.00 56.25 56.50 56.75 57.00 57.25 57.50 57.75 58.00 58.25 58.50 58.75 59.00 59.25 59.50 59.75 60.00 60.25 8,448 8,416 8,384 8,351 8,319 8,287 8,254 8,222 8,190 8,157 8,125 8,093 8,060 8,028 7,995 7,962 7,929 7,895 7,862 7,828 7,795 7,762 7,728 7,695 7,661 7,628 7,595 7,561 7,528 7,494 7,459 7,425 7,390 7,356 7,321 7,287 7,252 7,218 7,183 7,149 7,114 7,080 7,045 7,011 6,976 6,941 6,907 6,872 6,838 6,803 6,769 6,734 6,700 6,665 6,631 6,596 6,562 6,527 6,492 6,458 6,423 6,389 6,354 6,320 Stencil Volume: Nozzle Height Included? 60.50 60.75 61.00 61.25 61.50 61.75 62.00 62.25 62.50 62.75 63.00 63.25 63.50 63.75 64.00 64.25 64.50 64.75 65.00 65.25 65.50 65.75 66.00 66.25 66.50 66.75 67.00 67.25 67.50 67.75 68.00 68.25 68.50 68.75 69.00 69.25 69.50 69.75 70.00 70.25 70.50 70.75 71.00 71.25 71.50 71.75 72.00 72.25 72.50 72.75 73.00 73.25 73.50 73.75 74.00 74.25 74.50 74.75 75.00 75.25 75.50 75.75 76.00 76.25 6,285 6,251 6,216 6,182 6,147 6,113 6,078 6,044 6,009 5,973 5,937 5,902 5,866 5,830 5,794 5,759 5,723 5,687 5,651 5,616 5,580 5,544 5,508 5,472 5,437 5,401 5,365 5,329 5,294 5,258 5,222 5,186 5,151 5,115 5,079 5,043 5,008 4,973 4,938 4,904 4,869 4,835 4,800 4,766 4,731 4,697 4,662 4,628 4,593 4,559 4,524 4,490 4,456 4,422 4,388 4,354 4,320 4,286 4,252 4,218 4,184 4,150 4,116 4,082 76.50 76.75 77.00 77.25 77.50 77.75 78.00 78.25 78.50 78.75 79.00 79.25 79.50 79.75 80.00 80.25 80.50 80.75 81.00 81.25 81.50 81.75 82.00 82.25 82.50 82.75 83.00 83.25 83.50 83.75 84.00 84.25 84.50 84.75 85.00 85.25 85.50 85.75 86.00 86.25 86.50 86.75 87.00 87.25 87.50 87.75 88.00 88.25 88.50 88.75 89.00 89.25 89.50 89.75 90.00 90.25 90.50 90.75 91.00 91.25 91.50 91.75 92.00 92.25 4,048 4,014 3,981 3,947 3,913 3,879 3,845 3,811 3,777 3,743 3,709 3,675 3,641 3,607 3,573 3,539 3,505 3,474 3,443 3,411 3,380 3,349 3,317 3,286 3,255 3,224 3,192 3,161 3,130 3,098 3,067 3,036 3,005 2,974 2,943 2,912 2,881 2,850 2,820 2,789 2,758 2,727 2,696 26,66 2,635 2,604 2,573 2,542 2,511 2,481 2,450 2,419 2,388 2,357 2,327 2,296 2,265 2,234 2,203 2,174 2,144 2,114 2,085 2,055 11348 Yes 92.50 92.75 93.00 93.25 93.50 93.75 94.00 94.25 94.50 94.75 95.00 95.25 95.50 95.75 96.00 96.25 96.50 96.75 97.00 97.25 97.50 97.75 98.00 98.25 98.50 98.75 99.00 99.25 99.50 99.75 100.00 100.25 100.50 100.75 101.00 101.25 101.50 101.75 102.00 102.25 102.50 102.75 103.00 103.25 103.50 103.75 104.00 104.25 104.50 104.75 105.00 105.25 105.50 105.75 106.00 106.25 106.50 106.75 107.00 107.25 107.50 107.75 108.00 108.25 Tare: 67200 Type: Outage Liquid 2,025 1,996 1,966 1,936 1,907 1,877 1,847 1,818 1,789 1,761 1,734 1,706 1,678 1,651 1,623 1,595 1,568 1,540 1,513 1,485 1,457 1,430 1,402 1,378 1,354 1,329 1,305 1,281 1,256 1,232 1,208 1,184 1,159 1,135 1,111 1,086 1,062 1,038 1,014 990 966 943 919 895 872 848 825 801 781 761 741 721 701 681 661 641 621 601 582 563 544 525 506 486 108.500 108.750 109.000 109.250 109.500 109.750 110.000 110.250 110.500 110.750 111.000 111.250 111.500 111.750 112.000 112.250 112.500 112.750 113.000 113.250 113.500 113.750 114.000 114.250 114.500 114.750 115.000 115.250 115.500 115.750 116.000 116.250 116.500 116.750 117.000 117.250 117.500 117.750 118.000 118.250 118.500 118.750 119.000 119.250 119.500 119.750 120.000 120.625 467 448 429 410 393 377 362 347 331 316 300 285 270 254 239 223 208 194 182 169 156 144 131 119 106 96 88 79 71 63 54 48 43 39 34 30 26 21 17 12 9 8 6 5 4 2 1 0 46 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES Table F-4 — Tank Car Capacity Table Tank Car: Capacity Table: 0.00 0.25 0.50 0.75 1.00 1.25 1.50 1.75 2.00 2.25 2.50 2.75 3.00 3.25 3.50 3.75 4.00 4.25 4.50 4.75 5.00 5.25 5.50 5.75 6.00 6.25 6.50 6.75 7.00 7.25 7.50 7.75 8.00 8.25 8.50 8.75 9.00 9.25 9.50 9.75 10.00 10.25 10.50 10.75 11.00 11.25 11.50 11.75 12.00 12.25 GATX 40671 GAT 6895 3 8 18 30 45 61 80 100 121 144 169 194 221 248 277 307 338 370 403 436 471 506 543 580 618 656 696 736 777 819 861 904 948 992 1,037 1,083 1,129 1,176 1,223 1,272 1,320 1,369 1,419 1,470 1,521 1,572 1,624 1,677 1,730 1,783 12.50 12.75 13.00 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 15.25 15.50 15.75 16.00 16.25 16.50 16.75 17.00 17.25 17.50 17.75 18.00 18.25 18.50 18.75 19.00 19.25 19.50 19.75 20.00 20.25 20.50 20.75 21.00 21.25 21.50 21.75 22.00 22.25 22.50 22.75 23.00 23.25 23.50 23.75 24.00 24.25 24.50 24.75 Nozzle Volume: 0 Nozzle Height: 0 1,837 1,892 1,947 2,002 2,058 2,115 2,172 2,229 2,287 2,346 2,404 2,464 2,523 2,583 2,644 2,705 2,766 2,828 2,890 2,953 3,016 3,079 3,143 3,207 3,271 3,336 3,401 3,467 3,533 3,599 3,666 3,733 3,800 3,868 3,936 4,005 4,073 4,142 4,212 4,281 4,352 4,422 4,492 4,563 4,635 4,706 4,778 4,850 4,923 4,995 25.00 25.25 25.50 25.75 26.00 26.25 26.50 26.75 27.00 27.25 27.50 27.75 28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50 32.75 33.00 33.25 33.50 33.75 34.00 34.25 34.50 34.75 35.00 35.25 35.50 35.75 36.00 36.25 36.50 36.75 37.00 37.25 Stencil Volume: Nozzle Height Included? 5,068 5,142 5,215 5,289 5,363 5,438 5,512 5,587 5,663 5,738 5,814 5,890 5,966 6,043 6,119 6,196 6,273 6,351 6,429 6,506 6,585 6,663 6,742 6,820 6,900 6,979 7,058 7,138 7,218 7,298 7,378 7,459 7,540 7,621 7,702 7,783 7,865 7,946 8,028 8,110 8,193 8,275 8,358 8,440 8,523 8,607 8,690 8,773 8,857 8,941 37.50 37.75 38.00 38.25 38.50 38.75 39.00 39.25 39.50 39.75 40.00 40.25 40.50 40.75 41.00 41.25 41.50 41.75 42.00 42.25 42.50 42.75 43.00 43.25 43.50 43.75 44.00 44.25 44.50 44.75 45.00 45.25 45.50 45.75 46.00 46.25 46.50 46.75 47.00 47.25 47.50 47.75 48.00 48.25 48.50 48.75 49.00 49.25 49.50 49.75 33648 No 9,025 9,109 9,193 9,278 9,362 9,447 9,532 9,617 9,703 9,788 9,873 9,959 10,045 10,131 10,217 10,303 10,389 10,476 10,562 10,649 10,736 10,823 10,910 10,997 11,084 11,172 11,259 11,347 11,435 11,523 11,610 11,699 11,787 11,875 11,963 12,052 12,140 12,229 12,318 12,406 12,495 12,584 12,673 12,762 12,852 12,941 13,030 13,120 13,209 13,299 Tare: Type: 50.00 50.25 50.50 50.75 51.00 51.25 51.50 51.75 52.00 52.25 52.50 52.75 53.00 53.25 53.50 53.75 54.00 54.50 55.00 55.50 56.00 56.50 57.00 57.50 58.00 58.50 59.00 59.50 60.00 60.50 61.00 61.50 62.00 62.50 63.00 63.50 64.00 119.00 100800 Outage Vapor 13,388 13,478 13,568 13,658 13,748 13,838 13,928 14,018 14,108 14,198 14,288 14,378 14,469 14,559 14,650 14,740 14,830 15,012 15,193 15,374 15,556 15,737 15,919 16,100 16,282 16,464 16,646 16,828 17,010 17,191 17,373 17,555 17,737 17,918 18,100 18,281 18,463 33,653 SECTION 1 — CALCULATION OF STATIC PETROLEUM QUANTITIES, PART 2 — CALCULATION PROCEDURES FOR TANK CARS 47 Table F-5 — Tank Car Capacity Table Tank Car: ACFX 79298 Capacity Table: ACF 1769 0.00 0.25 0.50 0.75 1.00 1.25 1.50 1.75 2.00 2.25 2.50 2.75 3.00 3.25 3.50 3.75 4.00 4.25 4.50 4.75 5.00 5.25 5.50 5.75 6.00 6.25 6.50 6.75 7.00 7.25 7.50 7.75 8.00 8.25 8.50 8.75 9.00 9.25 9.50 9.75 10.00 10.25 10.50 10.75 11.00 11.25 11.50 11.75 12.00 12.25 12.50 12.75 0 3 7 11 17 23 30 37 46 55 65 75 87 99 111 124 138 153 168 184 200 218 239 263 288 316 346 377 409 442 476 510 544 579 616 653 691 730 769 809 850 890 932 973 1,015 1,058 1,100 1,144 1,188 1,233 1,279 1,325 13.00 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 15.25 15.50 15.75 16.00 16.25 16.50 16.75 17.00 17.25 17.50 17.75 18.00 18.25 18.50 18.75 19.00 19.25 19.50 19.75 20.00 20.25 20.50 20.75 21.00 21.25 21.50 21.75 22.00 22.25 22.50 22.75 23.00 23.25 23.50 23.75 24.00 24.25 24.50 24.75 25.00 25.25 25.50 25.75 1,371 1,418 1,465 1,513 1,561 1,609 1,658 1,707 1,757 1,807 1,858 1,910 1,961 2,014 2,066 2,119 2,173 2,228 2,283 2,338 2,394 2,450 2,506 2,563 2,619 2,676 2,732 2,789 2,846 2,904 2,962 3,020 3,079 3,139 3,199 3,260 3,321 3,383 3,446 3,508 3,571 3,635 3,699 3,763 3,826 3,890 3,954 4,018 4,082 4,146 4,211 4,276 26.00 26.25 26.50 26.75 27.00 27.25 27.50 27.75 28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50 32.75 33.00 33.25 33.50 33.75 34.00 34.25 34.50 34.75 35.00 35.25 35.50 35.75 36.00 36.25 36.50 36.75 37.00 37.25 37.50 37.75 38.00 38.25 38.50 38.75 Nozzle Volume: 0 Nozzle Height: 13.375 4,341 4,406 4,472 4,538 4,605 4,672 4,739 4,807 4,874 4,941 5,009 5,076 5,144 5,212 5,280 5,348 5,417 5,485 5,554 5,623 5,693 5,763 5,833 5,904 5,975 6,046 6,118 6,191 6,264 6,337 6,410 6,484 6,557 6,631 6,704 6,778 6,852 6,926 7,001 7,075 7,150 7,224 7,299 7,374 7,449 7,524 7,599 7,674 7,750 7,825 7,901 7,976 39.00 39.25 39.50 39.75 40.00 40.25 40.50 40.75 41.00 41.25 41.50 41.75 42.00 42.25 42.50 42.75 43.00 43.25 43.50 43.75 44.00 44.25 44.50 44.75 45.00 45.25 45.50 45.75 46.00 46.25 46.50 46.75 47.00 47.25 47.50 47.75 48.00 48.25 48.50 48.75 49.00 49.25 49.50 49.75 50.00 50.25 50.50 50.75 51.00 51.25 51.50 51.75 8,052 8,128 8,204 8,280 8,356 8,433 8,509 8,585 8,662 8,738 8,815 8,892 8,969 9,046 9,123 9,200 9,277 9,355 9,432 9,510 9,588 9,666 9,745 9,823 9,902 9,980 10,059 10,138 10,217 10,296 10,375 10,454 10,534 10,613 10,693 10,772 10,852 10,931 11,011 11,091 11,170 11,250 11,330 11,409 11,489 11,569 11,649 11,728 11,808 11,888 11,967 12,047 52.00 52.25 52.50 52.75 53.00 53.25 53.50 53.75 54.00 54.25 54.50 54.75 55.00 55.25 55.50 55.75 56.00 56.25 56.50 56.75 57.00 57.25 57.50 57.75 58.00 58.25 58.50 58.75 59.00 59.25 59.50 59.75 60.00 60.25 60.50 60.75 61.00 61.25 61.50 61.75 62.00 62.25 62.50 62.75 63.00 63.25 63.50 63.75 64.00 64.25 64.50 64.75 Stencil Volume: Nozzle Height Included? 12,127 12,206 12,286 12,366 12,446 12,526 12,606 12,686 12,766 12,846 12,927 13,007 13,087 13,167 13,248 13,328 13,408 13,489 13,569 13,650 13,730 13,810 13,891 13,971 14,051 14,132 14,212 14,292 14,372 14,452 14,532 14,612 14,692 14,772 14,852 14,932 15,011 15,091 15,171 15,251 15,331 15,411 15,491 15,571 15,651 15,731 15,811 15,891 15,971 16,051 16,131 16,210 65.00 65.25 65.50 65.75 66.00 66.25 66.50 66.75 67.00 67.25 67.50 67.75 68.00 68.25 68.50 68.75 69.00 69.25 69.50 69.75 70.00 70.25 70.50 70.75 71.00 71.25 71.50 71.75 72.00 72.25 72.50 72.75 73.00 73.25 73.50 73.75 74.00 74.25 74.50 74.75 75.00 75.25 75.50 75.75 76.00 76.25 76.50 76.75 77.00 77.25 77.50 77.75 16,290 16,370 16,450 16,529 16,609 16,688 16,768 16,847 16,926 17,005 17,084 17,163 17,242 17,320 17,398 17,477 17,555 17,633 17,710 17,788 17,865 17,943 18,020 18,097 18,174 18,250 18,327 18,404 18,480 18,557 18,633 18,709 18,785 18,861 18,937 19,013 19,089 19,164 19,240 19,315 19,391 19,466 19,541 19,616 19,691 19,766 19,841 19,916 19,990 20,065 20,139 20,214 26859 No 78.00 78.25 78.50 78.75 79.00 79.25 79.50 79.75 80.00 80.25 80.50 80.75 81.00 81.25 81.50 81.75 82.00 82.25 82.50 82.75 83.00 83.25 83.50 83.75 84.00 84.25 84.50 84.75 85.00 85.25 85.50 85.75 86.00 86.25 86.50 86.75 87.00 87.25 87.50 87.75 88.00 88.25 88.50 88.75 89.00 89.25 89.50 89.75 90.00 90.25 90.50 90.75 20,288 20,362 20,436 20,510 20,584 20,658 20,732 20,805 20,878 20,951 21,024 21,096 21,168 21,239 21,311 21,382 21,453 21,523 21,594 21,664 21,734 21,803 21,873 21,942 22,011 22,080 22,149 22,218 22,287 22,355 22,423 22,491 22,558 22,624 22,691 22,757 22,822 22,888 22,953 23,018 23,082 23,147 23,211 23,275 23,340 23,403 23,465 23,526 23,587 23,647 23,707 23,767 Tare: 65900 Type: Innage Liquid 91.00 91.25 91.50 91.75 92.00 92.25 92.50 92.75 93.00 93.25 93.50 93.75 94.00 94.25 94.50 94.75 95.00 95.25 95.50 95.75 96.00 96.25 96.50 96.75 97.00 97.25 97.50 97.75 98.00 98.25 98.50 98.75 99.00 99.25 99.50 99.75 100.00 100.25 100.50 100.75 101.00 101.25 101.50 101.75 102.00 102.25 102.50 102.75 103.00 103.25 103.50 103.75 23,827 23,888 23,949 24,010 24,070 24,131 24,191 24,251 24,310 24,368 24,425 24,482 24,539 24,595 24,650 24,705 24,759 24,813 24,866 24,919 24,971 25,023 25,075 25,126 25,176 25,226 25,276 25,325 25,374 25,423 25,471 25,520 25,568 25,616 25,664 25,711 25,757 25,803 25,847 25,891 25,933 25,975 26,018 26,060 26,102 26,143 26,183 26,223 26,262 26,299 26,335 26,370 104.00 104.25 104.50 104.75 105.00 105.25 105.50 105.75 106.00 106.25 106.50 106.75 107.00 107.25 107.50 107.75 108.00 108.25 108.50 108.75 26,403 26,434 26,463 26,493 26,524 26,555 26,586 26,616 26,645 26,674 26,701 26,727 26,750 26,772 26,791 26,807 26,820 26,830 26,836 26,838 48 CHAPTER 12 — CALCULATION OF PETROLEUM QUANTITIES Bibliography 1. API Manual of Petroleum Measurement Standards (MPMS) Chapter 7, Temperature Determination 2. API Manual of Petroleum Measurement Standards (MPMS) Chapter 11.1, Temperature and Pressure Volume Correction Factors for Generalized Crude Oils, Refined Products, and Lubricating Oils 3. API Manual of Petroleum Measurement Standards (MPMS) Chapter 11.5, Density / Weight / Volume Intraconversion, Part 1 — Conversions of API Gravity at 60 °F 4. API Manual of Petroleum Measurement Standards (MPMS) Chapter 11.5, Density / Weight / Volume Intraconversion, Part 2 — Conversions for Relative Density (60 / 60 °F) 5. API Manual of Petroleum Measurement Standards (MPMS) Chapter 12.1.1, Calculation of Petroleum Quantities – Upright Cylindrical Tanks and Marine Vessels 6. Std 2554 Measurement and Calibration of Tank Cars 7. GPA, 8195-952, Tentative Standard for Converting Net Vapor Space Volumes to Equivalent Liquid Volumes 8. U.S. DOT Title 49 Code of Federal Regulations (CFR) Parts 106 to 1803 9. U.S. DOT Title 49 Code of Federal Regulations (CFR) Chapter II, Part 215.201 10. AAR Manual of Standards and Recommended Practices, Section C, Part III, Specifications for Tank Cars, M100214