ChE 102 – Chemistry for Engineers – Fall 2015 University of Waterloo Instructors E. Boghaert*, P. Chen, J. Grove*, K. Hassel, R. Legge, F. Ng, G. Rempel & M. Robinson *Course coordinators Course Description and Learning Objectives This course introduces students to chemical principles with applications in engineering. Topics covered include stoichiometric calculations, properties of gases, properties of liquids and solutions, gas phase chemical equilibrium, ionic equilibrium in aqueous solution, oxidation-reduction reactions and chemical kinetics. By the end of the course students should be able to: Explain the behaviour of ideal systems (including different states of matter, physical and chemical equilibrium and reaction kinetics) in terms of the molecular nature of matter. Write balanced chemical reactions and perform stoichiometric calculations. Apply the Ideal Gas Law while appreciating the limitations of this law. Identify which principles of physical chemistry are relevant to the analysis of problems involving physical and chemical equilibrium and rates of reaction. Select and apply an appropriate law to solve problems described above and explain his/her reasoning to others in the field of chemistry and/or chemical engineering. On-Line Resources Course material can be accessed at: http:\\learn.uwaterloo.ca\. If you get a message that your account is blocked until you are “fees arranged”, then you should contact student accounts in Needles Hall. Your instructor may make use of the e-mail facility in Learn to contact you. It is your responsibility to ensure that you monitor the e-mail address linked to your account regularly. Useful information can also be found in the First Year Engineering website: http://uwaterloo.ca/engineering/current-undergraduate-students/first-year Textbook General Chemistry: Principles and Modern Applications, 10th Edition, 2010. R.H. Petrucci, F.G. Herring, J.D. Madura, and C. Bissonnette. Pearson Canada Inc., Toronto, Ontario. The previous edition (9th) is also acceptable. Second-hand copies of both new and old editions are readily available. If you purchase the textbook new from the bookstore, it will come bundled with Mastering Chemistry (a set of online problems and access to the e-textbook) and an iClicker voucher (a $10 mail-in rebate that also requires you to buy the clicker in the same transaction as the chemistry textbook); the bookstore has indicated that there is no additional charge for these beyond the regular textbook price. It is also possible to rent (note, not a permanent purchase) solely an electronic copy of the textbook at a significantly reduced price. However, you should be aware that you may not be able to return an etextbook for refund, that access is provided for a limited period only (your access will probably expire shortly after the end of term) and that you cannot later sell access to an e-textbook (while you may be able to sell a physical copy of the textbook). If you are still interested, the electronic version is available at: http://www.coursesmart.com/IR/2737759/9780135097755?__hdv=6.8 iClickers Some instructors make use of iClickers in this course. If you require an iClicker, your instructor will inform you of this on the first day of class. Course Grading Regular grading scheme: Tutorial Quizzes 5 Weekly Assignments 10 Midterm Exam 25 (multiple choice) Final Exam 60 (multiple choice) TOTAL 100 YOU MUST PASS THE COMBINED EXAMINATIONS TO PASS THE COURSE The above marking scheme will apply provided an average of at least 50% is achieved in the combined mid-term and final. If your combined average in the examinations is below 50% (i.e., you score fewer than 42.5 out of the 85 marks available for the two examinations), then you will receive that mark instead. Alternative grading scheme used if the combined examinations are failed: Tutorial Quizzes 0 Weekly Assignments 0 Midterm Exam 25 (multiple choice) Final Exam 60 (multiple choice) TOTAL 85 Examples of the grading scheme 1 2 Quizzes 100% (5/5) 90% Assignments 100% (10/10) Mid-term 80% Final 75% Total 3 4 (4.5/5) 100% (5/5) 100% (5/5) 80% (8/10) 90% (9/10) 90% (9/10) (20/25) 40% (10/25) 50% (12.5/25) 30% (7.5/20) (45/60) 30% (18/60) 50% (30/60) 50% (30/60) 80/100 40.5/100 56.5/100 51.5/100 Total in exams 20 + 45 = 65 10 + 18 = 28 12.5 + 30 = 42.5 7.5 + 30 = 37.5 Passed combined exams? (Total > 42.5) YES NO YES NO COURSE GRADE AWARDED 80/100 = 80% (PASS) 28 / 85 = 33% (FAIL) 57 / 100 = 57% (PASS) 37.5 / 85 = 44% (FAIL) 2 Tutorials Two-hour tutorials will take place every week. At the beginning of tutorial the TA will discuss common misconceptions and difficulties stemming from the previous week’s assignment and lectures. During the remainder of the tutorial you will work in small (2-3 students) groups to complete a tutorial quiz. You will submit one quiz per group and receive a grade based on completion. For a small number of tutorial sessions this term you will explore chemistry concepts through an Engineering IDEAs Clinic activity. Homework Assignments Homework assignments are designed to reinforce content covered during the weekly lectures. These assignments will be administered using Maple T.A. and can be accessed through Learn. Instructions for accessing and using Maple T.A. are posted on Learn in the “Information for All Students” section. Please note that Safari and Google Chrome are not supported browsers for Maple T.A. Assignments will typically be available on Friday and due the following Thursday. Sample solutions to the assignments will be posted on the course website the week after the assignment is completed. Examinations Examinations are multiple choice. Samples of previous examinations with correct answers will be posted on Learn for practice. Complete worked solutions to these sample exams will not be provided. During exams (both midterm and final) students are allowed to consult one letter-sized (8½” × 11”) sheet of paper, either hand- or typewritten on both sides with any information they consider relevant. Students are also allowed to use calculators (any type). No other consulting material is allowed. Locations: Exam room locations will be announced nearer the date of each exam. Practice Test: Details will be provided by the first-year office. Midterm Exam: Friday, October 23, 2015, 4:30–6:00 pm (subject to confirmation). Final Exam: To be scheduled by the Registrar’s Office during the final examination period. Sources of Help There are many sources of help available to you. Many of these are listed on the First Year Engineering website (https://uwaterloo.ca/engineering/current-undergraduate-students/first-year). We would like everyone to succeed in this course, so please don’t wait until the end of the term to seek assistance! Office hours: Your instructor and TA are available – they will let you know how and when to contact them during the first week of classes and tutorials. TA office hours and locations will be posted on Learn. Supported Learning Groups: These groups will meet regularly throughout the term. You will meet your Supported Learning Group (SLG) leader in class during your first ChE102 lecture. Nicole Francis (SLG Leader) nafrancis@uwaterloo.ca WEEF TAs: These TAs are available to assist you throughout the term and are located in E2 1309E. Stacey Oum s2oum@uwaterloo.ca Patricia Duong pp2duong@uwaterloo.ca Natalie Ehlers nsehlers@uwaterloo.ca Tutoring in residence is available to all first-year students, even those not living in residence. 3 Holidays The University will be closed on Monday October 12th for Thanksgiving Day. To make up for the missed class time, Saturday November 21st will be a class day following a Monday schedule (see https://uwaterloo.ca/quest/undergraduate-students/important-dates/important-dates-20152016). Software Engineering students: you will make up your missed tutorial session from Monday October 12th on Monday October 19th (which is during mid-term week for first-year students). Therefore there will be no tutorial session for ChE102 on Saturday November 21st. Academic Offences These will not be tolerated (See examples from UW Policy #71 which is attached). On first offence, the offence will be reported to First Year Engineering and appropriate action will be taken. If you are unsure of what constitutes an academic offense in UW after reading Policy #71, please contact your instructor. Important Information about Academic Offences Academic integrity: In order to maintain a culture of academic integrity, members of the University of Waterloo community are expected to promote honesty, trust, fairness, respect and responsibility. [Check the Office of Academic Integrity for more information.] Grievance: A student who believes that a decision affecting some aspect of his/her university life has been unfair or unreasonable may have grounds for initiating a grievance. Read Policy 70, Student Petitions and Grievances, Section 4. When in doubt, please be certain to contact the department’s administrative assistant who will provide further assistance. Discipline: A student is expected to know what constitutes academic integrity to avoid committing an academic offence, and to take responsibility for his/her actions. [Check the Office of Academic Integrity for more information.] A student who is unsure whether an action constitutes an offence, or who needs help in learning how to avoid offences (e.g., plagiarism, cheating) or about “rules” for group work/collaboration should seek guidance from the course instructor, academic advisor, or the undergraduate associate dean. For information on categories of offences and types of penalties, students should refer to Policy 71, Student Discipline. For typical penalties, check Guidelines for the Assessment of Penalties. Appeals: A decision made or penalty imposed under Policy 70, Student Petitions and Grievances (other than a petition) or Policy 71, Student Discipline may be appealed if there is a ground. A student who believes he/she has a ground for an appeal should refer to Policy 72, Student Appeals. Note for Students with Disabilities AccessAbility Services, located in the Needles Hall extension, Room 1401, collaborates with all academic departments to arrange appropriate accommodations for students with disabilities without compromising the academic integrity of the curriculum. If you require academic accommodations to lessen the impact of your disability, please register with AccessAbility Services at the beginning of each academic term. 4 Tentative Lecture Schedule and Suggested Readings from Petrucci et. al. WEEK OF September 14th September 21st September 28th October 5th October 12th October 19th October 26th November 2nd November 9th November 16th November 23rd November 30th LECTURE TOPIC SUGGESTED READINGS UNIT 1: UNIT CONVERSION AND STOICHIOMETRY Course Introduction Unit Conversions 1.3 – 1.5 Applying the Mole Concept 2.7, 2.8 & 3.1 – 3.3 Chemical Equations and Stoichiometry 4.1 & 4.2 Reactions in Solution and Limiting Reactant 4.3 & 4.4 Percent Yield 4.5 UNIT 2: GASES Gas Pressure and the Ideal Gas Law 6.1 – 6.5 Applying the Ideal Gas Law 6.1 – 6.5 Dalton’s Law 6.6 Kinetic Molecular Theory of Gases 6.7 Real Gases 6.8 & 6.9 UNIT 3: PHASES AND SOLUTIONS Phase Transitions and Vapor Pressure 12.1 – 12.3 Phase Diagrams 12.4 Solutions and Henry’s Law 13.1 – 13.5 Midterm Review MIDTERM WEEK: No lectures or tutorials for 1st year students Software engineering students will make up the missed tutorial from October 12th Raoult’s Law and Distillation 13.6 Boiling Point Elevation and Freezing Point 13.6 & 3.8 Depression Electrolyte Solutions 13.9 Osmotic Pressure 13.7 UNIT 4: CHEMICAL EQUILIBRIUM Chemical Equilibrium and Equilibrium 15.1 – 15.4 & 15.7 Constants Le Chatelier’s Principle and van ‘t Hoff 15.5, 15.6 & 19.7 Equation Solubility Constants 18.1 – 18.5 UNIT 5: ELECTROCHEMISTRY Oxidation Reduction Reactions 3.4, 5.1, 5.2, 5.4 & 5.5 Galvanic Cell and Faraday’s Law 20.1 & 20.5 Standard Cell Potential 20.2 Nernst Equation 20.2 & 20.4 Electrolysis and Equilibrium 20.3, 20.7 & 20.8 UNIT 6: CHEMICAL KINETICS Rates of Reaction 14.1 – 14.3 Integrated Rate Laws 14.3 – 14.7 Arrhenius Equation 14.8 Reaction Mechanism 14.9 & 14.10 Catalysis 14.11 Review for Final Exam Excerpts from University of Waterloo Policy #71 “Student Academic Discipline Policy” Original text available at: http://uwaterloo.ca/secretariat/policies-procedures-guidelines/policy-71 A university is a community of scholars in which knowledge is generated and disseminated through scholarship and teaching. All members of the community – faculty, students and staff – are bound to conduct themselves with honesty, integrity, fairness and concern for others. Any action which unnecessarily impedes the scholarly activities of members of the University is an offence punishable by appropriate disciplinary action. Academic offences Some of the academic offences outlined by the University include: Infringing unreasonably on the work of other members of the University community (disrupting classes or examination; harassing, intimidating or threatening others). Cheating on examinations, assignments, work term reports, or any other work used to judge student performance. Cheating includes copying from another student’s work or allowing another student to copy from one’s own work, submitting another person’s work as one’s own, fabrication of data, consultation with an unauthorized person during an examination or test, and use of unauthorized aids. Plagiarism, which is the act of presenting the ideas, words or other intellectual property of another as one’s own. The use of other people’s work must be properly acknowledged and referenced in all written material such as take-home examinations, essays, laboratory reports, work-term reports, design projects, statistical data, computer programs and research results. The properly acknowledged use of sources is an acceptable and important part of scholarship. Use of such material without complete and unambiguous acknowledgement, however, is an offence under this policy. Submitting an essay, report, or assignment when a major portion has been previously submitted or is being submitted for another course without the express permission of all instructors involved. You should also consult the course responsibilities webpage of the First Engineering Office: http://uwaterloo.ca/engineering/current-undergraduate-students/academic-support 6