WR445:Waste Water Treatment Edwin Ndibalema University of Dar es Salaam Monday : 8:00 - 9.00 HRS, Wednesday : 11:00 -13:00 HRS TEST: ? Group of 10 members - By ?. 1 Sources of wastewater? 2 Sources of Wastewater Domestic Industrial Infiltration/inflow Domestic sewage flow WASTEWATER CHARACTERISTICS TOTAL Volume (L/cap. year) Nitrogen 25,000-100,000 GREY WATER*** 25,000-100,000 2-4 kg/ca. year 5% 85% 10% Phosphorus 0.3-0.8 kg/ca. year 10%** 60% 30% Potassium 1.4 -2.0 kg/ca. year 30 kg/cap. year 34% 54% 12% 41% 12% 47% 104-106/100 ml 0* 107-109/100 ml COD Faecal Coliforms - URINE FAECES 500 50 * Health people ** can be as high as 50% *** values representative for industrialized countries Domestic sewage flow Population served No Urine Toilet washing Toilet Flushing Hand Cleansing Laundry water Kitchen Shower Total Daily flow Unit No l/c/d l/c/d l/c/d l/c/d l/c/d l/c/d l/c/d l/d Amount Remark 1.5 1 6 0.5 15 15 15 54 l/c/d Black water Grey water Black water Grey water Grey water Grey water Grey water Source (Odhiambo 2009):Technical Guide to Ecosan Promotion 1. Experience in design : roughly 50 L/c/d of wastewater 2. Rely in Per capital water consumptions (70-80% will be Wastewater) SANITATION SYSTEMS LECTURE NOTES DOMESTIC, INDUSTRIAL, INFLITRATION - PRINTING UNIT Problems with untreated wastewater -Oxygen Depletion -Aesthetics –Odour, colour, foam, solids -Eutrophication -Diseases transmission-Cholera, Typhoid etc, Wastewater Quality Parameters/components The five most important parameters to characterize pollution of wastewater are: Other Literatures • Solids • Indicators of organic matter • Nitrogen • Phosphorus • Indicators of faecal contamination • Suspended Solids •Inorganics • Organic wastes (BOD) • Nutrients •Pathogens Solids In wastewater treatment, the solids can be classified according to a) Their size and state -Suspended solids(non-filterable) -Dissolved Solids (Filterable) -Colloidal Solids b) Their chemical characteristics -Volatile Solids (Organic) -Fixed Solids (Inorganic) c) Their settleability -Settleable suspended solids -Non-settleable suspended solids Classification of Solids by size and state Source (SPERLING,2007) -Dissolved Solids with diameter < 10-3µm -Colloidal Solids with diameter between 10-3 µm and 100 µm -Suspended Solids (Particulate) with diameter > 100 µm Classification of Solids by chemical characteristics -The volatile solids represent an estimate of the organic matter in the solids -The non-volatile solids (fixed) represents the inorganic or mineral matter Volatile solids (VS) – Also called “organic solids” – That fraction of the total solids which can be burnt (volatilised) in the muffle oven at 520°C – Only the volatile solids can be broken down by anaerobic digestion – Inorganic (Fixed)(e.g. grit, sand) Total solids (TS) • = (organic solids + inorganic solids) • Measured after drying at 105°C • “Dry solids” is another word for total solids Standard Methods:2540 SOLIDS Total Solids Dried at 103 -105oC 𝑚𝑔 𝐴 − 𝐵 ∗ 1000 𝑇𝑆 ( ) = 𝐿 𝑆𝑎𝑚𝑝𝑙𝑒 𝑣𝑜𝑙𝑢𝑚𝑒 (𝐿) – Where A: Weight of dried residue +dish,g B :Weight of dish,g Volatile Solids after ignition at 550oC 𝑚𝑔 𝐴 − 𝐵 ∗ 1000 𝑉𝑆 ( ) = 𝐿 𝑆𝑎𝑚𝑝𝑙𝑒 𝑣𝑜𝑙𝑢𝑚𝑒 (𝐿) – Where A: Weight of dried residue +dish, before ignition,g B : Weight of dried residue +dish, after ignition,g Standard Methods:2540 SOLIDS Suspended Solids Dried at 103 -105oC 𝑚𝑔 𝐴 − 𝐵 ∗ 1000 𝑆𝑆 ( ) = 𝐿 𝑆𝑎𝑚𝑝𝑙𝑒 𝑣𝑜𝑙𝑢𝑚𝑒 (𝐿) – Where A: Residue on filter after drying ,g B :Total Mass of filter,g Volatile Suspended Solids after ignition at 550oC 𝑚𝑔 𝐴 − 𝐵 ∗ 1000 𝑉𝑆S ( ) = 𝐿 𝑆𝑎𝑚𝑝𝑙𝑒 𝑣𝑜𝑙𝑢𝑚𝑒 (𝐿) – Where A: Residue on filter after drying ,g at 105 oC B : Residue on filter after ignition at ,550 oC Standard Methods:2540 SEMI SOLIDS SAMPLES 𝐴 − 𝐵 ∗ 100 𝑇𝑆 (%) = 𝐶−𝐵 𝑀𝑜𝑖𝑠𝑡𝑢𝑟𝑒 % = xxxxxxx? ? 𝐴 − 𝐷 ∗ 100 𝑉𝑆 (%) = 𝐷 − 𝐵 ∗ 100 𝑉𝑆 (TS%) = 𝐶−𝐵 𝐴−𝐵 𝐷 − 𝐵 ∗ 100 𝐹𝑆 (%) = 𝐴−𝐵 – Where A: Weight of dried residue +dish,mg B :Weight of dish,mg C :Weight of wet sample+dish,mg D :Weight of residue+dish after ignition Standard Methods:2540 SEMI SOLIDS SAMPLES – Example of the Reported Results in Literature: Classification of Solids by Settleability -Settleable solids are considered those that are able to settle in period of 1 hour. -The volume of the solids accumulated in the bottom of a recipient called an Imhoff cone is measured and expressed as mL/L. – Generally,part of the solids can be separated from the liquid phase by gravity settling – As rough guideline it can be expected that about 1/3 of the solids in raw-sewage are particulate and can settle,1/3 are partculate but do not settle and 1/3 of the solids are dissolved in the water – -Approximate measure of the quantity that will be removed by primary sedimentation