Name:______________________________Class: _________________ Date: _________________ Assessment Chapter Test B Teacher Notes and Answers 7 Chemical Formulas and Chemical Compounds TEST B 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. c d d a d d c b +6 1 +2 +4 SiO2 CI4 Sn(CrO4)2 Ba(OH)2 phosphorus(III) iodide dinitrogen tetroxide iron(II) nitrite carbon tetrachloride carbon monoxide copper(II) carbonate CaCl2, calcium chloride PbCrO4, lead(II) chromate Al2(SO4)3, aluminum sulfate Sn3(PO4)4, tin(IV) phosphate cyanide ion oxide ion hydroxide ion S2 Cu+ CO 32 H, +1; O, 1 C, +4; O, 2 N, 3; H, +1 323.5 g/mol 134.45 amu 47.27% Cu, 52.73% Cl 43.2 g CF4 C4H10 C2H6 Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 1 Chapter Test Name:______________________________Class: _________________ Date: _________________ Assessment Chapter Test B Chapter: Chemical Formulas and Chemical Compounds PART I In the space provided, write the letter of the term or phrase that best completes each statement or best answers each question. _____ 1. Changing a subscript in a correctly written chemical formula will a. change the electron configuration of that element. b. change the charges on the other ions in the compound. c. change the formula so that it no longer represents the same compound. d. have no effect on the formula. _____ 2. Using the Stock system of nomenclature, Cr2(SO4)3 is named a. chromium(II) sulfate. b. chromic sulfate. c. dichromium trisulfate. d. chromium(III) sulfate. _____ 3. In a polyatomic ion, the algebraic sum of the oxidation numbers of all atoms is equal to a. 0. b. 10. c. the number of atoms in the ion. d. the charge on the ion. _____ 4. The first part of the name of a binary ionic compound is the a. cation. b. polyatomic ion. c. oxyanion. d. anion. _____ 5. The empirical formula may not represent the actual composition of a(n) a. ionic compound. b. crystal. c. salt. d. molecular compound. _____ 6. The formula for phosphoric acid is a. HPO4. b. H(PO4)2. c. H2PO3. d. H3PO4. Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 2 Chapter Test Name:______________________________Class: _________________ Date: _________________ Chapter Test B, continued _____ 7. The term formula mass can be applied to both ionic compounds and molecular compounds because a. ionic compounds exist as individual molecules. b. not all molecular formulas are empirical formulas. c. not all formulas represent individual molecules. d. all molecular formulas are Lewis formulas. _____ 8. To determine the correct molecular formula of a compound from an empirical formula, one must determine the a. density. b. formula mass. c. structural formula. d. crystal lattice. PART II Write the oxidation number for the given element in the space provided. 9. Sulfur in H2SO4 ____________________ 10. Oxygen in peroxides ____________________ 11. Magnesium in MgO ____________________ 12. Silicon in SiCl4 ____________________ Write the formulas for the following compounds in the space provided. 13. Silicon dioxide _____________________ 14. Carbon tetriodide _____________________ 15. Tin(IV) chromate _____________________ 16. Barium hydroxide _____________________ Write the names of the following compounds in the space provided. Use the Stock system or prefixes, as indicated. 17. PI3, Stock system ____________________________ 18. N2O4, prefixes ____________________________ 19. Fe(NO2)2, Stock system ____________________________ 20. CCl4, prefixes ____________________________ Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 3 Chapter Test Name:______________________________Class: _________________ Date: _________________ Chapter Test B, continued 21. CO, prefixes ____________________________ 22. CuCO3, Stock system ____________________________ Write the formulas and give the names of the compounds formed by the following ions in the space provided. 2+ 23. Ca 2+ 24. Pb 3+ 25. Al 4+ 26. Sn and Cl ____________________________________ 2 and CrO 4 ____________________________________ and SO 24 ____________________________________ and PO 34 ____________________________________ Name each of the following ions in the space provided. 27. CN 28. O 2 29. OH ____________________________ ____________________________ ____________________________ Write the formulas and indicate the charges for the following ions in the space provided. 30. sulfide ion ___________________ 31. copper(I) ion ___________________ 32. carbonate ion ___________________ Write each atom and its oxidation number in the space provided. 33. H2O2 ___________________________ 34. ___________________________ 35. CO 32 NH +4 ___________________________ Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 4 Chapter Test Name:______________________________Class: _________________ Date: _________________ Chapter Test B, continued PART III Use the table of atomic masses to answer the following questions. Write your answer on the line to the left, and show your work in the space provided. Element Symbol Atomic mass Element Symbol Atomic mass Aluminum Al 26.98 u Lead Pb Bromine Br 79.90 u Li Carbon C 12.01 u Mg 24.30 u Chlorine Cl 35.45 u Lithium Magnesiu m Manganes e Mn 54.94 u Chromium Cr 52.00 u Nitrogen N 14.01 u Copper Cu 63.55 u Oxygen O 16.00 u Fluorine Hydrogen F H 19.00 u 1.01 u Sodium Sulfur Na S 22.99 u 32.07 u 207.2 u 6.94 u 36. ________________ What is the molar mass of tetraethyl lead, Pb(C2H5)4? 37. ________________ What is the formula mass of copper(II) chloride, CuCl2? 38. ________________ What is the percentage composition of CuCl2 by mass? 39. ________________ What is the mass of 0.240 mol glucose, C6H12O6? 40. ________________ What is the empirical formula for a sample of a compound that contains 259.2 g F and 40.8 g C? Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 5 Chapter Test Name:______________________________Class: _________________ Date: _________________ Chapter Test B, continued 41. ________________ The empirical formula for a compound is C2H5 and its formula mass is 58 u. What is its molecular formula? 42. ________________ A sample of a compound is 80% carbon and 20% hydrogen by mass. Its formula mass is 30 u. What is its molecular formula? Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 6 Chapter Test Name:______________________________Class: _________________ Date: _________________ CHAPTER 7 REVIEW Chemical Formulas and Chemical Compounds Teacher Notes and Answers SHORT ANSWER 1. a. b. c. d. e. 2. a. b. c. d. e. CuCO3 Na2SO3 (NH4)3PO4 SnS2 HNO2 magnesium perchlorate iron(II) nitrate iron(III) nitrite cobalt(II) oxide nitrogen(V) oxide Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 1 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ CHAPTER 7 REVIEW Chemical Formulas and Chemical Compounds MIXED REVIEW SHORT ANSWER Answer the following questions in the space provided. 1. Write formulas for the following compounds: __________________ a. copper(II) carbonate __________________ b. sodium sulfite __________________ c. ammonium phosphate __________________ d. tin(IV) sulfide __________________ e. nitrous acid 2. Write the Stock system names for the following compounds: __________________________ a. Mg(ClO4)2 __________________________ b. Fe(NO3)2 __________________________ c. Fe(NO2)3 __________________________ d. CoO __________________________ e. dinitrogen pentoxide 3. ___________________ a. How many atoms are represented by the formula Ca(HSO4)2? __________________ b. How many moles of oxygen atoms are in a 0.50 mol sample of this compound? __________________ c. Assign the oxidation number to sulfur in the HSO 4 anion. 4. Assign the oxidation number to the element specified in each of the following: _______ a. hydrogen in H2O2 _______ b. hydrogen in MgH2 _______ c. sulfur in S8 _______ d. carbon in (CO3)2 _______ e. chromium in Na2Cr2O7 _______ f. nitrogen in NO2 Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 2 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ MIXED REVIEW continued PROBLEMS Write the answer on the line to the left. Show all your work in the space provided. 5. ___________________ Following are samples of four different compounds. Arrange them in order of increasing mass, from smallest to largest. a. 25 g of oxygen gas c. 3 1023 molecules of C2H6 b. 1.00 mol of H2O d. 2 1023 molecules of C2H6O2 6. ___________________ a. What is the formula for sodium hydroxide? __________________ b. What is the formula mass of sodium hydroxide? __________________ c. What is the mass in grams of 0.25 mol of sodium hydroxide? 7. ___________________ What is the percentage composition of ethane gas, C2H6, to the nearest whole number? 8. __________________ Ribose is an important sugar (part of RNA),with a molar mass of 150.15 g/mol. If its empirical formula is CH2O, what is its molecular formula? Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 3 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ MIXED REVIEW continued 9. Butane gas, C4H10, is often used as a fuel. __________________ a. What is the mass in grams of 3.00 mol of butane? __________________ b. How many molecules are present in that 3.00 mol sample? __________________ c. What is the empirical formula of the gas? 10. __________________ Naphthalene is a soft covalent solid that is often used in mothballs. Its molar mass is 128.18 g/mol and it contains 93.75% carbon and 6.25% hydrogen. Determine the molecular formula of napthalene from this information. 11. Nicotine has the formula CxHyNz. To determine its composition, a sample is burned in excess oxygen, producing the following results: 1.0 mol of CO2 0.70 mol of H2O 0.20 mol of NO2 Assume that all the atoms in nicotine are present as products. __________________ a. Determine the number of moles of carbon present in the products of this combustion. Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 4 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ MIXED REVIEW continued __________________ b. Determine the number of moles of hydrogen present in the combustion products. __________________ c. Determine the number of moles of nitrogen present in the combustion products. __________________ d. Determine the empirical formula of nicotine based on your calculations. __________________ e. In a separate experiment, the molar mass of nicotine is found to be somewhere between 150 and 180 g/mol. Calculate the molar mass of nicotine to the nearest gram. 12. When MgCO3(s) is strongly heated, it produces solid MgO as gaseous CO2 is driven off. __________________________ a. What is the percentage loss in mass as this reaction occurs? __________________________ b. Assign the oxidation number to each atom in MgCO3. __________________________ c. Does the oxidation number of carbon change upon the formation of CO2? Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 5 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ CHAPTER 7 REVIEW Chemical Formulas and Chemical Compounds Teacher Notes and Answers SECTION 2 Chapter 7 SECTION 1 SHORT ANSWER 1. a. +4 b. +6 c. 2 d. +1 e. +6 f. +5 g. +4 h. 3 2. a. SCl2 b. nitrogen(IV) oxide 3. a. fluorine b. 0; F2 4. a. tin(IV) oxide b. SnO 5. a. NO, NO2 b. ClO 6. a. N2O3 b. +3 c. The three oxygen atoms have oxidation states of 6 total, and because the algebraic sum of the oxidation states in a neutral compound must be zero, the two nitrogen atoms must have oxidation states of +6 total, therefore +3 each. nitrogen(III) oxide 7. a. Carbon is +4 and each oxygen is 2. b. Carbon is 4 and each hydrogen is +1. c. Each carbon is 0, each hydrogen is +1, and each oxygen is 2. d. Each carbon is 8/3 and each hydrogen is +1. 8. a. Each iron is +3 and each oxygen is 2. b. Nitrogen is +4 and each oxygen is 2. c. Chromium is +4 and each oxygen is 2. SHORT ANSWER 1. c 2. c 3. a. 4 elements b. 6 oxygen atoms c. 21 atoms d. 4.2 1024 atoms 4. a. 11 atoms b. 45 atoms c. 10 atoms d. 9 atoms 5. a. N2O5 b. iron(II) oxide c. H2SO3 d. phosphoric acid 6. a. True b. True 7. a. In general, if the anion name ends in ate, the corresponding acid name will end in a suffix of -ic. In general, if the anion name ends in -ite, the corresponding acid name will end in a suffix of -ous. b. In general, if the anion name ends in ide, the corresponding acid name will end in a suffix of -ic and begin with a prefix of hydro-. The prefix hydro- is never used for anions ending in -ate or -ite. 8. Compound name Formula Aluminum sulfide Al2S3 Cesium carbonate Cs2CO3 Lead(II) chloride PbCl2 Ammonium phosphate (NH4)3PO4 Hydroiodic acid HI Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 1 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ SECTION 3 2. C4H8 3. a. Na2S2O3 b. neither 4. a. 36% b. 5 c. The second heating is to ensure that all the water in the sample has been driven off. If the mass is less after the second heating, water was still present after the first heating. 5. a. CF2 b. C4F8 6. a. CuClO3 b. copper(I) chlorate SHORT ANSWER 1. a. True b. False c. True 2. 10 mol of calcium, 20 mol of nitrogen, 60 mol of oxygen 3. a. 0.250 mol b. 1.50 1023 molecules c. 4.51 1023 carbon atoms d. 10.1% 4. a. 52.9% b. 2100 lb 5. a. 20 g b. 0.17 mol c. 4.0 mol SECTION 4 SHORT ANSWER 1. a. CH3O2 b. N2O5 c. HgCl d. CH2 Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 2 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ CHAPTER 7 REVIEW Chemical Formulas and Chemical Compounds SECTION 1 SHORT ANSWER Answer the following questions in the space provided. 1. _____ In a Stock system name such as iron(III) sulfate, the Roman numeral tells us (a) how many atoms of Fe are in one formula unit. (b) how many sulfate ions can be attached to the iron atom. (c) the charge on each Fe ion. (d) the total positive charge of the formula unit. 2. _____ Changing a subscript in a correctly written chemical formula (a) changes the number of moles represented by the formula. (b) changes the charges on the other ions in the compound. (c) changes the formula so that it no longer represents the compound it previously represented. (d) has no effect on the formula. 3. The explosive TNT has the molecular formula C7H5(NO2)3. __________________ a. How many elements make up this compound? __________________ b. How many oxygen atoms are present in one molecule of C7H5(NO2)3? __________________ c. How many atoms in total are present in one molecule of C7H5(NO2)3? __________________ d. How many atoms are present in a sample of 2.0 1023 molecules of C7H5(NO2)3? 4. How many atoms are present in each of these formula units? __________________ a. Ca(HCO3)2 __________________ b. C12H22O11 __________________ c. Fe(ClO2)3 __________________ d. Fe(ClO3)2 5. ___________________ a. What is the formula for the compound dinitrogen pentoxide? __________________ b. What is the Stock system name for the compound FeO? __________________ c. What is the formula for sulfurous acid? __________________ d. What is the name for the acid H3PO4? Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 2 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ SECTION 1 continued 6. Some binary compounds are ionic, others are covalent. The type of bond favored partially depends on the position of the elements in the periodic table. Label each of these claims as True or False; if False, specify the nature of the error. a. Covalently bonded binary molecular compounds are typically composed of nonmetals. _______________________________________________________________ _______________________________________________________________ b. Binary ionic compounds are composed of metals and nonmetals, typically from opposite sides of the periodic table. _______________________________________________________________ _______________________________________________________________ 7. Refer to the text for examples of names and formulas for polyatomic ions and acids. a. Derive a generalization for determining whether an acid name will end in the suffix -ic or -ous. _______________________________________________________________ _______________________________________________________________ _______________________________________________________________ b. Derive a generalization for determining whether an acid name will begin with the prefix hydro- or not. _______________________________________________________________ _______________________________________________________________ _______________________________________________________________ 8. Fill in the blanks in the table below. Compound name Formula Aluminum sulfide Cesium carbonate PbCl2 (NH4)3PO4 Hydroiodic acid Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 3 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ CHAPTER 7 REVIEW Chemical Formulas and Chemical Compounds SECTION 2 SHORT ANSWER Answer the following questions in the space provided. 1. Assign the oxidation number to the specified element in each of the following examples: _______ a. S in H2SO3 _______ b. S in MgSO4 _______ c. S in K2S _______ d. Cu in Cu2S _______ e. Cr in Na2CrO4 _______ f. N in HNO3 _______ g. C in (HCO3) _______ h. N in (NH4)+ 2. ___________________ a. What is the formula for the compound sulfur(II) chloride? __________________ b. What is the Stock system name for NO2? 3. ___________________ a. Use electronegativity values to determine the one element that always has a negative oxidation number when it appears in any binary compound. __________________ b. What is the oxidation number and formula for the element described in part a when it exists as a pure element? 4. Tin has possible oxidation numbers of +2 and +4 and forms two known oxides. One of them has the formula SnO2. __________________ a. Give the Stock system name for SnO2. __________________ b. Give the formula for the other oxide of tin. 5. Scientists think that two separate reactions contribute to the depletion of the ozone, O3, layer. The first reaction involves oxides of nitrogen. The second involves free chlorine atoms. The equations that represent the reactions follow. When a compound is not stated as a formula, write the correct formula in the blank beside its name. a. ______ (nitrogen monoxide) + O3 ______ (nitrogen dioxide) + O2 Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 4 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ SECTION 2 continued b. Cl + O3 ______ (chlorine monoxide) + O2 6. Consider the covalent compound dinitrogen trioxide when answering the following: __________________ a. What is the formula for dinitrogen trioxide? __________________ b. What is the oxidation number assigned to each nitrogen atom in this compound? Explain your answer. _______________________________________________________________ _______________________________________________________________ _______________________________________________________________ _________________ c. Give the Stock name for dinitrogen trioxide. 7. The oxidation numbers assigned to the atoms in some organic compounds have unexpected values. Assign oxidation numbers to each atom in the following compounds: (Note: Some oxidation numbers may not be whole numbers.) a. CO2 _______________________________________________________________ b. CH4 (methane) _______________________________________________________________ c. C6H12O6 (glucose) _______________________________________________________________ d. C3H8 (propane gas) _______________________________________________________________ 8. Assign oxidation numbers to each element in the compounds found in the following situations: a. Rust, Fe2O3, forms on an old nail. _______________________________________________________________ b. Nitrogen dioxide, NO2, pollutes the air as a component of smog. _______________________________________________________________ c. Chromium dioxide, CrO2, is used to make recording tapes. _______________________________________________________________ Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 5 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ CHAPTER 7 REVIEW Chemical Formulas and Chemical Compounds SECTION 3 SHORT ANSWER Answer the following questions in the space provided. 1. Label each of the following statements as True or False: __________________ a. If the formula mass of one molecule is x u, the molar mass is x g/mol. __________________ b. Samples of equal numbers of moles of two different chemicals must have equal masses as well. __________________ c. Samples of equal numbers of moles of two different molecular compounds must have equal numbers of molecules as well. 2. How many moles of each element are present in a 10.0 mol sample of Ca(NO3)2? _______________________________________________________________ PROBLEMS Write the answer on the line to the left. Show all your work in the space provided. 3. Consider a sample of 10.0 g of the gaseous hydrocarbon C3H4 to answer the following questions. __________________________ a. How many moles are present in this sample? __________________________ b. How many molecules are present in the C3H4 sample? __________________________ c. How many carbon atoms are present in this sample? Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 6 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ SECTION 3 continued __________________ d. What is the percentage composition of hydrogen in the sample? 4. One source of aluminum metal is alumina, Al2O3. __________________ a. Determine the percentage composition of Al in alumina. __________________ b. How many pounds of aluminum can be extracted from 2.0 tons of alumina.? 5. Compound A has a molar mass of 20 g/mol, and compound B has a molar mass of 30 g/mol. __________________ a. What is the mass of 1.0 mol of compound A, in grams? __________________ b. How many moles are present in 5.0 g of compound B? __________________ c. How many moles of compound B are needed to have the same mass as 6.0 mol of compound A? Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 7 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ CHAPTER 7 REVIEW Chemical Formulas and Chemical Compounds SECTION 4 SHORT ANSWER Answer the following questions in the space provided. 1. Write empirical formulas to match the following molecular formulas: __________________ a. C2H6O4 __________________ b. N2O5 __________________ c. Hg2Cl2 __________________ d. C6H12 2. ___________________ A certain hydrocarbon has an empirical formula of CH2 and a molar mass of 56.12 g/mol. What is its molecular formula? 3. A certain ionic compound is found to contain 0.012 mol of sodium, 0.012 mol of sulfur, and 0.018 mol of oxygen. __________________ a. What is its empirical formula? __________________ b. Is this compound a sulfate, sulfite, or neither? PROBLEMS Write the answer on the line to the left. Show all your work in the space provided. 4. Water of hydration was discussed in Sample Problem K in Section 4 of the text. Strong heating will drive off the water as a vapor in hydrated copper(II) sulfate. Use the data table below to answer the following: Mass of the empty crucible Mass of the crucible plus hydrate sample 4.00 g 4.50 g Mass of the system after heating 4.32 g Mass of the system after a second heating 4.32 g __________________ a. Determine the mass percentage of water in the original sample. Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 8 Chemical Bonding Name:______________________________Class: _________________ Date: _________________ SECTION 4 continued __________________ b. The compound has the formula CuSO4 • xH2O. Determine the value of x. c. What might be the purpose of the second heating? _______________________________________________________________ _______________________________________________________________ _______________________________________________________________ _______________________________________________________________ 5. Gas X is found to be 24.0% carbon and 76.0% fluorine by mass. __________________ a. Determine the empirical formula of gas X. __________________ b. Given that the molar mass of gas X is 200.04 g/mol, determine its molecular formula. 6. A compound is found to contain 43.2% copper, 24.1% chlorine, and 32.7% oxygen by mass. __________________ a. Determine its empirical formula. b. What is the correct Stock system name of the compound in part a? _______________________________________________________________ Original content Copyright © by Holt, Rinehart and Winston. Additions and changes to the original content are the responsibility of the instructor. Modern Chemistry 9 Chemical Bonding