X
PsoIn
=
p020
·
+20
Mole fraction
Vapor
XH20
=
pson=aStorr
pressure
1
=
.X solute 1-X solvent
1/
=
=
=
0.1765 1
=
-
0.8235
I
NaCl mole fraction
=
NaCl
=
0.1765/2
NaCl
=
0.08825
Molarity
11
=
mass
75
atm
moles
of
=
of
solute/2
0.0245 atm
=
#
0.0245
m
at
- >
(0.0821)(z5 213)
1.00 x
10-3 mol/L
=
of
protein
103g/mo1
x
=
=
massofproteinone
1.00
0.159
=
x
10-3 mol/L
volume
sortion
of
0.002
*
1
r
x
p
solvent
71.9
x
pressure
450c 59.2096
ions.
+
Molarity
molar
=
450 3
torr
0.8235
NaCI will produce
x
0.825
=
59.209G torr
Vapor
18.6 tour
solution
of
the solvent at
=X solvent
11
X solute
+
solvent
in
=0.3 is
Psoin
X
of
water
the solution
of
torr
at
mole fraction
XA XB
+
1
XB
X
=
1
B
-
-
=
XB
toluene
of
in
the
solution
1
=
mole fraction of
toluene
XA
enns
rnapor-
0.590
0.410
=
P=
XAP10
T
=
XBPB
+
(0.590)((s) (0.410)(2a0)
+
439.55
=
PT 558.45
=
118.9
+
torr
Partial pressure oftoluene
PB xBPB0
=
PB (0.410)(za0)
=
PB
118.9 torr
=
mass
4.5 mol of
of
Cack=
4.5(1) 499.5
=
density 1.37 g/mL
=
Assume
mass
mass
1000mL
Volume 1 =
=
of
solution 1000
=
percent
=
(1.37) 1370
=
hags) (100)
36.459%
=
in the vapor
0.23
=
-aterCF
re
82.26,10-3
=
cen
0.90
Rate
k
2.5393
(0907"
[A]
afe., 7.90e
k
=
=
=
0.0118675
=
1.19
=
2.5393
10g
10g
2.53334
=
2.5393
10925333"
=
2.5393 n
=
n
log
2.5333
11092.63he
=
Rate Law k
=
-
=
(N20s]'
1
or
k[NzOs]
x
10
-
25 +
1
rates
Later clo
e
3
on
-
=
atez
=
k
-30y!T .or
n
*
OSO
=
4 27
0.5
=
log
4
log4
n
n
10g2
0s00]m
n
log
=575x10-wast
=
=
4
230m
2.30
=
=
rate
en-j,
=
=
0.5
2
1094
=
2
=
log
0.5
log
0.5
m
m
-
25
0.5m
10g
m
=
0.5m
10g
0.5
9.0.S
=
1
=
[C102] [on -]
Rate k
=
k
102
2.30 x
=
[C102]0
[01
-
M
0.15
=
-
25
-
1
mol/L
10 0.0844mB/L
=
Rate
k[z] [B]'
230(0.175)2(0.0842)
230(0.030625)(0.004n)
=
=
=
=
0.5974925M.5-
=
5.9x10
=
-
M.S-1
1
1
x102M 25
=
=
-
-
-
1
71yz
+112
=
0043554
=
=
=
+
tyz
27]0
2693
112
160s <1half-life
100.0
=
[A] 100.0
90.0 10.0
-
=
=
In(+000) (0.004335-)
2
=
+
160sx
z
=
320s<
=
2nd Half-life
+
(0.004335 1) +
t 0.530357 532sfor
-
2.303
=
=
=
90%completion
Rate
1
N0z
Ea
k[NOz]
law:
+
167
=
sE + 28
=
xz
yz
+
2xy
-
-
ICOz
kJ/mo)
kJ/mol
2xy
xz yz
+
->
1N0 + 1CO2
(EA)
decomposition
of
xy EA
=
=
167
-
-
sE
28
139k5/mo)
=
Later Corzy
e
-4 10.10
-40x10
a
=
17
2
log
n
=
e
u9
=
e
-rates Cchzs
3
x 10
1
-
5.40
x
10
-
4
m
Ozo
=
2 1m
=
log
z
logz
m
10g /m
=
m
=
log
09,2
=
m 2
=
|
I
is
explain data.
"
=
logz
[pN+] [(H3I]z
=
*
Mechanism
to
=
log2 1091
rate
a
possible
mechanism