10/13/2022 B.TECH FIRST YEAR ACADEMIC YEAR: 2020-2021 SESSION OUTCOME COURSE NAME: ENGINEERING PHYSICS COURSE CODE “UNDERSTAND THE BASIC PRINCIPLES OF WAVE OPTICS” : PY1001 LECTURE SERIES NO : 01 (ONE) CREDITS : 4 MODE OF DELIVERY : ONLINE (POWER POINT PRESENTATION) FACULTY : DR. NILANJAN HALDER EMAIL-ID : nilanjan.halder@jaipur.manipal.edu DATE OF DELIVERY: 10 October 2021 1 2 Diffraction Topics ASSIGNMENT QUIZ MID TERM EXAMINATION –I END TERM EXAMINATION ASSESSMENT CRITERIA’S 3 4 Diffraction and wave theory of light Single-slit diffraction Intensity in single-slit diffraction Diffraction at a circular aperture Double-slit interference and diffraction combined Multiple slits Diffraction gratings Dispersion and resolving power X-ray diffraction Text Book: PHYSICS VOL 2 by Halliday, Resnick and Krane 10/13/2022 DIFFRACTION AND INTERFERENCE Diffraction v/s Interference Both involve superposition of coherent light waves. Diffraction and interference are similar phenomena. Interference is the effect of superposition of 2 coherent waves. Here Slit width a<<λ very small and neglected. So, fringes are of equal width and intensity on the screen is of uniform distribution. Bending of light around the obstacle. The interfering beam originate from continuous distribution of sources (Huygens’ principle). The waves emerging from different paths of the same wave front superimpose with each other to produce Diffraction pattern. The width of the diffraction fringes are not equal. Minimum intensity point will not be perfectly dark Bright fringes in the diffraction pattern are not of same intensity. Diffraction is the superposition of many coherent waves. Slit width ‘a’ is finite. Intensity on the screen is non-uniform. 5 6 DIFFRACTION AND WAVE THEORY OF LIGHT DIFFRACTION AND WAVE THEORY OF LIGHT • The phenomenon of bending of light around the edges of obstacles or slits, and hence its encroachment into the region of geometrical shadow is known as diffraction. For diffraction effects to be noticeable, the size of the object causing diffraction should have dimensions comparable to the wavelength of light falling on the object. • Diffraction pattern of razor blade viewed in monochromatic light 7 Meeting of two waves. The interfering beam originate from discrete number of sources. The superposition of waves coming from two different wave front originating from the same source, produce Interference pattern. The width of the interference fringes may/ may not be equal. Minimum intensity point will be perfectly dark. Bright fringes in the interference pattern are of uniform intensity. 8 Diffraction pattern occurs when coherent wave-fronts of light fall on opaque barrier B, which contains an aperture of arbitrary shape. The diffraction pattern can be seen on screen C. When C is very close to B a geometric shadow is observed because the diffraction effects are negligible. 10/13/2022 Huygens’ Principle DIFFRACTION AND WAVE THEORY OF LIGHT Ꙫ A single slit placed between a distant light source and a screen produces a diffraction pattern. Ꙫ It will have a broad, intense central band called the central maximum Ꙫ The central band will be flanked by a series of narrower, less intense secondary bands called side maxima or secondary maxima Ꙫ The central band will also be bordered by a series of dark bands called minima. Ꙫ The diffraction pattern consists of the central maximum and a series of secondary maxima and minima. Ꙫ The pattern is similar to an interference pattern as shown in figure. 9 • Every point on a propagating wavefront serves as the source of spherical wavelets, such that the wavelets at sometime later is the envelope of these wavelets. • If a propagating wave has a particular frequency and speed, the secondary wavelets have that same frequency and speed. The phenomenon of diffraction is caused by the interference of innumerable secondary wavelets that are produced by unobstructed portions of the same wave front or from the portions of the wave front which are allowed to pass through a aperture. 10 Fresnel diffraction & Fraunhofer diffraction Diffraction patterns are usually classified into two categories depending on the source and screen are placed. DIFFRACTION AND WAVE THEORY OF LIGHT The pattern formed on the screen depends on the separation between the screen C and the aperture B. Let us consider the following three cases. Case 1: Very small separation: when screen C is very close to B. Fresnel diffraction: When either the source or the screen is near the aperture or obstruction, the wavefronts are spherical and the pattern is quite complex. (near-field) Aperture From distant source Fraunhofer diffraction: When both the source and the screen are at a great distance from the aperture or obstruction, the incident light is in the form of plane wave and the pattern is simpler to analyze. (far-field) 11 “Isotropic” Screen Geometrical shadow of the aperture B C The waves travel only a short distance after leaving the aperture, and the rays diverge very little. The effects diffraction are negligible, and the pattern on the screen is the geometric shadow of the aperture. 12 10/13/2022 Case 2: Very large separation: When screen C is far from the aperture (Fraunhofer diffraction). Plane wave front Plane wave front f f Very large separation C Very large separation When the screen is so far from the aperture, then we can regard the rays as parallel or wavefronts as planes. In this case , we also assume the source to be far from the aperture, so that the incident wavefronts are also planes. This is one way of achieving Fraunhofer diffraction. 13 In the laboratory, two converging lenses are used to achieve this condition. The first lens converts the diverging light from the source in to a plane wave, and the second lens focuses plane waves leaving the aperture parallel to the point on screen. 14 Case 3: Intermediate separation: When screen C and source (S) are at finite distances from the aperture (Fresnel diffraction): Plane wave front Plane wave front Spherical wave front Spherical wave front P Source (S) Very large separation Finite distance B Finite distance C In Fresnel diffraction: 1. the incident and the diffracted wave fronts are spherical. 2. The source and the screen are at finite distances from the aperture/slit or obstacle causing diffraction. 3. No lenses/ mirrors are used. 15 Very large separation C In Fraunhofer type of diffraction: 1. Both the source and the screen are effectively at infinite distances, from the aperture causing diffraction. 2. both the incident and emergent wavefronts are plane. That is, both the incident and the diffracted beams are parallel. 3. can be realized in practice by using a pair of converging lenses of suitable focal lengths (L1 and L2) and placing the source and the screen at the foci of L1 and L2 respectively. 16 10/13/2022 SINGLE-SLIT DIFFRACTION Fraunhofer diffraction is a special (limiting) case of the more general Fresnel diffraction. But, analysis of Fresnel diffraction is complicated compared to Fraunhofer. That is, Fraunhofer diffraction is easier to handle mathematically. So, in our study on diffraction phenomenon, we deal only with Fraunhofer diffraction. 17 All the diffracted rays arriving at P0 are in-phase. Hence they interfere constructively and produce maximum (central maximum) of intensity I0 at P0. 18 SINGLE-SLIT DIFFRACTION SINGLE-SLIT DIFFRACTION At point P1, path difference between r1 and r2 is (a/2) sin ⁕The finite width of slits is the basis for understanding Fraunhofer diffraction. ⁕According to Huygens’s principle, each portion of the slit acts as a source of light waves. ⁕Therefore, light from one portion of the slit can interfere with light from another portion. ⁕The diffraction pattern is actually an interference pattern. ⁕The different sources of light are different portions of the single slit. 19 So the condition for first minimum, a sin 2 2 or a sin This is satisfied for every pair of rays, one of which is from upper half of the slit and the other is a corresponding ray from lower half of the slit. 20 10/13/2022 SINGLE-SLIT DIFFRACTION SINGLE-SLIT DIFFRACTION Problem: 1 At point P2, path difference between A slit of width a is illuminated by white light. For what value of a does the minimum for red light ( = 650nm) fall at = 15o? r1 and r2 is (a/4) sin So the condition for second minimum, a sin or a sin 2 4 2 This is satisfied for every pair of rays, separated by a distance a/4. In general, the condition for m TH minima, a sin m m 1, 2, 3, . . . There is a secondary maximum approximately half way between each adjacent pair of minima. 21 22 SINGLE-SLIT DIFFRACTION SINGLE-SLIT DIFFRACTION Problem: E42-5 Problem: 2 In P-1, what is the wavelength ’ of the light whose first diffraction maximum (not counting the central maximum) falls at 15o, thus coinciding with the first minimum of red light? 23 A single slit is illuminated by light whose wavelengths are a and b, so chosen that the first diffraction minimum of a component coincides with the second minimum of the b component. (a) What is the relationship between the two wavelengths? (b) Do any other minima in the two patterns coincide? 24 10/13/2022 INTENSITY IN SINGLE – SLIT DIFFRACTION INTENSITY IN SINGLE – SLIT DIFFRACTION • Aim is to find an expression for the intensity of the entire pattern as a function of the diffraction angle. Phasor showing • The phase difference between two waves arriving at point P a) Central maximum from two points on the slit (with separation x) is, b) A direction slightly shifted 2 x sin from central maximum c) First minimum d) First maximum beyond the central maximum (corresponds to N = 18) 25 26 INTENSITY IN SINGLE – SLIT DIFFRACTION From diagram, E 2 R sin is the phase difference 2 Em Also R Combining, E E m sin 2 2 sin Or , E E m where 27 INTENSITY IN SINGLE – SLIT DIFFRACTION between rays from the top and bottom of the slit. So we can write, 2 a sin a So, sin 2 2 28 10/13/2022 INTENSITY IN SINGLE – SLIT DIFFRACTION The intensity E 2 sin E m2 INTENSITY IN SINGLE – SLIT DIFFRACTION 2 2 sin 2 m where m E m is the max. intensity From the above eqn., for minima, sin 0 m where m 1, 2, 3,..... or, a sin m where m 1, 2, 3,..... The intensity distribution in single-slit diffraction for three different values of the ratio a/ 29 30 Position of dark fringes in single-slit diffraction sin Width of central maximum •We can define the width of the central maximum to be the distance between the m = +1 minimum and the m=-1 minimum: m a y If, like the Young’s 2-slit treatment we assume small angles, sin ≈ tan =ymin/D, then ymin Dm a Positions of intensity MINIMA of diffraction pattern on screen, measured from central position. the narrower the slit, the more the diffraction pattern “spreads out” a sin θ = λ first minima Very similar to expression derived for 2-slit experiment: m ym D d 31 D D 2 D a a a Intensity distribution But remember, in this case ym are positions of MAXIMA In interference pattern image of diffraction pattern If we narrow the slit the angle must get bigger more flaring - what happens when a = λ? 32 10/13/2022 INTENSITY IN SINGLE – SLIT DIFFRACTION INTENSITY IN SINGLE – SLIT DIFFRACTION Problem: SP42-3 Problem: SP42-4 Calculate, approximately, the relative intensities of the maxima in the single slit Fraunhofer diffraction pattern. 33 Find the width of the central maximum in a single slit Fraunhofer diffraction. The width can be represented as the angle between the two points in the pattern where the intensity is one-half that at the center of the pattern. 34 INTENSITY IN SINGLE – SLIT DIFFRACTION DIFFRACTION AT A CIRCULAR APERTURE Problem: E42-11 Monochromatic light with wavelength 538 nm falls on a slit with width 25.2m. The distance from the slit to a screen is 3.48m. Consider a point on the screen 1.13cm from the central maximum. Calculate (a) (b) (c) ratio of the intensity at this point to the intensity at the central maximum. DIFFRACTION PATTERN DUE TO A CIRCULAR APERTURE 35 36 10/13/2022 DIFFRACTION AT A CIRCULAR APERTURE The mathematical analysis of diffraction by a circular aperture shows that the first minimum occurs at an angle from the central axis given by sin 1 . 22 d where d is the diameter of aperture. The equation for first minimum in single slit diffraction is sin a where a is the slit width DIFFRACTION AT A CIRCULAR APERTURE Raleigh’s criterion for optical resolution: The images of two closely spaced sources is said to be just resolved if the angular separation of the two point sources is such that the central maximum of the diffraction pattern of one source falls on the first minimum of the diffraction pattern of the other. R sin11.22 d since R is very small, it can be appoximated as R 1.22 d separation for which we can resolve the images of two objects. a. Not resolved In case of circular aperture, the factor 1.22 arises when we divide the aperture into elementary Huygens sources and integrate over the aperture. 37 R is the smallest angular b. Just resolved c. Well resolved 38 DIFFRACTION AT A CIRCULAR APERTURE Using a circular instrument (telescope, human eye), when can we just resolve two distant objects? Problem: SP42-5 d R is very small, since the sources are distant and closely spaced A converging lens 32mm in diameter has a focal length f of 24 cm. (a) What angular separation must two distant point objects have to satisfy Rayleigh’s criterion? Assume that = 550nm. (b) How far apart are the centers of the diffraction patterns in the focal plane of the lens? R sin 1 1.22 R is the smallest angular separation for which we can resolve the images of two objects. 39 40 10/13/2022 DOUBLE-SLIT INTERFERENCE AND DIFFRACTION 1.Young’s double-slit experiment is an idealized situation in which slits were assumed to be very narrow (a << λ). 2.This cannot occur with actual slits because the condition a << λ cannot usually be met. 41 In case of double slit experiment: Each of the two slit has a finite width and the light is diffracted through it in a single slit diffraction pattern Usually, the width of each of the slits (a) is quite a bit less than the separation (d) between their centers Two single slit diffraction pattern is to be superposed to get the final intensity The final result can be obtained by drawing a two slit interference pattern inside the envelope of a single slit diffraction pattern 42 DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED 43 44 10/13/2022 DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED Interference I , INT I m, INT Diffraction I , DIF m, DIF cos m cos 2 β sin α α Interference + Diffraction I 2 sin α α 2 2 45 DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED Each of the two slits is divided into N zones. Electric field at P is found by adding the phasors. There is phase difference of = /N between each of the N phasors where is the phase difference between1st phasor and Nth phasor. 46 DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED From the figure , E 2E 1 sin where or 47 2 2 ( ) sin cos .........( A ) 2 2 2 2 and ( d a ) sin 2 a Adding sin to both sides of above eqn , we get , 2 d sin which is 2 Also Adding all the phasors, we get the resultant E1 due to the first slit. is the phase difference between the light waves at the point P, emitted from bottom edge of the first slit and top edge of the second slit. E2 is the resultant due to the second slit. E is the resultant of E1 and E2. 2 48 sin 10/13/2022 DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED Substituti ng this in eqn( A ), we get, sin cos 2 From sin gle slit diffractio n, we have, Problem: SP42- 6 Ina double slit experiment, the distance D of the screen the electric amplitude at P due to one slit, sin E1 Em E 2E1 sin 2 from the slits is 52cm, the wavelength is 480nm, slit separation d is 0.12mm and the slit width a is 0.025mm. sin ie, E ( 2Em ) cos sin m (cos )2 a) What is the spacing between adjacent fringes? b) What is the distance from the central maximum to the 2 DOUBLE-SLIT INTERFERENCE PATTERN first minimum of the fringe envelope? SINGLE-SLIT DIFFRACTION PATTERN 49 50 DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED Problem: SP42- 7 What requirements must be met for the central maximum of the envelope of the double-slit interference pattern to contain exactly 11 fringes? 51 52 10/13/2022 53 54 MULTIPLE SLITS: Width of the Central maximum Interference pattern from 3 slits 55 56 10/13/2022 For N slits, intensity of the primary maxima is N 2 times greater than that due to a single slit. 57 58 MULTIPLE SLITS Multiple slit arrangement will be the interference pattern multiplied by the single slit diffraction envelope. This assumes that all the slits are For N slits, intensity of the primary maxima is N 2 times greater than that due to a single slit. As the number of slits increases, the primary maxima increase in intensity and become narrower, while the secondary maxima decrease in intensity identical. As number of slits increases, number of secondary maxima also increases. In fact, the number of secondary maxima is always N - 2, where N is the number of slits. 59 60 10/13/2022 MULTIPLE SLITS MULTIPLE SLITS Condition for principal maxima, d sin = m where d is the separation between Intensity pattern for (a) Two-slit diffraction (b) Five-slit diffraction (diffraction effect is neglected) adjacent slits. Location of principal maxima is independent of number of slits. 61 62 MULTIPLE SLITS Width of the maxima: Central maximum The pattern contains central maximum with minima on either side. At the location of central maximum, the phase difference between the waves from the adjacent slits is zero. At minima, the phase difference is such that, 2 where N is the number of slits N MULTIPLE SLITS Width of the maxima: Central maximum L 2 N Also we know, L d sin 0 d sin 0 N sin 0 Nd 0 Nd Corresponding path difference is, L N 2 63 64 From the equation, for given and d if we increase number of slits (N), then the angular width of principal maximum decreases. ie the principal maximum becomes sharper. 10/13/2022 MULTIPLE SLITS MULTIPLE SLITS Width of the maxima: Other principal maxima Width of the maxima: Other principal maxima λ d sinθ θ mλ N d sin cos cos sin m N 1 For the mth principal maximum at by a grating: d sin = m . For the first minimum at + after the mth principal maximum d sinθ θ d sin d cos m d cos N d cos λ mλ N ANGULAR HALF WIDTH OF mTH PRINCIPAL MAXIMUM AT mth PRINCIPAL MAXIMUM AT θ MINIMUM AT θ +θ mth PRINCIPAL MAXIMUM AT θ 66 MULTIPLE SLITS MULTIPLE SLITS Problem: SP43- 1 A certain grating has 104 slits with a spacing of d = 2100 nm. It is illuminated with yellow sodium light ( = 589 nm). Find (a) the angular position of all principal maxima observed and (b) the angular width of the largest order maximum. 67 m N The principal maximum become sharper as number of slits (N) increases MINIMUM AT θ +θ 65 m N Problem: E43-5 Light of wavelength 600 nm is incident normally on a diffraction grating. Two adjacent principal maxima occur at sin = 0.20 and sin = 0.30. The fourth order is missing. (a) what is the separation between adjacent slits? (b) what is the smallest possible individual slit width? (c) Name all orders actually appearing on the screen with the values derived in (a) and (b). 68 10/13/2022 Grating contains : greater number of slits, or rulings, as many as several 1000 per millimeter 69 70 Diffraction Gratings DIFFRACTION GRATINGS Grating contains : greater number of slits, or rulings, as many as several 1000 per millimeter The diffraction grating, a useful device for analyzing light sources, consists of a large number of equally spaced parallel slits. Light passed through the grating forms narrow interference fringes that can be analyzed to determine the wavelength A transmission grating can be made by cutting parallel grooves on a glass plate with a precision ruling machine. The spaces between the grooves are transparent to the light and hence act as separate slits. As the number of rulings increases beyond 2 the intensity plot changes from that of a double slit pattern to one with very narrow maxima (called lines) surrounded by relatively wide dark regions 71 A reflection grating can be made by cutting parallel grooves on the surface of a reflective material. The reflection of light from the spaces between the grooves is specular, and the reflection from the grooves cut into the material is diffuse. 72 72 10/13/2022 the condition for interference maxima at a specific angle () is We can use this expression to calculate the wavelength if we know the grating spacing d and the angle (). If the incident radiation contains several wavelengths, the mth-order maximum for each wavelength occurs at a specific angle. All wavelengths are seen at = 0, corresponding to m = 0, the zeroth-order maximum. The first-order maximum (m = 1) is observed at an angle that satisfies the relationship sin = λ/d. The second-order maximum (m =2) is observed at a larger angle , and so on. 73 74 DIFFRACTION GRATINGS Grating spectrometer m=0 m=1 m=2 m=3 Sample spectra of visible light emitted by a gaseous source 75 76 10/13/2022 DIFFRACTION GRATINGS Problem: SP43-2 A diffraction grating has 1.20 x 104 rulings uniformly spaced over W= 2.50cm. It is illuminated at normal incidence by yellow light from sodium vapor lamp which contains two closely spaced lines of wavelengths 589.0nm and 589.59nm. (a) At what angle will the first order maximum occur for the first of these wavelengths? (b) What is the angular separation between the first order maxima of these lines? (c) How close in wavelength can two lines be (in first order) and still be resolved by this grating? (d) How many rulings can a grating have and just resolve the sodium doublet lines? 77 78 DIFFRACTION GRATINGS DIFFRACTION GRATINGS Problem: E43-9 Problem: E43-11 Given a grating with 400 rulings/mm, how many orders of the entire visible spectrum (400-700nm) can be produced? White light (400 nm < < 700 nm) is incident on a grating . Show that, no matter what the value of the grating spacing d, the second- and third-order spectra overlap. A grating has 315 rulings / mm. For what wavelengths in the visible spectrum can fifth-order diffraction be observed? 79 80 10/13/2022 DISPERSION AND RESOLVING POWER The ability of a grating to produce spectra that permit precise measurement of wavelengths is determined by two intrinsic DISPERSION A grating with high dispersive power must widely spread apart the diffraction lines associated with nearly equal wavelengths. Dispersion properties of the grating, Angular separation between spectral lines Difference between wavelength of spectral lines (1) Dispersion: High dispersive powers refers to the wide separation of the spectral lines D (2) Resolving power: Ability of the instrument to show the close spectral lines as the separate ones 81 82 DISPERSION AND RESOLVING POWER Dispersion D Δθ Δλ d sin = m Differentiating the above equation, d cos = m D Δθ Δλ m d cos θ To achieve higher dispersion we must use a grating of smaller grating spacing and work in higher order m . 83 Δθ Δλ RESOLVING POWER Ability of grating to resolve two nearby spectral lines so that two Lines can be viewed or photographed as separate lines. To resolve lines whose wavelengths are close together, the lines should be as narrow as possible. For two close spectral lines of wavelength 1 and 2, just resolved by the grating, the resolving power is defined as 1 2 1 2 R 2 The limit of resolution is determined by the Rayleigh criterion the minimum wavelength separation we can resolve min 2-1 occurs when the maximum of 2 overlaps with the first diffraction minimum of 1. 84 84 10/13/2022 DISPERSION AND RESOLVING POWER DISPERSION AND RESOLVING POWER Resolving power We have, Resolving power D Δθ Δλ m d cos θ N = 5,000 d = 10 m R = 5,000 D = 1.0 x 10-4 rad/m N d cos Putting second equation in first equation, N d cos N = 5,000 d = 5 m R = 5,000 D = 2.0 x 10-4 rad/m m d cos N = 10,000 d = 10 m R = 10,000 D = 1.0 x 10-4 rad/m R Nm Resolving power increases with increasing N 85 86 DISPERSION AND RESOLVING POWER DISPERSION AND RESOLVING POWER Problem: SP43-3 A grating has 9600 lines uniformly spaced over a width 3cm and is illuminated by mercury light. a) What is the expected dispersion in the third order, in the vicinity of intense green line ( = 546nm)? b) What is the resolving power of this grating in the fifth order? 87 Intensity patterns of two close lines due to three gratings A, B, C. Problem: SP43-4 A diffraction grating has 1.20 X 104 rulings uniformly spaced over a width W = 2.50cm. It is illuminated at normal incidence by yellow light from a sodium vapor lamp. This light contains two closely spaced lines of wavelengths 589.0 nm and 589.59 nm. (a) At what angle does the first maximum occur for the first of these wavelengths? (b) What is the angular separation between these two lines (1st order)? (c) How close in wavelength can two lines be (in first order) and still be resolved by this grating? (d) How many rulings can a grating have and just resolve the sodium doublet line? 88 10/13/2022 DISPERSION AND RESOLVING POWER DISPERSION AND RESOLVING POWER Problem: E43-17 Problem: E43-21 The sodium doublet in the spectrum of sodium is s pair of In a particular grating, the sodium doublet is viewed in lines with wavelengths 589.0 and 589.6 nm. Calculate the third order at 10.2 to the normal and is barely resolved. minimum number of rulings in a grating needed to resolve Find (a) the ruling spacing and (b) the total width of this doublet in the second-order spectrum. grating. 89 90 X-RAY DIFFRACTION X-RAY DIFFRACTION For the observation of diffraction phenomenon by grating, the grating space should have the dimension of the wavelength of the wave diffracted. Since the x-ray wavelength and the interplanar spacing in crystals are of the same order, a crystal can be a suitable grating for observing the diffraction of x-rays. x-ray diffraction producing Laue’s pattern 91 X-ray tube When a monoenergetic x-ray beam is incident on a sample of a single crystal, diffraction occurs resulting in a pattern consisting of an array of symmetrically arranged diffraction spots, called Laue’s spots. The single crystal acts like a grating with a grating constant comparable with the wavelength of x-rays, making the diffraction pattern distinctly visible. Since the diffraction pattern is decided by the crystal structure, the study of the diffraction pattern helps in the analysis of the crystal parameters. 92 A Laue pattern of a single crystal. Each dot represents a point of constructive interference. 10/13/2022 X-RAY DIFFRACTION X-RAY DIFFRACTION A plane through a crystal of NaCl NaCl crystal (a0 = 0.563nm) NaCl unit cell 93 (a) Electron density contour of an organic molecule (b) A structural representation of same molecule The x-rays are diffracted by the electron concentrations in the material. By studying the directions of diffracted x-ray beam, we can study the basic symmetry of the crystal. By studying the intensity, we can learn how the electrons are distributed in a unit cell. 94 X-RAY DIFFRACTION Bragg’s Law In every crystal, several sets of parallel planes called the Bragg planes can be identified. Each of these planes have an identical and a definite arrangement of atoms. Different sets of Bragg planes are oriented at different angles and are characterized by different inter planar distances d. 95 X-RAY DIFFRACTION Bragg’s Law Glancing angle. ie angle between the incident x-ray beam and the reflecting crystal planes. For constructive interference of diffracted x-rays the path difference for the rays from the adjacent planes, (abc in the figure) must be an integral number of wavelength. ie 2d sin = n 96 10/13/2022 X-RAY DIFFRACTION X-RAY DIFFRACTION Problem: SP43-5 Problem: E43-25 At what angles must an x-ray beam with wavelength = 0.110 nm fall on the family of planes in figure if a diffracted beam is to exist? Assume material to be sodium chloride (a0 = 0.563nm) 97 A beam of x-rays of wavelength 29.3 pm is incident on a calcite crystal of lattice spacing 0.313 nm. Find the smallest angle between the crystal planes and the beam that will result in constructive reflection of the x-rays. 98 QUESTIONS – DIFFRACTION QUESTIONS – DIFFRACTION Discuss the diffraction due to single-slit. Obtain the locations of the minima and maxima qualitatively. Explain Rayleigh’s criterion for resolving images due to a circular apperture. Obtain an expression for the intensity in single-slit diffraction pattern, using phasor-diagram. Obtain an expression for the intensity in double-slit diffraction pattern, using phasor-diagram. Calculate, approximately, the relative intensities of the first three secondary maxima in the single-slit diffraction pattern. Discuss qualitatively the diffraction due to multiple slits (eg, 5 slits). Discuss qualitatively diffraction at a circular aperture. 99 Obtain an expression for the width of the central maximum in diffraction pattern due to multiple slits. 100 10/13/2022 QUESTIONS – DIFFRACTION Obtain an expression for the width of a principal maximum at an angle in diffraction pattern due to multiple slits. Obtain an expression for dispersion by a diffraction grating. Obtain an expression for resolving power of a diffraction grating. Discuss Bragg’s law for X-ray diffraction. 101