fiziks Institute for NET/JRF, GATE, IIT‐JAM, M.Sc. Entrance, JEST, TIFR and GRE in Physics (e) Planck’s Theory of Radiation (Quantum Mechanical Theory) Basic Assumption and Methodology (1) Max Planck used Boltzmann distribution to determine the average energy of black body radiation. The probability to find energy between E to E dE is E 1 P E dE exp k BT k BT E P E dE 0 . dE . The average energy is given by E P E dE 0 (2) Planck assumed that energy E is not continuous rather discrete values. According to Planck, the allowed energy for black body radiation for frequency is E nh where n 0,1, 2,3... (3) The average energy is E EP E n 0 PE n 0 nh nh exp n 0 k BT k BT nh 1 exp n 0 k BT k BT h h exp k BT 1 Derivation of Average Energy Put the value, h , kT E k BT n exp n 0 exp n 0 d ln exp n d n 0 d d exp n n exp n exp n d n 0 n 0 d n 0 exp n exp n n 0 n 0 exp n n 0 d d E k BT ln exp n h ln exp n d n 0 d 0 2 3 exp n 1 exp exp 2 exp 3 ... 1 X X X ... n 0 where X exp 1 X X 2 X 3 ... 1 X 1 H.No. 40-D, Ground Floor, Jia Sarai, Near IIT, Hauz Khas, New Delhi-110016 Phone: 011-26865455/+91-9871145498 Website: www.physicsbyfiziks.com | Email: fiziks.physics@gmail.com Revised Edition 2019 1 fiziks Institute for NET/JRF, GATE, IIT‐JAM, M.Sc. Entrance, JEST, TIFR and GRE in Physics E h 1 d ln 1 exp d h 1 exp 1 1 1 exp 2 exp h h exp k BT 1 (3) Planck also used the same analogy of Rayleigh and Jeans theory to count the number 8 Va 3 2 of standing waves dN in the frequency interval to d dNd d c3 (4) Energy density d between frequency to d is d N d E d 8 2 . c3 Rayleigh - Jeans h h exp 1 k BT Wein's Distribution ρ(v)dv Planck's Distribution Observed Figure 1: Energy density versus frequency according to Planck The equation does accurately describe the low frequency (high wavelength) spectrum of Frequency,vHz thermal emission from objects, as well as accurately fit the experimental data for high frequency (short wavelengths) emission. H.No. 40-D, Ground Floor, Jia Sarai, Near IIT, Hauz Khas, New Delhi-110016 Phone: 011-26865455/+91-9871145498 Website: www.physicsbyfiziks.com | Email: fiziks.physics@gmail.com Revised Edition 2019 2