1 Forestry ENERGYPlantation&Biofuel s 2 By Javed Iqbal ENERGY PLANTATION AND BIO-FUELS 3(2-1) Objective: To develop understanding regarding the prospects and possibilities of raising bioenergy plantations, bio-fuel production, and conversion technologies. Course Outlines: Theory Introduction and advantages of energy plantations. Global overview of energy and biomass consumption patterns. Energy and biomass consumption patterns in Pakistan. Environmental impacts of biomass energy. Basic concepts of forest production ecology; the biomass production potential of a forest ecosystem; production of energy wood at special short-rotation plantations; use of residual biomass from traditional forestry operations for energy; harvesting and transportation logistics of energy wood production. A brief introduction to bio-energy conversion technologies; utilization of bio-energy with reference to the global carbon cycle and climatic change, especially with regard to CO 2 emissions and carbon storage; and the role of bio-energy in Pakistan and other countries, especially its potential for the development of rural areas. Assessment of bio-energy programs in Pakistan. Power generation from energy plantation, biomass gasification-producer gas. High Density Energy Plantations (HDEP).Land and biomass availability for sustainable bio energy. Bio-fuels introduction, Tree Born Oils (TBO‘s), potentials and advantages, bio-diesel transesterification, Important bio-fuel species and their silvicultural management. Overview of the markets for wood biomass for energy production globally and within the Pakistan this includes the supply, quantity, demand, and consumption as well as consumer market aspects. Fundamentals of the policies that have impacts on the supply and consumption of the energy wood; wood based fuels; and/ or bio-energy and bio-fuels‘ markets Need for research and development on environment friendly and socio economically relevant technologies. Energy from plants-problems and prospects. Petro-crops. Criteria for evaluation of different species for energy plantation. Advanced energy technologies in the production of bio-fuels Practical: Identification of important fuel woods and petro-crops. Study of different properties of bio fuels used in Pakistan. Determination of calorific value, moisture and ash content in biomass. Study of energy consumption pattern in rural and urban areas through survey. Visit to nearby Bio-energy units. Suggested Readings 1. Donald L. Klass. 2010. Biomass for Renewable Energy, Fuels, and Chemicals. Amazon Publishers 2. Snelder, D.J. & Lasco. R. 2008. Small Holder Tree Growing for Rural Development and Environmental Services. Springer Publisher. 3. Kumar V. 1999. Nursery and Plantation Practice in Forestry. Scientific Publications. 4. Luna RK. 1989. Plantation Forestry in India. International Book Distributors. 5. Chaturvedi AN. 1994. Technology of Forest Nurseries. Khanna Bandhu 6. William, B. R. & Gowen. 1994. Forest Resources and Wood based biomass. Oxford and IBH New Delhi. 3 CHAPTER NO. 01 INTRODUCTION TO ENERGY PLANTATION Globally, woodfuels are the main and often the only accessible energy sources for over two billion people, including the poorest segments of rural and sub-urban populations. Forest resources can be placed into two categories: industrial wood and fuelwood (USDA Forest Service 1989). Industrial wood is all merchantable wood, also known as roundwood, which is utilized for lumber, timber, pulp and paper, and other commercial products. Fuelwood is roundwood that is used for fuel plus forest residues. Forest residues can in turn be broken down into three groupings: slash from final fellings, slash and small trees from thinning and cleanings, and un-merchantable wood (EUBIA 2007). 1.1 ENERGY PLANTATION Technically speaking, energy plantation means growing select species of trees and shrubs which are harvestable in a comparably shorter time and are specifically meant for fuel. Energy plantation is the practice of planting trees, purely for their use as fuel. Terrestrial biomass i.e., the wood plants has been used since long time to generate fire for cooking and other purposes. In recent years, to meet the demand of energy, plantation of energy plants has been re-emphasized. According to a report, if fuel/fire wood plants were not raised rapidly, by 2,000 AD more than 250 millions people would not be able to manage fuels for cooking purpose and, therefore, they would be forced to burn animal dung which, however, depends on availability of animals and agricultural crop residues (Anonymous, 1980 c). Same situation occur in past few years which make the human to think about the alternative uses of energy resources. The fuel wood may be used either directly in wood burning stoves and boilers or processed into methanol, ethanol and producer gas. These plantations help provide wood either for cooking in homes or for industrial use, so as to satisfy local energy needs in a decentralised manner. The energy plantations provide almost inexhaustible renewable sources (with total time constant of 3-8 years only for each cycle) of energy which are essentially local and independent of unreliable and finite sources of fuel . The attractive features of energy plantations are: (a) heat content of wood is similar to that of coal, (b) wood is low in sulphur and not likely to pollute the atmosphere, (c) ash from burnt wood is a valuable fertiliser, (d) utilisation of erosion prone land for raising these plantations helps to reduce wind and water erosion, thereby minimising hazards from floods, siltation, and loss of nitrogen and minerals from soil and (e) help in rural employment generation - it is estimated that an hectare of energy plantation is estimated to provide employment for at least seven persons regularly. Selection of multipurpose species provides a number of by-products like oils, organic compounds, fruits, edible leaves, forage for livestock, etc. Data collected from Forest Department (India) reveals that annual woody biomass available is in the range 11.9 to 21 t/ha/yr. An energy forest raised at Hosalli village in Tumkur district to support a wood gasifier plant has annual yield of 6 t/ha/yr. 1.1.1 Status of Forest and Fuelwood India is the biggest fuel wood producing country in the world, but the per capita fuel wood production is very low i.e. 290 m2/head. Mitchell (1979) estimated that the need of fire wood for cooking purpose in India is 0.8 kg per capita per day. But this value does not hold good for cold areas where firewood is also required for keeping houses warm. Energy plays a pivotal role in socio-economic development by raising standard of living. Biomass has been used as an energy source for thousands of years by the humankind. Traditional fuels like firewood, dung and crop residues currently contribute a major share in meeting the everyday energy requirements of rural and low-income urban households in Pakistan. An average biomass using household consumes 2325 kg of firewood or 1480 kg of dung or 1160 kg of crop residues per annum. There are good prospects for using biogas energy in rural areas through a network of community biogas plants. Development of fuel-efficient cook stoves is a modest effort to help conserve biomass energy at domestic level. PCRET has so far installed 60,000 energy-conserving, improved cooking stoves all over the country, which are 12– 28% efficient. E-10 gasoline pilot project and research on biodiesel production are underway. Sugarcane bagasse can potentially be used to generate 2000 MW of electric power. Attention is now being given to the use of municipal and industrial waste for power generation. The government is financing many 4 projects related to biomass energy development in the country, but still lot more efforts are needed for harnessing full potential and taking maximum benefit out of this important renewable energy resource. In Pakistan, conditions of hills are quite different from that of plains. The villagers hardly get fire-wood plants, as they have to go in interior of forest and collect wood-falls. Even they have very limited right to fell trees and therefore, they depend on wood, falls and loppings of minor tree branches. If one talks about to meet their needs by making available technologies developed for plains, it is not feasible. For example, they cannot be motivated to use solar cooker, because of being solely traditional to which religious factors have been associated. Even gobar gas plant cannot be useful in hills, because of prevailing low temperature in mountain belt. Therefore, the search for renewable source of energy is highly desirable for survival of population in hills and for reducing the pressure on forests. About 200 billion tonnes of carbon per year is fixed photosynthetically into the terrestrial and aquatic biomass. This amount of biomass contains 3,000 billion giga (109) jules energy every year. It has been estimated that at present, only one seventh of the World's total energy comes from biomass and a large amount of it remains untapped. In view of getting maximum biomass, afforestation and forest management systems will have to be developed. These must include social forestry, silviculture (short-rotation forestry) tree-use systems, coppicing system, drought, salt-, pollutant - resistant plantations and high density energy plantations (HDEP). HDEP is the practice of planting trees at close spacing. This leads to rapid growth of trees due to struggle for survival. It provides quick and high returns, and opportunities for permanent income and employment. Therefore, annual plants should be grown to meet the demand of energy. Keeping in view the climatic and edaphic factors, plantation of deciduous trees should be encouraged, as their growth is faster than the coniferous ones. The species to be planted should have the following characters: (i) Fast growth, (ii) Stress resistance, (iii) Less palatable to cattle and other animals, (iv) Early propagable, (v) High caloric value, (vi) Absence of deleterious volatiles when smokes come out, (vii) High yield of biomass, and (viii) Disease/pest resistant. 1.1.2 Social Forestry Plantation through social forestry has been much emphasized by the Government to meet the demand of fuel and fodder in the rural areas. It will certainly decrease the gradually increasing pressure on the forests. This includes planting trees along road sides, canals, railway lines and waste lands in villages. Some of important plants are: Acacia nilotica, Albizia lebbek, A. procera, Anthocephalus chinensis, Azadirachta indica, Bauhinia variegata, Butea monosperma, Cassia fistula, Dalbergia sissoo, Eucalyptus globulus, E. citriodora, Ficus glomerata, Lagerstroemia speciosa, Madhuca indica, Morus alba, Populus ciliata, P. nigra, Terminalia arjuna, Toona ciliata, Salix alba and S. tetrasperma. 1.1.2.1 Silviculture Energy Farms (Short Rotation Forestry) Silviculture energy farms employ techniques more similar to agriculture than forestry. The chief objective of energy plantation is to produce biomass from the selected trees and shrub species in the shortest possible time (generally 5-10 yrs) and at the minimal cost, so as to satisfy local energy needs in the decentralized manner. This would certainly relieve the pressure on the consumption of fossil fuel like kerosene and prevent the destruction of plant cover which is one of the primary components of the life support system (Khoshoo, 1988). 1.1.2.2 Advantages of Short Rotation Management Jahn (1982) has discussed the following advantages from short rotation management from production of fuel biomass : (i) High yield per unit of land area, (ii) Smaller land requirements for given biomass output, (iii) Shorter time span from initial stand establishment to harvestable crop, (iv) Increased labor efficiency through mechanization and other methods similar to those used in agriculture, (v) Ability of most short rotation species to regenerate by coppicing; and (vi) Ability to take advantages of cultural and genetic advances quickly. Therefore, production of plant-based renewable energy is a part of the dynamic agro-botany-forestry system and the need is to integrate both modern biology and culture in agriculture (Khoshoo, 1988, p. 356). 5 1.2 ADVANTAGES OF ENERGY PLANTATIONS. 1.2.1 Biomass Energy and its Benefits Biomass is a substantial renewable resource that can be used as a fuel for producing electricity and other forms of energy. Biomass feedstock, or energy sources, are any organic matter available on a renewable basis for conversion to energy. Agricultural crops and residues, industrial wood and logging residues, farm animal wastes, and the organic portion of municipal waste are all biomass feedstock. Biomass fuels, also known as biofuels, may be solid, liquid, or gas and are derived from biomass feedstock. Biofuel technologies can efficiently transform the energy in biomass into transportation, heating, and electricity generating fuels. Biomass is a proven option for electricity generation. Biomass used in today's power plants includes wood residues, agricultural/farm residues, food processing residues (such as nut shells), and methane gas from landfills. In the future, farms cultivating energy crops, such as trees and grasses, could significantly expand the supply of biomass feedstock. Currently, there are over 7000 megawatts of biomass power capacity installed at more than 350 plants in the U.S. (DOE, NREL, 1998). These plants are owned by a diverse range of producers including the pulp and paper industry, wood manufacturing industry, electric utilities, and independent power producers. (a) Economic Benefits Economic activity associated with biomass currently supports about 66,000 jobs in the U.S., most of which are in rural regions. It is predicted that by the year 2010, over 13,000 megawatts of biomass power could be installed, with over 40 percent of the fuel supplied from 4 million acres of energy crops and the remainder from biomass residues (DOE, NREL, 1998). This would support over 170,000 U.S. jobs and could significantly benefit rural economies. Use of biofuels can reduce dependence on out-of-state and foreign energy sources, keeping energy dollars invested in Ohio's economy. Biomass energy crops can be a profitable alternative for farmers, which will complement, not compete with, existing crops and provide an additional source of income for the agricultural industry. Biomass energy crops may be grown on currently underutilized agricultural land. In addition to rural jobs, expanded biomass power deployment can create high skill, high value job opportunities for utility, power equipment, and agricultural equipment industries. (b) Environmental Benefits Biomass fuels produce virtually no sulfur emissions, and help mitigate acid rain. Biomass fuels "recycle" atmospheric carbon, minimizing global warming impacts since zero "net" carbon dioxide is emitted during biomass combustion, i.e. the amount of carbon dioxide emitted is equal to the amount absorbed from the atmosphere during the biomass growth phase. The recycling of biomass wastes mitigates the need to create new landfills and extends the life of existing landfills. Biomass combustion produces less ash than coal, and reduces ash disposal costs and landfill space requirements. The biomass ash can also be used as a soil amendment in farm land. Perennial energy crops (grasses and trees) have distinctly lower environmental impacts than conventional farm crops. Energy crops require less fertilization and herbicides and provide greater vegetative cover throughout the year, providing protection against soil erosion and watershed quality deterioration, as well as improved wildlife cover. Landfill gas-to-energy projects turn methane emissions from landfills into useful energy. 1.2 GLOBAL OVERVIEW OF ENERGY AND BIOMASS CONSUMPTION PATTERNS. World Energy Consumption refers to the total energy used by all of human civilization. Typically measured per-year, it involves all energy harnessed from every energy source we use, applied towards humanity's endeavors across every industrial and technological sector, across every country. Being the power source metric of civilization, World Energy Consumption has deep implications for humanity's social-economic-political sphere. Institutions such as the International Energy Agency (IEA), the U.S. Energy Information Administration (EIA), and the European Environment Agency record and publish energy data periodically. Improved data and understanding of World Energy Consumption may reveal systemic trends and 6 patterns, which could help frame current energy issues and encourage movement towards collectively useful solutions. According to IEA (2012) the climate goal of limiting warming to 2 °C is becoming more difficult and costly with each year that passes. If action is not taken before 2017, all the allowable CO2 emissions would be locked-in by energy infrastructure existing in 2017. Fossil fuels are dominant in the global energy mix, supported by $523 billion subsidies in 2011, up almost 30% on 2010 and six times more than subsidies to renewable. Fossil energy use increased most in 2000-2008. In October 2012 IEA wrote last decade ca half of the increased energy use is coal, growing faster than all renewable energy. Since Chernobyl disaster in 1986 investments in nuclear power have been small. Trend Energy use (TWh) According to IEA data from 1990 to 2008, Fossil Nuclear Renewable Total the average energy use per person increased 10% while world population 1990 83,374 6,113 13,082 102,569 increased 27%. Regional energy use also 94,493 7,857 15,337 117,687 grew from 1990 to 2008: the Middle East 2000 increased by 170%, China by 146%, India by 2008 117,076 8,283 18,492 143,851 91%, Africa by 70%, Latin America by 66%, Change 2000-2008 22,583 426 3,155 26,164 the USA by 20%, the EU-27 block by 7%, and world overall grew by 39%. In 2008, total worldwide energy consumption was 474 exajoules (474×1018 J=132,000 TWh). This is equivalent to an average power use of 15 terawatts (1.504×1013 W).The potential for renewable energy is: solar energy 1600 EJ (444,000 TWh), wind power 600 EJ (167,000 TWh), geothermal energy 500 EJ (139,000 TWh), biomass250 EJ (70,000 TWh), hydropower 50 EJ (14,000 TWh) and ocean energy 1 EJ (280 TWh). Energy consumption in the G20 increased by more than 5% in 2010 after a slight decline of 2009. In 2009, world energy consumption decreased for the first time in 30 years, by −1.1% (equivalent to 130 Megatonnes of oil), as a result of the financial and economic crisis, which reduced world GDP by 0.6% in 2009. This evolution is the result of two contrasting trends: Energy consumption growth remained vigorous in several developing countries, specifically in Asia (+4%). Conversely, in OECD, consumption was severely cut by 4.7% in 2009 and was thus almost down to its 2000 levels. In North America, Europe and the CIS, consumptions shrank by 4.5%, 5% and 8.5% respectively due to the slowdown in economic activity. China became the world's largest energy consumer (18% of the total) since its consumption surged by 8% during 2009 (up from 4% in 2008). Oil remained the largest energy source (33%) despite the fact that its share has been decreasing over time. Coal posted a growing role in the world's energy consumption: in 2009, it accounted for 27% of the total. Most energy is used in the country of origin, since it is cheaper to transport final products than raw materials. In 2008 the share export of the total energy production by fuel was: oil 50% (1,952/3,941 Mt), gas 25% (800/3,149 bcm), hard coal 14% (793/5,845 Mt) and electricity 1% (269/20,181 TWh). Most of the world's energy resources are from the conversion of the sun's rays to other energy forms after being incident upon the planet. Some of that energy has been preserved as fossil energy, some is directly or indirectly usable; for example, via wind, hydro- or wave power. The amount of energy is measured by satellite to be roughly 1368 watts per square meter, though it fluctuates by about 6.9% during the year due to the Earth's varying distance from the sun. This value is the total rate of solar energy received by the planet; about half, 89 PW, reaches the Earth's surface. The estimates of remaining non-renewable worldwide energy resources vary, with the remaining fossil fuels totaling an estimated 0.4 YJ (1 YJ = 1024J) and the available nuclear fuel such as uranium exceeding 2.5 YJ. Fossil fuels range from 0.6 to 3 YJ if estimates of reserves of methane clathrates are accurate and become technically extractable. The total energy flux from the sun is 3.8 YJ/yr, dwarfing all nonrenewable resources. Regional energy use (kWh/capita & TWh) and growth 1990–2008 (%) kWh/capita Population (million) Energy use (1,000 TWh) 7 1990 2008 Growth 1990 2008 Growth 1990 2008 Growth USA 89,021 87,216 – 2% 250 305 22% 22.3 26.6 20% EU-27 40,240 40,821 1% 473 499 5% 19.0 20.4 7% Middle East 19,422 34,774 79% 132 199 51% 2.6 6.9 170% China 8,839 18,608 111% 1,141 1,333 17% 10.1 24.8 146% Latin America 11,281 14,421 28% 355 462 30% 4.0 6.7 66% Africa 7,094 7,792 10% 634 984 55% 4.5 7.7 70% India 4,419 6,280 42% 850 1,140 34% 3.8 7.2 91% Others* 25,217 23,871 nd 1,430 1,766 23% 36.1 42.2 17% The World 19,422 21,283 10% 5,265 6,688 27% 102.3 142.3 39% Source: IEA/OECD, Population OECD/World Bank Energy use = kWh/capita* Mrd. capita (population) = 1000 TWh Others: Mathematically calculated, includes e.g. countries in Asia and Australia. The use of energy varies between the "other countries": E.g. in Australia, Japan or Canada energy is used more per capita than in Bangladesh or Burma. Energy Supply vs. End Use Total world energy supply is distinct from actual world energy usage due to energy loss. For example, in 2008, total world energy supply was 143,851 TWh, while end use was 98,022 TWh. Energy loss depends on the energy source itself, as well as the technology used. For example, Nuclear Power (as of 2008) loses 67% of its energy to water cooling systems. In 2008, world nuclear energy was 8,283 TWh (constituting 5.8% of total world energy), while nuclear energy end-use was 2,731 TWh (2.8%). Some renewable energy sources have small energy losses, although hydropower has essentially non-existent energy loss. Given significant energy supply-to-usage ratios, It is important to note these differences across various energy sources. Emissions Global warming emissions resulting from energy production are a serious environmental problem. Efforts to resolve this include the Kyoto Protocol, which is a UN agreement aiming to reduce harmful climate impacts, which a number of nations have signed. Dangerous concentration remains a subject of debate. A global temperature rise of 2 degrees Celsius is considered high risk by the SEI. Even to limit global temperature rise to 2 degrees Celsius demands a 75% decline in carbon emissions in industrial countries by 2050, if the population is 10 mrd in 2050.Across 40 years, this averages to a 2% decrease every year. In 2011, the warming emissions of energy production continued rising regardless of the consensus of the basic problem. According to Robert Engelman (World watch institute), in order to prevent collapse, human civilization must stop increasing emissions within a decade regardless of the economy or population (2009). Primary Energy The United States Energy Information Administration regularly World energy and power supply (TWh) publishes a report on world consumption for most types of Energy Power primary energy resources. According to IEA total world energy 1990 102 569 11 821 supply was 102,569 TWh (1990); 117,687 TWh (2000); 133,602 TWh (2005) and 143,851 TWh (2008). World power generation 2000 117 687 15 395 was 11,821 TWh (1990); 15,395 TWh (2000); 18,258 TWh 2005 133 602 18 258 (2005) and 20,181 TWh (2008). Compared to power supply 20,181 TWh the power end use was only 16,819 TWh in 2008 2008 143 851 20 181 including EU27: 2 857 TWh, China 2 883 TWh and USA 4 533 Source: IEA/OECD TWh. In 2008 energy use per person was in the USA 4.1 fold, EU 1.9 fold and Middle East 1.6 fold the world average and in China 87% and India 30% of the world average. 8 In 2008 energy supply by power source was oil 33.5%, coal 26.8%, gas 20.8% (fossil 81%), 'other' (hydro, peat, solar, wind, geothermal power, biofuels etc.) 12.9%, and nuclear 5.8%. Oil was the most popular energy fuel. Oil and coal combined represented over 60% of the world energy supply in 2008. Since the annual energy supply increase has been high, e.g. 2007–2008 4,461 TWh, compared to the total nuclear power end use 2,731 TWh environmental activists, like Greenpeace, support increase of energy efficiency and renewable energy capacity. These are also more and more addressed in the international agreements and national Energy Action Plans, like the EU 2009 Renewable Energy Directive and corresponding national plans. The global renewable energy supply increased from 2000 to 2008 in total 3,155 TWh, also more than the nuclear power use 2,731 TWh in 2008. The energy resources below show the extensive reserves of renewable energy. Energy by power source 2008 TWh % Regional energy use (kWh/cap.) kWh/capita Population (mil) Fossil Oil 48 204 33.5% fuels 1990 2008 1990 2008 The Coal 38 497 26.8% twenti USA 89 021 87 216 305 eth Gas 30 134 20.9% EU-27 40 240 40 821 centur Nuclear 8 283 5.8% Middle East 19 422 34 774 199 y saw Hydro 3 208 2.2% a rapid China 8 839 18 608 1 333 twenty Other RE* 15 284 10.6% Latin America 11 281 14 421 462 fold Others 241 0.2% increa Africa 7 094 7 792 984 se in Total 143 851 100% India 4 419 6 280 1 140 the Source: IEA *`=solar, wind, geothermal use of The World 19 421 21 283 6 688 and biofuels fossil Source: IEA/OECD, Population OECD/World Bank fuels. Between 1980 and 2006, the worldwide Average power in TW annual growth rate was 2%. According to the Fuel type US Energy Information Administration's 2006 1980 2004 2006 estimate, the estimated 471.8 EJ total Oil 4.38 5.58 5.74 consumption in 2004 was divided as given in the Gas 1.80 3.45 3.61 table above, with fossil fuels supplying 86% of the world's energy: Coal 2.34 3.87 4.27 Coal fueled the industrial revolution in the 18th Hydroelectric 0.60 0.93 1.00 and 19th century. With the advent of the automobile, airplanes and the spreading use of Nuclear power 0.25 0.91 0.93 electricity, oil became the dominant fuel during the wind, twentieth century. The growth of oil as the largest Geothermal, 0.02 0.13 0.16 solar energy, wood fossil fuel was further enabled by steadily dropping prices from 1920 until 1973. After the oil shocks Total 9.48 15.0 15.8 of 1973 and 1979, during which the price of oil Source: The USA Energy Information Administration increased from 5 to 45 US dollars per barrel, there was a shift away from oil. Coal, natural gas, and nuclear became the fuels of choice for electricity generation and conservation measures increased energy efficiency. In the U.S. the average car more than doubled the number of miles per gallon. Japan, which bore the brunt of the oil shocks, made spectacular improvements and now has the highest energy efficiency in the world. From 1965 to 2008, the use of fossil fuels has continued to grow and their share of the energy supply has increased. From 2003 to 2008, coal was the fastest growing fossil fuel. If production and consumption of coal continue at the rate as in 2008, proven and economically recoverable world reserves of coal would last for about 150 years. This is much more than needed for a irreversible climate catastrophe. Coal is the largest source of carbon dioxide emissions in the world. According to IEA Coal Information (2007) world production and use of coal have increased considerably in 9 recent years. According to James Hansen the single most important action needed to tackle the climate crisis is to reduce CO2 emissions from coal. Coal Regional coal supply (TWh), share 2010 (%) and share of change 2000–2010 2000 2008 2009* 2010* %* Change 2000–2009* North America 6,654 6,740 6,375 6,470 16% -1.2% Asia excl. China 5,013 7,485 7,370 7,806 19% 18.9% China 7,318 16,437 18,449 19,928 48% 85.5% EU 3,700 3,499 3,135 3,137 8% -3.8% Africa 1,049 1,213 1,288 1,109 3% 0.4% Russia 1,387 1,359 994 1,091 3% -2.0% Others 1,485 1,763 1,727 1,812 4% 2.2% Total 26,607 38,497 39,340 41,354 100% 100% Source: IEA, *in 2009, 2010 BP* Change 2000–2009: Region's share of the world change +12,733 TWh from 2000 to 2009 In 2000 coal was used in China 28%, other Asia 19%, North America 25% and the EU 14%. In 2009 the share of China was 47%. Single most coal using country is China. It's share of the world coal production was 28% in 2000 and Top 10 coal exporters (Mt) 48% in 2009. Coal use in the world increased 48% from 2000 to Share 2009. In practice majority of this growth occurred in China and 2010 2011 2011 % the rest in other Asia. 1 Indonesia 162 309 29.7% World annual coal production increased 1,905 Mt or 32% in 6 year in 2011 compared to 2005, of which over 70% was 2 Australia 298 285 27.4% in China and 8% on India. Coal production was in 2011 7,783 Mt, 3 Russia 89 99 9.5% and 2009 6,903 Mt, equal to 12.7% production increase in two years. 4 US 57 85 8.2% Indonesia and Australia exported together 57.1% of the world 5 Colombia 68 76 7.3% coal export in 2011. China, Japan, South Korea, India and Taiwan had 65% share of all the world coal import in 2011. 6 South Africa 68 70 6.7% Gas 7 Kazakhstan 33 34 3.3% In Regional gas supply (TWh) and share 2010 (%) 2009 8 Canada 24 24 2.3% 2000 2008 2009* 2010* % the 9 Vietnam 21 23 2.2% worl North America 7,621 7,779 8,839 8,925 27% d use 10 Mongolia 17 22 2.1% Asia excl. China 2,744 4,074 4,348 4,799 14% of X Others 19 14 1.3% China 270 825 1,015 1,141 3% gas was Total (Mt) 856 1041 EU 4,574 5,107 4,967 5,155 16% 131% Top ten 97.8% 98.7% Africa 612 974 1,455 1,099 3% comp ared to year 2000. 66% of the this Russia 3,709 4,259 4,209 4,335 13% growth was outside EU, North America Latin Latin America 1,008 1,357 958 nd nd America and Russia. Others include Middle East, Asia and Africa. The gas Others 3,774 5,745 6,047 7,785 23% supply increased also in the previous Total 24,312 30,134 31,837 33,240 100% regions: 8.6% in the EU and 16% in the North America 2000–2009. Source: IEA, in 2009, 2010 BP 10 Nuclear power As of December 2009, the world had 436 reactors. Since commercial nuclear energy began in the mid 1950s, 2008 was the first year that no new nuclear power plant was connected to the grid, although two were connected in 2009. Annual generation of nuclear power has been on a slight downward trend since 2007, decreasing 1.8% in 2009 to 2558 TWh with nuclear power meeting 13–14% of the world's electricity demand. Renewable energy Renewable energy comes from natural resources such as sunlight, wind, rain, tides, and geothermal heat, which are renewable (naturally replenished). As of 2010, about 16% of global final energy consumption comes from renewables, with 10% coming from traditional biomass, which is mainly used for heating, and 3.4% from hydroelectricity. New renewables (small hydro, modern biomass, wind, solar, geothermal, and biofuels) accounted for another 2.8% and are growing very rapidly. The share of renewables in electricity generation is around 19%, with 16% of global electricity coming from hydroelectricity and 3% from new renewables. Hydroelectricity Hydroelectricity is the term referring to electricity generated by hydropower; the production of electrical power through the use of the gravitational force of falling or flowing water. It is the most widely used form of renewable energy, accounting for 16 percent of global electricity consumption, and 3,427 terawatt-hours of electricity production in 2010, which continues the rapid rate of increase experienced between 2003 and 2009. Hydropower is produced in 150 countries, with the Asia-Pacific region generating 32 percent of global hydropower in 2010. China is the largest hydroelectricity producer, with 721 terawatt-hours of production in 2010, representing around 17 percent of domestic electricity use. There are now three hydroelectricity plants larger than 10 GW: the Three Gorges Dam in China, Itaipu Dam in Brazil, and Guri Dam in Venezuela. Wind power Wind power: worldwide installed capacity (not actual power generation) Wind power is growing at the rate of 30% annually, with a worldwide installed capacity of 238,351 megawatts (MW) at the end of 2011, and is widely used in Europe, Asia, and the United States. Several countries have achieved relatively high levels of wind power penetration, such as 21% of stationary electricity production in Denmark, 18% in Portugal, 16% in Spain, 14% in Ireland and 9% in Germany in 2010. As of 2011, 83 countries around the world are using wind power on a commercial basis. Solar energy 11 Solar Power Plants Solar energy, radiant light and heat from the sun, has been harnessed by humans since ancient times using a range of ever-evolving technologies. Solar energy technologies include solar heating, solar photovoltaics, solar thermal electricity and solar architecture, which can make considerable contributions to solving some of the most urgent problems the world now faces. The International Energy Agency projected that solar power could provide "a third of the global final energy demand after 2060, while CO2 emissions would be reduced to very low levels." Solar technologies are broadly characterized as either passive solar or active solar depending on the way they capture, convert and distribute solar energy. Active solar techniques include the use of photovoltaic panels and solar thermal collectors to harness the energy. Passive solar techniques include orienting a building to the Sun, selecting materials with favorable thermal mass or light dispersing properties, and designing spaces that naturally circulate air. Geothermal Geothermal energy is used commercially in over 70 countries. In the year 2004, 200 PJ (57 TWh) of electricity was generated from geothermal resources, and an additional 270 PJ of geothermal energy was used directly, mostly for space heating. In 2007, the world had a global capacity for 10 GW of electricity generation and an additional 28 GW of direct heating, including extraction by geothermal heat pumps. Heat pumps are small and widely distributed, so estimates of their total capacity are uncertain and range up to 100 GW. Biomass and biofuels Until the beginning of the nineteenth century biomass was the predominant fuel, today it has only a small share of the overall energy supply. Electricity produced from biomass sources was estimated at 44 GW for 2005. Biomass electricity generation increased by over 100% in Germany, Hungary, the Netherlands, Poland, and Spain. A further 220 GW was used for heating (in 2004), bringing the total energy consumed from biomass to around 264 GW. The use of biomass fires for cooking is excluded. World production of bioethanol increased by 8% in 2005 to reach 33 billion litres (8.72 billion US gallons), with most of the increase in the United States, bringing it level to the levels of consumption in 12 Brazil. Biodiesel increased by 85% to 3.9 billion litres (1.03 billion US gallons), making it the fastest growing renewable energy source in 2005. Over 50% is produced in Germany. By Country Energy consumption is loosely correlated with gross national product and climate, but there is a large difference even between the most highly developed countries, such as Japan and Germany with an energy consumption rate of 6 kW per person and the United States with an energy consumption rate of 11.4 kW per person. In developing countries, particularly those that are sub-tropical or tropical such as India, the per person energy use rate is closer to 0.7 kW. Bangladesh has the lowest consumption rate with 0.2 kW per person. A map depicting world energy consumption per capita based on 2003 data from the IEA Energy consumption from 1989 to 1999 The US consumes 25% of the world's energy with a share of global GDP at 22% and a share of the world population at 4.59%. The most significant growth of energy consumption is currently taking place in China, which has been growing at 5.5% per year over the last 25 years. Its population of 1.3 billion people (19.6% of the world population) is consuming energy at a rate of 1.6 kW per person. One measurement of efficiency is energy intensity. This is a measure of the amount of energy it takes a country to produce a dollar of gross domestic product. Oil Saudi Arabia, Russia and the United States accounted for 34% of oil production in 2011. Saudi Arabia, Russia and Nigeria accounted for 36% of oil export in 2011. Top 10 oil producers (Mt) 2005 2008 2009 2010 2011 1 Saudi Arabia 519 509 452 471 Top 10 oil exporters (Mt) Share 2011 517 12.9% 2011 1 Saudi Arabia Share 2011 % 333 17.0% 13 2 Russia 470 485 494 502 510 12.7% 2 Russia 3 United States 307 300 320 336 346 8.6% 3 Nigeria 129 6.6% 4 Iran 205 214 206 227 215 5.4% 4 Iran 126 6.4% 5 China 183 190 194 200 203 5.1% 5 UAE 105 5.4% 6 Canada 143 155 152 159 169 4.2% 6 Iraq 94 4.8% 7 UAE nd 136 120 129 149 3.7% 7 Venezuela 87 4.4% 8 Venezuela 162 137 126 149 148 3.7% 8 Angola 84 4.3% 9 Mexico 188 159 146 144 144 3.6% 9 Norway 78 4.0% 10 Nigeria 133 nd nd 130 139 3.5% 10 Mexico 71 3.6% x Kuwait nd 145 124 nd nd nd x Norway 139 nd nd nd nd nd x Others 246 12.5% 609 31.0% Total (Mt) 1,962 Total 3,923 3,941 3,843 3,973 4,011 100% Top ten 62% 62% 61 % 62% 63% Coal Top 10 coal importers (Mt) Top 10 coal producers (Mt) 1 2005 2008 2009 2010 2011 Share % 2011 China 2,226 2,761 2,971 3,162 3,576 46% 2 US 1,028 1,076 985 997 1,004 13% 2005 2008 2009 2010 2011 1 China 25 nd 114 157 177 2 Japan 178 186 165 187 175 3 South Korea 77 100 103 119 129 4 India 37 58 66 88 101 5 Taiwan 61 66 60 63 66 6 Germany 38 46 38 45 41 7 UK 44 43 38 26 32 8 Turkey nd 19 20 27 24 9 Italy 24 25 19 22 23 10 Malaysia nd nd nd 19 21 3 India 430 521 561 571 586 8% 4 Australia 372 397 399 420 414 5% 5 Indonesia 318 284 301 336 376 5% 6 Russia 222 323 297 324 334 4% 7 South Africa 315 236 247 255 253 3% 8 Germany nd nd nd nd 189 2% 9 Poland 160 144 135 134 139 2% x Spain 25 19 16 nd nd 10 Kazakhstan 79 108 101 111 117 2% x France nd 21 nd nd nd 11 65 79 73 74 1% nd x US 28 nd nd nd nd Total 5,878 6,796 6,903 7,229 7,783 100% Total 778 778 819 Colombia Top ten 89% 949 1,002 90% Top ten 69% 75% 78% 79% 79% * include hard coal and brown coal Import of 16% 13% 14% 15% production 13% 87% 88% 88% nd * 2005-2010 hard coal Natural gas Top 10 natural gas producers (bcm) 2005 2008 2009 2010 2011 Share 2011 Top 10 natural gas importers (bcm) 2005 2008 2009 2010 2011 Share 2011 14 1 Russia 627 657 589 637 677 20.0% 1 Japan 81 95 93 99 2 US 517 583 594 613 651 19.2% 2 Italy 73 77 69 75 70 8.4% 3 Canada 187 175 159 160 160 4.7% 3 Germany 91 79 83 83 68 8.2% 4 Qatar nd 79 89 121 151 4.5% 4 US 121 84 76 74 55 6.6% 5 Iran 84 121 144 145 149 4.4% 5 South Korea 29 36 33 43 47 5.6% 6 Norway 90 103 106 107 106 3.1% 6 Ukraine 62 53 38 37 44 5.3% 7 China nd 76 90 97 103 3.0% 7 Turkey 27 36 35 37 43 5.2% 8 Saudi Arabia 70 nd nd 82 92 2.7% 8 France 47 44 45 46 41 4.9% 9 Indonesia 77 77 76 88 92 2.7% 9 UK nd 26 29 37 37 4.4% 10 Netherlands 79 85 79 89 81 2.4% 10 Spain 33 39 34 36 34 4.1% nd nd x Algeria 93 82 81 nd nd nd x Netherlands 23 nd nd nd x UK 93 nd nd nd nd nd Total 838 783 749 820 Total 2,872 3,149 3,101 3,282 100% 3,388 Top ten 67% 65% 65% 65% 67% bcm = billion cubic meters 116 13.9% 834 100% Top ten 70% 73% 71% 69% 67% Import of 29% 25% 24% 25% 25% production bcm = billion cubic meters Wind Power Top by nameplate Country 10 countries windpower capacity (2011 year-end) Windpower capacity ǂ (MW) provisional % Top by world total windpower Country 10 electricity countries production (2010 totals) Windpower % production (TWh) world total ǂ 26.3 United States 95.2 27.6 United States 46,919 19.7 China 55.5 15.9 Germany 29,060 12.2 Spain 43.7 12.7 Spain 21,674 9.1 Germany 36.5 10.6 India 16,084 6.7 India 20.6 6.0 France ǂ 2.8 Italy 6,747 2.8 United Kingdom 10.2 3.0 United Kingdom 6,540 2.7 France 9.7 2.8 Portugal 9.1 2.6 Canada 5,265 2.2 Italy 8.4 2.5 Portugal 4,083 1.7 Canada 8.0 2.3 (rest of world) 32,446 13.8 (rest of world) 48.5 14.1 World total 238,351 MW 100% World total 344.8 TWh 100% China 62,733 6,800 15 By Sector Industrial users (agriculture, mining, World energy use per sector manufacturing, and construction) consume about 37% of the total 15 TW. Personal and 2000 2008 2000 2008 commercial transportation consumes 20%; TWh %* residential heating, lighting, and appliances Industry 21,733 27,273 26.5 27.8 use 11%; and commercial uses (lighting, heating and cooling of commercial Transport 22,563 26,742 27.5 27.3 buildings, and provision of water and sewer Residential and service 30,555 35,319 37.3 36.0 services) amount to 5% of the total. The other 27% of the world's energy is lost Non-energy use 7,119 8,688 8.7 8.9 in energy transmission and generation. In Total* 81,970 98,022 100 100 2005, global electricity consumption averaged 2 TW. The energy rate used to Source: IEA 2010, Total is calculated from the given sectors generate 2 TW of electricity is Numbers are the end use of energy approximately 5 TW, as the efficiency of a Total world energy supply (2008) 143,851 TWh typical existing power plant is around 38%. The new generation of gas-fired plants reaches a substantially higher efficiency of 55%. Coal is the most common fuel for the world's electricity plants. Total world energy use per sector was in 2008 industry 28%, transport 27% and residential and service 36%. Division was about the same in the year 2000. European Union The European Environmental Agency (EEA) measures final energy consumption (does not include energy used in production and lost in transportation) and finds that the transport sector is responsible for 31.5% of final energy consumption, industry 27.6%, households 25.9%, services 11.4% and agriculture 3.7%. The use of energy is responsible for the majority of greenhouse gas emissions (79%), with the energy sector representing 31%, transport 19%, industry 13%, households 9% and others 7%. While efficient energy and resource efficiency are growing as public policy issues, more than 70% of coal plants in the European Union are more than 20 years old and operate at an efficiency level of between 32–40%. Technological developments in the 1990s have allowed efficiencies in the range of 40–45% at newer plants. However, according to an impact assessment by the European Commission, this is still below the best available technological (BAT) efficiency levels of 46–49%. With gas-fired power plants the average efficiency is 52% compared to 58–59% with best available technology (BAT), and gas and oil boiler plants operate at average 36% efficiency (BAT delivers 47%). According to that same impact assessment by the European Commission, raising the efficiency of all new plants and the majority of existing plants, through the setting of authorisation and permit conditions, to an average generation efficiency of 51.5% in 2020 would lead to a reduction in annual consumption of 15 billion m3 of natural gas and 25 Mt of coal. Alternative energy Paths 16 Wind power in Germany 1990-2011: Capacity (MW) in red and Generated Energy (GW-h) in blue. Denmark and Germany have started to make investments in solar energy, despite their unfavorable geographic locations. Germany is now the largest consumer of photovoltaic cells in the world. Denmark and Germany have installed 3 GW and 17 GW of wind power respectively. In 2005, wind generated 18.5% of all the electricity in Denmark. Brazil invests in ethanol production from sugar cane, which is now a significant part of the transportation fuel in that country. Starting in 1965, France made large investments in nuclear power and to this date three quarters (75%) of its electricity comes from nuclear reactors. Switzerland is planning to cut its energy consumption by more than half to become a 2000-watt society by 2050 and the United Kingdom is working towards a zero energy building standard for all new housing by 2016. Total Primary energy supply of the world 17 *Other includes geothermal, solar, wind, heat etc. Total Consumption of the world 18 *Data prior to 1994 for biofuels and waste final consumption have been estimated. **Others include geothermal, wind, solar, heat etc. Global supply and consumption 1.3 ENERGY AND BIOMASS CONSUMPTION PATTERNS IN PAKISTAN. 1.5 ENVIRONMENTAL IMPACTS OF BIOMASS ENERGY. 1.5.1 Biomass Energy and the Environment Unlike any other energy resource, using biomass to produce energy is often a way to dispose of biomass waste materials that otherwise would create environmental risks. In the following ways, using biomass for energy can deliver unique environmental dividends as well as useful energy. 1.5.2 Reducing Greenhouse Gases: Carbon Dioxide Carbon dioxide (CO2), methane, nitrous oxide and certain other gases are called greenhouse gases because they trap heat in the Earth´s atmosphere. The global concentration of CO2 and other greenhouse gases is increasing. A natural greenhouse effect of trace gases and water vapor warms the atmosphere and makes the Earth habitable. However, human-caused greenhouse gas emissions are having an effect 19 on regional climate and weather patterns. The rate and magnitude of climate change effects are not yet clear. Trees and plants remove carbon from the atmosphere through photosynthesis, forming new biomass as they grow. Carbon is stored in biomass. When biomass is burned, carbon returns to the atmosphere in the form of CO2. This cycle makes it possible for biomass energy to avoid increasing the net amount of CO2 in the atmosphere. There is no net increase in atmospheric CO2 if the new growth of plants and trees fully replaces the supply of biomass consumed for energy. However, if the collection or processing of biomass consumes any fossil fuel, additional biomass would need to be grown to offset the carbon released from the fossil fuel. In contrast, the combustion of natural gas, coal and petroleum fuels for energy adds CO2 to the atmosphere without a balancing cycle to remove it. Using biomass fuels instead of fossil fuels may reduce the risk of adverse climate change from greenhouse gas emissions. 1.5.3 Reducing Greenhouse Gases: Methane Compared to CO2, methane has 21 times the global warming potential. Natural decomposition of organic material, especially in wetlands, releases methane. It has been estimated that 60 to 80 percent of methane emissions are the result of human activity. For example, solid waste landfills, cattle feedlots and dairies are sources of human-caused methane emissions. Because human-caused emissions, the global atmospheric concentration of methane increased 6 percent from 1984 to 1994. Using biomass-derived methane to produce useful energy consumes methane and reduces the risk to the environment that would otherwise result from natural decomposition. In addition, generating electricity with biomass-derived methane fuel can offset power produced from fossil fuels and reduce the net CO2 emissions from electric power generation. Federal Clean Air Act regulations require collection of methane produced in landfills. The regulations allow operators to use landfill methane for energy production or burn off the gas to avoid the release of methane into the atmosphere. Besides the potential effect of methane emissions on climate, uncontrolled landfill gas emissions cause odor problems and a risk of explosion and fire. Methane released from decomposition of livestock and poultry manure generates about 9 percent of all human-caused methane emissions in the United States. Processing manure through anaerobic digesters can make the methane available for conversion to useful energy and avoid methane emissions to the atmosphere. 1.5.4 Protecting Clean Water land on which cattle are fattened for market. Livestock manure generated at feedlots and dairies poses a risk of surface and ground water contamination from runoff. Microorganisms such as salmonella, brucella and coliforms in manure can transmit disease to humans and animals. Anaerobic digestion of manure destroys most of these microorganisms. The process produces environmentally stable liquid and fiber residue. The liquid portion of digester residue (called filtrate) contains approximately 75 percent of the nitrogen present in raw manure but in a more soluble form. In this form, the nitrogen is more available to plants. However, the filtrate should be applied as close to the ground as possible to avoid volatile ammonia emissions. Farmers must carefully manage land application of filtrate to avoid overloading the soil with more nutrients than the plants can use. 1.5.5 Keeping Waste Out of Landfills Using urban wood waste for fuel reduces the volume of waste that otherwise would be buried in landfills. The ash residue that remains after combustion of waste wood is less than 1 percent of the volume of the wood waste consumed. Uncontaminated ash can be used as a soil amendment to add minerals and to adjust soil acidity. 1.5.6 Reducing Air Pollution Field burning of agricultural residue emits particulate matter and other air pollutants. Because of air quality concerns, state regulations have reduced the amount of open field burning of grass seed straw in Oregon's Willamette Valley. Grass seed straw and other agricultural residues are potential biomass fuels. These materials are suitable as fuel for appropriately designed combustion boilers to produce heat, steam or electric power. They are also potential feedstock for conversion to ethanol. Smoke emissions from forest fires and slash burning adversely affect air quality. Removing biomass from forested areas where an excess of dead wood has accumulated reduces forest fire risk. Compared to the smoke emitted from forest fires and slash burning, the emissions from using wood fuel for energy are far 20 less harmful. Industrial combustion boilers with pollution control equipment in place burn more efficiently and cleanly than open fires. Residential woodstoves can be a major source of particulate air pollution. Improvements in stove technology have made woodstoves more efficient and have reduced particulate matter emissions by as much as 90 percent over older woodstoves and fireplaces. In 1983, Oregon became the first state to enact regulations restricting woodstove emissions. New woodstoves currently must meet certification standards of the U.S. Environmental Protection Agency. 1.5.7 Reducing Acid Rain and Smog Air pollution from burning fossil fuels is the major cause of acid rain. Emissions of sulfur dioxide (SO2) and nitrogen oxides (NOx) react in the atmosphere with water, oxygen and oxidants to form acidic compounds (sulfuric acid and nitric acid). Some of these compounds fall to earth in the form of acid rain, snow or fog. Acid rain increases acidity of lakes and streams and damages trees at high elevations. Acid rain accelerates the decay of building materials and paints. Aside from their contribution to acid rain, SO2 and NOx gases and their particulate matter derivatives (sulfates and nitrates) contribute to smog and endanger public health. Tighter control of these emissions is desirable in areas with frequent smog problems and in areas protected for their pristine qualities. Efficient combustion of biomass results in low emissions of SO2 and production of fewer organic compounds that cause smog compared to emissions from facilities that burn coal or oil. Co-firing biomass with coal can reduce SO2 and NOx emissions at coal-fired power plants. The level of NOx emissions from biomass combustion facilities depends on the design of the facility and the nitrogen content of the feedstock. Pollution control equipment can further reduce NOx and particulate emissions. 1.5.8 Protecting Forests Dense growth has limited the size and resiliency of trees in some forested areas of the state. In the Blue Mountains of eastern Oregon, for example, the health of large areas of forestland has deteriorated. Similar conditions exist in forests throughout the Western United States. In many areas the natural ecosystem has been significantly altered, creating a high risk of intense wildfire. According to Western Forest Health and Biomass Energy Potential, a study prepared for the Department of Energy, 39 million acres (about 30 percent) of National Forest land in the West is threatened by unnatural fuel accumulations. The condition of the forest in these overgrown areas is not natural. It is largely the result of fire suppression and past logging practices. Selective thinning would improve the general health of the remaining trees and reduce the risk of fire. With less competition for nutrients and water, the remaining trees would have a better chance of maturing into old growth stands. The surplus biomass that could be available from thinning unnaturally overgrown forest areas is a large renewable energy resource. Carefully planned forest thinning activities can preserve wildlife habitat and minimize soil erosion so that the use of forest biomass can be done in a sustainable manner. 1.5.9 Zero–impact does not exist Every type of energy utilisation for electricity generation has environmental consequences. The main consequences of burning fossil fuels and of nuclear power are well-known. Renewable energy sources (wind, solar, biomass, hydroelectric, geothermal, etc.) are generally thought of as harmless, but this doesn’t mean they have no environmental consequences at all. Most of them have a significant aesthetic impact and require large areas of land. Some also have a significant impact on the eco-system (birds, fishes, etc.). 1.5.10 Avoiding greenhouse gases The CO2 emissions of fossil fuels are currently the most worrying energy-related environmental problem. Up to now, nuclear power is still the only solution applicable everywhere on a large scale that has no CO 2 emissions. How to process nuclear waste however is still a problem that largely remains to be solved. And despite maximum efforts, safety will always remain an issue for nuclear power due to its potential for large scale contamination. Renewable energy is still used on too small of a scale to replace all fossil fuels. If one day current renewable energy systems are applied to replace present fossil fuel output, the resulting aesthetic impact and land use will be large. Since every type of energy utilization has some degree of environmental impact, energy conservation should get top priority in every instance, no matter which mix of primary energy sources is used. 21 1.5.11 Environmental impact Some forms of forest bioenergy have recently come under fire from a number of environmental organizations, including Greenpeace and the Natural Resources Defense Council, for the harmful impacts they can have on forests and the climate. Greenpeace recently released a report entitled Fuelling a BioMess which outlines their concerns around forest bioenergy. Because any part of the tree can be burned, the harvesting of trees for energy production encourages Whole-Tree Harvesting, which removes more nutrients and soil cover than regular harvesting, and can be harmful to the long-term health of the forest. In some jurisdictions, forest biomass is increasingly consisting of elements essential to functioning forest ecosystems, including standing trees, naturally disturbed forests and remains of traditional logging operations that were previously left in the forest. Environmental groups also cite recent scientific research which has found that it can take many decades for the carbon released by burning biomass to be recaptured by regrowing trees, and even longer in low productivity areas; furthermore, logging operations may disturb forest soils and cause them to release stored carbon. In light of the pressing need to reduce greenhouse gas emissions in the short term in order to mitigate the effects of climate change, a number of environmental groups are opposing the large-scale use of forest biomass in energy production. CHAPTER NO.02 BIOMASS ECOLOGY 2.1 BASIC CONCEPTS OF FOREST PRODUCTION ECOLOGY; Ecologists and ecosystem managers are unlikely to achieve desired management objectives unless they are familiar with the distribution and movements of energy that are responsible for the character and productivity of ecosystems under their management(Kimmins2004). Theoretical production ecology Theoretical production ecology tries to quantitatively study the growth of crops. The plant is treated as a kind of biological factory, which processes light, carbon dioxide, water and nutrients into harvestable parts. Main parameters kept into consideration are temperature, sunlight, standing crop biomass, plant production distribution, nutrient and water supply. Modelling 22 Modelling is essential in theoretical production ecology. Unit of modelling usually is the crop, the assembly of plants per standard surface unit. Analysis results for an individual plant are generalised to the standard surface, e.g. the Leaf Area Index is the projected surface area of all crop leaves above a unit area of ground. Processes The usual system of describing plant production divides the plant production process into at least five separate processes, which are influenced by several external parameters. Two cycles of biochemical reactions constitute the basis of plant production, the light reaction and the dark reaction. In the light reaction, sunlight photons are absorbed by chloroplasts which split water into an electron, proton and oxygen radical which is recombined with another radical and released as molecular oxygen. The recombination of the electron with the proton yields the energy carriers NADH and ATP. The rate of this reaction often depends on sunlight intensity, leaf area index, leaf angle and amount of chloroplasts per leaf surface unit. The maximum theoretical gross production rate under optimum growth conditions is approximately 250 kg per hectare per day. The dark reaction or Calvin cycle ties atmospheric carbon dioxide and uses NADH and ATP to convert it into sucrose. The available NADH and ATP, as well as temperature and carbon dioxide levels determine the rate of this reaction. Together those two reactions are termed photosynthesis. The rate of photosynthesis is determined by the interaction of a number of factors including temperature, light intensity and carbon dioxide. The produced carbohydrates are transported to other plant parts, such as storage organs and converted into secondary products, such as amino acids, lipids, cellulose and other chemicals needed by the plant or used for respiration. Lipids, sugars, cellulose and starch can be produced without extra elements. The conversion of carbohydrates into amino acids and nucleic acids requires nitrogen, phosphorus and sulfur. Chlorophyll production requires magnesium, while several enzymes and coenzymes require trace elements. This means, nutrient supply influences this part of the production chain. Water supply is essential for transport, hence limits this too. The production centers, i.e. the leaves, are sources, the storage organs, growth tips or other destinations for the photosynthetic production are sinks. The lack of sinks can be a limiting factor for production too, as happens e.g. in apple orchards where insects or night frost have destroyed the blossoms and the produced assimilates cannot be converted into apples. Biennial and perennial plants employ the stored starch and fats in their storage organs to produce new leafs and shoots the next year. The amount of crop biomass and the relative distribution of biomass over leafs, stems, roots and storage organs determines the respiration rate. The amount of biomass in leafs determines the leaf area index, which is important in calculating the gross photosynthetic production. extensions to this basic model can include insect and pest damage, intercropping, climatical changes, etc. Parameters Important parameters in theoretical production models thus are: Climate Temperature - The temperature determines the speed of respiration and the dark reaction. A high temperature combined with a low intensity of sunlight means a high loss by respiration. A low temperature combined with a high intensity of sunlight means that NADH and ATP heap up but cannot be converted into glucose because the dark reaction cannot process them swiftly enough. Light - Light, also called photosynthetic Active Radiation (PAR) is the energy source for green plant growth. PAR powers the light reaction, which provides ATP and NADPH for the conversion of carbon dioxide and water into carbohydrates and molecular oxygen. When temperature, moisture, carbon dioxide and nutrient levels are optimal, light intensity determines maximum production level. Carbon dioxide levels - Atmospheric carbon dioxide is the sole carbon source for plants. About half of all proteins in green leaves have the sole purpose of capturing carbon dioxide. Although CO2 levels are constant under natural circumstances [on the contrary, CO2 concentration in the atmosphere has been increasing steadily for 200 years], CO2 fertilization is common in greenhouses and is 23 known to increase yields by on average 24% [a specific value, e.g., 24%, is meaningless without specification of the "low" and "high" CO2 levels being compared] . C4 plants like maize and sorghum can achieve a higher yield at high solar radiation intensities, because they prevent the leaking of captured carbon dioxide due of the spatial separation of carbon dioxide capture and carbon dioxide use in the dark reaction. This means that their photorespiration is almost zero. This advantage is sometimes offset by a higher rate of maintenance respiration. In most models for natural crops, carbon dioxide levels are assumed to be constant. Crop Standing crop biomass - Unlimited growth is an exponential process, which means that the amount of biomass determines the production. Because an increased biomass implies higher respiration per surface unit and a limited increase in intercepted light, crop growth is a sigmoid function of crop biomass. Plant production distribution - Usually only a fraction of the total plant biomass consists of useful products, e.g. the seeds in pulses and cereals, the tubers in potato and cassava, the leafs in sisal and spinach etc. The yield of usable plant portions will increase when the plant allocates more nutrients to this parts, e.g. the high-yielding varieties of wheat and rice allocate 40% of their biomass into wheat and rice grains, while the traditional varieties achieve only 20%, thus doubling the effective yield. Different plant organs have a different respiration rate, e.g. a young leaf has a much higher respiration rate than roots, storage tissues or stems do. There is a distinction between "growth respiration" and "maintenance respiration". Sinks, such as developing fruits, need to be present. They are usually represented by a discrete switch, which is turned on after a certain condition, e.g. critical day length has been met. Care Water supply - Because plants use passive transport to transfer water and nutrients from their roots to the leafs, water supply is essential to growth, even so that water efficiency rates are known for different crops, e.g. 5000 for sugar cane, meaning that each kilogram of produced sugar requires up to 5000 liters of water. Nutrient supply - Nutrient supply has a twofold effect on plant growth. A limitation in nutrient supply will limit biomass production as per Liebig's Law of the Minimum. With some crops, several nutrients influence the distribution of plant products in the plants. A nitrogen gift is known to stimulate leaf growth and therefore can work adversely on the yield of crops which are accumulating photosynthesis products in storage organs, such as ripening cereals or fruit-bearing fruit trees. Phases in crop growth Theoretical production ecology assumes that the growth of common agricultural crops, such as cereals and tubers, usually consists of four (or five) phases: Germination - Agronomical research has indicated a temperature dependence of germination time (GT, in days). Each crop has a unique critical temperature (CT, dimension temperature) and temperature sum (dimensions temperature times time), which are related as follows. When a crop has a temperature sum of e.g. 150 °C·d and a critical temperature of 10 °C, it will germinate in 15 days when temperature is 20 °C, but in 10 days when temperature is 25 °C. When the temperature sum exceeds the threshold value, the germination process is complete. Initial spread - In this phase, the crop does not cover the field yet. The growth of the crop is linearly dependent on leaf area index, which in its turn is linearly dependent on crop biomass. As a result, crop growth in this phase is exponential. Total coverage of field - in this phase, growth is assumed to be linearly dependent on incident light and respiration rate, as nearly 100% of all incident light is intercepted. Typically, the Leaf Area Index (LAI) is above two to three in this phase. This phase of vegetative growth ends when the plant gets a certain environmental or internal signal and starts generative growth (as in cereals and pulses) or the storage phase (as in tubers). 24 Allocation to storage organs - in this phase, up to 100% of all production is directed to the storage organs. Generally, the leafs are still intact and as a result, gross primary production stays the same. Prolonging this phase, e.g. by careful fertilization, water and pest management results directly in a higher harvest. Ripening - in this phase, leafs and other production structures slowly die off. Their carbohydrates and proteins are transported to the storage organs. As a result, the LAI and, hence, the primary production decreases. Existing plant production models Plant production models exist in varying levels of scope (cell, physiological, individual plant, crop, geographical region, global) and of generality: the model can be crop-specific or be more generally applicable. In this section the emphasis will be on crop-level based models as the crop is the main area of interest from an agronomical point of view. As of 2005, several crop production models are in use. The crop growth model SUCROS has been developed during more than 20 years and is based on earlier models. Its latest revision known dates from 1997. The IRRI and Wageningen University more recently developed the rice growth model ORYZA2000. This model is used for modeling rice growth. Both crop growth models are open source. Other more cropspecific plant growth models exist as well. SUCROS SUCROS is programmed in the Fortran computer programming language. The model can and has been applied to a variety of weather regimes and crops. Because the source code of Sucros is open source, the model is open to modifications of users with FORTRAN programming experience. The official maintained version of SUCROS comes into two flavours: SUCROS I, which has non-inhibited unlimited crop growth (which means that only solar radiation and temperature determine growth) and SUCROS II, in which crop growth is limited only by water shortage. ORYZA2000 The ORYZA2000 rice growth model has been developed at the IRRI in cooperation with Wageningen University. This model, too, is programmed in FORTRAN. The scope of this model is limited to rice, which is the main food crop for Asia. Other models The United States Department of Agriculture has sponsored a number of applicable crop growth models for various major US crops, such as cotton, soy bean, wheat and rice. Other widely-used models are the precursor of SUCROS (SWATR), CERES, several incarnations of PLANTGRO, SUBSTOR, the FAOsponsored CROPWAT, AGWATER and the erosion-specific model EPIC. A less mechanistic growth and competition model, called the Conductance Model, has been developed, mainly at Warwick-HRI, Wellesbourne, UK. This model simulates light interception and growth of individual plants based on the lateral expansion of their crown zone areas. Competition between plants is simulated by a set algorithms related to competition for space and resultant light intercept as the canopy closes. Some versions of the model assume overtopping of some species by others. Although the model cannot take account of water or mineral nutrients, it can simulate individual plant growth, variability in growth within plant communities and inter-species competition. This model was written in Matlab. See Benjamin and Park (2007) Weed Research 47, 284-298 for a recent review. 2.2 THE BIOMASS PRODUCTION POTENTIAL OF A FOREST ECOSYSTEM; We can view a forest, a stream, or an ocean as a system that absorbs, transforms, and stores energy. In this view, physical, chemical, and biological structures and processes are inseparable. When we look at natural systems in this way we view them as ecosystems. An ecosystem is a biological community plus all of the abiotic factors influencing that community. Primary production, the fixation of energy by autotrophs, is one of the most important ecosystem processes. The rate of primary production is the amount of energy fixed over some interval of time. Gross primary production is the total amount of energy fixed by all the autotrophs in the ecosystem. Net primary production is the amount of energy left over after autotrophs have met their own energetic needs. Terrestrial primary production is generally limited by temperature and moisture. The variables most highly correlated with variation in terrestrial primary production are temperature and moisture. 25 Highest rates of terrestrial primary production occur under warm, moist conditions. Temperature and moisture conditions can be combined in a single measure called annual actual evapotranspiration, or AET, which is the total amount of water that evaporates and transpires off a landscape during the course of a year. Annual AET is positively correlated with net primary production in terrestrial ecosystems. However, significant variation in terrestrial primary production results from differences in soil fertility. Aquatic primary production is generally limited by nutrient availability. One of the best documented patterns in the biosphere is the positive relationship between nutrient availability and rate of primary production in aquatic ecosystems. Phosphorus concentration usually limits rates of primary production in freshwater ecosystems, while nitrogen concentration usually limits rates of marine primary production. Consumers can influence rates of primary production in aquatic and terrestrial ecosystems. Piscivorous fish can indirectly reduce rates of primary production in lakes by reducing the density of plankton-feeding fish. Reduced density of planktivorous fish can lead to increased density of herbivorous zooplankton, which can reduce the densities of phytoplankton and rates of primary production. Intense grazing by large mammalian herbivores on the Serengeti increases annual net primary production by inducing compensatory growth in grasses. Energy losses limit the number of trophic levels in ecosystems. Ecosystem ecologists have simplified the trophic structure of ecosystems by arranging species into trophic levels based upon the predominant source of their nutrition. A trophic level is determined by the number of transfers of energy from primary producers to that level. As energy is transferred from one trophic level to another, energy is lost due to limited assimilation, respiration by consumers, and heat production. As a result of these losses, the quantity of energy in an ecosystem decreases with each successive trophic level, forming a pyramidshaped distribution of energy among trophic levels. As losses between trophic levels accumulate, eventually there is insufficient energy to support a viable population at a higher trophic level. Stable isotope analysis can be used to trace the flow of energy through ecosystems. The ratios of different stable isotopes of important elements such as nitrogen and carbon are generally different in different parts of ecosystems. As a consequence, ecologists can use isotopic ratios to study the trophic structure and energy flow through ecosystems. Stable isotope analysis has helped quantify dietary composition of wild populations and the major sources of energy used by prehistoric human populations. Primary Production and Energy Flow Suntight shines down on the canopy of a forest-- some is reflected, some is converted to heat energy, and some is absorbed by chlorophyll. Infrared radiation is absorbed by the molecules in organisms, soil, and water, increasing their kinetic state and raising the temperature of the forest. Forest temperature affects the rate of biochemical reactions and transpiration by forest vegetation. Forest plants use photosynthetically active solar radiation, or PAR, to synthesize sugars. The plants use some of this fixed energy to meet their own energy needs. Some fixed energy goes directly into plant growth: to produce new leaves, to lengthen the tendrils of vines, to grow new root hairs, and so forth. Some fixed energy is stored as nonstrucrural carbohydrates, which act as energy stores in roots, seeds, or fruits. Photosynthesis may increase forest biomass. A portion of the energy fixed by forest vegetation is consumed by herbivores, some is consumed by detritivores, and some ends up as soil organic matter. Energy fixed by forest vegetation powers bird flight through the forest canopy and fuels the muscle contractions of earthworms as they burrow through the forest soil. The forest vegetation is sunlight transformed, as are all the associated bacteria, fungi, and animals and all their activities (fig. 18.1). 26 We can view a forest as a system that absorbs, transforms, and stores energy. In this view, physical, chemical, and biological structures and processes are inseparable. When we look at a forest (or stream or coral reef) in this way we view it as an ecosystem. An ecosystem is a biological community plus all of the abiotic factors influencing that community. The term ecosystem and its definition were first proposed in I935 by the British ecologist Arthur Tansley. Sometime during his exploration of nature, he realized the importance of considering organisms and their environment as an integrated system. Tansley wrote: "Though the organisms may claim our primary interest .... we cannot separate them from their special environment, with which they form one physical system. It is the [eco]systems so formed which, from the point of view of the ecologist, are the basic units of nature on the face of the earth." FIGURE 18.1 In most ecosystems, sunlight Ecosystem ecologists study the flows of energy, water, and nutrients in ecosystems and, as suggested provides the ultimate source of energy to by Tansley, pay as much attention to physical and power all biological activity, such as the chemical processes as they do to biological one. Some singing of this treefrog and the growth of fundamental areas of interest for ecosystem ecologists the plant on which it sits. are primary production, energy flow, and nutrient cycling. The photosynthetic machinery of plants uses solar energy to synthesize sugars. To considered photosynthesis from the perspective of the individual grass, tree, or cactus. Here we discuss the biochemical and physiological details of photosynthesis and even from the individual organism to look at photosynthesis at the level of the whole ecosystem. Primary production is the fixation of energy by autotrophs in an ecosystem. The rate of primary production is the amount of energy fixed over some interval of time. Ecosystem ecologists distinguish between gross and net primary production. Gross primary production is the total amount of energy fixed by all the autotrophs in the ecosystem. Net primary production is the amount of energy left over after autotrophs have met their own energetic needs. Net primary production is gross primary production minus respiration by primary producers; it is the amount of energy available to the consumers in an ecosystem. Ecologists have measured primary production in a variety of ways but mainly as the rate of carbon uptake by primary producers or by the amount of biomass or oxygen produced. Ecosystem ecologists have simplified the trophic structure of ecosystems by arranging species into trophic levels based on the predominant source of their nutrition. A trophic level is a position in a food web and is determined by the number of transfers of energy from primary producers to that level. Primary producers occupy the first trophic level in ecosystems since they convert inorganic forms of energy, principally light, into biomass. Herbivores and detritivores are often called primary consumers and occupy the second trophic level. Carnivores feeding on herbivores and detritivores are called secondary consumers and occupy the third trophic level. Predators that feed on carnivores occupy a fourth trophic level. Since each trophic level may contain several species, in some cases hundreds, an ecosystem perspective simplifies trophic structure. Primary production, the conversion of inorganic forms of energy into organic forms, is a key ecosystem process. All consumer organisms, including humans, depend upon primary production for their existence. Because of its importance and because rates of primary production vary substantially from one ecosystem to another, ecosystem ecologists study the factors controlling rates of primary production in ecosystems. Patterns of natural variation in primary production provide clues to the environmental factors that control this key ecosystem process. Experiments test the importance of those controls, we discuss the 27 major patterns of variation in primary production in terrestrial and aquatic ecosystems and key experiments designed to determine the mechanisms producing those patterns. CASE HISTORIES: Patterns of terrestrial primary production Terrestrial primary production is generally limited by temperature and moisture. The major terrestrial biomes of the geographic variation in rates of primary production. Perhaps you also developed a feeling for the major environmental correlates with that variation. The variables most highly correlated with variation in terrestrial primary production are temperature and moisture. Highest rates of terrestrial primary production occur under warm, moist conditions. Actual Evapotranspiration and Terrestrial Primary Production Michael Rosenzweig (1968) estimated the influence of moisture and temperature on rates of primary production by plotting the relationship between annual net primary production and annual actual evapotranspiration. Annual actual evapotranspiration (AET) is the total amount of water that evaporates and transpires off a landscape during the course of a year and is measured in millimeters of water per year. The AET process is affected by both temperature and precipitation. The ecosystems showing the highest levels of primary production are those that are warm and receive large amounts of precipitation. Conversely, ecosystems show low levels of AET either because they receive little precipitation, are very cold, or both. For instance, both hot deserts and tundra exhibit low levels of AET. Figure 18.2 shows Rosenzweig's plot of the positive relationship between net primary production and AET. Tropical forests show the highest levels of net primary production and AET. At the other end of the spectrum, hot, dry deserts and cold, dry tundra show the lowest levels. Intermediate levels occur in temperate forests, temperate grasslands, Woodlands, and high-elevation forests. Figure 18.2 shows that AET accounts for a significant proportion of the variation in annual net primary production among terrestrial ecosystems. FIGURE 18.2 Relationship between actual evapotranspiration and net aboveground primary production in a series of terrestrial 28 ecosystems (data from Rosenzweig 1968). Rosenzweig's analysis attempts to explain variation in primary production across the whole spectrum of terrestrial ecosystems. What controls variation in primary production within similar ecosystems? O. E. Sala and his colleagues (1988) at Colorado State University explored the factors controlling primary production in the central grassland region of the United States. Their study was based on data collected by the U.S. Department of Agriculture Soil Conservation Service at 9,498 sites. To make this large data set more manageable, the researchers grouped the sites into 100 representative study areas. The study areas extended from Mississippi and Arkansas in the east to New Mexico and Montana in the west and from North Dakota to southern Texas. Primary production was highest in the eastern grassland study areas and lowest in the western study areas. This east-west variation corresponds to the westward changes from tall-grass prairie to short-grass prairie that we reviewed in chapter 2. Sala and his colleagues found that this east-west variation in primary production among grassland ecosystems correlated significantly with the amount of rainfall (fig. 18.3). Compare the plot by Sala and his colleagues (fig. 18.3) with the one constructed by Rosenzweig (fig.18.2). How are they similar? How are they different? Both graphs have primary production plotted on the vertical axis as a dependent variable. However, while the Rosenzweig plot includes ecosystems ranging from tundra to tropical rain forest, the plot by Sala and his colleagues includes grasslands only. In addition, different variables are plotted on the horizontal axes of the two graphs. While Rosenzweig plotted actual evapotranspiration, FIGURE 18.3 Influence of annual precipitation on net aboveground which depends upon temperature and primary production in grasslands of central North America (data from Sala et al. 1988). precipitation, Sala and his colleagues plotted precipitation only. They found that including temperature in their analysis did not improve their ability to predict net primary production. Why do you think precipitation alone was sufficient to account for most of the variation in grassland production? A likely reason is that warm temperatures occur during the growing season at all of the study areas included by Sala and his colleagues. In contrast, Rosenzweig's study areas vary widely in growing season temperature. These researchers found strong correlations between AET or precipitation and rates of terrestrial primary production. However, their models did not completely explain the variation in primary production among the study ecosystems. For instance, in figure 18.2 ecosystems with annual AET levels of 500 to 600 mm of water showed annual rates of primary production ranging from 300 to 1,000 g per square meter. In figure 18.3, grassland ecosystems receiving 400 mm of annual precipitation had annual rates of primary production ranging from about 100 to 250 g per square meter. These differences in primary production challenge ecologists for an explanation. Soil Fertility and Terrestrial Primary Production Significant variation in terrestrial primary production can be explained by differences in soil fertility. Farmers have long known that adding fertilizers to soil can increase agricultural production. However, it was not until the nineteenth century that scientists began to quantify the influence of specific nutrients, 29 such as nitrogen (N) or phosphorus (P), on rates of primary production. Justus Liebig (1840) pointed out that nutrient supplies often limit plant growth. He also suggested that nutrient limitation to plant growth could be traced to a single limiting nutrient. This hypothetical control of primary production by a single nutrient was later called "Liebig's Law of the Minimum." We now know that Liebig's perspective was too simplistic. Usually several factors, including a number of nutrients, simultaneously affect levels of terrestrial primary production. However, his work led the way to a concept that remains true today; variation in soil fertility can significantly affect rates of terrestrial primary production. Liebig's work, and most practical experience prior to Liebig, concerned the productivity of agricultural ecosystems. Do nutrients influence rates of primary production in other ecosystems, such as the tundra or deserts, where human manipulation has been less prominent? Ecologists have demonstrated the significant influence of nutrients on terrestrial primary production through numerous experiments involving addition of nutrients to natural ecosystems. Ecologists have increased primary production by adding nutrients to a wide variety of terrestrial ecosystems, including arctic tundra, alpine tundra, grasslands, deserts, and forests. For instance, Gaius Shaver and Stuart Chapin (1988) studied the potential for nutrient limitation in arctic tundra. They added commercial fertilizer containing nitrogen, phosphorus, and potassium to several tundra ecosystems in Alaska. They made a single application of fertilizer to half of their experimental plots and two applications to the remaining experimental plots. Shaver and Chapin measured net primary production at their control and experimental sites 2 to 4 years after the first nutrient additions. Nutrient additions increased net primary production (by 23%300%) at all of the study sites. The response to fertilization was substantial and clear at most study sites. Four years after the initial application of fertilizer, net primary production on Kuparuk Ridge was twice as high on the fertilized plots compared to the unfertilized control plots (fig. 18.4). Nutrient additions to alpine tundra indicate that the response of ecosystems to nutrient addition is affected by prior nutrient availability. William Bowman and his colleagues (1993) added nutrients to the alpine tundra on Niwot Ridge, Colorado. They conducted their experiment in adjacent dry alpine and wet alpine meadows at an elevation of 3,510 m. One of four treatments was applied in both the dry and wet alpine meadows: (l) control (no nutrient additions), (2) nitrogen added, (3) phosphors added, and FIGURE 18.4 Effect of addition of nitrogen, (4) nitrogen phosphorus, and potassium on net aboveground and phosphorus added. primary production in Arctic tundra (data from The researchers then Shaver and Chapin 1986). measured soil nitrogen and phosphorus concentrations and annual net primary production in each study plot. 30 Initial concentration of both nitrogen and phosphorus were higher in the wet meadow ecosystem~ And while fertilizing raised the concentrations of both nitrogen and phosphorus in the dry meadow, fertilizing the wet meadow raised the concentration of nitrogen but not phosphorus. Fertilizing produced greater increases in primary production in the dry meadow than in the wet meadow. Adding nitrogen to the dry meadow increased primary production by 63%. Adding nitrogen and phosphorus increased primary production by 178%. In contrast, the wet meadow only showed relatively small but statistically significant responses to the additions of both nitrogen and phosphorus (fig. 18.5). Bowman and his colleagues suggest that these results show that nitrogen is the main nutrient limiting net primary production in the dry meadow and that nitrogen and phosphorus jointly limit net primary production in the wet meadow. They also suggest that light, not nutrients, may limit net primary production in the wet meadow. In other words, the higher biomass in the wet meadow may have produced enough shading to inhibit the growth response of some species to nutrient additions. Experiments such as these have shown that despite the major influence FIGURE 18.5 Effect of adding phosphorus (P) and/or nitrogen (N) on of temperature and aboveground primary production in two environments in alpine tundra moisture on rates of (clara from Bowman et al. 1993). primary production in terrestrial ecosystems, variation in nutrient availability can also have measurable influence. As we shall see in the next Case Histories section, nutrient availability is the main factor limiting primary production in aquatic ecosystems. CASE HISTORIES: patterns of aquatic primary production Aquatic primary production is generally limited by nutrient availability. Limnologists and oceanographers have measured rates of primary production and nutrient concentrations in many lakes and at many coastal and oceanic study sites. These studies have produced one of the best documented patterns in the biosphere: the positive relationship between nutrient availability and rate of primary production in aquatic ecosystems. Patterns and Models A quantitative relationship between phosphorus, an essential plant nutrient, and phytoplankton biomass was first described for a series of lakes in Japan (Hogetsu and Ichimura 1954, Ichimura 1956, Sakamoto 1966). The ecologists studying this relationship found a remarkably good correspondence between total phosphorus and phytoplankton biomass. Later, Dillon and Rigler (1974) described a similar positive relationship between phosphorus and phytoplankton biomass for lake ecosystems throughout the Northern Hemisphere. Remarkably, the slopes of the lines describing the relationship between phosphorus and phytoplankton biomass for the Japanese and Canadian lakes were nearly identical (fig. 18.6). 31 The data from Japan and North America strongly support the hypothesis that nutrients, particularly phosphorus, control phytoplankton biomass in lake ecosystems. However, what is the relationship between phytoplankton biomass and the rate of primary production? This relationship was explored by Val Smith (1979) for 49 lakes of the north temperate zone. The data from these lakes showed a strong positive correlation between chlorophyll concentrations and photosynthetic rates (fig. 18.7). Smith also examined the relationship between total phosphorus concentration and photosynthetic rate directly. Aquatic ecologists have extended these correlational studies of the relationship between nutrient availability and primary production by manipulating nutrient availability in entire lake ecosystems. Whole Lake Experiments on Primary Production FIGURE 18.6 Relationship between phosphorus concentration and algal biomass in north temperate lakes (data from Dillon and Rigler 1974). The Experimental Lakes Area was founded in northwestern Ontario, Canada, in 1968 as a place in which aquatic ecologists could manipulate whole lake ecosystems (Mills and Schindler 1987, Findlay and Kasian1987). For instance, ecologists manipulated nutrient availability in a lake called Lake 226. They used a vinyl curtain to divide Lake 226 into two 8 ha basins each containing about 500,000 m3 of water. Think about these numbers for a second. This was a huge experiment! Each subbasin of Lake 226 was fertilized FIGURE 18.7 Relationship between algal biomass and rate of from 1973 to 1980. The primary production in temperate zone lakes (data from Smith 1979). researchers added a mixture of carbon in the form of sucrose and nitrate to one basin and carbon, nitrate, and phosphate to the other basin. They stopped fertilizing the lakes after 1980 and then studied the recovery of the Lake 226 ecosystem from 1981 to 1983. Both sides of Lake 226 responded significantly to nutrient additions. Prior to the manipulation, Lake 226 supported about the same biomass of phytoplankton as two reference lakes (fig. 18.8). However, when experimenters began adding nutrients, the phytoplankton biomass in Lake 226 32 quickly surpassed that in the reference lakes. Phytoplankton biomass remained elevated in Lake 226 until the experimenters stopped adding fertilizer at the end of 1980. Then, from 1981 to 1983 the phytoplankton biomass in Lake 226 declined significantly. In conclusion, both correlations-between phosphorus concentration and rate of primary production, and whole lake experiments, involving nutrient additions---support the generalization that nutrient availability controls rates of primary production in freshwater ecosystems. Now, let's examine the evidence for this relationship in marine ecosystems. Global Patterns of Marine Primary Production The geographic distribution of net primary production in the sea indicates a positive influence of nuUient availability on rates of primary production. Oceanographers have observed FIGURE 18.8 A whole lake experiment shows the effect of nutrient on average phytoplankton biomass (data that the highest rates of primary additions from Findlay and Kasian 1987). production by marine phytoplankton are generally concentrated in areas with higher levels of nutrient availability (fig. 18.9). The highest rates of primary production are concentrated along the margins of continents over continental shelves and in areas of upwelling. Along continental margins nutrients are renewed by runoff from the land and by biological or physical disturbance of bottom sediments. As we saw in chapter 3, the upwelling that brings nutrientladen water from the depths to the surface is concentrated along the west coasts of continents and around the continent of Antarctica, areas that appear dark red on figure 18.9, indicating high to very high rates of primary production. FIGURE 18.9 Geographic variation in marine primary production (data from F.A.O. 1972). Meanwhile, the central portions of the major oceans show low levels of nutrient availability and low rates of primary production. The main source of nutrient renewal in the surface waters of the open 33 ocean is vertical mixing. Vertical mixing is generally blocked in open tropical oceans by a permanent thermocline. Consequently, the surface waters of open tropical oceans contain very low concentrations of nutrients and show some of the lowest rates of marine primary production. What is the experimental evidence for nutrient limitation of marine primary production? Some of the most thorough studies have been conducted in the Baltic Sea. For instance, Edna Graneli and her colleagues (1990) have used nutrient enrichment to test whether nutrient availability limits primary production in the Baltic Sea. In a test using a single algal species, Graneli added nutrients to filtered seawater from a series of study sites. She added nitrate to one experimental group, phosphates to another, and nothing to a third group of flasks (fig. 18.10). Notice that the flasks with additional nitrate showed increased chlorophyll a concentrations at all sites, while the flasks with additional phosphate had chlorophyll a concentrations very similar to the control flasks. What do these results indicate? They suggest that the rate of primary production in the Baltic Sea is limited by nutrients. However, in contrast to most freshwater lakes, the limiting nutrient appears to be nitrogen, not phosphorus. 34 Graneli did similar enrichment studies along a series of stations in the Kattegat, the Belt Sea, and the Skagerrak, where the salinity approaches that of the open ocean. However, in this second series of experiments, she used indigenous phytoplankton rather than a single standardized test species. Once again the concentrations of chlorophyll a were higher in the flasks to which nitrate had been added while the control and phosphate treatment groups were virtually indistinguishable. Again, the results indicate nitrogen limitation along virtually the entire study area. There have been no experiments done in the marine environment that are equivalent to the whole lake manipulations at the Experimental Lakes Area (e.g., Schindler 1990). However, in one experiment, researchers were able to alter the nutrient inputs and concentrations in Himmer fjard, Sweden, a brackish water coastal inlet of the Baltic Sea with a surface area of 195 km2 (see fig. 18.10). (For comparison, the lake sub basins manipulated in the whole lake experiments were < 0.1 km2.) The results of this manipulative experiment indicate that nitrogen FIGURE 18.10 Nitrate control of primary production in the Baltic limitation of primary Sea (data frorn Graneli etal. 1990). production can shift to phosphorus limitation by altering nitrogen: phosphorus ratios. Increasing additions of phosphorus to Himmer fjord reinforced nitrogen limitation, while decreasing phosphorus additions and increasing nitrogen additions led to increased phosphorus limitation. Dillon and Rigler suggested that limnologists pay attention to the scatter of points around lines showing a relationship between nutrient concentrations and phytoplankton biomass (F.A.O. 1972). We call that scatter of points residual variation. Residual variation is that proportion of variation not explained by the independent variable, in this case, by nutrient concentration. Dillon and Rigler suggested that environmental factors besides nutrient availability significantly influence phytoplankton biomass. One of those factors is the intensity of predation on the zooplankton that feed on phytoplankton. As we 35 shall see in the next Case Histories section, consumers can influence rates of primary production in both terrestrial and aquatic ecosystems. CASE HISTORIES: consumer influences Consumers can influence rates of primary production in aquatic and terrestrial ecosystems. In the first section of this chapter, we emphasized the effects of physical and chemical factors on rates of primary production. More recently, ecologists have discovered that primary production is also affected by consumers. Ecologists refer to the influences of physical and chemical factors, such as temperature and nutrients, on ecosystems as bottom-up controls. The influences of consumers on ecosystems are known as top-down controls. In the previous two sections we discussed bottom-up controls on rates of primary production. Here we discuss top-down control. Piscivores, Planktivores, and Lake Primary Production Stephen Carpenter, James Kitchell, and James Hodgson (1985) proposed that while nutrient inputs determine the potential rate of primary production in a lake, piscivorous and planktivorous fish can cause significant deviations from potential primary production. In support of their hypothesis, Carpenter and his colleagues (1991) cited a negative correlation between zooplankton size, an indication of grazing intensity, and primary production. Carpenter and Kitchell (1988) proposed that the influences of consumers on lake primary production propagate through food webs. Since they visualized the effects of consumers coming from the top of food webs to the base, they called these effects on ecosystem properties "trophic cascades.'' The trophic cascade hypothesis (fig. 18.11) is very similar to the keystone species hypothesis (see chapter 17). However, notice that thetrophic cascade model is focused on the effects of consumers on ecosystem processes, such as primary production, and not on their effects on species diversity. 36 Carpenter and Kitchell (1993) interpreted the trophic cascade in their study lakes as follows: Piscivores, such as largemouth bass, feed on planktivorous fish and invertebrates. Because of their influence onplanktivorous fish, largemouth bass indirectly affect populations of zooplankton. By reducing populations of planktivorous fish, largemouth bass reduce feeding pressure on zooplankton and zooplankton populations. Large-bodied zooplankton, the preferred prey of sizeselective planktivorous fish (see chapter 6), soon dominate the zooplankton community. A dense population of large zooplankton reduces phytoplankton biomass and the rate of primary production. This interpretation of the trophic cascade is consistent with the negative correlation between zooplankton body size and primary production reported by Carpenter and his research team. This FIGURE 18.11 The trophic cascade hypothesis. hypothesis is summarized in figure 18.12. 37 FIGURE 18.12 Predicted effects of piscivores on planktivore, herbivore, and phytoplankton biomass and production (data from Carpenter: Kitchell, and Hodgson 1985). Carpenter and Kitchell tested their trophic cascade model by manipulating the fish communities in two lakes and using a third lake as a control. Figure 18.13 shows the overall design of their experiment. Two of the lakes contained substantial populations of largemouth bass. A third lake had no bass, due to occasional winterkill, but contained an abundance of planktivorous minnows. The researchers removed 90% of the large-mouth bass from one experimental lake and put them into the other. They simultaneously removed 90% of the planktivorous minnows from the second lake and introduced them to the first. They left a reference lake unmanipulated as a control. The responses of the study lakes to the experimental manipulations support the trophic cascade hypothesis (fig. 18.13). Reducing the planktivorous fish population led to reduced rates of primary production. In the absence of planktivorous minnows, the predaceous invertebrate Chaoborus became more numerous. Chaoborus fed heavily upon the smaller herbivorous zooplankton, and the herbivorous zooplankton assemblage shifted in dominance from small to large species. In the presence of abundant, large herbivorous zooplankton, phytoplankton biomass and rate of primary production declined. 38 FIGURE 18.13 Experimental manipulations of ponds and responses. Adding planktivorous minnows produced a complex ecological response. Increasing the planktivorous fish population led to increased rates of primary production. However, though the researchers increased the population of planktivorous fish in this experimental lake, they did so in an unintended way. Despite the best efforts of the researchers, a few bass remained. So, by introducing a large number of minnows they basically fed the remaining bass. An increased food supply combined with reduced population density induced a strong numerical response by the bass population (see chapter 10). The manipulation increased the reproductive rate of the remaining largemouth bass 50-fold, producing an abundance of young largemouth bass that feed voraciously on zooplankton. The lake ecosystem responded to the increased biomass of planktivorous fish (young largemouth bass) as predicted at the outset of the experiment. The biomass of zooplankton decreased sharply, the average size of herbivorous zooplankton decreased, and phytoplankton biomass and primary production increased. The results of these whole lake experiments show that the trophic activities of a few species can have large effects on ecosystem processes. However, the majority of trophic cascades described by ecologists have been in aquatic ecosystems with algae as primary producers. This pattern prompted Donald Strong (1992) to ask, "Are trophic cascades all wet?'' Strong suggested that trophic cascades most likely occur in ecosystems of lower species diversity and reduced spatial and temporal complexity. These are characteristics of many aquatic ecosystems. Despite these restrictions, consumers have significant effects on rates of primary production in some terrestrial ecosystems; one of those is the Serengeti grassland ecosystem. Grazing by Large Mammals and Primary Production on the Serengeti The Serengeti-Mara a 25,000 km2 grassland ecosystem that straddles the border between Tanzania and Kenya, is one of the last ecosystems on earth where great numbers of large mammals still roam freely. SamMcNanghton (1985) reported estimated densities of the major grazers in the Serengeti that included 1.4 million wildebeest, Connochaetes taurinus albujubatus, 600,000 Thomson's gazelle, GazeUa thomsonii, 200,000 zebra, Equus burchelli, 52,000 buffalo, Syncerus eaffer, 60,000 topi, Damaliscus korrigum, and large numbers of 20 additional grazing mammals. McNaughton estimated that these grazers consume an average of 66% of the annual primary 39 production on the Serengeti. In light of this estimate, the potential for consumer influences on primary production seems very high. Over two decades of research on the Serengeti ecosystem in Tanzania led McNaughton to appreciate the complex interrelations of abiotic and biotic factors there. For instance, both soil fertility and rainfall stimulate plant production and the distributions of grazing mammals. However, grazing mammals also affect water balance, soil fertility, and plant production. As you might predict, the rate of primary production on the Serengeti is positively correlated with the quantity of rainfall. However, McNaughton (1976) also found that grazing can increase primary production. He fenced in some areas in the western Serengeti to explore the influence of herbivores on production. The migrating wildebeest that flooded into the study site grazed intensively for 4 days, consuming approximately 85% of plant biomass. During the month after the wildebeest left the study area, biomass within the enclosures decreased, while the biomass of vegetation outside the enclosures increased (fig. 18.14). Grazing increases the growth rate of many grass species, a response to grazing called compensatory growth. The mechanisms underlying compensatory growth include lower rates of respiration due to lower plant biomass reduced self-shading. and improved water balance due to reduce leaf area. FIGURE 18.14 Growth response by grasses grazed by wildebeest (data from McNaughton 1976). The compensatory growth observed by McNanghton was highest at intermediate grazing intensities (fig. 18.15). Apparently, light grazing is insufficient to produce compensatory growth and very heavy grazing reduces the capacity of the plant to recover. The large grazing mammals of the Serengeti have substantial influences on its rate of primary production. As McNanghton put it, "African ecosystems cannot be understood without close consideration of the large mammals. These animals interact with their habitats in complex and powerful patterns influencing ecosystems for long periods." 40 What McNaughton and his colleagues described is essentially atrophic cascade in a terrestrial environment where the feeding activities of consumers have a major influence on ecosystem properties. The Serengeti is now an exceptional terrestrial ecosystem but it was not always so. As we saw in chapter 2, the extensive grasslands of North America and Eurasia were also once populated by vast herds of mammalian grazers. Historians estimate that the population of North American bison in the middle of the nineteenth century numbered up to 60 million. Such a dense concentration of grazers must have had significant influences upon the grassland ecosystems of which they were part. It appears that terrestrial FIGURE 18.15 Grazing intensity and primary production of Serengeti consumers, as well as the grassland (data from McNaughton 1985). aquatic ones studied by Carpenter and Kitchell, can have important influences on primary production. In the Serengeti, lions are the top predators. Though they are occasionally killed by hyenas, there are no predators that depend principally upon hunting lions as a source of energy. In the ponds studied by Carpenter and Kitchell, largemouth bass were the top carnivores. The number of trophic levels in ecosystems ranges from two to five or six, perhaps seven or eight in exceptional ecosystems. In any case, ecosystems have a limited number of trophic levels. What limits the number of trophic levels? We will consider the factors that limit the number of trophic levels in ecosystems in the next section. CASE HISTORIES: trophic levels Energy losses limit the number of trophic levels in ecosystems. We began this chapter with a partial and highly qualitative energy budget for a forest: Sunlight shines down on the canopy of a forest--some is reflected, some is converted to heat energy, and some is absorbed by chlorophyll. The energy budgets of ecosystems reveal that with each transfer or conversion of energy, some energy is lost. To verify that these losses have the potential to limit the number of tropbic levels in ecosystems, we need to quantify the flow of energy through ecosystems. One of the very first ecologists to quantify the flux of energy through ecosystems was Raymond Lindeman. A Trophic Dynamic View of Ecosystems Raymond Lindeman (1942) received his Ph.D. from the University of Minnesota in 1941, where his studies of the ecology of Cedar Bog Lake led him to a view of ecosystems far ahead of its time. Lindeman went from Minnesota to Yale University, where his association with G. E. Hutchinson from 1941 to 1942 led to the publication of a revolutionary paper with the provocative title, "The TrophicDynamic Aspect of Ecology." In this paper, Lindeman articulated a view of ecosystems centered on energy fixation, storage, and flows that remains influential to this day. Like Tansley before him, Lindeman pointed out the difficulty and artificiality of separating organisms from their environment and promoted an ecosystem view of nature. Lindeman concluded that the ecosystem concept is fundamental to the study of trophic dynamics, which he defined as the transfer of energy from one part of an ecosystem to another 41 Lindeman suggested grouping organisms within an ecosystem into trophic levels: primary producers, primary consumers, secondary consumers, tertiary consumers, and so forth. In this scheme, each trophic level feeds on the one immediately below it. Energy enters the ecosystem as primary producers engage in photosynthesis and convert solar energy into biomass. As energy is transferred from one trophic level to another, energy is lost due to limited assimilation, respiration by consumers, and heat production. As a result of these losses, the quantity of energy in an ecosystem decreases with each successive trophic level, forming a pyramid-shaped distribution of energy among trophic levels. Lindeman called these trophic pyramids "Eltonian pyramids," since Charles Elton (1927) was the first to propose that the distribution of energy among trophic levels is shaped like a pyramid. Figure 18.16 shows the distribution of annual primary production among trophic levels in Cedar Bog Lake and in Lake Mendota, Wisconsin. Energy losses at each trophic level determine the trophic structure of these two ecosystems. As predicted by Elton, the distribution of energy across trophic levels in both lakes is shaped like a pyramid. As suggested at the beginning of this section, the number of trophic levels is limited in both lakes. Lake Mendota includes four trophic levels, while Cedar Bog Lake includes just three. FIGURE 18.16 Annual production by trophic level in two lakes (data from Lindeman 1942). Following Lindeman's pioneering work, many other ecologists studied energy flow within ecosystems. One of the most comprehensive of these later studies focused on the Hubbard Brook Experimental Forest in New Hampshire. Energy Flow in a Temperate Deciduous Forest James Gosz and his colleagues (1978) studied energy flow in the Hubbard Brook Experimental Forest, which is managed for research by the U.S. Forest Service. They concentrated their efforts on a stream catchment called watershed 6, which was left undisturbed so it could serve as a control for experimental studies on other stream catchments. The energy flow in the Hubbard Brook Experimental Forest was quantified as kilocalories (kcal) per square meter per year. The results of the analysis are shown in figure 18.17. 42 FIGURE 18.17 Energy budget for a temperate deciduous forest (data from Gosz et al. 1978). First let's examine the distribution of organic matter among the major components of the Hubbard Brook ecosystem. The largest single pool of energy in the forest, 122,442 kcal/m2, occurred as dead organic matter. Most of the dead organic matter, 88,120 kcal/m2, was organic matter in the upper 36 cm of soil. The remainder, 34,322 kcal/m2, occurred as plant litter on the forest floor. Total living-plant biomass amounted to 71,420 kcal/m2, of which 59,696 kcal/m2 was stored in above ground biomass and 11,724 kcal/m2 as belowground biomass. The total standing stock of energy occurring as dead organic matter and living plant biomass was 193,862 kcal/m2. This estimate by Gosz and his colleagues dwarfs the energy stored in all other portions of the ecosystem. For instance, the energetic content of a caterpillar population during a severe population outbreak amounted to only 160 kcal/m2. However, even this amount far exceeds the total energetic content of all vertebrate biomass. The researchers estimated that the total energetic content of the most numerous vertebrates, including chipmunks, mice, shrews, salamanders, and birds, amounted to less than 1 kcal/m2. Now that we have inventoried the major standing stocks of energy, let's look at energy flow through the Hubbard Brook Forest. The main source of energy for the ecosystem is solar radiation. The total input of solar energy to the study area during the growing season was estimated to be 480,000 kcal/m2 (expressed as 100% in fig. 18.17). Of this total energy input, 15% was reflected, 41% was converted to heat, and 42% was absorbed during evapotranspiration. About 2.2% of the solar input was fixed by plants as gross primary production. Plant respiration accounted for 1.2%, leaving about 1% as net primary production. In other words, only about 1% of the solar input to the Hubbard Brook ecosystem was available to the herbivores and detritivores that made up the second trophic level. 2 About 1,199 kcal/m of net primary production in the Hubbard Brook Forest went into plant growth. Herbivores consumed only about 41 kcal/m2, approximately 1% of net primary production. Most of the energy available to consumers, approximately 3,037 kcal/m2, occurred as surface litter fall. About 150 kcal/m2 of the litter fall was stored as organic matter on the forest floor. The remainder was used by 43 consumers. An additional source of detritus, amounting to 437 kcal/m2, occurred belowground as root exudates and litter. Most of the energy consumed by grazers and detritivores, approximately 3,353 kcal/m2, was lost as consumer respiration. Now let's go back to the concept that started this section: Energy losses limit the number of trophic levels in ecosystems. The energy budget carefully constructed by Gosz and his colleagues gives us a basis for understanding this concept. Net primary production in the Hubbard Brook Forest ecosystem was less than 1% of the input of solar energy. In other words, over 99% of the solar energy available to the Hubbard Brook was unavailable for use by a second trophic level. Of the net primary production available to consumers, approximately 96% is lost as consumer respiration. This leaves very little for a third trophic level. It is such losses with each transfer of energy in a food chain that limit the number of trophic levels. As these losses between trophic levels accumulate, eventually there is insufficient energy left over to support a viable population at a higher trophic level. The top predator on the African savanna is the lion. We might imagine predators fierce enough to prey on lions, but the energetics of energy conversion and transfer within ecosystems would preclude such a predator. We can see from the studies of Gosz and his colleagues and others that ecosystems depend upon an outside input of energy. Ecosystems store some energy in the form of dead organic matter and biomass, but most energy flows through. As we shall see in chapter 19, however, ecosystems recycle elements such as nitrogen and sulfur. In the next Applications and Tools section we review how forms of these and other elements can be used as a tool to determine the trophic structure of ecosystems. 2.3 PRODUCTION OF ENERGY WOOD AT SPECIAL SHORT-ROTATION PLANTATIONS; The Production of Short-rotation Woody Crops Eucalyptus species constitute about 38% of all short-rotation plantations worldwide and hardwoods in general make up about 63% of all plantations. In temperate regions, poplar, willow, and black locust predominate. Ranney estimates that about 10 million ha could be classified as short-rotation plantations. 23 However, he notes that less than half of this planted area could be termed as successful or commercially viable. Ranney's technical criteria for successful plantations for energy use are described as follows (with slight modification): more than 80% survival of planted materials; annual productivity greater than 10-12 dry tonnes/ha of harvested wood and bark; uniformity in diameter, height and straightness; less than $50/dry tonne in delivered cost; and less than 2 tonnes/ha in erosion each year. This chapter discusses the factors to consider in site and species selection, plantation establishment, maintenance and protection as well as yield expectations to achieve the above measures of success. In addition, some of the distinctive aspects of producing trees on short-rotations versus practices used for producing timber in longer rotations will be addressed. More detailed technical information suitable for landowners or companies considering woody crop establishment may be located in some of the references provided in the notes to this chapter. Site Selection It is often assumed that tropical countries have a major advantage over temperate regions with regard to biomass production, but this is not necessarily true. While total annual biomass production does increase from higher latitudes towards the equator, the increase is primarily in leaf production rather than wood production 44 Fig. 2.1. Annual production of wood and leaf biomass of natural forests across a latitudinal gradient from the Boreal Zone to the Tropics.25 In general, the annual wood production of native tropical forests is slightly less than that of high latitude native forests. Reasons for the lower production rates of lowland tropical forests include acidic, highly leached soils and warm temperatures that increase respiration rates and burn off carbon that would otherwise be used to produce wood. Fortunately, wellmanaged plantations on good sites in tropical and temperate zones can achieve yields 2 to 10 times higher than natural forests. Examples of plantation yield levels currently being achieved around the world are summarized in Table 1. Table 2.1. Plantation biomass annual production rates from around the world Species High Yield Average Yield dry tonnes/ha Production Region References26 Poplar 43 9-20 Eastern US & Pacific Northwest Wright, 1994 Eucalyptus 30 21 13-15 5-8 12.5 NW Spain SW Spain Spain San Miguel, 1988 9-26a Mid Brazil Hall et al, 1993 Eucalyptus Eucalyptus 27 13-27 Hawaii Whitesell et al, 1992 Willow 24 13-24b Northeast US White, 1995 Willow 14 8-14 Sweden Willebrand et.al 1993 Willow 23 13-23 Sweden Christinson, 1987 Eucalyptus 28 3-21 NE Brazil Carpentieri et al 1993 At a global scale, soil fertility generally decreases toward the equator. At a regional scale there is variation in soil properties relevant to tree growth at scales ranging from 10's of meters to entire continents. Any farmer or forester is familiar with variations in soil fertility that produce great differences in crop production across areas as small as a hectare. Factors such as soil depth, water availability, pH, texture and slope are all extremely important to crop production potential. While naturally fertile soils are most desirable, there are instances where poorer soils can be managed.24 Soils with moderate limitations can be used, if technologies are available to manage the soils effectively. These lands with moderate limitations require careful planning and management to avoid problems related to erosion and water quality, and soil nutrient deficiencies. One of the first challenges for any commercial activity requiring short-rotation plantations is to determine where suitable and available lands are located. A favorable site may allow a project to survive initial mistakes or miscalculations, while an unfavorable site requires great technical expertise, and even simple errors can result in major setbacks or failure. In site selection, there is no substitute for test plots of the potential tree species on the range of soils present on the prospective sites. A potentially disastrous consequence of over-estimation of yield is the under-estimation of planted area needed to support a power plant. With the increased plantation area needed on unfavorable, low productivity sites comes increasing expenses for road and harvesting infrastructure, increasing haul distances, less efficient harvesting, and greater potential impacts on the environment, society, and biodiversity. 45 Site selection must consider and balance a wide range of biological, economic, and societal factors. The biomass decision tree shown in Fig. 2.2 summarizes the information required and decisions that need to be made to determine whether a biomass plantation may be feasible. Site selection and planning at the national, regional, and local level requires geographically located information on soils and geology, natural vegetation, current land uses, topography, watershed boundaries, stream/river systems, roads, local political jurisdictions, land ownership and tenure information, location of cultural and historical resources, location of nature preserves and rare habitats and species. It is also very valuable to have sitespecific research data on the yields that can be expected from the preferred species. The information is particularly helpful if it can be conveniently summarized, compared, and presented on maps using computer-based geographical information systems (GIS). The HNRIS database developed for the state of Hawaii is an excellent example of the type of data and GIS systems that is very valuable for making decisions regarding the best locations for biomass plantations. Fig. 2.2. Biomass project decision tree. Species Selection Once a site is chosen, the next key to the success of the plantation is the selection of genetically superior tree species, varieties or clones suitable for the climate, soils, and desired products of the plantation. Most species achieve their best growth under a fairly narrow range of climate and soil conditions, and failure to match species to site has been the cause of the failure of many plantation projects. Even within a species that is suited to a particular site, there can be great variation in the growth and wood characteristics from different seed sources or regions within the species range." The largest, cheapest, and fastest gains in most tree improvement programs can be made by assuring the use of the proper species and seed sources within species."29 Many of the problems of plantation health, productivity, tree quality, and the economic viability of early plantation programs were the result of use of inappropriate species or clones and suboptimal plant materials. For example, Jari Cellulose S/A of Brazil is currently replacing all of the pines and gmelina planted on over 90,000 ha due to the poor growth. Although indigenous species would be preferable from an environmental perspective, a large number of the plantations being successfully established in tropical regions are using exotics such as E. grandis and P. caribaea. Several acacia species, which are native to many tropical areas are showing good performance. In the U.S. and Europe, hybrid poplars and willows are, in most cases, outperforming native poplar species, although fast-growing native poplar clones have also been identified. The best hardwood species and clones for lumber and veneer are likely to be different than those that are best for energy or hardwood pulp. In some temperate agricultural regions, herbaceous energy crops are being investigated. One advantage of such crops is that they can be planted and harvested using standard agricultural equipment rather than specialized forestry machinery. Perennial herbaceous crops, such as certain native prairie grasses, have the advantages of providing quick erosion control and wildlife habitat, quickly reaching full production, and providing continuous harvests without replanting. The best tropical analogy is sugar cane, although other tropical grasses or canes might have potential as well. Normal variation in topography, soils, and moisture conditions dictates that more than one species may be desirable to optimize sustainable production. While it may be desirable to use both grasses and trees as feedstock options from an environmental standpoint. Use of mixed tree species plantings would also provide more desirable habitat for wildlife than single species plantings. Where the conversion technology or product depends on feedstock uniformity, site differences can be partially compensated for by using many clones of the preferred species. Pulp companies such as Aracruz Celulose S/A in Brazil have developed a working set of 40 to 80 clones for taking advantage of small site differences, and attaining functional diversity for pest management and risk spreading Nitrogen-fixing species, or fast-growing nurse species could be beneficial components of the overall species mix. Such species are likely to be particularly important where plantations are being established on degraded or abandoned agricultural lands though plantings would likely need to be subsidized since returns to the land owner may be limited due to low yields. In such cases, the initial species mix used to reclaim the site is likely to be different than the preferred species mix once the site has been improved by the initial rotations. Conversion technologies which can adjust to changing species composition over time will offer the greatest opportunity for producing environmentally sound, low-cost feedstocks. 46 Species and clonal selections cannot be made exclusively from a study of literature. Unless a research program exists in the vicinity of a desired project, some trials of promising species will have to be part of the project development process. As described by Evans, these trials will normally be of four different types:31 Step 1. Species screening and elimination trials to identify the most promising species. Step 2. Species refinement trials to examine genetic variation among provenances, families, and clones. Step 3. Larger production trials to provide stand growth data, test cultivation methods. Step 4. Tree improvement activities including breeding and clonal propagation. This sequence takes time and often decisions are made after only step 1. Steps 2 and 3 may be carried out while a project is being established and result in changes along the way. Step 4 is an ongoing commitment that is required once significant investment in a project has been made. Plantation Establishment, Tending, and Protection Plantation establishment is a critical phase of a large-scale biomass energy project, since the timing of wood supply must be coordinated with the construction of a complex and expensive power plant. Mistakes or miscalculations at any one of many stages can result in expensive delays in power generation. Issues that must be addressed include: site preparation, seedling or cutting supply and quality, availability of required soil microorganisms, nursery operation, spacing of plantings, fertilization, watering, weed control, road construction, protection of nursery stock and plantings from insect pests, disease, animals, humans, fire, and other threats. The particular properties of each plantation site and the species selected will affect how each of the above issues should be addressed. Site Preparation Site preparation is the key phase of establishing a short-rotation woody crop plantation. Site preparation on land not already used for cropping includes demarcation of boundaries, planning and construction of access roads, and installation of erosion control measures. While alteration of drainage to improve conditions for tree growth and minimize negative effects on the quality of water leaving the plantation may be needed, care should be taken that wetlands and or water quality regulations are properly addressed. The primary goal of site preparation is to create the best possible conditions for the growth of the tree species that will be planted. Site preparation requirements vary greatly among tree species and with variation in climate and soils. Most current recommendations suggest using land already cleared or planted in tree crops both for economic and environemental reasons. The most suitable sites for biomass plantations and the least expensive to prepare are lands recently or currently being used for agriculture. On many agricultural sites, ripping may be necessary to break-up hard pans that have devoloped over many years. On recently abandoned agricultural lands, the main problem is often competition between planted seedlings or cuttings and pre-existing vegetation. Consequently, the goal of site preparation is to kill or remove as much as possible of the vegetation without degrading the site and creating erosion. For species that are extremely sensitive to competition from grasses, including most fast-growing eucalypts, poplars and willows, complete kill of the competing vegetation is essential. Figure 2.3 indicates the strategies that may be required depending on existing vegetation. Fig. 2.3. Steps in a recommended site preparation strategy.32 Both herbicides and cultivation may be required if mowing is not sufficiant. This is particularly important in areas that have been invaded by aggressive grasses, such as Imperata cylindrica. Other species, including Acacia mangium, alder, and many pines, are tolerant of some competition from grass, and do not require such intensive site preparation, but also usually fail to produce high yields at a young age. Experience in the U.S. suggests that site preparation should begin at least one full year in advance of planting short-rotation crops, if cultivation is required. Soil cultivation aids in reducing weeds, but also can be used to improve soil structure for root penetration in areas with compacted soil, impervious clay layers, or poor drainage. No-till site preparation may be appropriate if herbicides can be effectively used to achieve total grass and weed kill in strips where trees are to be planted. In some situations, clearing and burning may be appropriate, although this is usually ineffective for grasses because they have adapted to fire. Inadequate site preparation is the most common mistake made by companies and researchers initiating a new short-rotation woody crop project. 47 On severely degraded sites, competition with grass and weeds is less an issue than is the nutrient content and available moisture in the soil. Appropriate establishment methods may include leaving weeds, planting grasses in strips, applying organic matter, establishing a cover crop, and/or building berms or other structures to concentrate water. Seeds, Cuttings, and Nursery Operation Many first time plantings fail because high quality plant materials are scarce and poor quality planting materials are used. The materials may be too small, too big, diseased or too weak. Guidelines for optimal seedling and cutting size and handling requirements are available for the most commonly planted species. A common problem is that insufficient quantity of select material is available so the tendency is to use the poor quality material just to meet planting goals. Obtaining rapid growth early is so important for short-rotation systems that time and money should not be wasted on planting poor quality or unhealthy material. Large centralized plant propagation and nursery operations that are owned by the power companies (or their subsidiaries) may be required for large-scale biomass power projects. Nursery operations are a standard component of most pulp and paper operations which depend on plantation grown wood. For smaller power project operations, it may be easier and more cost-effective to purchase seedlings or cuttings from commercial nurseries. If plants are to be established from seed, the issues of seed availability, seed quality, seed storage, and germination requirements must be fully resolved in the project planning stage. The quality of seeds is particularly important, and success may depend on having a good supply not just of the desired species, but of the specific variety or provenance of that species that is best suited for the plantation site. To assure continuing supplies of improved high quality seeds, some investment in seed orchards and longterm breeding programs is necessary. Most hardwood species receiving serious consideration as biomass plantations species can be propagated without seeds, from cuttings of twigs and branches that can be induced to grow roots, from root sections or branches that can be placed directly into the ground, or from tissue culture and micropropagation methods. A major advantage of vegetative propagation is that the individual trees that have the most desirable properties, disease resistance or rapid growth under specific local site conditions, can be rapidly multiplied as part of a tree improvement or clonal expansion program. Species vary greatly in their suitability for vegetative propagation, with some easily sprouting roots and leaves, and others only surviving under the most favorable conditions. Species that sprout and grow readily include: many Eucalyptus and Populus species, Acacia cyanophylla, Azadiracta indica, Cassia siamea, Chlorophora excelsa, Cordia alliodora, Dalbergia sissoo, Gmelina arborea, Leucaena leucocephala, Nauclea diderichii, Paraserianthes falcataria, Pterocarpus spp., Triplochiton scleroxylon, and Tectona grandis. Depending on whether the species being planted are most effectively established as bareroot seedlings, containerized stock, or hardwood cuttings, propagation and nursery procedures will be quite different. Larger-seeded species can be sown in large beds and root- pruned to produce bare-root stock for planting. Trees being clonally propagated require stool beds of clearly identified clones for generating cuttings. Sprouts species such as poplars and willows are then harvested from the stool beds, sectioned, graded for size, packed, and kept in cool temperatures until planting season. Eucalypts which are produced from small seeds or small cuttings and species produced through micro-propagation, require well-run seed or propagule handling, containerization, and hardening operations to produce adequate sized planting stock. In general, container grown plants have a higher survival rate, than bareroot seedlings or cuttings, particularly in drier areas. However, container grown plants may cost from 25% to 250% more to produce than bare-root seedlings or hardwood cuttings. In all nursery operations, particular attention must be paid to fertilization and the prevention and control of fungal diseases and insect pests, as well as plant size and root quality/quantity. Many species may have unique properties and problems at the nursery stage. Consequently, the experience that has been gained around the world with particular species under specific climate conditions should be utilized in nursery design. Local practices that work perfectly well for some species may result in total failure with different species. When Shell International chose to establish a eucalyptus plantations in Chile, local builders failed to follow exact specifications from Shell staff with previous experience in South Africa. This resulted in major problems and loss of much of the planting stock in the 48 first year of operation. Once the buildings were reconstructed according to specifications, propagation was successful.33 Spacing A primary question during the planning phase is the spacing (or density). Planting density affects the total cost of planting stock, the rate at which the tree canopy closes, the growth form of the trees, the optimal rotation age and the size at optimal rotation or harvest age. While production of large saw logs is most effective at large spacings or in thinned stands, plantations for biomass or pulp generally use narrower spacings ranging from about 4 x 4 m down to about 1 x 0.5 m.34 The tightest spacings are characteristic of willow plantings, which are cut after 1 year to generate many sprouts, thereafter being harvested on a 2 to 3 year schedule. The widest spacings are more characteristic of plantings where the trees are expected to reach a 15 to 20 cm diameter (d.b.h.) by harvest age. Within a certain range, maximum short-rotation plantation yields are not particularly sensitive to spacing, if weeds are effectively controlled and the stand is allowed to grow. The spacing does, however, affect weed competition. Tight spacings minimize weed problems by closing canopy within the first year. Wider spacings require weed control for 2 to 3 years, however, weeds can be effectively controlled by cultivation, and herbicides. Planting Planting techniques will vary depending on the type of material being planted and the terrain. Hand planting is probably the most common approach even in industrialized countries. Hand planting by an experienced crew can be nearly as fast as mechanized planting with fewer mistakes. Unrooted cuttings offer the greatest flexibility in choosing hand or machine planting methods. However, it is suggested that painting or marking tops of unrooted cuttings will ease planting efforts and ensure that the right side is planted up. Weed and Pest Control Weed competition can be severe in the establishment phase of plantations and most establishment methods involve some use of cultivation and herbicides.35 It is most important to eliminate weeds close to the trees. Cultivation is most effective if the spacing is square and wide enough to allow cultivation. Application of herbicides over the trees, prior to leaf out, may accomplish the control needed close to the trees. Mulching is another alternative. In countries where labor costs are low and chemical costs may be high, manual labor is likely to be used to reduce weed growth immediately around trees. Depending on the relative costs of labor, machinery, and chemicals, the most cost-effective weed control practices can differ greatly from one area to another. Another weed control alternative is agroforestry in which manual labor is used to tend food crops grown between rows of trees for one to two years.36 This practice can provide both subsistence and cash crops to the local community, while accomplishing weed control without harmful chemicals.37 Because of the economic and environmental advantages shown by agroforestry experiments in Brazil, some forest companies are beginning to recommend agroforestry in their tree farmer programs.38 Insect and fungal pests tend to be most serious when plants are stressed by poor soils, crowding, or other unfavorable environmental conditions. Pests can spread rapidly and cause extensive damage in single species plantations. The incidence of pest problems and thus the need for toxic chemicals could be reduced by use of multispecies plantings, either intermixed or blocked, by selection of resistant species and clones, and by carefully matching species and clones to site conditions to minimize stress. A combination of biological and chemical controls of pests using the principles of Integrated Pest Management (IPM) is usually much more effective and much less costly than large-scale pesticide application. Protection from Fires and Animals Fires are a major risk factor that must be considered in planning the layout of short-rotation woody crops. Separation of planting blocks with strips of natural vegetation may assist in reducing fire hazard as well as increase local biodiversity. The roads needed for harvest access and wood removal should be made wide enough to serve as fire breaks. Large animals, such as deer and moose, can create problems by browsing the tender shoots of young plants. While solar-powered electric fences could be used for keeping out large animals, this would normally be too expensive for large-scale operations. It may simply be necessary to accept some level of 49 damage and claim credit for game populations in the region. Hunting is considered to be the most effective means of protecting plantations from excessively large populations of browsing animals.39 Rabbits and rodents can damage or kill trees by gnawing the bark and girdling the base of the trees. There is little protection for such animals in well managed plantations with low weed cover, thus providing another rationale for good weed control. There are no other suitable methods for protecting plantations against small rodents.40 Stand Renewal The initial planting strategy should include a plan for stand renewal after harvest. Most short-rotation species being planted or under evaluation offer the option of stand renewal through resprouting or coppice growth. Although it was originally conceived that plantations would use the natural coppicing ability of hardwood trees, researchers growing poplar in the U.S. and eucalypts in Brazil are now suggesting that planting new and higher-yielding clones after each harvest will increase production and more than offset the increased costs associated with stump removal and site reestablishment. Continuous introduction of new clones also reduces risks associated with the buildup of pests and diseases. 2.4 USE OF RESIDUAL BIOMASS FROM TRADITIONAL FORESTRY OPERATIONS FOR ENERGY; HARVESTING AND TRANSPORTATION LOGISTICS OF ENERGY WOOD PRODUCTION. Use of Plantation-grown Biomass for Power Generation The conversion of wood energy feedstocks to energy beginning with harvesting and ending with export of power to the electric grid is depicted in Fig. 3.1, Process diagram: plantation-grown biomass to power generation. Post-harvest fuel preparation, transport, storage, and fuel preparation and handling are key steps linking fuel production with conversion. These process steps influence the efficiency of the conversion facility through feedstock quality (moisture content, size, uniformity) as well as overall system cost. Figure 3.1 also shows feedstock handling and long-term storage losses. These losses can be significant and must be accounted for in determining total feedstock requirements for the conversion facility. Harvest, transport, storage, and fuel preparation techniques and requirements are discussed in the following section. A second section provides a brief overview of conversion processes. Harvesting, Transport, Storage, Handling and Fuel Preparation Harvesting is a significant cost and a technical barrier to commercialization and use of plantation-grown biomass for power generation. In the industrialized countries, considerable efforts have been expended to develop equipment for harvesting plantation-grown trees. Results of studies conducted during the mid-1980s conclude that cost-effective harvesting requires equipment be appropriately sized and be able to cut and handle large numbers of relatively small diameter trees. Conventional forest harvesting equipment tends to be inappropriate because it is designed for single-stemmed severance of large trees. Such equipment is also high-powered and expensive relative to the value of plantation-grown trees. Much of the work on harvesting systems in the industrialized countries has been based on the development of feller bunchers, often as attachments to standard tractors. These harvesters have three functions: severing or cutting, accumulating, and offloading.41 For example, the prototype Hyd-Mech FB7 continuous feller-buncher uses two counter-rotating saws for severing. Accumulating arms push severed trees off into holding areas. Once the holding areas are filled (8 to 10 trees), the trees are dumped alongside and parallel to the feller buncher. Other equipment (forwarder, grapple skidder, or tractor with grapple) is then used to move the piled trees to a landing area. Here the trees can be chipped and blown directly into a trailer or van for transport or simply loaded in whole form and hauled to a conversion facility. In the latter situation, chipping or size reduction is done at the conversion facility. Stokes and Hartsough analyzed the productivity and cost of three systems for harvesting a small diameter and large diameter plantation stand. 42Their analysis was based on studies conducted on 7.6 cm sycamore stand in south Alabama and a 10.2 to 15.2 cm eucalyptus stand in central California. The systems included a continuous feller-buncher, a three-wheel feller-buncher, and chainsaw harvesting. A grapple skidder or tractor with winch and a whole-tree chipper were also configured into a balanced harvesting system. Their results are displayed in Fig. 3.2a and Fig. 3.2b.43 Fig. 3.2. A comparison of productivity and cost of harvesting systems for a large diameter (15.2 cm) and small diameter (7.6 50 cm) plantation stand. The first panel shows how tree diameter influences harvest system productivity. For the continuous feller-buncher system, productivity was significantly higher when harvesting the larger diameter stands. In contrast, a chainsaw harvesting system was more efficient for the small diameter stand. The second panel shows a similar relationship -- the continuous feller-buncher is more cost-effective for the larger diameter stands with chainsaw harvesting more cost-effective for small diameter stands. Although not specifically shown in Fig. 3.2, the Stokes and Hartsough data indicate that chainsaw felling is about 2.5 times more productive than the continuous feller-buncher for the small-diameter trees. However, bunching and skidding the cut trees to a landing greatly diminishes the productivity of the chainsaw system. A comparison of the production rates achieved on other felling machines is shown in Table 3.1. These data also show a fundamental relationship between tree size (spacing or planting density) and productivity. A research team at the University of Hawaii (Manoa) has modeled this relationship and used it to identify optimum spacing and rotation age for short-rotation eucalyptus.44 Table 3.1. Productivity Summary of Machine and Manual Felling in Short Rotation, Biomass Plantations53 Type of Machine Species Average diameter (cm) Spacing (m) (Trees/ha) Productivitya (Dry tonnes/hr) Hyd-Mech FB-7a Sycamore 6.3 1.5 x 3 8.7 51 (1824) Hydro-Ax 411 " 4.3 " 2.2 Hydro-Ax 411 " 7.6 1.8 x 2.7 (2017) 13.0 Sycamore 7.6 " 5.3 Chainsaw w/felling frame " 7.6 " 5.1 Chainsaw " 4.3 " 1.3 Poplar 8.0 0.5 x 0.9 (21,607) 10.9 Cottonwood 19.8 3.9 x 3.9 (670) 26.2 " 19.8 " 45.4 Eucalyptus 7.0 1x1 (10,116) 9.0 Poplar 11.4 2.4 x 2.4 (1700) 5.8 Morbark Mark V VPI/DOE Harvester John Deere 493D Barko 775 UH Harvester USFS Harvester aProductivity converted from green tonnes to dry tonnes assuming 50% moisture content. The productivity and cost of plantation harvesting systems are quite variable. In industrialized or highlabor cost countries, estimated harvesting costs generally range from about $18 to $35/dry tonne for felling, skidding, and chipping.45 The low-end costs tend to presume the availability of prototype plantation harvesters while the high-end costs tend to be based on the use or modification of conventional forestry equipment.46 A large component of total harvesting system cost (about 30 to 40%) is tree handling or skidding of bunched trees to a landing for chipping or loading. In an effort to minimize handling operations, whole-tree energytm (WTEtm) technology is under development.47 In the WTEtm system, trees are severed, accumulated, and loaded directly onto specially designed trailers for transport. This concept differs from conventional approaches in following respects. First, whole-tree harvesting eliminates tree skidding or forwarding, a major cost of plantation harvesting systems. Second, trees are not chipped or processed in the field. Instead, feedstock size reduction is done at the conversion plant. Third, the minimization of tree handling steps reduces significantly, if not eliminates, feedstock handling losses. Fourth, whole-tree harvesting equipment is optimized for singlestem severance (not coppice growth) and is utilized year-round. These factors have potential to reduce greatly harvesting costs.48 However, a WTE system as now envisioned is likely to be limited to sites that are relatively flat and accessible. Soil compaction is also a potential concern. In contrast to the industrialized countries, where harvesting and handling operations have been focused on the development of dedicated plantation harvesting machinery, developing countries are basing their harvesting systems on the availability of low-cost and underutilized labor. In Brazil, most felling is done with chainsaws. A typical harvesting operation has chainsaw operators cutting three rows of trees at a time, directionally felling the trees so that they line-up.49 The trees are then crowned and cut to length or left whole for moving to a landing area. Production rates for an experienced chain saw operator can reach 120 trees/day. This is about 60 m3 or 28 dry tonne (0.47 dry tonne per m3) per day (3.5 dry tonnes/hour). After felling and cutting to length, grapple loaders are used to forward the logs to a landing for loading onto trucks (tractor-trailers) for transport to the conversion facility. For some applications, the availability of excess labor in rural areas, low wage rates, and scarcity of capital for equipment, maintenance and repairs, and fuel dictates that all harvesting operations (felling and forwarding) be done manually. For example, in Southwest China, Perlack et al. estimate that 75 workdays per hectare are required to fell, trim, carry, and stack logs at a roadside.50 Each hectare is assumed to 52 yield 30 dry tonnes of wood energy at harvest excluding the smaller limbs and branches, which are left for nutrient recycling and fuelwood purposes. This production scenario implies a harvest rate of 0.4 dry tonnes/day. In the Philippines, Durst estimated that over 130 days would be required to cut, top, and stack one hectare using handtools.51 This translates into a production rate of about 0.6 dry tonnes/day. A similar rate is provided by Denton, (100 kg/hour or 0.5 dry tonnes/day assuming a 10 hour workday).52 In general, it is difficult to summarize production rates for manual harvesting operations because estimates are highly dependent upon local site conditions (topography, plantation density, tree size, forwarding distances, climate, season, etc.). However, relative to capital intensive harvesting systems, costs are generally a smaller percentage of total delivered feedstock costs. Harvest and handling operations will result in losses in product yield (Fig. 3.1). The significance of these losses depend on local factors including the degree of mechanization used in harvest operations. Some studies have conservatively assumed that felling, forwarding, and chipping operations can result in a 5% loss in the total standing dry weight yield. In manual harvesting operations, losses can be higher depending on how tree crowns and smaller limbs are treated. It is more likely that these smaller pieces are left on-site for use as fuelwood (plantation by-product) and for nutrient recycling purposes. When wood is harvested it normally contains about 50% moisture (wet basis). Moisture and other physical properties of wood should be taken into account when designing and operating wood-fired power systems. The presence of moisture in wood can affect combustion by absorbing heat during evaporation; increasing the time it takes for wood to burn, and reducing the temperature of the combustion gases. Operational experience suggests that there can be significant decreases in boiler efficiency when moisture content begins to exceed 50%. If feedstocks are allowed to air-dry to 30% moisture, there can be usable net heat gains. However, if the feedstock is allowed to absorb moisture during storage, a point can be reached where combustion can no longer be sustained. In this instance boiler blackouts can occur and auxiliary fuel will be needed to sustain combustion. Boilers specifically designed to handle high moisture content fuels do not have these problems, but they tend to be higher in cost.54 Moisture in wood feedstocks also creates problems in storing fuels for later use. These other problems include decomposition, self-heating, spontaneous combustion, and buildup of spores and moulds.55 Research on plantation-grown wood feedstocks in temperate climates has shown that harvest during the dormant growing season will be required to obtain good coppice regrowth. An added benefit is that leaves will be left on site to enhance nutrient recycling.56 Under such a scenario several months of storage is required to ensure a continuous supply of feedstock to the conversion facility.57 When feedstocks are stored for long periods decomposition losses can be high. Decomposition can be especially high under conditions of high humidity, rainfall, and evapotranspiration. How the feedstocks are stored (covered or uncovered) and in what physical form (chips or as bundles of whole-tree) also affects decomposition and the moisture content of the feedstock. Under less than ideal conditions, decomposition losses can easily reach 2% per month of storage. One option to avoid storage problems and decomposition losses is to harvest year-round. With year-round harvesting crop decomposition losses do not occur as trees are in effect stored on the stump. This practice may not promote good regrowth and new stands may have to be established. Moreover, there may be periods during year, especially in tropical climates, where the plantation may not be accessible or roads not passable (e.g., during moonsoon periods). There are numerous factors that must be considered in designing fuel storage facilities. These include: the available storage area and its proximity to the boiler; the physical properties of the fuel (chips, chunks, whole-trees, etc.); additional fuel preparation requirements; back-up storage capacity and reliability of the fuel supply; seasonal weather conditions; and operational requirements of the boiler. Fuel storage systems that are in use include both open and covered systems. For the open systems, the fuel is stored either directly on the ground or on a concrete pad. The covered systems can include plastic on slab (or on ground), open sheds, closed sheds, silos, and air bags. A typical operation is likely to include two types of storage facilities. An inactive area (open or covered on slab) where fuel is received and an active area (usually covered) that can store about 3 days supply. Front-end loaders and manual labor are 53 most often used to move chipped wood feedstocks between inactive and active storage areas. The WTEtm technology uses a very large shed (air supported) to store and dry a 30-day supply of whole-trees using waste heat from the power plant. Fuel-feed systems are used to transfer wood from the active storage area to the fuel hopper for metering and feeding into the boiler. This handling equipment can include various types of conveyors (belt, drag, screw, pneumatic) and elevators. Fuel hoppers are usually designed to avoid bridging and clogging (e.g., sloped walls), and they are covered to prevent sparks and smoke from escaping to the storage area. Screens and knife hogs or hammermills may also be used to remove unwanted material (e.g., rocks and debris) and to ensure appropriate particle sizes and uniformity. Uniform feedstock size helps to ensure more efficient fuel handling and combustion. The characteristics and quality of biomass feedstocks greatly influences the design, choice, and performance of conversion technologies as well as the requirements for feedstock storage, fuel handling, and ash disposal. Biomass feedstocks that are variably sized and high in moisture or ash content can reduce boiler efficiencies, increase O&M costs, and lower capacity factors. There is a variety of equipment on the market that can be used for sizing. This equipment ranges from small-scale chippers that are towed or trailered to a site to large-scale equipment. The large-scale equipment can be mobile (trailered or self-propelled) or stationary. This equipment is usually configured with grapples for fuel feeding. Whether small- or large-scale, chips can be blown directly into a van or trailer for transport or piled at the conversion facility for storage. There also exists a number of options regarding fuel preparation and handling systems. The wood feedstocks can be chipped "green" immediately after harvesting. Because many conversion systems are designed to burn green or high moisture materials (<50%) and a variety of fuels, storing fuels to reduce the moisture content may not be necessary. Some conversion systems require that the feedstocks be dried significantly below 50% moisture. In this case, green chips would then have to be stored. Alternatively, felled trees can be stored in whole form (or chunks) for storage and drying. This practice would reduce decomposition losses. However, drier wood is more difficult to chip and to ensure uniform size. Power Generation Options The use of plantation-grown biomass can be used for power generation in three general applications, these include: stand-alone, grid-connected biomass-based power plants using plantation grown feedstocks or mixed with agricultural residues; cogeneration at agricultural (e.g., sugar mills and rice mills) and forestry processing facilities for on-site heat and power needs with export of excess power to the local distribution grid using a combination of mill wastes (bagasse, rice hull, wood waste) and plantation-grown biomass; and co-firing at fossil-fired electric generation facilities. For each of these applications, the current conversion technology of choice is the steam-turbine cycle (Rankine cycle). The technology is relatively simple to operate and it can accept a wide variety of biomass fuels. However, at the scale appropriate for biomass, the technology is expensive and relatively inefficient when compared with fossil fuel power plants.58 As such, the technology is relegated to applications where there is a readily available supply of low-, zero-, or negative-cost feedstocks. The low efficiency of biomass-fired power plants, relative to fossil-fuel plants, is due in part to the use of more moderate steam conditions. Biomass steam-turbine plants use lower pressures and temperatures because of the strong scale dependence of the unit capital cost ($/kW).59 Biomass plants can not be built at sufficiently large sizes to take advantage of scale economies (>300 MWe) because the cost of supplying fuel to the plant would be excessive. Woody biomass has an energy density of slightly less than 20 GJ/dry tonne. When freshly cut, wood contains about 50% moisture. The high moisture effectively reduces the energy content of the wood by half. Relative to coal, a tonne of dry wood has about one-third less heat value than a tonne of coal. The high costs associated with handling, transporting, and storing large quantities of biomass effectively will this negate any scale economies associated with building large conversion facilities. The remainder of this section examines several combustion technologies for biomass power generation.60 The technologies can be classified into currently available technologies that are in operation at the present time or capable of being in operation with minimal developmental barriers, and 54 emerging technologies that are expected to require overcoming some technical barriers, before commercialization can be considered. Currently Available Technologies Conventional steam turbine systems. Except for differences in fuel handling and preparation and emissions control, wood-fired steam turbine power systems use essentially the same technology as that found in coal-fired plants. However, the lower density and heating value of wood relative to coal means that biomass systems require more combustion and heat transfer surface area. The tradeoff between additional costs of fuel handling and extra boiler combustion area for wood, and simpler emissions controls relative to coal translates into approximately the same installed costs ($/kWe) for biomass systems. In a conventional biomass-fired combustion steam turbine, wood is first prepared (sized and possibly dried) then burned in a boiler to produce pressurized steam. The steam is expanded in a turbine to generate electricity. For power production, a fully condensing turbine is used. If process heat is to be produced in addition to electricity, a condensing-extraction (or back-pressure) turbine is used instead. In this cogeneration mode, some steam after producing electricity is taken from the turbine for process heat. Specific boiler types used to generate steam include pile burners (dutch oven), grate burners (stationary or traveling grate), suspension burners, and atmospheric fluidized-bed combustors (bubbling-bed or circulating-bed). These combustion methods will produce boiler efficiencies ranging from 65 to 75% with net plant efficiencies from 20 to 25%. The most commonly used boilers for wood-fired systems are grate burners. The grates can be either stationary or traveling. Stollers are used to fuel wood into the boiler. For wood-fired systems, the spreader-stokes is most often used decause it can easily handle a wide variety of fuels. A second combustion design available for biomass are fluidized beds. In these designs wood (biomass) is injected into the combustion chamber through ports and burned in suspension. Air entering the boiler fluidizes a bed of hot, granular, inert material. The inert material heats the biomass quickly to ignition temperature, stores the thermal energy, and provides the appropriate residence time for full combustion. Co-firing biomass feedstocks with coal. Co-firing plantation-grown biomass feedstocks with coal in existing utility steam boilers is a potentially useful process to reduce SO2 emissions. The addition of scrubbers to a coal-fired plant would sharply reduce SO2 emissions, but at a high cost. If only a moderate amount of SO2 emissions reduction is required, co-firing wood and coal can be a very cost effective alternative. Additions of new fuel handling equipment, modifications and improvements to boilers and electrostatic precipitators are required to co-fire with coal, but these changes would likely be less costly than installing scrubbers, switching to low sulfur coal, or purchasing emission allowances. Because of the moisture present in wood, some derating of the boiler may occur. Emerging Technologies The currently available biomass conversion technologies are relatively robust with minimal operating problems.61 However, a significant limitation of these technologies are low operating efficiencies that are due in part to the high moisture inherent in biomass feedstocks. One technology under development and testing that offers higher conversion efficiency is Whole Tree Energy (WTEtm) technology. WTEtm is an innovative steam turbine technology that uses an integral fuel drying process.62 Waste heat, preheated by the flue gas at 54C is used to dry the wood stacked in a large, air-inflated building for 30 days before it is conveyed to a boiler and burned. Allowing the waste heat to dry the wet whole tree fuel can result in furnace efficiency approaching 87% with a net plant efficiency comparable to that of a modern coal-fired plant (35%). WTEtm also reduces wood harvesting and handling costs as well as the need for equipment such as hammer mills, screens, and chippers that are used for reducing the size of the wood feedstock. In the Lake States region of the U.S., busbar electricity costs from WTEtm are projected to be about $0.043/kWh or about $0.015/kWh less than that of a coal-fired plant.63 WTEtm can be built in sizes as small as 25 MWe; however, it is more likely that the market for this technology will be utility-scaled systems. Although there exists technical potential to increase the conversion efficiency of WTEtm technology and other steam-turbine cycle systems, these developments are unlikely to be costeffective.64 According to some experts the most promising technologies for wood-fired power generation lie in the development of gas turbine cycles.65 Gas turbines (or Brayton cycles) have already been developed for 55 natural gas and clean liquid fuels. A key advantage of gas turbine technology is the potential for substantially reduced capital costs, which are relatively insensitive to scale, higher conversion efficiencies (upwards of 45%), and greater modularity. Adapting the technology for biomass (i.e., Biomassgasifier/gas turbine -- BIG/GT) would require the use of a gasifier to thermochemically convert wood to a gas. The resultant gas would then be cooled and cleaned before being burned in a gas turbine. There are a number of technology choices for both the gasification and power generation portions of the BIG/GT cycle. BIG/GT gasification. There are two principal gasification options for use with biomass or plantationgrown wood. These are the fixed-bed and fluidized-bed gasifiers. The most promising of the fixed-bed gasifierdesigns for biomass are updraft designs. In these gasifiers, wood is fed from the top of the gasifier undergoing drying, pyrolysis, and char gasification and combustion as it moves to the bottom of the gasifier. The gas is removed from the top side of the gasifier with air and steam injected into the bottom sides of the gasifier. Fixed-bed gasifiers are simple to operate and efficient when used with uniform and appropriately sized, high bulk density (e.g., wood chips) feedstocks. The most important technical issue associated with these gasifiers is hot-gas cleanup, primarily the removal of alkali compounds and particulates. Controlling the temperature of the gas and using cyclones for particulate removal can be used to provide a gas suitable for the turbines. Relative to fixed-bed gasifiers, fluidized-bed gasifiers have greater throughput and can handle a greater variety of fuels including low-density materials such as agricultural wastes. This fuel flexibility characteristic may make fluidized-bed gasifiers the more appropriate choice for biomass applications.66 However, the resultant gas from fluidized beds is more problematic for gas cleaning. The exit gas has a temperature about 300oC higher than that for fixed-beds (500 to 600oC). The higher gas temperature requires gas cooling to condense the alkali compounds. Particulate control is also likely to be more problematic and require the use of advanced filtering techniques. BIG/GT turbine cycles. There are a number of alternative turbine cycles available and under development that can use clean fuel gas. In a simple-cycle configuration, fuel gas is burned in air pressurized by a compressor. The hot combustion gases are then used to drive a turbine. The exhaust gases from the turbine can be discharged (open cycle) or used in a heat recovery steam generator to raise steam for industrial or agricultural processing needs (cogeneration cycle). Because waste heat is used, the overall efficiency of the cogeneration cycle is higher than that of the simple cycle. Both the open cycle and cogeneration cycle can generate electricity with an efficiency of about 32% (less than that from a modern, large-scale steam-turbine cycle). There are a number of cycles under development and/or demonstration that have the potential to increase significantly the efficiency of the power generation side of the cycle. One of these is the BIG/GT combined cycle (BIG/GTCC). This cycle is similar to the simple cycle except that steam from the heat recovery steam generator is used to generate additional power in a conventional steam turbine.67 About one-third of the total power output of a BIG/GTCC would come from the steam-turbine side of the combined cycle. Steam injected gas turbine systems (BIG/STIG) are another option under development. In the BIG/STIG system waste steam from the heat recovery steam generator that is not needed for process uses is injected back into the gas turbine combustor, and at additional points along the flow path the gas is reheated to turbine inlet temperature, and then passed through the turbine. The additional steam mass injected into the turbine increases the total power output of the system and does not consume power at the turbine's compressor. Full steam injection allows the total system efficiency to approach 40%. An advanced form of the STIG is the intercooled steam-injected gas turbine (ISTIG). This variation of the STIG can raise both thermal efficiency (from 47% to 50%) and shaft power output. Environmental and Social Benefits/Costs of Biomass Plantations Tree biomass plantations potentially offer many direct and indirect environmental benefits, but they may have negative environmental impacts as well. As recently discussed by Graham, ascertaining the environmental impacts are complex because the impacts of using biomass for energy must be considered in the context of alternative energy options while the impacts of producing energy crops must be considered in the context of alternative land uses.70 Globally significant environmental benefits may result from using wood for energy rather than fossil fuels. The greatest benefit is derived from substituting biomass energy for coal.71 The degree of benefit depends greatly on the efficiency with which the wood is converted to electricity. If the efficiency of 56 conversion of wood to electricity is similar to coal conversion to electricity then the benefits are several. Airborne pollutants such as toxic heavy metals, ozone-forming chemicals, and releases of sulfur that contribute to acid rain will be reduced. The ash and waste products from burning will, in most cases, be sufficiently benign to return to the soil. There will be a considerable reduction in net carbon dioxide emissions that contribute to the greenhouse effect. For example, one dry tonne of wood will displace 15 GJ of coal. The 15 GJ of coal will have the equivalent of 0.37 tonnes of carbon assuming the wood is converted at an efficiency of 25%. Table 4.1. Example carbon offsets from short-rotation plantation energy used for power production and displacing coal Factor Wood Coal Energy density (GJ/Dry tonne) 19.8 29.3 Heat rates (kJ/kWh) 7,200-18,000 10,900 Feedstock carbon (kg C/GJ) 50 70 % Carbon 25.3 24.1 Input carbon (kg C/GJ) 1.34 0.53 Total carbon (kg C/GJ) 26.62 24.65 1 dry tonne of wood displaces 370 kg of coal carbon (19.8GJ/tonne*10.9/14.4 MJ/kWh)*24.65 kg C/tonne) Note: Feedstock carbon is the carbon embodied in the biomass or the carbon sequestered by plant growth. Input carbon is the carbon embodied in the factor inputs (e.g., diesel fuel) used to grow, harvest, and transport the biomass. Locally significant environmental benefits can be maximized when tree biomass plantations replace annual crops, heavily grazed pastures, or degraded lands.72 Benefits can include: 1. protection of water quality, 2. reduction of floods during wet seasons and maintenance of water supplies during dry seasons, 3. erosion prevention, 4. improvement of local microclimate through evaporative cooling and humidification, 5. wind breaks and shelters that reduce erosion and conserve water, particularly in dry regions, 6. reduction of fire danger, 7. reduction in use of fertilizer and agricultural chemicals, 8. improvement of soil properties, and 9. protection of wildlife and other components of biodiversity. Negative environmental effects of plantations may occur locally if unmanaged natural forests or forests managed for low intensity uses are removed and replaced with short-rotation biomass plantations. Negative impacts can include: 1. increased erosion and reduction of water quality as a result of forest harvesting; 2. increased rates of runoff and decreased water-holding capacity; 3. increased chemical pollution from fertilizers and pesticides; 4. degradation of soil quality and productivity; and 5. reduction of biodiversity through alteration of forest structure, creation of tree monocultures, and use of non-native tree species which local wildlife are unable to use.73 Concern over possible negative impacts has led environmental groups at both national and international levels to attempt to establish environmental guidelines prior to the commercialization of biomass energy technologies.74 In Brazil, early mistakes in establishment of Eucalyptus plantations, along with increasing environmental sensitivity, have led to substantial regulation of the forest industry.75 To minimize or avoid negative impacts from energy crop production, most proponents of biomass energy are recommending that biomass plantations be established on existing agricultural lands or degraded lands.76 Forestry codes and plantation management procedures currently being developed and 57 implemented around the world generally prohibit the conversion of natural forest to forestry plantations. Many of the natural forests occur on relatively poor soils, and destruction of natural forests is now recognized to have environmental costs in terms of biodiversity, environmental quality, and economic sustainability that far outweigh short-term economic gains from forest clearing. Principles recently formulated in the U.S. for the wise development of biomass resources include the following:77 Biomass energy system development must be guided by consistent decision criteria and should foster the multiple goals of environmental protection, economic revitalization, and energy security. Energy crop production practices and energy conversion technologies must be selected to ensure that the use of biofuels substantially reduces anthropogenic emissions that may contribute to global climate change. The use of biofuels should not exacerbate greenhouse gas emissions when compared with conventional fuels on a full-fuel cycle basis. The development and management of biomass resources should protect and, wherever possible, enhance ecological integrity and biological diversity, while minimizing adverse impacts to land, air, and water. The development and management of biomass resources should contribute to the economic well being of producers, local communities, and the nation as a whole. The use of biomass resources for energy purposes must rationalize trade-offs in terms of competing uses for the land and plants (whether for food, fiber, recreation, wildlife habitat, or other uses), while also recognizing the impacts and trade-offs implicit in the use of other energy resources. The remainder of this chapter provides more discussion of the effects of tree plantation on soils and water, biodiversity, chemical pollution, and social economics. Tree Plantations and Soil/water Issues The beneficial effects of forests on water quality, soil erosion prevention, and the reliability of water supply have long been recognized. The oldest forest reserve in the Western Hemisphere was established in Trinidad and Tobago in 1765 with the designation "Reserved in Forest for the Rains," followed by further assessments in the 1880s into "Forest Conservation and the Maintenance of Water Supplies." Many natural forest reserves have been established around the world in mountainous areas for the protection of municipal water supplies. Biomass plantations can also serve this purpose, particularly if the negative effects of harvest on soils and water supply can be minimized. Plantations are particularly valuable in improving the water supply on land that has been degraded by deforestation or desertification.78 Fig. 4.1a. Effects of land-cover type, precipitation, and slope on surface runoff at four tropical sites. The positive effects of plantations on soil and water conservation results primarily from protection of the soil surface from the direct impact of rain and from the improvement of soil structure through root penetration and the addition of organic matter from decomposing leaves, roots, and wood. In comparison to either crops or bare soil, forest greatly reduces the proportion of rainfall that is lost as runoff, thus leaving much more water available to feed springs and streams during dry periods (Fig. 4.a). The positive effects of trees on water retention tend to increase over time, so long rotations and practices that enhance organic matter input into the soil are particularly favorable. Tree species vary greatly in their effect on soil properties and on water cycling. Some tree species, such as E. globulus and E. tereticormis, tend to use water very rapidly, leading to reduced water yield from 58 watersheds, stress during dry seasons, and creation of unfavorable conditions for interplanting with food crops.79 On the other hand, studies on Eucalyptus grandis in Brazil have found the annual variation in soil water to be similar to that for Pinus caribea and savanna-like native forests.80 Tree plantations have also been shown to reduce wind erosion, reduce evaporative losses of water, and improve soil moisture conditions sufficiently to allow cropping on degraded lands.81 Nitrogen-fixing species, such as acacias and leaucena, can improve the soil, reduce the need for expensive nitrogen fertilizer, and produce fodder for farm animals. A primary difference between short rotation plantations, and forests harvested for timber with regard to erosion and water issues is the frequency of harvesting and replanting. Because 40% of tropical rainfall falls at erosive rates (greater than 25 mm/hr), soils exposed during and after harvesting are susceptible to serious erosion. 82 Harvesting and reestablishment practices thus become a very important determinant of the potential for environmental damage. When reestablishment occurs through coppice resprouting, risk of soil loss is minimized by rapid regrowth. The use of cover crops or grass strips between the rows can reduce erosion when replanting is required. Fig. 4.1b. Effects of land-cover type, precipitation, and slope on erosion at four tropical sites.84 The potential for soil loss increases greatly with increasing precipitation and on hilly or mountainous land (Fig. 4.1b). Harvesting with heavy equipment during rainy seasons is especially likely to cause serious soil erosion and soil compaction and may destroy the longterm productivity of a plantation. Due to both equipment constraints and erosion hazards, biomass plantations that are likely to be harvested every 510 years should not be located on steep, erodible soils. In general, tropical soils are much more subject to degradation from harvesting than forests on younger soils, such as those found in much of the temperate zone.83 Tree Plantations and Biodiversity Biodiversity refers to the number of different kinds of plants and animals that are found in a particular area such as a hectare of forest, and entire country, or the earth. Concern about the loss of biodiversity is based on the idea that each organism, even those that are unknown and unnamed, has some value. Many plants and animals are valued for the medicinal chemicals they produce or for their importance to forestry or agriculture. Other species are valued for their beauty or other special properties. Many species, even obscure organisms in the soil, may play important but poorly understood roles in improving soil fertility, in preventing diseases and pests from affecting crops, or otherwise maintaining a balance of nature that is favorable to human existence. For these and many other reasons, there is a broad consensus among scientists, citizens, and politicians that biodiversity should be preserved by preventing the extinction of species wherever possible. Because many birds, mammals, insects, and other animals depend on one to several particular tree species, extensive biomass plantations of a single tree species can be extremely destructive to biodiversity when displacing natural habitats. Clearing natural forests to establish plantations usually destroys biodiversity and should be avoided. Many of the forests with high biodiversity occur on soils that are too poor to support productive plantations, so there is usually no economically or biologically sound reason to replace them with plantations. Establishment of plantations on degraded lands that were previously deforested will usually have a positive effect on local biodiversity by improving the habitat for plants and animals that cannot survive deforested areas and may have other benefits such as improvement of water quality and quantity and soil improvement. 59 Tree plantations can be beneficial to biodiversity if properly designed or can be destructive of biodiversity when designed inappropriately.85 The effect of biomass plantations on biodiversity may depend as much on how they fit into the landscape as the particular species and management systems selected. Studies in the United States on hybrid poplar plantings have shown varied use by wildlife, depending on the surrounding landscape. For example, plantations adjacent to natural forest seem to reduce "edge effects" and expand the usable areas for forest interior bird species in predominately agricultural areas. There is considerable controversy on the use of non-native species on the scale that might be required for biomass energy. Plantations based on non-native species, such as eucalyptus outside of Australia and teak outside of Asia, are generally believed to provide little suitable habitat for native animals,86 although research on this issue is continuing. Depending on the planned energy conversion technology, plantations for biomass may be able to utilize a wider variety of tree species and thus may support a higher biodiversity of plants and animals than single-species hardwood or pulp plantations that must produce a crop that is extremely uniform in form and other properties. Biomass plantations can have a positive effect on biodiversity if their design includes preserving areas of natural forest of different types within the overall plantation area. Research has shown that areas of natural forest included within plantations is favorable for many native species of plants and animals.87 Properly designed plantations should include areas of natural vegetation, appropriate wooded buffers for waterways and corridors for wildlife movement, as well as protection of historical areas.88 Since the 1960s Brazil has required forest companies to either leave 10% of the managed area in natural vegetation or ensure that 1% of the trees planted are native species. The 10% option has normally been preferred and has resulted in positive benefits for both bird diversity and insect pest control. 89 Specific guidelines developed by the National Biofuels Roundtable in the United States for improving habitat are: Match native ecosystem cover types as much as possible (e.g., perennial grasses in prairie regions and trees in woodland regions). In addition, emulate natural vegetation patterns and functions when establishing energy crops on agricultural lands. Locate, plant, and harvest tracts of energy crops in ways that help improve pathways for animals to move between habitats and across landscapes in any particular year. Employ energy crops in ways that minimize the fragmentation of desirable habitats and improve overall habitat quality of the landscape for native species. Tree Plantations and Chemical Pollution The previous use of the land will determine the extent to which chemical pollution is an issue. Plantations generally require fewer inputs of fertilizers, herbicides, and pesticides than more intensive forms of agriculture.90 In regions of extensive agricultural activity where non-point pollution of streams is a problem, tree plantations may improve water quality by serving as a filter of agricultural chemicals. Establishment of plantations on pasture land, as may occur in many parts of the developing world, would result in additional use of some chemicals unless hand labor is used to control weeds. As described in Chapter 2, methods are available to minimize chemical use such as mulching and applying chemical only in strips around the trees though the relative costs of these measures have not been well established. Pest control can occur with minimal chemical use if frequent monitoring and biological control methods are used. The most effective method of pest control is to maintain ongoing breeding and genetic selection program so that susceptible trees can be eliminated and replaced with resistant varieties. Brazilian pulp and paper companies have been successful in controlling pest problems though genetic selection programs. Tree Plantations and Social Economics Successful woody crops can provide multiple economic, social, and environmental benefits to a state, region, country if properly planned and integrated into the multiple landuse opportunities within the country. In regions where the amount of good quality soil is limited, use of the best soils for biomass crop production will displace other land uses. The concern expressed most often is that use of land to produce biomass crops will reduce food availability. Such a concern was expressed in the mid-eighties when sugarcane establishment was accelerating in the agricultural state of São Paulo, Brazil as a result of subsidies provided by the National Program for Alcohol production (commonly referred to as ProAlcool). The article entitled "Brazilian Alcohol: Food versus Fuel" by Rosillo-Calle and Hall describes the complexity of food production and export policies in Brazil as well as details on the sugar cane expansion.91 The food 60 versus fuel controversy was exaggerated in their view. They conceded that the ProAlcool might be part of a larger overall problem which would best be described as a "commodity export crop production versus domestic food production" issue. With 64% of the sugar cane expansion in the state of São Paulo occurring on pasture land owned by large land-holders, displacement of primary food production was not the major issue. Tree plantations always exist in a social and cultural setting based on the inhabitants of the area before the plantation was created, and the inhabitants who arrived after the plantation was established. To be economically successful, and to avoid negative effects on society and the natural environment, each plantation must be designed for its own specific social, cultural, and environmental setting. Factors that must be considered include 1. preexisting land uses; 2. local agricultural practices; 3. local political systems and hierarchies of authority; 4. local cultural divisions of labor and authority between men and women; 5. local traditions of land tenure and stewardship including private property right; and 6. local cultural values.92 Because plantations must depend on local labor, it is desirable to maintain the structure of the local community in a way that provides a steady supply of reliable workers. The more the plantation can be integrated into the daily economic and social life of the community, to the mutual benefit of both the community and the plantation, the more likely it is to succeed in the long run. For this reason, Brazil and China are leaders in investigation of agroforestry techniques for large scale use. Tree establishment can be enhanced, and the need for dangerous chemicals reduced, through the interplanting of agricultural crops during the first years after planting. This type of agroforestry benefits the plantation as well as the local community by providing food and/or cash crops. The use of multipurpose trees that provide energy products, animal fodder, and enrich the soil through nitrogen fixation are viewed as the ideal energy tree.93 It is likely this is the reason that leucaena was the species selected for use in the Philippine Dendrothermal program. Research has continued around the world on leucaena, acacias and other nitrogen fixing trees such as black locust. However, there has been an unfortunate tendency for these species to be susceptible to insect pests. Leucaena plantings have largely been destroyed by a psyllid pest and black locust is susceptible to a stem borer. These problems may be solved through genetic selection, biotechnology or biological control agents ,but at present, the widespread planting of nitrogen fixing trees for energy or pulp is not occurring. Even so, the multipurpose tree concept is a good one that deserves continued consideration. One success story is occurring in Brazil with a company that has a specialized conversion technology to produce pulp, alcohol, cattle feed and even electricity from a bamboo (Bambusa vulgaris) species.94 In summary, plantations for production of biomass energy have numerous potential environmental benefits. Conclusions from a roundtable of industry, academic, and government participants in the United States found that "if energy crops are included in the general mix of agricultural crops in a considered and informed way, environmental damage can be avoided; in fact, there could be significant environmental and ecological benefits achieved in tandem with the development of a fully sustainable energy resource."95 In addition to gas turbines, fuel cells are also under development. Fuel cells convert energy produced by electrochemical oxidation of a fuel like biomass into electricity. The operation of a fuel cell has gaseous fuels being fed continuously to the fuel cell's negative electrode (anode), while oxygen or air (oxidant) is fed continuously to the positive electrode (cathode). A continuous electrochemical reaction occurs which produces an electrochemical potential or voltage and electric current similar to that of a conventional lead-acid battery. Several fuel cell types are currently under development. However, the phosphoric acid fuel cell (PAFC) is closest to commercialization.68 The PAFC fuel cell operates at approximately 390F and has a cycle efficiency of as high as 45%. Advanced fuel cell designs could reach efficiencies of about 57% by 2020.69 Biocrude oils can also be produced from wood using a pyrolysis process similar to that used in gasification. The wood feedstocks are thermochemically converted to a sulfur free mixture of biocrude oil vapors, non-condensible gases, water vapor, and char particles. The biocrude oil vapors are condensed to 61 form a higher viscosity mixture of organic compounds with a heat value of 8,000 Btu/lb. After the residual non-condensible gases exit the condenser, the gases are collected and burned as process heat for drying the feedstock or supplying heat to the reactor. Approximately 60% to 80% of the feedstock can be converted to biocrude. Biocrude can be used as a substitute for fuel oil for gas turbine cycles. Biocrude can also be co-fired with other fossil fuels. The pyrolysis process does not have to take place at the power generation site since the biocrude can be stored and transported. CHAPTER NO.03 BIOENERGY THECNOLOGY 3.1Introduction Based on FAO’s Unified Bioenergy Terminology (FAO, 2004), the conceptual view of bio- energy systems is shown in Figure 2, describing the flow of bio-energy production from biomass as a source of energy. Biomass Biofuels Bio energy Figure 2. Bio-energy production flow Bio-energy can be defined as energy obtained from biological and renewable sources (biomass); bioenergy may be derived in the form of heat or transformed into electricity for distribution. Biomass also can be transformed into biofuels, which are portable feedstock for use in the generation of bio-energy. Biofuels are defined as feedstock intended for the production of bio-energy, produced directly or indirectly from biomass. Biofuels can be in solid form (fuelwood, charcoal, wood pellets, briquettes etc.) or liquid (bioethanol, biodiesel). With the emerging development on bio-energy today using more modern technology, biomass energy can be divided into traditional biomass and modern bio-energy. Traditional biomass is the main source of energy used in developing countries primarily for cooking and space heating at the household level, mostly using three-stone stoves, or in some areas improved cooking stoves. This source of energy is in the form of woodfuel (including fuelwood and charcoal), crop residues and animal dung and is often collected by women and children on a daily basis. In some areas traditional biomass is also traded within villages and among villages or with nearer townships. Another characteristic of traditional biomass is using traditional technology with low efficiency due to poor design, uncontrolled and open burning, which have important health implications. Modern bio-energy, is used mostly for the generation of electricity or transportation. Liquid biofuels for transportation such as ethanol and biodiesel are examples of the emerging energy alternatives. Table 1 describes in detail the key differences between traditional and modern biomass in terms of input, output and conversion technology. Traditional forms of biomass use are characterized by low capital, low conversion efficiency, poor utilization of fuel, and poor emission controls whereas modern forms of biomass use are characterized by higher capital, higher conversion efficiency, better utilization of fuel, and better emission controls (Rajagopal and Zilberman, 2007). Transformation of low efficiency fuels to high efficiency convenient fuels involves substantial investments, and often the transformation process involves loss of energy. Table 1. Comparison between traditional and modern bio-energy systems 62 (Rajagopal and Zilberman, 2007) Characteristics of technology Traditional Modern Fuel Mostly gathered or collected and in some cases purchased Commercially procured Capital Low capital cost High capital cost Labour High labour intensity at household level in collection of fuel Conversion process Energy uses Low efficiency and poor utilization of biomass Energy for cooking and heating in poor households in developing countries Poor emission controls Low labour intensity at household level but overall high labour intensity compared to other energy sources Higher efficiency and higher utilization of biomass Commercial heating, electricity and transportation Emission controls Co-product No co-products Controlled emissions Commercially useful co-products 3.1.1 Wood Bioenergy Basics What is wood-based biofuel? Biofuel is one specific form of bioenergy, or energy derived from biomass. There are many forms that both biomass and biofuel can take. However these research projects focus primarily on woody biomass that will be turned into cellulosic ethanol and used as a component of transportation fuel. Some aspects of this research can also apply to other wood-based forms of energy, such as heat and electricity. There are many potential sources of woody biomass, including shrubs or trees grown on plantations, managed natural forests, and waste products left behind after forest harvesting or management activities. Different refineries or conversion processes may require different types of feedstock, or biomass material for their supply. Using wood as a fuel source has implications for current energy and climate concerns. Carbon dioxide released by burning fuel can be removed from the atmosphere by the re-growth of plant material. Replacing fossil fuels with fuel produced from sustainably managed sources of woody biomass can therefore play a role in mitigating climate change. As a locally available, renewable resource, woody fuels also have the potential to contribute to energy independence for Michigan. 3.2 A BRIEF INTRODUCTION TO BIO-ENERGY CONVERSION TECHNOLOGIES 3.2.1 Bioenergy Conversion Technologies Conversion challenges Conversion technologies There are four types of conversion technologies currently available, each appropriate for specific biomass types and resulting in specific energy products: 1. Thermal conversion is the use of heat, with or without the presence of oxygen, to convert biomass materials or feedstocks into other forms of energy. Thermal conversion technolgies include direct combustion, pyrolysis, and torrefaction. 2. Thermochemical conversion is the application of heat and chemical processes in the production of energy products from biomass. A key thermochemical conversion process if gasification. 3. Biochemical conversion involves use of enzymes, bacteria or other microorganisms to break down biomass into liquid fuels, and includes anaerobic digestion, and fermentation. 63 4. Chemical conversion involves use of chemical agents to convert biomass into liquid fuels. 3.2.1.1 Thermal conversion As the term implies, thermal conversion involves the use of heat as the primary mechanism for converting biomass into another form. Combustion, pyrolysis, torrefaction, and gasification are the basic thermal conversion technologies either in use today or being developed for the future. Combustion Direct combustion is the burning of biomass in the presence of oxygen. Furnaces and boilers are used typically to produce steam for use in district heating/cooling systems or to drive turbines to produce electricity. In a furnace, biomass burns in a combustion chamber converting the biomass into heat. The heat is distributed in the form of hot air or water. In a boiler, the heat of combustion is converted into steam. Steam can be used to produce electricity, mechanical energy, or heating and cooling. A boiler’s steam contains 60-85% of the energy in biomass fuel. Co-firing is a practice which has permitted biomass feedstocks to be used early on in the renewable energy transformation. Co-firing is the combustion of a fossil-fuel (such as coal or natural gas) with a 1 (com.biomasswithplants) biomass feedstock. Co-firing has a number of advantages, particularly when electricity is an output. If the conversion facility is situated near an agro-industrial or forestry product processing plant, large quantities of low cost biomass residues are available to be burnt with a fossil-fuel feedstock. It is now widely accepted that fossil-fuel power plants are usually highly polluting in terms of sulfur, CO2 and other GHGs. Use of existing equipment, with modifications, to co-fire biomass may be a cost-effective means for meeting more stringent emissions targets. Biomass fuel’s comparatively low sulfur content allows biomass to potentially offset the higher sulfur content of fossil fuel. Biomass can also be used in co-generation, also called combined heat and power (CHP) which is the simultaneous production of heat and electricity. All power plants produce heat as a by-product of electricity production, and this heat is typically released to the environment through cooling towers (which release heat to the atmosphere) or discharge into near-by bodies of water. However, in CHP processes, some of the “waste heat” is recovered for use in district heating. Co-generation coverts about 85% of biomass’ potential energy into useful energy. Pyrolysis and torrefaction These processes do not necessarily produce useful energy directly, but under controlled temperature and oxygen conditions are used to convert biomass feedstocks into gas, oil or forms of charcoal. These energy products are more energy dense than the original biomass, and therefore reduce transport costs, or have more predictable and convenient combustion characteristics allowing them to be used in internal combustion engines and gas turbines. Pyrolysis is a processes of subjecting a biomass feedstock to high temperatures (greater than 430 °C) under pressurized environments and at low oxygen levels. In the process, biomass undergoes partial combustion. Processes of pyrolysis result in liquid fuels and a solid residue called char, or biochar. Biochar is like charcoal and rich in carbon. Liquid phase products result from temperatures which are too low to destroy all of the carbon molecules in the biomass so the result is production of tars, oils, methanol, acetone, etc. Torrefaction, like pyrolysis, is the conversion of biomass with the application of heat in the absence of oxygen, but at lower temperatures than those typically used in pyrolysis. In torrefaction temperatures 64 typically range between 200-320 °C. In the torrefaction process water is removed and cellulose, hemicellulose and lignins are partially decomposed. The final product is an energy dense solid fuel frequently referred to as “bio-coal”. Thermochemical conversion (Corning Museum of Glass) Thermochemical technologies are used for converting biomass into fuel gases and chemicals. The thermochemical process involves multiple stages. The first stage involves converting solid biomass into gases. In the second stage the gases are condensed into oils. In the third and final stage the oils are conditioned and synthesized to produce syngas. Syngas contains carbon and hydrogen and can be used to produce ammonia, lubricants, and through the Fischer-Tropsch process can be used to produce biodiesel. Gasification Gasification is the use of high temperatures and a controlled environment that leads to nearly all of the biomass being converted into gas. This takes place in two stages: partial combustion to form producer gas and charcoal, followed by chemical reduction. These stages are spatially separated in the gasifier, with gasifier design very much dependant on the feedstock characteristics. Gasification requires temperatures of about 800°C. Gasification technology has existed since the turn of the century when coal was extensively gasified in the UK and elsewhere for use in power generation and in houses for cooking and lighting. A major future role is envisaged for electricity production from biomass plantations and agricultural residues using large scale gasifiers with direct coupling to gas turbines. Biochemical conversion The use of micro-organisms for the production of ethanol is an ancient art. However, in more recent times such organisms have become regarded as biochemical "factories" for the treatment and conversion of biological materials. Fermentation technologies, with the assistance of biological engineering, are leading to breakthrough processes for creating fuels and fertilizer, and other products useful in agriculture. Anaerobic digestion and fermentation are key biochemical conversion technologies. Anaerobic digestion Anaerobic digestion is the use of microorganisms in oxygen-free environments to break down organic material. Anaerobic digestion is widely used for the production of methane- and carbon-rich biogas from crop residues, food scraps, and manure (human and animal). Anaerobic digestion is frequently used in the treatment of wastewater and to reduce emissions from landfills. Anaerobic digestion involves a multi-stage process. First, bacteria are used in hydrolysis to break down carbohydrates, for example, into forms digestible by other bacteria. The second set of bacteria convert the resulting sugars and amino acids into carbon dioxide, hydrogen, ammonia and organic acids. Finally, still other bacterias convert these products into methane and carbon dioxide. Mixed bacterial cultures are 65 characterized by optimal temperature ranges for growth. These mixed cultures allow digesters to be operated over a wide temperature range, for example, above 0° C and up to 60° C. When functioning well, the bacteria convert about 90% of the biomass feedstock into biogas (containing about 55% methane), which is a readily useable energy source. Solid remnants of the original biomass input are left over after the digestion process. This by-product, or digestate, has many potential uses. Potential uses include fertilizer (although it should be chemically assessed for toxicity and growth-inhibiting factors first), animal bedding and low-grade building products like fiberboard. Fermentation At its most basic, fermentation is the use of yeasts to convert carbohydrates into alcohol – most notably ethanol, also called bioethanol. The total process involves several stages. In the first stage crop materials are pulverized or ground and combined with water to form a slurry. Heat and enzymes are then applied to break down the ground materials into a finer slurry. Other enzymes are added to convert starches into glucose sugar. The sugary slurry is then pumped into a fermentation chamber to which yeasts are added. After about 48-50 hours, the fermented liquid is distilled to divide the alcohol from the solid materials left over. In the U.S., corn grain is the primary feedstock in ethanol production. About 2.8 gallons of ethanol is produced from one bushel of corn. A by-product of the corn-to-ethanol process is spent grains. These spent grains are dried and can be used as feed for livestock – termed Distillers Dried Grains, or DDGs. Cellulosic ethanol production by fermentation is more complex than conversion of starch or sugar components of plants. Cellulosic ethanol production involves use of wood, grasses and the stems, leaves and stalks of non-grass plants. Lignocellulose, the structural material of plants, must first be broken down into sugars before being fermented into ethanol. Molecules of cellulose, hemicellulose and lignin – the components of lignocellulose, have strong chemical bonds and are difficult to separate. Mechanical pretreatment and enzymatic are necessary to breakdown lignocellulose. As a result, at present, conversion of lignocellulosic materials into ethanol is less cost-effective than conversion of starch and sugar crops to ethanol. Reducing the cost and improving the efficiency of separating and converting cellulosic materials into fermentable sugars is one of the keys to a viable industry. Research and development efforts are focusing on the development of cost-effective biochemical hydrolysis and pretreatment processes to overcome this barrier. Hydrolysis is a chemical process in which molecules are split into parts with the addition of water and a salt or weak acid. Another form of hydrolysis involves use of enzymes. Such technological advances promise substantially lower processing costs. Chemical conversion (uiowa.edu) Chemical conversion of biomass involves use of chemical interactions to transform biomass into other forms of useable energy. Transesterification is the most common form of chemical-based conversion. Transesterification is a chemical reaction through which fatty acids from oils, fats and greases are bonded to alcohol. This process reduces the viscosity of the fatty acids and makes them combustible. Biodiesel is a common end-product of transesterification, as are glycerin and soaps. Almost any bio-oil (such as soybean oil), animal fat or tallow, or tree oil can be converted to biodiesel. 3.3 UTILIZATION OF BIO-ENERGY WITH REFERENCE TO THE GLOBAL CARBON CYCLE AND CLIMATIC CHANGE, ESPECIALLY WITH REGARD TO CO2 EMISSIONS AND CARBON STORAGE; 66 3.3.1 Bio-energy with carbon capture and storage Bio-energy with carbon capture and storage (BECCS) is a greenhouse gas mitigation technology which produces negative carbon dioxide emissions by combining biomass use with geologic carbon capture and storage. The concept of BECCS is drawn from the integration of trees and crops, which extract CO 2 from the atmosphere as they grow, the use of this biomass in processing industries or power plants, and the application of carbon capture and storage. BECCS is a form of carbon dioxide removal, along with technologies such as biochar, carbon dioxide air capture and biomass burial. According to a recent Biorecro report, there is 550 000 tonnes CO2/year in total BECCS capacity currently operating, divided between three different facilities (as of January 2012). It was pointed out in the IPCC Fourth Assessment Report by the Intergovernmental Panel on Climate Change (IPCC) as a key technology for reaching low carbon dioxide atmospheric concentration targets. The negative emissions that can be produced by BECCS has been estimated by the Royal Society to be equivalent to a 50 to 150 ppm decrease in global atmospheric carbon dioxide concentrations and 67 according to the International Energy Agency, the BLUE map climate change mitigation scenario calls for more than 2 gigatonnes of negative CO2 emissions per year with BECCS in 2050. The Imperial College London, the UK Met Office Hadley Centre for Climate Prediction and Research, the Tyndall Centre for Climate Change Research, the Walker Institute for Climate System Research, and the Grantham Institute for Climate Change issued a joint report on carbon dioxide removal technologies as part of the AVOID: Avoiding dangerous climate change research program, stating that "Overall, of the technologies studied in this report, BECCS has the greatest maturity and there are no major practical barriers to its introduction into today’s energy system. The presence of a primary product will support early deployment." According to the OECD, "Achieving lower concentration targets (450 ppm) depends significantly on the use of BECCS". Negative emission The main appeal of BECCS is in its ability to result in negative emissions of CO2. The capture of carbon dioxide from bioenergy sources effectively removes CO2 from the atmosphere. Bio-energy is derived from biomass which is a renewable energy source and serves as a carbon sink during its growth. During industrial processes, the biomass combusted or Carbon flow schematic for different energy systems. processed re-releases the CO2 into the atmosphere. The process thus results in a net zero emission of CO2, though this may be positively or negatively altered depending on the carbon emissions associated with biomass growth, transport and processing, see below under environmental considerations. Carbon capture and storage (CCS) technology serves to intercept the release of CO2 into the atmosphere and redirect it into geological storage locations. CO2 with a biomass origin is not only released from biomass fuelled power plants, but also during the production of pulp used to make paper and in the production of biofuels such as biogas and bioethanol. The BECCS technology can also be employed on such industrial processes. It is argued that through the BECCS technology, carbon dioxide is trapped in geologic formations for very long periods of time, whereas for example a tree only stores its carbon during its lifetime. In its report on the CCS technology, IPCC projects that more than 99% of carbon dioxide which is stored through geologic sequestration is likely to stay in place for more than 1000 years. While other types of carbon sinks such as the ocean, trees and soil may involve the risk of negative feedback loops at increased temperatures, BECCS technology is likely to provide a better permanence by storing CO2 in geological formations. The amount of CO2 that has been released to date is believed to be too much to be able to be absorbed by conventional sinks such as trees and soil in order to reach low emission targets. In addition to the presently accumulated emissions, there will be significant additional emissions during this century, even in the most ambitious low-emission scenarios. BECCS has therefore been suggested as a technology to reverse the emission trend and create a global system of net negative emissions. This implies that the emissions would not only be zero, but negative, so that not only the emissions, but the absolute amount of CO2 in the atmosphere would be reduced. 68 Projected cost to reach the respective 350ppm and 450ppm target scenarios by 2100. 265ppm indicates the pre-industrial atmospheric CO2 level. Application Source CO2 Source Sector Electrical power Combustion of biomass or biofuel in steam or gas powered generators Energy plants releases CO2 as a by-product Heat plants power Combustion of biofuel for heat generation releases CO2 as a by-product. Energy Usually used for district heating Pulp and paper mills CO2 produced in recovery boilers CO2 produced in lime kilns For gasification technologies, CO2 is produced during the gasification of black liquor and biomass such as the tree bark and woody. Huge amounts of CO2 are also released by the combustion of syngas, a product of gasification, in the combined cycle process. Industry Ethanol production Fermentation of biomass such as sugarcane, wheat or corn releases CO2 as a Industry by-product Biogas production In the biogas upgrading process, CO2 is separated from the methane to Industry produce a higher quality gas Technology The main technology for CO2 capture from biotic sources generally employs the same technology as carbon dioxide capture from conventional fossil fuel sources. Broadly, three different types of technologies exist: post-combustion, pre-combustion, and oxy-fuel combustion. Cost The sustainable technical potential for net negative emissions with BECCS has been estimated to 10 Gt of CO2 equivalent annually, with a economic potential of up to 3.5 Gt of CO2 equivalent annually at a cost of less than 50 €/tonne, and up to 3.9 Gt of CO2 equivalent annually at a cost of less than 100 €/tonne. Policy Based on the current Kyoto Protocol agreement, carbon capture and storage projects are not applicable as an emission reduction tool to be used for the Clean Development Mechanism (CDM) or for Joint Implementation (JI) projects. Recognising CCS technologies as an emission reduction tool is vital for the implementation of such plants as there is no other financial motivation for the implementation of such systems. There has been growing support to have fossil CCS and BECCS included in the protocol. Accounting studies on how this can be implemented, including BECCS, have also been done. Environmental considerations Some of the environmental considerations and other concerns about the widespread implementation of BECCS are similar to those of CCS. However, much of the critique towards CCS is that it may strengthen the dependency on depletable fossil fuels and environmentally invasive coal mining. This is not the case with BECCS, as it relies on renewable biomass. There are however other considerations which involve BECCS and these concerns are related to the possible increased use of biofuels. 69 Biomass production is subject to a range of sustainability constraints, such as: scarcity of arable land and fresh water, loss of biodiversity, competition with food production, deforestation and scarcity of phosphorus. It is important to make sure that biomass is used in a way that maximizes both energy and climate benefits. There has been criticism to some suggested BECCS deployment scenarios, where there would be a very heavy reliance on increased biomass input. These systems may have other negative side effects. There is however presently no need to expand the use of biofuels in energy or industry applications to allow for BECCS deployment. There is already today considerable emissions from point sources of biomass derived CO2, which could be utilized for BECCS. Though, in possible future bio-energy system upscaling scenarios, this may be an important consideration. The BECCS process allows CO2 to be collected and stored directly from the atmosphere, rather than from a fossil source. This implies that any eventual emissions from storage may be recollected and restored simply by reiterating the BECCS-process. This is not possible with CCS alone, as CO2 emitted to the atmosphere cannot be restored by burning more fossil fuel with CCS. Carbon Cycling and Climate One of the most daunting challenges facing science in the 21st Century is predicting the response of Earth’s ecosystems to global climate change. Although the global carbon cycle plays a central role in regulating atmospheric carbon dioxide (CO₂) levels and thus Earth’s climate, our understanding of the interlinked biological processes that drive this cycle remains limited. Whether ecosystems will capture, store, or release carbon is highly dependent on how changing climate conditions affect processes performed by the organisms that form Earth’s biosphere. Advancing our knowledge of biological components of the global carbon cycle is crucial to predicting potential climate change impacts, assessing the viability of climate change adaptation and mitigation strategies, and informing relevant policy decisions. Greater insight particularly is needed into the role microbial communities play in many critical carbon cycle processes. In many cases, these microbially mediated processes are only minimally represented in carbon cycle models, which may limit their predictive capability and scale of resolution. Elimination of these so-called “black boxes” will require innovative approaches aimed at linking structural and functional characterization of microbial communities with quantitative measurement of carbon cycle processes. 70 3.4 AND THE ROLE OF BIO-ENERGY IN PAKISTAN AND OTHER COUNTRIES, ESPECIALLY ITS POTENTIAL FOR THE DEVELOPMENT OF RURAL AREAS. 3.4.1 A Future Role for Biomass Energy Biomass could become a central part of future sustainable energy supplies. Both the economic and practical feasibility of such a developmental approach has been demonstrated by Johansson et al. {1993} in their Renewables Intensive Global Energy Scenario (RIGES). RIGES demonstrates that it is possible to provide energy for growth and development at no extra cost compared to conventional fossil-based systems. A reduction in global CO2 emissions would occur as a result of such an increase in renewablesbased energy supply of which biomass would be a significant energy resource. Two recent studies have recently emerged which provide independent support for such an important economic claim. Kulsum Ahmed of the World Bank {1993} has shown that biomass conversion technologies are capable of providing modern energy carriers at costs comparable with equivalent oilbased carriers if oil is priced at about US$ 20 per barrel. An important conclusion of this report is that there is a strong downward trend in the costs of biomass based technologies which is likely to continue. Secondly, a Shell Co. report has shown the promise of biomass based electricity generating units (BIG/GT) which could be produced at the same or lower capital costs to fossil based units ie. at about US$ 1,500 per MWe, if the anticipated results of an existing Global Environment Funded (GEF) project are achieved. {Elliott P., 1993} To put the potential contribution of biomass in context, under RIGES by 2050, biomass would provide 17% of electrical power and 38% of direct fuel use. Altogether, "renewables" could supply 3/5 of electrical power production and 2/5 of direct fuel use by 2050 at the same or lower cost to future advanced fossil fuel-based systems. (see section 6) Such a switch to modern bioenergy systems of the scale outlined above would have significant benefits to both developing and industrialised countries. In developing countries, the provision of affordable rural energy supplies will provide important improvements in both food and cash crop yields, mainly by enabling farmers to provide irrigation and agro-industrial energy at the various levels. Indeed, such rural biomass-based systems could provide the catalyst for self-sustaining indigenous rural development once constraints are removed (see below), also providing a sustainable energy source for urban centres. As such, modern biofuel technologies may actually aid developing country farmers to increase food crop yields at a faster rate than population growth. In so doing, indigenous biomass energy crops could help avoid the need to expand food production onto marginal land thus, negating potential food versus fuel arguments. {Williams, 1994} A growing number of industrialised countries are beginning to view biomass-based energy systems as an important policy tool for addressing complex problems such as GHG emissions, rural development and energy security. Industrialised countries where biomass is providing a fast growing share of the energy sector include Austria, Denmark, Finland, France, Norway, Sweden and the USA. Sustainably grown biofuels are CO2-neutral and low acid rain polluters and need large quantities of land. This land use intensity is regarded as a benefit as it allows policy makers a novel use for the excess cropland areas which are now emerging due to rationalisation of agricultural policies in Europe and North America. A major facet of modern bioenergy growth and conversion facilities is their modularity at relatively modest scales (1 to 100 MW). Modularity is an important concept as it allows energy planners to provide small incremental additions to the production capacity as opposed to the large-scale (500 to 1,000 MWe) fossil-based additions usually needed. For example, modern bioenergy conversion facilities are not prone to the economies of scale of existing fossil-based systems, thus, negating the necessity to add very large increments (500 to 1,000 MW) to the energy production capacity in order to benefit from those economies of scale. Thus, inaccurate supply and demand forecasting will not be as important with such biomass systems. In addition, the relatively large number of small biomass energy generating systems provides an inherent increase in supply security. 3.4.2 Constraints. Why then have modern biomass energy technologies not been spontaneously and widely adopted and thereby obtaining a more significant share of the energy market? The answer lies partly in the complexity and site specificity of the factors governing biomass growth and conversion. Whilst in developing countries traditional biomass use may already be highly important, 71 present trends in its use are often unsustainable and of low efficiency. In industrialised countries, biomass use for energy up until the last few years has been restricted to niche markets where feedstock costs have been low or zero such as in sawmills, pulp and paper industries, etc. Despite the site specificity of factors such as feedstock cost, proximity to market and likely market size, a number of general constraints to increased bioenergy use can be identified: i. subsidies to competitors e.g. kerosine, or fossil fuel derived electricity, the so-called "uneven playing field." ii. Scepticism over the reliability and economic feasibility of biomass energy projects due to a number of high profile biomass energy project failures. Often these failures were due to social incompatibilities or inflexibility of project aims and not necessarily concerned with the technology per se, however, the sentiment persists. iii. A secure market must exist for biomass-energy products. iv. Traditional biomass conversion technologies are dogged by low conversion efficiencies and viewed more as a means of waste disposal than for energy production. v. There is a lack of awareness by senior decision makers, potential users and financiers about the multiple benefits of bioenergy systems. vi. Bioenergy systems require co-operation between sectors which do not normally communicate. At the national level, the agriculture and forestry sectors must communicate effectively with the energy and land planning sectors. At the international level there needs to be an integrated approach between institutions such as the World Bank, the UN (including UNEP, UNDP, FAO) and multi-national companies which must also involve NGOs. vii. At the local/village level there is a need for the strengthening or creation of a transparent organisational infrastructure so as to ensure technically sound biofuel systems provide effective and equitable returns to consumers and suppliers alike. viii. The initial capital costs of conversion equipment may be higher than comparable fossil fuel systems, and potential financiers may be difficult to find despite the cheaper full life-cycle costs. There may also be little or no backup or operation and maintenance facilities due to the novelty of the technology. Despite these constraints when full life-cycle costs and potential environmental and wider social benefits are accounted for biomass-based energy systems will, in many cases be the least-cost long-run option. 3.4.3 Environment & Management. Besides potential greenhouse abatement benefits of biomass energy, its production can address many other "secondary" issues. {Ranney, 1992a} Such problematic areas which may benefit from large scale biomass energy are: soil erosion, raising habitat diversity, control of nitrogen run-off and the protection of watersheds. (see section 5) Bioenergy is certainly no panacea for solving the world's energy problems since it is not without its difficulties. Indeed, the production of the biomass itself can be intensive in planning, management, labour and land. For sustainable growth, detailed planning will be required from local, to national, to regional levels. The inappropriate selection and site-matching of species or management strategies can have deleterious effects and lead to degradation and abandonment of land. However, the correct selection of plant species can allow the economic production of energy-crops in areas previously only capable of sustaining low plant productivities; simultaneously multiple benefits may accrue to the environment. Such selection strategies may allow synergistic increases in food-crop yields and decreased fertiliser applications whilst providing sustainable local sources of energy and employment. 3.4.4 Biomass Use for Large scale Energy Production. The perception of biomass energy has changed recently in a number of industrialised countries. This has led to biomass gaining a growing and significant share of the primary energy sector in USA, Sweden and Austria (4%, 16% and 10% of primary energy respectively; see section 3). Biomass has previously been regarded as a low-grade, "poor man's" fuel, but is increasingly viewed as an environmentally and socially advantageous source of energy. In the newly industrialising countries, for example Brazil, biomass energy has always been an important traditional energy source, predominantly for the domestic sector. However, under the initiative of various programmes in a number of countries, such as for ethanol and electricity production, biomass energy has attained a significantly higher profile. With a better understanding of the negative aspects of biomass supply and methods for their mitigation, bioenergy is 72 increasingly perceived by energy planners not as a problem, but as an opportunity for the sustainable provision of energy. 3.4.4 Global Warming The Intergovernmental Panel on Climate Change's 1992 Supplement (IPCC92) has found no evidence to markedly change their 1990 global warming predictions. They now state i.e. missions resulting from human activities are substantially increasing the atmospheric concentrations of greenhouse gases. ii) modelling studies indicate that the mean surface temperature sensitivity to doubling CO 2 is unlikely to lie outside the range 1.5°C to 4.5°C, iii) the global mean surface temperature has increased by 0.3°C to 0.6°C over the past 100 years, and iv) the unequivocal detection of the enhanced greenhouse effect from observations is not likely for a decade or more. Furthermore, of the 6.0 ±0.5 GtC emitted in 1989/90 from the two primary atmospheric CO2 sources, mainly, the combustion of fossil-fuels and secondly, land-use changes, the latter change accounts for 1.6 ± 1.0 GtC. A substantial proportion of the carbon emissions from land-use changes are derived from the 17 Mha yr.-1 of tropical deforestation estimated to have occurred between 1981 and 1990, which is expected to continue {IPCC, 1992}. However, the measured increase in the atmospheric concentration of CO2 is not consistent with the calculated level of emissions from fossil fuel use and land use changes. These measurements indicate that either the level of emissions is exaggerated, which seems unlikely, or that more CO 2 is being reabsorbed, by an unknown mechanism, than estimated, i.e. there exists a "missing sink." The destination of the socalled "missing sink" carbon is still uncertain. It is thought that not all this "missing" CO 2 has been absorbed into a large oceanic sink but that a terrestrial sink exists possibly resulting from a C0 2 fertilisation effect on vegetation growth. {Wigley 1992.} Even though there is some uncertainty over the extent of global warming the latest estimates only serve to make the arguments concerning "the precautionary principle" and the possible benefits from land rehabilitation of greater importance. 3.4.5 A Conflict for Resources Of greater certainty is that the global population will continue to increase. The IPCC92 revised estimates of population growth predict rises of between 1.27% and 2.28% per year or the equivalent of a gross increase of 44% to 80% by the year 2025 from 1990 levels. Population growth makes increasing both food and energy supplies of paramount importance. Potential conflicts between these resources must be assessed and planned for. The perception that all development requires more energy per se, is not necessarily valid. Improvements in the efficiency with which energy is produced and used, have highlighted the importance of the services that energy can provide, as opposed to increasing total amounts of energy i.e. less energy can be made to do more. Future policies for indigenous biomass energy production should ensure that improvements in income generation, provision of modern energy services and trade benefits are returned in a significant fraction to the local populations. This implies that the rural incentives and the infrastructure necessary for the sustainable development and provision of such biomass energy services are developed at the local level. (see section 3, Hosahalli) However, the provision of biomass-based energy services should not conflict with land requirements for food production. Research indicates that the problem is not the size of the land resource, but its efficient management for biomass production in all its forms- for food, fuel, fodder, etc. (see sections 2 and 3.) Research on wood energy activities over the last decade (after the 1981 Nairobi Plan of Action), has shown that contrary to popular belief, "factors other than the use of fuelwood and charcoal are the chief causes of deforestation; processes such as farming, forest fires and the industrial use of forests are the chief causes." {FAO, 1993} Small increases in energy inputs (especially where none previously existed) will provide significant returns in yield improvements, effectively increasing land availability rather than competing for it, hopefully reducing the pressures causing deforestation and land degradation. Modern, efficient industrial and domestic energy conversion technologies are also required if full advantage is to be taken of the potential environmental, economic and health facets of biomass energy. (see chapters 4 & 5). 3.4.6 Energy Balances. The high yields presently achieved by intensive agriculture require significant energy inputs and mechanical methods of production. For many crops under intensive management the energy required for cultivation and processing may exceed the energy content of the food produced. However, the energy output to input ratio of woody and fibrous energy crops is very favourable (in excess of 10 times and 73 about 6 to 7 times for ethanol from sugarcane); for these crops high energy inputs can be rewarded with net increases in energy output. {Ledig, 1981; Gladstone & Ledig, 1990} In general, cereal crops give a positive energy return even under intensive management e.g. maize contains 3.5 times the energy in the harvested grain alone than it requires to cultivate and process. However, some crops presently require more energy to produce than they return in the food produced e.g., energy output to input ratios are: apples 0.9, lettuce 0.2, tomatoes 0.6 and cabbage 0.8 {Pimentel, 1984}. Note that many of these calculations do not account for the energy content of the associated residues which are significant. There are considerable opportunities to make farms and forests both net energy exporters and net carbon sequesterers2. This potential has been highlighted in a recent report by the USA Council for Agriculture, Science and Technology (CAST, 1992). It states that "a great opportunity for U.S. agriculture to help mitigate climate change lies (through the) stashing of carbon in soil and trees and displacing fossil fuel." CAST estimates that US agriculture could plausibly displace 8% of US energy with biomass fuels which would reduce total US CO2 emissions by 10%. 2 "Sequester" is defined as the net removal of CO2 from the atmosphere and subsequent storage in organic matter. However, where fossil fuels are used in the production of biofuels some CO2 is inevitably emitted, even where this CO2 is effectively re-absorbed through increases in standing carbon or in fossil fuel substitution benefits. In the future these emissions could be eliminated through the use of biofuels or non-CO2emitting renewables to supply the energy for growth and processing of the biofuels. 3.4.7 The Potential Biomass Energy Resource. Given appropriate institutional and management policies biomass energy offers the opportunity for the provision of substantial amounts of energy. At the same time it can provide rural employment and environmental benefits. The adoption of biomass energy systems globally may, however, require changes in farming, forestry and energy-use practices. Initially, such energy systems would have to be based primarily on agricultural residues during the establishment and development of bioenergy plantations. The potential for sustainable energy supplies from such plantations is considerable. For example, energy plantations on only 3% of Brazil's land could theoretically provide much more than its current total primary energy consumption. It is now recognised that biomass presently plays an integral role in the energy provision of most developing countries. However, the future potential of biomass energy must be realistically assessed accounting for present (usually very inefficient) production and use, and the problems of future energy provision. Prevailing climatic conditions in many developing countries lend themselves to high biomass yields if growth is not unduly limited by nutrient, water or pest and disease constraints. Many of these countries e.g. Brazil, Zaire and Thailand are also well endowed with large potential land areas for biomass growth and could thus become net energy exporters. The development of the rural energy industries required would provide significant levels of employment and income generation. It is difficult to over-estimate the range of uses and importance of different traditional and modem forms of biomass products and residues in both the rural and urban sectors of developing countries. The industrial sectors of developing countries consume an average of 40 to 60% of commercial fossil fuel supplies and also use significant amounts of biomass fuels. These biomass fuels are often sold on the commercial market. Industry also provides roughly 25 to 35% of rural non-farm employment. {OTA, 1991} Whilst biomass production and supply is almost exclusively rural, its use in the urban sector is highly diverse, economically important and energetically vital. The consumption of other, more convenient fuels (especially kerosene) is widespread; however, fuelwood remains the dominant source of energy in many developing countries.(box 1) Biomass is used mainly in the form of charcoal and fuelwood, but agricultural residues, including dung and The uses of biomass include: physical- construction timber, poles (houses and fencing) and thatch; fibrous-mats and mixed with mud in hut walls; thermal- fuel for cooking, tobacco curing (requiring approx. 6-60 t of wood per t of cured tobacco produced, i.e. 90 to 900 GJ/t), tea/coffee drying, brick and tile making (roughly between 1,500 to 19,000 MJ/1000 bricks; 500 to 6,300 MJ/t for 3 kg bricks), paddy parboiling (4.17 GJ/t), gur making (24.95 GJ/t, brown sugar) rubber making, coconut, bakeries, tanneries/cloth makers and charcoal in metal production and processing, pulp for paper making, food preparation in shops and restaurants and shops, (table 8 for various types of industrial biomass use.) 74 There is a large potential for increasing the level of energy services from biomass sources through the adoption of modernised forms of bioenergy production and the use of energy-efficient equipment, without proportional increases in the amount of biomass use. Such strategies may make one unit of biomass work for longer e.g. cook more food from 1 kg of charcoal, or provide more services e.g. light, water pumping, milling, etc. per unit of biomass consumed, (see Hosahalli village section) (I) Biomass use in Bangladesh In Bangladesh in 1988, biomass provided about 70% (519 PJ) of Bangladesh's energy, 20% of which was used by industry. The remaining 80% of total biomass fuel consumption was for domestic cooking, 45% of which was used in the urban sector and 65% in rural areas. Commercial fuels (mostly diesel and gas) provided about 220 PJ. Whilst most towns have piped gas supplies and many households are connected, consumption is often overestimated as many households which are connected still use charcoal and agricultural residues due to the cost of the gas and service facilities. {Ahsan Ul Haye, 1988} Charcoal. Charcoal use is wide-spread throughout developing countries, however, its increasing production and use is causing concern as unsustainable sources of wood are mined, destroying forests and eroding land. It is preferred by domestic users because of its convenience of use (small size, low weight) and quality of burning (constant heat, long lasting) compared to other accessible energy sources, such as firewood, crop residues and dung. It is preferred by industry and charcoal producers because of its energy density (about 30 GJ/t) and relative ease to transport compared to wood (small chunks which pack easily). The charcoal industry often has a large infrastructure, based on an indigenous, if often unsustainable supply sources (i.e. forests & woodlands). Charcoal's low price and convenience for transport and use means that attempts to induce industrial and domestic users to switch from charcoal to other fuel sources, mainly fossil fuels, are unlikely to succeed in the near to medium term in many developing countries. During the 1980's, however, due to increases in the efficiency with which charcoal was produced from wood, and the switch to plantation derived wood from natural sources, Brazil has been able to significantly increase its charcoal use. Brazil has been able to achieve this increase without increasing charcoal production from natural sources. The Brazilian charcoal industry is discussed in detail below. (II) Brazil Large amounts of charcoal are consumed in the reduction and heating of iron ore for pig iron production. In 1990, Brazil consumed over 36 Mm3 of charcoal of which 18.6 Mm3 was for pig-iron production. Before 1975, virtually all the charcoal was supplied from native forests with increasingly detrimental effects to the environment, mainly resulting from the destruction of natural forests. This essentially free energy source allowed Brazilian pig iron to become highly competitive in the world markets; it was finally recognised, however, that the continued exploitation of natural forests at such a rate was unsustainable. In an effort to establish sustainable wood production for the charcoal and pulp + paper industries the Government introduced tax incentives for the commercial growth of plantations in its 1965 Forestry Act. The consequences of this Act have been far reaching as 1t stipulated target percentages of total production (not quantities) which had to be reached within specified time periods (table 7). Presently all pulp and paper and 34% of charcoal production is plantation-derived, the wood being provided from an estimated 4 to 6 Mha of plantations, mostly Eucalyptus. By 1995, the plantation-derived charcoal percentage is required to rise to 100% according to Brazilian regulations; however, the effective total will only be around 80% due to a stipulated allowance for charcoal production from forest residues (see table 7). Estimates of present plantation areas are complicated by the abandonment of young plantations which had been registered under the Act, or the death of parts of plantations (hence also resulting in lower than predicted productivities.) It is now believed that between 4 and 6 Mha of commercial plantations are in operation, with an increase of between 0.2 and 0.45 Mha/yr. since 1970. {de Jesus, 1990; Rosillo-Calle, 1992}. Pandey {1992} has estimated a net area of plantations in Brazil (1990) of 6.1 Mha. This is dependant on the success rate for the establishment of plantations having been maintained at the 87% success level ascertained from the 1981-82 inventory of plantations. {Pandey, 1992} It may be reasonable to expect this success rate to have increased as the results of continuing R&D are incorporated into plantation 75 management techniques, and hence net plantation areas may actually be higher than suggested. Charcoal production. The efficiency with which wood is converted to charcoal has also benefited from the Brazilian regulations since the large iron and steel producing companies have been forced to obtain reliable supplies of plantation charcoal. This has inevitably led to many of them investing in the development of large plantation and charcoal production facilities. Such competition has resulted in the need for increased yields, efficiency and benefits from economies of scale. Most charcoal is still produced using internally heated beehive kilns (mud or brick, taking 9-50 m3 wood), the technology of which is up to 100 years old and is often inefficient. (Ch.4, carbonisation) There is considerable room for improvement in efficiency, perhaps to over 30% of the weight of the original wood being converted to charcoal, so also reducing costs. Present conversion efficiencies are often below 20% by weight. Larger kiln sizes can allow partial mechanisation of the charcoal making process by using forklift trucks to load and unload the kilns allowing faster overall production cycle times. For example, the 300 m 3 kilns now used by CAF in Bahia state can be loaded, carbonized and unloaded in 7 days, resulting in significant savings in labour and more socially acceptable weekly work patterns. The carbonisation process is also much more closely controlled increasing the efficiency of conversion. Many of the larger kilns also allow tar and oil recuperation which is sold as low-grade fueloil; this practice also results in less environmental damage from the leakage of these oils into surrounding soils. Costs of wood production for charcoal are highly dependant on the original cost of the land, soil type, yield and relief. Harvesting costs can increase by up to 75% depending on the steepness of the land. The four main cost components in charcoal production i.e. wood yields, harvest, carbonisation and transport, usually result in production costs above 1992 US$ 25 per m 3 charcoal (about US$ 3.5/GJ). Transport costs are generally above US$ 0.0125 per m3.km, and thus for average transport distances of about 300 km, total minimum delivered charcoal costs about 1992 US$ 4/GJ. In general, costs for industrially produced and delivered charcoal are in the range US$ 3.8 to 4.4 per GJ (US$ 27 to 31 per m3). {Rosillo-Calle et al, 1992} (III) Somalia Whilst the present political instability of this country makes continued monitoring impossible, detailed data obtained previously highlights many important aspects of industrial charcoal production in a poor developing country. It is thus included here. In many countries, the demand for energy in the cities is having adverse effects on the livelihoods of the rural inhabitants who reside near the source of biomass to be exploited as a fuel. In Somalia, for example, the capital city Mogadishu consumed about 42,000 t fuelwood in 1983 or about 0.5 t/capita. Mogadishu's fuelwood production for domestic consumption was estimated to be about 17,000 t's, institutional (hospitals, schools, prisons, military) and for the industrial sector (e.g. lime production) more than 29,000 t's. In contrast to Brazil where most of charcoal production is industrial, 95% of Somalian charcoal produced was consumed for cooking, and was mainly derived from small scale artisanal production, generally of low efficiency. Households in Mogadishu spent on average about 10% of all household expenditure on fuel, one third of which was for charcoal. The concentrated urban purchasing power in Somalia and elsewhere (large centralised market) made it economically possible to transport fuels over long distances, and therefore spread the influence of the cities and towns further into the rural sector. Thus, the biomass supply resources were exhausted at ever increasing distances from the urban centres. The size of the market in Mogadishu resulted in its ability to absorb rising prices allowing low efficiencies in conversion of fuelwood to charcoal (often less than 15% by weight); the resulting high costs could be paid for through the gains in energy density of charcoal thereby facilitating longer transport distances compared to wood. Charcoal contains twice as much energy per tonne as wood, and is more convenient to package, hence over distances greater than 100 km the energy lost through conversion to charcoal is compensated for by its lower transportation costs per GJ. {Robinson, 1989). These factors expand the radius to which forests and woodlands can be exploited for urban energy provision. This analysis holds true in many other countries where natural vegetation can be regarded as a free feedstock for charcoal production. In addition, whilst the exploitation of woodlands around Mogadishu was supposed to be carefully controlled (only trees above 15 cm dbh of certain species should be cut) monitoring was superficial, if it existed at all; the wood was therefore regarded as virtually "free". However, the rural populations nearby the woodland source (of the charcoal) noticed that when the selection criteria for suitable trees to be cut 76 was not being followed, resupply was not ensured and degradation inevitably followed. Improper harvesting practices render such land areas prone to severe degradation as a result of loss of vegetative cover leading to soil erosion. Since the costs of restoring the land to its former productivities (if possible) are not met by the charcoal producers, they can simply afford to move to new sources of wood. Thus, whilst regulations are an important tool in the control of such industries, they can be rendered meaningless without proper monitoring and institutional backup. (section 6, policies) Ethanol. The need for an economically competitive, indigenous and sustainable supply of liquid fuel for transportation has resulted in a number of biomass to ethanol projects in developing countries. Most of these projects have been based on sugarcane as the source of biomass. Sugarcane is the world's most photosynthetically efficient agronomic crop, utilising about 2-3% of the energy in the incident radiation for biomass production. Sugarcane is also associated with high levels of by-product formation e.g. bagasse, molasses, stillage. Much of the by-product is either suitable for processing into higher value products (such as animal feed) or for use as energy (thermal, electricity). This multi-product potential, including the ability to upgrade previously unwanted waste products into useful commodities such as electricity and animal feed, has resulted in renewed interest from international development funding organisations. For example, the Global Environment Facility is now funding two major projects involving the utilisation and optimisation of sugarcane for energy. It is presently providing funds for a Brazilian project (1992 US$ 30 million) for the production of electricity from both sugarcane and wood residues, and a Mauritian project (1992, US$ 3.3 million) to optimise the use of bagasse for electricity production (see Electricity section). The potential of cane to produce products tailored to a changing market has been explored by Smith {1992}. Based on recent Puerto Rican data he suggests that the concept of a cane mill which produces ethanol, sugar, animal feed, fiber and recycles refuse would be economically viable. Such a plant would be theoretically able to provide an internal rate of return of 8.7% and a simple payback of less 7½ years, based on a plant life of 30 years in Puerto Rico. Instead of using bagasse residues solely for the production of steam, the majority of the energy required is derived from processed MSW. MSW disposers pay a significant tipping fee; once sorted, however, it could provide revenue from sales of scrap and energy from the combustible fraction. Whilst only 26% of sales are projected to be derived from ethanol, sensitivity analysis suggests that the wide range of products produced (ethanol, feed, fibre and scrap) make this type of plant relatively immune to inflation. {Smith, 1992} Brazil Brazil has been producing ethanol for use as a fuel since 1903. However, after the introduction of government incentives under the 1975 "Proalcool" programme, ethanol has become a significant energy source (4% of total energy consumption). Ethanol is produced as a petrol substitute for the transport sector where it accounted for 18% of fuel consumption by 1987, with annual production now reaching 12 billion litres. It is sold as either a 22% ethanol (0.4% moisture):gasoline blend (Gasohol) for use in unmodified internal combustion engines, or as neat hydrated ethanol (4.5% moisture) for dedicated ethanol cars and light vans. In 1989, there were 4.2 million cars running on neat ethanol and about 5 million on gasohol. This programme has been successful at reducing Brazil's foreign exchange burden from imported liquid fuels. The share of the total energy market occupied by gasoline has dropped from 12% in 1973 to 4% in 1987 and is now equalled by ethanol (substituting for about 250,000 bbl oil/day). Total savings in oil imports between 1976 and 1987 are estimated at $12.48 billion whilst the total investment in the programme was only $6.97 billion. Presently ethanol costs about 18.5 US c/1 with a high value of 23 c/1 and low of 17 c/1 (approx. US $ 7.9 per GJ). At these prices ethanol (as gasohol) would compete economically with crude oil priced at US$ 24/bbl (1992 US$). {Goldemberg et al., 1992} Despite such an apparent lack of economic competitiveness, continued gains in productivity and efficiency have meant that subsidies and price controls are now regarded as detrimental to the viability of the private ethanol production companies and car manufacturers {Goldemberg, 1992}. Furthermore, straightforward economic analysis fails to account for the secondary benefits arising from this programme, such as indigenous employment, wealth generation and reduced atmospheric pollution in the cities. 77 Zimbabwe The Zimbabwean Triangle Programme was commissioned in 1980. Construction was carried out entirely in Zimbabwe using indigenous materials wherever possible. The final cost of 1980 US$ 6.4 million, made it one of the cheapest plants of its capacity to be constructed. However, this cost effectiveness was not at the expense of reliability, as it has run with few problems for over a decade. It has a maximum ethanol production capacity of 40 million litres per year with a target blend of 13% (ethanol; gasoline). Whilst originally having been conceived with strategic goals in mind, its performance in foreign exchange savings have been significant and is presently estimated to be reducing foreign exchange spending by over Z$4 million per year {Chadzingwa, 1987}. Furthermore, the alcohol presently costs little more than imported petrol to produce. {Scurlock et al., 1991} Heat The provision of heat in temperate countries is a major source of domestic energy consumption, and often occurs when power production is most expensive i.e. at night. Even the most efficient thermal power stations produce large amounts of low quality heat which is no longer useful for power generation. The use of this "low quality" heat, which is still of sufficient temperature to supply domestic heating systems, can significantly increase the overall efficiencies of thermal generating systems. In some countries, the development of district-heating supply infrastructure has allowed this "waste" heat to be sold as a commodity to the domestic market providing heat in winter. (see below) Austria. During the 1980's Austria increased the share of primary energy consumption provided by biomass from about 2 or 3% to about 10%. This rapid increase in biomass energy use is predominantly due to the successful promotion of District Heating plants powered by wood chips. The prime political motivation for this scheme continues to be concern about security of energy supplies, the environment and a wish to support the rural economy. It has been greatly facilitated by the decentralised form of government which exits in Austria, and the availability of large quantities of relatively cheap wood residues from forest industries. The size of the present forest industry is mainly a function of the large areas of natural forests remaining in Austria. Presently, approximately 30% of its land area is forest covered, with individual states such as Steiermark, having an excess of 50%. There are now over 80 to 90 district heating systems of 1 to 2 MW average capacity (compromising a total of 11,000 installations), producing 100 PJ (1,200 MW total capacity) which represents about 10% of total energy consumption in 1991. This is expected to increase to 25% of total primary energy consumption by the turn of the century. {Howes R., 1992} The success of this scheme has required both supply and demand side incentives and regulations. Unlike the UK, for example, there are unlikely to be dedicated wood energy plantations in Austria in the near future because of the abundance of existing forestry residues. In particular the banning of practices such as landfill disposal of bark residues by sawmills now means that bark is being sold at 50 to 80 schillings per m3 (approx. 1991 US$ 19-30/t). Sawdust and offcuts are sold at US$ 28 to $ 38/t. Commercial timber is sold at above US$ 40/t. Supply-side incentives are available through the provision of grants for capital equipment. The Federal government provides 10% of the capital costs and the State government a further 3.3%. In addition, the Department of Agriculture provides an extra capital grant of 40% of the final cost if a scheme is set up by a farmer's group. Thus, incentives may be as high as 50% of total capital costs. On the demand side the government will pay 30% of the heat exchanger costs. Further state grants may be available based on the connection fee (additional to the cost of the heat exchanger), charged in proportion to the heating capacity required by each house8. In general this grant is sufficient to cover the connection fee for the average house (peak demand of 15 KW). 8 Cost of connection is between Schillings 40,000 to 60,000, and thus a 30% grant is equivalent to 1991 US$ 1,100 to 1,700. [Exchange rates are assumed to 20 schillings = 1991 US$ 1.9] High capital costs for installed equipment (especially pipes) have rendered these schemes relatively insensitive to fuel price, with success a function of overall intensity of use (defined as kWh per km of pipe) and reliability of supply. Subsidies have in effect only reduced payback times from 14 or 15 years to 10 or 11 years. Thus, income received from domestic users covers all the running costs and a slight surplus; hence the long payback times. 78 The cost of the heat varies, but is in general similar to fossil-fuel (including electrical) heating. It is worth emphasising, however, that in regions where the cost of wood-fired district heating is greater than its alternatives, surveys indicate that people are willing to pay slightly more because they perceive that this money is returned to the local community. It may therefore indirectly benefit the consumer through increasing local wealth and economic activity. {Howes. 1992} Combined heat and power (CHP). Presently thermal conversion efficiencies of well run modern power stations are between 20-35% fuel to electricity. The maximum efficiencies of thermal conversion facilities (the "Carnot Limit", see chp 4) means that it is physically impossible for thermal technologies to raise their power generating efficiencies above 60%. Thus, many countries are now concentrating on methods of using the low-grade "waste heat" which cannot be turned into a higher value energy carrier. This heat may be ideally suited for space heating or even for the various heat requirements of an associated factory. Sweden's Combined Heat and Power programme. In 1991, biomass provided 25% of the fuel consumed in District Heat and CHP programmes. In total, biomass (including peat, 1%) provided approximately 15% of Sweden's primary energy consumption. {NUTEK, 1992} The CHP programme now provides 142 PJ (39.7 TWh) of energy, of which 93% is consumed as district heat and the rest for electricity. There is now a considerable infrastructure in place, with over 8,000 km of pipes for heat distribution, and 2.4 GW of installed CHP capacity. Having curtailed the nuclear option for environmental and economic reasons, Sweden is pursuing methods to increase its energy production from renewable sources. In particular, it continues to invest large quantities of time and money in woodchip technologies both for present thermal technology, mainly for district heat supplies, and also gasification for CHP production from wood powered gas turbines. While the concept is certainly not new, the technologies being applied and developed are innovative. Both Sweden and Denmark now run significant programmes for the use of biomass powered CHP. (box 2 Sweden) Denmark (biogas). Denmark has a long standing tradition for the use of renewable forms of energy. It is presently best known for its widespread use of wind-generated electricity for supply to the grid. However, since the early 1970's it has also provided incentives for the use of cereal straw for heat and the digestion of animal manure to produce biogas. The anaerobic digestion of animal manure for the production of biogas has many potential advantages. These range from the safe disposal of manure (presently a costly procedure for farmers due to stringent environmental regulations regarding its disposal) and to the production of electricity and heat. However, during the 1970's all the digesters were of a technically simple design and based on single farms. This led to problems of maintaining stable conditions in the digester due to their relatively small capacity and low cost. Forty of such small scale digesters have been built but about 30 of them have since been abandoned. Nevertheless, animal manure still represents a significant problem and large potential energy resource. The first large-scale biogas plant, Vester Hjermitslev, was constructed by the beginning of 1984 and nine more have since been built. It has a digester capacity of 1,500 m 3 (approx. 50 t manure per day) designed to produce 3,500 m3/day biogas; it also included a wind turbine for electricity production. The plant was commissioned and run by a private company consisting entirely of members of the local village, who put up over 2/3 of the construction cost (DKK 12.4 M; 1992 US$ 2 million). The Danish government provided DKK 4 M. It was built as part of the North Jutland County Council's "village energy project," designed to bring a measure of energy self-sufficiency to its villages by providing electricity and heat. The plant encountered a series of technical problems which never allowed it to meet its specifications, eventually resulting in its reconstruction in 1989. The costs of the years of development have resulted in the plant's debts becoming unserviceable, but the county council has arranged a moratorium. During the reconstruction extra pre-storage was added to enable the plant to use fish processing sludge. Since reconstruction the plant has increased its gas production substantially and an extra gas-powered generator has been added. There are now nine more large-scale biogas plants running in Denmark with the latest plants have capitalising on the lessons from the previous plants. "Lemvig," the most recent plant to become 79 operational (May 1992) was constructed in only 8 months. It was commissioned by a farmers cooperative who supply the manure; the plant manufacturers entered into a novel service agreement which makes them responsible for the operation and maintenance of the plant for five years. This contract also guarantees the co-operative a minimum budgeted profit. The total construction cost was DKK 40 M (1992 US$ 6.5 million) of which the government provided DKK 9.5 M ($ 1.5 million). There have been no serious problems in operation since its start-up. Lemvig is the largest plant built to date (7,600 m3) and is based on the continuous one-step design from a previous plant. It is a thermophilic (55°C) plant, which uses a highly automated wood chip heating process to maintain the temperature of the digester. The biogas is supplied to CHP gas-engines in the nearby town via a 4.5 km low pressure pipeline, developed for land-fill gas systems. In 1986, the Danish government recognised the potential for centralised biogas production and set up an Action Programme whose task it was to review the potential feasibility of the biogas programme. In June 1991, the Action Programme stated that "it would be possible to establish profitable centralised biogas plants without subsidies from the public purse." It did, however, qualify this remark by stating that economic feasibility would continue to depend on the present governments policy of not taxing biogas, which represents an indirect subsidy. In 1991, only one plant realised enough income to break-even, whilst five have budgeted sufficient income to break even in 1992. (table 17) In the Action Programme's report the conditions necessary for profitability are stated as: 1) 10 to 25% of easily convertible organic material is added to the manure delivered (the main source is from source-sorted household waste and sewage sludge), 2) there must be a steady/reliable market, and the biogas must not be taxed, and 3) good management is necessary to keep down running costs and maintain high gas production levels. The Danish government has continued its commitment to the biogas programme through the commissioning of the "follow-up programme," under which six or seven new large-scale plants will be established. It bases its renewed commitment to several factors: a) The potential improvements in economic status through continued development, many of which are already being demonstrated. b) Presently only 2% (0.5 PJ) of the potential biogas production is being utilised (25-30 PJ). c) The need for farmers to dispose of their waste products in an environmentally acceptable way. d) Possible environmental benefits include: displaced CO2 production from fossil fuel use, thus decreased net CO2 emissions, and decreased methane emissions as this is now burnt in the collected biogas. Also, correctly timed applications of the digested sludge on farmers land, which take advantage of the increased availability of nitrogen in digested manure and increased nutrients from the household waste, results in reduced need for artificial fertilisers. A saving of both economic and energy inputs. e) The potential to distribute biogas through the existing natural gas pipeline network, possibly as a mixture (natural gas and biogas), resulting in considerable savings in transport costs, and siting problems with the digesters. f) Helps to dispose of household waste. g) Stimulus to the rural economy. Electricity. United States of America In 1987, the Public Utility Regulatory Policy Act (PURPA) was introduced requiring US Electricity Utilities to purchase electricity from other suppliers at the cost they "avoided." The "avoided cost" sets the price the utilities are obliged to buy electricity from independent suppliers. It is calculated as the marginal cost of electricity production from a new conventional power station, i.e. equivalent to the cost (c/kWh) of producing electricity from new coal, gas or oil power stations. PURPA thus forced these utilities to procure electricity from suppliers who have alternative cheaper fuel supplies. The utilities were obliged to buy this electricity regardless of internal economic considerations i.e. even if the most economic way of providing base-load and peak demand was through the use of electricity supplies from other sources, including their own power stations. {Turnbull, 1993} PURPA resulted in an explosion of co-generators who use waste materials and by-products as a cheap source of heat. These by-products are obtained from associated processing plants e.g. saw mills, abattoirs, food processors and paper manufacturers, which then gain an income from a product which they may previously have had to pay to have removed. The 80 scale of electricity production is generally small scale i.e. < 50 MW. The guaranteed price at which the cogenerators can sell electricity has made long term economic planning possible, thus making it easier to procure loans and calculate profits. This Act is largely responsible for the present extent of electricity production from renewable sources; over 9 GW of installed capacity presently exists. In California, it has stimulated the growth of a market in biomass residues providing employment and clean energy. It is now being recognised that the use of these residues can help to reduce the level of US CO2 emissions. Concern over the present levels of US CO2 emissions have resulted in a number of studies being published detailing possible mitigation strategies. {Trexler, 1991; CAST, 1992; Ranney, 1992a; Wright et al., 1992} These studies have highlighted the potential for renewables in providing low cost (or even negative cost) options for the reduction in net CO2 emissions. One study from the US Environmental Protection Agency suggests that the "US will probably come close to stabilising its CO 2 emissions at 1990 levels by the year 2000." This, it is hoped, will mainly occur through increases in energy efficiency, the promotion of which utilities now find more cost effective than the construction of new plants. {Global Climate Change Digest, 1992} The prospects for increasing the production of energy from dedicated renewable sources, in combination with increased efficiency of production and use, seem auspicious both in the USA and elsewhere (see below). In the US, Hall et al {1990} estimated that advanced wood gasifier-based electricity production could be economically competitive with advanced coal gasifier-powered electricity plants. Much of the wood could theoretically be supplied from Short Rotation Woody Coppice (SRWC) on the 139 Mha of economically marginal and environmentally sensitive crop, pasture and under-stocked forest lands held by private owners other than the forest industry. Furthermore, this would have the effect of offsetting up to 56% of present US CO2 emissions at negative cost. When compared with estimates for carbon sequestration, costing between US$ 20 and 40/tC by US forest plantations, or flue-gas CO2 removal from coal-fired steam electricity plants (estimated for the Netherlands) of about US$ 120/tC, biomass substitution options look highly competitive. It should be noted that biomass feedstock costs are strongly correlated with growth rates (estimated by Moulton and Richards {1990} in the US to be 2.7 tC/ha/yr. above ground productivity or 5.3 tC/ha/yr. if roots and soil carbon production is included); if the productivity is halved then biomass feedstock costs are roughly doubled. Brazil Historically, Brazil has relied on the development of large-scale hydro-electric projects to supply its increasing demand for energy. Electricity demand has grown at about 5% per year throughout the 1980's. In 1990, hydro electricity supplied about 96% of total electricity use (226,377 GWh). It thus satisfied the stated governmental aim of avoiding excessive reliance on imported fossil fuels. However, the most favourable sites have now been used. Further expansion of the hydro capacity seems limited due to increasing social and environmental costs and also physical and economic factors. For example, installation costs have ranged between 1988 US$ 100 and 2,700 per kWh and electricity production costs 1988 0.3 to 3.3 USc/kWh. Future costs are likely to be higher, ranging from US$ 1,000 to 3,200 per kW for installation, and from 1.8 to 7.8 c/kWh for production costs. {Carpentieri et al., 1992} There are also problems with the sheer size of the capital costs of such large scale dams. For example, the Itaipu dam was budgeted at $3.5 billion in 1975, but at final completion it is expected to cost US$ 21 billion, excluding interest payments. {Lenssen, 1992} Such problems have played a significant role in Brazil's continuing struggle with size of its foreign debt and the associated problems. When compared to the likely costs of future hydro-electric schemes, the relatively low production costs and the smaller incremental nature of the installation costs, future biomass energy projects seem highly competitive and desirable, (see below) Wood-based electricity. Under the conditions in Northeast Brazil, total life-cycle costs for fuelwood plantations are estimated to rise particularly sharply at productivities of less than 8 odt ha -1 yr.-1 (17 m3/ha). The average weighted cost (weighted by BCR distribution)10 is US$ 1.36 ±0.20 GJ-1 and falls to US$ 1.09 ±0.12 GJ-1 for the highest productivity zone, BCR I. The cost rises to $3.71 ± 0.89 GJ-1 for the worst zone, BCR V (fig. 5)11. At these costs, plantation-derived electricity could be extremely competitive with oil at present world traded prices12. In assessing the potential land areas available for forestry, Carpentieri has analyzed the Northeast region in detail, breaking it down into Bioclimatic regions (BCR's), using soil and rainfall, annual average 81 temperature, water deficit and altitude parameters. Being sensitive to possible land-use conflicts, only land which is not at present being utilised for settlements and which is unsuitable for agriculture has been targeted. This land has been divided into five Bioclimatic regions (analogous to the FAO's Agroecological zones), each of which is estimated to be capable of supporting average productivities of 44, 33, 28, 15 and 6 m3 ha-1 yr-1 for BCR's I through to V, respectively. The parameter most closely correlating to productivity was rainfall, and this was used as the dominant BCR allocation criterion. The weighted average productivity for the NE was 26.6 m 3/ha/yr. All costs are calculated using a 10% discount rate, wood transported 85 km at 0.39 c/GJ/km and a plantation life time of 30 years. Most of the cost variation is due to differences in potential land costs. The price of crude oil is presently (Nov. 1992) about US$ 3.5/GJ @ $20/barrel and 42 GJ/t (LHV). The costs which are related to a given amount of energy generated can be shown graphically in the form of "supply curves." Such supply curves show the quantity of wood which can be produced up to a given cost and are valuable in providing data for a realistic economic comparison with alternative fuel sources (fig. 5b). For example, the Carpentieri et al. {1992} analysis predicts that over 86% of the potential wood production would be produced at an average cost of less than $1.35 per GJ, less than half the cost of oil. The total potential energy production of this scheme, if all the available land were to be planted and expected productivities achieved, is 12.6 EJ yr.-1. Thus, there is considerable potential to meet future energy demand when compared to Brazil's total 1990 energy consumption of about 8.1 EJ {AEB91, 1992). Clearly a very large potential for such a biomass-based industry exists. Even if only a small portion of the total were to be realised, large amounts of energy could be produced. One of the main advantages of modern conversion facilities are the relatively small scales at which electricity production would be possible. The biomass can therefore be converted to electricity obviating the need for excessive biomass transport costs. 30 MW is envisaged as the largest practical size of a power generating unit which can be economically supplied by plantations (due to restrictive transport costs at greater distances). Approximately 12,000 ha of plantation would be required for each 30 MW unit. For economic reasons, these units will only be commissioned as demand requires, minimising capital costs (cf. large-scale hydroelectric plants.) Importantly, this modular approach also provides the chance to rectify technical problems before large capital investments have been made. Plantation biomass-toelectricity programmes would therefore allow energy planners to follow the electricity demand curve more closely, thus reducing costs resulting from periodic over supply- periods of oversupply are inevitable after the commissioning of each large-scale hydro plant. Another benefit resulting from the requirement for large numbers of generating units is an increase in supply reliability. Increased reliability is due to the relative size differential between the production capacity of one plant and total production; thus the lack of one or two plants due to failure, will have relatively little effect on total production. Sugarcane Electricity. The global energy content of potentially harvestable sugarcane residues is calculated to be 7.7 EJ {Williams & Larson, 1992}. Production of cash crops can be highly intensive in many developing countries, resulting in the production of significant amounts of residues. The energy content of these-residues can equal or even exceed commercial energy consumption e.g. Mauritius, Belize. Residues therefore represent a large potential energy resource, (table 9) The energy potential of sugarcane residues was also considered by Carpentieri et al. (1993) for the Northeast region of Brazil since the sugarcane residue resource is already available and essentially free. There are, however, sometimes opportunity costs associated with the bagasse resource since a part of it may already used as animal feed, paper making and fertiliser. Where conflict of use may exist, the relative benefits of the different types of use must be assessed. In comparison with the potential for tree plantation biomass the size of the bagasse resource is relatively small. However, when compared to the present energy consumption of the Northeast Brazil (1.1 EJ), the bagasse resource could still provide an estimated 174 PJ yr.-1 (16% of present energy consumption). The main importance of the sugarcane residues is their availability for collection and electricity production. Energy production from bagasse is well characterised since the quantity, energy content and moisture content of bagasse produced per tonne of crushed cane varies little from site to site {Alexander, 1985}. Thus gains in the amount of useful energy produced from bagasse is likely to come from increases in conversion efficiency and biomass productivity. More recently, more attention has been given to the energy potential of the tops and leaves, the so called "barbojo." The efficient of use of this barbojo may 82 be able to significantly increase energy production from cane. {Hall et al., 1992; Carpentieri et al., 1992; Williams and Larson, 1992; Howe and Sreesangkom, 1990; Tugwell et al., 1988.} Economic analysis shows that the conversion of sugarcane residues into electricity can be very competitive with alternative fuel sources. When factors such as transport, storage, drying and processing are accounted for residue-based electricity remains competitive, (table 11) The cost of using stored tops and leaves as an energy feedstock varies from 0.95-2.21 $/GJ, whilst bagasse is in the range 0.28-1.68 $/GJ. The variation between the costs for bagasse and barbojo arises because the barbojo is assumed to be collected and transported to the mills off-season, whilst the bagasse is a by-product of the sugar production. The bagasse is thus effectively transported free when the fresh cane stems are brought to the mills during harvest, whilst the barbojo requires separate collection and transport costs. The potential competitiveness of this indigenous source of fuel can be seen when compared to the fossil-fuel alternatives, i.e. fuel oil, 1985 US$ 2.45-7.50 per GJ and coal, (imported and indigenous) US$ 1985 1.434.22 per GJ. A similar study for Jamaica concluded that potential (present value) savings of US$ 270 M could be achieved if sugarcane residue-fired BIG/STIG were to replace state-of-the-art coal-fired CEST technology. Furthermore, if existing oil-fired plants were replaced, savings of up to US$ 300 million per annum might be feasible. {Tugwell, 1988} India The perceived developmental advantages of widespread access to electricity have been translated from public demand into the political imperative that every village and farm in India should be connected to the national grid. To a large extent this has been achieved with over 80% of the 550,000 villages now grid connected. However, connection has required the construction of many thousands of km's of transmission lines at a cost of US$ 800 to 1,200 km-1 {Ravindranath, 1993}. Furthermore, during the 1980's, oil imports cost India US$ 36.8 billion, the equivalent to one third of all foreign exchange earnings, or 87% of its new debt. When the capital cost of the imported electricity generation equipment was included in this analysis, the total expense for energy amounted to more than 80% of foreign exchange earnings between 1980 and 1986. {Lenssen, 1992} In addition, many of the villages connected to the grid only require small amounts of power and can also be distant from the power station. This combination of low loads and long transmission distances has led to a number of problems: i) high transmission & distribution losses, with a national average of about 22.4%, ii) low and fluctuating voltages (often below 180 V (estimated 20% of time) despite a nominal voltage of 220 V), iii) high operation & maintenance costs, iv) erratic supply and poor maintenance (power cuts are common), and v) the external costs of centralised power production including: CO 2, SO2, particulate emissions, no provision of local employment or wealth generation. {Ravindranath, 1993} The production of electricity in India is a significant contributor to Indian greenhouse gas emissions. Coal combustion accounts for 60% of total CO2 emissions, with 70% of electricity production being coalderived. Presently, the provision of electricity to villages consumes one quarter of total production. Electricity generation is responsible for a significant fraction of total Indian CO2 emissions even at today's low levels of per capita electricity consumption (i.e. 61 kWh/yr.). {Ravindranath, 1993} There are therefore several imperatives for the adoption of widespread decentralised systems for power generation. In addition to overcoming the above problems, such schemes should reduce the subsidies burden presently shouldered by the national government. {Reddy and Goldemberg, 1990} However, electricity production is expected to grow at 10% per year into the next decade. In fact, the constraint on growth is on the supply-side, with actual demand estimated to be much higher. {Grubb, 1990} The adoption of decentralised power generation systems which use indigenous energy sources has been proposed as an environmentally, economically and socially beneficial model for the development of India's rural villages.{Ravindranath, 1993} Furthermore, all the lighting and power needs of India's rural villages could be met on only 16 Mha of land; a small area when compared to the estimated 100 Mha of degraded land potentially available for tree planting. Ravindranath (1993), has further estimated "that biomass conservation programmes such as biogas and improved cook stoves could provide more than 95 Mt of woody biomass. If gasified, this biomass could provide energy in excess of the total rural energy requirements." Thus, theoretically, no extra land would be needed. The whole-hearted adoption of such small-scale systems (5 to 20 kW) by the villagers themselves will only be achieved if such systems can address their multiple needs at lower overall costs and more 83 conveniently than present traditional methods. Such needs include the provision of water (primarily for drinking and then for irrigation), light (domestic and street) and shaft power for milling, with cooking considered a low priority. According to Rajabapaiah et al. (1992) small scale decentralised systems in India could theoretically be both more cost effective than present centralised power production and less environmentally damaging. In fact, such systems could be beneficial to the environment in terms of decreases in the emissions of pollutants (including greenhouse gases) and in the rehabilitation of degraded lands if they were planted with energy forests. The demonstration of three such schemes by the Centre for the Application of Science to Rural Areas (ASTRA), of the Indian Institute of Science in Bangalore, has shown the feasibility of such an approach. The projects are based in three villages in Karnataka state South India, namely, Pura, Ungra and Hosahalli villages. The Pura village (population of 209) scheme was initially conceived as a biogas-for-cooking project requiring the collection and use of most of the villages cattle dung production. {Rajabapaiah et al., 1992} Surplus gas would then be utilised for electricity production, mainly for lighting. However, problems with inadequate incentives for dung collection resulted is less gas production than planned. Initially insufficient gas was produced to cook all the villagers' meals and thus the villagers became disinterested in the project. Thereafter, the implementation of community-based management with a transparent decision making process altered the project's priorities. The provision of cooking gas was demoted in favour of the supply of clean water and, at the same time, fair returns for dung provision were allocated. The Pura village project now recuperates its operation and maintenance costs and is fully accepted and welcomed by the village as a whole. This Pura village project demonstrates that local initiatives can be successful if they are adaptable and can take a longer term view over the provision of social and economic benefits. Hosahalli, a nearby village, has demonstrated the feasibility of electricity production from the gasification of fuelwood for lighting, water-pumping, milling and for irrigation (future). Hosahalli is analyzed in more detail below. Hosahalli: This is a small, non-electrified village of 42 households and a population of just over 200. As with Pura village, detailed discussions were undertaken between ASTRA and the villagers before the initiation of the scheme. The main aim of the project was to demonstrate the feasibility of small-scale energy plantations for the provision of sufficient wood to sustainably supply a 5 kW wood-gasifier. This wood-gas is then used in a diesel-engine as a substitute for diesel. The engine is connected to a 5 kWe alternator which generates 3-phase (nominally 220 V) electricity to supply specified village energy services. The project funded the hardware, and initially aimed for the operation and maintenance of the system to be "self funding. This is presently the case, and there are good prospects that developmental work, both hardware and social, will lead to full economic profitability and a reasonable payback period. The project is being implemented in 5 phases: I) Growing 2 ha energy forest to provide a sustainable wood supply. The installation of the wood gasifier/diesel engine and generating system. II) Electrification: the provision of lighting to all households (1x40 W fluorescent and 1x25 W incandescent bulbs) + 9 street lights. III) Installation of a water pump and tanks for drinking water. IV) Installation of a flour mill. (5 kW electrical). V) Provision of water pumping for irrigation. (10 pumps x 3.7 kWe/pump x 300 hr/yr./pump for flood irrigation). The engine is modified to run on both diesel and wood-gas, however, starting requires the use of the diesel-only mode until the gasifier reaches operating temperature. Once the gasifier is operating the wood-gas produced completely displaces the need for diesel. An overall diesel displacement of 67% has been achieved when compared to the diesel saved if the engine were running on diesel alone. Presently a saving of 42 litres of diesel a month is being achieved. A diesel substitution level of over 85% is possible if the gasifier is run for longer periods which would have significant economic benefits. Electricity for lighting has been supplied for 3 to 4 hours daily since September 1988, drinking water since September 1990 and the flour mill (2 hours daily) has been in operation since March 1992. This has been achieved with a reliability in the supply of power of 95%- a remarkable level of reliability when the 84 consistently high voltage level provided is taken into account, in contrast to the erratic supply and fluctuating voltage of the central electricity grid. In addition to the provision of these services, two men have been employed full-time to cut and supply wood from the energy forest and to maintain the gasifier and engine; more recently a woman has volunteered to be trained in running the equipment. A proper comparative economic analysis is made difficult because of the high level of subsidies given to centralised grid electricity. However, according to Ravindranath and Mukunda (1990), at the level of operation for lighting only (4 hr/day) the wood gasification system would only be economic, in terms of covering its running costs, if electricity is priced at Rs. 3.5 per kWh (14 USc/kWh). However, if the gasification system operates beyond 5 hr/day, the unit cost of energy becomes cheaper than the dieselonly system. For comparison, the current subsidised price of grid-based electricity is Rs. 0.65 (equivalent to about 3 USc/kWh). {Ravindranath, 1993} An important aspect of this project is that the villagers are prepared to pay over twice as much for their electricity (approx. Rs. 1.3/kWh (5 USc)) because: i) the supply is reliable, ii) provision of ancillary benefits (clean drinking water, flour mill, etc.), iii) quality of supply (never below 180 V) and iv) emergence of self reliance (the formation of village management committee). This emergence of self reliance for the decentralised and small-scale, provision of energy also plays an important role in the other two projects being implemented by ASTRA in Pura and Ungra. At the present rate of diesel-substitution (42 I/month), the monetary savings are equivalent to Rs. 2,520/yr. (US$ 101/yr.). This is the equivalent to a payback period of 9.5 years including the additional cost of the energy forest, gasification equipment and modification of the diesel engine, (table 15) However, the other benefits listed above, or the revenue from lighting, paid by each household (Rs. 10/household/month) is not accounted for and would reduce the payback period. A general increase in energy demand in combination with a demand for more powerful lights is resulting in the gasifier being run for longer periods of time and therefore should result in decreasing running costs per kWh. One concern voiced by the villagers was the amount of land which had to be devoted to the growth of wood for the gasifier. The eventual planting of 2 ha with 6 different species has resulted in an average annual yield of 6.9 dry t/ha/yr. compared with a total use of only 10.2 t over the 32 month period (3.8 t/ha/yr.). The productivity of this land is therefore considered more than sufficient to meet present and future demand. The excess wood can be used by the villagers or sold. Estimates for India as a whole, show that the use of degraded land (or edges of fields) around many villages would not only provide more than sufficient area to supply present demand, but would also help to rehabilitate such land. In addition, the potential of this land to becoming a C-sink could be significant, whilst at the same time helping rural development. {Ravindranath, 1992} (see also Land Use section) If such decentralised systems are to become widespread then the lessons learnt from these studies must be built into future policies aimed at their promotion. ASTRA emphasises that it is crucial to listen to and address the recommendations made by the users, and secondly, the continuing involvement of the community in the organisation and running of the plant is essential. Similarly, in Hosahalli, community involvement was only secured when phase II was implemented and clean drinking water made available. Thus, both Pura and Hosahalli required a long-term commitment and flexible approach by ASTRA, which have given them the confidence to recommend that decentralised power production systems, based on the experiences from Pura and Hosahalli, be broadened to encompass a "cluster" of villages (of about 100 in total). This would allow the system to be realistically compared with grid electricity. The interconnection of the villages would allow increased reliability and profitability making decentralised power generation more desirable. Mauritius Mauritius is a small island (1,865 km2) off the East coast of Africa with a population of just over 1 million. About a quarter of the workforce is currently employed in the agricultural sector. Its primary export crop is sugar, and with the decreasing export value of sugar (and raw commodities in general) the government has been seeking ways to increase the overall value of its sugarcane crop. There is an emerging view of sugarcane as a multi-product crop, able to produce both food (sugar and animal feed) and energy (ethanol, biogas and electricity). Thus sugarcane is increasingly seen as an opportunity for development and not a hinderance. Cane production in 1990 totalled over 5.5 Mt (fresh stems) but only one third (29%) of the potential excess energy from bagasse is presently being utilised. {Comarmond, 1992} However, whilst gross 85 electricity production from bagasse increased from 27 GWh in 1980 to 71 GWh in 1991, total electricity production doubled from 355 GWh to 737 GWh in the same time period. Consequently, bagasse's share of electricity rose only slightly from 7.5% to 9.6%. Prior to 1982, 16 of the 19 cane mills sold electricity during the milling season to the Central Electricity Board (CEB). All these mills used inefficient low pressure and temperature back pressure technology. {Comarmond, 1992}. In 1984, 14 of the sugar mills and 1 tea factory supplied 34 GWh of electricity to the grid. {Purmanund et al., 1992} The main purpose of the technology used is to deliver process steam to power the mill and secondly, as a means of bagasse disposal. Even so, a total of 31 GWh of bagasse generated electricity was purchased by the CEB during 1981. This inefficient technology is only capable of producing 300 kg of steam per tonne of cane (kg/tc), and thus the opportunities presented by newer technology (able to produce 550 to 600 kg/tc) were evident. The newer technologies do however, involved higher capital costs. In 1982, the Medine mill started operating a new 10 MW CEST system to exploit these potential benefits, and during the crushing season exported an additional 10 GW (2,770 kWh) to the CEB. In 1985, the largest sugar factory in Mauritius, the Flacq United Estate Limited (FUEL) commissioned a modern steam boiler capable of burning both bagasse and coal, sufficient to deliver high temperature and pressure steam to power both the factory and a 24 MW CEST alternator. The dual-fuel ability of the FUEL boiler enables it to burn bagasse during the harvesting season and coal during the off-season. Total electricity production is approximately half (40 GWh) from bagasse and half (40 to 45 GWh) from coal. All year round electricity production is obviously a more valuable commodity for the CEB than seasonal production. It results in the CEB needing less standby generating equipment to meet demand when seasonal production is not available. The CEB thus pays a premium for such electricity production; 100 c/KWh for permanent electricity production, 45 c/kWh for seasonal, and only 16 c/kWh for intermittent (wind, PV, tidal etc,). The tariffs paid by the CEB, are derived from the "avoided costs" that would be incurred if the demand were to be provided from CEB's own electricity generating plant i.e. specifically the cost of electricity production from a 24 MW diesel powered generating plant. {GEF, 1992} In fact, current forecasts for growth in electricity demand have resulted in the commissioning of 106 MW of new fossil fuel generating capacity; in addition, two future 24 MW bagasse/coal plants have been ordered. Funding for the two bagasse plants and the enhanced use of the sugar industries by-products is envisaged to cost about US$ 80 million over an eight year period. The funding will be allocated under the Bagasse Energy Development Programme (BEDP) which is a central part of the Mauritian Governments Sugar Energy Development Project (SEDP). Under the SEDP's US$ 55 million financing plan 48% of the funding (US$ 26.6 million) is from foreign sources, of which only US$ 3.3 million is provided by the Global Environment Facility (GEF). {GEF, 1992} The GEF funding is specifically for technical and staff development (US$ 1.9 million) BEDP co-ordination and for environmental monitoring (US$ 1.4 million). In justifying this funding GEF states that "increased use of sugarcane biomass as energy in Mauritius will have significant environmental benefits." To this end it estimates that CO2 emissions will be reduced, in terms of avoided fossil fuel emissions, from 75,000 t/yr. to between 60,000 and 67,000 t/yr., and at the same time NOx and SOx emissions will be reduced from 4,000 t/yr. to 1,000 t/yr. The primary aim of the BEDP is to increase cane residue-derived electricity production from the present level of 70 GWh to about 120 GWh. This will exploit about 56% of the total potential from bagasse, but due to increased electricity demand bagasse is only expected to provide about 9% of total electricity production by the year 2000. {Comarmond, 1992} However, if the full potential of sugarcane residues (bagasse and tops + leaves, and other crop residues) were to be exploited for electricity production, estimates of the potential resource for electricity production are much larger. A crude estimate of the theoretical total potential would be about 3,500 GWh (at 40% conversion efficiency, biomass to electricity) or 2,500 GWh at 30% efficiency. When compared with the CEB forecast of total electricity consumption of 1,678 GWh/yr. {Comarmond, 1992} in the year 2000, bagasse and barbojo represent a significant energy resource. Another independent estimate of the total theoretical energy potential from crop, forest and dung residues, based on 1984 data, is of 4,007.3 GWh (14.4 PJ).13{Purmanund et al., 1992} The energy value of cane tops & leaves (roughly equivalent to bagasse in weight) was not included in this study as it is presently either used as animal feed or left on the field to act as a mulch. However, the study did include 86 the potential alcohol production from molasses (8% of the total energy derived from cane). If half the tops and leaves from the sugarcane were to be used, the total potential energy from residues would rise to about 5,833 GWh.14 Using the efficiencies assumed (see footnote 13) for conversion to electricity residue-based energy could produce approximately 1,400 GWh of electricity or virtually the total Mauritian electricity production forecast for the year 2000. {Comarmond, 1992} 13 If the Purmanund et al. {1992} estimate for conversion efficiencies is used, which assumes a boiler efficiency of 70% and a thermal conversion efficiency (heat to electricity) of 35%, then an electricity production potential of 982 GWh is estimated. 14 It is estimated that in Puerto Rico 30 to 50% of the tops and leaves should be left on the field. {GEF, 1992} Estimates of potential energy production from sugarcane residues, such as those cited above, do not attempt to estimate the likely effects of optimised strategies for both energy and food production. It is estimated that large potential gains in both sugar and fibre production could be achieved from sugar cane if breeding programmes concentrated on total biomass production and not simply increasing the sugar concentration in the stem. {Alexander, 1985} If likely increases in the efficiencies of conversion of biomass to useful energy (i.e. electricity) are accounted for i.e. the use of biomass gasification and gas turbine technologies (BIG/STIG) much larger potentials are estimated. For example, Williams and Larson (1992) estimate that by 2027, the electricity potential from cane in Mauritius could be 29 times (14,300 GWh) Mauritius's total 1987 electricity production (490 GWh). This figure is based on the assumption that cane production grows at 3.1% per year and that BIG/ISTIG technology is used with a conversion efficiency (biomass to electricity) of 38%.15 {Williams & Larson, 1992} It is interesting to note that the installed cost in 1989 US$/kWe for BIG/ISTIG is estimated to be between $ 870 and $ 1,380 which is lower than the present installed cost of CEST at US$ 1,520 per kW. Biomass Integrated Gasifier/Intercooled Steam Injected Gas Turbine (BIG/ISTIG) technology is a derivative of BIG/STIG technology (section 4, Energy Conversion) and is used for the co-generation of process steam and electricity. BIG/ISTIG conversion efficiencies (biomass to electricity) are estimated at about 8% higher than BIG/STIG (30% efficient); however, commercialisation is expected to take longer. Employment potential. If rural communities are to prosper as a country develops then secure and financially beneficial rural employment must be a central theme. The history of agricultural development is often characterised by the reduction in man hours per tonne of produce harvested. The fall in manpower required in agriculture has accentuated, or is a direct cause of urban drift so exacerbating urban unemployment and related problems. One trait of agriculture is the seasonably of the employment. In developing countries where the bulk of the harvest is often carried out manually this requirement for large numbers of temporary jobs during the harvesting season is regarded as socially damaging. Whilst the quality of the work may be poor it does at least provide some form of income where there might not otherwise be any. It should therefore not be the aim of any investment programme to destroy this important opportunity for income. Rather the aim should be to secure those jobs throughout the year in the most economically efficient way, possibly by providing alternative employment during the off-season. The Carpentieri et al. (1992) study of biomass electricity in NE Brazil provided a detailed analysis of the manpower requirements for both the tree plantation and sugarcane biomass energy sectors. The sugarcane industry of the Northeast presently employs labour at the rate of 19.8 jobs per km 2 for onseason work and only 2.7 jobs per km for off-season (permanent) employment. If in the future labour was to be employed to bale and collect the tops & leaves which would be done off-season (an essential activity if enough energy is to be produced from sugarcane residues), then the on-season requirement for jobs would hardly change at 19.6 jobs km-2 but the off-season requirement would rise to 23.7 jobs km-2 At present only about 36,000 people are employed permanently by the sugarcane industry of the Northeast; however, if the industry became a combined sugar and energy production system the theoretical total number of permanent jobs is estimated to be more than 326,000. The seasonal requirement (harvesting period only) would fall from 272,600 to 55,800 people, with all the present seasonal jobs being absorbed into the extra permanent vacancies. The tree plantation industry is much less labour intensive with an average requirement of 2.7 jobs km 2. Approximately 12% of these jobs are needed for research and administration. In analysing the potential 87 plantation requirements to supply the additional electricity demand for the period 2000-2015, 32,454 jobs would be needed. This represents 9 % of the ultimate potential total if all the area identified as "free for forestry" in the Northeast were eventually to be planted for electricity production. In the agro-ethanol industry, job quality is also comparable or higher to many of the main large-scale employers in Brazil. It is estimated that the ethanol industry in Brazil has generated 700,000 jobs with a relatively low seasonal component compared to other agricultural employment. Job security and wages are important for workers in this industry; they receive higher wages on average than 80% of the agricultural sector, 50% of the service sector and 40% of those in industry. {Goldemberg et al., 1992} One of the most important developmental comparisons is the investment cost per job created. For the biomass energy industries envisaged above, this lies between $15,000 and $100,000 per job, with costs in the ethanol agro-industry between $12,000 and $22,000. Such job creation costs compare with the average employment costs in industrial projects in the Northeast at $40,000 per job created, in the petrochemical industry of about $800,000 per job, and for hydro power over $106 per job. Lower job creation costs are one of the most significant benefits of biomass energy. {Carpentieri et al., 1992; Goldemberg et al., 1992}. CHAPTER NO.04 BIOENERGY PROGREMS 4.1 ASSESSMENT OF BIO-ENERGY PROGRAMS IN PAKISTAN. 88 Energy in useful form is welcomed by the society if the generation process is eco-friendly, renewable and economical. It is well known that Biomass has been used in all the countries in general and tropical countries in particular mainly to generate thermal power either for home use or to run industrial boilers. Biomass is the residues generated out of plants, agricultural crops and trees and hence they are renewable. The recent advancement in science achieved especially at CGPL, IISc has shown that by adopting principles of Combustion, Gasification and Pollution control it is possible to generate ‘Clean’ power which is either in electrical or thermal form. With this technical strength it is found relevant that CGPL produce a country wide Biomass Atlas to enable assessment of biomass availability to forecast the power generation potential. Under this context, MNRE [Ministry of New and Renewable Energy] decided to bring out a Nation wide Biomass Atlas based on the guidelines given by CGPL. Biomass Data Collection and Methodology The Diagram shows the methodology used to integrate the data into Atlas. This software package is developed at CGPL, IISc, as the National Focal Point (NFP) that provides information on Biomass Residues form Agro-Crops, as related to Energy generation both in Spatial and Statistical form. The residue generation based on agricultural output is used to compute the surplus Biomass available for Energy production after accounting for the societal uses such as Fodder, Domestic Fuel, and Thatching. While all the use for fodder and thatching is considered unavailable for energy generation, use for domestic fuel is decided based on the district level surveys conducted with MNRE support. The data on agricultural outputs are obtained from the published data by Ministry of Agriculture where as the data on residues are obtained from Taluk and District surveys. The Taluk Study was initiated by MNREand conducted during 1999-2001 for strategically selected taluks (of about 500) across the country. Later, the District Survey instituted by MNRE was done during 2002-04 for 15 districts country wide. NFP has integrated these crop related data into a data base to be used for creating the spatial atlasIndian Bio-Residue Map (IBRM). The spatial maps providing the Land use were obtained from RRSSC (ISRO) through their satellite imagery at a ground resolution of 184x184 m. This was then set into GIS (Geographical Information System) by NFP (CGPL, IISc, Bangalore) to use the statistical crop data for spatial distribution at district level. AI based on Fuzzy Logic is adopted for distributing the polygons (with the appropriate crop names) by combining the information on the areas from the land-use with the statistical data on the crop area. The Maps were re-processed to also embed the District and taluk level spatial data extracted from the same crop distributed map. 89 Why Geographical Information System? The biomass is geographically distributed [spatial] and has to be transported to power generation centers economically. It is not enough that a simple data base is provided with conventional queries to assess the biomass. The biomass assessment has to be done geographically based on the location of ‘Use centers’. Additionally, Biomasses are of different types and exhibit different power generation characteristics. These features prompt the use of Geographical Information System [GIS] to asses the biomass along with conventional information data bases. This is done in two ways to make it available to the users. One is a stand alone digital atlas queriable on the user’s PC and the other is web enabled atlas. Indian Bio-Residue Map (IBRM) as a stand alone package. This is redistributable software which can be installed on the client PC which will contain a one time specific spatial biomass data. The different types of Biomass can be assessed in the circle of interest to forecast the power generation potential for either budgetary purposes or as an input to a DPR [Detailed Project Report] to set up an energy generation center. The only problem one may face is to update the Atlas if the year of assessment required is far away from that of the year of formation of the Atlas. Web enabled Indian Bio-Residue Map (IBRM) Unlike the stand alone package this is directly available to any remote client dynamically on his desk top PC [Personal Computer]. The updates on the biomass information will be seamlessly available to the users as the data sits on a central information server. The rest of the features are common with a difference that the circle of interest will be introduced in the next phase. The web Atlas is cautiously designed keeping in view the internet response to every query of the client. The atlas can be accessed through normal internet browsers. Excerpts of Atlas outputs Sample clippings on a stand alone PC 90 Karnataka Demography Layer Karnataka Kharif Crop Layer 91 Karnataka Kharif Crop Layer of Dharwad District Karnataka Rabi Crop Layer 92 Karnataka Rabi Crop Layer of Raichur District Search option to find Districts 4.2 POWER GENERATION FROM ENERGY PLANTATION 6. The potential use of wood residues for energy generation 6.1 Introduction 6.2 Sources of available wood residues 6.3 The fuel value of wood residues 6.4 The preparation of wood waste fuel 6.5 Applications for waste-based energy 93 6.6 Combustion 6.7 Cogeneration 6.1 Introduction Unlike most other industries, the forest industries are fortunate to be able to use their waste to help meet their energy needs. In mechanical wood processing the greater part of the thermal energy requirements can be met from the available residues, in fact, the sawmilling industry has the potential to produce both a surplus of heat and electricity and therefore could support other energy deficient conversion processes in an integrated complex producing, for example, lumber, plywood and particleboard or, in the rural areas, to supplying energy for the needs of the surrounding community. Over the years many mills have regarded wood waste as a troublesome by-product of the sawmilling operation, resulting in its being disposed of as landfill or incinerated in Wigwam burners or the like. However, both have recently become contentious environmental issues and, combined with the rising costs of energy, mill owners have been forced to seriously consider the merits of using the residues as an alternative fuel source this has also coincided with the increase in demand for the residues as furnish for paper-pulp and panel board manufacture, due to the rising cost and increased competition for solid wood. Nowadays most wood processing plants being built in developed countries incorporate hog fuel burners in order to safeguard against certain and costly fossil fuel supply. In instances where the amount of residues produced are insufficient to meet the plant's thermal needs, purchased hog fuel and/or fuel oil are used to make-up the balance. However, little use is made of the energy potential of sawmilling residues in developing countries, this being partly due to the minimal use of kiln drying and the investment capital involved in the installation of the heat generating plant. Although the heat produced from wood residues is less than that from oil or gas, its cost compared to fossil fuels makes it an attractive source of readily available heat or heat and power. In spite of the growing competition for the residues for other uses, its projected increase in price over the coming years will undoubtedly be less than that expected for traditional fuels. Although the handling, processing and combustion of the residues may involve a higher capital outlay, considerable developments in new and improved technology and plant design are now rendering it an economically attractive fuel source. The most effective utilization of wood residues, particularly in the sawmilling and plywood industry, plays an important role in energy efficient production and it can often prove to be an important factor in determining whether a sawmill is to operate at a profit or loss, especially if lumber is manufactured from marginal logs. However, when contemplating the use of wood residues as an energy source, whether it only be to provide heat for kiln drying or both heat and power for use in an integrated complex, the following items will need to be examined in detail as they can influence the economic viability of the venture: (a) present day and projected future costs of traditional energy sources and their availability; (b) energy requirements of the plant (heat and electricity); (c) availability and reliability of residue supplies, their cost, type, size, moisture content and proportion of contraries; 94 (d) the capital cost of equipment needed to collect, process and combust the wood residues; (e) disposal cost of residues; (f) resale value of the residues as a raw material for panel board or pulp manufacture, etc. It is only by undertaking a professional study of the above, as well as the most appropriate type and size of plant and the best use of the surplus heat and power, that an efficient waste handling, treatment and combustion system can be designed in which the return on investment would warrant capital expenditure. Obviously it would not be logical to invest in a plant in which the capital and operating costs exceed the gains from using the residues as fuel. Although residues may represent a free source of readily available fuel, it is a misconception to believe that it is a free source of energy. The cost of waste handling, treatment and combustion equipment, together with labour and maintenance can be a costly adjunct to a plant's operating costs and capital outlay, and may prove to be excessive for some small mills. Also, this particularly applies to on-site power generation, which, due to the high cost of steam raising and power generating plant, would not be considered an economically viable investment for most small- and medium-sized install 6.2 Sources of available wood residues 6.2.1 Forest residues 6.2.2 Mill-site generated wood waste 6.2.3 Integrated production 6.2.4 Alternative uses of residues The residues generated from the forest products industry may be divided into two parts; that which results from harvesting and extracting logs from the forest, and generally considered of no economic use for further processing, and that which is generated by the forest industries themselves during the process of manufacturing timber, plywood, particleboard and the like (refer to Figures 1, 2 and 3), namely: Source Forest operations Sawmilling Plywood production Particleboard production Type of residue Branches, needles, leaves, stumps, roots, low grade and decayed wood, slashings and sawdust; Bark, sawdust, trimmings, split wood, planer shavings, sanderdust; Bark, core, sawdust, lillypads, veneer clippings and waste, panel trim, sanderdust; Bark, screening fines, panel trim, sawdust, sanderdust. In general it may be said that of a typical tree, less than two-thirds is taken from the forest for further processing, the remainder being either left, burnt or collected as fuelwood by the local inhabitants. After processing, only 28 percent of the original tree becomes lumber, the remainder being residues, as indicated in Table 7. 95 Table 7. Division of a typical tree harvested for sawntimber Tree part or product Left in the forest: Top, branches and foliage Stump (excluding roots) Sawdust Sawmilling: Slabs, edgings and off-cuts Sawdust and fines Various losses Bark Sawn timber Total Portion (%) 23.0 10.0 5.0 17.0 7.5 4.0 5.5 28.0 100.0 Sources: (37) (144) It is only in the last few years that, due to the economics of rapidly rising fuel and wood costs, industry in the developed countries have invested in ways and means to extract the maximum quantity of recoverable wood during logging operations. Although this document draws attention mainly to the energy value of residues produced during the manufacturing operations, consideration should be given to the potential industrial use of residues left in the forest. 6.2.1 Forest residues It is not uncommon for some 60 percent of the total harvested tree to be left in the forest and for non-commercial species to be subjected to slash and burn, or merely felled and left to rot so as to make access easier for logging. Such practices as sawing and squaring logs in the forest, rather than at the sawmill, wastes a further eight to ten percent and 30 to 50 percent respectively (29). Proper training and provision of appropriate tools and logging equipment can do much to improve the methods of harvesting so as to substantially reduce the excessive wastes, which could otherwise represent a higher yield of solid wood or a source of fuel. However, although forest residues may appear to be an attractive fuel source, collection and handling costs must be taken into consideration, as well as its loss as a valuable soil nutrient. The viability of its use may be improved if collection be undertaken at the same time as log extraction, with shared equipment and management, whereby logging slash and marginal timber may be collected and chipped using portable or semi-portable chippers placed in the immediate logging areas. By ensuring that leaves, bark and thinnings are left behind, the soil's nutrients would not be depleted. Transport costs are also a critical factor in the use of forest residues, due to the low heat values of such bulky material, for which reason distances are to be kept low so as not to incur unnecessary expense if the waste is to remain economically attractive as a fuel source. Chipping of the residues does afford some degree of compaction, also several processes are in operation which further compress the waste into more manageable forms, such as pellets, thus improving their bulk handling characteristics. However, due to the high capital and operating costs involved, 96 densification tends to be only financially viable when the waste needs to be transported over long distances. Whilst regarding wood as a renewable energy resource, consideration should also be given at regional or national level to encourage the collection and use of logging residues, be they branches, tops or whole-tree utilisation, to the establishment of energy plantations using quick growing species especially selected for their value as a fuel. 6.2.2 Mill-site generated wood waste If one considers that approximately 45 to 55 percent of the log input to a sawmill or plywood plant is to become waste, it would be illogical not to maximize its use as a fuel source, if no other profitable market outlet can be found. The actual production of residues, or waste, generated from the manufacture of wood products, differs from plant to plant and depends on several factors, from the properties of the wood to the type, operation and maintenance of the processing plant. However, mean averages apply to each type of industry, which, for developing countries have been detailed in Tables 1, 2 and 3 of Appendix VI, and summarized in Table 8. Table 8. Proportion of residues generated in selected forest products indu stries 1/ Sawmilling 2/ Finished product (range) Finished product (average) Residues/Fuel Losses Total % 45-55 Plywood Manu. % 40-50 Particleboard Manu. % 85-90 Integrated Operations % 65-70 50 47 90 68 43 7 100 45 8 100 5 5 100 24 8 100 1/ Excluding bark 2/ Air-dried All wood waste and bark, which is also commonly referred to as hog fuel due to the process of reducing the residues in size in a "hogger", has a value as a fuel, although it is produced in a wide range of sizes with varying moisture contents, as shown in Table 10, and comprises mainly of the following: - Bark, which makes up some 10 to 22 percent of the total log volume depending on size and species, can in itself represent a serious waste disposal problem unless it can be used as a fuel or removed prior to log preparation; - Coarse residues, such as slabs, edgings, off-cuts, veneer clippings, sawmill and particleboard trim, when reduced in size, make ideal fuel, especially when dry. They also have a resale value as pulp and particleboard furnish; - Cores, from plywood peeler logs, are generally sold to sawmills or lumber or as pulp chips; 97 - Sawdust, being a product of all mechanical wood processing operations, particularly sawmilling, is generally not regarded as a prime pulping material due to its small size, although it proves to be acceptable for the manufacture of particleboard; - Planer shavings result from dimensioning and smoothing lumber, plywood and particleboard with planers during the finishing stage. They are considered ideal for particleboard production and are particularly good for heating kilns and dryers; - Sanderdust is produced during the abrasive sanding of lumber, plywood and particleboard during the finishing stage. Due to its size and very low moisture content it is well suited for direct firing; - Particleboard waste, being in the order of five percent, is negligible compared to that generated in other mechanical wood-based industries, as it is largely recycled within the production process. In fact the waste from sawmilling and plywood manufacture make up a large part of particleboard furnish. 6.2.3 Integrated production As previously indicated, the sawmilling and plywood industries each produce between 40 to 55 percent of waste from their incoming wood supply, with heat values in the range of 17 to 23 MJ/kg (dry weight), more than sufficient to meet their own energy requirements. Nonetheless, it is considered uneconomical to generate their own electricity from residues unless they have an additional sales outlet for the surplus power. However, particleboard production produces little waste, being in the order of five to ten percent, and insufficient to cover the needs for heat, yet, would be resolved in the case of an integrated operation of all three industries - market forces permitting (25). Sawmilling, veneer, plywood and particleboard production lend themselves quite readily to integration, with the advantages of shared waste handling processing facilities and services, and the maximum benefit derived from the use of the residues as a raw material and fuel, whereupon the surplus energy could be fully and economically used to the best advantage. But, the scale of such a complex may be beyond the means- of some developing countries. 6.2.4 Alternative uses of residues Residues derived from the forest industries normally do have alternative outlets, as chips for pulp manufacture, raw materials for particleboard and fibreboard manufacture and as fuelwood and building materials to local inhabitants - all dependent on market location and demand. Listed below are several outlet areas. Sawmilling - edgings and slabs - barked edging chips Plywood Manufacture Particleboard - peeler log cores - core chips - veneer chipping and chips - uses all the above mentioned residues as raw material for board manufacture, and the majority of - low cost building materials, fuelwood and pulp manufacture - pulp manufacture and fuelwood - lumber manufacture - pulp manufacture - fuelwood 98 its own residues are recycled within the process. Alternative markets and the sale value of wood residues must, of course, be taken into consideration when undertaking a feasibility study of a specific manufacturing plant, so as to assess its availability for fuel and to account for its opportunity value in manufacturing cost analysis. Apart from the use of residues as a potential fuel source to meet a plant's own energy requirements, its direct sale, or as pellets or briquettes, as fuel to other industrial users or electricity generating companies is becoming an attractive venture for some mills in developed countries. However, one must take into account its historic use in certain regions, as being a basic fuel for domestic heating and cooking in the smaller cities, villages and rural areas. In some countries the use of wood residues as a raw material for the production of say pulp and paper and particleboard, is deemed to be more beneficial to both the local and national economic and social well-being, than its use as a fuel. (100) This being due to the value added element in the form of labour and trade derived during the various stages of processing the residues into a saleable product, whereas its impact as an alternative fuel is solely to reduce oil imports - a debatable issue. 6.3 The fuel value of wood residues 6.3.1 Heating value 6.3.2 Effect of moisture content and particle size on heat values 6.3.1 Heating value When evaluating the properties of a combustible material with respect to its use as a fuel, the heating value, expressed in this document as gross calorific values or higher heating values, is one of the most important factors, which indicates the amount of thermal energy which may be obtained by combusting one mass unit of the material. The heating value of wood depends very much on the species and the part of the tree being used and varies between 17 to 23 MJ/kg of bone dry wood; generally softwoods have higher caloric values than hardwoods, with an average value of 21 MJ/kg BD for resinous woods and 19.8 MJ/kg BD for other woods being used. In fact, there is very little variation in the heating values of the wood substance itself, being some 19 MJ/kg BD, as it is, in fact, the variation in resin content, with a calorific value of 40 MJ/kg BD, which accounts for the differences in values between the species. It is for this reason that bark, with a high gum and resin content, tends to have a higher value than wood. However, although the fuel value may be fairly consistent in bone dry wood, the heating value depends on several factors, namely moisture content, particle size, type and efficiency of combustion equipment being used and the level of its operation and maintenance. Hence, in order to put the heating values of various wood residues into perspective one must take into consideration the heat content per unit of waste according to its moisture content, together with the efficiency of the energy conversion process which, as indicated in Table 9, provides a 99 comparative analysis to be made with other alternative fuels (refer to Tables 1 and 2 of Appendix IV). Table 9. The effect of moisture content on the net heating value of wood compared to that of other fuels Fuel As fired Gross calorific value (MJ/kg) Wood at 0% m.c 19.8 1/ 10% m.c 20% m.c. 30% m.c. 40% m.c. 50% m.c. Anthracite Lignite Heavy fuel oil Light fuel oil Butane Propane 17.8 15.9 14.5 12.0 10.0 31.4 26.7 42.6 43.5 49.3 50.0 Typical burner efficiency (%) 80 78 76 74 72 67 83 80 82.5 82.5 79.0 78.7 Useable Net heating value (MJ/kg) 15.8 13.9 12.1 10.7 8.6 6.7 26.1 21.4 35.1 35.9 38.9 39.4 1/ Wet basis Sources: (22) (61) (82) 6.3.2 Effect of moisture content and particle size on heat values Wood at the time of logging generally has a moisture content of approximately 50 to 55 percent, although the amount varies according to species, age and the portion of the tree from which it originated, i.e. branches, trunk, etc. Further fluctuations from the mean are influenced according to the season it is cut and the manner in which it is transported to the mill site and stored; logs that are floated down stream, wet-debarked or left in conditioning ponds could have moisture contents as high as 65 to 70 percent, whereas that which is road-hauled and dry-debarked would be in order of 45 to 50 percent m.c. Spring and summer storage can bring about a moisture loss of 10 to 25 percent. The moisture content of the manufacturing residues depend very much on at what stage of the process they are extracted and whether there has been any drying of the product before that stage. For instance, sanding dust from plywood or particleboard manufacture is taken from the plant after the driers and hot presses, where its moisture content could be as low as ten percent or less, as indicated in Table 10. Table 10. Range of characteristics of typical wood residues Residues Sanderdust Shavings Size (mm) Moisture content 1/ Ash & dirt content 2/ (%) (%) -1 2 - 10 0.1 - 0.5 1 - 12 10 - 20 0.1 - 1.0 100 Sawdust 1 - 10 Bark (hogged) 1 - 100 Log-yard clean-up up to 100 Forest residuals needles to stumps 25 - 40 25 - 75 40 - 60 30 - 60 0.5 - 2.0 1.0 - 2.0 5.0 - 50 3.0 - 20 1/ Wet basis By weight Source: (56) 2/ As mentioned previously, moisture content is a major determinant in the heating value of wood waste, which, from 19.8 MJ/kg at 0 percent m.c. drops to 10 MJ/kg at 50 percent m.c., as can be seen by refering to Figure 12. Although wood may be burnt at 55 percent m.c., and up to 58 percent m.c. with careful operator attention and boiler tuning, it is always better to aim for a moisture content of 50 percent or lower in order to achieve satisfactory and substained operation. When the moisture content rises to 60 percent, burning of the wood residues become difficult as its heating value drops dramatically, to the extent where, at approximately 68 percent m.c., "furnace blackout" occurs, being the point at which combustion can no longer be sustained, unless a supplementary fuel is used to maintain combustion. A high moisture content not only lowers the as-fired heat value of wood waste, but seriously affects the overall combustion efficiency due to the large amount of energy needed to heat considerable quantities of excess air and to vapourise the moisture in the waste, which, together with the moisture formed by the combustion process itself is subsequently lost up the stack as latent heat. Hence, it stands to reason that wood waste at ten percent m.c., with an as-fired heat value of 17.8 MJ/kg and a combustion efficiency of some 78 percent is preferable to green wood at 50 percent m.c. with an as-fired heat value of 10 MJ/kg and 67 percent combustion efficiency. Figure 12. The effect of wood residue moisture content on combustion efficiency (103) The size and form of the wood particle is also critical in both the handling characteristics and burning efficiency of residues and plays a major role in their combustibility and the selection and operation of processing and combustion plant. Whereas fine sanderdust and wood shavings may be burnt in suspension, larger sized wood-waste, in the form of large chips, coarsely hogged waste and slabs need a longer dwell time to burn which is generally undertaken on grates. Hence, all steps taken to reduce the moisture content and size of the residues to a minimum, pays dividends in energy generation. The provision of prepared storage, suitably protected against the elements, the use of flue gases to dry the fuel etc., all contribute towards maintaining low residual moisture and optimum combustion efficiency. 6.4 The preparation of wood waste fuel 6.4.1 Collection and handling 6.4.2 Storage 6.4.3 Size reduction and screening 6.4.4 Fuel drying 6.4.5 Densification 101 The handling, treatment and storage of wood waste fuel is considerably more costly and troublesome than that required for traditional fossil fuels. Hence, the importance of a well conceived and equipped woodfuel preparation system cannot be over-emphasized so as to maximize the fuel potential of a plant's residues and to minimize handling and combustion problems. The reduction of particle size and moisture content, together with the most appropriate storage and handling systems are necessary for an efficiently operated wood waste combustion system.. The waste preparation process generally involves hogging, dewatering, screening, size reduction, bulk storage, blending and drying prior to combustion so as to ensure a reliable and consistent supply of quality fuel to the burners. An equal amount of care and attention needs to be paid to the state of the wood waste used, as would normally be the case with any other fuel. The use of waste that is decayed, too wet or containing an excessive amount of contraries is false economy, due to the difficulty in handling and storing the wet residues, undue wear-and-tear on equipment and the detrimental effect on the overall combustion efficiency. 6.4.1 Collection and handling Waste collection and handling does not necessarily need to be either labour intensive or. involve costly and sophisticated mechanical handling plant, which could otherwise render the use of residues uneconomical. In small-scale forest industries in developing countries, the collection and handling of waste is predominantly manual, aided by a tractor or bulldozer to both convey and push the residues to a belt conveyor: system, thus avoiding the need for an enormous capital outlay and with maximized use of available labour. The handling systems should be so designed as to afford the highest degree of flexibility to the operator and to be able to cater for the full range of sizes and moisture contents of was. e expected from outside and within the mill. It is the failure to attend to such aspects of design that invariably give rise to fundamental problems in operation. Waste brought to the mill-site in the form of forest residues, or as purchased industrial wood waste, to supplement the plant's own wood-based fuel, may be delivered by road or rail. Methods of unloading range from the use of manual labour or a knuckle boom loader fitted with a clamshell bucket, to live bottom vans or hydraulically elevated dump trucks, all of which are determined by economic considerations. The manner in which mill residues are best removed and handled is again a matter of economics, availability of labour and the quantity and type of waste produced and is normally undertaken by a combination of belt. and pneumatic conveyors, front-arid loaders and trucks, with manual gathering predominating in mills with an input rapacity of 20 000 m3/A and below. Generally slabs, edgings, peeler cores, veneer waste and trimmings would be transported by mechanical conveyors or carried manually to a chipper and, after screening, conveyed to storage piles for use as either furnish for pulp or particleboard manufacture or as fuel. Bark, panel trim and waste from ply glue spreaders would be hogged and conveyed to the hog-fuel storage area. Sawdust and sanderdust, depending on the quantities produced, would be pneumatically extracted and conveyed to a separate storage area (preferably covered). Retrieval is normally achieved by the use of belt, drag link, flight or pneumatic conveyors, in conjunction with front-end loaders, which may also be used to build-up the piles. In order to safeguard against damage to moving parts, stone traps and magnetic separators need to be incorporated in the handling system, ahead of the reduction plant so as to remove all stones and 102 tramp iron. Depending on the proportion of contraries normally expected in the fuel supply and the type of burning equipment employed, air classification may need to be employed in order to remove rocks and sand from the smaller-sized fuel particles, but only if they are comparatively dry. 6.4.2 Storage The type of wood waste storage will be largely determined by: - the form and moisture content of the residues; - the frequency and reliability of year-round deliveries to the mill and production of residues; - the availability of land; - climatic conditions; - the need for air drying; - the volume of wood waste fuel involved; - the system of waste handling and treatment adopted. Storage systems may be divided into two distinct categories, namely: Outdoor storage, in piles on prepared concrete or gravel pads to aid drainage and reduce the entrainment of contraries, is the least expensive means of maintaining stocks. This form of storage is generally suited for stocks of 20 to 30 day's capacity of green forest residues, bark, moist wood slabs or chips. However, unless adequate preparations and precautions are taken, deterioration and fires from overheating and biological action can take place. Hence, residues should be monitored and those that do not benefit from drying with time should have a fast turnaround and be used on a first-in-first-out basis (109). In instances where a large variety of residue sizes are involved, it is always advisable to segregate according to size, either before or after storage, and, in most cases, it is preferable to reduce the larger-sized waste in hoggers or chippers at an early stage in order to facilitate handling. Mixing of wet and dry waste should be avoided, as such a practice will reduce the efficiency of combustion; it is far better to have dual storage and feed systems in order to segregate the feed to the burners according to moisture content. Covered storage systems, to safeguard against loss and damage due to wind and rain, is normally provided for materials which are readily wind-borne or freely absorb moisture, such as dry sawdust, planer shavings and sanderdust. Such storage systems as open-sided buildings, hoppers, bins or silos are usually located in the near vicinity of the combustion plant, with approximately 48 hours capacity so as to sustain continuous operation without being hampered by weekends or interruptions in the flow of supply from the processing plant. 6.4.3 Size reduction and screening Whereas sawdust, planer shavings and sanderdust may be burnt directly without the need for further processing, other forms of wood waste have to be reduced in size in order to facilitate handling, storage and metering to the combustion chamber. By achieving a uniform particle size, combustion efficiency will be improved due to the uniform and controlled fuel feed rate and the ability to regulate the air supply. Additionally, in the case of fuels with a high moisture content, the reduction process exposes a greater surface area of the particle to the heated gases, thus releasing the moisture more rapidly, thereby enhancing its heating value. 103 Size reduction may be carried out in several stages in a hog or attrition mill, with screening before and in between. The hog basically comprises of a set of knives or swing hammers mounted on a rapidly rotating shaft within a robust casing. The impact of the rotating impellers on the wood waste against the breaking plate reduces it to a standard size of approximately 20 to 50 mm (100). Screening, directly before or after the hog, separates the dirt and fines and conserves energy in the subsequent reduction stages by removing those particles of acceptable size which would otherwise be reprocessed. Attrition mills are used to reduce residues still further in size, by passing them between a stationary and a rotating disc, each fitted with slotted or grooved segments. The particles produced may, after screening, then be burnt in direct-fired suspension burners to produce hot gases for drying lumber, plywood and particleboard furnish and other such heating requirements. 6.4.4 Fuel drying As previously mentioned, combustion efficiency, boiler control and the operator's ability to provide a quick response to changes in steam demand become seriously impaired by a combination of high and fluctuating moisture content of incoming fuel. This situation may be improved by drying the fuel, which will also effectively increase boiler capacity and lead to better emission control. The moisture in residues may be reduced either by mechanical pressing, air-drying or the use of hot air dryers, or a combination of all three. It is common practice for mechanical presses to be used on bark and wood waste with moisture levels in excess of 70 percent in order to reduce it to 55 to 60 percent m.c., which would then enable the waste to be mixed with dryer incoming materials to produce a combustible fuel. However, in the event that sufficient supplies of wood waste are readily available to meet the plant's energy needs and the disposal of bark does not present a serious problem to the mill, then it is not considered economically justified for it to be pressed and dried in view of the maintenance, power demand and the high capital intensive plant involved. Air-drying of logging residues, assuming the right climatic conditions prevail, can bring about a moisture loss of some 10 to 15 percent, and the level may even drop further to 25 percent (67) should the residues be left in clear-felled spaces open to the action of wind and sun. Air-drying of mill waste, time and space permitting; is preferable under covered well-ventilated areas, especially for the smaller-sized residues such as sawdust, which is more liable to absorb rainfall and takes longer to air-dry than say mixed wood waste. Green whole chips and mixed waste, when stored outside in piles for several months, may lose up to 10 to 25 percent (105) of their moisture content by way of the drying effect of wind, sun and spontaneous internal heating due to bacteriological action on the materials in the interior of the pile (108). The use of fuel dryers to dry fuel to approximately 30 percent m.c. using plant such as rotary drum, flash and cascade type dryers employing waste stack gases, direct combustion of residues, steam or hot water as heating sources, undoubtedly lead to better combustion efficiency and boiler utilization. Nonetheless, the use of fuel dryers in medium-sized installations is questionable as the heat energy gained would be off-set by that which would be needed to dry the fuel, added to which one must take into consideration the high capital and operating costs involved. 104 6.4.5 Densification A growing awareness has developed in recent years in the use of compacted wood waste, in the form of briquettes, pellets or "logs", as a domestic or industrial fuel. Briquettes or logs are generally formed by forcing dry sawdust or shavings through a split cylindrical die using a hydraulic ram. The exerted pressure, of some 1 200 kg/cm2, and the resultant heat generated bonds the wood particles into "logs". The production of pellets involves the reduction of wood waste to the size of sawdust, which is then dried to approximately 12 percent m.c., before being extruded in specially adapted agricultural pellet mills to form pellets of some 6 to 18 mm diameter and 15 to 30 mm long, with a density in the range of 950 to 1 300 kg/m3 1/. Drying of the furnish prior to extrusion is usually undertaken in rotating drum dryers, fired by approximately 15 to 20 percent of the plant's pellet production. 1/ Bulk density being 480 to 640 kg/m3 (106) Although pelleting produces a product with excellent handling and storage characteristics, with four times the energy concentration of woodfuel, thus greatly reducing transport costs and improving boiler efficiency, it has been found that high capital investment in the processing plant and operating costs only prove economically attractive if transportation distances of the fuel exceed 250 km from the source of the raw material, and is normally not warranted for sitegenerated fuels. 6.5 Applications for waste-based energy A mill or integrated complex, with a readily available supply of hog-fuel, has several operations open to it as to the manner in which it may convert its waste into useable energy. However, before embarking upon a general description of the proven methods of combustion and combustion plants, a brief outline of several alternative applications for the recovered heat has been listed below. By examining Figures 5, 7 and 9 in Chapter 2, it becomes apparent which production centres will gain the most from either onsite heat or power generation or both. The choice of the most efficient and cost-effective use of waste-based energy, and the selection of appropriate heating mediums would need to be studied on a case-by-case basis, in view of the individuality of each mill. Heating medium Hot air Hot water and thermic oil Broad outline of possible applications For direct drying of: (a) lumber; (b) plywood veneer; (c) particleboard furnish; As an indirect means to supply heat for: (d) log conditioning; (e) lumber and veneer drying; (f) glue and resin preparation; (g) hot pressing of ply and particleboard; 105 Steam (h) space heating; May be used as a heating medium in all the above-mentioned applications, as well as: (i) to provide transmission power to process plant through the use of a system of line-shaft and belt drives. (In the past, many sawmills were powered in this way, a large number of which are still operating successfully); (j) to directly drive plant, such as boiler feed water pumps, induced draft fans, large air compressors, etc., by way of small steam turbines; (k) steam which is surplus to the mill's requirements may be sold to neighbouring consumers for industrial, commercial and community use; (l) to produce electricity by way of a turbine-generator to help meet the power demand of the integrated complex; (m) in the case of non-integrated sawmills and plywood plants, in which their residue production far exceeds their actual heat energy needs and market demand, consideration may be given to on-site power generation to meet their own requirements, with the sale of the surplus to the public utilities. 6.6 Combustion 6.6.1 Firetube and watertube boilers 6.6.2 Pile burners 6.6.3 Suspension and cyclone burners 6.6.4 Fluidized-bed combustors The range of combustion systems now available to the forest products industry is quite considerable, with a large choice of equipment for each category. Apart from the end use of the heat, particle size plays an important role in influencing the combustion plant. Whereas fine sanderdust and wood shavings may be burnt in suspension, larger-sized wood waste, in the form of chips, coarsely hogged residues and slabs need longer to burn which is generally undertaken on grates. The decision whether to select the combustion plant to suit the available fuel or, process the fuel to the requirements of the preferred plant, can only be made after a thorough analysis has been carried out. Traditional methods of burning hogged fuel for steam or hot water production has been with the use of firetube and watertube boilers employing the pile burning method of combustion on a grate. The difference between standard oil or gas fired boilers and those for firing wood waste in that the slow-burning characteristics of wood, together with its high moisture content, necessitates a larger combustion chamber capacity with a high furnace so as to create low upward velocities and cater for the longer residence time needed to burn the wood fuel (16). The necessity of a larger-sized boiler, together with the need for waste handling plant involves up to 1.5 to 4 times the investment cost of oil fired package boilers. As indicated in Table 9, combustion efficiencies of 65 to 75 percent may be expected when burning wood waste, compared to 80 percent obtained from gas or oil fired units. The difficulty of automatic firing, slow response to peak demand and the need for ash removal and disposal are other disadvantages 106 which must be carefully weighted up when considering the use of, what may at first appear to be, a cheap fuel. The direct firing of sanderdust and pulverized wood waste presents a somewhat simpler way in which to use the fuel's energy value to heat drying kilns, air heaters and boilers. However, there is still some hesitation in the industry to adopt the various direct-fire systems and other newer technologies, such as wood gasifiers, until they have been adequately proven, though they do hold promising prospects. A brief description of the basic combustion systems, with the exception of gasification and pyrolysis, is given, without attempting to make any comparisons as each system has its own champions and needs to be assessed according to the circumstances of the mills. It must be pointed out, however, that the capacity ranges, technology and cost of several of the mentioned plants are inconsistent with medium-sized mills in developing countries. 6.6.1 Firetube and watertube boilers Boilers fall into two categories, being firetube and watertube. Firetube boilers are principally used where steam pressures of not more than 20 kg/cm, (12) are required in small to medium-sized operations, and are well suited for the heat requirements of the mechanical wood-based industry. They are relatively inexpensive and operate on the principle of hot combustion gases passing through steel tubes set in a water jacket. Watertube boilers consist of tubes welded together in such a manner as to form complete walls enclosing the combustion chamber, through which flows the water to be heated. By virtue of its construction, the watertube boiler is almost exclusively used where steam pressures above ten kg/cm2 (12) are employed, especially in providing motive power to turbine-generators. Both types of boiler may be further sub-divided into those which arrive as a package of fielderected on-site. Package boilers are generally shop assembled units, thus allowing them to be readily shipped, installed and operated and tend to be less than 22 500 kg/hr steam capacity. Whereas all the component parts of the field-erected units are entirely assembled and welded onsite. 6.6.2 Pile burners Pile burners, as the name implies, burn the fuel in piles either on a refractory floor or grate, and may be divided into two classes, namely: Heaped pile burning furnaces, such as the tee-pee burners and clutch ovens, which are fed with fuel from the top of the furnace in batch form via chutes located across the grates or, continuously by way of variable screw feeders, to be burnt in a pile on a refractory floor or grate. Primary air for combustion is introduced through ports located on all four sides of each chamber and the heat transmitted to the boiler surface situated above and behind the combustion chamber. Such furnaces may be used to burning fuels of up to 65 percent m.c., regardless of size or shape (98), although they do require a lot of attention and considerable time to build-up and burn down the pile and have low efficiencies in the order of 50 to 60 percent. In some furnaces, fuel of high moisture content may be added to the base of the pile by hydraulic rams, thus allowing the waste to burn more slowly and completely. The provision of more than one chamber permits ash to be removed in one compartment whilst the other is being fired. 107 Thin pile furnaces burn hogged fuel, up to 55 to 60 percent m.c., as a thin bed spread across the grate. Sloping grates, pinhole grates, travailing grates are but some of the systems currently in use enabling the fuel to progressively advance along the grate through the combustion chamber, whilst being exposed to primary air from below, to be then discharged by an assortment of removal systems as ash. Spreader stokers, using pneumatic or mechanical spreaders, are used in the larger-sized furnaces to evenly meter and distribute hogged wood or particles, of up to 45 to 50 percent m.c., into the firing zone of the combustion chamber, allowing the finer particles to burn in suspension and for the larger-sized fuel to fall to the grate where it is burnt. 6.6.3 Suspension and cyclone burners Suspension and cyclone burners are proven technology, having been successfully used with pulverized coal for several years and adapted for use with woodfuels. Suspension burners, as the term suggests, burns fine wood particles in suspension, in either special combustion chambers or boiler fireboxes, in a highly turbulent environment caused by forced combustion air. In order to operate efficiently the wood particles need to be no more than 6 mm in size and a maximum moisture content of 15 percent (98). Such units are particularly well-suited for use with lumber kilns, veneer and particleboard furnish dryers and boilers. Apart from combustion efficiencies of approximately 75 percent, they often have a quick response to swing loads with high turndown ratios, although provision must be made to safeguard against the risk of explosions due to the nature of the fine fuel particles used. In the case of cyclone burners, pulverized wood fuel, of a maximum 3.5 mm size and 12 percent m.c., is mixed in the first stage of the burner and combusted in an external cyclone burner. 6.6.4 Fluidized-bed combustors Fluidized-bed combustors are capable of burning untreated hog fuel, with moisture levels as high as 55 to 60 percent (100), in a turbulent mixing zone above a fluidized bed of inert silica sand. The fuel is maintained in suspension during combustion by a high velocity of air forced through the bed of sand, which results in the sand adopting free-flowing and fluidized properties. 6.7 Cogeneration 6.7.1 Restrictive regulations and penalties 6.7.2 Economic considerations The simultaneous production of both electrical power and a useable form of thermal energy, such as steam, is termed cogeneration. This may be achieved by generating high pressure steam in a hog-fuel boiler, which would then be passed through a turbine generator for power before being used as exhaust steam in drying or process heating. Therefore, rather than just generating electricity from wood waste with a conversion efficiency of 25 to 30 percent, cogeneration raises the efficiency of energy utilization to some 75 percent (46). 108 The use of a condensing turbine generator with single or double automatic extraction or a backpressure turbine generator are options available to the forest products industry, though the latter is often favoured. Although the fuel potential of the residues generated from sawmilling and plywood manufacture exceed the plants' heat and power requirements, energy self-sufficiency in electricity in an integrated operation, including particleboard production, is more difficult to attain due to the fact that there is a given ratio between the power output and the output of industrial heat generated by a back-pressure power plant (approximately 1:1.5) (25). This shortfall may be overcome by the following alternative solutions: (25) (47) - to design a power plant in which the ratio between power and heat production meets that of the integrated complex's consumption ratio. However, this option involves both costly and sophisticated plant and therefore is not considered suitable for developing countries; - to supplement the plant's own hog-fuel production with purchases wood and wood residues or fuel oil. Yet this option either places on increased load on existing waste treatment and combustion systems or necessitates larger plant capacity, with heat production being surplus to needs; - to make-up the balance of the mill's power requirements by either using diesel generating sets or purchasing power from the national grid. 6.7.1 Restrictive regulations and penalties In certain countries legislation and regulations discourage the generation of power for sale, and those mills that meet their own needs for power are often penalized by having to pay higher rates for their purchased power in the event of a shortfall or shut-down in their on-site power supply (58). Although such regulations may well have been established to dissuade mills from investing in small unviable power plants, they do not take into account the potential for hog-fuelled backpressure power. Hopefully, in the light of the anticipated rise in fuel costs such restrictive tariffs shall be removed. 6.7.2 Economic considerations Although it is technically feasible to use wood waste as fuel for power generation, it is the economics that invariably prove to he the limiting factor in most cases. Whereas there are obvious benefits to be gained by burning wood residues to reduce a manufacturer's fuel oil and electricity bill, they may be off-set by the high capital costs involved, low plant efficiencies and increased manning levels. Of course the economics of wood waste energy generation becomes more attractive as traditional fuel prices increase, though the real value of the wood waste as a fuel source must take into account its available heat content, the investment and operating costs of the plant needed to handle and convert it to useable energy, before any worthwhile comparative studies can be made. It must be noted that the capacity of most energy generation plant available to the industry, especially for cogeneration, exceeds that which can be economically utilized by most mills and integrated units. Additionally, the limited finance available to the small- and medium-scale mills tend to be a major deterrent in their contemplating cogeneration as an option worthy of consideration, regardless of the possible long-term gains. 109 Hence, it is for these reasons that, in spite of their self-sufficiency in self-generated fuel, it is generally not considered economically justified for the individual sawmill or plywood plant of less than 150 000 m3/A log input capacity (34) to generate their own power, unless they be part of an integrated production unit consisting of sawmilling, plywood and particleboard manufacture, etc., with shared services. 4.3 BIOMASS GASIFICATION-PRODUCER GAS. Gasification is a process that converts organic or fossil based carbonaceous materials into carbon monoxide, hydrogen and carbon dioxide. This is achieved by reacting the material at high temperatures (>700 °C), without combustion, with a controlled amount of oxygen and/or steam. The resulting gas mixture is called syngas (from synthesis gas or synthetic gas) or producer gas and is itself a fuel. The power derived from gasification and combustion of the resultant gas is considered to be a source of renewable energy if the gasified compounds were obtained from biomass.[1][2][3][4] The advantage of gasification is that using the syngas is potentially more efficient than direct combustion of the original fuel because it can be combusted at higher temperatures or even in fuel cells, so that the thermodynamic upper limit to the efficiency defined by Carnot's rule is higher or not applicable. Syngas may be burned directly in gas engines, used to produce methanol and hydrogen, or converted via the Fischer-Tropsch process into synthetic fuel. Gasification can also begin with material which would otherwise have been disposed of such as biodegradable waste. In addition, the high-temperature process refines out corrosive ash elements such as chloride and potassium, allowing clean gas production from otherwise problematic fuels. Gasification of fossil fuels is currently widely used on industrial scales to generate electricity[citation needed]. Contents 1 History 2 Chemical Reactions 3 Gasification processes o 3.1 Counter-current fixed bed ("up draft") gasifier o 3.2 Co-current fixed bed ("down draft") gasifier o 3.3 Fluidized bed reactor o 3.4 Entrained flow gasifier o 3.5 Plasma gasifier o 3.6 Free radical gasifier 4 Feedstock o 4.1 Waste disposal 5 Current applications o 5.1 Heat o 5.2 Electricity o 5.3 Combined heat and power o 5.4 Transport fuel o 5.5 Renewable energy and fuels 6 See also 7 References 8 External links 110 History Adler Diplomat 3 with gas generator (1941) The process of producing energy using the gasification method has been in use for more than 180 years. During that time coal and peat were used to power these plants. Initially developed to produce town gas for lighting & cooking in 1800s, this was replaced by electricity and natural gas, it was also used in blast furnaces but the bigger role was played in the production of synthetic chemicals where it has been in use since the 1920s. During both world wars especially the Second World War the need of gasification produced fuel reemerged due to the shortage of petroleum.[5] Wood gas generators, called Gasogene or Gazogène, were used to power motor vehicles in Europe. By 1945 there were trucks, buses and agricultural machines that were powered by gasification. It is estimated that there were close to 9,000,000 vehicles running on producer gas all over the world. Chemical Reactions In a gasifier, the carbonaceous material undergoes several different processes: Pyrolysis of carbonaceous fuels Gasification of char 1. The dehydration or drying process occurs at around 100°C. Typically the resulting steam is mixed into the gas flow and may be involved with subsequent chemical reactions, notably the water-gas reaction if the temperature is sufficiently high enough (see step #5). 2. The pyrolysis (or devolatilization) process occurs at around 200-300°C. Volatiles are released and char is produced, resulting in up to 70% weight loss for coal. The process is dependent on the properties of the carbonaceous material and determines the structure and composition of the char, which will then undergo gasification reactions. 111 3. The combustion process occurs as the volatile products and some of the char reacts with oxygen to primarily form carbon dioxide and small amounts of carbon monoxide, which provides heat for the subsequent gasification reactions. Letting C represent a carboncontaining organic compound, the basic reaction here is 4. The gasification process occurs as the char reacts with carbon and steam to produce carbon monoxide and hydrogen, via the reaction 5. In addition, the reversible gas phase water gas shift reaction reaches equilibrium very fast at the temperatures in a gasifier. This balances the concentrations of carbon monoxide, steam, carbon dioxide and hydrogen. In essence, a limited amount of oxygen or air is introduced into the reactor to allow some of the organic material to be "burned" to produce carbon monoxide and energy, which drives a second reaction that converts further organic material to hydrogen and additional carbon dioxide. Further reactions occur when the formed carbon monoxide and residual water from the organic material react to form methane and excess carbon dioxide. This third reaction occurs more abundantly in reactors that increase the residence time of the reactive gases and organic materials, as well as heat and pressure. Catalysts are used in more sophisticated reactors to improve reaction rates, thus moving the system closer to the reaction equilibrium for a fixed residence time. Gasification processes Several types of gasifiers are currently available for commercial use: counter-current fixed bed, co-current fixed bed, fluidized bed, entrained flow, plasma, and free radical.[1][6][7][8] Counter-current fixed bed ("up draft") gasifier A fixed bed of carbonaceous fuel (e.g. coal or biomass) through which the "gasification agent" (steam, oxygen and/or air) flows in counter-current configuration.[9] The ash is either removed dry or as a slag. The slagging gasifiers have a lower ratio of steam to carbon,[10] achieving temperatures higher than the ash fusion temperature. The nature of the gasifier means that the fuel must have high mechanical strength and must ideally be non-caking so that it will form a permeable bed, although recent developments have reduced these restrictions to some extent. The throughput for this type of gasifier is relatively low. Thermal efficiency is high as the gas exit temperatures are relatively low. However, this means that tar and methane production is significant at typical operation temperatures, so product gas must be extensively cleaned before use. The tar can be recycled to the reactor. In the gasification of fine, undensified biomass such as rice hulls, it is necessary to force air into the reactor by means of a fan. This creates very high gasification temperatures, at times as high as 1000 C. Above the gasification zone, a bed of fine, hot char is formed, and as the gas is forced through this bed, most complex hydrocarbons are broken down into simple components of hydrogen and carbon monoxide.[citation needed] Co-current fixed bed ("down draft") gasifier Similar to the counter-current type, but the gasification agent gas flows in co-current configuration with the fuel (downwards, hence the name "down draft gasifier"). Heat needs to be added to the upper part of the bed, either by combusting small amounts of the fuel or from external heat sources. The produced gas leaves the gasifier at a high temperature, and most of this heat is often transferred to the gasification agent added in the top of the bed, resulting in an energy efficiency 112 on level with the counter-current type. Since all tars must pass through a hot bed of char in this configuration, tar levels are much lower than the counter-current type. Fluidized bed reactor The fuel is fluidized in oxygen and steam or air. The ash is removed dry or as heavy agglomerates that defluidize. The temperatures are relatively low in dry ash gasifiers, so the fuel must be highly reactive; low-grade coals are particularly suitable. The agglomerating gasifiers have slightly higher temperatures, and are suitable for higher rank coals. Fuel throughput is higher than for the fixed bed, but not as high as for the entrained flow gasifier. The conversion efficiency can be rather low due to elutriation of carbonaceous material. Recycle or subsequent combustion of solids can be used to increase conversion. Fluidized bed gasifiers are most useful for fuels that form highly corrosive ash that would damage the walls of slagging gasifiers. Biomass fuels generally contain high levels of corrosive ash. Entrained flow gasifier A dry pulverized solid, an atomized liquid fuel or a fuel slurry is gasified with oxygen (much less frequent: air) in co-current flow. The gasification reactions take place in a dense cloud of very fine particles. Most coals are suitable for this type of gasifier because of the high operating temperatures and because the coal particles are well separated from one another. The high temperatures and pressures also mean that a higher throughput can be achieved, however thermal efficiency is somewhat lower as the gas must be cooled before it can be cleaned with existing technology. The high temperatures also mean that tar and methane are not present in the product gas; however the oxygen requirement is higher than for the other types of gasifiers. All entrained flow gasifiers remove the major part of the ash as a slag as the operating temperature is well above the ash fusion temperature. A smaller fraction of the ash is produced either as a very fine dry fly ash or as a black colored fly ash slurry. Some fuels, in particular certain types of biomasses, can form slag that is corrosive for ceramic inner walls that serve to protect the gasifier outer wall. However some entrained flow type of gasifiers do not possess a ceramic inner wall but have an inner water or steam cooled wall covered with partially solidified slag. These types of gasifiers do not suffer from corrosive slags. Some fuels have ashes with very high ash fusion temperatures. In this case mostly limestone is mixed with the fuel prior to gasification. Addition of a little limestone will usually suffice for the lowering the fusion temperatures. The fuel particles must be much smaller than for other types of gasifiers. This means the fuel must be pulverized, which requires somewhat more energy than for the other types of gasifiers. By far the most energy consumption related to entrained flow gasification is not the milling of the fuel but the production of oxygen used for the gasification. Plasma gasifier In a plasma gasifier a high-voltage current is fed to a torch, creating a high-temperature arc. The inorganic residue is retrieved as a glass-like substance. Free radical gasifier A single stage gasifier that employs a thermolytic (heat energy) and photolytic (light energy) conversion process in an oxygen starved environment. The free radical gasifier uses electrical input energy to cause thermal breakdown and ultraviolet light based degradation of material, along 113 with harnessing free radical reactions to further convert carbon-based materials into syngas.[citation needed] Feedstock There are a large number of different feedstock types for use in a gasifier, each with different characteristics, including size, shape, bulk density, moisture content, energy content, chemical composition, ash fusion characteristics, and homogeneity of all these properties. A wide variety of feedstocks can be gasified, with wood pellets and chips, waste wood, plastics and aluminium, Municipal Solid Waste (MSW), Refuse-derived fuel (RDF), agricultural and industrial wastes, sewage sludge, switch grass, discarded seed corn, corn stover and other crop residues all being used.[1] Chemrec has developed a process for gasification of black liquor.[11] Waste disposal HTCW reactor, one of several proposed waste gasification processes. According to the sales and sales management consultants KBI Group a pilot plant in Arnstadt implementing this process has completed initial tests.[12] Waste gasification has several advantages over incineration: The necessary extensive flue gas cleaning may be performed on the syngas instead of the much larger volume of flue gas after combustion. Electric power may be generated in engines and gas turbines, which are much cheaper and more efficient than the steam cycle used in incineration. Even fuel cells may potentially be used, but these have rather severe requirements regarding the purity of the gas. Chemical processing (Gas to liquids) of the syngas may produce other synthetic fuels instead of electricity. Some gasification processes treat ash containing heavy metals at very high temperatures so that it is released in a glassy and chemically stable form. 114 A major challenge for waste gasification technologies is to reach an acceptable (positive) gross electric efficiency. The high efficiency of converting syngas to electric power is counteracted by significant power consumption in the waste preprocessing, the consumption of large amounts of pure oxygen (which is often used as gasification agent), and gas cleaning. Another challenge becoming apparent when implementing the processes in real life is to obtain long service intervals in the plants, so that it is not necessary to close down the plant every few months for cleaning the reactor. Several waste gasification processes have been proposed, but few have yet been built and tested, and only a handful have been implemented as plants processing real waste, and most of the time in combination with fossil fuels.[13] One plant (in Chiba, Japan using the Thermoselect process[14]) has been processing industrial waste since year 2000, but has not yet documented positive net energy production from the process. In the USA, gasification of waste is expanding across the country. Ze-gen is operating a waste gasification demonstration facility in New Bedford, Massachusetts. The facility was designed to demonstrate gasification of specific non-MSW waste streams using liquid metal gasification.[15] In addition, construction of a biomass gasification plant was approved in DeKalb County, Georgia on June 14, 2011 and in Green Bay Wisconsin a deal was made with the Oneida Nation and the city of Green Bay to build a gasification power plant which will supply electricity to over 4,000 homes.[16] Also in the USA, plasma is being used to gasify municipal solid waste, hazardous waste and biomedical waste at the Hurlburt Field Florida Special Operations Command Air Force base. PyroGenesis Canada Inc. is the technology provider.[17] Current applications Syngas can be used for heat production and for generation of mechanical and electrical power. Like other gaseous fuels, producer gas gives greater control over power levels when compared to solid fuels, leading to more efficient and cleaner operation. Syngas can also be used for further processing to liquid fuels or chemicals. Heat Gasifiers offer a flexible option for thermal applications, as they can be retrofitted into existing gas fueled devices such as ovens, furnaces, boilers, etc., where syngas may replace fossil fuels. Heating values of syngas are generally around 4-10 MJ/m3. Electricity Industrial-scale gasification is currently mostly used to produce electricity from fossil fuels such as coal, where the syngas is burned in a gas turbine. Gasification is also used industrially in the production of electricity, ammonia and liquid fuels (oil) using Integrated Gasification Combined Cycles (IGCC), with the possibility of producing methane and hydrogen for fuel cells. IGCC is also a more efficient method of CO2 capture as compared to conventional technologies. IGCC demonstration plants have been operating since the early 1970s and some of the plants constructed in the 1990s are now entering commercial service. 115 Combined heat and power In small business and building applications, where the wood source is sustainable, 250-1000 kWe and new zero carbon biomass gasification plants have been installed in Europe that produce tar free syngas from wood and burn it in reciprocating engines connected to a generator with heat recovery. This type of plant is often referred to as a wood biomass CHP unit but is a plant with seven different processes: biomass processing, fuel delivery, gasification, gas cleaning, waste disposal, electricity generation and heat recovery.[18] Transport fuel Diesel engines can be operated on dual fuel mode using producer gas. Diesel substitution of over 80% at high loads and 70-80% under normal load variations can easily be achieved.[19] Spark ignition engines and SOFC fuel cells can operate on 100% gasification gas.[20][21][22] Mechanical energy from the engines may be used for e.g. driving water pumps for irrigation or for coupling with an alternator for electrical power generation. While small scale gasifiers have existed for well over 100 years, there have been few sources to obtain a ready to use machine. Small scale devices are typically DIY projects. However, currently in the United States, several companies offer gasifiers to operate small engines. In 2009 21stCenturyMotorworks claimed to have developed gasification technology in a prototype pickup truck that could use any biomass materials for fuel,[23] the vehicle was displayed at multiple events including the 2009 Boston Greenfest. Renewable energy and fuels Gasification plant Güssing, Austria (2006) In principle, gasification can proceed from just about any organic material, including biomass and plastic waste. The resulting syngas can be combusted. Alternatively, if the syngas is clean enough, it may be used for power production in gas engines, gas turbines or even fuel cells, or converted efficiently to dimethyl ether (DME) by methanol dehydration, methane via the Sabatier reaction, or diesel-like synthetic fuel via the Fischer-Tropsch process. In many gasification processes most of the inorganic components of the input material, such as metals and minerals, are retained in the ash. In some gasification processes (slagging gasification) this ash has the form of a glassy solid with low leaching properties, but the net power production in slagging gasification is low (sometimes negative) and costs are higher. 116 Regardless of the final fuel form, gasification itself and subsequent processing neither directly emits nor traps greenhouse gases such as carbon dioxide. Power consumption in the gasification and syngas conversion processes may be significant though, and may indirectly cause CO2 emissions; in slagging and plasma gasification, the electricity consumption may even exceed any power production from the syngas. Combustion of syngas or derived fuels emits exactly the same amount of carbon dioxide as would have been emitted from direct combustion of the initial fuel.[dubious – discuss] Biomass gasification and combustion could play a significant role in a renewable energy economy, because biomass production removes the same amount of CO2 from the atmosphere as is emitted from gasification and combustion.[dubious – discuss] While other biofuel technologies such as biogas and biodiesel are carbon neutral, gasification in principle may run on a wider variety of input materials and can be used to produce a wider variety of output fuels. There are at present a few industrial scale biomass gasification plants. Since 2008 in Svenljunga, Sweden, a biomass gasification plant generates up to 14 MWth, supplying industries and citizens of Svenljunga with process steam and district heating, respectively. The gasifier uses biomass fuels such as CCA or creosote impregnated waste wood and other kinds of recycled wood to produces syngas that is combusted on site.[24][25] In 2011 a similar gasifier, using the same kinds of fuels, is being installed at Munkfors Energy's CHP plant. The CHP plant will generate 2 MWe (electricity) and 8 MWth (district heating).[26][27] Examples of demonstration projects include: Those of the Renewable Energy Network Austria,[28] including a plant using dual fluidized bed gasification that has supplied the town of Güssing with 2 MW of electricity, produced utilising GE Jenbacher reciprocating gas engines[29][30] and 4 MW of heat,[31] generated from wood chips, since 2003. Chemrec's pilot plant in Piteå that has produced 3 MW of clean syngas since 2006, generated from entrained flow gasification of black liquor.[11] The US Air Force Transportable Plasma Waste to Energy System (TPWES) facility at Hurlburt Field, Florida.[17] Technology of Biomass Gasification Biomass has been a major energy source, prior to the discovery of fossil fuels like coal and petroleum. Even though its role is presently diminished in developed countries, it is still widely used in rural communities of the developing countries for their energy needs in terms of cooking and limited industrial use. Biomass, besides using in solid form, can be converted into gaseous form through gasification route. 1. Concept and Principle Gasification is the process of converting solid fuels to gaseous fuel. It is not simply pyrolysis; pyrolysis is only one of the steps in the conversion process. The other steps are combustion with air and reduction of the product of combustion, (water vapour and carbon dioxide) into combustible gases, (carbon monoxide, hydrogen, methane, some higher hydrocarbons) and inerts, (carbon dioxide and nitrogen). The process leads to a gas with some find dust and condensable compounds termed tar, both of which must be restricted to less than about 100 ppm each if the gas is to be used in internal combustion engines. 2. Uses of Producer Gas The producer gas obtained by the process of gasification can have end use for thermal application or for mechanical/electrical power generation. Like any other gaseous fuel, producer gas has the control for 117 power when compared to that of solid fuel, in this solid biomass. This also paves way for more efficient and cleaner operation. The producer gas can be conveniently used in number of applications as mentioned below. 2.1 Thermal Thermal energy of the order of 5 MJ is released, by flaring 1 m3 of producer gas in the burner. Flame temperatures as high as 1550 K can be obtained by optimal pre-mixing of air with gas. For applications which require thermal energy, gasifiers can be a good option as a gas generator, and retrofitted with existing devices. Few of the devices to which gasifier could be retrofitted are a) Dryers: Drying is the most essential process in beverage and spices industry like tea and cardamom. This calls for hot gases in the temperature range of 120 - 130 oC, in the existing designs. Typically the heat energy required is equivalent to 1 kg of wood for 1 kg made tea. Gasifier is an ideal solution for the above situation, where hot gas after combustion can be mixed with the right quantity of secondary air, so as to lower its temperature to the desired level for use in the existing dryers. b) Kilns: Baking of tiles, potteries require hot environment in the temperature range of 800 - 950 oC. This is presently being done by combusting large quantities of wood in an inefficient manner. Gasifiers could be suitable for such applications, which provides a better option of regulating the thermal environment. There will also be an added advantage of smokeless and sootless operation, whereby enhancing the product value. c) Furnaces: In non-ferrous metallurgical and foundry industries high temperatures (~650 - 1000 oC) are required for melting metals and alloys. This is commonly done by using expensive fuel oils or electrical heaters. Gasifiers are well suited for such applications. d) Boilers: Process industries which require steam or hot water, use either biomass or coal as fuel in the boilers. Biomass is used inefficiently with higher pollutants like NOx and with little control with respect to power regulation. Therefore these devices are appropriate to be retrofitted with gasifiers for efficient energy usage. Apart from these, energy requirements in poultry farms, cold storage devices (vapour compression refrigerator), rubber industry and so on could be met using wood gasifiers.. 2.2 Power Generation Using wood gas, it possible to operate a diesel engine on dual fuel mode. Diesel substitution of the order of 80 to 85% can be obtained at nominal loads. The mechanical energy thus derived can be used either for energising a water pump set for irrigational purpose or for coupling with an alternator for electrical power generation, either for local consumption or for grid synchronisation. An appropriate site to realise the above application is an unelectrified village or hamlet. The benefits derived from this could be many, right from irrigation of fields to the supply of drinking water, and illuminating the village to supporting village industries. The other suitable sites could be saw mills and coffee plantations, where waste wood (of course of specified size) could be used as a feed stock in gasifiers. 3. Wood Gasifier This system is meant for biomass having density in excess of 250 kg/m3. Theoretically, the ratio of air-tofuel required for the complete combustion of the wood, defined as stoichiometric combustion is 6:1 to 6.5:1, with the end products being CO 2 and H2O. Whereas, in gasification the combustion is carried at substoichiometric conditions with air-to-fuel ratio being 1.5:1 to 1.8:1. The product gas thus generated during the gasification process is combustible. This process is made possible in a device called gasified, in a limited supply of air. A gasifier system (Fig. 1) basically comprises of a reactor where the gas is generated, and is followed by a cooling and cleaning train which cools and cleans the gas. The clean combustible gas 118 is available for power generation in diesel-gen-set. Whereas, for thermal use the gas from the reactor can be directly fed to the combustor using an ejector. 4. Gasifier Specification 4.4 HIGH DENSITY ENERGY PLANTATIONS (HDEP). An Assessment of High Density Energy Plantations (HDEP) in Gujarat on Silvicultural, Ecological, Management and Economic Aspects Practice of planting forest tree species, particularly eucalypts, more density, which is termed as "High Density Energy Plantations (HDEP)", is based on the assumption that the factors defining maximum returns/density of planting are the availability of soil nutrients, sunlight and water. Under tropical conditions wherein sunlight is ample, with adequate water and soil nutrients, through application of irrigation and ferlilizers, 5 to 6 times more yield per unit area is expected. Density of planting, however, is governed by number of other factors viz. availability and economics of inputs like irrigation, fertilisers, growth hormones, insecticides, managerial skills, industrial base for utilisation of outputs, feasibility of diverting land and ground water resources which are immensely suitable for agriculture to forestry tree 119 crops etc. Projected Cost/benefits apparently show very attractive net returns and thus practice is gaining popularity. These projections do not, however stand close scrutiny and thus blind following of the practice is not advocated. Short and long rang impacts of intensive Euaclyptus tree crop management under semi-arid conditions are highlighted. A need for evolving appropriate technology packages to ensure optimum sustained yield under different agro-climatic edaphic conditions and providing basic nutrient requirements is indicated. In view of its long range impacts on the ecology, there is need for moderation in providing surh inputs. Approach of dense planting with high inputs is a step in right direction however, in view of its economic and policy implications the whole issue deed be carefully examined. 4.5 LAND AND BIOMASS AVAILABILITY FOR SUSTAINABLE BIO ENERGY. Biomass is a renewable resource, but two specific features distinguish it from all other renewable energy sources: The conversion efficiency of solar energy into chemical energy in plants is only 13% which implies significantly more land needed to indirectly harvest solar energy through terrestrial biomass cultivation than through more concentrated hydro, direct solar or wind energy systems11. Biomass is the “stuff of life” on this planet so that changes in biomass production, e.g. replacing natural vegetation with cultivated plant varieties, collecting forest residues, or improving crop yields, could have positive or negative impacts on ecosystem services, carbon balances, and human livelihoods. Thus, land is a fundamental issue closely related to biomass in general, and to bioenergy in particular. Therefore, the sustainability of bioenergy depends on the productivity of the land use12. As bioenergy can also be derived from biogenic residues and wastes stemming from various flows of biomass which has previously being grown, harvested and processed for non-energy purposes, the efficiency of converting such “secondary” biomass resources into useful energy products is another aspect of sustainable resource use needed to be addressed. Indicator: Land Use Efficiency The productivity of converting cultivated bioenergy feedstocks into useful energy products such as gaseous, liquid or solid bioenergy carriers, expressed in terms of available bioenergy carriers per hectare of cultivated area, should be set to a minimum net energy yield. As both cultivation and conversion systems evolve over time, these minimum requirements should be set to different levels for 2020 and 2030 to factor in the learning curve for yields and conversion efficiencies. 11 See Table 1 in the Annex for data on life-cycle land use figures for non-renewable and renewable electricity compared to biomass-derived electricity: The overall life-cycle land use intensity of bioelectricity systems (using 2 maize or short-rotation coppices as feedstock) is in the 2030 time horizon around 100-150 m /GJel, while direct 2 solar systems need 2 (CSP in Spain) to 3 m /GJel (PV in Germany), and onshore wind parks require a 120 2 maximum of 0.3 m /GJel. Fossil fuel and nuclear-based powerplants in 2030 will need again less land (0.02-0.1 2 m /GJel). Thus, the land use intensity of bioelectricity from biomass cultivation is approx. 50 times higher than direct solar, and 300 times higher than from onshore wind. 12 Possible effects of land use changes associated with the incremental production of bioenergy are discussed in Criterion 3 (see Section 0) with regard to GHG emissions. 121 Furthermore, crop yields depend on cultivation system, input levels, bioclimatic conditions, and overall land suitability. Thus, a further differentiation is needed to account for land productivity categories. In the Annex, results of respective calculations are given for various “settings” to produce liquid biofuels, and solid and gaseous bioenergy carriers13. From this data, the following minimum net energy yield requirements for bioenergy carriers were derived: Setting 2020 2030 unit smallholder, marginal/degraded land >25 >35 GJbio/ha plantation, marginal/degraded land >50 >75 GJbio/ha >100 >150 GJbio/ha plantation, arable land* Source: compilation by Oeko-Institut; * = mainly for intercropping, agro-forestry systems, etc. In calculating the net bioenergy yield (or bioenergy productivity), by- and coproducts along the bioenergy life cycles need to be taken into account14. Indicator: Secondary Resource Use Efficiency For bioenergy carriers stemming from the conversion of secondary biomass resources such as residues and wastes, a minimum efficiency, expressed in terms of the heating value of the bioenergy output divided by the heating value of the secondary resource input, should be set to increase the resource-efficient use of those resources. Taken into account the results of model calculations15, the minimum conversion efficiencies for biofuels should be set to 55 % by 2020, and 60% by 2030 for biodiesel, and 50 % by 2020 and 55 % by 2030 for ethanol, and 65 % for biomethane (2020 and 2030), again taking into account by- and co-products along the product life cycles. For conversion to solid bioenergy carriers (chips, pellets etc.), no minimum requirement is necessary, as their conversion efficiency is typically > 85%. Biomass Futures Criteria and Indicators for Sustainable Bioenergy Table 1: 122 Resource Criterion Indicator Metrics Sustainable Use Land Use Efficiency* GJbio/ha Secondary Resource Use Efficiency* % Conservation of land with significant biodiversity values no-go areas Land management without negative practices effects on biodiversity sustainable applied Biodiversity Climate Protection Life cycle GHG emissions incl. direct land use changes 75% Inclusion of GHG effects from indirect land use changes10 3.5 t CO2/ha/year Soil Quality Erosion zero erosion cultivation systems and practices Soil Organic Carbon Soil Nutrient Balance Water Use and Quality maintain SOC identifying Water Availability and Use Efficiency Water Quality maps soil “go” areas11 TARWR12 + BOD and P N, pesticide loadings SO2 equivalents13 g/GJbioenergy Particulate Emissions PM10 g/GJbioenergy Food Security Price and supply of national food basket €/t, t/a Airborne Emissions Social Use of Land changes in land tenure and access evidence14 Healthy Livelihoods and Labor Conditions Adherence to ILO Principles evidence Source: compiled from OEKO (2012); * = considering by- and co-products of bioenergy life cycles 123 CHAPTER NO.05 BIOFUELS 5.1 BIO-FUELS INTRODUCTION, A biofuel is a type of fuel whose energy is derived from biological carbon fixation. Biofuels include fuels derived from biomass conversion, as well as solid biomass, liquid fuels and various biogases. Biofuels are gaining increased public and scientific attention, driven by factors such as oil price hikes and the need for increased energy security. However, according to the European Environment Agency, biofuels do not address global warming concerns. Bioethanol is an alcohol made by fermentation, mostly from carbohydrates produced in sugar or starch crops such as corn or sugarcane. Cellulosic biomass, derived from non-food sources, such as trees and grasses, is also being developed as a feedstock for ethanol production. Ethanol can be used as a fuel for vehicles in its pure form, but it is usually used as a gasoline additive to increase octane and improve vehicle emissions. Bioethanol is widely used in the USA and in Brazil. Current plant design does not provide for converting the lignin portion of plant raw materials to fuel components by fermentation. Biodiesel is made from vegetable oils and animal fats. Biodiesel can be used as a fuel for vehicles in its pure form, but it is usually used as a diesel additive to reduce levels of particulates, carbon monoxide, and hydrocarbons from diesel-powered vehicles. Biodiesel is produced from oils or fats using transesterification and is the most common biofuel in Europe. In 2010, worldwide biofuel production reached 105 billion liters (28 billion gallons US), up 17% from 2009, and biofuels provided 2.7% of the world's fuels for road transport, a contribution largely made up of ethanol and biodiesel. Global ethanol fuel production reached 86 billion liters (23 billion gallons US) in 2010, with the United States and Brazil as the world's top producers, accounting together for 90% of global production. The world's largest biodiesel producer is the European Union, accounting for 53% of all biodiesel production in 2010. As of 2011, mandates for blending biofuels exist in 31 countries at the national level and in 29 states or provinces. According to the International Energy Agency, biofuels have the potential to meet more than a quarter of world demand for transportation fuels by 2050. Liquid fuels for transportation Most transportation fuels are liquids, because vehicles usually require high energy density, as occurs in liquids and solids. High power density can be provided most inexpensively by an internal combustion engine; these engines require clean-burning fuels, to keep the engine clean and minimize air pollution. The fuels that are easiest to burn cleanly are typically liquids and gases. Thus, liquids (and gases that can be stored in liquid form) meet the requirements of being both portable and clean-burning. Also, liquids and gases can be pumped, which means handling is easily mechanized, and thus less laborious. First-generation biofuels 'First-generation' or conventional biofuels are made from sugar, starch, or vegetable oil. 124 Bioalcohols Biologically produced alcohols, most commonly ethanol, and less commonly propanol and butanol, are produced by the action of microorganisms and enzymes through the fermentation of sugars or starches (easiest), or cellulose (which is more difficult). Biobutanol (also called biogasoline) is often claimed to provide a direct replacement for gasoline, because it can be used directly in a gasoline engine (in a similar way to biodiesel in diesel engines). Neat ethanol on the left (A), gasoline on Ethanol fuel is the most common biofuel worldwide, the right (G) at a filling station in Brazil particularly in Brazil. Alcohol fuels are produced by fermentation of sugars derived from wheat, corn, sugar beets, sugar cane, molasses and any sugar or starch from which alcoholic beverages can be made (such as potato and fruit waste, etc.). The ethanol production methods used are enzyme digestion (to release sugars from stored starches), fermentation of the sugars, distillation and drying. The distillation process requires significant energy input for heat (often unsustainable natural gas fossil fuel, but cellulosic biomass such as bagasse, the waste left after sugar cane is pressed to extract its juice, can also be used more sustainably). Ethanol can be used in petrol engines as a replacement for gasoline; it can be mixed with gasoline to any percentage. Most existing car petrol engines can run on blends of up to 15% bioethanol with petroleum/gasoline. Ethanol has a smaller energy density than that of gasoline; this means it takes more fuel (volume and mass) to produce the same amount of work. An advantage of ethanol (CH3CH2OH) is that it has a higher octane rating than ethanol-free gasoline available at roadside gas stations, which allows an increase of an engine's compression ratio for increased thermal efficiency. In high-altitude (thin air) locations, some states mandate a mix of gasoline and ethanol as a winter oxidizer to reduce atmospheric pollution emissions. Ethanol is also used to fuel bioethanol fireplaces. As they do not require a chimney and are "flueless", bioethanol fires are extremely useful for newly built homes and apartments without a flue. The downside to these fireplaces is their heat output is slightly less than electric heat or gas fires. In the current corn-to-ethanol production model in the United States, considering the total energy consumed by farm equipment, cultivation, planting, fertilizers, pesticides, herbicides, and fungicides made from petroleum, irrigation systems, harvesting, transport of feedstock to processing plants, fermentation, distillation, drying, transport to fuel terminals and retail pumps, and lower ethanol fuel energy content, the net energy content value added and delivered to consumers is very small. And, the net benefit (all things considered) does little to reduce imported oil and fossil fuels required to produce the ethanol. Although corn-to-ethanol and other food stocks have implications both in terms of world food prices and limited, yet positive, energy yield (in terms of energy delivered to customer/fossil fuels used), the technology has led to the development of cellulosic ethanol. According to a joint research agenda conducted through the US Department of Energy, the fossil energy ratios (FER) for cellulosic ethanol, corn ethanol, and gasoline are 10.3, 1.36, and 0.81, respectively. Even dry ethanol has roughly one-third lower energy content per unit of volume compared to gasoline, so larger (therefore heavier) fuel tanks are required to travel the same distance, or more fuel stops are required. With large current unsustainable, unscalable subsidies, ethanol fuel still costs much more per distance traveled than current high gasoline prices in the United States. Methanol is currently produced from natural gas, a nonrenewable fossil fuel. It can also be produced from biomass as biomethanol. The methanol economy is an alternative to the hydrogen economy, compared to today's hydrogen production from natural gas. 125 Butanol (C4H9OH) is formed by ABE fermentation (acetone, butanol, ethanol) and experimental modifications of the process show potentially high net energy gains with butanol as the only liquid product. Butanol will produce more energy and allegedly can be burned "straight" in existing gasoline engines (without modification to the engine or car), and is less corrosive and less watersoluble than ethanol, and could be distributed via existing infrastructures. DuPont and BP are working together to help develop butanol. E. coli strains have also been successfully engineered to produce butanol by hijacking their amino acid metabolism. Biodiesel Biodiesel is the most common biofuel in Europe. It is produced from oils or fats using transesterification and is a liquid similar in composition to fossil/mineral diesel. Chemically, it consists mostly of fatty acid methyl (or ethyl) esters (FAMEs). Feedstocks for biodiesel include animal fats, vegetable oils, soy, rapeseed, jatropha, mahua, mustard, flax, sunflower, palm oil, hemp, field pennycress, Pongamia pinnata and algae. Pure biodiesel (B100) is the lowestemission diesel fuel. Although liquefied petroleum gas and hydrogen have cleaner combustion, they are used to fuel much less efficient petrol engines and are not as widely available. Biodiesel can be used in any diesel engine when mixed with mineral diesel. In some countries, manufacturers cover their diesel engines under warranty for B100 use, although Volkswagen of Germany, for example, asks drivers to check by telephone with the VW environmental services department before switching to B100. B100 may become more viscous at lower temperatures, depending on the feedstock used. In most cases, biodiesel is compatible with In some countries, biodiesel is less diesel engines from 1994 onwards, which use 'Viton' (by expensive than conventional diesel. DuPont) synthetic rubber in their mechanical fuel injection systems. Electronically controlled 'common rail' and 'unit injector' type systems from the late 1990s onwards may only use biodiesel blended with conventional diesel fuel. These engines have finely metered and atomized multiple-stage injection systems that are very sensitive to the viscosity of the fuel. Many current-generation diesel engines are made so that they can run on B100 without altering the engine itself, although this depends on the fuel rail design. Since biodiesel is an effective solvent and cleans residues deposited by mineral diesel, engine filters may need to be replaced more often, as the biofuel dissolves old deposits in the fuel tank and pipes. It also effectively cleans the engine combustion chamber of carbon deposits, helping to maintain efficiency. In many European countries, a 5% biodiesel blend is widely used and is available at thousands of gas stations. Biodiesel is also an oxygenated fuel, meaning it contains a reduced amount of carbon and higher hydrogen and oxygen content than fossil diesel. This improves the combustion of biodiesel and reduces the particulate emissions from unburnt carbon. Biodiesel is also safe to handle and transport because it is as biodegradable as sugar, one-tenth as toxic as table salt, and has a high flash point of about 300°F (148°C) compared to petroleum diesel fuel, which has a flash point of 125°F (52°C). In the USA, more than 80% of commercial trucks and city buses run on diesel. The emerging US biodiesel market is estimated to have grown 200% from 2004 to 2005. "By the end of 2006 biodiesel production was estimated to increase fourfold [from 2004] to more than" 1 billion US gallons (3,800,000 m3). 126 Green diesel Green diesel is produced through hydrocracking biological oil feedstocks, such as vegetable oils and animal fats. Hydrocracking is a refinery method that uses elevated temperatures and pressure in the presence of a catalyst to break down larger molecules, such as those found in vegetable oils, into shorter hydrocarbon chains used in diesel engines. It may also be called renewable diesel, hydrotreated vegetable oil or hydrogen-derived renewable diesel. Green diesel has the same chemical properties as petroleum-based diesel. It does not require new engines, pipelines or infrastructure to distribute and use, but has not been produced at a cost that is competitive with petroleum. Gasoline versions are also being developed. Green diesel is being developed in Louisiana and Singapore by ConocoPhillips, Neste Oil, Valero, Dynamic Fuels, and Honeywell UOP. Vegetable oil Straight unmodified edible vegetable oil is generally not used as fuel, but lower-quality oil can and has been used for this purpose. Used vegetable oil is increasingly being processed into biodiesel, or (more rarely) cleaned of water and particulates and used as a fuel. Also here, as with 100% biodiesel (B100), to ensure the fuel injectors atomize the vegetable oil in the correct pattern for efficient combustion, vegetable oil fuel must be heated to reduce its viscosity to that of diesel, either by electric coils or heat exchangers. This is easier in warm or temperate climates. Big corporations like MAN B&W Diesel, Wärtsilä, and Deutz AG, as well as a number of smaller companies, such as Elsbett, offer engines that are compatible with straight vegetable oil, without the need for after-market modifications. Vegetable oil can also be used in many older diesel engines that do not use common rail or unit injection electronic diesel injection systems. Due to the design of the combustion chambers in indirect injection engines, these are the best engines for use with vegetable oil. This system allows the relatively larger oil molecules more time to burn. Some older engines, especially Mercedes, are driven experimentally by enthusiasts without any conversion, a handful of drivers have experienced limited success with earlier pre-"Pumpe Duse" VW TDI engines and other similar engines with direct injection. Several companies, such as Elsbett or Wolf, have developed professional conversion kits and successfully installed Filtered waste vegetable oil hundreds of them over the last decades. Oils and fats can be hydrogenated to give a diesel substitute. The resulting product is a straight-chain hydrocarbon with a high cetane number, low in aromatics and sulfur and does not contain oxygen. Hydrogenated oils can be blended with diesel in all proportions. They have several advantages over biodiesel, including good performance at low temperatures, no storage stability problems and no susceptibility to microbial attack. Bioethers Bioethers (also referred to as fuel ethers or oxygenated fuels) are cost-effective compounds that act as octane rating enhancers. They also enhance engine performance, whilst significantly reducing engine wear and toxic exhaust emissions. Greatly reducing the amount of ground-level ozone, they contribute to air quality. 127 Biogas Biogas is methane produced by the process of anaerobic digestion of organic material by anaerobes. It can be produced either from biodegradable waste materials or by the use of energy crops fed into anaerobic digesters to supplement gas yields. The solid byproduct, digestate, can be used as a biofuel or a fertilizer. Biogas can be recovered from mechanical biological treatment waste processing systems. Note:Landfill gas, a less clean form of biogas, is produced in landfills through naturally occurring anaerobic digestion. If it escapes into the atmosphere, it is a potential greenhouse gas. Farmers can produce biogas from manure from their cattle Pipes carrying biogas by using anaerobic digesters. Syngas Syngas, a mixture of carbon monoxide, hydrogen and other hydrocarbons, is produced by partial combustion of biomass, that is, combustion with an amount of oxygen that is not sufficient to convert the biomass completely to carbon dioxide and water. Before partial combustion, the biomass is dried, and sometimes pyrolysed. The resulting gas mixture, syngas, is more efficient than direct combustion of the original biofuel; more of the energy contained in the fuel is extracted. Syngas may be burned directly in internal combustion engines, turbines or high-temperature fuel cells. The wood gas generator, a wood-fueled gasification reactor, can be connected to an internal combustion engine. Syngas can be used to produce methanol, DME and hydrogen, or converted via the FischerTropsch process to produce a diesel substitute, or a mixture of alcohols that can be blended into gasoline. Gasification normally relies on temperatures greater than 700°C. Lower-temperature gasification is desirable when co-producing biochar, but results in syngas polluted with tar. Solid biofuels Examples include wood, sawdust, grass trimmings, domestic refuse, charcoal, agricultural waste, nonfood energy crops, and dried manure. When raw biomass is already in a suitable form (such as firewood), it can burn directly in a stove or furnace to provide heat or raise steam. When raw biomass is in an inconvenient form (such as sawdust, wood chips, grass, urban waste wood, agricultural residues), the typical process is to densify the biomass. This process includes grinding the raw biomass to an appropriate particulate size (known as hogfuel), which, depending on the densification type, can be from 1 to 3 cm (0 to 1 in), which is then concentrated into a fuel product. The current processes produce wood pellets, cubes, or pucks. The pellet process is most common in Europe, and is typically a pure wood product. The other types of densification are larger in size compared to a pellet, and are compatible with a broad range of input feedstocks. The resulting densified fuel is easier to transport and feed into thermal generation systems, such as boilers. One of the advantages of solid biomass fuel is that it is often a byproduct, residue or waste-product of other processes, such as farming, animal husbandry and forestry. In theory, this means fuel and food production do not compete for resources, although this is not always the case. A problem with the combustion of raw biomass is that it emits considerable amounts of pollutants, such as particulates and polycyclic aromatic hydrocarbons. Even modern pellet boilers generate much more pollutants than oil or natural gas boilers. Pellets made from agricultural residues are usually worse than wood pellets, producing much larger emissions of dioxins and chlorophenols. Notwithstanding the above noted study, numerous studies have shown biomass fuels have significantly less impact on the environment than fossil based fuels. Of note is the US Department of 128 Energy Laboratory, operated by Midwest Research Institute Biomass Power and Conventional Fossil Systems with and without CO2 Sequestration – Comparing the Energy Balance, Greenhouse Gas Emissions and Economics Study. Power generation emits significant amounts of greenhouse gases (GHGs), mainly carbon dioxide (CO2). Sequestering CO2 from the power plant flue gas can significantly reduce the GHGs from the power plant itself, but this is not the total picture. CO 2 capture and sequestration consumes additional energy, thus lowering the plant's fuel-to-electricity efficiency. To compensate for this, more fossil fuel must be procured and consumed to make up for lost capacity. Taking this into consideration, the global warming potential (GWP), which is a combination of CO 2, methane (CH4), and nitrous oxide (N2O) emissions, and energy balance of the system need to be examined using a life cycle assessment. This takes into account the upstream processes which remain constant after CO2 sequestration, as well as the steps required for additional power generation. Firing biomass instead of coal led to a 148% reduction in GWP. A derivative of solid biofuel is biochar, which is produced by biomass pyrolysis. Biochar made from agricultural waste can substitute for wood charcoal. As wood stock becomes scarce, this alternative is gaining ground. In eastern Democratic Republic of Congo, for example, biomass briquettes are being marketed as an alternative to charcoal to protect Virunga National Park from deforestation associated with charcoal production. What Is Biodiesel? Biodiesel is an alternative fuel similar to conventional or ‘fossil’ diesel. Biodiesel can be produced from straight vegetable oil, animal oil/fats, tallow and waste cooking oil. The process used to convert these oils to Biodiesel is called transesterification. This process is described in more detail below. The largest possible source of suitable oil comes from oil crops such as rapeseed, palm or soybean. In the UK rapeseed represents the greatest potential for biodiesel production. Most biodiesel produced at present is produced from waste vegetable oil sourced from restaurants, chip shops, industrial food producers such as Birdseye etc. Though oil straight from the agricultural industry represents the greatest potential source it is not being produced commercially simply because the raw oil is too expensive. After the cost of converting it to biodiesel has been added on it is simply too expensive to compete with fossil diesel. Waste vegetable oil can often be sourced for free or sourced already treated for a small price. (The waste oil must be treated before conversion to biodiesel to remove impurities). The result is Biodiesel produced from waste vegetable oil can compete with fossil diesel. More about the cost of biodiesel and how factors such as duty play an important role can be found here. What are the benefits of Biodiesel? Biodiesel has many environmentally beneficial properties. The main benefit of biodiesel is that it can be described as ‘carbon neutral’. This means that the fuel produces no net output of carbon in the form of carbon dioxide (CO2). This effect occurs because when the oil crop grows it absorbs the same amount of CO2 as is released when the fuel is combusted. In fact this is not completely accurate as CO2 is released during the production of the fertilizer required to fertilize the fields in which the oil crops are grown. Fertilizer production is not the only source of pollution associated with the production of biodiesel, other sources include the esterification process, the solvent extraction of the oil, refining, drying and transporting. All these processes require an energy input either in the form of electricity or from a fuel, both of which will generally result in the release of green house gases. To properly assess the impact of all these sources requires use of a technique called life cycle analysis. Our section on LCA looks closer at this analysis. Biodiesel is rapidly biodegradable and completely non-toxic, meaning spillages represent far less of a risk than fossil diesel spillages. Biodiesel has a higher flash point than fossil diesel and so is safer in the event of a crash. Biodiesel Production 129 As mentioned above biodiesel can be produced from straight vegetable oil, animal oil/fats, tallow and waste oils. There are three basic routes to biodiesel production from oils and fats: Base catalyzed transesterification of the oil. Direct acid catalyzed transesterification of the oil. Conversion of the oil to its fatty acids and then to biodiesel. Almost all biodiesel is produced using base catalyzed transesterification as it is the most economical process requiring only low temperatures and pressures and producing a 98% conversion yield. For this reason only this process will be described in this report. The Transesterification process is the reaction of a triglyceride (fat/oil) with an alcohol to form esters and glycerol. A triglyceride has a glycerine molecule as its base with three long chain fatty acids attached. The characteristics of the fat are determined by the nature of the fatty acids attached to the glycerine. The nature of the fatty acids can in turn affect the characteristics of the biodiesel. During the esterification process, the triglyceride is reacted with alcohol in the presence of a catalyst, usually a strong alkaline like sodium hydroxide. The alcohol reacts with the fatty acids to form the mono-alkyl ester, or biodiesel and crude glycerol. In most production methanol or ethanol is the alcohol used (methanol produces methyl esters, ethanol produces ethyl esters) and is base catalysed by either potassium or sodium hydroxide. Potassium hydroxide has been found to be more suitable for the ethyl ester biodiesel production, either base can be used for the methyl ester. A common product of the transesterification process is Rape Methyl Ester (RME) produced from raw rapeseed oil reacted with methanol. The figure below shows the chemical process for methyl ester biodiesel. The reaction between the fat or oil and the alcohol is a reversible reaction and so the alcohol must be added in excess to drive the reaction towards the right and ensure complete conversion. The products of the reaction are the biodiesel itself and glycerol. A successful transesterification reaction is signified by the separation of the ester and glycerol layers after the reaction time. The heavier, co-product, glycerol settles out and may be sold as it is or it may be purified for use in other industries, e.g. the pharmaceutical, cosmetics etc. Straight vegetable oil (SVO) can be used directly as a fossil diesel substitute however using this fuel can lead to some fairly serious engine problems. Due to its relatively high viscosity SVO leads to poor atomisation of the fuel, incomplete combustion, coking of the fuel injectors, ring carbonisation, and accumulation of fuel in the lubricating oil. The best method for solving these problems is the transesterification of the oil. The engine combustion benefits of the transesterification of the oil are: Lowered viscosity Complete removal of the glycerides Lowered boiling point Lowered flash point Lowered pour point Production Process 130 An example of a simple production flow chart is proved below with a brief explanation of each step. Mixing of alcohol and catalyst The catalyst is typically sodium hydroxide (caustic soda) or potassium hydroxide (potash). It is dissolved in the alcohol using a standard agitator or mixer. Reaction. The alcohol/catalyst mix is then charged into a closed reaction vessel and the oil or fat is added. The system from here on is totally closed to the atmosphere to prevent the loss of alcohol. The reaction mix is kept just above the boiling point of the alcohol (around 160 °F) to speed up the reaction and the reaction takes place. Recommended reaction time varies from 1 to 8 hours, and some systems recommend the reaction take place at room temperature. Excess alcohol is normally used to ensure total conversion of the fat or oil to its esters. Care must be taken to monitor the amount of water and free fatty acids in the incoming oil or fat. If the free fatty acid level or water level is too high it may cause problems with soap formation and the separation of the glycerin by-product downstream. Separation Once the reaction is complete, two major products exist: glycerin and biodiesel. Each has a substantial amount of the excess methanol that was used in the reaction. The reacted mixture is sometimes neutralized at this step if needed. The glycerin phase is much more dense than biodiesel phase and the two can be gravity separated with glycerin simply drawn off the bottom of the settling vessel. In some cases, a centrifuge is used to separate the two materials faster. Alcohol Removal Once the glycerin and biodiesel phases have been separated, the excess alcohol in each phase is removed with a flash evaporation process or by distillation. In others systems, the alcohol is removed and the mixture neutralized before the glycerin and esters have been separated. In either case, the alcohol is recovered using distillation equipment and is re-used. Care must be taken to ensure no water accumulates in the recovered alcohol stream. Glycerin Neutralization The glycerin by-product contains unused catalyst and soaps that are neutralized with an acid and sent to storage as crude glycerin. In some cases the salt formed during this phase is recovered for use as fertilizer. In most cases the salt is left in the glycerin. Water and alcohol are removed to produce 80-88% pure glycerin that is ready to be sold as crude glycerin. In more sophisticated operations, the glycerin is distilled to 99% or higher purity and sold into the cosmetic and pharmaceutical markets. Methyl Ester Wash Once separated from the glycerin, the biodiesel is sometimes purified by washing gently with warm water to remove residual catalyst or soaps, dried, and sent to storage. In some processes this step is 131 unnecessary. This is normally the end of the production process resulting in a clear amber-yellow liquid with a viscosity similar to petrodiesel. In some systems the biodiesel is distilled in an additional step to remove small amounts of color bodies to produce a colorless biodiesel. Product Quality Prior to use as a commercial fuel, the finished biodiesel must be analyzed using sophisticated analytical equipment to ensure it meets any required specifications. The most important aspects of biodiesel production to ensure trouble free operation in diesel engines are: Complete Reaction Removal of Glycerin Removal of Catalyst Removal of Alcohol Absence of Free Fatty Acids Rural fuelwood: Significant relationships Amulya Kumar N. Reddy 1. Introduction Solar energy collected by plants and stored, in the form of biomass, particularly as wood, is a major source of energy in developing countries, as it war in the preindustrial past of developed countries. But wood, is a renewable sources only when the rate at which it is depleted is less than the rate at which it is regenerated. This is certainly not the case in most developing countries where wood is a rapidly dwindling resources due to the multiplicity of its uses and the escalation in the magnitude of its consumption resulting from the burgeoning populations. Attention has therefore been focussed on programmes for the regeneration of wood resources, but very few of those have been successful. The reasons for the failure of these programmes are many, but one important reason is the fact that wood is involved in a number of relationships and there is insufficient appreciation of either the nature or extent of these relationships. The aim of this paper, therefore, is to develop a scheme which permits the display and description of (a) the relationships involving the use of wood and (b) the potentialities of wood as a resources in the economy. 2. The ecosystem approach One of the most useful ways in which the inter-relationships involving wood can be portrayed is through the ecosystem approach in which the term ecosystem is used to designate any area of nature that includes living organism and non-living substances interacting to produce an exchange of materials between the living and non-living parts. The advantage of the ecosystem approach in that it clearly reveals the entities involved in the functioning of the ecosystem, their interactions, the flows of materials, nutrients and energy, and above all, the environmental constraints on economic activities as well au the impact of these activities upon, the environment. If the depletion and regeneration of wood resources is being considered in a particular geographical region, then that region becomes the "area of nature" defining the spatial aspect of the ecosystem. Further, if the society of human beings in that area is differentiated from other living organisms and assigned special attention, then a human ecosystem has been defined. 132 There are several types of human ecosystems, but it is the agricultural ecosystem in developing countries which is particularly relevant to this paper because it involves wood resources to a significant extent. In additional, there are the two types of forest ecosystems: one type which involves people living in forests and the other type in which forests are linked to wood-based industry, but these will not be discussed further because they are lops relevant to fuelwood projects than agricultural ecosystems. 3. Agricultural ecosystems The essential characteristic of an agricultural ecosystem is that it includes a human settlement engaged in the production of food. One widely prevalent version of such a settlement is a village. Unfortunately, there have been few investigations of village agricultural ecosystems, but a recent study of Ungra in South India (Ravindranath et al 1981, Reddy 1981) provides a useful basis for the present paper which aims at the development of a methodology rather than a universal analysis. The study provided quantitative information inter alia on the pattern of land-use (Table 2-1) and cropping (Table 2-2), the above-ground plant biomass productivities (Table 2-3), the disaggregation of the above-ground plant biomass into components such as grain, straw, etc. (Table 2-4), the model of utilization of these components (Figure 2-1), the fodder consumption by live-stock (Table 2-5) and the sources of fuel (Table 2-6).1 From this information, it is possible (Ravindranath et al 1981) to represent the operation of the Ungra village agricultural ecosystem by means of the usual type of diagram with the symbols used, by Odum (Odum, 1971). 1 The tables and Figure 2-1 appear at the end of the paper. Such an ecosystem diagram helps to reveal clearly the complex inter-relationships between human beings, livestock, land, energy and water, and water, and between food, fuel, fodder and fertilizer. But the inclusion of the Ungra ecosystem diagram in the present paper would divert attention to a great deal of information directly relevant to a discussion of wood resources. In addition, it would the detailed description of a specific village with all its peculiar features, for instance the absence of fuel exports. Nevertheless, the understanding derived from the Ungra ecosystem is useful in evolving a simplified generalized diagram which can then be used to discuss the role of wood in typical village agricultural ecosystems. The procedure will consist of considering all the ecosystem components and activities land, water, nutrients, inanimate and animal, energy, fodder, cooking, trees, building, etc.) one by one and discussing the interactions between fuelwood and each of these components or activities. This understanding of pair-wise interactions will, then be integrated into an ecosystem diagram which displays all the complex and varied inter-relationships involving fuelwood. What follows therefore is the step-by-step development of suck a diagram and a description of the ecosystem relationships involving wood. It must be stressed, however, that the ensuing analysis is derived from an understanding of the Ungra ecosystem. Hence, it refers mainly to India, but it can be applied after suitable modifications to other parts of the world. 4. Fuelwood projects and development The goal of fuelwood projects is to advance development, which is viewed as a process of satisfying the basic needs of human beings, particularly the needs of the neediest, in a self-reliant, ecologically sound manner. Hence it is vital to consider wood resources in their relationship to basic needs. Taking the basic needs as food, clothing and shelter, the following points are obvious. 133 (i) Land must be allocated for food and other crops. (ii) In addition to land, the growing of crops requires water, nutrients and energy. (iii) Traditional agriculture is based on human energy, but in India, and much of Asia, the energy for many critical agricultural operations such as ploughing comes from draught animals. (iv) Apart from the grain from crops, human beings also consume milk and meat; which means that livestock-rearing is an integral part of meeting food requirements. (v) Draught animals and other livestock require fodder, and this fodder comes from crop residues and/or grazing in pasture land; hence, pasture lands and fodder production are crucial. (vi) Most food is cooked, and the energy required for cooking is obtained primarily from fuelwood, but agricultural residues and cattle dung are also used. (vii) Fuelwood comes predominantly from trees which grow in special woodlots and/or along the sides of fields or roads. Forests may also become a fuelwood sources if they are close enough to the villages. (viii) The wood from such trees is used not only as fuel for cooking, but also as fuel in many industries and as a sources of lumber. (ix) One of the important categories of industries which depends upon fuelwood is that involving the production of bricks and tiles for building to satisfy the basic need for shelter. Another fuelwood-using industry is pottery which provides utensils for cooking. (x) Fuelwood, lumber and fuelwood-based products such as bricks are often exported to or imported from other agricultural ecosystems and towns and cities. (xi) Apart from providing fuel, trees fulfil many other functions - they give shade, shelter, edible nuts, oilseeds, medicines, and provide for many other needs. There are a number of relationships, synergisms and conflicts involved in the situation which merit elaboration because they have a major influence on the outcome of fuelwood projects. Figure 2-2: Land and fuelwood 134 Figure 2-3: Water and fuelwood 135 5. Land and fuelwood In an agricultural ecosystem, there are several demands upon the available land it has to be used for housing and other parts of the human settlement, some in submerged by natural and artificial water bodies, but the bulk of the land is devoted to crops and pastures (Figure 2-2). The traditional land-utilization practice (which embodies a great deal of wisdom) is to have woodlots only on non-arable land. Since this practice does not lead to any reduction in the land set apart for crops and pastures, it prevents the development of any conflict between food and fodder, on the one hand and fuel on the other. In case non-arable land is unavailable, the growth of trees has to be restricted to the borders of fields, water-bodies or roads. If however, the fuelwood output of these "border trees" is inadequate to meet the requirements of the ecosystem, then attempts to allocate land for separate woodlots will result in a reduction of the area available for cropland and pastureland, and therefore in a conflict between the need for fuelwood and the requirement of food and fodder. Several possible ways of resolving the conflict between woodlots and land, for crops and pastures can be considered. (i) The fuelwood requirements can be eliminated by the adoption of alternative fuel(s) or reduced by improving the efficiency with which fuelwood is used. (ii) The area set apart for pastureland can be reduced through the cultivation of highproductivity fodder species. 136 (iii) Pastureland can be put to multiple use by combining the growth of fodder species and fuelwood trees in two-tier forests where the lower tier is devoted to fodder and the upper tier to fuelwood. (iv) The land devoted to non-food crops can be reduced and the corresponding land used for woodlots. In the absence of such deliberate measures, what generally happens is that land which is under tree cover is cleared for cultivation. This removal of tree cover leads to soil erosion - and, in extreme cases, to desertification - and therefore to a deterioration in the quality of cropland. Thus, as is well known, deforestation to promote food production may frustrate the very capacity to produce foods The result is the same when the deforestation is carried out to secure fuelwood, i.e., the satisfaction of the need for fuelwood can lead to a diminution in the quality of land. 6. Water and fuelwood (figure 2-3) Crop production is generally water-limited. This water limitation may be due to the seasonality and insufficiency of rainfall and/or the restricted availability of groundwater and/or the inadequacy of energy to transfer the water from where it in available to where it is required. If ground-water resources are limited, then an increase in the supply of water can be achieved by importing water through irrigation projects or by harvesting rain-water, i.e. by collecting rain-water from micro-catchments and storing it in tanks and ponds. The import of water depends upon decisions and actions taken outside the ecosystem, but water-harvesting within the ecosystem implies an increase in the area occupied by water-bodies. This increase may take place at the expense of land useful for woodlots - thus there is a possibility of conflict between water-harvesting and woodlots, analogous to the conflicts on a large scale between dame and forests. If, however, ground water is available, then energy must to utilized to lift the water. This energy must either be imported from sources outside the ecosystem with all the attendant transmission/transport costs of electricity/oil or be made available from within the ecosystem through the supply of animate energy (for example, animal power) or biomass-derived fuels, or the harnessing of wind energy. If these local sources of energy are used for water-lifting, then there can be conflict between the energy needs of water-lifting and those of other tasks. If fuelwood projects are based on irrigation, the above-mentioned conflicts between water-harvesting and woodlots and between the energy requirements of water-lifting and other energy needs are aggravated. In such situations, the resolution of these conflicts can be achieved by ensuring that the irrigation of fuelwood trees satisfies the following conditions: Figure 2-5: Inanimate energy and fuelwood 137 Figure 2-4: Nutrients and fuelwood (i) The extra volume of harvested rain-water required for woodlot irrigation should be obtained without increasing the area of water-bodies, i.e., the depth of these waterbodies should be increased, or if the area of these water-bodies increases when the volume of harvested water is increased to permit woodlot irrigation, the extra water should be used to obtain, apart from greater fuelwood production, a simultaneous increase of crop and/or fodder yields so that these increased yields compensate for any loss of cropland and/or pastureland. 138 (ii) If fuelwood trees are irrigated with ground-water, then the energy for the waterlifting should be derived by energy conservation measures, i.e., by an increased use of the same draught animals and/or more efficient use of the inanimate energy already being utilized in the ecosystem so that the delivered energy for other tasks is not reduced, or by an increased supply of energy in the form of fuelwood. There can also be the following synergism between water-harvesting and woodlots. Woodlots tend to reduce water run-off and increase the recharge of stored/ground water. They generally make the water balance more favourable, particularly with the use of tree species which draw deep water. 7. Nutrients and fuelwood (figure 2-4) The supply of nutrients to land use for growing crops and/or fodder and/or trees, or at least the replenishment of nutrients removed from this land, is essential for, sustainable agriculture and/or silviculture. In traditional village agricultural ecosystems, only organic sources are used: (i) farmyard manure obtained by composting animal waste, (ii) green manure from leguminous crops and/or from leaves which are the nitrogen - and the phosphorus - rich parts of plants, and (iii) household wastes. A dependence on farmyard manure implies the existence of livestock in the ecosystem which in turn creates a demand for fodder and therefore for land if the fodder comes from pasture land. Thus in an ecoystem depending upon farmyard manure, there can be a conflict between nutrients and land. If, however, the dependence is on green manure which can also be consumed by livestock as fodder, then there is the possibility of a conflict between nutrients and fodder. Under these circumstances, the introduction of fuelwood projects requiring the use of organic nutrients is likely to aggravate the situation and lead to a conflict between organic nutrients and fuelwood trees. The main mechanism for resolving these conflicts is to import the nutrients which may be required for fuelwood projects. On the other hand, there is a synergism &rising from the "nutrient pump effect" in which deep-rooted trees bring up nutrients. 8. Inanimate energy and fuelwood (figure 2-5) The only sources of inanimate energy available within traditional village agricultural ecosystems are fuelwood, agricultural wastes and cattle-dung-cakes. All these sources are used in varying proportions an fuels to provide heat energy. Since the combustion of dung-cakes leads to the vaporization of nitrogen and phosphorus, there can be a conflict between fuel and fertilizer, and since the burning of many agricultural residues deprives cattle of sustenance, there in a possibility of conflicts between fuel and fodder. The only traditional source of inanimate energy which does not directly reduce fertilizer and fodder use is fuelwood, a ligneous material. But, the problem with the traditional fuelwood technologies used in the agriculture of developing countries is that they cannot provide mechanical energy for the operation of stationary and/or mobile equipment.1 Therefore, the requirements of stationary and/or mobile power must be met with human energy and/or animal energy and/or electricity/oil generally imported from outside the ecosystem. Dependence on animal energy increases fodder requirements but at the same time reduces electricity/oil imports. But, the power output of draught animals in limited to about 0.5 HP, which means that tasks requiring greater power inputs will necessarily require the substitution of animal energy with, imported electricity/oil. 139 1 In the early stages of the industrialization of the developed countries, wood-fired steam/stirling engines were often used. Figure 2-6 Animal energy and fuelwood All this means that if fuelwood trees are going to be irrigated with current technologies of lifting groundwater, then there will be an increase in the requirements of animal energy and/or imported electricity/oil leading respectively to increased fodder requirements and/or decreased self-sufficiency of the ecosystem. One of the possible ways out of this dilemma is to drive waterpumps with engines running with wood-based fuels such as producer gas (mainly a mixture of carbon monoxide and hydrogen) or methanol (obtained by the conversion of producer gas). Another alternative is to operate diesel-engine-driven pumpsets with biogas (a mixture of methane and carbon dioxide) obtained by the aerobic fermentation of animal wastes and/or other non-ligneous cellulosic materials. 9. Animal energy and fuelwood (figure 2-6) Draught animals are the main source of power for stationary and mobile operations when the power requirements exceed the output of human beings. In particular, draught animals supply the power for: (i) agricultural operations such an ploughing, harrowing, water-lifting, and threshing, (ii) transport with animal-drawn vehicles, and (iii) many industrial operations such an crushing, grinding, etc. The only way of replacing animal power is with engines in mobile equipment and with engines and/or motors in stationary equipment. While this mechanization has permitted an increase in power beyond the limits of animals, it has created a demand for oil and/or electricity which invariably have to be imported from outside the ecosystem. In addition, 140 whereas a single draught animal or pair of such animals can accomplish all the agricultural, transport and industrial functions mentioned above, it is usual to have separate items of specialized equipment for each -task or class of tasks. Thus, the replacement of animal power usually requires an array of equipment. As oil-fuelled and electrical equipment take over the functions of animals, the load factor on animals goes down. Nevertheless, until all the mechanical functions of animals are taken over by machines, draught animals must be maintained to carry out the remaining functions. In these circumstances, the traditional approach is to give the draught animals just enough fodder to enable them to carry out the residual tasks, bat despite this, the input cannot go below maintenance levels. At these dietary levels, the draught animals deliver far less power than what they are capable of with proper feeding. Thus, the partial, as opposed to complete, substitution of animal power by machines may increase the productivity of certain operations, but it does not eliminate the need, for maintenance fodder for draught animals and with such a maintenance diet their power output and productivity are significantly reduced. Animal energy, therefore, promotes the self-sufficiency of the ecosystem with respect to mechanical power but probably achieves this goal at the expense of productivity; and machines driven with inanimate energy may facilitate greater productivity but lead to greater dependence on the external environment (of the ecosystem) for oil, and/or electricity. This dilemma of animal power vs mechanization can be resolved in several ways. In situations where the use of animal power is continued, its efficiency can be improved by better design and/or conditions. For example, the productivity of ploughing with draught animals can be enhanced by increasing the soil moisture - thin in a synergism between animal energy and water. Another important approach is to identify those situations whore the replacement of animal power with machines it; justified and to drive these machines with wood-based fuels (producer gas and/or methanol) produced from fuelwood. This would be tantamount to fuelwood replacing animal energy. Figure 2-7 Fodder and fuelwood 141 From the transport point of view, however, animal-driven vehicles can provide lowcost transportation for fuelwood. In fact, it appears that, within specific distance regimes - for example about 0.4 kms. to 3.0 kms. in a particular study made in South India (Jagadish, 1979) - animal-drawn vehicles are more economical than either trucks or tractors for fuelwood transport. This implies that animal energy can assist the distribution aspect of the fuelwood system. 10. Fodder and fuelwood (figure 2-7) The food requirements of the human beings in the ecosystem include, in addition to grain, many non-grain components such as milk, meat, vegetables, etc. The grain components have to be produced by agriculture which requires draught power if it in based, as it invariably in, on tillage. An already mentioned, the draught power in traditional agricultural ecosystems comes from draught animals or human beings. The non-grain components of food include dairy products such as milk, butter, cheese and eggs as well as meat. This means that agricultural ecosystems must support, in addition to draught animals, other non-draught categories of livestock such as cows, buffaloes, goats, sheep, pigs and chickens. In other words livestock are reared to meet the requirements of both energy and food. Through its ability to provide alternative fuels for engines, fuelwood production can diminish the energy contribution demanded of livestock, but the food contribution still remains, necessitating the rearing of livestock. Livestock rearing, however, generates a demand for fodder. If arboreal forage is not considered part of the fodder system, there are two traditional sources of fodder, agricultural residues and pastureland. The contribution of these two fodder sources to the total fodder requirement varies very widely from ecosystem to ecosystem ranging 142 from one extreme where all the fodder requirements are met by grazing in pastureland to the opposite extreme where fodder is supplied to stable-bound livestock. In situations where agricultural residues contribute significantly to the total fodder requirements by virtue of their digestibility, it in important that crop varieties are selected both for their grain and straw output. This seems to have been the case with the traditional crop varieties, but the modern dwarf varieties of the green revolution achieve high yields of grain at the expense of the stalk portion which in often used for livestock. This implies a greater demand for fodder from pastureland, and this demand way lead to a reduction in the area available for fuelwood production. Thus, highyielding varieties may load to a conflict between food and fodder requirements, which In turn may result in a conflict between fodder and fuel. (Incidentally, ouch direct conflicts are avoided in the agricultural systems of the developed countries because they have virtually eliminated their requirements of draught animal power - and the associated fodder requirements - through inputs of inanimate energy in the form of fossil fuel, and because they import significant quantities of livestock feed from the developing countries.) Even with traditional crop varieties which produce fodder along with grain, there is strong demand in village agricultural ecosystems for pastureland. In fact, the netting apart of land, for livestock grazing was a common feature of these ecosystems in the not too distant past, but increasingly pastureland has been converted into cropland due to pressures of population and land distribution and, as a result, the prospects of using arable land for woodlots have become bleak. One approach to the resolution of the conflict between food and fodder on the one hand and fuel on the other is to restrict woodlots only to non-arable land. Even when this in done, fuelwood trees suffer from very high "infant mortality" because they become victims of grazing livestock during their seedling and sapling stages of growth. In other words, the conflict between fodder and fuel can have a destructive impact on woodlots on non-arable land during the early stages of growth of fuelwood trees when they are extremely vulnerable to grazing. In this context, the rational approach is to plan simultaneously for both fodder and fuel requirements through a two-tier forest and first to ensure fodder production on a renewable basin before attempting to protect fuelwood seedlings/saplings from grazing. Figure 2-8 Cooking and fuelwood 143 11. Cooking and fuelwood (figure 2-8) Cooking is done almost exclusively with fuelwood (either directly or after conversion into charcoal), agricultural wastes and dung-cakes. As-already pointed out, the combustion of agricultural wastes leads to the lose of fodder unless the waste is not edible by livestock (e.g. sugarcane bagasse) and the burning of dung-cakes results in the lose of nutrients. In fact, it appears that villagers use dung-cakes as cooking fuel only when fuelwood is not available or not conveniently accessible. (There are, however, regions where dung-cakes are used in order to have a very slow-burning fuel, e.g., to thicken milk). Thus, the general preference for fuelwood has a rational basis because it does not involve direct conflicts with fodder and fertilizer requirements. There are many aspects of the ecological implications of the use of fuelwood for cooking. If the fuelwood for cooking in the ecosystem is obtained predominantly in the form of fallen twigs and branches, i.e. without tree felling, - and this is the case in many regions (Astra 1981) - then the fuelwood resources are being used in a renewable manner. Thus, cooking in the ecosystem with internally available fuelwood resources may not be as responsible for deforestation as is sometimes made out. Butt as soon as the fuelwood has to be transported from or to distances which are far from the ecosystem (which is what happens in the case of fuelwood imports or exports), the preference is for a denser form of fuel, in other words for logo or for charcoal made from such logs. Hence, one of the justifications for planning and establishing fuelwood projects is to increase the supply of fuelwood and avert the catastrophe of not being able to cock the food even if food production can keep pace with population. At the same time, however, attention is being focussed on the fuelwood utilization question. Studies of the performance of wood stoves are coming up with efficiency values of under 10%, and typically 5%, which means that 90-95% of the heat energy available in fuelwood is being wasted (Geller 1981, De Lepeleire et al., 1981). The initial hopes that the efficiency of the wood stoves of technologically simple peoples can be radically improved are diminishing. It now appears that, barring a 144 breakthrough, one cannot expect more than a doubling or trebling of the efficiency of firewood stoves, and that the ideal stove may well be one in which the wood is converted in situ into producer gas which then becomes the cooking fuel. None of the so-called "improved stoves" approach this ideal and many, in fact, lead to enhanced firewood consumption when subjected to rigorous testing procedures. All this provides a rational technical basis for villagers to reject the "improved stoves". In addition, it is a moot point whether the poorer strata will ever consider wood-burning stoves (even costlier and improved ones!) as an elevation in their standard of life when they are aware of the fact that the more affluent sections of their society always prefer cleaner and more convenient cooking fuels to wood. The poor know that there is a hierarcy of cooking fuels and they view changes from fuelwood to charcoal to kerosene to electricity/gas as steps in the improvement of the quality of their life. There is in fact a technical basis for these preferences. Gaseous cooking fuels offer a tremendous advantage - the rate of gas flow, and therefore the rate of combustion and the rate of release of heat energy to the cooking vessel, can be very rapidly altered and easily controlled. This is extremely important because there are cooking operations such as boiling which require a high power output from the stove, and others such as simmering which need a low power output (Dutt 1978). In addition to the control over the gas flow rate, which facilitates easy and quick variations of the power output, a gaseous cooking fuel permits manipulation of the air to fuel ratio and therefore ensures the completeness of the combustion process. The net result of these advantages is that stoves using gaseous cooking fuels can achieve efficiencies which can be five to ten times the efficiency of traditional firewood stoves. In view of this conflict between cooking efficiencies and fuelwood, the option of conserving fuelwood by using gaseous fuels instead of wood for cooking seems much more attractive than improving the performance of woodstoves. The two gaseous fuels which can be generated from the internal resources of agricultural ecosystems are producer gas obtained by the partial combustion of wood and biogas obtained by the anaerobic fermentation of livestock wastes. Figure 2-9 Trees and fuelwood Figure 2-10 Other uses of wood 145 Figure 2-11 Wood and buildings 12. Trees and fuelwood (figure 2-9) Fuelwood is obtained mainly from trees, but Many shrub species also serve as a source. Since there is a great pressure on land for agriculture, the growth of fuelwood trees is generally restricted to separate areas, or woodlots. But due to the conflict between food, fodder and fuel requirements, it is becoming increasingly difficult to find land, even of the non-arable variety, for woodlots. Very often, therefore, the only trees are those that can be integrated with agricultural use of the land with little or no competition with food and fodder; for example, trees that can be grown on the borders of fields, water-bodies, roads, etc. In a sense, these "border trees" do not occupy land which is required for food and fodder, particularly if they are straight and tall and do not deprive the ground crops of too much light. It is important that they are not profligate with their requirements of water - otherwise, the conflict between fuel and water will be aggravated. Fuelwood trees must also not be too demanding with regard to soil nutrients, and should preferably be nitrogen-fixers so that they enrich the soil. It is an advantage if they also contribute by products of economic value, such as fodder or fruit. In other words, there can be conflicts between particular fuelwood species and the requirements of food, water and fertilizer. Fortunately there are species which satisfy these conditions. Leucaena leucocephala, for example, casts a light shade, needs little water, is leguminous and if; a source of fodder. 13. Other uses of wood (figure 2-10) 146 The wood resources of the agricultural ecosystem are used to meet the requirements of several end uses. Of these, cooking is the most important, but it is essential to reckon with other end uses. In the household sector, for instance, fuelwood is also consumed for water heating and space heating. In addition, fuelwood is used in all the traditional industries which require heat energy. It is only very recently that these small scale industrial uses of wood fuel in rural areas have started to be investigated (e.g. Donovan 1980). In particular, attention is being focussed on brick-burning, tilemaking, pottery, processing of tobacco, tea, cardamon, etc., black-smithy, soapmaking, etc. Wood is also used as a structural material in buildings and animal-drawn vehicles. The scarcity of wood resources implies the possibility of conflicts between wood as a cooking fuel and wood for other end ages. 14. Wood and buildings (figure 2-11) Significant quantities of wood are used in the building sector. Wood, is utilized both directly as a structural material in the form of lumber and indirectly as a fuel for the production of fired bricks and tiles. In both these applications, twigs and branches are usually not used, and logo which can only come from felled trees are required. Brickburning in particular generates considerable demand for wood especially when it in achieved with batch production - in a specific region in South India, approximately 0.4 tonnes of fuelwood is used to burn a 1000 bricks (Jagadish 1979a). It in becoming clear that, in many parts of the Third World, the depletion of fuelwood resources will inhibit the success of building programmes based on burnt bricks and tiles. This implies a conflict between fuelwood and shelter, There appear to be many ways in which this conflict can be resolved - for instance, one promising approach is to use unburnt, but machine-compacted and water-proofed, mud blocks instead of burnt bricks, and alternative roofing materials, preferably based on agricultural residues, in place of tiles. An interesting synergism between roofing materials and wooden structural roof supports can be exploited - the lighter the roofing, the less the volume (and therefore weight) of lumber required to support the roof. Figure 2-12: Wood exports and imports 147 Figure 2-13: Human beings and fuelwood 15. Wood exports and imports (figure 2-12) The dependence on fuelwood for cooking is not a rural phenomenon only; in most developing countries, the use of fuelwood and charcoal in urban areas is significant. In India, for instance, about 20% of the total population lives in towns and cities and approximately 65% of the urban households use firewood as a cooking fuel - this corresponds to about 30 million tonnes (Government of India, 1979) Most towns and cities, however, do not have woodlots as part of their ecosystem, which means that they import their firewood and/or charcoal from the rural areas. Further, to facilitate the transport of this firewood, it has to be in the denser form of logo, which means that tree-felling is almost a necessary part of supplying fuelwood to urban conglomerations. Thus, both the magnitude of firewood exports to towns and cities as well as the type of fuelwood exported, logo, constitute a significant drain on the wood resources of village agricultural ecosystems; they are perhaps far more responsible for the deforestation in such ecosystems than the internal use of wood as a cooking fuel. There is a conflict, therefore, between fuelwood exports and the fuel requirements of agricultural ecosystems. Of course, exports from an ecosystem also bring income into it, but the point is that an export orientation changes the behaviour of the ecosystem, sometimes for the worse. This conflict is aggravated by a common urban preference for charcoal. This preference arises mainly because charcoal has a higher calorific value per unit volume, and it neither catches fire nor deteriorates as easily as wood. First, charcoal produced from twigs and thin branches crumbles and powders easily during storage and transport. Hence charcoal production requires logs from felled trees. Second, high-quality charcoal requires wood from the trees with dense wood which are the best for timber uses Third, in the interest of transport economies, the charcoal required by towns and cities is produced where wood resources are available and in a decentralized manner, often on a household scale. Since the conversion efficiency in such miniscule charcoal-production units is only about 25% (0.25 kgs. charcoal/kg. wood) and the efficiency of' charcoal stoves is only 1.8 times greater than woodstoves, the overall consumption of wood resources is greater when fuelwood is converted into charcoal cooking fuel than when it is used directly. Hence, there is a conflict between charcoal and fuelwood. Wood exports from agricultural ecosystems take place not only to supply the cooking fuel requirements, but also the raw materials needs of lumber mills located in towns and cities. In this case, too, wood is required in the form of large logs and trunks 148 which can be obtained only by cutting down trees. Thus the export of lumber-wood from agricultural ecosystems also has a negative impact on their wood resources. The various unwelcome consequences of wood exports can be diminished by two important strategies. With regard to urban fuel requirements, programmes can be initiated (1) to utilize the biogas obtained by the treatment of urban sewage, (2) to convert town and city garbage into combustible fuels, and (3) to establish green belts around towns and cities and generate producer gas from the fuelwood obtained from the trees in these belts. Such programmes can involve piped supply of sewage, garbage and producer gases. 16. Human beings and fuelwood (figure 2-13) Of course, human beings are the most important, part of the agricultural ecosystem and the focus of the development process. Human beings and, wood resources are related in five obvious ways. First, there is theoretically a maximum to the population which can be supported by the food produced from a given area of land, but this so-called "carrying capacity" depends in part upon the agricultural technologies which are deployed, there being the possibility of adaptive strategies. Green revolution agricultural technologies have increased the carrying capacity many-fold, but this increase has been achieved by increased inputs such as water, fertilizer or inanimate energy. When technologies of enhancing the carrying capacity are not used (for reasons ouch as the lack of capital, water, fertilizer, energy or skills), the only way of augmenting food production after the population approaches the carrying capacity is to increase the area under crop cultivation, for example by clearing forests. This leads to an indirect conflict between people and land which is suitable for woodlots. Figure 2-14 Fuelwood in an agricultural ecosystem 149 Second, an increasing human population loads, in the absence or non-implementation of alternative cooking fuels, to an increasing fuelwood demand at the rate of about 600 tonnes per year for every 1000 additional persons. Thus there is a direct conflict between human beings and fuelwood resources. Third, a growth in human population loads to increased demand for all the other noncooking-fuel uses of wood - i.e. for other domestic uses and for industrial uses of fuelwood and lumber. Fourth, it has been recently argued that domestic chores such as gathering fuelwood, fetching drinking water and grazing livestock encourage people to have large families because children contribute a significant fraction of the human energy necessary to accomplish these tasks which are so vital to a family's survival. As a result, the greater the distance from which fuelwood has to be gathered, and the more the hardship and time required for the task of gathering fuel, the more important it is for a family to have children. Hence there can be a conflict between fuelwood collection and population control. Finally, children have to be removed from school in order to perform the tack of gathering fuelwood, and this creates a conflict between the use of fuelwood and the education of rural children. 17. Fuelwood in an agricultural ecosystem The above presentation has focused on a number of pairs of interactions, each pair consisting of fuelwood and one other ecosystem component or activity. But the pairs are all inter-related, not only through fuelwood, but because there are separate 150 linkages between the ecosystem components and activities. For example, the landfuelwood and humans-fuelwood pairs are linked through the fact that human energy plays a major role in utilizing land for growing food. This means that the separate diagrams (Figures 2-2 - 2-13) portraying each pair interaction must be assembled and integrated into a single diagram which will display, not only the pair-wise interactions, but also the inter-relationships between pairs. The result of such a procedure is shown in Figure 2-14 which reveals the complex, inter-relationships involving fuelwood. The diagram shows that the planning of a fuelwood project requires an understanding of all these linkages. What often happens, however, is that many fuelwood projects ignore crucial interactions and adopt a naive fuelwood-forcooking approach. There is a further complication. Human beings have been treated thus far as a single category, as is customary in ecosystem studies. In stratified, societies, however, several phenomena in human ecosystems become comprehensible only when human society is disaggregated into the relevant economic categories, particularly those categories which describe the inequalities in the ownership and control over assets. Thus, discussions of fuelwood must take into account the fact that in most developing countries all families do not have the same extent, of dependence on fuelwood or the same degree and type of access to this fuel. The rich and powerful sections of rural society own a disproportionately greater fraction of the land, they derive the greatest benefits from water-bodies and groundwater, they have much better access to trees even when they do not own them, they can hire labour to obtain fuelwood, they use liquid and gaseous fuels to a greater extent, and so on. In contrast, the poorest sections, invariably consisting of the landless groups, have the greatest problems with regard to fuelwood. Almost always, they have to get their fuel supplies at zero private direct cost by gathering fuelwood from wherever they are allowed to collect it, and this effort consumes a considerable amount of time, apart from involving them in a client-patron relationship. Such groups are usually the least likely to get a proportionate share in the produce of fuelwood projects, and as a result, they are chary about making contributions of voluntary or communal labour to fuelwood projects. Even if the labour for fuelwood projects is paid for, its seasonality must be taken into account. There can be a conflict between the need for labour on woodlots and the requirements for labour on the farms. When there is such a conflict, the marginal and small farmers who are the ones most likely to work on woodlots (i.e., apart from landless labourers) may prefer to work on their own farms in the hope of much greater returns from their land. Families below or around the poverty line usually make illicit use of resources. For instance, they seek to supplement their incomes by raising livestock - goats, sheep and cattle - many categories of which have to be taken out for grazing wherever grass and leaves are available. The saplings of fuelwood trees are usually a prime target in these grazing expeditions. Thus, the high "infant mortality" of fuelwood species is predominantly due to the survival value of livestock grazing to the poorest sections of rural society. Another important impact of inequalities in land ownership on fuelwood is a result of a mechanism that is often adopted for satisfying the land hunger of the landless. An egalitarian approach would consist of redistributing land by imposing ceilings and distributing the excess land of those with large holdings; instead, the large landowners are often left untouched by the so-called "land reform" and pastureland or land 151 under tree cover is given to the landless. Such measures reduce the fuelwood availability as well as the land which could be used for woodlots - hence, there can be a conflict between land distribution and fuelwood. It appears therefore that whereas the fuelwood situation per se can be remedied if equity considerations are ignored, it is much more difficult to accomplish fuelwood projects with equity. The problem is further complicated by three other factors: (i) Women, rather than men, have a much clearer perception of the fuelwood crisis, because the burden of gathering firewood falls primarily on women and children; (ii) fuelwood is often ranked lower than other needs such as food, employment or water in the villager's perception of priorities; (iii) fuelwood in many regions is traditionally viewed as a common good and the persistence of this attitude can interfere with the implementation of projects which require a different approach. Table 2-1 Land-use pattern Cultivated (22)* Fallow (1) Grass land (3) Marsh land (1) Plantation (coconut, fuel) (2) Water-bodies (2) Settlement (houses, road, etc.) (4) 2. Ragi 3. Sorghum 4. Sugarcane 5. Horsegram 6. Coconut 7. Others (20) Hectares % 243.7 67.7 Crop land 47.0 13.0 290.7 80.7 15.8 4.4 15.4 4.3 0.8 0.3 0.2 37.3 10.3 360.2 100.0 * Number in brackets refers to number of items aggregated. Table 2-2 Cropping pattern - AY 1979-80 1. (a) Paddy (local) (b) Paddy (KYV) Kharif Summer June/Jul-Nov./Dec. Area (ha) % Area (ha) % 126.7 52.0 33.7 13.8 160.4 65.8 41.1 16.9 10.1 50.8 8.7 3.6 7.1 2.9 7.1 35.7 6.7 2.7 4.6 1.9 228.6 93.8 17.2 86.5 15.1 6.2 2.7 13.5 152 Total 243.7 100.0 19.9 100.0 Table 2-3 Above-ground plant biomass productivity Entity Productivity Ratios Production % (tonnes/ha) (tonnes) 1. Crops 1(a) Paddy (local) 6.9 1.38 791.5 41.4 1(b) Paddy (HYV) 7.1 1.42 216.5 11.3 1008.0 52.7 1.2 Ragi 3.8 0.76 111.6 5.8 1.3 Sorghum 1.4 Sugarcane 1.5 Horsegram 1.6 Coconut 1.7 Others 6.1 27.3 1.9 9.2 - 1.22 5.46 0.38 1.84 - 2. Grass land 3. Fallow land 4. March 5. Shrub 5.0 5.3 5.0 12.5 1.00 1.06 1.00 2.50 Total average 6.0 50.1 194.0 13.3 97.4 24.2 1498.6 73.7 249.6 76.7 14.4 414.4 1 913.0 2.6 10.1 0.7 5.1 1.3 78.3 3.9 13.1 4.0 0.7 21.7 100.0 Table 2-4 Disaggregation of above-ground plant biomass Table 2-5 Fodder consumption by livestock Total Bullocks Cows Calves Buffalo Goat(s) and Sheep Paddy straw 571 180 207 17 167 Sorghum grain 1 1 Sorghum straw 49 20 23 6 Grass + Fallow 400 78 91 124 107 1021 279 321 17 297 107 Fodder from crops 621 (60.8%) Fodder from grass = 400 (39.2%) Land + Fallow land + = 400 (39.2%) Marsh land = 400 (39.2%) Table 2-6 Fuel sources From Ecosystem Tonnes/yr. Coconut 61 153 Other crops Trees (Twigs) Trees (Felled) Shrubs 2 172 20 5 260 Imports from outside Ecosystem FW (Bought) 203 Fit (Gathered) 59 262 Total 522 Figure 2-1 Utilization of Paddy Biomass 5.2 TREE BORN OILS (TBO‘S), 5.3 POTENTIALS AND ADVANTAGES, Benefits of Biomass Energy As our society experiences high and volatile energy prices as well as issues of national security, power generated from biomass material is becoming increasingly important. Biomass power facilities benefit: Local communities The national economy and 154 The environment, including significant climate change benefits. Economic Benefits of Biomass Energy Biomass energy plants make a substantial, positive impact on local and regional economies by generating well-paying jobs in: Construction and operation of the plant and Collection and transportation of biomass material. Biomass energy plants support local industry and businesses and encourage new investment in rural communities. Biomass energy facilities can help stabilize the local timber and forestry industry by providing stable demand for biomass material, which allows loggers, harvesters, processors and transporters to make capital investments. Biomass facilities also increase the local tax base without requiring substantial services from the local community. Unlike many other energy fuels, the dollars spent on biomass material stay in the local, state and regional economies since biomass plants primarily use fuel sources that are within 75 miles of the plant. During peak construction, a 100-MW biomass power facility will create approximately 400 construction jobs. Once operational, the facility will create approximately 40 direct full-time positions at the site, and will also generate approximately 700 indirect jobs throughout the region. Social Benefits of Biomass Energy As demand for power increases, many regions of the country face potential supply shortfalls. These shortfalls could result in significantly higher electric prices and potential blackouts. Biomass power generation can help address this issue by providing a source of electricity that is: Reliable, Domestically-produced, Dispatchable, Economically-competitive and Environmentally sustainable. Unlike other forms of renewable energy such as wind and solar energy, biomass energy plants are able to provide crucial, reliable baseload generation. In addition to providing baseload generation, biomass plants provide fuel diversity, which protects communities from volatile fossil fuels. Since biomass energy uses domestically-produced fuels, biomass power greatly reduces our dependence on foreign energy sources and increases our national security. Besides these economic development benefits, biomass plants help ensure a sustainable market for forest products. The jobs created as a result of these facilities help to protect and preserve the unique culture of many rural communities. Environmental Benefits of Biomass Energy Biomass power facilities have numerous attributes, which benefit the environment and world climate change. Environmental benefits include: Cleaner air and Better forestry management. Biomass plants produce far less particulate matter than the alternative method of open burning wood wastes. "In many regions of the United States, the biomass energy industry has become an integral part of the solid waste disposal infrastructure. If the biomass industry were to fail, finding new disposal outlets for all the biomass residue material currently being used for fuel would be difficult." U.S. National Renewable Energy Laboratory Beyond providing cleaner air, biomass energy plants: Encourage better forestry practices which in turn lead to increased protection of critical wildlife habitats, 155 Produce ash which can be used for soil enhancement in farmland, Reduce the impact of invasive species, Reduce wildfire risk, Improve solid waste management by providing an outlet for land-clearing debris, diseased/infected trees and other wood wastes rather than open burning or depositing in already crowded landfills and Reduce the impact of natural disasters by providing an outlet for storm debris. "The record shows that electric generation using biomass that would otherwise be disposed of under a variety of conventional methods (such as open burning, forest accumulation, landfills, composting) results in a substantial net reduction in GHG emissions." California Public Utilities Commission, January 2007, Decision 07-01-039 Climate Change Benefits of Biomass Energy Unlike energy derived from fossil fuels such as coal, oil and natural gas, biomass energy does not contribute to climate change. The carbon, which is stored in biomass material as it grows, is already part of the atmosphere. Biomass energy does not add new carbon to the active carbon cycle, whereas fossil fuels remove carbon from geologic storage. Carbon emissions from biomass facilities would have been released back into the atmosphere through natural decay or disposal through open-burning. The advanced emissions controls on a biomass energy facility significantly reduce the amount of carbon dioxide emitted into the atmosphere along with other emissions such as particulate matter. Biomass energy is considered a "zero-greenhouse-gas-emitting technology" by the Regional Greenhouse Gas Initiative in the Northeast U.S. and the E.U. Emission Trading Scheme. In addition to not emitting new carbon into the active carbon cycle, biomass energy has additional climate change benefits. Like all renewable energy technologies, biomass energy displaces the production of an equivalent amount of energy from fossil fuels. However, biomass energy is not just carbon neutral but actually carbon negative. In the absence of biomass energy, a large portion of biomass material would be left to decompose naturally, be open-burned or landfilled. Landfilled or naturally decaying biomass material releases carbon in the form of methane as well as carbon dioxide. Methane is 20 to 25 times more potent as a greenhouse-gas than carbon dioxide. Biomass energy contributes to forest health and fire resiliency, which increases the amount of carbon stored on a sustainable basis. 156 5.4 BIO-DIESEL TRANS-ESTERIFICATION, 5.5 IMPORTANT BIO-FUEL SPECIES AND THEIR SILVICULTURAL MANAGEMENT. CHAPTER NO.06 WOOD BIOMASS PRODUCTION 6.1 Introduction Energy sources will play an important role in the world’s future. The energy sources have been split into three categories: fossil fuels, renewable sources and nuclear sources. The fossil fuels are coal, petroleum and natural gas. The world’s energy markets rely heavily on the fossil fuels coal, petroleum crude oil, and natural gas as sources of energy, fuels, and chemicals. Since millions of years are required to form fossil fuels in the earth, their reserves are finite and subject to depletion as they are consumed. The only other naturally-occurring, energy-containing carbon resource known that is large enough to be used as a substitute for fossil fuels is biomass. Biomass is all non-fossil organic materials that have intrinsic chemical energy content. They include all water- and land-based vegetation and trees, or virgin biomass, and all waste biomass such as municipal solid waste, municipal bio-solids (sewage) and wastes. Unlike fossil fuels, 157 biomass is renewable in the sense that only a short period of time is needed to replace what is used as an energy resource. Biomass potential includes wood and animal and plant wastes. Biomass is only organic petroleum substitute that is renewable. The term ‘biomass’ refers to forestry, purposely grown agricultural crops, trees and plants, organic wastes, agricultural, agroindustrial and domestic wastes (Garg and Datta, 1998). Table 1 Biomass and other energy sources: production and consumption in the world 1998 Production quad btu Percent of total production 1998 consumption Oil 152.0 40.0% 73.60 million barrels/day Natural gas 85.5 22.5% 82.20 tcf/year Coal 88.6 23.3% 5.01 billion tons/year Nuclear 24.5 6.5% 2.30 trillion kWh/year Hydroelectric 26.6 7.0% 2.60 trillion kWh/year Biomass (other) 2.5 0.7% 196.00 billion kWh/year Total 397.7 100.0% Source: EIA, 1998. World production of biomass is estimated at 146 billion metric tons a year, mostly wild plant growth (Cuff and Young, 1980). Biomass fuel is a renewable energy source and its importance will increase as national energy policy and strategy focuses more heavily on renewable sources and conservation. Biomass power plants have advantages over fossil-fuel plants because their pollution emissions are less. Biomass production and consumption in the world is given Table 1. Biomass Potential Biomass can be considered as the best option and has the largest potential that meets these requirements and could insure fuel supply in the future. Mainly in the form of wood, it is the oldest form of energy used by humans. Biomass has great potential as a renewable energy source, both for the richer countries and for the developing world (Demirbas, 2001a). World wide biomass ranks fourth as an energy source, and provides about 14% of the world’s energy needs. In addition, biomass is a clean renewable energy source. Upon combustion, carbon dioxide is released into the atmosphere, but carbon dioxide was the source of the carbon to generate the biomass, so there is no net gain of carbon dioxide (Surmen, 2002). Biomass is the only renewable source of fixed carbon and therefore, it has attracted considerable attention as a renewable energy source in recent years (Yorgun et al., 2001). Biomass energy is more economic to produce and it provides more energy than other energy forms. Biomass production is eight times greater than the total annual world consumption of all other energy sources. Biomass mainly now represents only 3% of primary energy consumption in industrialized countries. However, much of the rural population in developing countries, which represents about 50% of the world’s population, is reliant on biomass, mainly in the form of wood for fuel. Biomass accounts for 35% of primary energy consumption in developing countries, raising the world total to 14% of primary energy consumption. Total annual production of biomass is 2,740 quads in the world. The world primary energy production and consumption by energy sources are given in Table 2 and Table 3. The United States has only about 5% of the world’s population, but is responsible for about onequarter of the total global primary energy demand. The markets for biomass Table 2 World primary energy production by energy source (Quadrillion Btu∗) 1990 1992 1994 1996 1998 1999 Oil 136.35 136.50 138.30 144.93 151.89 149.72 158 Natural gas 75.91 Coal 91.87 Hydroelectric power 22.57 Nuclear electric power 20.37 Biomass and others 1.72 British thermal units (Source: EIA, 2001). 76.89 87.87 22.94 21.36 2.00 79.16 86.76 24.48 22.50 2.21 84.06 89.24 26.10 24.13 2.36 85.39 89.36 26.68 24.41 2.63 87.31 84.90 27.10 25.25 2.83 Table 3 World primary energy consumption by energy source (Quadrillion Btu∗) 1990 1992 1994 1996 1998 1999 Oil 134.87 136.61 139.11 145.41 149.84 152.20 Natural gas 74.51 76.12 78.33 84.01 84.50 86.89 Coal 89.96 86.62 87.44 90.41 89.26 84.77 Hydroelectric power 22.66 23.18 24.76 26.42 26.88 27.29 Nuclear electric power 20.37 21.36 22.50 24.13 24.41 25.25 Biomass and others 1.72 2.00 2.21 2.36 2.63 2.83 British thermal units (Source: EIA, 2001). energy in the United States are therefore already established. They are large, widespread, and readily available as long as the end-use economics are competitive. The contribution of biomass energy to U.S. energy consumption in the late 1970s was over 850,000 barrels of oil equivalent (BOE)/day, or more than 2% of energy consumption at that time. By 1990, it had increased to about 1.4 million BOE/day, or 3.3% of total energy consumption, and is expected to continue to show significant growth. According to the United Nations, global biomass energy consumption was about 6.7% of the world’s total energy consumption in 1990. Use of Biomass Biomass energy is one of humanity’s earliest sources of energy. Biomass is used to meet a variety of energy needs, including generating electricity, heating homes, fueling vehicles and providing process heat for industrial facilities (Surmen, 2002). Energy from biomass fuels is used in electric utility, lumber and wood products, and pulp and paper industries. Wood fuel is a renewable energy source and its importance will increase in the future. Three main determinants of the costs of operating and constructing a wood-fired power plant of a given size exist. They are: the availability of the required fuel, the delivered fuel prices, and the financing and construction of the desired power plant (Joutz, 1992). Most recent research has focused on the feasibility of single-source fuel plants. One popular approach has been to examine the feasibility of short-rotation intensive-cultivation plantations (Jennergren and Thornqvist, 1988). Source: ISBF (International Slovak Table 4 Biomass Forum), 2003. Proportions of carbon, hydrogen and oxygen in fuels Biomass can be used directly (e.g., Ratio of atoms By weight % burning wood for heating and cooking) Fuel C H O C H O or indirectly by converting it into a Coal 1 1 <0.1 85 6 9 liquid or gaseous fuel (e.g., alcohol Oil 1 2 0 85 15 0 from sugar crops or biogas from Methane 1 4 0 75 25 0 animal waste). The net energy Wood 1 1.5 0.7 49 6 45 available from biomass when it is combusted ranges from about 8 MJ/kg for green wood, to 20 MJ/kg for dry plant matter, to 55 MJ/kg for methane, as compared with about 27 MJ/kg for coal (Demirbas, 2001b). Plant oils, bio-diesel, bio-gas and ethanol have been successfully introduced and are already in use. Innovative synthetic fuels are related to aspects and the new developments in conversion technologies to fuels: Gasification, pyrolysis and upgrading to gasoline, diesel and hydrogen, methanol, DME as well as the possibilities of their generation from the biomass. Biomass can be considered as a source for carbon and hydrogen (Table 4). The possible outcome of oil from biomass 159 depends on the productivity of energy plants and up to 9000 oil through modern conversion technologies from one hectare could be achieved (Table 5). While a large part of this white paper target is expected to be reached with biomass for heating, it is expected that biomass will later be used for cogeneration of heat and power as well as for production of hydrogen for transport. Industrial and Home Use of Biomass Wood related industries and homeowners consume the most biomass energy. The lumber, pulp and paper industries burn their own wood wastes in large furnaces and boilers to supply 60% of the energy needed to run the factories. Table 5 Fuel yields from biomass Biomass yield(t ha−1, y−1, kg−1) Energy Conversion Fuel yield(t Fuel yield content(MJ.Kg−1) efficiency(η) ha−1, y−1) (1ha−1, y −1) 10 17.5 0.48 1.9 2448 (3000) 20 17.5 0.48 3.8 4895 (6000) 30 17.5 0.48 5.7 7343 (9000) Source: ISBF, 2003. Biomass is burned by direct combustion to produce steam, which turns a turbine, and the turbine drives a generator, producing electricity. Because of potential ash build-up, only certain types of biomass materials are used for direct combustion. Gasifiers are used to convert biomass into a combustible gas (biogas). The biogas is then used to drive a high efficiency, combined cycle gas turbine. Biogas energy conversion devices that are discussed are reciprocating engines, turbines, micro turbines, fuel cells, and anaerobic digesters. Simple biogas producing devices create anaerobic digestion by decomposing organic matter like crop residues or domestic wastes in an oxygen deprived environment. The resulting biogas—a mix of other gases—can be burnt to provide energy for cooking and space heating, or create electricity to power other equipment. Since many of the parasites and disease producing organisms in the waste are killed by the relatively high temperature in the digester tanks, the digested material can also be used as fertilizer or fish feed. Heat is used to convert biomass chemically into a pyrolysis oil. The oil, which is easier to store and transport than solid biomass material, is then burned like petroleum to generate electricity. Pyrolysis also can convert biomass into phenol oil, a chemical used to make wood adhesives, molded plastics and foam insulation. Wood adhesives are used to glue together plywood and other composite wood products. Electricity Production from Biomass As older power plants age and need to be replaced, and if the cost of fossil fuels continues to rise, cogeneration will be an increasingly attractive alternative for generating electricity. The future of biomass electricity generation lies in biomass integrated gasification/gas turbine technology, which offers high-energy conversion efficiencies. The electricity is produced by direct combustion of biomass, advanced gasification and pyrolysis technologies, and is almost ready for commercial scale use. A steam power plant is actually a two-fluid system; that is, energy is exchanged between the combustion gases and water. The feasibility of combining gas and steam expansion in a power cycle has been extensively explored. Because steam generation involves the flow of large volumes of combustion gases, gas expansion is most appropriately accomplished in a gas turbine (Sorensen, 1983). In the short to medium term, biomass waste and residues are expected to dominate biomass supply, to be substituted by energy crops in the longer term. The future of biomass electricity generation lies in biomass integrated gasification/gas turbine technology, which offers high-energy conversion efficiencies. Biomass power plants (BPPs) use technology that is very similar to that used in coal-fired 160 power plants. For example, biomass plants use similar BPP efficiencies of about 25% steam-turbine generators and fuel delivery systems. Electricity costs are in the −8 c/kWh range. The average BPP is about 20 MW in size, with a few dedicated wood-fired plants in the 40–50 MW capacity, with gas turbine/steam combined cycle. Biomass is burned to produce steam, the steam turns a turbine and drives a generator, producing electricity. The biomass power industry in the United States has grown from less than 200 MW in 1979 to more than 6000 MW in 1990. The United States Department of Energy (USDOE) is projecting installed capacity will grow to about 22 GW by the year 2010 (Bain, 1993). USDOE estimates the present and future impact of biomass-power production of the US economy (Meridian and Antares, 1992). In the year 1992, electrical production from biomass, primarily wood, had a net impact of $1.7 billion and biomass electrical-generating capacity will have grown to approximately 22 GW in 2010. At this capacity level, the economic benefits are estimated to be $6.2 billion in personal and corporate income and 238,000 jobs (Demirbas, 2002). Biomass energy uses, such as electric power generation, also have market entry problems. Tax incentives have been provided to stimulate and encourage the use of biomassbased power generation, but several of the incentives have expired or the conditions that permit their use are difficult to satisfy. Currently, there are no virgin biomass species that are routinely grown in the United States for use as power plant fuels. There are many power plants, however, that are fueled throughout the United States with waste biomass. These plants often take credit for waste disposal, such as the tipping fees for accepting and disposing of MSW, or the power generated as a by-product and is used on-site, the plant is located in or near the center of readily available waste biomass whose disposal is a serious problem, or the power purchase contracts priced at the so-called avoided cost, which is the cost that the utility would incur by generating the power itself, are sufficiently favorable to justify the generation of electric power. Hydrogen from Biomass Hydrogen is a clean burning fuel. It is not a primary fuel; it must be manufactured from water with either fossil or non-fossil energy sources. Hydrogen is produced from pyroligneous oils produced from the pyrolysis of lingocellulosic biomass (Demirbas and Caglar, 1998). Gasification of solid wastes and sewage is a recent innovation. The synthesis gas formed with air or oxygen is reformed to hydrogen. The solid waste concept solves two problems: (1) disposal of urban refuse and sewage, and (2) a source of hydrogen powered vehicles (Veziroglu, 1975). Hydrogen from biomass has generally been based on the following reactions (Demirbas et al., 1996): Municipal solid waste + Air = CO + H2 Biomass + H2O + Air = H2 + CO2 Cellulose + H2O + Air = H2 + CO + CH4 Ethanol Production from Biomass Ethanol costs could be reduced dramatically if efforts to produce ethanol from biomass are successful. Biomass feed stocks, including forest residue, agricultural residue, and energy crops, are abundant and relatively inexpensive, and they are expected to lower the cost of producing ethanol and provide stability to supply and price. Ethanol is a cleaner-burning, renewable fuel that can be produced from a number of domestic feed stocks, mostly crops such as corn and grains. Some conventional food crops that are high in starches and sugars, like sugarcane, corn, sorghum, etc. can be fermented to produce ethanol, a relatively clean burning, high-energy fuel. The choice of biomass is important as feedstock costs typically make up 55–80% of the final alcohol selling price (WEC, 1994). Ethanol is produced by a process known as fermentation. Typically, sugar is extracted from the biomass crop by crushing, then mixing with water and yeast and warm in large tanks called fermenters. The yeast breaks down the sugar and converts it to methanol. 161 A distillation process is required to remove the water and other impurities in the diluted alcohol product (10–15% ethanol). The concentrated ethanol (95% by volume with a single step distillation process) is drawn off and condensed to a liquid form (Demirbas, 2001b). Other less expensive biomass feedstock, such as wood or plant wastes, can also be used for ethanol production, but present conversion techniques in this field are not very efficient, hence, overall cost of ethanol produced from these sources is relatively greater. Overall output is forecast to reach 31.4 billion liters compared with 29.9 billion in 2000 and 31.1 billion in 1999. Nevertheless, the world total is still below the all-time high reached in 1997, when a total of 33.0 billion liters were produced. By the year 2000, 500 million gallons of biomass ethanol will displace 13 million barrels of oil. By the year 2020, 14 billion gallons of ethanol will displace 348 million barrels of oil. The Future of Biomass Biomass provides a number of local environmental gains. Energy forestry crops have a much greater diversity of wildlife and flora than the alternative land use, which is arable or pasture land. Energy crops may also offer a corridor for wildlife between woodland habitats. Energy crops that are carefully sited and designed will enhance local landscapes and provide a new habitat for recreation. Provision of recreation habitat is important near urban centers. It is important to underline here that the collection of fuel from European forestry and agriculture and the use of energy crops is a sustainable activity that does not deplete future resources. By the year 2050, it is estimated that 90% of the world population will live in developing countries (Ramage and Scurlock, 1996). In industrialized countries, the main biomass processes utilized in the future are expected to be direct combustion of residues and wastes for electricity generation, Bioethanol and bio diesel as liquid fuels and combined heat and power production from energy crops. The future of biomass electricity generation lies in biomass integrated gasification/gas turbine technology, which offers high energy conversion efficiencies. Biomass will compete favorably with fossil mass for niches in the chemical feedstock industry. Biomass is a renewable, flexibly and adaptable resource. Crops can be grown to satisfy changing end use needs (Demirbas, 2001b). Environmental Impacts As with all forms of energy production, biomass energy systems raise some environmental issues that must be addressed. In biomass energy projects, issues such as air pollution, impacts on forest, and impacts due to crop cultivation must be addressed on a case by case basis. Unlike other nonrenewable forms of energy, biomass energy can be produced and consumed in a sustainable fashion, and there is no net contribution of carbon dioxide to global warming (Demirbas, 2001b). The environmental repercussions of using biomass as a source of fuel vary according to the type of conversion technology. The combustion of biomass produces significantly fewer nitrogen oxides and sulfur dioxide than the burning of fossil fuels. Liquid biomass fuels like ethanol and methanol produce less carbon monoxide, hydrocarbons and potentially carcinogenic compounds than gasoline and diesel. Unlike fossil fuel combustion, the use of biomass fuels in a well managed, sustainable production programmer will not contribute to carbon dioxide levels that cause global warming. If, however, a forest region is indiscriminately cleared for fuel, carbon dioxide levels will increase because carbon dioxide released into the atmosphere is not recycled for new growth. Biomass fuel is a renewable energy source and its importance will increase as national energy policy and strategy focuses more heavily on renewable sources and conservation. Biomass power plants have advantages over fossil-fuel plants, because their pollution emissions are less. Technologies have advanced to be largely pollution free. There is zero to little production of slag, ash, SOx, NOx, or CO2 in biomass consumption. However, the use of appropriate, modern technology is critical, so there is zero to little contribution of pollution to the greenhouse effect. There is also no 162 nuclear waste. Since biomass energy does not contribute anything harmful to the environment, it lies very consistently with environmental protection policies. Wood combustion results in lower emissions of SO2 than, for example, coal and would contribute to amelioration of acid rain. Burning wood produces 90% less sulfur than coal. Research on coutilization of biomass with coal has shown that, through dilution effects, emissions of SO2 are reduced linearly with increasing percentage of wood used. In some circumstances, reduced NOx emissions occur because of a reaction between components of the wood and coal particles. Sulfur can be considered as a part of the ecological balance in nature. No additional sulfur comes from bio energy. The effects of using wood biomass for energy on the level of emissions of acidifying compounds are small. Major improvements in heat and power production technology have already been achieved regarding sulfur emissions. In agricultural land, there may be a certain amount of sulfur from fertilizer that is recycled in the environment if short rotation forest or grass is used as a fuel. The energy dimension of biomass use is importantly related to the possible increased use of this source as a critical option to tackle the global warming issue. Biomass is generally considered as an energy source completely CO2-neutral. The underlying assumption is that the CO2 released in the atmosphere is matched by the amount used in its production. This is true only if biomass energy is sustainable consumed, i.e., the stock of biomass does not diminish in time. This may not be the case in many developing countries. The reduction of CO2 emissions applies for electricity production with biomass as for any other use of biomass source of energy. Globally significant environmental benefits may result from using wood for energy rather than fossil fuels. The greatest benefit is derived from substituting biomass energy for coal. The degree of benefit depends greatly on the efficiency with which the wood is converted to electricity. If the Table 6 efficiency of conversion of wood to Example carbon offsets from short-rotation plantation electricity is similar to coal energy used for power production and displacing coal conversion to electricity, then the Factor Wood Coal benefits are several. The ash and Energy density (GI/dry ton) 19.80 29.30 waste products from burning will, in Heat rates (kJ/kWh) 7,200–18,000 10.90 most cases, be sufficiently benign to Feed stock carbon (kgC/GI) 50.00 70.0 return to the soil. There will be a Carbon % 25.30 24.10 considerable reduction in net carbon Input carbon (kgC/GI) 1.34 0.53 dioxide emissions that contribute to Total carbon (kgC/GI) 26.62 24.65 the greenhouse effect. For example, one dry ton of wood will displace 15 GJ of coal. The 15 GJ of coal will have the equivalent of 0.37 ton of carbon, assuming the wood is converted at an efficiency of 25%. Example carbon offsets from short-rotation plantation energy used for power production and displacing coal is given Table 6. Conclusions Biomass is the most important renewable energy source in the world. Biomass fuel is a renewable energy source and its importance will increase as national energy policy and strategy focuses more heavily on renewable sources and conservation. Biomass power plants have advantages over fossilfuel plants because their pollution emissions are less. World production of biomass is estimated at 146 billion metric tons a year, through mostly wild plant growth. Total annual production of biomass is 2,740 quads in the world. In the future, biomass has the potential to provide a cost-effective and sustainable supply of energy, while at the same time aiding countries in meeting their greenhouse gas reduction targets. It is important to underline here that the collection of fuel from European forestry and agriculture and the use of energy crops is a sustainable activity that does not deplete future resources. By the year 2050, it is estimated that 90% of the world population will live in developing countries. 163 6.2 OVERVIEW OF THE MARKETS FOR WOOD BIOMASS FOR ENERGY PRODUCTION GLOBALLY AND WITHIN THE PAKISTAN THIS INCLUDES THE SUPPLY, QUANTITY, DEMAND, AND CONSUMPTION AS WELL AS CONSUMER MARKET ASPECTS. 6.3 FUNDAMENTALS OF THE POLICIES THAT HAVE IMPACTS ON THE SUPPLY AND CONSUMPTION OF THE ENERGY WOOD; In order to build scenarios for future wood supply, forecasts are needed. One main source for future forest products demand and supply is the European Forest Sector Outlook Study (2005). In this study, outlooks for industrial roundwood consumption, as well as consumption of sawnwood, pulpwood and panels are made. However, no forecasts are made for the consumption of fuelwood; consumption was assumed to stay level. Since during recent years fuelwood consumption for energy generation is becoming increasingly important, the present study is incorporating this demand by taking policy objectives for renewable energy and wood energy in particular to predict the wood demand for 2010 and 2020. The EFSOS provides three different scenarios on the sectoral growth (of real production and consumption) of the wood-based industries. The baseline scenario, assuming a moderate growth rate, was used in this study since it is considered to reflect best the expected growth rate of the forest-based industries if energy industries enhance competition for the raw material. The others are based on slower economic growth due to environmental considerations and higher growth taking more globalisation into account. The reference data (production, net trade, prices, etc) for the EFSOS model is the average of 1999 - 2001. The annual growth of production, net trade and consumption in the model is determined by the various input variable to the model. As shown by Schulmeyer (2006) the EFSOS model predicts the international developments in forest products demand and supply mostly correctly. However, in some countries, most notably in Germany, the production has increased substantially more than predicted by EFSOS. Therefore, the reference data for 7 production and consumption of forest products (sawnwood, panels and pulp) was updated on the basis of the average data from 2004 - 2006. The annual growth rates (2005 - 2020) for production and net trade were considered to remain unchanged. These growth rates were applied to the new reference data, to obtain forecasts for production and consumption of forest products for 2010 and 2020. The assumption that material efficiency of the wood-processing industries (wood input per unit produced) would remain constant, leads to a slight over-estimation of the wood consumption in this sector in the future. 3.3 Calculating the consequences of policy objectives Various paths can be chosen to predicting the future role of wood in energy generation. In this study, no econometric models were used to forecast the demand for wood energy, since EFSOS so far does not model the consumption of wood for energy generation, but it was assumed that the demand would be driven by policies. Prices are not included in the study, in order to keep the analysis simple and comprehensible. However, this implies certain assumptions and restrictions when looking at the results. Thus, no conclusions are made on the price of reaching the policy targets, but rather on the amounts of wood needed (also in 164 comparison with other wood consumers), and this is leading to the question of possible impacts of the policies. This study has collected national and EU targets for renewable energy, bioenergy and wood energy (if available) and translated them into wood volumes, by applying number of simple transparent assumptions: 1. Obtain credible official scenario for total primary energy supply (taking account of foreseen efficiency savings) if available. Otherwise assume the same energy supply as in 2005; 2. Apply official policy target for energy production from renewable sources to total energy supply. If no targets were found the overall EU targets were assumed (2010: 12% and 2020: 20% 4). 3. Apply national target for bioenergy if available. Otherwise, estimate the share of energy production from biomass as percentage of energy production from renewable sources (typically by assuming the same share as in 2005) 4. Apply target for wood energy if available. Otherwise, estimate the share of energy production from wood as percentage of energy production from biomass sources (typically by assuming the same share as in 2005) The same methodology was used for 2010 and 2020, bearing in mind that for 2020 much less information was found on national targets, or targets for bioenergy or even wood energy. 4 If the 2010 target was below 12%, and no target was set for 2020, the growth rate of renewable energy (as targeted between 2005 and 2010) is assumed to continue. This leads mostly to a lower figure than 20%. If the target is already above the EU target and no new targets were set, it is assumed to stay. 8 "75 % scenario" for 2020 Wood energy has the highest share of all renewable sources in 2005 in most countries (wood energy constitutes over 50% of all renewable energy over the EU as a whole). Therefore, an increase in renewable energy would affect wood energy the most, if the relative shares of different energies would remain constant (as suggested in assumptions 3 and 4). However, in particular this assumption seems unrealistic in the long term (2020), since other renewable energies will develop further and faster (form a lower base) and become more competitive. In addition, the availability of wood raw material is likely to be decreasing, leading to a wood price increase, and in any case the use of wood would probably remain mostly for heating or CHP. Therefore, the study suggests a scenario, where the relative share of wood compared to all other renewable energy sources decreases to 75%5 of the percent share in 2005 by 2020. However, the scenario made the assumption that despite the decrease in relative share of wood energy compared to other renewable sources, the absolute figures would not be less then 2010. If targets for wood energy for 2020 were available, the scenario stuck to the national targets (as for Finland and Slovakia). In recent years, wood energy has attracted attention as an environmentally-friendly alternative to fossil energy, especially in industrial applications for heat and power generation and co-firing for bioelectricity generation. A key priority is aligning energy policies so that the production and use of woody biomass for energy is based on what can be sustainably 165 supplied. FAO assists Member States to improve their wood energy situation in terms of social and economic viability, ecological sustainability, resource efficiency and greenhouse gas emissions. The Organization supports its Members by: raising awareness of the importance of wood energy; collecting, improving and sharing accurate data; formulating, implementing and monitoring sound wood energy policies; facilitating cross-sectoral communication and collaboration; and applying sustainable and resource efficient production and consumption practices. Read more Wood energy is most competitive when produced as a by-product of the wood processing industry. Wood residues from forests provide possibly the greatest immediate opportunity for bioenergy generation given their availability, relatively low-value and their proximity to forestry operations. Wood residues from mills represent another, more easily accessible, source of residues. FAO regularly conducts wood energy outlook studies for different regions. The latest study for Europe presents comprehensive scenarios on wood energy development that offers decision-makers from governments and industries information on the potential impacts of their decisions and provides guidance on how to prepare for future challenges (e.g. the intensive mobilization of wood resources). In many parts of the world, particularly in rural communities in developing countries, wood from forests remains a very important source of energy for cooking and heating. Wood-based energy is also widely used in commercial applications such as fish drying, tobacco curing and brick baking. Total consumption of woodfuel is still increasing in much of Africa, largely due to population growth. In rural areas of most developing countries, fuelwood is the predominant form of wood energy. Charcoal remains a significant energy source in many African, Asian and Latin American households in urban areas. Paramount to finding viable and sustainable solutions for energy access in rural and urban settings is a clear understanding of the local impacts of fuelwood collection in forests and 166 from trees outside forests, its role in livelihoods and its impact on forest degradation and deforestation. 6.4 WOOD BASED FUELS; AND/ OR BIO-ENERGY AND BIO-FUELS‘ MARKETS World Biofuels Markets: Waste Versus Fuel? Food versus fuel is the alliterative catchphrase we're all beginning to hear more and more of, as the global population increases the need for a more sustainable source of fuel rises. Delegates came together at World Biofuels Markets in Rotterdam earlier this month, to discuss the future of biofuels and their feedstocks, writes TheBioenergySite Editor, Gemma Hyland. Speaking at the keynote session was Raffaello Garofalo, Secretary General of the European Biodiesel Board, Suzanne Hunt, Senior Advisor of the Carbon War Room, Dr Damian Carrington, Head of Environment for The Guardian and Sander van Bennekom, Policy Advisor for Oxfam Novib. "From where I sit, the biofuels industry does have an image problem, which needs to be addressed," said Dr Carrington. The Renewable Energy Directive (RED) states that biofuels should account for 10 per cent of land transport fuel by 2020. However the more the industry tries to reach their ambitious targets, the more hurdles they come up against. Initially, in 2006, high oil prices and surplus feedstocks garnered support from governments to increase research and development into biofuel production. Fast-forward six years and a slumping economy, expired tax credits, soaring feedstock costs and a rising population has given way to a new argument on whether biofuel production is sustainable any longer. Yes it is, say some, but at what cost? In November 2011 the global population reached 7 billion and is expected to hit more than 9 billion by 2050. "Food is an issue in the growing world," said Dr Carrington. "Environment groups should be the biggest supporters of biofuels. Fossil fuels are driving climate change, which is a problem for everybody and yet I hear from environment groups every day and they are still not the greatest supporters of biofuels at the moment and that is mainly down to the link between biofuels and food prices." Political Support "The biofuels industry needs political support. I have spoken to quite a lot of MEP's over the last few years who are pretty confused at the moment. They say five years ago biofuels were the answer to everything, yet now they are the villain." According to the International Energy Agency (IEA) biofuel production dropped for the first time in 167 2011. "That is not the sign of an industry heading towards 25 per cent of global energy. Ironically I think the cause of that drop was to do with the rising cost of food prices, the feedstock became more expensive," concluded Dr Carrington. In contrast, earlier this month it was reported that ethanol refiners are consuming more of the US corn crop than livestock producers, for the first time in US history, and this trend is set to continue until 2014 as government mandates and exports boost fuel demand. However, respondents to the World Biofuel Markets annual survey declared feedstocks are shifting to non-food and waste. When asked which next generation feedstocks they thought would be the most promising in 2012, the responses were fairly evenly split among municipal solid waste at 26 per cent, non-food energy crops, such as camelina and jatropha at 24 per cent and algae at 20 per cent. Cellulosic trailed slightly at around 17 per cent. "To me, even the title of the debate is sometimes misleading," said Raffaello Garofalo, Secretary General of the European Biodiesel Board. "Instead of talking 'food versus fuel' we should talk food and fuel. Are we convinced that we cannot make it so that the land can sustainably produce both food and fuel? It is a matter of how we can do it efficiently." Suzanne Hunt, Senior Advisor of the Carbon War Room stated that she agrees bioenergy has an important role to play, but there are issues to overcome first. The one factor mentioned during the debate, which gets increasingly overlooked, is that there can be no clear winner or loser in this ongoing battle. We need both food and fuel to survive, and better practise and understanding of how to provide both sustainably. Surprisingly there was no mention of food waste during the keynote session. In the UK alone 7.2 million tonnes of food is thrown away as each year, even more shockingly the UN Food Agency reports that 1.3 billion tonnes of food was wasted last year. "When we talk about making bioenergy sustainable, the thing we should be debating is not whether it can be done 'right', we all agree that, that's possible, the issue is how to improve it," concluded Ms Hunt. March 2012 168 Biofuel trade is expected to expand in the decade to 2021, with cross trade likely to occur. » Focus: Biofuel mandates in the United States to encourage trade? Error! Error! » See all data for biofuels Market situation World ethanol prices increased strongly in 2011 well above the levels of the 2007/08 highs in a context of strong energy prices, although the commodity prices of ethanol feedstock, mainly sugar and maize, decreased from their peaks in 2010. The two major factors behind this increase were the stagnating ethanol supply in the United States and a drop in Brazilian sugar cane production. Additionally, ethanol production was also significantly below expectations in developing countries having implemented mandates or ambitious targets for the use of biofuels. World biodiesel prices also increased in 2011. Contrary to the global ethanol market, production did not stagnate in 2011; the four major biodiesel producing regions (the European Union, the United States, Argentina, and Brazil) increased their supply compared to 2010. This increase was moderated by a decreasing biodiesel production in Malaysia (from about 1 Bnl in 2010 to almost nothing in 2011). Projection highlights Over the projection period, ethanol and biodiesel prices are expected to remain supported by high crude oil prices and by the implementation and continuation of policies promoting biofuel use. Changes in the implementation of biofuel policies can strongly affect biofuel markets. Global ethanol and biodiesel production are projected to expand but at a slower pace than in the past. Ethanol markets are dominated by the United States, Brazil and to a smaller extent the European Union. Biodiesel markets will likely remain dominated by the European Union and followed by the United States, Argentina and Brazil. 169 Biofuel trade is anticipated to grow significantly, driven by differential policies among major producing and consuming countries. The United States, Brazil and the European Union policies all “score” fuels differently for meeting their respective policies. This differentiation is likely to lead to additional renewable fuel trade as product is moved to its highest value market, resulting in potential cross trade of ethanol and biodiesel. Focus: Biofuel mandates in the United States to encourage trade? There are many uncertainties concerning the future of biofuel policies. An important one concerns the policy options faced by the US Environmental Protection Agency (EPA) in the implementation of the US biofuel policy. The Outlook report provides a scenario analysis of three alternative policy implementation options that take into account the fact that the cellulosic mandate as defined in the Energy Independence and Security Act of 2007 (EISA) will not be met. Those scenarios have been produced to illustrate the policy space, and not to promote any particular policy option. The results of the scenario can be summarised as follows: If the shortfall in the cellulosic mandate in the global US mandate is met by raising the mandate for advanced biofuels or by allowing more corn-based ethanol, the impacts on world prices for biofuels (in particular ethanol) as well as for biofuel feedstocks (coarse grains, sugar cane) are likely to be important. Spill-over effects on other agricultural commodity prices (including meat and fish) would occur. Meeting the adjusted US biofuel mandate will require some adjustment in terms of ethanol production and consumption patterns, as well as in terms of ethanol feedstock use around the world. Food is likely to cost more as a result of such adjustments. An important policy driven two-way ethanol trade is likely to emerge between Brazil and the United States under certain conditions. Brazil is likely to be the sole country able to adapt and respond to US demand. This is due to the nature of its ethanol production based on sugar cane, its flexibility to switch between ethanol and sugar production, and to the rising demand for ethanol used for flex-fuel vehicles in Brazil. 170 CHAPTER NO.07 BIOENERGY RESEARCH AND DEVELOPMENT 7.1 NEED FOR RESEARCH AND DEVELOPMENT ON ENVIRONMENT FRIENDLY AND SOCIO ECONOMICALLY RELEVANT TECHNOLOGIES. 7.2 ENERGY FROM PLANTS-PROBLEMS AND PROSPECTS. 7.3 PETRO-CROPS. 7.4 CRITERIA FOR EVALUATION OF DIFFERENT SPECIES FOR ENERGY PLANTATION. 171 CHAPTER NO.08 ADVANCED ENERGY TECHNOLOGY 8.1 ADVANCED ENERGY TECHNOLOGIES IN THE PRODUCTION OF BIO-FUELS Second-generation (advanced) biofuels Second-generation biofuels are produced from sustainable feedstock. Sustainability of a feedstock is defined, among others, by availability of the feedstock, impact on GHG emissions, and impact on biodiversity and land use. Many second-generation biofuels are under development such as Cellulosic ethanol, Algae fuel., biohydrogen, biomethanol, DMF, BioDME, Fischer-Tropsch diesel, biohydrogen diesel, mixed alcohols and wood diesel. Cellulosic ethanol production uses nonfood crops or inedible waste products and does not divert food away from the animal or human food chain. Lignocellulose is the "woody" structural material of plants. This feedstock is abundant and diverse, and in some cases (like citrus peels or sawdust) it is in itself a significant disposal problem. Producing ethanol from cellulose is a difficult technical problem to solve. In nature, ruminant livestock (such as cattle) eat grass and then use slow enzymatic digestive processes to break it into glucose (sugar). In cellulosic ethanol laboratories, various experimental processes are being developed to do the same thing, and then the sugars released can be fermented to make ethanol fuel. In 2009, scientists reported developing, using "synthetic biology", "15 new highly stable fungal enzyme catalysts that efficiently break down cellulose into sugars at high temperatures", adding to the 10 previously known. The use of high temperatures has been identified as an important factor in improving the overall economic feasibility of the biofuel industry and the identification of enzymes that are stable and can operate efficiently at extreme temperatures is an area of active research. In addition, research conducted at Delft University of Technology by Jack Pronk has shown that elephant yeast, when slightly modified, can also produce ethanol from inedible ground sources (e.g. straw). The recent discovery of the fungus Gliocladium roseum points toward the production of so-called myco-diesel from cellulose. This organism (recently discovered in rainforests of northern Patagonia) has the unique capability of converting cellulose into medium-length hydrocarbons typically found in diesel fuel. Scientists also work on experimental recombinant DNA genetic engineering organisms that could increase biofuel potential. Scientists working with the New Zealand company Lanzatech have developed a technology to use industrial waste gases, such as carbon monoxide from steel mills, as a feedstock for a microbial 172 fermentation process to produce ethanol. In October 2011, Virgin Atlantic announced it was joining with Lanzatech to commission a demonstration plant in Shanghai that would produce an aviation fuel from waste gases from steel production. Scientists working in Minnesota have developed co-cultures of Shewanella and Synechococcus that produce long-chain hydrocarbons directly from water, carbon dioxide, and sunlight. The technology has received ARPA-E funding. Issues with biofuel production and use There are various social, economic, environmental and technical issues with biofuel production and use, which have been discussed in the popular media and scientific journals. These include: the effect of moderating oil prices, the "food vs fuel" debate, poverty reduction potential, carbon emissions levels, sustainable biofuel production, deforestation and soil erosion, loss of biodiversity, and impact on water resources, as well as energy balance and efficiency. The International Resource Panel, which provides independent scientific assessments and expert advice on a variety of resource-related themes, assessed the issues relating to biofuel use in its first report, Towards sustainable production and use of resources: Assessing Biofuels. The report outlined the wider and interrelated factors that need to be considered when deciding on the relative merits of pursuing one biofuel over another. It concluded not all biofuels perform equally in terms of their impact on climate, energy security, and ecosystems, and suggested environmental and social impacts need to be assessed throughout the entire life-cycle. Although many current issues are noted with biofuel production and use, the development of new biofuel crops and second-generation biofuels attempts to circumvent these issues. Many scientists and researchers are working to develop biofuel crops that require less land and use fewer resources, such as water, than current biofuel crops do. According to the journal Renewable fuels from algae: An answer to debatable land based fuels, algae are a source for biofuels that could use currently unprofitable land and wastewater from different industries. Algae are able to grow in wastewater, which does not affect the land or freshwater needed to produce current food and fuel crops. Furthermore, algae are not part of the human food chain, so do not take away food resources from humans. The effects of the biofuel industry on food are still being debated. According to a recent study, biofuel production accounted for 3-30% of the increase in food prices in 2008. A recent study for the International Centre for Trade and Sustainable Development shows market-driven expansion of ethanol in the US increased corn prices by 21% in 2009, in comparison with what prices would have been had ethanol production been frozen at 2004 levels. This has prompted researchers to develop biofuel crops and technologies that will reduce the impact of the growing biofuel industry on food production and cost. One step to overcoming these issues is developing biofuel crops best suited to each region of the world. If each region used a specific biofuel crop, the need to use fossil fuels to transport the fuel to other places for processing and consumption will be diminished. Furthermore, certain areas of the globe are unsuitable for producing crops that require large amounts of water and nutrient-rich soil. Therefore, current biofuel crops, such as corn, are unpractical in different environments and regions of the globe. In 2012, the United States House Committee on Armed Services put language into the 2013 National Defense Authorization Act that would prevent the Pentagon from purchasing biofuels that offered improved performance for combat aircraft. Current research Research is ongoing into finding more suitable biofuel crops and improving the oil yields of these crops. Using the current yields, vast amounts of land and fresh water would be needed to produce enough oil to completely replace fossil fuel usage. It would require twice the land area of the US to be devoted to soybean production, or two-thirds to be devoted to rapeseed production, to meet current US heating and transportation needs. Specially bred mustard varieties can produce 173 reasonably high oil yields and are very useful in crop rotation with cereals, and have the added benefit that the meal leftover after the oil has been pressed out can act as an effective and biodegradable pesticide. The NFESC, with Santa Barbara-based Biodiesel Industries, is working to develop biofuels technologies for the US navy and military, one of the largest diesel fuel users in the world. A group of Spanish developers working for a company called Ecofasa announced a new biofuel made from trash. The fuel is created from general urban waste which is treated by bacteria to produce fatty acids, which can be used to make biofuels. Ethanol biofuels As the primary source of biofuels in North America, many organizations are conducting research in the area of ethanol production. The National Corn-to-Ethanol Research Center (NCERC) is a research division of Southern Illinois University Edwardsville dedicated solely to ethanol-based biofuel research projects. On the federal level, the USDA conducts a large amount of research regarding ethanol production in the United States. Much of this research is targeted toward the effect of ethanol production on domestic food markets. A division of the U.S. Department of Energy, the National Renewable Energy Laboratory (NREL), has also conducted various ethanol research projects, mainly in the area of cellulosic ethanol. Algal biofuels From 1978 to 1996, the US NREL experimented with using algae as a biofuels source in the "Aquatic Species Program".A self-published article by Michael Briggs, at the UNH Biofuels Group, offers estimates for the realistic replacement of all vehicular fuel with biofuels by using algae that have a natural oil content greater than 50%, which Briggs suggests can be grown on algae ponds at wastewater treatment plants. This oil-rich algae can then be extracted from the system and processed into biofuels, with the dried remainder further reprocessed to create ethanol. The production of algae to harvest oil for biofuels has not yet been undertaken on a commercial scale, but feasibility studies have been conducted to arrive at the above yield estimate. In addition to its projected high yield, algaculture — unlike crop-based biofuels — does not entail a decrease in food production, since it requires neither farmland nor fresh water. Many companies are pursuing algae bioreactors for various purposes, including scaling up biofuels production to commercial levels. Prof. Rodrigo E. Teixeira from the University of Alabama in Huntsville demonstrated the extraction of biofuels lipids from wet algae using a simple and economical reaction in ionic liquids. Jatropha Several groups in various sectors are conducting research on Jatropha curcas, a poisonous shrub-like tree that produces seeds considered by many to be a viable source of biofuels feedstock oil. Much of this research focuses on improving the overall per acre oil yield of Jatropha through advancements in genetics, soil science, and horticultural practices. SG Biofuels, a San Diego-based jatropha developer, has used molecular breeding and biotechnology to produce elite hybrid seeds that show significant yield improvements over first-generation varieties. SG Biofuels also claims additional benefits have arisen from such strains, including improved flowering synchronicity, higher resistance to pests and diseases, and increased coldweather tolerance. Plant Research International, a department of the Wageningen University and Research Centre in the Netherlands, maintains an ongoing Jatropha Evaluation Project that examines the feasibility of large-scale jatropha cultivation through field and laboratory experiments. The Center for Sustainable Energy Farming (CfSEF) is a Los Angeles-based nonprofit research organization dedicated to jatropha research in the areas of plant science, agronomy, and horticulture. Successful exploration of these disciplines is projected to increase jatropha farm production yields by 200-300% in the next 10 years. Fungi A group at the Russian Academy of Sciences in Moscow, in a 2008 paper, stated they had isolated large amounts of lipids from single-celled fungi and turned it into biofuels in an economically efficient manner. More research on this fungal species, Cunninghamella japonica, and others, is 174 likely to appear in the near future. The recent discovery of a variant of the fungus Gliocladium roseum points toward the production of so-called myco-diesel from cellulose. This organism was recently discovered in the rainforests of northern Patagonia, and has the unique capability of converting cellulose into medium-length hydrocarbons typically found in diesel fuel. Greenhouse gas emissions According to Britain's National Non-Food Crops Centre, total net savings from using first-generation biodiesel as a transport fuel range from 25-82% (depending on the feedstock used), compared to diesel derived from crude oil. Nobel Laureate Paul Crutzen, however, finds that the emissions of nitrous oxide due to nitrate fertilisers is seriously underestimated, and tips the balance such that most biofuels produce more greenhouse gases than the fossil fuels they replace. Producing lignocellulosic biofuels offers potentially greater greenhouse gas emissions savings than those obtained by first-generation biofuels. Lignocellulosic biofuels are predicted by oil industry body CONCAWE to reduce greenhouse gas emissions by around 90% when compared with fossil petroleum, in contrast first generation biofuels were found to offer savings of 20-70%. Some scientists have expressed concerns about land-use change in response to greater demand for crops to use for biofuel and the subsequent carbon emissions. The payback period, that is, the time it will take biofuels to pay back the carbon debt they acquire due to land-use change, has been estimated to be between 100 and 1000 years, depending on the specific instance and location of land-use change. However, no-till practices combined with cover-crop practices can reduce the payback period to three years for grassland conversion and 14 years for forest conversion. Biofuels made from waste biomass or from biomass grown on abandoned agricultural lands incur little to no carbon debt. Biomass planting mandated by law (as in European Union) is causing concerns over raising food prices and actual emissions reductions, as large quantities of biomass are being transported to the EU from Africa, Asia, and the Americas (Canada, USA, Brazil). For example in Poland, as much as 85% of biomass used is imported from outside of the EU, with a single electric plant in Łódź importing over 7000 tons of wood biomass from the Republic of Komi (Russia) over distance of 7000 kilometers on monthly basis. 175 CHAPTER NO.09 Acetic acid: An acid with the structure of C2H4O2. Acetyl groups are bound through an ester linkage to hemicellulose chains— especially xylans—in wood and other plants. The natural moisture present in plants hydrolyzes the acetyl groups to acetic acid, particularly at elevated temperatures. Acid detergent fiber (ADF): Organic matter, often cellulose and lignin based, that is not solubilized after one hour of refluxing in an acid detergent of cetyltrimethyl ammonium bromide in 1N sulfuric acid. Acid hydrolysis: The treatment of cellulosic, starch, or hemicellulosic materials using acid solutions (usually mineral acids) to break down the polysaccharides to simple sugars. Acid insoluble lignin: Mostly insoluble in mineral acids so it can be analyzed gravimetrically after hydrolyzing the cellulose and hemicellulose fractions of the biomass with sulfuric acid. ASTM E-1721-95 describes the standard method for determining acid insoluble lignin in biomass. See lignin and acid soluble lignin. Acid soluble lignin: A small fraction of the lignin in a biomass sample that is solubilized during the hydrolysis process of the acid insoluble lignin method. May be quantified by ultraviolet spectroscopy. Acid: A solution that has an excess of hydrogen ions (H+), with a pH of less than 7. Acre — An area of land measuring 43,560 square feet. GLOSSARY Adaptive Management — A dynamic approach to forest management in which the effects of treatments and decisions are continually monitored and used, along with research results, to modify management on a continuing basis to ensure that objectives are being met. Adsorption: The adhesion of molecules (as in gases, solutions, or liquids) in an extremely thin layer to the surface of solid bodies or liquids with which they are in contact. Aerobic fermentation: Fermentation processes that require the presence of oxygen. Aerobic: Able to live, grow, or take place only where free oxygen is present. Agricultural Residue - Agricultural crop residues are the plant parts, primarily stalks and leaves, not removed from the fields with the primary food or fiber product. Examples include corn stover (stalks, leaves, husks, and cobs); wheat straw; and rice straw. With approximately 80 million acres of corn planted annually, corn stover is expected to become a major biomass resource for bioenergy applications. Air dry - The state of dryness at equilibrium with the water content in the surrounding atmosphere. The actual water content will depend upon the relative humidity and temperature of the surrounding atmosphere. Alcohol - The family name of a group of organic chemical compounds composed of 176 carbon, hydrogen, and oxygen. The molecules in the series vary in chain length and are composed of a hydrocarbon plus a hydroxyl group. Alcohol includes methanol and ethanol. OR An organic compound with a carbon bound to a hydroxyl (hydrogen and oxygen, or –OH) group. Examples are methanol, CH3OH, and ethanol, CH3CH2OH. Aldehyde: Any of a class of highly reactive organic chemical compounds characterized by the common group CHO and used in the manufacture of resins, dyes, and organic acids. Aldoses: Occurs when the carbonyl group of a monosaccharide is an aldehyde. (Source: Voet, D.; Voet, J. G. Biochemistry. New York: John Wiley, 1990.) Algae: Simple photosynthetic plants containing chlorophyll, often fast growing and able to live in freshwater, seawater, or damp oils. May be unicellular and microscopic or very large, as in the giant kelps. Alkali lignin: Lignin obtained by acidification of an alkaline extract of wood. Alkali: Soluble mineral salts with characteristically "basic" properties. A defining characteristic of alkali metals. Alkaline hydrolysis: The use of solutions of sodium hydroxide (or other alkali) in the treatment of cellulosic material (wood) to break down cellulose to simple sugars. Alkaline metals - Potassium and sodium oxides (K2O + NaO2) that are the main chemicals in biomass solid fuels that cause slagging and fouling in combustion chambers and boilers. Amylase: Family of enzymes that act together to hydrolyze starch to individual glucose and dextran units. Anaerobic Digestion — Decomposition of biological wastes by micro-organisms, usually under wet conditions, in the absence of oxygen, to produce a gas comprising mostly methane and carbon dioxide. or Degradation of organic matter by microbes that produces a gas comprised mostly of methane and carbon dioxide, usually under wet conditions, in the absence of oxygen. Anaerobic: Living or active in environment without oxygen. Anhydrous: A material that does not contain water, either adsorbed on its surface or as water of crystallization. Annual Removals — The net volume of growing stock trees removed from the inventory during a specified year by harvesting, cultural operations such as timber stand improvement, or land clearing. Aquatic plants: The aquatic biomass resources, such as algae, giant kelp, other seaweed, and water hyacinth. Certain microalgae can produce hydrogen and oxygen while others manufacture hydrocarbons and a host of other products. Microalgae examples include Chlorella, Dunaliella, and Euglena. Arabinan: The polymer of arabinose with a repeating unit of C5H8O4. Can be hydrolyzed to arabinose. (Source: Voet, D.; Voet, J. G. Biochemistry. New York: John Wiley, 1990.) Arabinose: A five-carbon sugar: C5H10O5. A product of the hydrolysis of arabinan found in the hemicellulose fraction of biomass. Archaea (formerly Archaebacteria): A group of single-celled microorganisms. A single individual or species from this domain is called an archaeon (sometimes spelled "archeon"). They have no cell nucleus or any other organelles within their cells. Aromatic: A chemical that has a benzene ring in its molecular structure (benzene, toluene, xylene). Aromatic compounds have strong, characteristic odors. ASABE Standard X593 - The American Society of Agricultural and Biological Engineers (ASABE) in 2005 produced a new standard (Standard X593) entitled “Terminology and Definitions for Biomass Production, Harvesting and Collection, Storage, Processing, Conversion and Utilization.” The purpose of the standard is to provide uniform terminology and definitions in the general area of biomass production and utilization. This standard includes many terminologies that are used in biomass feedstock production, harvesting, collecting, handling, storage, pre-processing and conversion, bioenergy, biopower and bioproducts. The terminologies were reviewed by many experts from all of the different fields of biomass and bioenergy before being accepted as part of 177 the standard. The full-text is included on the online Technical Library of ASABE (http://asae.frymulti.com); members and institutions holding a site license can access the online version. Print copies may be ordered for a fee by calling 269-429-0300, emailing martin@asabe.org, or by mail at: ASABE, 2950 Niles Rd., St. Joseph, MI 49085. Asexual reproduction - The naturally occurring ability of some plant species to reproduce asexually through seeds, meaning the embryos develop without a male gamete. This ensures the seeds will produce plants identical to the mother plant. Ash — The noncombustible components of fuel. Ash content: Residue remaining after ignition of a sample determined by a definite prescribed procedure. Attainment area: A geographic region where the concentration of a specific air pollutant does not exceed federal standards. Auger: A rotating, screw-type device that moves material through a cylinder. In alcohol production, it is used to transfer grains from storage to the grinding site and from the grinding site to the cooker. Avoided costs - An investment guideline describing the value of a conservation or generation resource investment by the cost of more expensive resources that a utility would otherwise have to acquire. Baghouse - A chamber containing fabric filter bags that remove particles from furnace stack exhaust Gases. Used to eliminate particles greater than 20 microns in diameter. B20: A mixture of 20% biodiesel and 80% petroleum diesel based on volume. Bacteria: A small single-cell organism. Bacteria do not have an organized nucleus, but they do have a cell membrane and protective cell wall. Bacteria can be used to ferment sugars to ethanol. Bagasse: Residue remaining after extracting a sugar-containing juice from plants like sugar cane. Bark: The outer protective layer of a tree, including the inner bark and the outer bark. The inner bark is a layer of living bark that separates the outer bark from the cambium. In a living tree, inner bark is generally soft and moist while the outer bark is a layer of dead bark that forms the exterior surface of the tree stem. The outer bark is frequently dry and corky. Barrel of Oil Equivalent (BOE) — The amount of energy contained in a barrel of crude oil, i.e. approximately 6.1 GJ (5.8 million Btu), equivalent to 1,700 kWh. A "petroleum barrel" is a liquid measure equal to 42 U.S. gallons (35 Imperial gallons or 159 liters); about 7.2 barrels are equivalent to one metric ton of oil. Barrel (of oil): A liquid measure equal to 42 U.S. gallons (35 Imperial gallons or 159 liters); about 7.2 barrels are equivalent to one tonne of oil (metric), or typically about 306 pounds of oil. One barrel equals 5.6 ft3; for crude oil, one barrel contains about 5.8 x 106 Btu of energy (6.1 GJ, equivalent to 1,700 kWh). Basal Area — (a) The cross- sectional area (in square feet) of a tree trunk at 4.5 feet above the ground (Basal area of a tree is feet per acre. OR The area of the cross section of a tree stem, including the bark, measured at breast height (4.5 feet above the ground). Base: A solution that has an excess of hydroxide ions (OH-) in aqueous solution and has a pH greater than 7. Batch distillation: A process in which the liquid feed is placed in a single container and the entire volume is heated (see batch fermentation and batch process). Batch fermentation: Fermentation conducted from start to finish in a single vessel without addition to, or removal of, a major substrate or product stream until the process is complete (see batch distillation and batch process). Batch process: Unit operation where one cycle of feedstock preparation, cooking, fermentation, and distillation is completed before the next cycle is started (see batch distillation and batch fermentation). Beer: A fermented broth that consists of water, ethanol, and small amounts of ether and assorted alcohols. Benzene: An aromatic component of gasoline, which is a known cancer-causing agent. It is a 178 6-sided structure with three alternating double bonds. Best Management Practices: maintain and improve the environmental values of forests associated with soils, water, and biological diversity; primarily used for the protection of water quality. Biobased product - The term 'biobased product,' as defined by Farm Security and Rural Investment Act (FSRIA), means a product determined by the U.S. Secretary of Agriculture to be a commercial or industrial product (other than food or feed) that is composed, in whole or in significant part, of biological products or renewable domestic agricultural materials (including plant, animal, and marine materials) or forestry materials. Biochar — A type of charcoal produced from biomass via pyrolysis. Often used as a soil amendment. Biochemical Conversion — The use of fermentation or anaerobic digestion to produce fuels and chemicals from organic sources. OR A general term describing the use of biological systems to transform one compound into another. Examples are digestion of organic wastes or sewage by microorganisms to produce methane and the synthesis of organic compounds from carbon dioxide and water by plants. Biodiesel — A form of fuel for use in diesel engines that is produced through a chemical process called transesterfication whereby glycerin is separated from organically derived oils and fats. OR Fuel derived from vegetable oils or animal fats. It is produced when a vegetable oil or animal fat is chemically reacted with an alcohol. OR A biodegradable transportation fuel for use in diesel engines that is produced through the transesterfication of organically derived oils or fats. It may be used either as a replacement for or as a component of diesel fuel. Biodiversity — The variety of life forms in a given area. Diversity can be categorized in terms of the number of species, the variety in the area’s plant and animal communities, the genetic variability of the animals, or a combination of these elements. Bioenergy — Renewable energy produced from organic matter through the conversion of complex carbohydrates. This energy may either be used directly as fuel, processed into liquids or gasses, or be a residual of the processing or conversion mechanisms. OR Useful, renewable energy produced from organic matter - the conversion of the complex carbohydrates in organic matter to energy. Organic matter may either be used directly as a fuel, processed into liquids and gasses, or be a residual of processing and conversion. Bioethanol - Ethanol produced from biomass feedstocks. This includes ethanol produced from the fermentation of crops, such as corn, as well as cellulosic ethanol produced from woody plants or grasses. Biofuels — Liquid, solid, or gaseous fuels made from biomass resources, or their processing and conversion derivatives. Examples include biodiesel from vegetable oil, bioethanol from sugar cane or wood chips, and biogas from anaerobic decomposition of wastes. Biogas - A combustible gas derived from decomposing biological waste under anaerobic conditions. Biogas normally consists of 50 to 60 percent methane. See also landfill gas. OR A gaseous mixture of carbon dioxide and methane produced by the anaerobic digestion of organic matter. Biogasification or biomethanization - The process of decomposing biomass with anaerobic bacteria to produce biogas. Biological oxygen demand (BOD) - An indirect measure of the concentration of biologically degradable material present in organic wastes. It usually reflects the amount of oxygen consumed in five days by biological processes breaking down organic waste. Biomass energy - See Bioenergy. Biomass processing residues - Byproducts from processing all forms of biomass that have significant energy potential. For example, making solid wood products and pulp from logs produces bark, shavings and sawdust, and spent pulping liquors. Because these residues are already collected at the point of processing, they can be convenient 179 and relatively inexpensive sources of biomass for energy. Biomass - Any organic matter that is available on a renewable or recurring basis, including agricultural crops and trees, wood and wood residues, plants (including aquatic plants), grasses, animal manure, municipal residues, and other residue materials. Biomass is generally produced in a sustainable manner from water and carbon dioxide by photosynthesis. There are three main categories of biomass - primary, secondary, and tertiary. OR Biomass is any organic matter including forest and mill residues, agricultural crops and wastes, wood and wood wastes, animal wastes, livestock operation residues, aquatic plants, and municipal and industrial wastes. OR An energy resource derived from organic matter. These include wood, agricultural waste, and other living-cell material that can be burned to produce heat energy. They also include algae, sewage, and other organic substances that may be used to make energy through chemical processes. Biopower - The use of biomass feedstock to produce electric power or heat through direct combustion of the feedstock, through gasification and then combustion of the resultant gas, or through other thermal conversion processes. Power is generated with engines, turbines, fuel cells, or other equipment. Bioproduct: Materials that are derived from renewable feedstocks. Examples include paper, ethanol, and palm oil. Biorefinery — A facility that processes and converts biomass into value-added products. These products include biomaterials, fuels (ethanol), or important feedstocks for the production of chemicals and other materials. Biorefineries can be based on a number of processing platforms using mechanical, thermal, chemical, and biochemical processes. Black Liquor — Solution of lignin-residue and the pulping chemicals used to extract lignin during the manufacture of paper. Bone dry - Having zero percent moisture content. Wood heated in an oven at a constant temperature of 100°C (212°F) or above until its weight stabilizes is considered bone dry or oven dry. Bone-dry-unit (BDU): 2,400 pounds of moisture-free wood, unless otherwise stated. Bottom Ash — Ash that collects under the grates of a combustion furnace. Bottoming cycle - A cogeneration system in which steam is used first for process heat and then for electric power production. Bound nitrogen - Some fuels contain about 0.1-5 % of organic bound nitrogen which typically is in forms of aromatic rings like pyridine or pyrrole. British thermal unit - (Btu) A non-metric unit of heat, still widely used by engineers. One Btu is the heat energy needed to raise the temperature of one pound of water from 60°F to 61°F at one atmosphere pressure. 1 Btu = 1055 joules (1.055 kJ). BTL - Biomass-to-Liquids. Btu = 1055 joules (1.055 kJ). Btu/hr. Btu/lb. Bulk density - Weight per unit of volume, usually specified in pounds per cubic foot. Bundlers — A machine that collects, compresses, and binds forest residues in to bundles. Bunker - A storage tank. Buyback Rate - The price a utility pays to purchase electricity from an independent generator. By-product - Material, other than the principal product, generated as a consequence of an industrial process or as a breakdown product in a living system. OR Leftover material, generated as a result of an industrial process or as a breakdown product in a living system. Capacity factor - The amount of energy that a power plant actually generates compared to its maximum rated output, expressed as a percentage. Calorific Value — The maximum amount of energy that is available from burning a substance. See Higher Heating Value. Cambium: The layer of reproducing cells between the inner bark (phloem) and the wood (xylem) of a tree that repeatedly subdivides to form new wood and bark cells. 180 Cant — The remaining square section of a log when rounded edges and bark are removed. Capacity: The maximum instantaneous output of an energy conversion device, often expressed in kilowatts (kW) or megawatts (MW). Capital cost: The total investment needed to complete a project and bring it to an operable status. The cost of construction of a new plant. The expenditures for the purchase or acquisition of existing facilities. Carbohydrate: A class of organic compounds including sugars and starches. The name comes from the fact that many (but not all) carbohydrates have the basic formula CH2O. Carbon Cycle — The distribution and transfer of carbon through the Earth’s ecosystem that includes such processes as photosynthesis, decomposition, and respiration. OR The carbon cycle includes the uptake of carbon dioxide by plants through photosynthesis, its ingestion by animals and its release to the atmosphere through respiration and decay of organic materials. Human activities like the burning of fossil fuels contribute to the release of carbon dioxide in the atmosphere. Carbon Dioxide (CO2) — A colorless, odorless, incombustible gas formed during respiration, combustion of fossil fuels, and organic decomposition. OR A colorless, odorless, non-poisonous gas that is a normal part of the ambient air. Carbon dioxide is a product of fossil fuel combustion. OR A colorless, odorless gas produced by the respiration and combustion of carboncontaining fuels, used by plants as food in the photosynthesis process. Represented as CO2. Carbon Displacement — Offsetting of carbon dioxide emissions from fossil fuel combustion by substituting fossil fuels with bioenergy. Carbon monoxide: A colorless, odorless, poisonous gas produced by incomplete combustion. Represented as CO. Carbon Sequestration — The long-term storage of carbon in the terrestrial biosphere, underground, or oceans to reduce the buildup of atmospheric carbon dioxide concentrations. Carbonization - The conversion of organic material into carbon or a carbon-containing residue through pyrolysis. Catalyst - A substance that increases the rate of a chemical reaction, without being consumed or produced by the reaction. Enzymes are catalysts for many biochemical reactions. Cellulase: A family of enzymes that break down cellulose into glucose molecules. Cellulose — A carbohydrate that is the principal component of the cell secondary walls of trees and other higher-order plants. It occurs with other components such as lignin’s, hemicellulose, waxes, and gums to form long, hollow fibers. OR The main carbohydrate in living plants. Cellulose forms the skeletal structure of the plant cell wall. OR A carbohydrate that is the principal component of wood. It is made of linked glucose molecules (a six-carbon sugar) that strengthen the cell walls of most plants. Cellulosic/woody biomass contains cellulose components. Cetane number: A measurement of the combustion quality of diesel fuel during compression ignition. It serves as an expression of diesel fuel quality among a number of other measurements that determine overall diesel fuel quality (often abbreviated as CN). Cetane (also called Hexadecane): An alkane hydrocarbon with the chemical formula C16H34. Consists of a chain of 16 carbon atoms, with 3 hydrogen atoms bonded to the 2 end carbon atoms, and 2 hydrogens bonded to each of the 14 other carbon atoms. Cetane is often used as a short-hand for cetane number, a measure of the detonation of diesel fuel. Cetane ignites very easily under compression; for this reason, it is assigned a cetane number of 100, and serves as a reference for other fuel mixtures. CFM: Cubic feet per minute (1,000 cfm = 0.472 cubic meters per second, m3/s). Char: The remains of solid biomass that has been incompletely combusted (e.g., charcoal, if wood is incompletely burned). See Biochar. Chemical oxygen demand (COD) - The amount of dissolved oxygen required to combine with chemicals in wastewater. A 181 measure of the oxygen equivalent of that portion of organic matter that is susceptible to oxidation by a strong chemical oxidizing agent. Chip Van —Enclosed box trailers, generally 8 to 8.5 ft in width, designed to be less than 12.50 ft high when pulled by a road tractor. The difference between the box trailers seen on most highways and vans hauling harvesting products (bulk vans) is that most box trailers are built for containerized cargo (commodities in boxes or on pallets). Chip-n-saw — A cutting method used in cutting lumber from trees that measure between 6 and 14 inches diameter at breast height. The process chips off the rounded outer layer of a log before sawing the remaining cant or rectangular inside section into lumber. Chip-n-saw mills provide a market for trees larger than pulpwood and smaller than sawtimber. Chipper — A large mechanized device that reduces logs, whole trees, slab wood, or lumber to chips of more or less uniform size. Stationary chippers are used in sawmills, while trailer-mounted whole-tree chippers are used in the woods. Chips — Woody material cut into short, thin wafers. Chips are used as raw material for production of paper, fiberboard, biomass fuel, and other products. OR Small fragments of wood chopped or broken by mechanical equipment. Total tree chips include wood, bark, and foliage. Pulp chips or clean chips are free of bark and foliage. Clean Chips — Chipped wood free of bark, needles, leaves, and soil contamination. Cleaning — Release treatment made in forest stand not past the sapling stage to free the favored trees from less desirable vegetation that currently or soon will overtop them. Clearcutting — Regeneration or harvesting method that removes essentially all woody vegetation that would otherwise compete with future crop trees in a single harvesting operation. Closed-loop biomass - Crops grown, in a sustainable manner, for the purpose of optimizing their value for bioenergy and bioproduct uses. This includes annual crops such as maize and wheat, and perennial crops such as trees, shrubs, and grasses such as switchgrass. Cloud point - The temperature at which a fuel, when cooled, begins to congeal and take on a cloudy appearance due to bonding of paraffins. Coarse materials - Wood residues suitable for chipping, such as slabs, edgings, and trimmings. Coarse materials: Wood residues suitable for chipping, such as slabs, edgings, and trimmings. Co-firing — Utilization of bioenergy feedstocks to supplement energy source in high efficiency boilers, usually with coal. OR The use of a mixture of two fuels within the same combustion chamber. Co-generation — The sequential production of electricity and useful heat energy from a common fuel source. Heat from this industrial process can be used to power an electric generator, used for industrial processes, or space and water heating purposes. Combined cycle: Two or more generation processes in a series or in parallel, configured to optimize the energy output of the system. Combined heat and power: More commonly referred to as CHP. See co-generation. Combined-cycle power plant: The combination of a gas turbine and a steam turbine in an electric generation plant. The waste heat from the gas turbine provides the heat energy for the steam turbine. Combustion — Burning. The transformation of biomass fuel into heat, chemicals, and gases through chemical combination of hydrogen and carbon in the fuel with oxygen in the air. OR A chemical reaction between a fuel and oxygen that produces heat (and usually light). Combustion air: The air fed to a fire to provide oxygen for combustion of fuel. Combustion Efficiency — A measure of the 182 productive capture of chemical energy in the fuel to heat energy, often expressed as a percentage or ratio. OR Actual heat produced by combustion, divided by total heat potential of the fuel consumed. Combustion turbine - A type of generating unit normally fired by oil or natural gas. The combustion of the fuel produces expanding gases, which are forced through a turbine, which produces electricity by spinning a generator. Commercial forest land: Forested land which is capable of producing new growth at a minimum rate of 20 cubic feet per acre per year, excluding lands withdrawn from timber production by statute or administrative regulation. Commercial species - Tree species suitable for industrial wood products. Comminuted Material — Biomass material that has been pulverized or precision reduced into smaller sized material. Condensing turbine - A turbine used for electrical power generation from a minimum amount of steam. To increase plant efficiency, these units can have multiple uncontrolled extraction openings for feed-water heating. Conifer: A tree, usually evergreen, with cones and needle-shaped or scalelike leaves, producing wood known commercially as softwood. Conservation Reserve Program (CRP): Provides farm owners or operators with an annual per-acre rental payment and half the cost of establishing a permanent land cover in exchange for retiring environmentally sensitive cropland from production for 10- to 15-years. In 1996, Congress reauthorized the program, commonly referred to as CRP, for an additional round of contracts, limiting enrollment to 36.4 million acres at any time. The 2002 Farm Act increased the enrollment limit to 39 million acres. Producers can offer land for competitive bidding based on an Environmental Benefits Index (EBI) during periodic signups or can automatically enroll more limited acreages in practices such as riparian buffers, field windbreaks, and grass strips on a continuous basis. CRP is funded through the Commodity Credit Corporation. Construction and Demolition (C&D) Debris Building materials and solid waste from construction, deconstruction, remodeling, repair, cleanup or demolition operations. Container Trailer — A trailer designed to hold bulk material. Built to be sturdy and abused, they can be left on a site and filled as desired, and then removed and replaced with an empty container. Continuous fermentation: A steady-state fermentation system in which substrate is continuously added to a fermenter while products and residues are removed at a steady rate. Coppice regeneration: The ability of certain hardwood species to regenerate by producing multiple new shoots from a stump left after harvest. Coppicing - A traditional method of woodland management, by which young tree stems are cut down to a low level, or sometimes right down to the ground. In subsequent growth years, many new shoots will grow up, and after a number of years the cycle begins again and the coppiced tree or stool is ready to be harvested again. Typically a coppice woodland is harvested in sections, on a rotation. In this way each year a crop is available. Co-products: The resulting substances and materials that accompany the production of a fuel product. Cord — A stack of round or split wood consisting of 128 cubic feet f wood, bark, and airspace. A standard cord measures 4 feet by 4 feet by 8 feet. One cord weighs approximately 2.68 tons for pine and 2.90 tons for hardwoods. OR A stack of wood comprising 128 cubic feet (3.62 m3); standard dimensions are 4 x 4 x 8 feet, including air space and bark. One cord contains approximately 1.2 U.S. tons (ovendry) = 2400 pounds = 1089 kg. Corn Distillers Dried Grains (DDG) - Obtained after the removal of ethanol by distillation from the yeast fermentation of a grain or a grain mixture by separating the resultant coarse grain fraction of the whole stillage and 183 drying it by methods employed in the grain distilling industry. Corn stover: The refuse of a corn crop after the grain is harvested. Course Woody Debris — Any piece(s) of dead woody material (includes trunks, branches, and roots) on the ground in forest stands or streams with the large end diameter often greater than 5 inches. Cracking: A reduction of molecular weight by breaking bonds, which may be done by thermal, catalytic, or hydrocracking. Heavy hydrocarbons, such as fuel oils, are broken up into lighter hydrocarbons such as gasoline. Crop failure: consists mainly of the acreage on which crops failed because of weather, insects, and diseases, but includes some land not harvested due to lack of labor, low market prices, or other factors. The acreage planted to cover and soil improvement crops not intended for harvest is excluded from crop failure and is considered idle. Crop Tree — Any tree selected to grow to final harvest or to a selected size. Crop trees are selected for quality, species, size, timber potential, or wildlife value. Cropland harvested: includes row crops and closely sown crops; hay and silage crops; tree fruits, small fruits, berries, and tree nuts; vegetables and melons; and miscellaneous other minor crops. In recent years, farmers have double-cropped about 4 percent of this acreage. Cropland pasture - Land used for long-term crop rotation. However, some cropland pasture is marginal for crop uses and may remain in pasture indefinitely. This category also includes land that was used for pasture before crops reached maturity and some land used for pasture that could have been cropped without additional improvement. Cropland pasture: Land used for long-term crop rotation. However, some cropland pasture is marginal for crop uses and may remain in pasture indefinitely. This category also includes land that was used for pasture before crops reached maturity and some land used for pasture that could have been cropped without additional improvement. OR Includes cropland harvested, crop failure, and cultivated summer fallow. Cropland harvested includes row crops and closely sown crops; hay and silage crops; tree fruits, small fruits, berries, and tree nuts; vegetables and melons; and miscellaneous other minor crops. Cropland used for crops - Cropland used for crops includes cropland harvested, crop failure, and cultivated summer fallow. Cropland - Total cropland includes five components: cropland harvested, crop failure, cultivated summer fallow, cropland used only for pasture, and idle cropland. Crown Thinning — Removal of trees from the upper level in the canopy in order to favor desired crop trees whose crowns are at a lower position in the canopy. Cull — A tree or log of marketable size that is rejected because it does not meet certain specifications of usability or grade because of species type or defects. Defects can include crookedness, decay, injuries, or damage from disease or insects. Cull tree - A live tree, 5.0 inches in diameter at breast height (dbh) or larger that is nonmerchantable for saw logs now or prospectively because of rot, roughness, or species. (See definitions for rotten and rough trees.) Cultivated summer fallow: refers to cropland in sub-humid regions of the West cultivated for one or more seasons to control weeds and accumulate moisture before small grains are planted. This practice is optional in some areas, but it is a requirement for crop production in the drier cropland areas of the West. Other types of fallow, such as cropland planted with soil improvement crops but not harvested and cropland left idle all year, are not included in cultivated summer fallow but are included as idle cropland. Cut-to-Length — A harvest system in which trees are felled, delimbed, and cut to various log lengths at the stump. Deadwood — Dead, standing or fallen, woody biomass from trees or shrubs. Deadwood can be the results of old age, fire, disease, logging, and natural disasters. Deck — A pile of logs on a landing. See 184 Landing. OR (also known as "landing", "ramp", "set-out") An area designated on a logging job for the temporary storage, collection, handling, sorting and/or loading of trees or logs. Dehydration: The removal of the water from any substance. Dehydrogenation: The removal of hydrogen from a chemical compound. Denaturant: A substance that makes ethanol unfit for consumption. Denatured - In the context of alcohol, it refers to making alcohol unfit for drinking without impairing its usefulness for other purposes. Deoxygenation - A chemical reaction involving the removal of molecular oxygen (O2) from a reaction mixture or solvent. Dewatering: The separation of free water from the solids portion of spent mash, sludge, or whole stillage by screening, centrifuging, filter pressing, or other means. Diameter at breast height (dbh): The diameter measured at approximately breast height from the ground (often between 1.3 and 1.5 meters depending on the country and tree type). OR Digester — An airtight vessel or enclosure in which bacteria decomposes biomass in water to produce gas. Also a chemical process for pulping operations. OR A biochemical reactor in which anaerobic bacteria are used to decompose biomass or organic wastes into methane and carbon dioxide. Dimethyl ether Also known as methoxymethane, methyl ether, wood ether, and DME, is a colorless, gaseous ether with with an ethereal smell. Dimethyl ether gas is water soluble and has the formula CH3OCH3. Dimethyl ether is used as an aerosol spray propellant. Dimethyl ether is also a cleanburning alternative to liquified petroleum gas, liquified natural gas, diesel and gasoline. It can be made from natural gas, coal, or biomass. Dirty Chips — Chipped wood containing bark, needles, leaves, and soil. Disaccharides: The class of compound sugars that yields two monosaccharide units upon hydrolysis; examples are sucrose, maltose, and lactose. Discount rate - A rate used to convert future costs or benefits to their present value. Distillate: The portion of a liquid that is removed as vapor and condensed during a distillation process. Distillation: The process by which the components of a liquid mixture are separated by boiling and recondensing the resultant vapors. The main components in the case of alcohol production are water and ethanol. Distillers Dried Grains (DDG) - The dried grain byproduct of the grain fermentation process, which may be used as a high-protein animal feed. Distillers Wet Grains (DWG) - is the product obtained after the removal of ethyl alcohol by distillation from the yeast fermentation of corn. Distributed generation - The Generation of electricity from many small on-site energy sources. It has also been called also called dispersed generation, embedded generation or decentralized generation. Down Woody Debris — Any piece(s) of dead woody material (includes trunks, branches, and roots) on the ground in forest stands or streams. The woody debris can be categorized as course woody debris or fine woody debris based on its large-end diameter. Downdraft gasifier - A gasifier in which the product gases pass through a combustion zone at the bottom of the gasifier. Drop-in fuel: A substitute for conventional fuel that is completely interchangeable and compatible with conventional fuel. A drop-in fuel does not require adaptation of the engine, fuel system, or the fuel distribution network and can be used "as is" in currently available engines in pure form and/or blended in any amount with other fuels. Dry ton: 2,000 pounds of biomass on a moisture-free basis. Drying: Moisture removal from biomass to improve serviceability and utility. Dutch oven furnace - One of the earliest types of furnaces, having a large, rectangular box lined with firebrick (refractory) on the 185 sides and top. Commonly used for burning wood. Heat is stored in the refractory and radiated to a conical fuel pile in the center of the furnace. E-10: A mixture of 10% ethanol and 90% gasoline based on volume. In the United States, it is the most commonly found mixture of ethanol and gasoline. E-85: A mixture of 85% ethanol and 15% gasoline based on volume. Ecology — The science or study of the relationships between organisms and their environment. Ecosystem Services — Benefits people obtain from ecosystems. These include provisioning services such as food, water, timber, and fiber; regulating services that affect climate, floods, disease, wastes, and water quality; cultural services that provide recreational, aesthetic, and spiritual benefits; and supporting services such as soil formation, photosynthesis, and nutrient cycling. Effluent — The liquid or gas discharged from a process or chemical reactor, usually containing residues from that process. OR The liquid or gas discharged after processing activities, usually containing residues from such use. Also discharge from a chemical reactor. Effluent - The liquid or gas discharged from a process or chemical reactor, usually containing residues from that process. Elemental analysis: The determination of carbon, hydrogen, nitrogen, oxygen, sulfur, chlorine, and ash in a sample. See ultimate analysis. Emissions - Waste substances released into the air or water. See also Effluent. Energy crop: A commodity (crop) grown specifically for its fuel value. These include food crops such as corn and sugarcane and nonfood crops such as poplar trees and switchgrass. OR Crops grown specifically for their fuel value. These include food crops such as corn and sugarcane, and nonfood crops such as poplar trees and switchgrass. Currently, two types of energy crops are under development; short-rotation woody crops, which are fast-growing hardwood trees harvested in 5 to 8 years, and herbaceous energy crops, such as perennial grasses, which are harvested annually after taking 2 to 3 years to reach full productivity. Energy Ratio — The ratio of the energy output versus the energy input. The energy ratio of a bioenergy process can be calculated and compared to a conventional fuel lifecycle. An energy ratio below one suggests energy input is greater than energy yield. Environment — The interaction of climate, soil, topography, and other plants and animals in any given area. An organism’s environment influences its form, behavior, and survival. Enzymatic hydrolysis: Use of an enzyme to promote the conversion, by reaction with water, of a complex substance into two or more smaller molecules. Enzyme - A protein or protein-based molecule that speeds up chemical reactions occurring in living things. Enzymes act as catalysts for a single reaction, converting a specific set of reactants into specific products. Ester: A compound formed from the reaction between an acid and an alcohol. In esters of carboxylic acids, the -COOH group of the acid and the -OH group of the alcohol lose a water and become a -COO linkage. Ethanol (CH3CH2OH): A colorless, flammable liquid produced by fermentation of sugars. Ethanol is used as a fuel oxygenate; the alcohol found in alcoholic beverages. Ethanol (CH5OH) - Otherwise known as ethyl alcohol, alcohol, or grain-spirit. A clear, colorless, flammable oxygenated hydrocarbon with a boiling point of 78.5 degrees Celsius in the anhydrous state. In transportation, ethanol is used as a vehicle fuel by itself (E100 – 100% ethanol by volume), blended with gasoline (E85 – 85% ethanol by volume), or as a gasoline octane enhancer and oxygenate (E10 – 10% ethanol by volume). Even-aged Management — Management technique for a stand of trees composed of a single age class. Examples of petrochemical feedstocks are ethylene, propylene, butadiene, benzene, toluene, xylene, and naphthalene. 186 Exotic species - Introduced species not native or endemic to the area in question. Externality - A cost or benefit not accounted for in the price of goods or services. Often "externality" refers to the cost of pollution and other environmental impacts. Extractives: Any number of different compounds in biomass that are not an integral part of the cellular structure. The compounds can be extracted from wood by means of polar and non-polar solvents including hot or cold water, ether, benzene, methanol, or other solvents that do not degrade the biomass structure. The types of extractives found in biomass samples are entirely dependent upon the sample itself. (Source: Fengel, D.; Gerd, W. Wood Chemistry, Ultrastructure, and Reactions. Berlin-New York: Walter de Gruyter, 1989.) Farmgate price - A basic feedstock price that includes cultivation (or acquisition), harvest, and delivery of biomass to the field edge or roadside. It excludes on-road transport, storage, and delivery to an end user. For grasses and residues this price includes baling. For forest residues and woody crops this includes minimal comminution (e.g. chipping). Fast pyrolysis - Thermal conversion of biomass by rapid heating to between 450 and 600 degrees Celsius in the absence of oxygen. OR Pyrolysis in which reaction times are short, resulting in higher yields of certain fuel products, ranging from primary oils to olefins and aromatics, depending on the severity of conditions. Fatty acid: A fatty acid is a carboxylic acid (an acid with a -COOH group) with long hydrocarbon side chains. OR A group of chemical compounds characterized by a chain made up of carbon and hydrogen atoms and having a carboxylic acid (COOH) group on one end of the molecule. They differ from each other in the number of carbon atoms and the number and location of double bonds in the chain. When they exist unattached to the other compounds, they are called free fatty acids. Feedstock — Raw material used for the generation of bioenergy and the creation of other bioproducts. Feedstock - A product used as the basis for manufacture of another product. OR Any material used directly as a fuel, or converted to another form of fuel or energy product. Bioenergy feedstocks are the original sources of biomass. Examples of bioenergy feedstocks include corn, crop residue, and woody plants. Feller-buncher — A self-propelled machine that cuts trees with saw or shears near ground level and then stacks the trees in piles to await transport (skidding). Fermentation — Conversion of carboncontaining compounds by microorganisms for production of fuels and chemicals such as alcohols, acids or energy-rich gases. OR A biochemical reaction that breaks down complex organic molecules (such as carbohydrates) into simpler materials (such as ethanol, carbon dioxide, and water). Bacteria or yeasts can ferment sugars to ethanol. Fiber products - Products derived from fibers of herbaceous and woody plant materials. Examples include pulp, composition board products, and wood chips for export. Fine materials - Wood residues not suitable for chipping, such as planer shavings and sawdust. Fine Woody Debris — Any piece(s) of dead woody material (includes trunks, branches, and roots) on the ground in forest stands or streams with the large end less than 5 inches in diameter. Firm power - (firm energy) Power which is guaranteed by the supplier to be available at all times during a period covered by a commitment. That portion of a customer's energy load for which service is assured by the utility provider. Fischer-Tropsch Fuels - Liquid hydrocarbon fuels produced by a process that combines carbon monoxide and hydrogen. The process is used to convert coal, natural gas and lowvalue refinery products into a high-value diesel substitute fuel. Fixed bed: A collection of closely spaced particles through which gases move up or 187 down for purposes of gasification or combustion. Fixed carbon: The carbon that remains after heating in a prescribed manner to decompose thermally unstable components and distill volatiles. Part of the proximate analysis group. Flail Delimber — A machine used for delimbing tree stems. Flails are mounted on spinning drums that mechanically beat the limbs from the tree stem. Flash point: The temperature at which a combustible liquid will ignite when a flame is held over the liquid; anhydrous ethanol will flash at 51°F. Flash pyrolysis - See fast pyrolysis. Flash vacuum pyrolysis (FVP) - Thermal reaction of a molecule by exposing it to a short thermal shock at high temperature, usually in the gas phase. Flow control - A legal or economic means by which waste is directed to particular destinations. For example, an ordinance requiring that certain waste be sent to a landfill is waste flow control. Flow rate - The amount of fluid that moves through an area (usually pipe) in a given period of time. Fluidized bed: A gasifier or combustor design in which feedstock particles are kept in suspension by a bed of solids kept in motion by a rising column of gas. The fluidized bed produces approximately isothermal conditions with high heat transfer between the particles and gases. Fluidized-bed boiler - A large, refractory-lined vessel with an air distribution member or plate in the bottom, a hot gas outlet in or near the top, and some provisions for introducing fuel. The fluidized bed is formed by blowing air up through a layer of inert particles (such as sand or limestone) at a rate that causes the particles to go into suspension and continuous motion. The super-hot bed material increased combustion efficiency by its direct contact with the fuel. Fly Ash — Ash transported through the combustion chamber by the exhaust gases and generally deposited in the boiler heat exchanger. OR Small ash particles carried in suspension in combustion products. FOB — An acronym for free on board, indicating that the price quoted includes loading on or in the specified container. Foliage — trees and other plant leaves, considered as a group. Forest Health — A measure of the vigor of forest ecosystems. Forest health includes biological diversity; soil, air, and water productivity; natural disturbances; and the capacity of the forest to provide a sustained flow of goods and services for people. OR A condition of ecosystem sustainability and attainment of management objectives for a given forest area. Usually considered to include green trees, snags, resilient stands growing at a moderate rate, and endemic levels of insects and disease. Natural processes still function or are duplicated through management intervention. Forest land - Land at least 10 percent stocked by forest trees of any size, including land that formerly had such tree cover and that will be naturally or artificially regenerated. Forest land includes transition zones, such as areas between heavily forested and nonforested lands that are at least 10 percent stocked with forest trees and forest areas adjacent to urban and built-up lands. Also included are pinyon-juniper and chaparral areas in the West and afforested areas. The minimum area for classification of forest land is 1 acre. Roadside, streamside, and shelterbelt strips of trees must have a crown width of at least 120 feet to qualify as forest land. Unimproved roads and trails, streams, and clearings in forest areas are classified as forest if less than 120 feet wide. Forest Residue — Tops, limbs, bark, foliage, and other woody materials, left after a harvest. Forest Type — Groups of tree species commonly growing in association because of similar environmental requirements. Examples include pine and mixed hardwood; cypress, tupelo, and black gum; and oak and hickory. 188 Forestry residues - Includes tops, limbs, and other woody material not removed in forest harvesting operations in commercial hardwood and softwood stands, as well as woody material resulting from forest management operations such as precommercial thinnings and removal of dead and dying trees. Forwarder — A vehicle that carries logs completely off the ground from stump to road side landing. OR A self-propelled vehicle to transport harvested material from the stump area to the landing. Trees, logs, or bolts are carried off the ground on a stake-bunk, or are held by hydraulic jaws of a clam-bunk. Chips are hauled in a dumpable or open-top bin or chip-box. Fossil fuel - Solid, liquid, or gaseous fuels formed in the ground after millions of years by chemical and physical changes in plant and animal residues under high temperature and pressure. Oil, natural gas, and coal are fossil fuels. OR A carbon or hydrocarbon fuel formed in the ground from the remains of dead plants and animals. It takes millions of years to form fossil fuels. Oil, natural gas, and coal are fossil fuels. Fouling - The coating of heat transfer surfaces in heat exchangers such as boiler tubes caused by deposition of ash particles. Fuel Cell — A device that converts the energy of a fuel directly to electricity and heat, without combustion. Fuel cycle - The series of steps required to produce electricity. The fuel cycle includes mining or otherwise acquiring the raw fuel source, processing and cleaning the fuel, transport, electricity generation, waste management and plant decommissioning. Fuel handling system: A system for unloading wood fuel from vans or trucks, transporting the fuel to a storage pile or bin, and conveying the fuel from storage to the boiler or other energy conversion equipment. Fuel Treatment Evaluator (FTE) - A strategic assessment tool capable of aiding the identification, evaluation, and prioritization of fuel treatment opportunities. Fuel Treatment Thinnings — The process of harvesting trees and underbrush from the forest to reduce the risk of wildfires. Fuelwood - Wood used for conversion to some form of energy, primarily for residential use. Full Cost Method — Cost accounting method that allocates the total production cost across biomass and conventional wood products. Fungi: Plant-like organisms with cells with distinct nuclei surrounded by nuclear membranes, incapable of photosynthesis. Fungi are decomposers of waste organisms and exist as yeast, mold, or mildew. Furfural: An aldehyde derivative of certain biomass conversion processes; used as a solvent. Furnace: An enclosed chamber or container used to burn biomass in a controlled manner to produce heat for space or process heating. Galactan: The polymer of galactose with a repeating unit of C6H10O5. Found in hemicellulose; it can be hydrolyzed to galactose. Galactose: A six-carbon sugar with the formula C6H12O6. A product of hydrolysis of galactan found in the hemicellulose fraction of biomass. Gas Turbine: Sometimes called a combustion turbine; a gas turbine converts the energy of hot compressed gases (produced by burning fuel in compressed air) into mechanical power, which can be used to generate electricity. Gasification: A chemical or heat process to convert a solid fuel to a gaseous form. OR Any chemical or heat process used to convert a feedstock to a gaseous fuel. Gasifier: A device for converting solid fuel into gaseous fuel. In biomass systems, the process is referred to as pyrolitic distillation. See Pyrolysis. OR A device that converts solid fuel to gas. Generally refers to thermochemical processes. Gasohol - A mixture of 10% anhydrous ethanol and 90% gasoline by volume; 7.5% anhydrous ethanol and 92.5% gasoline by volume; or 5.5% anhydrous ethanol and 94.5% gasoline by volume. There are other fuels that contain methanol and gasoline, but these fuels are not referred to as gasohol. 189 Genetic selection: Application of science to systematic improvement of a population, e.g. through selective breeding. Geographic Information Systems (GIS): Technology used as a framework for gathering and organizing spatial data and related information so it can be displayed and analyzed. A GIS is an integrated collection of computer software and data used to view and manage information about geographic places, analyze spatial relationships, and model spatial processes. A GIS enables users to quickly visualize data, extract trends, optimize routes, and interpret other relationships via maps and charts. The technology helps solve problems and answer questions by presenting complex data in understandable and easily sharable ways. Gigawatt (GW): A measure of electrical power equal to 1 billion watts (1,000,000 kW). A large coal or nuclear power station typically has a capacity of about 1 GW. Global Climate Change - Global climate change could result in sea level rises, changes to patterns of precipitation, increased variability in the weather, and a variety of other consequences. These changes threaten our health, agriculture, water resources, forests, wildlife, and coastal areas. Global warming: A term used to describe the increase in average global temperatures due to the greenhouse effect. Scientists generally agree that the Earth's surface has warmed by about 1ºF in the past 140 years. Glucan: The polymer of glucose with a repeating unit of C6H10O5. Cellulose is a form of glucan. Can be hydrolyzed to glucose. (Source: Voet, D.; Voet, J. G. Biochemistry. New York: John Wiley, 1990.) Glucose (C6H12O6): A six-carbon fermentable sugar. Glycerin (C3H8O3): A liquid by-product of biodiesel production. Used in the manufacture of dynamite, cosmetics, liquid soaps, inks, and lubricants. Grade — Utilization and established quality or use classification of lumber, trees, or other forest products. Grassland pasture and range: Grassland pasture and range comprises all open land used primarily for pasture and grazing, including shrub and brush land types of pasture; grazing land with sagebrush and scattered mesquite; and all tame and native grasses, legumes, and other forage used for pasture or grazing. Because of the diversity in vegetative composition, grassland pasture and range are not always clearly distinguishable from other types of pasture and range. At one extreme, permanent grassland may merge with cropland pasture, or grassland may often be found in transitional areas with forested grazing land. Green diesel: A diesel fuel substitute made from renewable feedstocks by using traditional distillation methods. It is also known as renewable diesel. Green gasoline: A liquid identical to petroleum-based gasoline, but is produced from biomass such as switchgrass and poplar trees. In the United States, it is still in the development stages. It is also known as renewable gasoline. Green Power Purchasing/Aggregation Policies - Municipalities, state governments, businesses, and other non-residential customers can play a critical role in supporting renewable energy technologies by buying electricity from renewable resources. At the local level, green power purchasing can mean buying green power for municipal facilities, streetlights, water pumping stations and other public infrastructure. Several states require that a certain percentage of electricity purchased for state government buildings come from renewable resources. A few states allow local governments to aggregate the electricity loads of the entire community to purchase green power and even to join with other communities to form an even larger green power purchasing block. This is often referred to as "Community Choice." Green power purchasing can be achieved via utility green pricing programs, green power marketers (in states with retail competition), special contracts, or community aggregation. Green Power - Electricity that is generated from renewable energy sources is often 190 referred to as “green power.” Green power products can include electricity generated exclusively from renewable resources or, more frequently, electricity produced from a combination of fossil and renewable resources. Also known as “blended” products, these products typically have lower prices than 100 percent renewable products. Customers who take advantage of these options usually pay a premium for having some or all of their electricity produced from renewable resources. Green Ton — 2000 lbs of undried biomass. Moisture content must be specified if green tons are used as a measure of fuel energy. Greenhouse effect: The heat effect due to the trapping of the sun's radiant energy, so that it cannot be reradiated. In the earth's atmosphere, the radiant energy is trapped by greenhouse gases produced from both natural and human sources. OR The effect of certain gases in the Earth's atmosphere in trapping heat from the sun. Greenhouse gas: A gas, such as water vapor, carbon dioxide, tropospheric ozone, methane, and low level ozone, which contributes to the greenhouse effect. OR A gas that absorbs radiant energy from the earth, re-emitting it as infrared radiation, contributing to the warming of the earth. Examples of greenhouse gases include carbon dioxide and water vapor. OR Gases that trap the heat of the sun in the Earth's atmosphere, producing the greenhouse effect. The two major greenhouse gases are water vapor and carbon dioxide. Other greenhouse gases include methane, ozone, chlorofluorocarbons, and nitrous oxide. Grid: An electric utility's system for distributing power. Grinder — A machine that reduce particles in size by repeatedly pounding them into smaller pieces through a combination of tensile, shear and compressive forces. Gross heat of combustion: See higher heating value. Group Selection — Is an uneven-aged regeneration method used for sun loving tree species in which trees are removed and new age classes are established in groups. The width of a group is approximately twice the height of mature trees. Growing stock: A classification of timber inventory that includes live trees of commercial species meeting specified standards of quality or vigor. Cull trees are excluded. When associated with volume, includes only trees 5.0 inches dbh and larger. Guaiacyl: A chemical component of lignin. It has a six-carbon aromatic ring with one methoxyl group attached. It is the predominant aromatic structure in softwood lignins. See syringyl. Habitat: The area where a plant or animal lives and grows under natural conditions. Habitat includes living and non-living attributes and provides all requirements for food and shelter. OR The place or environment where a plant or animal naturally or normally lives, grows and reproduces. Hammermill - A device consisting of a rotating head with free-swinging hammers which reduce chips or wood fuel to a predetermined particle size through a perforated screen. Hardwood: One of the botanical groups of dicotyledonous trees that have broad leaves in contrast to the conifers or softwoods. The botanical name is angiosperms; hardwood has no reference to the actual hardness of the wood. Short-rotation, fast growing hardwood trees are being developed as future energy crops. OR Usually broad-leaved and deciduous trees. Heat rate: The amount of fuel energy required by a power plant to produce one kilowatt-hour of electrical output. A measure of generating station thermal efficiency, generally expressed in Btu per net kWh. It is computed by dividing the total Btu content of fuel burned for electric generation by the resulting net kWh generation. Heat transfer efficiency: Useful heat output released / actual heat produced in the firebox. Heating value - The maximum amount of energy that is available from burning a substance. See higher heating value and lower heating value. 191 Hectare: Common metric unit of area, equal to 2.47 acres. 100 hectares = 1 square kilometer. Hemicellulose: Consists of short, highly branched chains of sugars. In contrast to cellulose, which is a polymer of only glucose, a hemicellulose is a polymer of five different sugars. It contains five-carbon sugars (usually D-xylose and L-arabinose), six-carbon sugars (D-galactose, D-glucose, and D-mannose), and uronic acid. The sugars are highly substituted with acetic acid. The branched nature of hemicellulose renders it amorphous and relatively easy to hydrolyze to its constituent sugars compared to cellulose. When hydrolyzed, the hemicellulose from hardwoods releases products high in xylose (a five-carbon sugar). The hemicellulose contained in softwoods, by contrast, yields more six-carbon sugars. OR A polysaccharide (complex carbohydrate) found in plant cells that is easily extracted by dilute alkalies. Herbaceous energy crops: Perennial nonwoody crops that are harvested annually, though they may take two to three years to reach full productivity. Examples include: Switchgrass (Panicum virgatum), Reed canarygrass (Phalaris arundinacea), Miscanthus (Miscanthus x giganteus), and Giant reed (Arundo donax). Herbaceous plants: Non-woody type of vegetation, usually lacking permanent strong stems, such as grasses, cereals and canola (rape). Hexose: Any of various simple sugars that have six carbon atoms per molecule (e.g., glucose, mannose, and galactose). HFCS - High fructose corn syrup. High Grading — A harvesting technique that removes only the biggest and most valuable trees from a stand and provides high returns at the expense of future growth potential. Poor quality, shade-loving trees tend to regenerate and dominate high- graded sites. Higher heating value (HHV): The heat produced by combustion of one unit of substance at constant volume in an oxygen bomb calorimeter under specified conditions. The conditions are: initial oxygen pressure of 2.0–4.0 MPa (20–40 atm), final temperature of 20º–35ºC, products in the form of ash, liquid water, gaseous CO2and N2, and dilute aqueous HCl and H2SO4. It is assumed that if significant quantities of metallic elements are combusted, they are converted to their oxides. In the case of materials such as coal, wood, or refuse, if small or trace amounts of metallic elements are present, they are unchanged during combustion and are part of the ash. Also known as gross heat of combustion. OR (HHV) The maximum potential energy in dry fuel. For wood, the range is from 7,600 to 9,600 Btu/lb and grasses are typically in the 7,000 to 7,500 Btu/lb range. Hog Fuel — Wood and wood waste biomass processed by grinding for use in a combustor. Hog - A chipper or mill which grinds wood into an acceptable form to be used for boiler fuel. Holocellulose: The total carbohydrate fraction of wood; cellulose plus hemicellulose. Horsepower (electrical horsepower; hp): A unit for measuring the rate of mechanical energy output, usually used to describe the maximum output of engines or electric motors. 1 hp = 550 foot-pounds per second = 2,545 Btu per hour = 745.7 watts = 0.746 kW. Hybrid: The offspring of genetically different parents; combines the characteristics of the parents or exhibits completely new traits. The term is applied as well to the progeny from matings within species and to those between species. Hydrocarbon emissions: In vehicle emissions, these are usually vapors of hydrogen-carbon compounds created from incomplete combustion or from vaporization of liquid gasoline. Emissions of hydrocarbons contribute to ground-level ozone. Hydrocarbon Feedstock — Petroleum (hydrocarbon) based substance used as a raw material in an industrial process of petrochemical feedstocks are ethylene, propylene, butadiene, benzene, toluene, xylene, and naphthalene. Hydrocarbon (HC): An organic compound molecule that contains only hydrogen and carbon. OR A compound containing only hydrogen and carbon. The simplest and lightest forms of hydrocarbon are gaseous. 192 With greater molecular weights they are liquid, while the heaviest are solids. Hydrocracking: A process in which hydrogen is added to organic molecules at high pressures and moderate temperatures; usually used as an adjunct to catalytic cracking. Hydrogenation: Treatment of substances with hydrogen and suitable catalysts at high temperature and pressure to saturate double bonds. Hydrolysis: A chemical reaction that releases sugars that are normally linked together in complex chains. In ethanol production, hydrolysis reactions are used to break down the cellulose and hemicellulose in the biomass. OR A chemical reaction that releases sugars from cellulose and hemicellulose, which are normally linked together in complex chains. OR A process of breaking chemical bonds of a compound by adding water to the bonds. Idle cropland: Land in cover and soil improvement crops; cropland on which no crops were planted. Some cropland is idle each year for various physical and economic reasons. Acreage diverted from crops to soilconserving uses (if not eligible for and used as cropland pasture) under federal farm programs is included in this component. Cropland enrolled in the federal Conservation Reserve Program (CRP) is included in idle cropland. Improvement Cutting — An intermediate, partial, harvest that removes less desirable trees of any species to improve the form, quality, health or wildlife potential of the remaining trees. Usually occurs after the sapling stage and before final harvest. Incinerator: Any device used to burn solid or liquid residues or wastes as a method of disposal. In some incinerators, provisions are made for recovering the heat produced. Inclined grate: A type of furnace in which fuel enters at the top part of a grate in a continuous ribbon, passes over the upper drying section where moisture is removed, and descends into the lower burning section. Ash is removed at the lower part of the grate. Incremental energy costs: The cost of producing and/or transporting the next available unit of electrical energy above a previously determined base cost. OR The cost of producing and transporting the next available unit of electrical energy. Short run incremental costs (SRIC) include only incremental operating costs. Long run incremental costs (LRIC) include the capital cost of new resources or capital equipment. Independent power producer: A power production facility that is not part of a regulated utility. Indirect Impacts — The inter-industry effects of input-output analysis; the impacts above and beyond the direct effects when applied to Type I multipliers. Indirect liquefaction: Conversion of biomass to a liquid fuel through a synthesis gas intermediate step. individual trees within 1 acre of forest. For example a wellInduced Impacts — The impacts of household expenditures in input-output analysis. Industrial wood: All commercial roundwood products, except fuelwood. Inoculum: Microorganisms produced from a pure culture; used to start a new culture in a larger vessel than that in which they were grown. Invasive species - A species that has moved into an area and reproduced so aggressively that it threatens or has replaced some of the original species. Iodine number - A measure of the ability of activated carbon to adsorb substances with low molecular weights. It is the milligrams of iodine that can be adsorbed on one gram of activated carbon. Joule - Metric unit of energy, equivalent to the work done by a force of one Newton applied over a distance of one meter (= 1 kg m2/s2). One joule (J) = 0.239 calories (1 calorie = 4.187 J). Joule: Metric unit of energy, equivalent to the work done by a force of one Newton applied over a distance of one meter (= 1 kg m2/s2). One joule (J) = 0.239 calories (1 calorie = 4.187 J). 193 JP-8 (or JP8 for "Jet Propellant 8"): A kerosene-based jet fuel, specified in 1990 by the U.S. government, as a replacement for the JP-4 fuel; the U.S. Air Force replaced JP-4 with JP-8 completely by the fall of 1996, to use a less flammable, less hazardous fuel for better safety and combat survivability. The U.S. Navy uses a similar formula, JP-5. KG and Pile — A site preparation method in which stumps are pushed up, sheared off, or split apart by a specially designed blade mounted on a bulldozer. Debris is then piled or placed in long rows (windrows) so that an area can be bedded or flat planted. KG Blade — A bulldozer-mounted blade used in forestry and land-clearing operations. A single spike splits and shears stumps at their base. Kilowatt hour (kWh): A measure of energy equivalent to the expenditure of one kilowatt for one hour. For example, 1 kWh will light a 100-watt light bulb for 10 hours. 1 kWh = 3,412 Btu. Kilowatt - (kW) A measure of electrical power equal to 1,000 watts. 1 kW = 3412 Btu/hr = 1.341 horsepower. See also watt. Klason lignin: Lignin obtained from wood after the non-lignin components have been removed with a prescribed sulfuric acid treatment. A specific type of acid-insoluble lignin analysis. Kraft process: Chemical pulping process in which lignin is dissolved by a solution of sodium hydroxide and sodium sulfide. Landfill gas: Biogas produced from the natural degradation of organic material in landfills. OR A type of biogas that is generated by decomposition of organic material at landfill disposal sites. Landfill gas is approximately 50 percent methane. See also biogas. Landing — A cleared working area in the forest where trees and logs are transported (skidded) to be sorted, processed, and loaded on a truck. See Deck. Legume - Any plant belonging to the leguminous family. Characterized by pods as fruits and root nodules enabling the storage of nitrogen. Levelized life-cycle cost: The present value of the cost of a resource, including capital, financing and operating costs, expressed as a stream of equal annual payments. This stream of payments can be converted to a unit cost of energy by dividing the annual payment amount by the annual kilowatt-hours produced or saved. By levelizing costs, resources with different lifetimes and generating capabilities can be compared. Liberation Cutting — Removal of poor quality or un-merchantable trees to favor the growth of desirable trees. Life-cycle assessment (LCA): The investigation and evaluation of the environmental impacts of a given product or service caused or necessitated by its existence. Also known as life-cycle analysis, ecobalance, and cradle-tograve analysis. Lignin pseudo-molecule for modeling: The lignin ratio of methoxy groups to phenylpropanoid groups (MeO:C9) is used to calculate an ultimate analysis for the lignin pseudo-molecule. This ultimate analysis is used to estimate other properties of the molecule, such as its higher heating value and lower heating value. Lignin methoxy (MeO) to phenlypropanoid (C9) ratio: Lignin empirical formulae are based on ratios of methoxy groups to phenylpropanoid groups (MeO:C9). The general empirical formula for lignin monomers is C9H10O2 (OCH3)n, where n is the ratio of MeO to C9 groups. Where no experimental ratios have been found, they are estimated as follows: 0.94 for softwoods; 1.18 for grasses; 1.4 for hardwoods. These are averages of the lignin ratios found in the literature. Paper products, which are produced primarily from softwoods, are estimated to have an MeO:C9 ratio of 0.94. Lignin: A complex polymer that serves as a component of wood and vascular plants, making them firm and rigid. Produces energy in the form of electricity when burned. OR Structural constituent of wood and (to a lesser extent) other plant tissues, which encrusts the cell walls and cements the cells together. 194 Lignocellulose: Refers to plant materials made up primarily of lignin, cellulose, and hemicellulose. Live cull: A classification that includes live cull trees. When associated with volume, it is the net volume in live cull trees that are 5.0 inches dbh and larger. Log Rule or Log Scale — A table that estimates volume or product yield from logs and trees, based on a diagram or mathematical formula. Log Trailer — A trailer designed to haul trees, poles, or shortwood in racks. They are lightweight and have high payload capacities. Logging residues: The unused portions of growing-stock and non-growing-stock trees cut or killed by logging and left in the woods. Low Thinning — Removal of smaller, weaker, and most deformed trees whose crowns are in the lower portion of the stand canopy. Lower heating value (LLV): The heat produced by combusting one unit of a substance, at atmospheric pressure, under conditions such that all water in the products remains in the form of vapor. The net heat of combustion is calculated from the gross heat of combustion at 20oC by subtracting 572 cal/g (1,030 Btu/lb) of water derived from one unit mass of sample, including both the water originally present as moisture and that formed by combustion. This subtracted amount is not equal to the latent heat of vaporization of water because the calculation also reduces the data from the gross value at constant volume to the net value at constant pressure. OR The potential energy in a fuel if the water vapor from combustion of hydrogen is not condensed. Lump Sum Sale — A timber sale in which the buyer and seller agree on a total price for the standing timber. The standing timber is either marked or is in a delineated area. Mannan: The polymer of mannose with a repeating unit of C6H10O5. Can be hydrolyzed to mannose. Mannose (C6H12O6): A six-carbon sugar. A product of hydrolysis of mannan found in the hemicellulose fraction of biomass. Marginal Cost Method — Cost accounting method that counts only the additional costs from the conventional logging operation as the biomass production cost. Marginal Land — Land that does not consistently produce a profitable crop because of infertility, drought, or other physical limitations such as shallow soils. Mash: A mixture of grain and other ingredients with water to prepare wort for brewing operations. Mass closure (%): The percent by weight of the total samples extracted from the biomass sample, compared to the weight of the original sample. It is a sum of the weight percent of moisture, extractives, ash, protein, total lignin, carboxylic acids, and five and six carbon sugar monomers and polymers. This is a good indicator of the accuracy of a complete biomass compositional analysis. MBF — Abbreviation denoting 1,000 board feet. MBF is a typical unit of trade for dimension lumber and sawtimber stumpage. Megawatt (MW): A measure of electrical power equal to one million watts (1,000 kW). See also watt. Merchantable Height — The stem length, measured from one foot above the ground to a 10-, 6-, or 4-inch diameter top, above which no other saleable product can be cut. Diameter, local markets, limbs, knots, and other defects collectively influence merchantable height. Merchantable - Logs from which at least some of the volume can be converted into sound grades of lumber ("standard and better" framing lumber). Metabolism: The sum of the physical and chemical processes involved in the maintenance of life and by which energy is made available to the organism. Methane (CH4): The major component of natural gas. It can be formed by anaerobic digestion of biomass or gasification of coal or biomass. 195 Methanol (wood alcohol) (CH3OH): A Methyl alcohol having the chemical formula CH30H. Also known as wood alcohol, methanol is usually produced by chemical conversion at high temperatures and pressures. Although usually produced from natural gas, methanol can be produced from gasified biomass (syngas). Microorganism: Any microscopic organism such as yeast, bacteria, fungi, etc. Mill residue: Wood and bark residues produced in processing logs into lumber, plywood, and paper. OR Excess material generated from wood processing mills and pulp and paper mills. Mill/kWh: A common method of pricing electricity in the United States. Tenths of a U.S. cent per kilowatt hour. Mixed Stand — A timber stand containing two or more prominent species in the main canopy. MMBtu — One million British thermal units. Moisture Content — The weight of the water contained in wood, usually expressed as a percentage of weight, either oven-dry or as received (green). Moisture content, dry basis - Moisture content expressed as a percentage of the weight of oven-dry wood, i.e.: [(weight of wet sample - weight of dry sample) / weight of dry sample] x 100 Moisture content, wet basis - Moisture content expressed as a percentage of the weight of wood as-received, i.e.: [(weight of wet sample - weight of dry sample) / weight of wet sample] x 100 Moisture: The amount of water and other components present in the biomass sample that are volatilized at 105ºC. Moisture-free basis: Biomass composition and chemical analysis data is typically reported on a moisture free or dry weight basis. Moisture (and some volatile matter) is removed prior to analytical testing by heating the sample at 105ºC to constant weight. By definition, samples dried in this manner are considered moisture free. Monoculture: The cultivation of a single species crop. Monosaccharide: A simple sugar such as a five-carbon sugar (xylose, arabinose) or sixcarbon sugar (glucose, fructose). Sucrose, on the other hand is a disaccharide, composed of a combination of two simple sugar units, glucose and fructose. Municipal solid waste (MSW): Any organic matter, including sewage, industrial, and commercial wastes, from municipal waste collection systems. Municipal waste does not include agricultural and wood wastes or residues. National Environmental Policy Act (NEPA) - A federal law enacted in 1969 that requires all federal agencies to consider and analyze the environmental impacts of any proposed action. NEPA requires an environmental impact statement for major federal actions significantly affecting the quality of the environment. NEPA requires federal agencies to inform and involve the public in the agency´s decision making process and to consider the environmental impacts of the agency´s decision. Native lignin: Lignin as it exists in the lignocellulosic complex before separation. net heat of combustion: See lower heating value. Natural Stand — A stand of trees grown from natural seed fall or sprouting. Negotiated Sale — A timber sale in which the buyer and seller negotiate a price for the standing timber. The standing timber is either marked or is in a delineated area. Net Annual Growth — The average annual net increase in the volume of trees during the period between inventoies. Net heat of combustion: See lower heating value. Net Metering - For those consumers who have their own electricity generating units, net metering allows for the flow of electricity both to and from the customer through a single, bi-directional meter. With net metering, during times when the customer's generation exceeds his or her use, electricity from the customer to the utility offsets electricity consumed at another time. In effect, the customer is using the excess 196 generation to offset electricity that would have been purchased at the retail rate. Under most state rules, residential, commercial, and industrial customers are eligible for net metering, but some states restrict eligibility to particular customer classes. Net present value: The sum of the costs and benefits of a project or activity. Future benefits and costs are discounted to account for interest costs. Neutral detergent fiber (NDF): Organic matter that is not solubilized after one hour of refluxing in a neutral detergent consisting of sodium lauryl sulfate and EDTA at pH 7. NDF includes hemicellulose, cellulose, and lignin. Nitrogen fixation: The transformation of atmospheric nitrogen into nitrogen compounds that can be used by growing plants. Nitrogen oxides (NOx): A product of photochemical reactions of nitric oxide in ambient air; the major component of photochemical smog. OR Gases consisting of one molecule of nitrogen and varying numbers of oxygen molecules. Nitrogen oxides are produced from the burning of fossil fuels. In the atmosphere, nitrogen oxides can contribute to the formation of photochemical ozone (smog), can impair visibility, and have health consequences; they are thus considered pollutants. Nonattainment area - Any area that does not meet the national primary or secondary ambient air quality standard established by the Environmental Protection Agency for designated pollutants, such as carbon monoxide and ozone. Non-condensing, controlled extraction turbine: A turbine that bleeds part of the main steam flow at one (single extraction) or two (double extraction) points. Non-forest land: Land that has never supported forests and lands formerly forested where use of timber management is precluded by development for other uses. OR Land that has never supported forests and lands formerly forested where use of timber management is precluded by development for other uses. (Note: Includes area used for crops, improved pasture, residential areas, city parks, improved roads of any width and adjoining clearings, powerline clearings of any width, and 1- to 4.5-acre areas of water classified by the Bureau of the Census as land. If intermingled in forest areas, unimproved roads and nonforest strips must be more than 120 feet wide, and clearings, etc., must be more than 1 acre in area to qualify as nonforest land.) Nonindustrial Private Forest (NIPF) — Forest land that is privately owned by individuals or corporations other than forest industry. Non-industrial private: An ownership class of private lands where the owner does not operate wood-using processing plants. Non-renewable resource: A resource that cannot be replaced after use. Although fossil fuels like coal and oil are in fact fossilized biomass resources, they form at such a slow rate, that in practice, they are non-renewable. Octane rating (octane number): A measure of a fuel's resistance to self-ignition, hence a measure of the antiknock properties of the fuel. Diesel fuel has a low octane rating, while gasoline and alcohol have high octane ratings, suitable for spark-ignition engines. Oilseed crops - Primarily soybeans, sunflower seed, canola, rapeseed, safflower, flaxseed, mustard seed, peanuts and cottonseed, used for the production of cooking oils, protein meals for livestock, and industrial uses. Old growth: Timber stands marked by the following characteristics: large mature and over-mature trees in the overstory, snags, dead and decaying logs on the ground, and a multi-layered canopy with trees of several age classes. On the Stump — Standing, uncut timber. One-pass Method — A harvest practice where biomass and conventional roundwood (sawlogs) are harvested and recovered simultaneously. Open-loop biomass - Biomass that can be used to produce energy and bioproducts even though it was not grown specifically for this purpose. Examples of open-loop biomass include agricultural livestock waste and 197 residues from forest harvesting operations and crop harvesting. Organic compound: Compound containing carbon chemically bound to hydrogen. Often contain other elements (particularly O, N, halogens, or S). Organic residuals: Surplus or waste organic materials derived from biomass, including, but not necessarily limited to products, production and processing wastes and byproducts, remnants, bodily fluids, excrement or effluents derived from plants, animals, or microorganisms that have been previously used, processed, preprocessed, or remain after their primary production or use has occurred. Other forest land: Forest land other than timberland and reserved forest land. It includes available forest land, which is incapable of annually producing 20 cubic feet per acre of industrial wood under natural conditions because of adverse site conditions such as sterile soils, dry climate, poor drainage, high elevation, steepness, or rockiness. Other removals: Unutilized wood volume from cut or otherwise killed growing stock, from cultural operations such as precommercial thinnings, or from timberland clearing. Does not include volume removed from inventory through reclassification of timberland to productive reserved forest land. Other sources: Sources of roundwood products that are not growing stock. These include salvable dead, rough, and rotten trees, trees of noncommercial species, trees less than 5.0 inches dbh, tops, and roundwood harvested from nonforest land (for example, fence rows). Output — The value of production by industry for a specific time period. Oven dry ton: An amount of wood that weighs 2,000 pounds at 0% moisture content. Overstory — The portion of the trees forming the uppermost canopy in a forest stand. Oxygenate: A compound which contains oxygen in its molecular structure. Ethanol and biodiesel act as oxygenates when they are blended with conventional fuels. Oxygenated fuel improves combustion efficiency and reduces tailpipe emissions of CO. OR A substance which, when added to gasoline, increases the amount of oxygen in that gasoline blend. Includes fuel ethanol, methanol, and methyl tertiary butyl ether (MTBE). Ozone: A compound formed when oxygen and other compounds react in sunlight. In the upper atmosphere, ozone protects the earth from the sun's ultraviolet rays. Though beneficial in the upper atmosphere, at ground level, ozone is called photochemical smog, and is a respiratory irritant and considered a pollutant. OR A compound that is formed when oxygen and other compounds react in sunlight. In the lower atmosphere (groundlevel) it is photochemical smog and is considered a pollutant. Particulates: A fine liquid or solid particle such as dust, smoke, mist, fumes, or smog, found in air or emissions. OR A small, discrete mass of solid or liquid matter that remains individually dispersed in gas or liquid emissions. Particulates take the form of aerosol, dust, fume, mist, smoke, or spray. Each of these forms has different properties. Per-unit Sale — A timber sale in which the buyer and seller negotiate a price per unit of harvested wood, and the buyer pays for the timber after it is cut and the volume is determined. Petrochemical Feedstock — Petroleum (hydrocarbon) based substance used as a raw material in an industrial process. Examples Petroleum: Substance comprising a complex blend of hydrocarbons derived from crude oil through the process of separation, conversion, upgrading, and finishing, including motor fuel, jet oil, lubricants, petroleum solvents, and used oil. Phloem: The principal tissue in a tree concerned with the transport of sugars and other nutrients from the leaves. In plants, the inner bark. Photoautotroph: An organism, typically a plant, obtaining energy from sunlight as its source of energy to convert inorganic materials into organic materials for use in 198 cellular functions such as biosynthesis and respiration. Photoconversion: Conversion of light into other forms of energy by chemical, biological, or physical processes. Photoheterotroph: Heterotrophic organisms that use light for energy, but cannot use carbon dioxide as their sole carbon source. Consequently, they use organic compounds from the environment to satisfy their carbon requirements such as carbohydrates, fatty acids, and alcohols. Examples are purple nonsulfur bacteria, green non-sulfur bacteria, and heliobacteria. Photosynthesis: A complex process used by many plants and bacteria to build carbohydrates from carbon dioxide and water, using energy derived from light. Photosynthesis is the key initial step in the growth of biomass and is depicted by the equation: CO2 + H2O + light + chlorophyll = (CH2O) + O2 OR A complex process that occurs in the chlorophyll cells of plants to build carbohydrates from carbon dioxide and water, using energy derived from light. OR Process by which chlorophyll-containing cells in green plants concert incident light to chemical energy, capturing carbon dioxide in the form of carbohydrates. Pilot scale: The size of a system between the small laboratory model size (bench scale) and a full-size system. Plantation — Planted pines or hardwoods, typically in an ordered configuration such as equally spaced rows. Poletimber trees: Live trees at least 5.0 inches in dbh, but smaller than sawtimber trees. OR Trees from 5 to 7 inches in diameter at breast height. Polymer: A large molecule made by linking smaller molecules ("monomers") together. Polysaccharide: A carbohydrate consisting of a large number of linked simple sugar, or monosaccharide, units. Examples of polysaccharides are cellulose and starch. Pour point - The minimum temperature at which a liquid, particularly a lubricant, will flow. Pre-commercial Thinning — Thinning that occurs when trees are too young, too small, or of species undesirable to be used for traditional timber products. Prescribed fire - Any fire ignited by management actions to meet specific objectives. Prior to ignition, a written, approved prescribed fire plan must exist, and National Environmental Protection Act requirements must be met. Present value: The worth of future receipts or costs expressed in current value. To obtain present value, an interest rate is used to discount future receipts or costs. Primary wood-using mill: A mill that converts roundwood products into other wood products. Common examples are sawmills that convert saw logs into lumber and pulp mills that convert pulpwood roundwood into wood pulp. Process development unit: An experimental facility that establishes proof of concept, preliminary process economics, and engineering feasibility for a pilot or demonstration plant. Process heat: Energy, usually in the form of hot air or steam, needed in the manufacturing operations of an industrial plant. OR Heat used in an industrial process rather than for space heating or other housekeeping purposes. Producer gas: Fuel gas high in carbon monoxide (CO) and hydrogen (H2), produced by burning a solid fuel with insufficient air or by passing a mixture of air and steam through a burning bed of solid fuel. Proof: The ethanol content of a liquid at 60°F, stated as twice the percent by volume of the ethyl alcohol. Protein: A chain of up to several hundred amino acids, folded into a more or less compact structure. About 20 different amino acids are used by living matter in making proteins, making the variety of protein types numerous. In their biologically active states, proteins function as catalysts in metabolism and to some extent as structural elements of cells and tissues. Protein content in biomass (in mass %) can be estimated by multiplying the mass % nitrogen of the sample by 6.25. Proximate analysis: The determination, by prescribed methods, of moisture, volatile 199 matter, fixed carbon (by difference), and ash. Does not include determinations of chemical elements or determinations other than those named. The group of analyses is defined in ASTM D 3172. OR An analysis which reports volatile matter, fixed carbon, moisture content, and ash present in a fuel as a percentage of dry fuel weight. Public power - The term used for not-forprofit utilities that are owned and operated by a municipality, state or the federal government. Public utility commissions: State agencies that regulate investor-owned utilities operating in the state. Public Utility Regulatory Policies Act (PURPA): A federal law requiring a utility to buy the power produced by a qualifying facility at a price equal to that which the utility would otherwise pay if it were to build its own power plant or buy power from another source. Pulp chips - Timber or residues processed into small pieces of wood of more or less uniform dimensions with minimal amounts of bark. Pulpwood: Roundwood, whole-tree chips, or wood residues that are used for the production of wood pulp. OR Wood used in the manufacture of paper, fiberboard, or other wood fiber products. Pulpwood- sized trees are usually a minimum of 4 inches in diameter. Pyrolysis: The breaking apart of complex molecules by heating in the absence of oxygen, producing solid, liquid, and gaseous fuels. OR The thermal decomposition of biomass at high temperatures (greater than 400° F, or 200° C) in the absence of air. The end product of pyrolysis is a mixture of solids (char), liquids (oxygenated oils), and gases (methane, carbon monoxide, and carbon dioxide) with proportions determined by operating temperature, pressure, oxygen content, and other conditions. Quad: One quadrillion Btu (1015 Btu) = 1.055 exajoules (EJ), or approximately 172 million barrels of oil equivalent. Reaction: A dissociation, recombination, or rearrangement of atoms. Reburning - Reburning entails the injection of natural gas, biomass fuels, or other fuels into a coal-fired boiler above the primary combustion zone—representing 15 to 20 percent of the total fuel mix—can produce NOx reductions in the 50 to 70 percent range and SO2reductions in the 20 to 25 percent range. Reburning is an effective and economic means of reducing NOx emissions from all types of industrial and electric utility boilers. Reburning may be used in coal or oil boilers, and it is even effective in cyclone and wetbottom boilers, for which other forms of NOx control are either not available or very expensive. Recombinant DNA: DNA that has been artificially introduced into a cell, resulting in alteration of the genotype and phenotype of the cell, and is replicated along with natural DNA. Used in industrial micro-organisms to produce more productive strains. Recovery boiler: A pulp mill boiler in which lignin and spent cooking liquor (black liquor) is burned to generate steam. Reforestation — Reestablishing a forest by planting or seeding an area from which forest vegetation has been removed. Refractory lining: A lining capable of resisting and maintaining high temperatures. Usually ceramic. Refuse-derived fuel (RDF): Fuel prepared from municipal solid waste. Noncombustible materials such as rocks, glass, and metals are removed, and the remaining combustible portion of the solid waste is chopped or shredded. RDF facilities process typically between 100 and 3,000 tons of MSW per day. Regeneration Cut — A cutting strategy in which old trees are removed while favorable environmental conditions are created for the establishment of a new stand of seedlings. Renewable diesel - Defined in the Internal Revenue Code (IRC) as fuel produced from biological material using a process called "thermal depolymerization" that meets the fuel specification requirements of ASTM D975 (petroleum diesel fuel) or ASTM D396 (home heating oil). Produced in free-standing facilities. 200 Renewable energy resource: An energy resource that can be replaced as it is used, including solar, wind, geothermal, hydro, and biomass. Municipal solid waste (MSW) is also considered to be a renewable energy resource. Renewable Fuel Standards - Under the Energy Policy Act of 2005, EPA is responsible for promulgating regulations to ensure that gasoline sold in the United States contains a minimum volume of renewable fuel. A national Renewable Fuel Program (also known as the Renewable Fuel Standard Program, or RFS Program) will increase the volume of renewable fuel required to be blended into gasoline, starting with 4.0 billion gallons in calendar year 2006 and nearly doubling to 7.5 billion gallons by 2012. The RFS program was developed in collaboration with refiners, renewable fuel producers, and many other stakeholders. Renewables Portfolio Standards/Set Asides Renewables Portfolio Standards (RPS) require that a certain percentage of a utility's overall or new generating capacity or energy sales must be derived from renewable resources, i.e., 1% of electric sales must be from renewable energy in the year 200x. Portfolio Standards most commonly refer to electric sales measured in megawatt-hours (MWh), as opposed to electric capacity measured in megawatts (MW). The term "set asides" is frequently used to refer to programs where a utility is required to include a certain amount of renewables capacity in new installations. Reproduction — (a) The process by which young trees grow to become the older trees of the future forest. (b) The process of forest replacement or renewal through natural sprouting or seeding or by the planting of seedlings or direct seeding. Reserve margin: The amount by which the utility's total electric power capacity exceeds maximum electric demand. Residual Stand — Trees left in a stand to grow until the next harvest. This term can refer to crop trees or cull trees. Residues - Bark and woody materials that are generated in primary wood-using mills when roundwood products are converted to other products. Examples are slabs, edgings, trimmings, sawdust, shavings, veneer cores and clippings, and pulp screenings. Includes bark residues and wood residues (both coarse and fine materials) but excludes logging residues. Residues, biomass: By-products from processing all forms of biomass that have significant energy potential. For example, making solid wood products and pulp from logs produces bark, shavings and sawdust, and spent pulping liquors. Because these residues are already collected at the point of processing, they can be convenient and relatively inexpensive sources of biomass for energy. OR Byproducts that have significant energy potential from processing all forms of biomass. Return on investment- (ROI) The interest rate at which the net present value of a project is zero. Multiple values are possible. Return on investment (ROI): The interest rate at which the net present value of a project is zero. Multiple values are possible. Rotation: Period of years between establishment of a stand of timber and the time when it is considered ready for final harvest and regeneration. OR The number of years required to establish and grow trees to a specified size, product, or condition of maturity. Rotten tree: A live tree of commercial species that does not contain a saw log now or prospectively, primarily because of rot (that is, when rot accounts for more than 50% of the total cull volume). Rough tree: (a) A live tree of commercial species that does not contain a saw log now or prospectively primarily because of roughness (that is, when sound cull due to such factors as poor form, splits, or cracks accounts for more than 50% of the total cull volume) or (b) a live tree of noncommercial species. Roundwood products: Logs and other round timber generated from harvesting trees for industrial or consumer use. 201 Saccharide: A simple sugar or a more complex compound that can be hydrolyzed to simple sugar units. Saccharification: A conversion process using acids, bases, or enzymes in which long-chain carbohydrates are broken down into their component fermentable sugars. OR The process of breaking down a complex carbohydrate, such as starch or cellulose, into its monosaccharide components. Salvable dead tree: A downed or standing dead tree that is considered currently or potentially merchantable by regional standards. Salvage Cutting — Removal of trees that have dead, damaged, or are expected to die, generally as a result of natural disaster, pest infestation, or disease infestation. Sanitation Cut — Removal of dead and weaker trees in an overstocked stand to reduce the danger of natural disasters. Saplings: Live trees 1.0 inch through 4.9 inches dbh. Saturated steam: Steam at boiling temperature for a given pressure. Screen analysis: Method for measuring a proportion of variously sized particles in solid fuels. The sample is passed through a series of screens of known size openings. Biomass fuel screen sizes usually range from 5 to 100 openings per inch. Scrubber: An air pollution control device that uses a liquid or solid to remove pollutants from a gas stream by adsorption or chemical reaction. Secondary wood processing mills: A mill that uses primary wood products in the manufacture of finished wood products, such as cabinets, moldings, and furniture. Seed-tree Harvest — A silvicultural system in which all trees are harvested except for a small number of selected trees are retained for seed production for natural regeneration. Shaft horsepower: A measure of the actual mechanical energy per unit time delivered to a turning shaft. See also horsepower. Shelterwood Harvest — A silvicultural system in which trees are removed in a series of two or more cuts, leaving those needed to produce sufficient shade to produce a new forest in a moderated microenvironment. This method produces an even-aged forest. Short Rotation Intensive Culture (SRIC): Growing tree crops for bioenergy or fiber, characterized by detailed site preparation, usually less than 10 years between harvests, usually fast-growing hybrid trees, and intensive management (some fertilization, weed and pest control, and possibly irrigation). Short-rotation Woody Crops — Fast growing species, such as willows and poplars, which are grown specifically for the production of energy. Shredder — A machine that tears material apart by shearing. Silviculture: Theory and practice of controlling the establishment, composition, structure, and growth of forests and woodlands. OR Science and art of managing the establishment, growth, composition, and quality of forest stands and woodlands for the desired needs and values of landowners and society on a sustainable basis. Site Index — See Site Productivity. Site Productivity — Combination of soil and climatic factors contributing to plant growth and development; may be measured as biomass accumulation per unit of time. Skidder — Machinery used to pull logs from their stump to a landing. Logs are pulled with a grapple, cable-winch, or clam-bunk. Slagging - The coating of internal surfaces of fireboxes and in boilers from deposition of ash particles. Slash — (a) Tree tops, branches, bark, or other residue left on the ground after logging or other forestry operations. (b) Tree debris left after a natural catastrophe. Slow pyrolysis: Thermal conversion of biomass to fuel by slow heating to less than 842°F (450°C), in the absence of oxygen. Softwood (conifer): Generally, one of the botanical groups of trees that in most cases have needle-like or scale-like leaves; the conifers; also the wood produced by such trees. The term has no 202 reference to the actual hardness of the wood. The botanical name for softwoods is gymnosperms. OR A tree belonging to the order Coniferales. Softwood trees are usually evergreen, bear cones, and have needles or scale-like leaves. Soil Fertility — The total availability, concentration, and amount of essential plant nutrients. Soil Function — The role that soils play in the environment and managed landscapes. Soil Productivity — The capacity of a soil to contribute to the production of a crop, whether it is agricultural crops or forest biomass. Sound dead: The net volume in salvable dead trees. Species: A group of organisms that differ from all other groups of organisms and that are capable of breeding and producing fertile offspring. This is the smallest unit of classification for plants and animals. OR This notation means that many species within a genus are included but not all. SRIC - Short rotation intensive culture - the growing of tree crops for bioenergy or fiber, characterized by detailed site preparation, usually less than 10 years between harvests, usually fast-growing hybrid trees and intensive management (some fertilization, weed and pest control, and possibly irrigation). Stand — A group of trees of similar ageclass, composition, and structure growing on a site of uniform quality. Stand density - The number or mass of trees occupying a site. It is usually measured in terms of stand density index or basal area per acre. Stand (of trees): Tree community that possesses sufficient uniformity in composition, constitution, age, spatial arrangement, or condition to be distinguishable from adjacent communities. Starch: A molecule composed of long chains of a-glucose molecules linked together (repeating unit C12H16O5). These linkages occur in chains of a-1,4 linkages with branches formed as a result of a-1,6 linkages (see below). This polysaccharide is widely distributed in the vegetable kingdom and is stored in all grains and tubers. OR A naturally abundant nutrient carbohydrate, found chiefly in the seeds, fruits, tubers, roots, and stem pith of plants, notably in corn, potatoes, wheat, and rice, and varying widely in appearance according to source but commonly prepared as a white amorphous tasteless powder. Steam turbine: A device for converting energy of high-pressure steam produced in a boiler into mechanical power. This power can then be used to generate electricity. stocked pine forest may have a basal area of 80 to 120 square Stocking — A description of the number of trees, basal area, or volume per acre in a forest stand compared with a desired level for balanced health and growth. Most often used in comparative expressions, such as wellstocked, poorly stocked, or overstocked. Stover: The dried stalks and leaves of a crop that remain after the grain has been harvested. Streamside Management Zones — Buffer zones in which cover is retained in riparian areas adjacent to surface water and aquatic habitat. Structural chemical analysis: The composition of biomass reported by the proportions of the major structural components: cellulose, hemicellulose, and lignin. Typical ranges are shown in the table below. Stumpage — The value or volume of a tree or group of trees as they stand uncut in the woods (on the stump). Substrate: The base on which an organism lives or a substance acts upon (as by an enzyme). Sulfur Dioxide (SO2) - Formed by combustion of fuels containing sulfur, primarily coal and oil. Major health effects associated with SO2include asthma, respiratory illness, and aggravation of existing cardiovascular disease. SO2 combines with water and oxygen in the atmosphere to form acid rain, which raises the acid levels of lakes and streams, affecting the ability of fish and some amphibians to survive. It also damages sensitive forests and 203 ecosystems, particularly in the eastern part of the US. It also accelerates the decay of buildings. Making electricity is responsible for two-thirds of all Sulfur Dioxide. Superheated steam: Steam that is hotter than boiling temperature for a given pressure. Surplus electricity: Energy produced by cogeneration equipment in excess of the needs of an associated factory or business. Sustainability — The capacity of forests to maintain their health, productivity, diversity, and overall integrity, in the long run, in the context of human activity and use. Sustainability can apply to single forest or ecoregions. Sustainable Forest Management — Forest management that ensures that forest resources will be managed to supply goods and services to meet the current demands of society while conserving and renewing the availability and quality of the resource for future generations. Sustainable: An ecosystem condition in which biodiversity, renewability, and resource productivity are maintained over time. Sustained Yield — A forest management strategy in which the net growth and yield are balanced. Switchgrass - Panicum virgatum, is a native grass species of the North American Praries that has high potential as an herbaceous energy crop. The relatively low water and nutrient requirements of switchgrass make it well suited to marginal land and it has longterm, high yield productivity over a wide range of environments. Syngas — A gas mixture that contains varying amounts of carbon monoxide and hydrogen generated by the gasification of a carbonbased fuel to a gaseous product with a heating value. Synthetic ethanol - Ethanol produced from ethylene, a petroleum by-product. Syringyl: A component of lignin, normally only found in hardwood lignins. It has a six-carbon aromatic ring with two methoxyl groups attached. Systems benefit charge - A small surcharge collected through consumer electric bills that are designated to fund certain "public benefits" that are placed at risk in a more competitive industry. Systems benefit charges typically help to fund renewable energy, research and development, and energy efficiency. Tar: A liquid product of thermal processing of carbonaceous materials. Therm: A unit of energy equal to 100,000 Btus (= 105.5 MJ); used primarily for natural gas. Thermal NOx - Nitrous Oxide (NOx) emissions formed at high temperature by the reaction of nitrogen present in combustion air. cf. fuel NOx. Thermochemical conversion: The use of heat to chemically change substances to produce energy products. Thinning — A tree removal practice that reduces tree density and competition among remaining trees in a stand. Timber Product Output Database Retrieval System (TPO): System developed in support of the 1997 Resources Planning Act (RPA) Assessment System, acting as an interface to a standard set of consistently coded TPO data for each state and county in the United States. This national set of TPO data consists of 11 data variables that describe for each county the roundwood products harvested, the logging residues left behind, the timber otherwise removed, and the wood and bark residues generated by its primary wood-using mills. Timber Stand Improvement (TSI) — Improving the quality of a forest stand by removing or deadening undesirable species to achieve desired stocking and species composition. TSI practices include applying herbicides, burning, girdling, or cutting. Timberland: Forest land that is producing, or is capable of producing, crops of industrial wood and that is not withdrawn from timber utilization by statute or administrative regulation. Areas qualifying as timberland are capable of producing more than 20 cubic feet per acre per year of industrial wood in natural stands. Currently inaccessible and inoperable areas are included. Tipping fee: A fee for disposal of waste. Tolerant Species — A species of tree that 204 has the ability to grow in the shade of other trees and in competition with them. Ton (tonne): One U.S. ton (short ton) = 2,000 pounds. One Imperial ton (long ton or shipping ton) = 2,240 pounds. One metric tonne (tonne) = 1,000 kilograms (2,205 pounds). One oven-dry ton or tonne (ODT, sometimes termed bone-dry ton/tonne) is the amount of wood that weighs one ton/tonne at 0% moisture content. One green ton/tonne refers to the weight of undried (fresh) biomass material - moisture content must be specified if green weight is used as a fuel measure. Topping and back pressure turbines: Turbines that operate at exhaust pressure considerably higher than atmospheric (noncondensing turbines). These turbines are often multistage types with relatively high efficiency. Topping cycle: A cogeneration system in which electric power is produced first. The reject heat from power production is then used to produce useful process heat. Total lignin: The sum of the acid soluble lignin and acid insoluble lignin fractions. Total solids: The amount of solids remaining after all volatile matter has been removed from a biomass sample by heating at 105ºC to constant weight. (Source: Ehrman, T. Standard Method for Determination of Total Solids in Biomass. NREL-LAP-001. Golden, CO: National Renewable Energy Laboratory, October 28, 1994.) Toxics: Substances including benzene, 1, 3 butadiene, formaldehyde, acetaldehyde, and polycyclic organic matter, as defined in the 1990 Clean Air Act Amendments. Transesterification: A process that includes chemical reactions of alcohols and triglycerides contained in vegetable oils and animal fats to produce biodiesel and glycerin. Transmission: The process of long-distance transport of electrical energy, generally accomplished by raising the electric current to high voltages. Transpiration Drying — The natural drying that occurs when leafy biomass material is left on the tree. Traveling grate: A type of furnace in which assembled links of grates are joined together in a perpetual belt arrangement. Fuel is fed in at one end and ash is discharged at the other. Tree-length — Trees felled, delimbed, and topped in the stump area and processed at the landing. Triglyceride: A combination of glycerol and three fatty acids. Most animal fats are comprised primarily of triglycerides. Trommel screen - A revolving cylindrical sieve used for screening or sizing compost, mulch, and solid biomass fuels such as wood chips. Tub grinder - A shredder used primarily for woody, vegetative debris. A tub grinder consists of a hammermill, the top half of which extends up through the stationary floor of a tub. As the hammers encounter material, they rip and tear large pieces into smaller pieces, pulling the material down below the tub floor and ultimately forcing it through openings in a set of grates below the mill. Various sized openings in the removable grates are used to determine the size of the end product. Turbine: A machine used to convert energy, such as converting the heat energy in steam or high temperature gas into mechanical energy. OR A machine for converting the heat energy in steam or high temperature gas into mechanical energy. In a turbine, a high velocity flow of steam or gas passes through successive rows of radial blades fastened to a central shaft. Turn down ratio: The lowest load at which a boiler will operate efficiently as compared to the boiler's maximum design load. Two-pass Method — A harvest practice where roundwood and biomass are recovered in separate passes. Biomass removal can precede or follow the conventional product harvest. Ultimate analysis: The determination of the elemental composition of the organic portion of carbonaceous materials. See elemental analysis. OR A description of a fuel´s elemental composition as a percentage of the dry fuel weight. Understory — (a) The layer formed by the crowns of smaller trees in a forest. (b) The trees beneath the forest canopy 205 Uneven-aged Management — A regeneration and management technique that removes some trees in all size classes either singly, in small groups, or strips in order to maintain a multi-aged stand. Unmerchantable wood - Material which is unsuitable for conversion to wood products due to poor size, form, or quality. Urban Residues — Wood and yard waste; construction and demolition debris from an urban source. Urban wood waste - Woody biomass generated from tree and yard trimmings, the commercial tree care industry, utility line thinning to reduce wildfire risk or to improve forrest health, and greenspace maintenance. Uronic acid: A simple sugar whose terminal CH2OH group has been oxidized to an acid, COOH group. The uronic acids occur as branching groups bonded to hemicelluloses such as xylan. (Source: Milne, T.A.; Brennan, A.H.; Glenn, B.H. Sourcebook of Methods of Analysis for Biomass Conversion and Biomass Conversion Processes. SERI/SP-220-3548. Golden, CO: Solar Energy Research Institute, February 1990.) Vacuum distillation: The separation of two or more liquids under reduced vapor pressure; reduces the boiling points of the liquids being separated. Value-added — Payments made by industry to workers, interest, profits, and indirect business taxes. Volatile matter - Those products, exclusive of moisture, given off by a material as a gas or vapor, determined by definite prescribed methods that may vary according to the nature of the material. One definition of volatile matter is part of the proximate analysis group usually determined as described in ASTM D 3175. Volatile matter: Those products, exclusive of moisture, given off by a material as a gas or vapor, determined by definite prescribed methods that may vary according to the nature of the material. Volatile organic compounds (VOC) - Nonmethane hydrocarbon gases, released during combustion or evaporation of fuel. Volatile: A solid or liquid material that easily vaporizes. Waste streams: Unused solid or liquid byproducts of a process. Water Quality — Suitability of the water coming from ground and surface water supplies for drinking water, recreational uses, and as habitat for aquatic organisms and other wildlife. OR Timing and total yield of water from a watershed. Water-cooled vibrating grate: A boiler grate made up of a tuyere grate surface mounted on a grid of water tubes interconnected with the boiler circulation system for positive cooling. The structure is supported by flexing plates allowing the grid and grate to move in a vibrating action. Ashes are automatically discharged. Watershed: The drainage basin contributing water, organic matter, dissolved nutrients, and sediments to a stream or lake. Watt: The common base unit of power in the metric system. One watt equals one joule per second, or the power developed in a circuit by a current of one ampere flowing through a potential difference of one volt. One Watt = 3.412 Btu/hr. See kilowatt and megawatt. Wet scrubber: An air pollution control device used to remove pollutants by bringing a gas stream into contact with a liquid. Wheeling: The process of transferring electrical energy between buyer and seller by way of an intermediate utility or utilities. Whole tree chips: Wood chips produced by chipping whole trees, usually in the forest, so that the chips contain both bark and wood. They are frequently produced from the lowquality trees or from tops, limbs, and other logging residues. Whole-tree chips - Wood chips produced by chipping whole trees, usually in the forest. Thus the chips contain both bark and wood. They are frequently produced from the low-quality trees or from tops, limbs, and other logging residues. OR Trees are felled and transported to roadside with branches and top intact. 206 Processing occurs at the deck or landing. OR A harvesting method in which the whole tree (above the stump) is removed. Willstatter lignin: Lignin obtained from the lignocellulosic complex after it has been extracted with hydrochloric acid. Wood Ash — Ash recovered from the combustion of woody biomass; may be used as fertilizer or soil liming agent to reduce soil acidity. Wood Processing Residue — The unused portion of materials generated during wood processing or by-products created during the pulping process. Wood: A solid lignocellulosic material naturally produced in trees and some shrubs, made of up to 40%–50% cellulose, 20%–30% hemicellulose, and 20%–30% lignin. Woody Biomass — The trees and woody plants, including limbs, tops, needles, leaves, and other woody parts, grown in a forest, woodland, or rangeland environment that are the byproducts of proper forest management. Wort: The liquid remaining from a brewing mash preparation following the filtration of fermentable beer. Xylan: A polymer of xylose with a repeating unit of CHO, found in the hemicellulose fraction of biomass. Can be hydrolyzed to xylose. Xylose (C5H10O5): A five-carbon sugar. A product of hydrolysis of xylan found in the hemicellulose fraction of biomass. Yarding : The initial movement of logs from the point of felling to a central loading area or landing, particularly by cable or helicopter. Yeast: Any of various single-cell fungi capable of fermenting carbohydrates. 207 PRACTICAL NO.01 PRACTICAL 208 IDENTIFICATION OF IMPORTANT FUEL WOODS AND PETRO-CROPS. IDENTIFICATION OF IMPORTANT FUEL WOODS AND PETRO-CROPS. PRACTICAL NO.02 STUDY OF DIFFERENT PROPERTIES OF BIO FUELS USED IN PAKISTAN. 209 STUDY OF DIFFERENT PROPERTIES OF BIO FUELS USED IN PAKISTAN. PRACTICAL NO.03 DETERMINATION OF CALORIFIC VALUE, MOISTURE AND ASH CONTENT IN BIOMASS. 210 DETERMINATION OF CALORIFIC VALUE, The gross calorific value (GCV) and, in particular, the net calorific value (NCV) are fundamental physical parameters in the use of energetic biomass. The method of measurement and the calculation of the GCV, defined by CEN/TS 14918, is rather complex and, in many cases, has a time and cost importance. In literature there are some studies in which the empirical correlations between GCV and the element composition have been calculated. In these contribution some of the most significant correlations in literature are tested and compared to others obtained from statistical processing of data from analysis on 200 samples of biomass carried out in the laboratory and with standard CEN methods. The study shows how the very simplified correlations based on the calculation of carbon and hydrogen content have performances that are similar to those of more complex ones based on the greater number of parameters. In particular, the empirical correlation (GCV=297.6+389.7C) produced from this work has errors that are comparable to those of the better correlation highlighted by literature (GCV=5.22C2-319C-1647H+38.6C.H+133N+21028). Biomass is becoming increasingly important as a renewable source of energy, by incineration as well as production of liquid biofuels, e. g. biodiesel or bioethanol. Compared to the incineration of fossil fuels the overall CO2 balance is considerably less affected by the usage of biomass. Typical biomass materials used for energy production are wood and so-called energy grass. Special types of cereals have a century old tradition in (bio-)alcohol production, recent developments also consider cereal incineration. An important property of a fuel is its heating value. The so called "higher heating value" (HHV) is the enthalpy of complete combustion of a fuel with all carbon converted to CO2, and all hydrogen converted to H2O. The higher heating value is given for standard conditions (101.3 kPa, 25 oC) of all products and includes the condensation enthalpy of water; it is generally used in the USA. In European countries the "lower heating value" - not used in this study - is more common. It does not include the condensation enthalpy of water. Direct determination of the heating value requires time-consuming calorimetric experiments, which hardly can be automated. Empirical equations have been K. Varmuza, B. Liebmann, A. Friedl published that relate the heating value of a fuel to its elemental composition. Elemental analysis requires tedious laboratory work too, but can be automated. Early mathematical models for coal date back to the late 19th century. Recently, modern chemometric methods have been applied for prediction of heating values of plant biomass from elemental composition. Determination of calorific values of some renewable biofuels Jothi V. Kumar *, Benjamin C. Pratt Department of Chemistry, North Carolina A & T State University. Greensboro, North Carolina, 27411, USA Received 16 October 1995; accepted 3 January 1996 The determination of the calorific values as well as the percentages of C, H,N, S, and 0 of biofuels are important in considering their suitability as environmentally safe energy sources. The biofuels tested such as the common milkweed, dogbane, kudzu, and eucalyptus tree can be replenished, unlike fossil and petroleum-based fuels. They are fast-growing renewable energy sources with recovery periods for harvesting ranging from less than a year [l-3] for the weed and vine-type plants [4,5], and up to seven years for eucalyptus tree [6]. The above biomass materials can be converted to synthetic liquid fuels [7,8] and chemical feedstocks [9, lo]. Other benefits of these plants are that they can be used to stop erosion and can be utilized in heating. Currently, about two percent of the U.S. energy consumption comes from woods, agricultural crops with their residues, and municipal and animal wastes plus other sources of biomass [ll, 121. The majority of the energy from biomass comes from its use in the forest industry [13,14]. By the year 2000 up to twenty percent of the U.S. energy consumption could be furnished by biomass [15]. Thermal methods such as differential scanning calorimetry (DSC) and elemental analysis (EA) were employed to determine calorific values of biofuels either directly or indirectly. The biofuels tested were the common milkweed, dogbane, kudzu, and eucalyptus tree. All the biofuels tested were mainly composed of lignocellulosic polymers (hemicellulose, cellulose, and lignin). The milkweed and dogbane contained some latex (liquid hydrocarbons) while kudzu and eucalyptus contained high molecular weight resins and oils respectively. The direct determination of calorific values of fuel materials by differential scanning calorimetry (DSC) was introduced by Fyans in 1977 [16]. This technique measures heat flow as a function of temperature with the total area under the curve being proportional to the heat of combustion. A typical thermocurve shows a two-step decomposition with the 211 first peak relating to the combustion of volatiles and the second to the fixed carbon in the sample. Earnest has reported calorific values for coal samples that are in close agreement with the values published by ASTM [17,18]. Earnest and Fyans [19,20] determined the calorific values of coal and coke specimens from the percentage of volatile matter and fixed carbon using a thermogravimetric technique. A method for calculating the calorific values from the elemental composition has been introduced by Culmo [21]. Percents of carbon, hydrogen, oxygen, sulfur, moisture and ash were used to calculate the calorific values from the Dulong equation. Giazzi and Colombo introduced a modification of this equation for calculating gross and net heat values [22]. Calorific values of standard coal samples determined by DSC and elemental analysis in our laboratory were compared to ASTM values of the same samples. The biofuels were analyzed under the same conditions as the standard coal samples and the calorific values of direct and indirect determinations were compared. 2. Experimental 2.1. Instruments and materials A Mettler DSC 20 with measuring cells containing medium-sensitivity sensors was used to determine calorific values of standard coal samples and biofuels. The instruments were calibrated as per the instructions in the manuals. Determination of C/H/N/S/O was made on a Carlo Erba Elemental Analyzer (EA), Model 1106. A microbalance, Cahn C-31, and an IBM computer were interfaced with the instrument. Eager 100 software of Carlo Erba was used for operating the system and data analysis. The Mettler TG-50 Thermogravimetric Analyzer was used to dry the samples. All gases used were 99.9% pure or better from National Speciality Gases, a division of National Welders Supply. Transparent traps filled with anhydrone and ascarite were added to the lines to absorb traces of moisture and CO 2. Nitrogen used for drying was purified with a Supleco High Capacity Heated Carrier Gas Purifier, catalogue # 2-3802. The standards, sulfanilamide for C/H/N/S and dextrose for oxygen analysis, were provided with the instrument for the standardization and calibration of the instrument. Chemicals to pack the combustion and pyrolysis reactors and other consumables like tin containers were obtained from Erba Company. The coal standards from National Bureau of Standards (NBS) (numbered 2684) a set of 8 premium coal samples from Argonne National Laboratories (ANL), and dextrose sugar were used throughout this work. Due to the decomposition of coal samples after the exposure to atmospheric conditions, a synthetic standard made of microanalytical chemicals was used to calibrate the elemental analyzer. Magnesium oxide, lead chromate (Analytical Reagent, Mallinckrodt), silver oxide (Baker and Adamson), praseodymium oxide, copper oxide (certified ACS, Fisher), and lead dioxide (Fisher) were used as received. 2.2. Sample collection and preparation Plants were collected in Winston-Salem, Kernersville, Greensboro, and Hillsborough, North Carolina. Coal standards were acquired from NBS and the Premium Coal Samples came from ANL. Several whole green plants of milkweed, dogbane, kudzu, and eucalyptus were selected. They were dried separately in a gravity oven (70-120°C for several hours), ground in a Waring blender, and sieved to obtain 100 mesh size samples. The portions that did not pass 100 mesh were kept as coarse ground. Leaves of the biofuels were cut into small pieces for analysis. 2.3. Procedure The Mettler TG-50 was used to dry about 10 mg of the sample in a tared platinum container in the furnace with dry, oxygen-free nitrogen flowing at 300 ml min-I. The sample was dried by slowly heating from 35 to 135°C and held isothermally for either 2 or 5 min depending on the moisture content. If the thermocurve indicated insufficient drying, the isothermal drying was repeated. The samples were then stored in nitrogen atmosphere for further analysis. A screening procedure recommended in the instrument manual for determining the calorific values by DSC was stored on the TC-I OA processor. This included a 10°C min-I heating rate from room temperature to 600°C. The experimental conditions were optimized using a standard coal sample as outlined in Table 1. The sample holders are 40 ul in capacity and each hole is about 0.50 mm in size. Sample weights of about 0.50 mg of coal samples (200 mesh) and biofuels (100 mesh) were integrated over a baseline starting at 105°C to the end of the run. Among the additives (catalysts) tested. a 1: 1 (by weight) magnesium oxide to silver oxide mixture improved the calorific values of both coal and the biofuels (Fig. 1). A Carlo Erba Elemental Analyzer was used to simultaneously analyze the samples for carbon (C), hydrogen(H), nitrogen(N), and sulfur(S). Due to the large differences in the elemental composition of sulfanilamide standards, a synthetic standard was made and used for calibration. The elements, C,H,N and S, were combusted to their respective oxides first. The nitrogen oxides were then reduced to nitrogen and sulfur trioxide to sulfur dioxide by metallic copper in 212 the reactor. The gas chromatographic separation of N2, CO2, H2O and SO2 is shown in Fig. 2. After separation, the gases pass through a detector which sends a signal to an integrator. The integrated values Table 1 Effect of DSC variables on the accuracy of heat value (using a demineralized bituminous coal standard, h.v. of 35672 J g-t-I) Exp. conditions Variable studied HV/Jg-I -I Heating rate/C min Mass approx. 1 mg, open 1 25844 container, and 80 ml min-I 0, flow 2.5 25114 rate 5 28130 10 27316 25 23712 50 21294 Holes in container cover Mass approx. 0.75 mg, 10°C min-I 1 holes 27737 -I heating rate, and 80 ml min flow 2 holes 29282 rate 4 holes 30489 7 holes 28604 8 holes 29885 No cover 27191 Sample mass/mg 10°C min-I heating rate, 80 ml 1.092 27316 min-I flow rate, no cover 0.830 28604 0.432 34287 0.393 30702 -I 0, flow rate/ml min Mass approx. 0.8 mg, heating 40 32392 rate 10°C min-I, no cover 80 27191 240 31370 320 29404 were used to prepare the calibration curves which were then used to calculate the percentages of the various elements present. The analysis of oxygen was carried out in an inert gas stream with the pyrolysis of sample over a catalytic layer of nickel-plated carbon. The oxygen was converted to carbon monoxide (CO) and was separated from any nitrogen on a chromatographic column, Fig. 3. The signal was recorded and integrated as above. Dextrose was used as a standard for oxygen. The gross heat value (GHV) of both coal standards and biofuels were calculated using the equation recommended by Giazzi and Columbo (Table 2). The effect of particle size of the biofuels on the calorific values was also studied to choose the best mesh size of the sample, Table 3. 3. Results and discussion The Mettler TG-50 equipped with TClO TA controller/processor was used for drying the coal samples and biofuels. The Mettler processor was changed from TClO to 213 Fig. la. DSC curves of a standard coal sample. Fig. lb. DSC curves of common milkweed TClOA and connected to an IBM/PC. This modification made the storage of raw data feasible and reduced the 4 linked methods to 2. This processor was tested with standard premium coal samples from ANL and then used for the biofuels. The samples were dried as described in the procedure and then used in DSC and EA. The optimized experimental conditions for DSC, based on the data on Table 2 are: 5°C min -I heating Fig. 2. Simultaneous determination of C, H, N, S 214 Fig. 3. Determination of oxygen by pyrolysis. and 40 ml min-I oxygen flow rate. Four holes were better than one because more holes allowed sufficient oxygen to enter into the container for better combustion. Since it took several hours to complete one analysis at a heating rate of 5°C min-It, the experimental conditions were slightly modified to a heating rate of 25°C min-I with Table 2 Elemental analysis of standard coal samples and biofuels Sample ID %C ASTM 65.7 75.5 86.7 66.2 65.8 ANL# 3 ANL#4 ANL# 5 ANL#7 ANL#8 Milkweed Dogbane Kudzu a Sample ID Milkweed (C) Milkweed(F) Milkweed(L) Dogbane (C) Dogbane (F) Dogbane (L) Kudzu (C) Kudzu (F) Kudzu (L) Eucalyptus Gr(LF) Eucalyptus Gr.(C) Eucalyptus CA.(L) a E.A 64.4 75.0 85.7 66.3 65.7 46.1 48.4 48.4 %N 1.45 2.17 4.91 1.78 1.75 4.10 1.49 3.26 4.72 1.66 0.62 2.53 %H ASTM 4.2 4.8 4.2 4.2 4.4 E.A 1.2 5.0 4.4 4.3 4.4 6.1 6.0 5.8 %N ASTM 1.2 1.5 1.3 1.3 1.0 E.A 1.4 1.5 1.2 1.2 0.9 1.8 1.8 2.0 %S ASTM 4.8 2.2 0.7 0.7 0.8 E.A 4.5 2.2 0.7 0.7 0.9 %O ASTM E.A 42.47 38.77 42.23 -1 Jg ASTM 27798 31701 34946 27470 25588 Table 3 Effect of particle size of the biofuels on the caloritic value %C 45.81 46.46 45.89 48.50 49.07 45.54 45.91 45.76 44.63 47.90 48.43 49.59 %H 6.00 6.08 6.23 6.05 6.16 6.37 5.86 5.84 5.99 5.41 5.80 6.87 %O 43.46 39.55 34.98 39.26 38.37 37.06 42.64 35.98 35.82 39.33 43.30 35.41 E.A 27130 31829 34946 27607 25556 17298 18201 17273 -1 Jg 16354 17392 18238 18094 18606 17947 16333 11452 18082 17043 16982 20336 C, coarse ground > 100 mesh; F, fine ground cc 100 mesh; L, leaf section; LF, leaves ground to < 100 mesh; Cr., Grandis; GI., Globulus. one hole in the cover. Varhegyi et al. [23] showed that DSC curves reveal considerably less energy release than the true heat of combustion due to experimental conditions. To correct this problem they proposed the use of catalysts as aids to combustion in DSC. In an effort to improve the DSC techniques for our samples, several metal oxides alone and in mixtures of various proportions were tested with a standard coal sample. Among the choices, 1: 1 magnesium oxide (MgO) to silver oxide (Ag,O) (by weight) proved to be the best mixture. Magnesium oxide aids the combustion of the volatile matter and also catalyzes the oxidation of carbon monoxide (CO) to carbon dioxide (CO,). Silver oxide catalyzes the combustion of fixed carbon in the sample as well as converting any CO to CO,. Formation of CO, releases approximately four times the 215 amount of heat as the formation of CO from the same amount of carbon [24]. The effect of the catalyst on a coal sample and a biofuel is presented in Fig. 1. The simultaneous determination of C, H, N, and S in organic compounds [25] and oxygen [26] has been done by Pella and Colombo using a Carlo Erba Elemental Analyzer, Model 1106. Sadek and deBot [27] have determined C, H, N, and S simultaneously along with oxygen (0) in coal samples using the same Model 1106 Elemental Analyzer whereas we used it for biofuels. A typical gas chromatographic separation is shown in Fig. 2. The Eager 100 computer program on an IBM personal computer interfaced to the Elemental Analyzer was used to run the instrument, calculate and store the results, as well as give the actual time plot showing the quality of the chromatographic separation. The regressional analysis for C, H, N, S, and 0 was done by the computer using the Eager program. Also, the program uses a modified Dulong equation introduced by Giazzi and Colombo to calculate the gross and net heat values of each sample. The calculated calorific values were then compared to the ASTM values derived using a bomb calorimeter. The results show good agreement with those Table 4 Comparison of heat values (J g-I) from DSC and EA Sample ID DSCa EA Difference ANL#3 27798 27130 + 668 ANL#4 31331 31829 -498 ANL#7 27470 27607 -137 ANL#8 25588 25556 +32 Milkweed 18236 17815 +421 Dogbane 18566 18201 + 365 Kudzu 17480 11273 + 207 Eucalyptus gl. [e] 17052 17652 -600 a With MgO/Ag,O 1: 1 mixture. generated by ASTM methods as presented in Table 2. The presence of sulfur was found to be below 0.20% or the limit of detection of the instrument and so considered to be negligible. The results listed in Table 3 reflect the effect of particle size on the calorific values. The finely ground sample (with larger surface area) reacted with the catalyst more effectively and released more heat than the coarse and leaf samples. At the same time, the fine grinding resulted in a loss of some heat and made the sample vulnerable to air oxidation. 4. Summary and conclusion The calorific values of the ANL premium coal samples as well as the biofuels determined by direct (DSC) and indirect (EA) methods (Table 4) are within f 668 J g-I. The difference is below the ASTM specified range of k 837 J g-I ( f 360 Btu/lb) for repeatability. Since the same methods and instruments were used to study the biofuels, the calorific values determined are considered to be accurate and reliable. The addition of the catalyst, 1: 1 (by weight) MgO : Ag,O mixture, improved the calorific values of the samples. The standard deviation of the elemental analysis of the biofuels ranged from 0.42 to 0.89 indicating that the results generated are reliable. MOISTURE AND ASH CONTENT IN BIOMASS. Overview Use of woody biomass such as mill residues and forest residues is not a new practice by any stretch of the imagination. There is a long and widespread tradition of the use of woody biomass in energy appli- cations such as a boiler fuel, and it represents a very large fraction of the total renewable energy produced in Wisconsin and across the United States. Interest in increased use of woody biomass has grown signifi- cantly in recent years, particularly in the Lake States, with increased conversion or replacement of fossil fuel fired boilers to the use of woody biomass and with consideration of woody biomass as a feedstock for the production of biofuels. While many sectors within the forest industry, such as sawmills, veneer operations, chip mills, pulp mills and all types of sec- ondary manufacturers routinely deal with moisture content of wood, other sectors of the industry such as loggers and practicing foresters have typically had much less need to concern themselves with moisture content determination. Additionally, the basis and methods of determining moisture content are quite variable depending on the products being dealt with and the sector of the industry being represented. With the expanded use of woody biomass, loggers, foresters and others within the industry (and some people 216 from outside the industry) are now being forced to understand and deal with wood moisture content issues. For example, loggers or foresters that may have sold woody biomass on a green ton basis may soon need to understand the practical aspects of selling the same woody biomass on a dry ton basis. Also boiler operators outside of the industry need an understanding of wood moisture determination in fuel acquisition and testing. This paper is designed to serve as a practical guide for anyone in the Wisconsin industry in understanding the issues related to deter- mination of moisture content of woody biomass and reasonable methods that can be used to determine moisture content of woody biomass in an industrial setting. Woody biomass can be composed of wood (in the form of some kinds of mill residues such as sawdust, trim ends, etc.), or bark (typically that has been removed in a debarking process), or a combination of wood and bark (such as cull logs or bolts, chipped tree trimmings etc.). Also the forms of the material can vary considerably, ranging from roundwood of various sizes and lengths, slabs, edgings, sawdust, hogged fuel, and whole-treechips and also in the form of recovered residue such as branchwood that may include some fraction of needles. For purposes of simplicity in this paper, the term “wood” in discus- sion will be used as a generic term for woody biomass in all its various forms in calculations and discussions for which the calculation would be the same for wood (xylem) or woody biomass. The basis on which moisture content % is determinded (i.e. MC as a % of what?) There are two common ways in which the moisture content percentage (MC%) of wood is routinely expressed. GREEN BASIS: In the green or wet basis (usually ab- breviated “Green basis”) method, the percent mois- ture in the wood is expressed as a percentage of the TOTAL weight of the wood, including both the dry wood material and the water. This method is most commonly used for pulp chips and hogged fuel and this method is generally the method used to deter- mine the MC of woody biomass. It is computed as follows: methods of determining moisture content are appropriate and are commonly It is important to note that both of these used. There is good reason to use the ovendry basis for measuring moisture content in solid wood products. For example, where calculations may need to be made regarding changing moisture contents over time using periodically measured sample pieces (such as sample board in a dry kiln), in using the ovendry basis method, the denominator in the equation would not change for the piece for the string of calculations to estimate moisture content at various times in the drying process. In a similar vein, there is good reason to use the green basis method for pulp chips and fuel, where it is used for a one-time point estimate of what fraction of the whole is usable fiber (or fuel) and what fraction is wa ter. As you will note, in the example provided above, MC% (Green basis) = (weight of water) * 100 217 218 weight of water + dry weight of wood OVENDRY BASIS: In the ovendry basis (usually ab- breviated “OD basis”) method, the % moisture in the wood is expressed as a percentage of the dry weight of wood. This method is the standard method used in this country to express moisture content for solid wood products of all kinds including lumber, veneer, plywood, OSB, particleboard and other panel products. the OD basis moisture content can (and will) exceed 100% on occasion – this is NOT an error – it simply reflects that the weight of water in the sample exceeds the weight of dry material (this is quite common in many circumstances in Wisconsin, such as with aspen in the winter, and for many softwoods and some lower density hardwoods). In any context regarding the expression of moisture content of woody biomass in an industrial setting it is essential that all parties concerned understand the basis on which the moisture content is determined and expressed. MC% (OD basis) = ( weight of water dry weight of wood )* 100 For this reason, it is highly desirable (if not essential) to clearly express the basis on which the moisture content was determined. It is so easy to succinctly, In terms of an example, assume you have taken a sample of woody biomass equal to 100 grams in total weight, and you are able to determine that the sample consists of 49 grams of dry woody biomass material (after water equal to 51 grams is removed), the moisture contents would be calculated as follows: 51 MC% (Green basis) =(100 )* 100 =51% MC (Green basis) And, for THE SAME SAMPLE: 49 51 MC% (OD basis) = ( )* 100 = 104% MC (OD basis) 219 clearly and accurately express “MC (OD basis)” or “MC (Green basis)” - which are two very different things – that it would be utterly foolish to simply express “moisture content” or “MC” (without any expressed basis) and create the potential for con- fusion. This potential for confusion (and contract disputes, disagreements etc.) can largely be avoided by simply specifying the basis being used to express the percentage moisture content. In almost all cases in transactions regarding woody biomass it will prob- ably be the case that using the Green basis moisture content would be used – but there are circumstances where MC may be determined using the OD basis and conversion could be required, prompting confusion. TO CONVERT OVENDRY BASIS %MC TO GREEN BASIS %MC: In the ovendry basis method, as indicated prior, the %MC in the wood is expressed as a percentage of the dry weight of wood. As long as this dry basis MC is known, this is all that is needed to establish the equivalent green basis %MC, because the %MC on the dry basis is a surrogate for the weight of water and the ovendry weight would be equivalent to 100% (relative to the weight of water), therefore, to convert from OD basis %MC to Green basis %MC the calculation is as follows: )100% ( MC % (OD basis) + MC% (OD basis) * 100 MC% (Green basis) = TO CONVERT GREEN BASIS %MC TO OVENDRY BASIS %MC: In the green basis method, as indicated prior, the %MC in the wood is expressed as a per- centage of the total weight of dry wood plus water combined. As long as this green basis MC is known, this is all that is needed to establish the ovendry basis %MC, because the %MC on the green basis is a surro- gate for the weight of water and the ovendry weight would be equivalent to subtracting this same % MC green basis from 100% to create a surrogate for the proportional dry weight, therefore, to convert from Green basis %MC to OD basis %MC the calculation is as follows: )100% (MC % (Green basis) - MC% (Green basis) * 100 MC% (OD basis) = It should be noted that in each case the conversion is simply accomplished by an appropriate adjustment to the denominator in the equation. This is very simple with a little practice. 220 Common methods of moisture content determination and what is most suitable for woody biomass of various types There are several common ways in which the mois- ture content percentage of wood is routinely estimat- ed. All of these have a purpose and place and there are often practical reasons (cost, convenience, time, practicality, etc.) that a given method of estimating moisture content may have an advantage over other methods. The precision level for the methods that are commonly used to estimate moisture content of woody biomass should not be assumed to be any greater than to the integer level (i.e. to the nearest 1%) and with a precision level of from +/- 1%, so calculated moisture contents should be rounded to the nearest integer value (i.e. the calculation should be rounded to the nearest 1%) The oven-drying method Overview of the oven-drying method: The primary oven-drying method (this is “Method A – Oven-Drying Primary” as detailed in ASTM D4442-07) is intended as the sole primary method and is structured for research purposes where the highest accuracy or degree of precision is needed and requires a specific oven type (i.e. a vented forced convection oven), closed weighing jars, and the performance of addi- tional special procedures. The oven-drying method most practically suited for use in determining the moisture content of wood biomass that is typically or most commonly in the forest industry is often simply referred to by most people in forest indus- try as “the oven-drying method” (this is actually “Method B – Oven-Drying Secondary” and is also detailed in ASTM D444207 which provides detail regarding calibration and standardization details for both methods). This oven-drying method is appropri- ate for use with woody biomass samples regardless of moisture content, and although it takes some time to complete the test (usually about 24 hours, and possibly more), the time spent in dealing with each of the individual samples is minimal, and given a large drying oven, a fairly large number of samples can be handled at one time. For these reasons, the oven- drying method is the method that is most commonly used, and other methods (while also suitable) are typically compared to the results of the oven-drying method to ensure their accuracy. The oven-drying method procedures: The oven being used must be capable of maintaining temperatures of 103°C +/- 2°C (or holding between 101°C to 105°C) near the drying endpoint (this is the same as holding between about 214°F and 221°F). The sensitivity of the balance (scale) that is being used to weigh the samples must be to within a minimum of 0.1% of the weight of the sample being tested (for example, if samples being tested are expected to be about 100 grams in weight when dry, the scale should be able to read to at least 0.1 gram (or a tenth of a gram) – this would be the minimum sensitivity allowable, but 221 a somewhat greater sensitivity, such as a sensitivity of 0.01 gram (or a hundredth of a gram) would be preferred in this situation. Samples collected for moisture content determination are to be kept in individual vapor-tight containers if there is any delay between the collection of the sample and the initial weighing which will determine the “green weight” that is the weight of wood and water combined. (Note: If the sample is placed, kept and weighed in a container, such as a small aluminum pan typically used to hold chips or sawdust in drying ovens, the weight of the empty pan needs to be known and subtracted from all numbers in the calculation, or else the balance needs to be tare weighted to eliminate the pan’s weight from what is recorded with each weighing.) After initial weighing, the sample is placed in the oven and kept there until the endpoint has been reached and is then removed and reweighed as soon as possible. It is known that the endpoint is reached when there is no appreciable change in the final weight at approximately 4 hour intervals. The weight of the sample at endpoint is a direct measurement of the dry weight of wood in the sample, which is subtracted from the green weight of the sample (from the initial weighing) to calculate the weight 222 of water. The weight of water is then divided by the green weight of the sample (from the initial weighing) to calculate the Green basis moisture content of the sample (round to the nearest 1%). In most cases the oven-drying method can be com- pleted in about 24 hours of testing, assuming the materials contained in the samples being tested are not very large in size (e.g. in testing samples of chips and smaller material, these samples can typically be processed within a 24 hour period in a good forced- convection oven that is properly vented and is not overloaded). If relatively large sizes of material are included as part of the samples being tested, or if a very large volume of highmoisture material is placed in the oven at one time, this can result in the samples requiring a longer time in the oven to reach end- point. In using an oven in testing various types of samples over time, an operator who has appropriate- ly tested for endpoints when running samples of vari- ous types and moistures (and with various loads in the oven and during various climatic conditions) could typically be expected to reasonably estimate the time to endpoint for the samples being tested relative to the conditions at hand. It should be obvious that it is important to get the samples to endpoint in using the oven-drying method of moisture calculation or the recorded dry weight for the sample will be overstated (i.e. what is recorded as dry weight of wood will be too high as it will have a residual water fraction) and consequently the resulting moisture content calcula- tion will then understate the moisture content (i.e. the calculated moisture content from the test will be less than the actual moisture content of the sample). In the circumstance where woody biomass is pur- chased on a dry ton basis, this failure to reach end- point in drying of samples and resulting understate- ment of moisture content will overstate the dry tons of material actually received by the purchaser and will result in an overpayment to the supplier – con- sequently it is not an error a purchaser can afford to make in a significant way on a regular basis. For this reason it is important for the purchaser to use good procedures and to ensure the samples being tested reach endpoint. Determining moisture content using a microwave oven Overview of determining moisture content using a microwave oven: A microwave oven may be used in determining the moisture content of particulate wood (as detailed in ASTM E1358-97), such as would be represented in many forms of woody biomass samples being tested for moisture content. The advantage of the procedure in using a microwave oven is that the test is relatively quick, typically requiring only about ten to fifteen minutes to perform. This aspect of timely results is generally what makes the procedure appear to be an attractive option. The negatives associated with the procedure are what generally reduce it to being a procedure more suited for occasional versus primary use in the eyes of most potential users. Two minor negatives to the procedure is that for all practical purposes only one sample may be tested in the oven at any given time, and that the testing of the sample needs to be closely monitored. A major negative to using the procedure is the risk of combustion of the sample during testing which is at least in part why the ASTM E1358-97 standard indicates: “This standard does not 223 purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.” Where a microwave oven is to be used in determining the moisture content of wood it is essential to have a plan and appropriate mechanisms and materials to deal with the fires that will occur with testing. Procedures for determining moisture content using a microwave oven: The microwave oven to be used can be any standard commercial microwave oven that has a power output of at least 600 W. The sample size to be tested is to be approximately 50 grams, so the sensitivity of the balance (scale) that is being used to weigh the samples should have a minimum sen- sitivity of 0.01 gram (or a hundredth of a gram). The approximately 50 g sample of the wood to be tested is placed on 3 sheets of standard paper towels placed 224 on top of each other, the weight of which (towels) has been recorded. The sample with the towels is weighed, the sample (on the towels) is then placed in the oven and is heated on full power for a heating interval, it is then removed from the oven after the heating interval, reweighed and stirred and returned to the oven for another heating interval. This is continued until endpoint, where the weight change after a drying interval is less than 0.5 g. The weight of the sample minus the weight of the towels (recorded prior) is the dry weight of wood for the calculation, and the weight of the original sample and towels minus the weight of the towels is the green weight of the sample for the moisture content calculation. An appropriate schedule of intervals of heating times (after which the sample should be reweighed and stirred before further heating) for higher moisture mixed woody biomass in particulate form would be something on the order of a first heating interval of 2 minutes, followed by two 1 minute intervals and then 30 second intervals thereafter. For lower mois- ture material (such as woody biomass well seasoned prior to chipping) it would be recommended to use a process cycle of three 1 minute intervals and then 30 second intervals thereafter. For drier materials still, a process cycle of two 1 minute intervals and then 30 second intervals thereafter would be more appropri- ate. The short intervals of heating times are very important to ensure that the sample is not overdried. When in doubt, shorter intervals are preferred. If material larger in size than normal chips or hogged fuel is included in the sample this does not simplify the situation, rather an even greater care must be exercised. Continuing the microwave heating of larger pieces of wood for too long will easily result in the sample starting on fire, and it will typically burn from the inside of the piece giving little early visual indica- tion of combustion (and perhaps no obvious indica- tion of combustion on the surface, but on cutting the piece a charred center would be obvious). For this reason, using a microwave in moisture content deter- mination of larger samples (such as rounds cut from logs or large materials from a grinder) is not recom- mended. It is difficult for most people to believe how easy it is to have a sample of wood start on fire by overheating it in the microwave until they experience it themselves in testing, but the wood will catch fire if it is heated in the microwave long enough. The first indication of combustion is usually smelling smoke and then realizing that what appeared to be water vapor or steam leaving the piece was actually smoke. Pouring water on a larger sample will not likely immediately extinguish the fire as it will almost certainly be burning in the center, so for safety sake it is desir- able to have a container of water that is large enough to easily hold the sample, and a means of holding it under the surface of the water is also desirable. (The sample could also be tossed outside if safe to do so – it will produce smoke for a long time.) Determining moisture content of chemically treated biomass Overview of determining moisture content of treated material: Although the oven-drying method is generally considered the standard to which other methods should be compared – none of oven-drying 225 methods of any kind (including Method A – Oven-Drying Primary” as detailed in ASTM D4442-07, Method B – Oven-Drying Secondary” as also detailed in ASTM D4442-07, or the practice of moisture content determination using a microwave oven, as detailed in ASTM E1358-97) are appropriate for use with any material that may have been chemically treated or impregnated. Any kind of an oven-drying procedure (conventional or microwave) may produce incorrect results in estimation of moisture content (beyond an acceptable margin of error) due to the potential concomitant removal of the treatment carrier (and/ or chemical itself) along with the moisture, resulting in an overestimation of moisture. More importantly such a practice should be considered inherently dangerous due to increased potential for increased safety risks related to fire or explosion, and for health 226 risks related to the potential for respiratory and other related exposure to chemicals in the sample being handled and volatilized in the drying process. DO NOT USE AN OVEN-DRYING METHOD OF ANY KIND TO DETERMINE MOISTURE CONTENT OF CHEMICALLY TREATED OR IMPREGNATED MATERIAL. Combustion of chemically treated materials can have special prob- lems or concerns, such as those related to stack emis- sions and ash disposal, and should not be undertaken without appropriate planning. Consideration regard- ing the moisture content determination of chemically treated biomass is just one aspect of a large potential problem that needs to be carefully considered before opportunities to use treated biomass can be exploited. Procedures for determining moisture content of treated material: The Distillation method (“this is Method C - Distillation (secondary) method —as de- tailed in ASTM D4442-07) is the appropriate method of determining the moisture content of chemically treated or impregnated material. This procedure re- quires special laboratory equipment and some basic level of knowledge and expertise related to chemistry lab practices. The detailed discussion of this method is beyond the scope of this paper. Determining moisture content using an electric moisture meter Overview of determining moisture content using an electric moisture meter: Electric moisture meters may be used in determining the moisture content of woody biomass in certain circumstances, but such use is inappropriate in other circumstances. Electric moisture meters are reasonably priced, portable, quick and easy to use, and already have widespread use in the forest industry and the building trades. Most people are more familiar with hand-held versions of these meters, but there are also stationary versions of these meters that can monitor material on a conveyor (and are often used to monitor veneer or lumber in manufacturing). Almost all of the handheld electric moisture meters readily available are conductance type meters which are able to operate using the relationship between moisture content and direct current conductance where direct cur- rent conductance increases with moisture content. (These are also sometimes called “resistance type” meters – resistance being the reciprocal of conductance.) There are also other types of moisture meters that use the relationship between moisture content and the dielectric loss factor of the wood (sometimes called the “power-loss type”) or which use the rela- tionship between moisture content and the dielectric constant of the (sometimes called the “capacitance type”). The publication “Electric Moisture Meters for Wood” (USDA - Forest Service Forest Products Laboratory General Technical Report FPL-GTR-6) by William James provides excellent information on the performance and limitations of these devices. The key element of concern for use of electric moisture meters with woody biomass is related to the mois- ture content of the piece being tested needing to be within the moisture content range at which the device may be reasonably expected to give a reason- ably accurate reading. Procedures for determining moisture content using an electric moisture meter: Since 227 manufacturers of stationary meters would establish the appropriate procedures and parameters for use of their equip- ment, this discussion is more specific to hand-held devices. Hand-held pin type moisture meters are useful for determining moisture content of some forms of woody biomass, such as edgings, slabs, scrap lumber and similar materials within appropriate moisture contents, and specialized hand-held meters are also made for sampling fine woody biomass (such as sawdust) also within appropriate moisture content ranges. Moisture meters are generally suited to giving quantitative measures of moisture content between about 7% and 30% MC on the ovendry basis (or about 6% to about 23% on the green basis). Most pin type meters readily available in the U.S. market indicate moisture content on the ovendry basis, but it is important to verify the basis (i.e. ovendry or green) on which the device you use is indicating moisture content. For higher moistures (i.e. anything above 228 about 30% MC on the ovendry basis) a conductance type device may be expected to provide a qualita- tive indication of high moisture but the quantitative reading indicated cannot usually be trusted – what this means is, just because the meter might indicate 40% or 50% or 60% MC, doesn’t really mean anything except that the piece is significantly above 30% MC. It must be understood that just because a meter gives an indication above 30% MC on the ovendry basis does not mean the meter is accurate at that reading (assume it is not). In a similar way, do not expect explicit accuracy for readings below about 6% or 7% MC on the ovendry basis. Temperature, moisture distribution and species affect the accuracy of readings for the meters, along with other factors. Temperature correction is actually a function of both moisture content and temperature, so a supplier provided correction table is preferred, but as a rule of thumb, you can correct the reading by subtracting 1 % MC for every 20°F above the calibration temperature and adding 1 % MC for every 20°F below the calibration temperature for (the most com- mon) conductance type meters. Some meters have correction buttons for use of the meter with different species, while others may have correction tables (corrections are usually less than 2% for U.S. species). Uneven moisture distributions can also give readings that will deviate from a true average (usually overestimating by reading along the lines of higher moisture). For determining moisture content of some types of solid woody biomass (such as partially dried slabs, edgings, etc.) the common, inexpensive hand-held pin-type electric (conductance) moisture meters are useful tools that should be on hand. Also, some of the newer meters that sample sawdust and other small particle residues are worth consideration of having on hand for anyone who purchases fine woody biomass residues that are below fiber saturation point of about 30% MC on the ovendry basis. These devices for particle materials generally work by a conduc- tance measurement of a small sample of sawdust or other fine material that has been compressed to a constant pressure of about 0.2 MPa. In using a pin type meter, it is desirable to have the pins oriented along the grain versus across the grain as a general practice (and this is more important as moisture con- tents increase towards the higher end of the working range – where failure to do this can result in lower than actual readings). Chemical treatments and glues can lead to inaccurate readings (usually higher than actual). Using a pin type meter, the pins should be inserted in the piece to a depth of about one fifth to one fourth of the thickness of the piece of wood be- ing measured, and where there is significant variabili- ty expected in the piece (e.g. due to rapid drying from the ends) it would be advisable for multiple reading to be made on the piece being sampled. Determining moisture content using specialized devices Overview of determining moisture content using specialized devices: Commercially produced bench- top devices are made for the express purpose of moisture measurement of wood or woody biomass. Usually these devices require a small sample that is tested in a process by the machine with the moisture content directly indicated. Different types of these devices have existed for a long time, and it is safe to assume that new products will continue 229 to be devel- oped. These are generally well suited to purposes where very small samples are acceptable and the results are required fairly quickly, and where running one sample at a time is practical. Many people like these devices and are satisfied with the price paid, the results obtained, and the volume of material they can handle – while other people prefer the more conventional tools and practices. These specialized devices are something that for some people may be worth examining – where that is the case it would probably be prudent to carefully examine what is available on the market, and if possible to try to talk to people who use the equipment and to understand how they use the equipment in terms of type of materials tested and number of samples tested in a day. 230 Sampling practices suitable for use with woody biomass of various types Overview of sampling practices for moisture con- tent determination of woody biomass: The sampling practices and the sample selection processes to be used to determine the moisture contents of woody biomass of various types, being delivered by various suppliers, from various locations, at different times of the years is something which deserves considerable thought and planning, with regard to how the sam- ples will be collected, labeled, stored and processed, and also what should be the required frequency of sampling. In doing this, the practical aspects of sampling that must be considered would include safety considerations, the form of the material as received, if the material will be immediately staged for use as received, or stored for drying (such as being held for drying in roundwood form prior to use), the volume of material coming from various suppliers, the vari- ability regarding moisture content for the material being received from the various suppliers, and the physical constraints and the costs of testing samples need to be considered at a minimum. First and foremost – it must be remembered that consideration of human safety is the most important consideration in developing sampling and testing practices. No woody biomass sample is worth anyone risking significant injury or death in sample collection or processing. Each circumstance is somewhat different, so each place of work must be carefully evaluated with an eye toward safety in developing sampling and testing practices. Particular concern should be given to developing practices that elimi- nate or at least greatly minimize the possibilities of serious injury or death, such as anyone being crushed or struck or by machine or material movement, and the risk of falling off of loads or piles. In the testing of material, particular concern should be given to proper venting of volatiles released from samples in drying ovens, prohibition of oven-drying test method of treated and/or contaminated materials and an eye towards fire safety. With regard to the frequency of sampling from vari- ous suppliers, consideration must be given to the costs associated with sampling and testing overall, the variability expected in the moisture content of material being received from various suppliers (at any particular point in time and over time), and physical constraints associated with sampling collection and processing, as well as having an eye towards overall costs and efficiency in the overall sampling process. Sampling practices for woody biomass in particle form – for oven-drying testing: In sampling most woody biomass in particle form (such as chips and sawdust); a sample volume that is roughly twice the desired average weight at endpoint is generally ap- propriate. For example, assuming a dry sample size of approximately 100 grams is desired for oven testing; an appropriate green sample of about 200 grams (slightly less than half a pound) would be desirable in sampling high-moisture residues such as most woods residues. If material being tested is known to be at significantly lower moisture content, then a roughly equivalent volume of sample of similar type of par- ticle material (having proportionately lower weight) would be appropriate for drier material. In practice it will quickly be recognized that samples should be large enough relative to the need for appropriate levels of precision in consideration of the equipment being used, however, overly large samples quickly take up the limited capacity of drying ovens. In a practical sense, the system for testing woody biomass in particle form needs to be considered on a holistic basis wherein the capacity of drying ovens available is sufficient to reasonably accommodate the material to be tested in a given time period, considering both the space required for the pans and the overall volume of material to be tested (and associated volume of water needing to be 231 removed). A sample selected to be tested in oven drying can be an individual sample selected specifically for that pur- pose, or can be obtained as a reduction from a gross sample (i.e. a sample from a gross sample) with that gross sample being simply a larger sample that is systematically collected over time. In terms of 232 example, the sample to be tested may be a sample selected to represent the moisture content of a truckload of material from a supplier who occasion- ally delivers a truckload of biomass – or in contrast, for a major supplier, it may be desirable to collect a gross sample, wherein a sample from each truckload of material delivered by that supplier from a particular job site may be collected and aggregated together in an airtight container as a gross sample, with the sample (or multiple samples) that is to be tested then being taken from the gross sample, and representing multiple truckloads for that job that are represented in the gross sample. Generally, the size of a gross sample should be fairly large, such as at least 10 kilograms (about 22 pounds) in green weight, and the removal or selection of the sample to be tested from the gross sample needs to follow an appropri- ate procedure (as detailed in ASTM E 871 – 82). The selection of the sample from the gross sample is most easily done by use of a riffle (such as a coal riffle) that progressively divides the gross sample into parts, from which one part is retained for further division, and that division continues until an appropriate size sample for testing remains. In terms of example, if a gross sample of about 10 kilograms in weight is pro- gressively divided into halves, with one half retained for division and the other half discarded (e.g. with the first division by half of the 10 kilos of the gross sample, about 5 will remain; with the 5 kilos divided in half, about 2.5 kilos will remain, etc.), in about six divisions by half, you will end up with a sample of about 200 grams. In a practical application, where the woody biomass material being tested is in the form of some types of forest residues that has been run through a tub grinder, there will likely be considerable variability in the size of the material delivered. In proper sampling this larger material will represent itself in the gross sample (note: you should not arbitrarily reject larger material from the sample or selectively chose material of a size desired). Where this is the case that you have larger material in the sample than the size of material that is desired for testing, from a practical standpoint it may be desirable (if not neces- sary) to accomplish some gross reduction in the size of material in the sample (such as running it through a hammermill) at least prior to oven testing and it may be necessary to perform a reduction on the entire gross sample itself, or at some point fairly early in the division process if very large pieces of material could represent a problem in sample division. Very large pieces of material in the sample may not easily be accommodated in the drying pans and if they do, it is possible they may delay the sample reaching end- point as they would not lose moisture as easily as smaller particles having greater surface area rela- tive to their mass. If a microwave oven is being used in the testing, the particle size in the sample being tested would obviously become even more impor- tant, due to the differences in rate of drying and the smaller sample size, consequently it may be desirable to generally reduce microwave samples to a smaller size particle than typical for testing in a conventional oven. As indicated prior, the material being collected for the gross sample needs to be held in an airtight container until the sample for testing is to be drawn from the gross sample. That sample for testing, and any individual samples selected from it for testing also need to be 233 held in an airtight container of some type until their initial weighing in the testing process to determine green weight of the sample. If this is not done, the sample to be tested may be expected to lose moisture to the atmosphere, and this loss of moisture in the sample will result in the calculation of a moisture content that is lower than would accu- rately represent the load or loads being represented by that sample. (Or the reverse could occur if very dry material was being received and tested, but this is un- likely.) In a practical sense it will quickly be recognized that containers for the collection and storage of gross samples that could easily weigh more than 25 pounds could be any of a number of durable, larger airtight storage containers readily available from a variety of sources. For holding an individual sample for testing until it is ready to begin to be processed, both larger “zip-loc” type food storage bags and reusable small, durable air-tight containers work well. 12 234 The physical collection of woody biomass samples should be done by a regular process – which as noted prior – gives key concern to safety. The sample may be physically taken by hand or by some collection device (such as a small container on a pole), and the sample for a load may be taken from one or more parts of the load (depending on what may be practi- cal or physically possible). Reasonable consideration should be given to not sampling primarily or solely from what would clearly be atypical for the load as a whole. For example, if biomass is transported in a truck with a rear screen on a rainy day or dur- ing a late or early snowfall, a very small layer of the load against that screen could pick up considerable moisture in the haul – and in a similar vein, a small portion of the load exposed by such a screen to hot, dry air could be expected to lose moisture in a long haul. In either case, although these extremes would indeed represent a very small part of the load, the extremes would not represent a reasonable average for the load from which the material was taken, if the extreme area of unusually higher or lower moisture was all that was selected from as a sample for the load. Where possible, sampling somewhere near the middle of the load as a regular practice should rea- sonably be expected to work best over time and to be most fair to both buyer and seller. Sampling practices for woody biomass in solid form – oven-drying testing: The sampling of woody biomass in larger solid form – such as from cull logs – presents some special problems. Where the form of the biomass as received has each component element that is huge relative to the desired size of a sample for testing in oven-drying, so clearly it is not possible to simply take samples by hand from the material received. To accomplish appropriate sampling of such material in the woods can be a relatively easy but time consuming process, wherein from a selected representative sample tree at the time of harvest, thin disks of uniform thickness (e.g. about one inch in thickness) may be cut from the stem as each bolt or log is bucked from the tree, such that the disks considered in total would provide a sample giving a weighted average for the stem as a whole, and the sample could be tested in its entirety (or each disk could be reduced by hand with a proportional pie-cut fraction retained, such as retaining a disk equal to a pie cut from outer surface to center, of equal propor- tion, such as a half, or a quarter, and that sample could be tested in its entirety), or the sample of disks could become a gross sample that could be reduced in a hammermill and then reduced in a riffle to provide a smaller sample for testing. However, in normal circumstances where such cull logs are received on a truck with no real opportunity to sample at the point of harvest, the possibility of maintaining the integrity of sample trees is lost. Disk collection from a sample of logs could still be an acceptable mechanism for collection of a gross sam- ple; however, there is a problem with cutting disks from woody biomass logs or boltwood as received for moisture content sampling. Once cut into logs or bolts, the logs will rapidly begin to dry longitudinally (from the ends), such that the wood at the ends would typically be at a lower moisture content than would be typical or average for the log. Cutting a disk from near the middle of the log would be expected to be a much better representation of the average 235 moisture content for the log – and this would be a good testing practice if it is practical – but in many cases this will not be practical. Increasingly some purchasers of woody biomass in roundwood form are purchasing the material and holding it for seasoning for a significant time (in many cases from six months to a year) in an effort to reduce moisture content of the material. In this circumstance in particular, and in other circumstances as well, bucking bolts or logs to retrieve sample disks for moisture measurement is not a practical alternative due to problems it will create further handling and storage of the logs. Sampling from near the (longitudinal) center of logs or bolts using an increment borer is a practical alter- native to the cutting of sample disks. The appropriate procedure for such sampling on a log would be to place the borer perpendicular to an imaginary plane on the tangential face of the log and bore to the center of the log (i.e. to the pith). The problem in such a sampling procedure is that the small cylinder 236 of wood removed is of equal diameter throughout (i.e. from the bark surface to the pith), and the sam- pling as such would tend to greatly over-sample the center half of the log (nearer the pith) and to under- sample the outer area of the log, relative to the proportional volumes of these areas. Given the expecta- tion of typical differences in the moisture content of heartwood versus sapwood, and also a significant understatement of the bark fraction in sampling, this creates some significant problems. A very simple solution to this is that in addition to taking the initial sample bore from bark surface to the pith (half the diameter or the radius) on a given log, two additional sample cores are then taken in the same approximate location and in the same way, except in taking those two additional cores, they are taken to a depth of only one half of the depth of the initial sample. This would entail taking a total of three cores in total from one general location (near the longitudinal center) on a given log being tested – the first being one sample core all the way from the bark surface to the pith (half the diameter) and two additional cores in the same general location but only going to half the depth of the original (i.e. to only one-fourth of the diameter or half the radius). This is a slight additional effort but represents a much better overall sample because it makes an adjustment to better propor- tionately sample the log’s volume in inner and outer fractions. For an understanding of why this differential sam- pling is important, consider a circle of any diameter representing the cross-section of a log. Two paral- lel lines placed close together extending from the center of the circle to the perimeter could be used to represent a sample of the circle removed by an increment core. This type of sampling would equally represent the portions of the circle represented in the area contained in the inner half of the radius and the outer half of the radius, however, the actual area represented with the inner “half” of the circle in the form of a smaller circle with the same center and half the original radius would only represent about one- third of the volume contained in the outer “half” of the circle (which is represented as a ring around the half-diameter circle). This would mean that about one fourth of the total area would be represented in the smaller (half-full diameter) inner circle, while about three fourths of the total area would be represented in the outside ring around that small circle, where the thickness of the ring is equal to half the radius of the larger circle and equal to the radius of the smaller circle. Essentially in using the increment core in the first extraction to the pith sample, half of the core will come from the inner circle and half from the outer ring – the two additional half-depth (or half full diameter) cores adjust the total sample to be representative of representing approximately three fourths of the total cores being taken from the outer “half” (outer ring) and one fourth from the inner “half” (half full diameter circle). The three cores are combined to form a sample for that log. In sampling a load, the three core sampling procedure may be applied to sampling multiple logs (taking three cores from each), with the sampling process mixing species and sizes as appropriate. All cores can then be combined to rep- resent a sample for testing representing an individual load or used in developing a form of a “gross sample” of cores across a number of loads that may be used to collect a volume of material suitable to represent a lab sample (that could be tested in total without divi- sion by a riffle or other means). The sampling of woody biomass in the form of asym- metrical high-moisture residual material (such as un- seasoned slab wood or edgings obtained from small mills) presents some difficulties as compared to the testing of logs, as the three core procedure described for logs 237 is not suited to this material being tested. This is because of the cross-section of these materi- als is not circular, rather it represent a fraction of a circle or an irregular shape. The problem is further exacerbated where the material may still be at quite a high moisture overall, but having a much greater surface area than is typical for logs, and some or all pieces of material may have had some seasoning processes begun (with associated loss of moisture) in short term storage and hauling. In sampling such materials, the use of an increment borer is still likely to be one of the best practical options, but the person 238 taking the samples needs to be cognizant of the fact there is likely to be considerable variation in moisture content, that could be directly related to size (i.e. material with greater thickness in crosssection might be expected to have higher moisture content ) , and also that there is likely to be a significant moisture profile in many pieces where the moisture content of the core may be expected to be significantly greater than the outer perimeter. Keeping these factors in mind can help underscore the need for selecting samples from a representative mix of materials in the load having different thicknesses and cross section. Also where these pieces would typically be fairly thin (compared to cull logs), sampling completely through the thickness of material may be a practical way of capturing a representative sample from pieces with a significant moisture profile. Sampling practices for well-seasoned or dry woody biomass in solid form: In circumstances where woody biomass in solid form is delivered in a well-seasoned or dry condition, this permits the use of a simple hand-held pin-type electric (conductance) moisture meters to collect moisture measurements. This would be a realistic possibility where all (or virtually all) of the load could be expected to be at an average moisture content that is low enough to permit testing with an electric moisture meter. This is a reasonable and practical alternative where the moisture content of the material being received does not exceed about 23% MC on the Green basis (or about 30% MC on the OD basis). Such very low average moisture contents should almost never be expected for woody biomass in roundwood form, but can be quite common for woody biomass in the form of well-seasoned slabs and edgings from smaller sawmills (that could typi- cally be at moisture contents close to the upper limit) and also in the form of dry solid wood residuals from secondary manufacturers that could be at quite low moisture contents (even possibly near the lower limit for accurate readings using such equipment). Where it is possible to use such a hand-held moisture meter for sampling an incoming load of material, it is a very quick and easy process to sample a number of pieces to estimate an average moisture content for the load, sampling near the longitudinal center of the longer pieces, as with other processes, to limit the effect of excessive moisture loss from the ends. In the case of well-seasoned slabs at such low moisture contents, in many cases bark will have sloughed off or will be sloughing off, but where firmly fixed, both wood and bark should be sampled. In sampling materials such as seasoned slabs and edgings that are likely at the upper end of moisture contents suitable for this process (e.g. well-seasoned slabs) if in about twenty to twenty five readings taken from different pieces yield no moisture readings so high that there is reason to mistrust any of the readings as being more likely reflective of a qualita- tive versus a quantitative nature, then an average of the readings may be used to represent an aver- age for the load. If one or two of the readings taken indicate moistures somewhat above 23% MC on the Green basis (or about 30% MC on the OD basis), then additional readings should be taken (on additional pieces) to attempt to confirm that there is not too large a number higher-moisture pieces such that the use of a moisture meter for sampling may be inappropriate. As long as no more than 5 or 10% of pieces sampled reflect moisture contents above 23% MC on the Green basis, the average of all displayed moisture content readings should represent a suit- able representative average for the load, however, if a significantly large number of pieces sampled are at a moisture where the reading is more qualitative versus quantitative, the average of the meter read- ings cannot be trusted to provide something that can confidently be projected as a true average for the load and testing better suited to higher moisture material (such as the oven-drying method) should be employed. In rare circumstances (usually in the win- ter) dry solid wood residuals received from secondary manufacturers could be at very low moisture con- tents such that for some 239 pieces the readings reflect a moisture content of something less than 6% which is at the lower limit for accuracy in using a hand-held pin-type electric (conductance) moisture meters. Where that is the case, there is no particular problem in simply averaging the readings taken as the possible 240 error introduced by inclusion of a few such readings is minimal where the range of difference between the true moisture content and the indicated moisture content on the meter is so small. Sampling practices for well-seasoned or dry woody biomass in particle form: In circumstances where woody biomass in solid form is delivered in a dry con- dition in particle form (such as sawdust or other fine particles), that permits use of an inexpensive hand- held meter that can sample sawdust and other small particle residues this is likely to be the tool of choice for quickly sampling the occasional truckload of such material. Where larger suppliers might routinely ship truckloads of such material, it will probably be the case that the moisture contents of the material as received will be quite uniform, and the hand-held meter is simply used to confirm that knowledge. One or two samples of material per truckload delivered would be an appropriate sample in most cases. Any reading that indicates a moisture content that is above, at (or even very close to) the upper limit of the devices capability should be an indication that testing better suited to higher moisture material (such as the oven-drying method) should be used for the material. Moisture content of wood in equilibrium with stated temperature and relative humidity (on the OVENDRY basis) Moisture content (%) on the OVENDRY basis at various relative Temperature humidity values °C °F 5% 10% 15% 20% 25% 30% 35% 40% 45% 50% 55% 60% -1.1 40 10 15.6 21.1 26.7 32.2 37.8 43.3 48.9 54.4 60 65.6 71.1 76.7 82.2 87.8 93.3 98.9 104.4 110 115.6 121.1 126.7 132.2 30 1.4 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 260 270 1.4 2.6 1.4 1.3 1.3 1.3 1.2 1.2 1.1 1.1 1 0.9 0.9 0.8 0.7 0.7 0.6 0.5 0.5 0.4 0.3 0.3 0.2 0.2 0.1 2.6 3.7 2.6 2.5 2.5 2.4 2.3 2.3 2.2 2.1 2 1.9 1.8 1.6 1.5 1.4 1.3 1.1 1 0.9 0.8 0.6 0.4 0.3 0.1 3.7 4.6 3.6 3.6 3.5 3.5 3.4 3.3 3.2 3 2.9 2.8 2.6 2.4 2.3 2.1 1.9 1.7 1.6 1.4 1.2 0.9 0.7 0.5 0.2 4.6 5.5 4.6 4.6 4.5 4.4 4.3 4.2 4 3.9 3.7 3.6 3.4 3.2 3 2.8 2.6 2.4 2.1 1.9 1.6 1.3 1 0.7 0.3 5.5 6.3 5.5 5.4 5.4 5.3 5.1 5 4.9 4.7 4.5 4.3 4.1 3.9 3.7 3.5 3.2 3 2.7 2.4 2.1 1.7 1.3 0.9 0.4 6.3 7.1 6.3 6.2 6.2 6.1 5.9 5.8 5.6 5.4 5.2 5 4.8 4.6 4.3 4.1 3.8 3.5 3.2 2.9 2.6 2.1 1.7 1.1 0.4 7.1 7.9 7.1 7 6.9 6.8 6.7 6.5 6.3 6.1 5.9 5.7 5.5 5.2 4.9 4.7 4.4 4.1 3.8 3.4 3.1 2.6 2.1 1.4 7.9 8.7 7.9 7.8 7.7 7.6 7.4 7.2 7 6.8 6.6 6.3 6.1 5.8 5.6 5.3 5 4.6 4.3 3.9 3.6 3.1 2.5 8.7 9.5 8.7 8.6 8.5 8.3 8.1 7.9 7.7 7.5 7.2 7 6.7 6.4 6.2 5.9 5.5 5.2 4.9 4.5 4.2 3.5 2.9 9.5 10.4 9.5 9.4 9.2 9.1 8.9 8.7 8.4 8.2 7.9 7.7 7.4 7.1 6.8 6.5 6.1 5.8 5.4 5 4.7 4.1 10.4 11.3 10.3 10.2 10.1 9.9 9.7 9.5 9.2 8.9 8.7 8.4 8.1 7.8 7.4 7.1 6.8 6.4 6 5.6 5.3 4.6 11.3 12.3 11.2 11.1 11 10.8 10.5 10.3 10 9.7 9.4 9.1 8.8 8.5 8.2 7.8 7.5 7.1 6.7 6.3 6 241 from table 3-4 of the USDA Wood Handbook - reprinted with permission METHODS FOR ESTIMATING BIOMASS DENSITY FROM EXISTING DATA 3.1 APPROACH 1: BIOMASS DENSITY BASED ON EXISTING VOLUME DATA 3.2 APPROACH 2: BIOMASS DENSITY BASED ON STAND TABLES 3.3 BIOMASS ESTIMATES OF INDIVIDUAL 3.4 BIOMASS ESTIMATES FOR PLANTATIONS 3.5 BIOMASS OF OTHER FOREST COMPONENTS This primer discusses two approaches for estimating the biomass density of woody formations based on existing forest inventory data. The first approach is based on the use of existing measured volume estimates (VOB per ha) converted to biomass density (t/ha) using a variety of "tools" (Brown et al. 1989, Brown and Iverson 1992, Brown and Lugo 1992, Gillespie et al. 1992). The second approach directly estimates biomass density using biomass regression equations. These regression equations are mathematical functions that relate ovendry biomass per tree as a function of a single or a combination of tree dimensions. They are applied to stand tables or measurements of individual trees in stands or in lines (e.g., windbreaks, live fence posts, home gardens). The advantage of this second method is that it produces biomass estimates without having to make volume estimates, followed by application of expansion factors to account for non-inventoried tree components. The disadvantage is that a smaller number of inventories report stand tables to small diameter classes for all species. Thus, not all countries in the tropics are covered by these estimates. To use either of these methods, the inventory must include all tree species. There is no way to extrapolate from inventories that do not measure all species. Use of forest inventory data overcomes many of the problems present in ecological studies. Data from forest inventories are generally more abundant and are collected from large sample areas (subnational to national level) using a planned sampling method designed to represent the population of interest. However, inventories are not without their problems. Typical problems include: Inventories tend to be conducted in forests that are viewed as having commercial value, i.e., closed forests, with little regard to the open, drier forests or woodlands upon which so many people depend for non-industrial timber. The minimum diameter of trees included in inventories is often greater than 10 cm and sometimes as large as 50 cm; this excludes smaller trees which can account for more than 30% of the biomass. The maximum diameter class in stand tables is generally open-ended with trees greater than 80 cm in diameter often lumped into one class. The actual diameter distribution of these large trees significantly affects aboveground biomass density. Not all tree species are included, only those perceived to have commercial value at the time of the inventory. 242 Inventory reports often leave out critical data, and in most cases, field measurements are not archived and are therefore lost. The definition of inventoried volume is not always consistent. Very little descriptive information is given about the actual condition of the forests, they are often described as primary, but diameter distributions and volumes suggest otherwise (e.g., Brown et al. 1991, 1994). Many of the inventories are old, 1970s or earlier, and the forests may have disappeared or changed. Despite the above problems, many inventories are very useful for estimating biomass density of forests. In the next two sections, details of the methods for using existing forest inventory data for biomass density estimation are presented. 3.1 APPROACH 1: BIOMASS DENSITY BASED ON EXISTING VOLUME DATA 3.1.1 GENERAL EQUATION 3.1.2 VOLUME-WEIGHTED AVERAGE WOOD DENSITY (WD) 3.1.3 BIOMASS EXPANSION FACTOR (BEF) 3.1.4 EXAMPLES OF CALCULATIONS OF BIOMASS DENSITY 3.1.5 ADJUSTMENTS TO APPROACH USING VOLUME EXPANSION FACTORS (VEF) 3.1.6 USE OF INVENTORIES OF OPEN FORESTS AND WOODLANDS The method presented here is based on existing volume per ha data and is best used for secondary to mature closed forests only, growing in moist to dry climates. It should be used for closed forest only because the original data base used for developing this approach was based on closed forests. The primary data needed for this approach is VOB/ha, that is inventoried volume over bark of free bole, i.e. from stump or buttress to crown point or first main branch. Inventoried volume must include all trees, whether presently commercial or not, with a minimum diameter of 10 cm at breast height or above buttress if this is higher. If the minimum diameter is somewhat larger, the VOB/ha information can be used with some adjustments as shown below. However, such adjustments to the primary data introduce larger errors in the estimate. 3.1.1 GENERAL EQUATION Biomass density can be calculated from VOB/ha by first estimating the biomass of the inventoried volume and then "expanding" this value to take into account the biomass of the other aboveground components as follows (Brown and Lugo 1992): (Eq. 3.1.1) 243 Aboveground biomass density (t/ha) = VOB * WD * BEF where: WD = volume-weighted average wood density (1 of oven-dry biomass per m3 green volume) BEF = biomass expansion factor (ratio of aboveground oven-dry biomass of trees to oven-dry biomass of inventoried volume) 3.1.2 VOLUME-WEIGHTED AVERAGE WOOD DENSITY (WD) Wood density here is defined as the oven-dry mass per unit of green volume (either tons/m3 or grams/cm3). Wood densities for trees of tropical American forests tend to be reported in these units. In contrast, few data on wood density for trees in tropical Africa and Asia are expressed in these units (Reyes et al. 1992). Rather, wood density is expressed in units of mass of wood at 12% moisture content per unit of volume at 12% moisture content. A regression equation was developed by Reyes et al. (1992) to convert wood density based on 12% moisture content to wood density based on oven-dry mass and green volume (Eq. 3.1.2). (Eq. 3.1.2) Y = 0.0134 + 0.800 X (r2= 0.99; number of data points n = 379) where: Y = wood density based on oven-dry mass/green volume X = wood density based on 12% moisture content Ideally, a weighted average (based on dominance of each species as measured by volume) wood density value is best used here, calculated as follows. (Eq. 3.1.3) WD = {(V1/Vt *WD1 + (V2/Vt) *WD2 +........... (Vn/Vt)* Wdn where: V1, V2,.... Vn = volume of species 1, 2,.. to the nth species Vt = total volume WD1 WD2,..... Wdn = wood density of species 1, 2,...... to the nth species However, sufficient wood density data of forest species to do such calculations are not always available. In these situations it is best to estimate a weighted mean wood density based on known species, using an arithmetic mean from the table below for unknown species. Wood density data for 1180 tropical tree species are given in Appendix 1. 244 The arithmetic mean and most common wood density values (t/m3 or g/cm3) for tropical tree species by region Tropical region No. of species Mean Common range Africa 282 0.58 0.50-0.79 America 470 0.60 0.50-0.69 Asia 428 0.57 0.40-0.69 (from Reyes et al. 1992) 3.1.3 BIOMASS EXPANSION FACTOR (BEF) Broadleaf forests: Biomass expansion factor is defined as: the ratio of total aboveground oven-dry biomass density of trees with a minimum dbh of 10 cm or more to the oven-dry biomass density of the inventoried volume. Such ratios have been calculated from inventory sources for many broadleaf forest types (young secondary to mature) growing in moist to seasonally dry climates throughout the tropics. Sufficient data were included in these inventory sources to independently calculate aboveground biomass density and biomass of the inventoried volume (Brown et al. 1989). The reported inventoried volume in the studies was based on the definition given above. Analysis of these data show that BEFs are significantly related to the corresponding biomass of the inventoried volume according to the following equations (Brown and Lugo 1992): (Eq. 3.1.4) BEF = Exp{3.213 - 0.506*Ln(BV)} for BV < 190 t/ha 1.74 for BV>=190t/ha (sample size = 56, adjusted r2 = 0.76) where: BV = biomass of inventoried volume in t/ha, calculated as the product of VOB/ha (m3/ha) and wood density (t/m3) Conifer forests: No model for calculating biomass expansion factors for native conifer forests is available at present because of the general lack of sufficient data for the type of analysis performed for the broadleaf forests. However, one would expect that BEFs for tropical pine forests would vary less than for broadleaf forests because of the generally similar branching pattern exhibited by different species of pine trees. Biomass expansion factors have been calculated based on a limited data base of 12 stands of Pinus oocarpa growing in Guatemala (Peters 1977) and the methodology given in Brown et al. (1989). The inventoried volume in this case was defined as volume over bark/ha from the stump to the tip of the tree; i.e. main stem based on total height. Volumes of these stands ranged from 64 to 331 m3/ha. The BEFs based on biomass of the main stem ranged from 1.05 to 1.58, with a mean of 1.3 (standard error of 0.06). No significant relationship between BEF and main stem biomass was obtained. Until additional data become available, a BEF of 1.3 can be used, with caution, for biomass estimation of pine forests. 245 3.1.4 EXAMPLES OF CALCULATIONS OF BIOMASS DENSITY To demonstrate the application of this methodology, aboveground biomass density is calculated for the following examples: Example 1. Broadleaf forest with a VOB = 300 m3/ha and weighted average wood density; WD = 0.65 t/m3 Step 1 Calculate biomass of VOB: = 300 m3/ha x 0.65 t/m3 = 194 t/ha Step 2 Calculate the BEF (Eq. 3.1.4): BV > 190 t/ha, therefore BEF = 1.74 Step 3 Calculate aboveground biomass density (Eq. 3.1.1): = 1.74 x 300 x 0.65 = 338 t/ha Example 2. Broadleaf forest with a VOB = 150 m3/ha and weighted average wood density, WD = 0.55 t/m3 Step 1 Calculate biomass of VOB: = 150 m3/ha x 0.55 t/m3 = 82.5 t/ha Step 2 Calculate the BEF (Eq. 3.1.4): BV < 190 t/ha, therefore BEF = 2.66 Step 3 Calculate aboveground biomass density (Eq. 3.1.1): = 2.66 x 150 x 0.55 = 220 t/ha As can be seen from these two examples, although there is a two-fold difference in VOB/ha, there is only a 1.5-fold difference in aboveground biomass density. 3.1.5 ADJUSTMENTS TO APPROACH USING VOLUME EXPANSION FACTORS (VEF) Forest inventories often report volumes to different standards, e.g., to minimum diameters greater than 10 cm. These inventories maybe the only ones available, and thus it is important that a means to unify the volume data to some kind of standard be developed so that these inventories can be used to estimate biomass density. In an attempt to unify data on inventoried volume measured to a minimum diameter greater than 10 cm, volume expansion factors (VEF) were developed (Brown 1990). After 10 cm, a common minimum diameter for inventoried volumes ranges between 25-30 cm. Data from inventories that reported volumes to minimum diameters in this range were combined into one data set to obtain sufficient number of studies for analysis. The VEF is defined here as the ratio of inventoried volume for all trees with a minimum diameter of 10 cm and above (VOB10) to inventoried volume for all trees with a minimum diameter of 25-30 cm and above (VOB30). The uncertainty in extrapolating inventoried volume based on a minimum diameter of larger than 30 cm to inventoried volume to a minimum diameter of 10 cm is likely to be 246 large and is not suggested. Estimates of the VEFs were based on a few inventories from tropical Asia and America which provided sufficient detail for this analysis (see Brown 1990). Volume expansion factors based on these inventories ranged from about 1.1 to 2.5, and they were related to the VOB30 as follows: (Eq. 3.1.5), VEF = Exp{1.300 - 0.209*Ln(VOB30)} for VOB30 < 250 m3/ha = 1.13 for VOB30 > 250 m3/ha (sample size = 66, adjusted r2 = 0.65) To demonstrate the use of this correction factor to estimating biomass density, consider the following example: Broadleaf forest with a VOB30 = 100 m3/ha and weighted average wood density; WD = 0.60 t/m3 Step 1 Calculate the VEF from Eq. 3.1.5: = 1.40 Step 2 Calculate VOB10: = 100 m3/ha x 1.40 = 140 m3/ha Step 3 Calculate biomass of VOB10: = 140 m3/ha x 0.60 t/m3 = 84 t/ha Step 4 Calculate the BEF from Eq. 3.1.4: BV < 190 t/ha, therefore BEF = 2.64 Step 5 Calculate aboveground biomass density (Eq. 3.1.1): = 2.64 x 140 x 0.60 = 222 t/ha 3.1.6 USE OF INVENTORIES OF OPEN FORESTS AND WOODLANDS No general approach for estimating aboveground biomass density of open forests and woodlands based on inventoried volume has been developed because of the general lack of suitable data. The method described above for closed forests is not generally applicable because trees have different branching patterns (often multi-stemmed) and inventoried volume of open forests and woodlands is usually measured to different standards than for closed forests. For example, inventories done in open forests and woodlands generally report inventoried volume per ha to minimum diameters less than 10 cm, and also often include branch volume. Earlier work suggested that total aboveground biomass density of open forests could be up to three times the inventoried volume (Brown and Lugo 1984), however further field testing would be needed to confirm this. It is recommended that the approach described in section 3.2 (next) for estimating aboveground biomass density be used for open forests and woodlands. 3.2 APPROACH 2: BIOMASS DENSITY BASED ON STAND TABLES 247 3.2.1 BIOMASS REGRESSION EQUATIONS 3.2.3 PROBLEMS WITH REGRESSION APPROACH Another estimate of biomass density is derived from the application of biomass regression equations to stand tables. The method basically involves estimating the biomass per average tree of each diameter (diameter at breast height, dbh) class of the stand table, multiplying by the number of trees in the class, and summing across all classes. A key issue is the choice of the average diameter to represent the dbh class. For small dbh classes (10 cm or less), the mid-point of the class has been used (e.g., Brown et al. 1989). The quadratic-mean-diameter of a dbh class would be a better choice, particularly for wider diameter classes. If basal area for each dbh class is known, the quadratic-mean-diameter (QSD) of trees in the class, or the dbh of a tree of average basal area in the class, should be used instead. To calculate the QSD, first divide the basal area of the diameter class by the number of trees in the class to find the basal area of the average tree. Then the dbh = 2 x {square root (basal area/3.142)}. For example, the dbh of a tree of basal area of 707 cm2 = 2 x {square root (707/3.142)} = 30 cm. 3.2.1 BIOMASS REGRESSION EQUATIONS The biomass regression equations for broadleaf forests were developed from a data base that includes trees of many species harvested from forests from all three tropical regions (a total of 371 trees with a dbh ranging from 5 to 148 cm from ten different sources; see Appendix 2; equation 3.2.2 in the table below was developed by Martinez-Yrizar et al. (1992)). The biomass regression equations can provide estimates of biomass per tree. The data base was stratified into three main climatic zones, regardless of species: dry or where rainfall is considerably less than potential evapotranspiration (e.g. <1500 mm rain/year and a dry season of several months), moist or where rainfall approximately balances potential evapotranspiration (e.g. 1500-4000 mm rain/year and a short dry season to no dry season), and wet or where rainfall is in excess of potential evapotranspiration (e.g. >4000 mm rain/year and no dry season). These rainfall regimes are just guides, and generally apply to lowland conditions only. As elevation increases, as in mountainous areas, temperature decreases as does potential evapotranspiration and the climate zone becomes wetter at a given rainfall. For instance, an annual rainfall of 1200 mm in the lowlands would be the dry zone, but at about 2500 m it would be the wet zone. Therefore, judgement should be used in selecting the appropriate equation. Figure 1 - Relationship between oven-dry biomass of tropical trees and dbh for (a) biomass regression equations by all climatic zones and trees with dbh between 5 to 40 cm, and (b) equations for moist and wet zones for trees in the full range of dbh. The equations are given in Section 3.2.1. (a) All zones 248 (b) Moist and wet zones Biomass regression equations for estimating biomass of tropical trees. Y= biomass per tree in kg, D = dbh in cm, and BA = basal area in cm2 Equation Climatic Equation Range in Number of Adjusted 249 Number 3.2.1 zone DRY a 3.2.2 3.2.3 MOIST b 3.2.4 3.2.5 WET c Y = exp{1.996+2.32*ln(D)} Y =10^{-0.535+log10 (BA)} Y = 42.6912.800(D)+1.242(D2) Y = exp{2.134+2.530*ln(D)} Y = 21.2976.953(D)+0.740(D2) dbh (cm) 5-40 trees 28 r2 0.89 3-30 191 0.94 5-148 170 0,84 0.97 4-112 169 0.92 None of the regression equations should be used for estimating the biomass of trees whose diameter greatly exceeds the range of the original data. a Eq. 3.2.1 revised from Brown et al. (1989) for dry forest in India, and Eq. 3.2.2 from Martinez-Yrizar et al. 1992 for dry forest in Mexico (original equation based on BA). For dry zones with rainfall less than 900 mm/year use equation 3.2.2 and for dry zones with rainfall > 900 mm/year use equation 3.2.1. "exp" means "e to the power of". b Both equations are based on the same data base; A. J. R. Gillespie, pers. comm. based on a revision of equation in Brown et al. (1989). c From Brown and Iverson (1992) Analysis of the data bases implied that the trees within the dry and wet zones could be grouped together within a zone (Brown et al. 1989). Within the moist zone, the analysis indicated that different data bases were not statistically homogeneous and theoretically could not be grouped. For practical purposes, however, the moist zone was considered to be the population of interest and the different data bases were considered to be subsamples from this population. Thus a combined regression for the pooled data sets was developed (Brown et al. 1989). Biomass regression equations for several species of pines combined into one data base was also developed. A simple method for estimating the biomass of palms was also developed (Frangi and Lugo 1985). Broadleaf forests: Details of the: (1) evaluation of several linear, nonlinear, and transformed nonlinear regression equations, (2) the testing of the behavior of the equations, and (3) selection of the final equations are given in Brown et al. (1989). A listing of the original data are given in Appendix 2. The behaviour of all these regression equations as a function of dbh is illustrated in Figure 1. Application of all five regression equations for smaller diameter classes shows that for a given dbh biomass is highest for trees in the moist zone (Fig. 1a; Eq. 3.2.3 and 3.2.4), followed by trees in the wet zone (Eq. 3.2.5), and trees in the dry zone (Eq. 3.2.1 and 3.2.2). 250 The regression equation for dry zone trees given by Eq. 3.2.1 gives higher biomass per tree for a given diameter than the regression developed for the Mexican dry zone (Eq. 3.2.2; see Fig. la). As tree diameters increase, the difference becomes larger so that by diameter 40 cm (the upper limit for the data bases) the biomass per tree based on Eq. 3.2.1 is about 1.7 times higher than that based on Eq. 3.2.2. The main reason for this trend is that the trees used for developing Eq. 3.2.1 grow in a dry deciduous forest zone of India that receives about 1200 mm/year of rainfall in contrast to the dry deciduous forests in Mexico where rainfall averaged about 700 mm/year. The result of this difference in rainfall regime is that the Mexican trees are shorter than those in India, and thus biomass for a given diameter is less. For example, height for the Mexican trees commonly ranged between 4 to 9 m, with an average height of about 7 m (Martinez-Yrizar et al. 1994), whereas those in India had heights up to about 15m (Bandhu 1973). The tropical dry forest zone describes areas where rainfall is less than 1500 mm/year or so. For a dry zone where rainfall is similar to that for the dry deciduous zone of Mexico (about 700 to 900 mm/year or less), Eq. 3.2.2 could be used. For dry zone 'forests at the wetter end of the zone, i.e., rainfall greater than 900 mm/year, Eq. 3.2.1 should be used. However, because of the high variability of tree biomass with rainfall in the dry zone, it is recommended that local biomass regression equations be developed, or at least a few trees harvested to test how well the two equations presented here fit the local conditions. The moist zone equations (Eq. 3.2.3 and 3.2.4) give essentially the same biomass estimates for trees with dbhs up to about 80 cm (Fig. 1b). After this diameter limit, estimates of the biomass per tree diverge markedly. However, the estimates from Eq. 3.2.4 are closer to the original data (cf. Appendix 2) and the r2 of the regression equation is higher than for Eq. 3.2.3 (0.97 versus 0.84). It is not recommended that any of the regression equations be used for estimating the biomass of trees whose dbh greatly exceeds the range of the original data. However, if trees with dbh greater than 160 cm or so are encountered in an inventory, it is recommended that Eq. 3.2.3 be used for these trees as the function behaves better in these larger classes. Equation 3.2.4 is an exponential function and biomass per tree increases rapidly at large diameters. In the ideal situation where many trees with dbhs larger than 150 cm are encountered, some new field measurement of their biomass should be made (see section 4.). It is important that the biomass of trees with large dbh be estimated as accurately as possible because their contribution to the biomass of a forest stand is much more than their number suggests. For example, in mature moist tropical forests, the biomass in trees of dbh greater than 70 cm can account for as much as 40% of the stand's biomass density, although the number of these trees corresponds to less than 5% of all trees (Brown and Lugo 1992, Brown 1996). The regression equation for trees in the wet zone (Eq. 3.2.5) matches the original data well and behaves well at larger diameters. As with the moist equation however, caution should be taken in using the equation much beyond the original data. Palm trees: In many tropical moist and wet forests, palms are sometimes common. Estimating their biomass is difficult as few studies have been made on this topic. Furthermore, many different species exist with different forms, different proportions of their mass in leaves, and different stem densities. To estimate the biomass of palms, height 251 measurements as well as diameter measurements will be needed. A simple way to estimate their biomass is to compute the volume of the stem as a cylinder (basal area x stem height) and then multiply this by an estimate of the density. Wood density of palms varies considerably by species and within the stem of the same species, and it can range from about 0.25 to almost 1.0 t/m3 (Rich 1987). The biomass of the leaves also has to be added, which in total may range from 10 to 65% of the stem biomass (Frangi and Lugo 1985, Rich 1986). An alternative approach is to use a regression equation developed for the palm Prestoea montana, a common species in the moist forests of Puerto Rico. Two regression equations were developed, based on either total height or stem height as follows (from Frangi and Lugo 1985): (Eq. 3.1.6) Y (biomass, kg) = 10.0 + 6.4 * total height (m); n=25, r2=0.96 (Eq. 3.1.7) Y (biomass, kg) = 4.5 + 7.7 * stem height (m); n=25, r2=0.90 An example is given here to demonstrate the variation in the estimates from the three different methods. For a palm of 15 cm diameter, 15 m total height, and 12 m stem height, the biomass estimates are: Method Based on volume: stem volume = 0.21 m3, wood density = 0.25 t/m3; stem mass = 53.0 kg; assume leaves are 65% of stem, total biomass = 87 kg 1 Method Based on Eq. 3.2.6: total biomass = 86 kg 2 Method Based on Eq. 3.2.7: total biomass = 97 kg 3 The three methods give similar values. Unless the forest is composed mostly of palms, any of these methods would be suitable for estimating biomass of palms scattered throughout moist or wet forests. However, the variation in wood density by species must be taken into consideration; higher wood density estimates need to be used for denser species. In the case of forest stands where palms are dominant, local biomass regression equations would need to be developed, or at least measurements of wood density of dominant palm species would need to be measured (see section 4.). Conifer forests: Few data on the biomass of conifer trees for tropical zones exist. To develop a preliminary biomass regression equation, data on the biomass of harvested pine trees from eight literature sources, including pine forests from the southeastern USA, India, and Puerto Rico were compiled. Several species of pine included in these sources were combined into one data base and analyzed as was done for the broadleaf forests. The resulting equation is: (Eq. 3.1.8) Y(kg) = exp{-1.170+2.119*ln(D)} 252 D = dbh, cm; range in dbh = 2-52 cm; number of trees =63; adjusted r2=0.98 For most situations where an estimate of the biomass density of pine forests is needed, Eq. 3.2.8 can be used. However, if time and resources are available, a local biomass regression equation should be developed. Below is an example of how to use the biomass regression equations with stand tables. The stand table example is for a moist forest in Ghana. Biomass density of this forest was estimated using the moist equation, Eq. 3.2.3. Maximum diameters are at about the upper limit for this equation (about 150 cm). Use if the biomass regression equation, an example Diameter class (cm) 5-20 20-40 40-60 60-90 90-120 120-150 >150 1. Number trees/ha 794 161 25.2 12.3 3.3 1.05 0.23 a 2. Mid-point of class, cm 12.5 30 50 75 105 135 155 b 3. Biomass of tree at mid-point of class using Eq. 3.2.3; kg 70.5 646 2353 6563 15375 29038 41 187 4. Biomass of all trees, t/ha = (product of rows 1 and 3)/1000° 56 104 59.3 80.7 50.8 30.5 9.5 Total aboveground biomass = sum of row 4 = 391 t/ha a As no additional information was available the mid-point of the diameter class was assumed to represent the class; as the classes are wide this could overestimate the biomass density estimate. b Assumed to be diameter of largest class; choice of this upper limit when no additional data are present is problematic (see section 3.2.4). c To convert kg to t Although the approach presented here has emphasized the use of regression equations with stand tables, the regression equations can also be used with individual tree measurements from stands. Using individual tree measurements overcomes the problem of choosing the diameter of the class. 3.2.3 PROBLEMS WITH REGRESSION APPROACH Several problems exist with this method, namely: (1) the small number of large diameter trees used in the regression equations (e.g., for the moist equation, the largest dbh was 148 cm, with only five trees >100 cm diameter), (2) the open-ended nature of the large diameter classes of the stand tables, (3) wide and often uneven-width diameter classes, (4) selection of the appropriate average diameter to represent a diameter class, and (5) missing smaller diameter classes (i.e., incomplete stand tables to minimum diameter of 10 cm). To overcome the potential problem of the lack of large trees (problem 1), equations were selected that were 253 expected to behave reasonably up to 150 cm or so or upon extrapolation somewhat beyond this limit (Brown et al. 1989). Rarely are stand tables encountered that contain trees much larger than the maximum dbh used in the regression. The problem with open-ended large diameter classes is knowing what diameter to assign to that class. Sometimes additional information is included that educated estimates can be made, but this is often not the case. Clearly, further improvements in reporting the distribution of the largest diameter trees in stand tables would improve the reliability of the biomass density estimates as it is often these large trees that account for significant proportions of the total biomass density (Brown and Lugo 1992, Brown 1995). In the above example, the approximately 1.3 trees greater than 120 cm constitute about 70% of the biomass represented by the 794 trees in the smallest class. Many inventories often report stand tables with wide and/or uneven-width classes. The most unbiased biomass density estimate is obtained when diameter classes are small, about 10 cm wide or smaller, and are even-width for the whole stand table. This problem is illustrated by the following example for a moist forest where in Example A the classes are 10 cm wide and in Example B two classes are combined to make them 20 cm wide. Example A Diameter class (cm) 10-19 20-29 30-39 40-49 50-59 60-69 70-79 80-89 90-99 100-109 110-119 >120 Number of stems/ha 183 80 35.1 11.8 4.7 2.3 1.5 0.9 0.5 0.4 0.2 0.5 Biomass/tree (kg) at mid-point of class(Eq. 3.2.3) 112 407 954 1 802 2995 4570 6563 9008 11936 15375 19354 23900 Biomass of trees (product of rows 1 and 2), t/ha 20.5 32.6 33.5 21.3 14.1 10.5 9.8 8.1 6.0 6.2 3.9 12.0 Total biomass density =178 t/ha Example B Diameter class (cm) 10-29 30-49 50-69 70-89 90-109 >110 1. Number of stems/ha 263 46.9 7.0 2.4 0.9 0.7 2. Biomass/tree (kg) at mid-point of class(Eq. 3.2.3) 232 1 338 3732 7727 13590 21 555 3. Biomass of trees (product of rows 1 and 2), t/ha 60.9 62.7 26.1 18.5 12.2 15.1 Total biomass density =196 t/ha The biomass density in Example B, based on the 20 cm wide classes, is about 10% higher than that in Example A, based on the 10 cm wide class. In general, wider classes will 254 overestimate the biomass density. However, regular estimation of biomass density as part of inventory analysis or accessibility to the field data should not encounter these problems because original inventory data generally includes details down to individual trees. Estimating the biomass of individual trees in inventory plots directly would overcome problems (2) to (4) given above. Foresters have wide experience in these type of calculations as they are basically no different from estimating volumes from volume equations. To overcome the problem of incomplete stand tables, an approach has been developed for estimating the number of trees in smaller diameter classes based on number of trees in larger classes (Gillespie et al. 1992). It is recommended that the method described here be used for estimating the number of trees in one to two small classes only to complete a stand table to a minimum diameter of 10 cm. It is also emphasized that this method should only be used when no other data for biomass estimation are available. The method is based on the concept that uneven-aged forest stands have a characteristic exponential or "inverse J-shaped" diameter distribution. These distribution have a large number of trees in the small classes and gradually decreasing numbers in medium to large classes. Pull details of the theory behind the approach and of the different methods tested are given in Gillespie et al. (1992). The best method was the one that estimated the number of trees in the missing smallest class as the ratio of the number of trees in dbh class 1 (the smallest reported class) to the number in dbh class 2 (the next smallest class) times the number in dbh class 1. This method is demonstrated in the following example: 1 Assume that: the minimum diameter class is 20-30 cm and we wish to estimate the number of trees in the 10-20 cm class. 2 The number of trees in the 20-30 cm class equals 80, and the number in the 30-40 cm class equals 35. 3 The estimated number of trees in the 10-20 cm class is the number in the 20-30 cm class x (number in 20-30/number in 30-40); this equals 80 x (80/35) =183. To use this approach, diameter classes must be of uniform width, preferably no wider than 10-15 cm, and should not be used for estimating numbers of trees in more than two "missing' classes. 3.3 BIOMASS ESTIMATES OF INDIVIDUAL The regression equations reported above can be applied to inventories of individual trees planted in lines, as living fence posts, for dune stabilization, for fuelwood, etc. Biomass estimates for individual trees are particularly useful in drier regions where the trees are grown for all the aforementioned products and services. However, as discussed above, the regression equations for dry zone trees are based on a small data base. Furthermore, trees grown in lines or in more open conditions generally display different branching patterns and are likely to have more biomass for a given diameter than a similar diameter tree grown in a stand. Although the above regression equations could be used where no other data exist for rough approximations, new regression equations need to be developed for trees growing in open conditions. 255 3.4 BIOMASS ESTIMATES FOR PLANTATIONS Estimating the biomass density of plantations can be done using techniques similar to those for native forests as described above. Inventoried volume can be converted to aboveground biomass density using Eq. 3.1.1 outlined in Section 3.1. However, the equation for BEFs (Eq. 3.1.4) would not necessarily work in the case of plantations of broadleaf species because tree form is likely to be different in managed forests and definitions of inventoried volumes are also likely to be different. It is recommended that BEFs be locally derived. The biomass regression equations for broadleaf species (Eq. 3.2.1-3.2.5) could also be used for plantations, but once again caution should be taken with their use. Direct biomass measurements of representative plantation trees should be made to check the validity of the regression equations, or even better local biomass regression equations should be developed. See Section 4 for further details on methods. For plantations of conifer species, the average BEF of 1.3 given for pine forests in Section 3.1.3 could be used if measured volume was based on the total stem. In the case where diameters of individual plantation trees or diameter distributions are given, Eq. 3.2.8 could be used, taking the same precautions as for broadleaf species. Kadeba (1989) developed biomass regression equations for plantations of Pinus caribaea trees growing in the savanna zone of Nigeria with annual rainfall ranging from 1250 to 1800 mm/year. However, the data base spanned a small diameter range, about 15-25 cm, and each equation was based on 12 trees only. For situations that mimic the conditions of Kadeba's study, the reader is referred to his work. In situations where lack of resources prevent the development of local biomass regression equations for plantations, use of any or the above approaches would give a reasonably good estimate of the aboveground biomass density. 3.5 BIOMASS OF OTHER FOREST COMPONENTS This primer does not include methods or approaches for making biomass density estimates for (1) understorey (including e.g., bamboo or rattan), (2) belowground woody biomass such as fine and coarse roots, (3) forest floor fine litter (e.g., dead leaves, twigs, fruits, etc.), nor (4) lying and standing dead wood. Most efforts on biomass estimation to date have generally focused on the aboveground tree component because it accounts for the greatest fraction of total biomass density and the methods are straightforward and generally do not pose too many logistical problems. Commonly reported ranges of biomass density estimates for these other components are given below, although they must be used with caution as the data base on which they are built is limited. Summary of estimates of biomass density of other forest components, expressed as a percent of aboveground biomass in trees Component Percent of aboveground! biomass of mature forest! Understorey 3 Belowground (roots) 4-230 Fine litter (dead plant material) 5 256 Dead wood 5-40 (sources of these data are given in the text) The amount of biomass in understorey shrubs, vines, and herbaceous plants can be variable but is generally about 3 percent or less of the aboveground biomass of more mature forests (Jordan and Uhl 1978, Tanner 1980, Hegarty 1989, Lugo 1992). However, in secondary forests or disturbed forest, this fraction could be higher (e.g., up to 30%; Brown and Lugo 1990, Lugo 1992) depending on age of the secondary forest and openness of canopy. Palms are common in many tropical moist forests and they are also often ignored in forest inventories. Their contribution to total biomass density can be very variable, from nearly 100 percent to less than a few percent (see section 3.2.1 above for more details on estimating the biomass of this component). The biomass of roots varies considerably among tropical forests depending mainly upon climate and soil characteristics (Brown and Lugo 1982, Sanford and Cuevas 1996). Root biomass is often expressed in relation to aboveground biomass, such as a root-to-shoot ratio (R/S ratio). A recent review of the literature gives the R/S ratios (from Sanford and Cuevas 1996) shown in the table on the next page. These estimates of R/S are based on only a few studies (about 30) and not all of them are consistent with respect to depth of sampling and nor whether coarse roots were included. It seems clear from this discussion that more studies of root biomass and their relationship with other factors such as aboveground biomass, climate and soil, are needed. The amount of dead plant material in a forest, or detritus, is composed of fine litter on the forest floor, (leaves, fruits, flowers, twigs, bark fragments, branches less than 10 cm diameter, etc.), standing dead trees and snags, and lying dead wood greater than 10 cm diameter. The biomass density of fine litter ranges from about 2 to 16 t/ha (average of 6 t/ha or less than 5% of aboveground biomass), with higher values generally in moist environments although no clear trend is apparent in the data base (Brown and Lugo 1982). The amount of fine litter on the forest floor represents the balance between inputs from litterfall and outputs from decomposition, both of which vary widely across the tropics. The amount of dead wood in tropical forests is poorly quantified but extremely variable. It is potentially a large pool of organic matter, perhaps accounting for an amount equivalent to less than 10 percent to more than 40 percent of the aboveground biomass of a forest depending upon forest age and climatic regime (Saldarriaga et al. 1986, Uhl et al. 1988, Uhl and Kauffman 1990; Delaney et al. 1997). Lack of data on this significant forest component obviously can lead to underestimates of the total amount of biomass in a forest. It is clear from the above discussion that ignoring these other forest components can seriously underestimate the total biomass of a forest by an amount equivalent to about 50 percent or more of aboveground biomass. Although beyond the scope of this primer, it is apparent that logistically and economically feasible methods and approaches must be developed to estimate this significant quantity of biomass and its range of uncertainty, especially for improving estimates of terrestrial sources and sinks of carbon and biogeochemical cycles of other elements. 257 Forest type Range of R/S Average R/S Moist forest growing on spodosols 0.7 - 2.3 1.5 Lowland moist forest 0.04 - 0.33 0.12 Montane moist forests 0.11 - 0.33 0.22 Deciduous forests 0.23 - 0.85 0.47 (e.g., tropical dry and seasonal forests) PRACTICAL NO.04 258 STUDY VISITS STUDY OF ENERGY CONSUMPTION PATTERN IN RURAL AND URBAN AREAS THROUGH SURVEY. VISIT TO NEARBY BIO-ENERGY UNITS. 259 REFERENCES