XM^NG FONXEYOI IH LMAHMLHSÊO _XÊJLNO \ JHYOEXSALO IHROSYOJHMYD ONOIÌJLND IH LMAHMLHSÊO _XÊJLNO HRL_ _XÊJLNO OMOEÊYLNO NXOMYLYOYLVO, _X->9? RSDCEHJO^ SH^XHEYD^ IH VDEXJHYSÊO IH RSHNLRLYONLÞM Vdeujhm ih rhontlvd rhquhrlid0 ?. (?>-3) o) ´_uì vdeujhm ih sdeunlþm ih CoNe 3 2,27>>> M sh rhqulhrh poro prhnlpltor tdid he suefotd ih umo sdeunlþm quh ndmtlhmh 2,9112 a ih K 3^D9Oe3(^D9)>39G3D4 c) ´Nuïe hs eo jdeorlioi ih eo sdeunlþm ih CoNe34 Iotds0 MCoNe3 : 2,27>>> Hq/E o) VCoNe3 : ´4 C) JCoNe3:4 jsuefotd : 2,9112 a o) m²jhq CoNe3 : m²jhq K3^D9.Oe3(^D9)>.39G3D Ñ : .39 : <97,2,9112 17 ⁉ 7222 ⁉ (VxM)CoNe3 : 9,239? jhq 9,239? : 97,3 : 2,27>> 27>>>> ⁉ 97,3<< VCoNE3 : 97,3< jE c)[CoNe3Z : ´4 jde/E 7>>⁉>⁉ : 2,29?668 : : 2,23 3 J : 2,29?668 jde/E 3. (?>-1) Nlhrto sdeunlþm ih FhNe>.6G3D ndmtlhmh hm noio jE um phsd ih Fh lauoe quh he ih 2,>22 ja ih Fh 3D> ´Nuïmtds jE ih OaMD > 2,2822 M sh rhquhrlrïm poro tltueor 82,2 jE ih eo sdeunlþm ih nedrurd o um ndedr rd`d ndm lmilnoidr K3NrD94 Iotds0 jFh3D> : 2,> ja/jE VFhNe> : 82,2 jE MOaMD> : 2,28 Hq/E VOaMD> : ´4 Nïenued ih eo nomtlioi ih Ne- hm eo sdeunlþm ih FhNe>.6G3D0 3 Ñ 31 312,2,>>22 Ñ 2,> . 6 Ñ 2,>>22 2 2 : . : 3 ?8<,6< jFhNe>.6G3D : ?,2?86 ja hm um jE ih sdeunlþm hm 82 jE shrêo 82,17 ja ih FhNe>.6G3D þ 2,28217 a Nïenued ih vdeujhm ih OaMD> 0 m²jhq OaMD> : m²jhq FhNe>.6G3D VÑM : FhNe. 6GD : 2,28217312Ñ,>2>22⁉2⁉ : ??,3 V : 22,86>6 ,28 ⁉ ??,311 VOaMD> : ??,31 jE >. (?>-?3) Xmo juhstro ih fheihspotd ndmtlhmh 1,87 % ih Mo3D y <,<> % ih K 3D ´Nuïe ihch shr eo mdrjoelioi ih umo sdeunlþm ih OaMD> sl sh rhqulhrhm 33,1? jE ih heeo poro prhnlpltor he Ne- ih eds nedrurds oenoelmds ndjclmoids quh sh dctlhmhm ih umo juhstro quh phso 2,?822 a4 Iotds0 Mo3D : 1,87 % jl : 2,?822a K3D : <,<> % VOaMD> : 33,1?jE MOaMD> : ´4 jMo3D : 2,?82 a x 2,2187 : 2,2??>1 a jK3D : 2,?82 a x 2,2<<> : 2,2?97<8 a 3 Ñ 8 7 , 8 : 3 Ñ : 2,2??>1 >1 : 2,23? 2,23?96 96 6?,<7 Ñ 2,2?? jMoNe : 2,23?96 a 3 Ñ 1 9, 8 6 : 3 Ñ : ?97<8 <8 : 2,223>8 3>877 <9,32 Ñ 2,22?97 jKNe : 2,23>87 a m²jhq OaMD> : m² m²jhq jhq MoNe + m²jhq KNe m²jhq : j / Rjhq 2,23>87 ² : 82,23?96 7,8 ⁉ 19,86 ⁉ ?222 ⁉ ?222 ⁉ m²jhq OaMD> : MOaMD> 2,>667 + 2,>?6> : 2,67>? jhq : 2,67>? : 2,2>227 33,1? : 2,2>227 jhq/jE Jïs ilrhntd0 m²jhq OaMD> : m²jhq Mo3D + m²jhq K3D 2??>1 2,2?97<8 Ñ : 2,6?,<7 <9,3 3222 3222 : 2,2> : 2,>667< 2,>?639 2,2>227 227 / 33,1? jE MOaMD> : 2,2>227 jhq/jE Η : 34 Mo3D ↓ 3Mo++3Ne- ↓ 3MoNe + 3OaMD> ↓ ↞ 3OaNe + 3MoMD> 9. (?>-9) Xmo sdeunlþm ih K3Nr3D1 quh hs 2,??3? M ndjd oahmth dxliomth sh uso poro prhnlpltor CoNrD9 ih 2,8262 a ih CoNe3.3G3D. o) ´Nuïe hs eo mdrjoelioi ih eo sdeunlþm ih ilnrdjotd ndjd oahmth prhnlpltomth hm hsto rhonnlþm4 c) ´Nuïe hs su jdeorlioi ndjd soe ih pdtosld4 n) ´_uì vdeujhm sh rhqulhrh4 Iotds0 MK3Nr3D1 : 2,??3? Hq/E (dxli) jCoNe3.3G3D : 2,8262 a o) MK3Nr3D1 :4 (pptomth) n) VK3Nr3D1 : ´4 c) Jsoe: ´4 Ndmvlrtlhmid o jdeorlioi eo mdrjoelioi ihe ilnrdjotd0 ??3? ⁉ :2,2?767 J : η : 2,6 6⁉ Nr3D1: + ?9G+ + 6h- ↓ 3Nr>+ + 1G3D o) Roro ndmvhrtlr eo ndmnhmtronlþm ih um dxliomth o prhnlpltomth0 Nr3D1 : + G3D 2,??3?M 2,2?767 J NrD9: + Co3+ NrD9: + 3NrD9: + 3G+ 2,??3? M 3 x 2,2?767 : 2,2>1>6 J CoNrD9 7G+ + >h- Nr>+ ndjd oahmth prhnlpltomth hs umo soe + 9G3D : Ñ Ñ : Ñ Ñ : Ñ : Ñ M : Jη Lauoeomid ojcos rheonldmhs0 : ↓ : Ñ : 2,??3? Ñ 3 > Msoe : 2,2191> Hq / E c) Eo jdeorlioi ndjd soe ih pdtosld hs0 191> ⁉ : 2,2>1>68 ⁉ J : : 2,23 3⁉ J : 2,2>1>68 jde/E n) m²jhq NrD9: : m²jhq Co3+ MÑV : Rjhq . : 2,8262399Ñ,33722⁉2⁉ : , : , , ⁉ VNrD93- : 88,99 jE 8. He ozufrh ihe norcþm jlmhroe sh ihthrjlmo pdr ndjcustlþm shno ih umo juhstro, ocsdrclhmid hm oauo he ^D> fdrjoid y tltueomid he suefotd quh sh prdiunh ndm sdeunlþm ih CoNe3. Eo ndmnhmtronlþm ih eo sdeunlþm tltueomth sh hstocehnh tltueomid umo juhstro shno ih Mo3^D9. Hm umo nlhrto ihthrjlmonlþm sh prdiunh eo ndjcustlþm ih umo juhstro ih 2,38 a ih norcþm. Eo tltueonlþm ihe suefotd dcthmlid rhqulhrh 9,7 jE ih eo sdeunlþm ih CoNe 3, ih eo nuoe sh rhqulhrhm ?1,33 jE hm eo tltueonlþm ih 2,2?77 a ih Mo3^D9. o) ´Nuïe hs eo ndmnhmtronlþm ih eo sdeunlþm ih CoNe3 hm ja ih ^/jE4 c) ´Nuïe hs he pdrnhmto`h ih ozufrh hm he norcþm4 Iotds0 j : 2,38 a V l : 9,7 jE CoNe3 V : ?1,33 jE CoNe3 jMo3^D9 : 2,2?77 a 3^ + >D3 + noedr G3^D9 + CoNe3 3^D> + 3G3D 3G3^D9 Co^D9 + 3GNe 9,7 jE o) NCoNe3 (ja ^ / jE) : ´4 Eo voedronlþm rhqulhrh 2,2?77 a ih Mo3^D9 y aosto ?1,33 jE ih CoNe 3 >3,? : Ñ : ?93 Ñ2,2?77 j^ : 9,38 x ?2-> a, hstd hs poro ?1,33 jE ih CoNe3 : 2,3967 ⁉ N : 9,38 ?1,33 jE NCoNe3 : 2,3967 ja ^/jE c) % ^ (n (norcþm) orcþm) : 4 j : 2,3967 Ñ 9,7 : ?,??796 79699 Ñ?22:2,919 % ^ : ?,?7969 382 % ^ : 2,919 Ih dtro jomhro0 ?77 Ñ 3222 ⁉ : 2,2?8>7 ⁉ M : 2?,923 ⁉ Ñ?1,33 MCoNe3 : 2,2?8>7 jhq/jE >3 / 2,2?8>7 Ñ 9 , 7 Ñ 3222 / Ñ?22 % : 2,38 % ^ : 2,9138 JÌYDID IH JDGS 6. Xmo juhstro ih ?,<<7 a quh ndmtlhmh Ne - y NeD9- sh ilsuhevh hm oauo suflnlhmth poro dcthmhr 382,2jE ih ilsdeunlþm. Xmo oeênudto ih 82,2jE rhqulhrh ?>,<1jE ih OaMD > 2,2788? J poro voedror he Ne-. Xmo shaumio oeênudto ih 82,2jE sh troto ndm V3(^D9)> poro rhiunlr he NeD9- o Ne-0 NeD9- + 9V3(^D9)> + 9G3D ↓ Ne- + ?3^D9: + 7VD3+ + 7G+ Eo voedronlþm ih eo juhstro rhiunlio prhnlso ih 92,?3jE ih eo ilsdeunlþm ih OaMD >. Noenueh eds pdrnhmto`hs ih phrnedrotd y nedrurd hm eo juhstro. Iotds0 jl : ?,<<7 a Vtdtoe : 382,2jE Vj : 82,2jE VOaMD> : ?>,<1jE (Ne-) JOaMD> : 2,2788? jde/E VOaMD> : 92,?3jE %NeD9- :4 %Ne- : ´4 Juhstro0 Ne- y NeD9- 0 ?,<<7 a ↓ 382jE 0 82jE + OaMD> ↓ ↞OaNe ?>,<1jE/2,2788?J:M ↞ 82 jE0 NeD9- + V>+ ↓ Ne- + OaMD>↓OaNe↞ 92,?3 jE Ih eo prljhro tltueonlþm0 %∓ : ² Ñ ∓ Ñ?22 %∓ : ÑÑ Ñ∓ Ñ?22 >8,98/ ?> ?>,< ,<1 1 Ñ Ñ 2, 2 2788 7 88? ?/ / Ñ Ñ ?222/ Ñ?22 %∓ : ?,<<7 /8 %∓ :, Hm eo shaumio tltueonlþm sh aosto 92,?3 jE ih OaMD>, quh hs tomtd poro he Ne- ih eo juhstro ndjd poro he Ne- prdiuntd ih eo rhiunnlþm ih NeD9-, hmtdmnhs sþed poro hsth ðetljd shrï0 92,?3 jE „ ?>,<1 jE : 36,?8 jE <<,98 2,2788? 36,?8 Ñ Ñ ?222 Ñ?22 %∓ : ?,<<7 /8 %∓ :, JÌYDID VDEGOSI 1. Xm omïelsls ihe ldm cdrdglirurd sh coso hm su rhonnlþm ndm Oa+0 CG9- + 7Oa+ + 7DG- ↓ G3CD>- + 7Oa(s) + 8G3D Eo purhzo ih umo nlhrto nomtlioi ih KCG9 quh sh usorï hm umo sêmthsls draïmlno sh hstocehnh oe ilsdevhr >,3?> a ihe jothrloe o hxontojhmth 822,2 jE, trotor umo oeênudto ih ?22 jE ndm 82,22 jE ih OaMD > 2,333? J y voedror he hxnhsd ih ldm peoto pe oto ndm >,>6 jE ih K^NM 2,2><1 J. Noenueh eo purhzo ihe KCG9 hm %(R) (8>,<9? a/jde). Iotds0 jl : >,3?> a Vtdtoe : 822,2 jE Vj : ?22 jE VOaMD> : 82,2 jE JOaMD> : 2,333? jde/E JK^NM : 2,2><1 jde/E Rurhzo : ´4 %(R) VK^NM : >,>6 jE CG9- + 7Oa+ + 7DG- ↓ G3CD>- + 7Oa(s) + 8G3D / Oa+(hxnhsd) >,3?>a/8 82 jE/2,333?J:M Oa+(hxnhsd) + K^NM ↓ ↞Oa^NM + K+ >,>6 jE/2,2><1J:M Hs umo rhtrdtltueonlþm0 Ñ?22 , ,%% : ² .Ñ ² ² .: . : Ñ Ñ ? m²jhq rhq. : 82 jE x 2,333?jhq/jE „ >,>6 jE x 2,2><1 jhq/jE m²jhq rhq. : ?2,<1?6 jhq Hm (?)0 8>,<9? ?2,<1?6 <1?6 Ñ Ñ 7222 Ñ?22 ,% : 2,6936 0 noio jde ih rhqulhrh 7 jdehs ih Oa+ y η poro noio Oa+ hs ?, hmtdmnhs poro shrï η : 7 Η poro Rurhzo : ??,97% 7. Xmo juhstro ih 2,38 a quh ndmtlhmh Os3D>, sh ilsuhevh hm umo cosh; eo ilsdeunlþm sh troto ihspuìs ih mhutroelzoio ndm 82,2 jE ih OaMD > 2,3 M. He prhnlpltoid ih Oa>OsD> sh shporo pdr fletronlþm eovomid he prhnlpltoid. He fletroid y eos oauos ih eovoid aostom 3?,?8 jE ih K^NM 2,?8 M hm su voedronlþm (Jìtdid Vdegori). He prhnlpltoid ih Oa>OsD> sh ilsuhevh hm GMD> y aosto hm su voedronlþm 98,88 jE ih eo jlsjo ilsdeunlþm ih K^NM. Noenueor he pdrnhmto`h ih Os3D>, hm eo juhstro0 + o) O portlr ih eo voedronlþm ihe hxnhsd ih Oa hm he fletroid. c) O portlr ih eo voedronlþm ih Oa >OsD> ilsuhetd hm GMD>. Iotds0 jl : 2,38 a VOaMD> : 82,2jE MOaMD> : 2,3Hq/E VK^NM : 3?,?8jE (rhtrdnhsd) MK^NM : 2,?8Hq/E c) VK^NM : 98,88jE (ilrhnto) %Os3D> :4 o) Os3D> + DG- + 6OaMD> 3Oa>OsD> + G3D / OaMD> (hxnhsd) 82 jE, 2,3 M OaMD> (hxnhsd) + K^NM ↞ Oa^NM 3?,?8 jE, 2,?8 M + KMD> + ² .. Ñ Ñ ?22 % : ?22 m²jhq Oa+ rhq. : m²jhq tdtoe OaMD> - m²jhq K^NM (hxnhsd) m²jhq Oa+ rhq. : 2,3 jhq/jE x 82 jE - 3?,?8 jE x 2,?8 jhq/jE m²jhq Oa+ rhq. : 6,7318 jhq Shhjpeozomid hm ()0 6,731 6,7 3188 Ñ Ñ 6?2<212,79⁉⁉ % : Ñ?22 :<2,28 2,38 % Os3D> : <2,28 c) Oa>OsD> + >GMD> OaMD> + K^NM >OaMD> + G>OsD> ↞ Oa^NM + KMD> 98,88 jE Ih eo hnuonlþm hnuonlþm quêjlno ih (o)0 m²jhq Oa>OsD> : m²jhq Os3D> Ih eo hnuonlþm quêjlno ih (c)0 m²jhqOs3D>:m²jhq Oa>OsD> : m²jhq OaMD> : m²jhq K^NM; hmtdmnhs0 m²jhq Os3D> : m²jhq K^NM % : ² ² Ñ Ñ?22 Shhjpeozomid iotds0 98,88 Ñ 2,?8 Ñ 6?2<212,79⁉⁉ % : Ñ?22 2,38 % Os3D> : <2,?3 <. Eo purhzo ih um ydiurd sdeuceh sh ihthrjlmo prhnlpltomid he L - ndm um hxnhsd ih sdeunlþm ih OaMD> hstïmior y tltueomid he hxnhsd ih Oa+ ndm sdeunlþm ih K^NM. Eo sdeunlþm ih mltrotd ih peoto sh prhporo ilsdevlhmid 3,?33 a ih Oa hm GMD > hvopdromid gosto shquhioi, ilsdevlhmid he rhsliud hm oauo y ileuyhmid gosto thmhr um eltrd. Ih umo curhto 62,22 jE ih hsto sdeunlþm sh oarhaom o ?22,22 jE ih ydiurd y he hxnhsd rhqulhrh ?,2> jE ih sdeunlþm ih K^NM, ih eo nuoe ?,22 jE prhnlplto 2,22?391 a ih Oa ndjd Oa^NM. Hmnuhmtrh he phsd ih ydid prhshmth ndjd L- hm eo pdrnlþm ih ?22 jE ih eo sdeunlþm. Iotds0 jOa : 3,?33 a Vj : ?22,2jE Vsde. : ?E VOaMD> : 62,2jE VK^NM : ?,2>jE, ?jE ≇ 2,22?391 a Oa jL-/?22jE :4 ?22 jE L- + OaMD> 62 jE OaMD>(hxn) + K^NM ?,2> jE OaL + MD>- / OaMD>(hxn) Oa^NM + KMD> (rhtrdnhsd) K^NM + Oa+ Oa^NM ? jE, 2,22?391 a Voedronlþm ih K^NM0 - jL- : m²jhq rhq. x Rjhq L (?) m²jhq rhq. : m²jhq Oa+ - m²jhq K^NM m²jhq rhq. : (V x M) Oa+ - (V x M) K^NM (3) Nïenued ih mdrjoelioihs0 M : Ñ : 3,?33 Ñ ? ⁉ : 2,2?<1 ⁉ RJÑV ?21,71 ⁉ Ñ ? MOa+ : 2,2?<1 Hq/E 22⁉ M : Rjhq Oa+ Ñ V : 2,22??2319,171Ñ⁉?222 Ñ ? MK^NM : 2,2??6 jhq/jE Shhjpeozomid hm (3)0 m²jhq rhq. : 62 jE x 2,2?<1 M - ?,2> ? ,2> jE x 2,2??6 M : ?,?1228 jhq Shhjpeozomid hm (?)0 : ?,?122 ?12288 Ñ ??23262,<?⁉⁉ : 2,?978 ?978 jL- : 2,?978 a hm ?22 jE ih sdeunlþm. OMÏEL^L^ IH JHPNEO^ ?2. (?>-32) Hm he omïelsls ih umo juhstro ih slelnotd quh phso 2,722 a, sh dctuvd umo jhzneo ih MoNe y KNe quh phsþ 2,392 a. Eds nedrurds sh ilsdevlhrdm hm oauo, sh oarhaordm 82 jE ih OaMD > 2,?2 M y he hxnhsd ih pe peoto oto sh tltueo ndm umo sdeunlþm ih K^NM (oeujcrh fìrrlnd ndjd lmilnoidr). ^l eo tltueonlþm rhqulrlþ ?9,96 jE y he K^NM hro 2,>2 % joydr hm mdrjoelioi quh eo sdeunlþm ih OaMD> ´Nuïe hs he pdrnhmto`h ih K3D y Mo3D hm he slelnotd4 Iotds0 jl : 2,722 a MOaMD> : 2,?2 M %K3D:4 j(MoNe+KNe j(MoNe+KNe)) : 2,392 a VK^NM : ?9,96jE VOaMD> : 82jE MK^NM : 2,?+2,>% Hq/E %Mo3D:4 ^lelnotd0 MoNe + KNe + G3D + 3OaMD> 3OaNe + MoMD> + KMD> 2,7 a 2,39 a 82 jE, 2,? M /OaMD>(hxn) OaMD> (hxn) + K^NM Oa^NM + KMD> (Jìt. Vdegori) ?9,96 jE; 2,? x ?,22> M ^ho0 MoNe : x KNe : y x + y : 2,39 (?) He OaMD> rhonnldmo ndm MoNe, KNe y K^NM, ih idmih thmhjds thmhjds00 m²jhq MoNe + m²jhq KNe + m²jhq K^NM : m²jhq OaMD> m²jhq MoNe + m²jhq KNe : m²jhq OaMD> - m²jhq K^NM : Ñ Ñ MK^NM : 2,? M + (2,>/?22) x 2,?M 2,? M : 2,?22> Hq/E ó jhq/jE : 82 Ñ 2,? ?9,96 Ñ2,?22> 2,28798 2,21986 2,21986 x + 2,28798 y : >,89<1 x 2,28798 x 2,21986 2,21986 x + 2,28798 y : 2,2?891 (3) Shsdevlhmid (?) y (3)0 x : 2,27<8 a ih MoNe y : 2,?828 a ih KNe 6?,<7 / Ñ 2,2 2,27< 7<88 3 Ñ 87 87,9 ,98 8 / / 3 % MoD : Ñ?22: Ñ?22 2,7 % Mo3D : 8,<> <9,32 Ñ 2,? ya 2,?82 8288 3 Ñ 1 9, 8 6 3 %D : Ñ?22 : Ñ?22 2,7 % K3D : ??,77 ??.Xmo jhzneo ih CoNe 3 y Mo3ND> sh vo o omoelzor hm nuomtd o su ndmthmlid ih corld pdr he jìtdid ih Vdegori. Eo sdeunlþm tltueomth ih OaMD > sh prhporo ilsdevlhmid 9,<7> a ih i h peoto jhtïelno ih <<,? % ih purhzo hm GMD > y ileuyhmid ndm oauo o 822 jE hm um jotroz vdeujìtrlnd. Hm eo voedronlþm ih eo sdeunlþm ih K^NM, 38 jE ih eo sdeunlþm ih OaMD > rhqulhrh 33,2 jE ih K^NM. Xmo juhstro ih 2,8 a sh ilsuhevh, sh onlilflno y sh eh oarhao 92,> jE ih OaMD>, he hxnhsd ih peoto sh rhtrdtltueo, rhqulrlìmidsh 6,33 jE ih sdeunlþm ih K^NM. o) Noenueh eo mdrjoelioi ih eo sdeunlþm ih peoto. c) Noenueh eo mdrjoelioi ih eo sdeunlþm ih K^NM n) Ihthrjlmor eo ndjpdslnlþm pdrnhmtuoe ih eo jhzneo. l. MOa : ´4 Rrhporonlþm ih eo sdeunlþm ih OaMD >0 jOa : 9,<7> a Rurhzo : <<,?% Vsde : 822 jE 3Oa + 9GMD> MOa :4 3OaMD> + 3MD3 + 3G3D jOa : 9,<7> a x 2,<<? : 9,<>73 a MOa : MOaMD> 9, < > 7 3 Ñ ? Ñ M : : :2,2<?86 RJÑV ?21,71 Ñ 2,8 MOaMD> : 2,2<?86 Hq/E c) MK^NM : ´4 Voedronlþm ih eo sdeunlþm ih K^NM0 VK^NM : 33jE VOaMD> : 38jE m²jhq K^NM : m²jhq OaMD> <?866 : 2,?292 : 38 Ñ 2,22<?8 M : Ñ ?292 33 MK^NM : 2,?292 Hq/E n) Omïelsls ih eo jhzneo0 V OaMD> : 92,>jE VK^NM : 6,31jE CoNe3 + Mo3ND> + 9OaMD> 3OaNe + Oa3ND> + 3MoMD> + Co(MD>)3 x y 92,>jE /OaMD>(hxn) OaMD> (hxn) + K^NM Oa^NM + KMD> 6,31jE m²jhq CoNe3 + m²jhq Mo3ND> + m²jhq K^NM : m²jhq OaMD> Gonlhmid eos josos ih CoNe3 : x Mo3ND> : y x + y : 2,8 (?) Ñ : Ñ 3Ñ?222 3Ñ?222 2,327> 3 2,?26 3 6,31 Ñ 2,?29 : 92,> Ñ 2,2<?86 3 3 : >,2>17 2,327> 2,?26 2,3?3 x + 2,9?66 y : 2,261? (3) Shsdevlhmid (?) y (3)0 x : 2,?13 a ih CoNe3 y : 2,>37 a ih Mo3ND> % CoNe : 2,?13 Ñ?22:>9,9 2,8 Ñ ?22 : 68,6 % MoND : 2,>37 2,8 % CoNe3 : >9,9 % Mo3ND> : 68,6 ?3. Xmo juhstro ih 2,9222 a quh ndmtlhmh ðmlnojhmth MoNe, MoCr y MoL aosto 99,>3 jE ih OaMD> 2,?382 J hm eo prhnlpltonlþm ih eds ndrrhspdmilhmths goeurds. Dtro juhstro liìmtlno sh troto ndm ilnrdjotd hm jhild ïnlid poro heljlmor Cr - y L-. Eo ilsdeunlþm rhsuetomth ndmsujh >3,78 jE ih eo jlsjo ilsdeunlþm ih OaMD > poro prhnlpltor he Ne-. Noenueor eo ndjpdslnlþm pdrnhmtuoe ih eo juhstro. Iotds0 jl : 2,9222 a VOaMD> : 99,>3jE JOaMD> 2,?382jde/E VOaMD> : >3,78jE (Ne-) Shonnldmhs quêjlnos quh sunhihm0 MoNe + MoCr + MoL + OaMD> ↓ OaNe + OaCr + OaL 2,922 a 99,>3jE; 2,?38J:M MoNe + 3MoCr + 3MoL + Nr3D1: + ?9G+ ↓ Cr3↟ + L3↟ + 3Nr>+ + 1G3D MoNe + OaMD> ↓ ↞OaNe + MoMD> >3,78jE %MoNe4 %MoCr4 %MoL4 Gonlhmid0 MoNe : x MoCr : y MoL : z x + y + z : 2,9 a (?) Ih eo ?ro. Yltueonlþm0 m²jhq MoNe + m²jhq MoCr + m²jhq MoL : m²jhq OaMD> : Ñ :(99,>3Ñ 2,?38 ) 2,28798 2,?23< 2,?9<7< ?1,?276x + <,1?73y + 6,61?6z : 8,89 (3) Nïenued ih jMoNe : x jMoNe : m²jhq OaMD> x Rjhq MoNe jMoNe : x : >3,78jE x 2,?38 jhq/jE x 2,28798 a/jhq a/ jhq x : 2,3922 a ih MoNe Shhjpeozomid hm (?) y (3)0 y + z : 2,9 „ 2,39 : 2,?6 (>) <,1?73y + 6,61?6z : 8,89 „ (?1,?276)(2,39) <,1?73y + 6,61?6z : ?,9>>< (9) Shsdevlhmid (>) y (9)0 y : 2,?323 a ih MoCr z : 2,2><< a ih MoL Nïenued ih pdrnhmto`hs0 Ñ?22: %: 2,39 2,9 a %: 2,?323 2,9 a Ñ?22:, Ñ?22:, %: 2,2><< 2,9 a Lma. Y. Oenorroz Oeford 3?2<32 RSDCEHJO^ RSDRXH^YD^ ?. Xmo juhstro ih 2,6822 a quh ndmtlhmh fdsfotd trlsþilnd h ljpurhzos lmhrths sh ilsuhevh y sh mhutroelzo. O ndmtlmuonlþm, sh oÿoihm 82,22 jE ih OaMD> 2,3822 J y sh shporo pdr fletronlþm he prhnlpltoid fdrjoid. He fletroid sh voedro pdr he jìtdid ih Vdegori, aostomid 36,>8 jE ih sdeunlþm ih K^NM 2,3222 J. (o) Noenueor he % ih R 3D8 hm eo juhstro. (c) ^l he prhnlpltoid quh sh gocêo shporoid pdr fletronlþm tros eo oilnlþm ih OaMD> sh ilsdevlhro hm GMD> y sh voedro ndm eo jlsjo sdeunlþm ih K^NM ´_uì vdeujhm sh aostorêo4 Spto. (o) 36,>?% (c) >6,?8jE 3. He ndmthmlid ih onhtlehmd ih umo ndrrlhmth ih aos sh ihthrjlmþ posomid >,22 E ih juhstro o trovìs ih ?22,2 jE ih OaMD> ojdmlonoe 2,2827 J. Eo rhonnlþm hs0 3Oa+ + N3G3 ↓ Oa3N3 + 3G+ Eo voedronlþm ihe hxnhsd ih ldm peoto ndmsujlþ 36,8 jE ih K^NM 2,2798 J. Noenueor eds jlelarojds ih onhtlehmd ndmthmlids hm noio eltrd ih aos. Spto. ?3,>? ja/E >. He ïnlid jdmdnedrdonìtlnd (NeNG3NDDG) hjpehoid ndjd ndmshrvomth hm ?22,2 jE ih umo chclio norcdmotoio sh hxtroh ndm ilhtleìthr y euhad sh poso o ilsdeunlþm onudso ndjd NeNG3NDD- jhilomth hxtronnlþm ndm MoDG ?J. Hsth hxtrontd onudsd sh onliueo y sh troto ndm 82,2 jE ih OaMD > 2,2983? J. Eo rhonnlþm hs0 NeNG3NDDG + Oa+ +G3D ↓ GDNG3NDDG + G+ + OaNe↞ Ihspuìs ih fletror he OaNe, eo voedronlþm ihe fletroid y eovoids rhqulhrh ?2,9> jE ih umo ilsdeunlþm ih MG9^NM. Eo voedronlþm ih um ceomnd iuromth tdid he prdnhsd ndmsujh 33,<7jE ih MG9^NM. Noenueh he phsd ih NeNG3NDDG (ja) hm eo juhstro. Spto. ??6,6> ja 9. He ndmthmlid ih Nd3+ puhih nuomtlflnorsh pdr trotojlhmtd ndm um hxnhsd ndmdnlid ih tldnlomotd hm prhshmnlo ih plrlilmo0 Nd3+ + 9N8G8M + 3^NM- ↓ ↞Nd(N8G8M)9(^NM)3 He prhnlpltoid sh shporo pdr fletronlþm, y he ndmthmlid ih ^NM- hm he fletroid sh ihthrjlmo pdr he jìtdid ih Vdegori. Xm vdeujhm ih 38,22 jE ih umo sdeunlþm prdcehjo sh troto ndm > jE ih plrlilmo y 38,22 jE ih K^NM 2,?237 J hm um jotroz ofdroid ih 382 jE . Eo sdeunlþm sh ileuyh gosto eo jorno ih ofdrd, sh jhzneo y sh fletro. Ihspuìs ih ihsnortor eds prljhrds jleleltrds ihe fletroid, um vdeujhm ih 82,22 jE ihe fletroid sh onlilflno ndm GMD > y sh troto ndm 8,22 jE ih OaMD> 2,?288 J. Ihspuìs ih eo oilnlþm ih Fh>+ ndjd lmilnoidr, he hxnhsd ih Oa + rhqulhrh >,16 jE ih K^NM 2,?237 J poro oenomzor he pumtd ih hqulvoehmnlo. Noenueh eo ndmnhmtronlþm ih Nd3+ hm eo sdeunlþm prdcehjo hm mdrjoelioi y ja/E. 8. Hxprhsh ndm elthroehs he pdrnhmto`h ih Mo 3D hm um slelnotd quh ndmtlhmh Mo y K, o portlr ih eds slaulhmths iotds0 Rhsd ih eo juhstro Oa; Rhsd ih MoNe + KNe dcthmlid : Ca; phsd ih nrlstoehs ih OaMD> oarhaoids poro prhnlpltor he Ne- ih hstds nedrurds y ior um hxnhsd : Na; vdeujhm ih K^NM I M rhquhrlid poro tltueor he hxnhsd ih Oa+ : H jE. Lma. Y. Oenorroz Oeford 3>2<32
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