lOMoARcPSD|20905076 Code Case N 822 for Pin Brazing Non-Structural Attachment Tabs for Buried Pipe Cathodic Protection Quimica General (Universidad Privada del Norte) Studocu no está patrocinado ni avalado por ningún colegio o universidad. Descargado por Marjan Suban (marjan.suban@gmail.com) lOMoARcPSD|20905076 Proceedings of the ASME 2018 Pressure Vessels and Piping Conference PVP2018 July 15-20, 2018, Prague, Czech Republic PVP2018-84897 CODE CASE N-822 FOR PIN BRAZING NON-STRUCTURAL ATTACHMENT TABS FOR BURIED PIPE CATHODIC PROTECTION Steven L. McCracken and Nick Mohr EPRI, Welding and Repair Technology Center Charlotte, North Carolina, USA ABSTRACT Cathodic protection (CP) is one of the primary methods to protect buried piping and pressure components from corrosion and is a critical element in asset management of buried piping at nuclear power plants. Implementation of cathodic protection requires non-structural attachments to the buried piping for electrical leads and connections. The method of attaching copper-copper alloy CP leads to carbon steel piping and components using traditional arc welding processes can be difficult and time consuming. A two-step process is frequently used where a carbon steel weld tab is first welded to the pipe or component by a traditional arc welding process. The copper-copper alloy CP lead is then joined to the carbon steel weld tab by the exothermic welding process. An alternative to this cumbersome two-step process is pin brazing which is an automatic brazing process that uses electric current resistance to heat the interface between a pin capsule and the component. An arc between the pin capsule and the outside surface of the electrical connector is then used to melt the capsule or pin that contains the brazing filler metal. The process is similar to stud welding in that the brazing pin is loaded into an automatic pistol and the brazement is made when the trigger is pulled. ASME Section XI Code Case N882 delineates rules and requirements for application of pin brazing on Class 2 and 3 pressure boundary components. This paper provides the background and description of the pin brazing process with a summary of the technical basis for Case N-882. The attachment of the sacrificial anode or direct current system electrical connection to components is difficult with traditional arc welding processes such as shielded metal arc welding (SMAW). Typically, a piece of carbon steel “weld tab” is welded (e.g. SMAW) to the system and a secondary process is used to join the electrical connector to the weld tab. Pin brazing is a proposed alternative joining process where the electrical connection is brazed directly to the carbon steel component eliminating the need for a weld tab. Pin brazing is similar to stud welding in that the brazing pin is loaded into an automatic pistol and the brazement is made when the trigger is depressed. The pin brazing process is relatively fast and simple with minimal components required. This process is currently not included within American Society of Mechanical Engineers (ASME) Section III or XI nuclear power codes although it is frequently used in other industries. ASME Section IX codified pin brazing in Code Case 2866 [2]. Code Case 2866 provides requirements for qualification of procedures and operators, but current wording in ASME Section XI does not provide specific guidance for using pin brazing to attach temporary or permanent nonstructural attachments to ASME Class 2 or 3 components. To address this gap new Case N-882 was developed to provide requirements for pin brazing nonstructural electrical connections specifically for applications such as cathodic protection and grounding for Class 2 and 3 moderate energy components. CODE CASE N-882 GENERAL REQUIREMENTS Draft Code Case N-882 is applicable for attaching copper or copper alloy nonstructural temporary and permanent electrical connections to Class 2 and 3 carbon steel components (P-No. 101 for brazing and P-No. 1 for welding), and is an alternative to IWA-4440 Welding and Brazing Qualifications [3, 4]. General requirements of the case include the maximum operating temperature not exceeding 200°F (95°C) and operating pressure exceeding 275 psig (1.9 MPa). The removal of temporary attachments is in accordance with NC-4435(b) or ND-4435(b). Lastly, cleanliness requirements are imposed such that brazing is done on a clean dry surface and protected from detrimental environmental conditions. BACKGROUND One of the primary methods in which buried piping and tanks are protected against the deleterious effects of corrosion is by using cathodic protection. Cathodic protection is applied as a system through impressed currents or passive means by instigating protection through galvanic coupling of a sacrificial anode. These systems are expected (based on design) to have shorter life spans than what power plants are experiencing, especially as plants seek license and subsequent license renewals. Resulting from this is a need for power plant personnel to review site conditions and existing CP systems to determine the feasibility and benefit of installing and/or upgrading CP systems [1]. 1 Downloaded From: https://proceedings.asmedigitalcollection.asme.org on 12/21/2018 TermsSuban of Use:(marjan.suban@gmail.com) http://www.asme.org/about-asme/terms-of-use Descargado por Marjan Copyright © 2018 ASME lOMoARcPSD|20905076 Process Description Pin brazing is a relatively simple process as detailed in the seven steps outlined below. Step 1 – Connecting Equipment, and Cleaning Base Material Initial equipment setup entails connecting the battery pack in the power unit, attaching the grounding lead to the workpiece and power supply, and attaching the automated pin brazing gun lead to the power supply. The base material is also cleaned at this time to bright metal removing any scale, oil, dirt, moisture, or debris. Step 2 – Setting the Ferrule The ceramic ferrule is inserted into the end of the pin brazing gun as shown in Figure 2. The ceramic ferrule has multiple purposes in the pin brazing process. The ferrule concentrates heat, keeps molten filler metal directed in the braze region, and provides arc shielding. In this model the ferrule also provides the correct standoff from the work when a cable lug is properly placed. The system will not initiate the brazing process without the ceramic ferrule unless the user willfully bypasses the safety feature. Ceramic ferrules are single use and must be replaced after each use [5]. The qualification requirements of procedures and brazing machine operators are the same as Case 2866 except for minor clarifications. The qualification requirements include brazing 10 pin brazements with the same equipment, connector, pin capsule, and position that will be done in the field. Each brazement is then bent at least 45 degrees and is acceptable if there is no more than 50% visible separation or fracture after bending. The test is acceptable if all 10 brazements meet these acceptance criteria. Brazing machine operators are qualified with acceptable procedure qualification under the essential variables of QB-351.2. Alternatively, each brazing machine operator shall successfully pin braze 5 samples meeting the acceptance criteria for the brazing procedure qualification. The Brazing Procedure Specification (BPS) is required to include at a minimum: base metal P-No., position(s) qualified, equipment description, connector type (size, shape, material), and brazing material (capsule type). PROCESS AND EQUIPMENT DESCRIPTION Equipment Description Typical equipment associated with pin brazing consists of a battery-operated power source, automatically timed brazing gun, ceramic ferrule, brazing pin, cable lug, and grounding lead as shown in Figure 1. Note that the equipment pictured is the Easybond unit by BAC® Corrosion Control (BAC®). There are several other pin brazing equipment manufacturers but they all have the same general characteristics (i.e. power source is battery operated (36V DC), similar consumables, and use an automatically timed brazing gun). Figure 2: Ceramic ferrule loaded into the pin brazing gun Step 3 – Loading the Pin Brazing Capsule The pin brazing capsule is loaded into the pin brazing gun and is automatically set via a spring-loaded mechanism. The pin brazing capsule is comprised of various parts and alloys that provide the flux, filler metal, and stops the brazing process (e.g. fuse wire) [6]. The loaded pin brazing capsule and a description of the various parts are shown in Figure 3. It should be noted that pin capsules come with or without fuse wires depending on the pin brazing gun and system. A pin brazing system that electronically controls the brazing time does not come with a fuse wire. Figure 1: Typical pin brazing equipment A) power supply, B) brazing pin with fuse wire, ceramic ferrule, cable lug (from left to right), C) pin braze gun, and D) magnetic grounding cable 2 Downloaded From: https://proceedings.asmedigitalcollection.asme.org on 12/21/2018 TermsSuban of Use:(marjan.suban@gmail.com) http://www.asme.org/about-asme/terms-of-use Descargado por Marjan Copyright © 2018 ASME lOMoARcPSD|20905076 4. Arc is extinguished when the circuit is mechanically opened (via a fuse wire) or electronically shut off and the brazing pin is pushed into the molten pool of brazing filler metal 5. Brazer maintains pressure for 2 to 4 seconds after the arc is extinguished Pictures of pin brazing when the arc has been initiated and after the arc is extinguished are shown in Figure 5. The total brazing time is approximately 6 to 10 seconds. Figure 3: Pin brazing capsule loaded into the pin brazing gun (left) and capsule description [3] (right) Step 4 – Seating the Connector The selected connector is properly placed with the pin brazing capsule through the center as shown in Figure 4. Note that a downward force was not applied on the pin brazing gun in Figure 4 purposely to show the pin brazing capsule in the center of the cable lug. The brazing process would not initiate unless the downward force was applied to properly seat the ferrule against the lug surface. A cable lug is shown, but there are multiple sizes and types of connectors. Figure 5: Pin brazing once arc has been initiated (left) and after the arc has been extinguished via fuse wire (right) Step 6 – Detaching the Pin Brazing Capsule Shank The pin brazing capsule shank left after the brazing process has been completed is designed for removal and is easily broken off the lug via a mild hammer blow. A picture containing a pin brazement with and without the shank removed is provided in Figure 6. Figure 4: Cable lug installed before commencement of brazing Step 5 – Brazing Once the proper setup has been completed the pin brazing process is initiated and automatically controlled when the trigger is depressed. The only tasks the brazer must perform are to keep the trigger depressed, and maintain constant pressure on the gun during brazing for 2 to 4 seconds after the arc is extinguished. The pin braze process sequence is described as follows [5, 7]: 1. Trigger is depressed. 2. Resistance of current between the pin brazing capsule head and base metal melts the silver capsule. 3. Arc is initiated between the outside surface of connector and pin braze capsule, bringing filler metal up to melting temperature and heating connector. Figure 6: As-brazed copper lug with pin braze capsule shank (top) and completed pin brazement with shank removed (bottom) Step 7 – Clean Soot Off Lug and Base Material The last step is removing the soot with a wire brush or other suitable method. 3 Downloaded From: https://proceedings.asmedigitalcollection.asme.org on 12/21/2018 TermsSuban of Use:(marjan.suban@gmail.com) http://www.asme.org/about-asme/terms-of-use Descargado por Marjan Copyright © 2018 ASME lOMoARcPSD|20905076 MECHANICAL AND METALLURGICAL TESTING PERFORMED BY EPRI Multiple pin brazements were made by the Electric Power Research Institute (EPRI) to evaluate the pin brazing process and to demonstrate qualification requirements proposed in Case 2866 (Case 2866 was not yet approved at the time of EPRI testing). This EPRI demonstration provides the data needed to support Section IX Case 2866 and Section XI Case N-882 while also providing multiple specimens for destructive evaluation. Pin brazing specimens were made with ASTM A-36 carbon steel base material (P-No. 101 for brazing and P-No. 1 for welding) using the pin brazing equipment and consumables discussed in the previous section of this paper. The qualification entailed pin brazing 10 cable lugs consecutively as shown in Figure 7. The 10 cable lugs were then bent approximately 45 degrees via a hammer and visually inspected to determine if there was visible separation greater than the allowable 50% between the lug and plate. All 10 of the pin brazes passed this visual acceptance criteria. Two of the lugs were then bent an additional 45 degrees in two incremental steps: 1) additional 20 degrees and 2) additional 25 degrees. These two lugs were visually inspected at both steps and found to have slightly more visible separation when bent past the required 45 degrees but still much less than the 50% allowable separation, and overall showing a sound brazed connection. The required 45 degrees bend test for the 10 cable lugs and the additional bending of two cable lugs are shown in Figure 8. A metallurgical plan was developed to further investigate three pin brazements. The pin brazement heat-affected-zone (HAZ), using the prescribed pin braze qualification process, was compared to the HAZ of a shielded metal arc weld (SMAW) single bead-on-plate specimen. The SMAW process was selected because it is commonly used to join the weld tab to the pressure boundary component for CP and ground connections. The selected analysis plan is detailed in Table 1 and the specimen cut plan is shown in Figure 9. A photograph of a pin brazement after mounting and polishing is shown in Figure 9 for familiarization to the expected cross section shape and appearance. Table 1: Analysis plan for pin brazement and bead-on-plate specimens Specimen Cross Section Location Macro Exam Microhardness Mapping Composition (EDS) 1 Medial X X X 2 Lateral X X - 3 Medial X - - Bead-onplate (BOP) Lateral X X - Figure 9: Cut plan for specimen removal (left and top right) and representative cross sections of a pin brazement taken from an earlier preliminary EPRI study (bottom right) Material Descriptions The base material selected was approximately 0.75 inch (19 mm) thick ASTM A-36 carbon steel plate with nominal composition of (0.18% C, 0.83% Mn, 0.14% Ni, 0.1% Ni, 0.05% Mo) with a carbon equivalent value (CEV) of 0.37, using the International Institute of Welding (IIW) formula. The chemical composition of the cable lug was identified in BAC® technical datasheet as annealed copper [11]. The pin shank and filler metal (pin) was stated in the datasheet to be brass and Silver Alloy AGA Silco 610 respectively. Searches on the internet for further information regarding AGA Silco 610 yielded no results. Therefore, energy dispersive x-ray analysis (EDS) via scanning electron microscope (SEM) was used to interrogate various regions of Specimen 1 after microhardness mapping was completed. Figure 10 shows six areas that were selected for composition analysis. Figure 7: Completed qualification coupon in the as-brazed condition prior to bend testing Figure 8: Qualification coupon after bending all pins approximately 45 degrees and two pins roughly an additional 45 degrees (left) and the qualification coupon after bending all pins approximately 45 degrees (right) 4 Downloaded From: https://proceedings.asmedigitalcollection.asme.org on 12/21/2018 TermsSuban of Use:(marjan.suban@gmail.com) http://www.asme.org/about-asme/terms-of-use Descargado por Marjan Copyright © 2018 ASME lOMoARcPSD|20905076 Table 2: Chemical composition of 6 areas identified in Figure 10 and BAg-36 braze metal Chemical Composition (wt. %) Figure 10: Composition locations investigated with EDS The EDS analyses corroborated the copper connector and brass pin shank composition listed in the technical datasheet by BAC®. The copper connector appears to be a relatively high purity copper (Areas 1 and 4) and this was expected due to the high conductivity of pure copper. The exact composition or material specification for the brass shank (Area 2) cannot be deduced from this analysis but certainly there is sufficient zinc additions to be classified as a brass alloy. Traces of lead were found in Area 2 which may be an intentional addition to the pin capsule shank, although it should be mentioned that these measurements had high percentage of error. Two areas (Areas 3 and 5) were investigated to gain further information about the brazing filler metal used in the pin brazing capsule. This could be difficult because the arc between the top of the lug and the pin may have caused some level of dilution among the filler metal and pin capsule shank. Thus, the true composition of the filler metal is thought to be higher in silver content while lower in copper and zinc. Brazing filler metal composition ranges found in ASME Section II Part C, SFA-5.8 were reviewed to determine if a known brazing filler metal overlapped the compositions found in Areas 3 and 5 [8]. No potential classification matches were found during review of SFA-5.8. The transition from pin brazement to the base metal was explored in Area 6 using 7 spots starting from the brazement moving towards the carbon steel base metal. It should be noted that very distinct compositions are determined because the small spot size can minimize averaging that are found when using line/area scans. The transition found nothing of significance to report. Spot 5 was removed from the table because the spectral analysis was found, after processing, to include carbon peaks. Carbon is difficult to detect accurately with the EDS system used, distorting the results, and should have been removed. It was observed that Spot 4 composition close to the interface but sufficiently away from carbon steel gave a composition close to BAg-36 filler metal. The average of the specification ranges for BAg-36 was taken by ASME Section II Part C, SFA-5.8 is included in Table 2 for convenience [8]. However, it is not known if the Spot 4 measurement is representative of the bulk filler composition or an Ag rich phase which coincidently aligns with BAg-36 composition ranges. Location Cu Zn Pb Ag Fe Sn Mn C Area 1 100.00 - - - - - - - Area 2 59.33 40.10 0.57* - - - - - Area 3 53.25 26.36 0.29* 20.11 - - - - Area 4 100.00 - - - - - - - Area 5 56.87 20.27 - 22.85 - - - - Area 6 - Spot 1 65.28 26.31 - 8.41 - - - - Spot 2 64.34 26.63 - 9.04 - - - - Spot 3 59.36 26.33 2.42 11.02 0.86* - - - Spot 4 29.16 21.79 0.57* 43.77 0.57* 4.14 - - Spot 5 - - - - - - - - Spot 6 - - - - 99.07 - 0.93 - Spot 7 - - - - 98.67 - 1.31 - BAg-36+ 27.00 25.00 - 45.00 - 3.00 - - * Error greater than 10%, +Average of range provided in SFA-5.8 [5] Macro Examination The three pin braze specimens were cross sectioned per the cut plan in Table 1, polished, and examined at 5X magnification. The un-etched cross sections are presented in Figure 11 with etched cross sections of Specimens 1 and 2 included in following Microhardness Testing subsection. The macrographs revealed some areas of porosity and small regions where the filler metal did not join to the shank or base metal. These observations were primarily seen in Specimen 1 (note that the large tear on the left side is a result of sectioning via the band saw and not a result of bend testing). Specimen 3 also showed a line along the shank that did not appear completely joined to the connector. However, even with excessive bending beyond 45 degrees, Specimen 3 only had minor separation as can be seen on the left side of the macrograph in Figure 11. Specimen 2 was cut in a different orientation (laterally) compared to Specimens 1 and 3, but showed similar discontinuities such as porosity. For all samples the filler metal interface between the pin brazement and the carbon steel plate was difficult to resolve at all locations. It did appear that a good bond was achieved, as no large areas of separation were seen during bending, but identifying the filler metal between the two was challenging in some cases. It was observed that Specimen 1 and 3 had several intergranular microcracks all less than 0.004 inch (0.10 mm) located under the pin brazement penetrating the carbon steel. 5 Downloaded From: https://proceedings.asmedigitalcollection.asme.org on 12/21/2018 TermsSuban of Use:(marjan.suban@gmail.com) http://www.asme.org/about-asme/terms-of-use Descargado por Marjan Copyright © 2018 ASME lOMoARcPSD|20905076 This is thought to be minor instances of copper penetration into the carbon steel, although a full analysis of the microcracks was not completed. The largest microcrack was found in Specimen 1 and pictures of the crack are presented in Figure 12. Literature was found that documents copper penetration into carbon steel base materials. It was mentioned that copper penetration in carbon steels was found to be shallower than compared to low alloy steels [9]. BAC® literature [5] also alludes to this phenomenon where it states: “When working with steel pipelines, in accordance with BS4515:1996, the fusion line of the braze should not be more than 1 mm below the pipe surface. Intergranular copper penetration of the pipe material should not exceed 0.5mm beyond the fusion line when a microsection is examined at a magnification not exceeding x50.” The EPRI test specimens had most instances of copper penetration below 0.002 inch (0.05 mm) with the largest at 0.004 inch (0.10 mm), well below 0.02 inch (0.50 mm). Another paper was located that discusses copper penetration for thermite welding. It was thought to be relevant to this discussion even though the article is specific to thermite welding. In a Nuclear Engineering and Design article [10] the following is reported: “In the microscopic examination the cross sections of all samples processed under different conditions were examined with an optical microscope. From microscopic examination of joints following remarks can be made: The copper and steel were formed intermediate layer, which contains the penetrated copper. The thickness of this layer is from 10 to 20 μm. In some places, just below the steel surface, martensite microstructure occurs due to rapid cooling. Just below the surface of the base material, an increased grain size can be found. In the martensite microstructure microcracks were observed. Their length was up to 0.12 mm. The microcracks were filled with copper. In the samples without martensite microstructure microcracks were not detected.” The authors of that article conclude that reducing formation of martensite via preheat could suppress the initiation of microcracks during thermite welding. They also did a cursory review of the influence of microcracks on the static strength and found only minor reduction in strength [10]. There are distinct difference between thermite welding and pin brazing. First is the fact that pin brazing does not have a fusion zone (what the authors call the intermediate layer). Second, there was not a distinct microstructure defining where copper penetration is found or is not found. Specimen 2 showed no indication of copper penetration although it had similar microstructure to Specimens 1 and 3. This could suggest that instances of copper penetration may tend to form in a location with surface irregularities due to preparation or cleaning. Instances of copper penetration were found in 2 out 4 pin braze specimens cross sectioned (including the initial evaluation specimen). It is concluded that the small size and limited number of these microcracks while being contained under the pin brazement render the microcracks of little consequence. They are not expected to be detrimental to the intended function of the piping/components or the connector. However, this may not be true for materials more susceptible to deeper copper penetration (e.g. low alloy steels and austenitic stainless steels), and these conditions would require further evaluation. The use of a preplaced brazing ribbon with high silver content such as BAg-7 or BAg-8 could be used to buffer the high copper content at the carbon steel interface. The use of the preplaced brazing ribbon may eliminate copper penetration, but has yet to be tested by EPRI at this time. Figure 11: Macrographs at 5X magnification for Specimen 1 (top), Specimen 2 (middle), and Specimen 3 (bottom) Figure 12: Specimen 1 micro crack identified via a circle (top), same microcrack magnified to 100X by optical microscope (bottom left), and same microcrack magnified to 1000X by SEM (bottom right) 6 Downloaded From: https://proceedings.asmedigitalcollection.asme.org on 12/21/2018 TermsSuban of Use:(marjan.suban@gmail.com) http://www.asme.org/about-asme/terms-of-use Descargado por Marjan Copyright © 2018 ASME lOMoARcPSD|20905076 Microhardness Testing Microhardness mapping was completed on Specimens 1 and 2 using a Vickers indenter and a load of 500 grams (HV 500 gf) with grid spacing of 0.01 inch (0.25 mm) in the X and Y directions. A weld bead was made using SMAW on the same qualification material to provide a comparison between Specimen 1, Specimen 2, and a bead-on-plate heat affected zone. The weld bead was made using 1/8-inch diameter E7018 electrode at ambient temperature which is consistent with filler metal that would be used to attach the weld tab in the field. The microhardness data was then used to develop a color map for each using Origin® software version 9.1. Each cross section along with the corresponding color map is presented in Figure 13, 14, and 15 (color map hardness scale is the same for each figure). The cross sections were etched using Nital solution. It should be noted that some areas of the carbon steel cross section became over-etched attempting to reveal more of the pin brazement microstructure and regions. Specimens 1 and 2 each have five additional measurements in the unaffected base metal to determine the average hardness for the bulk material. Analysis of the hardness maps showed that the HAZ associated with pin brazements are roughly three times shallower than the bead-on-plate specimen. Another difference is the highest hardness areas are centrally located under the pin brazement at the surface of the carbon steel. The area of highest hardness (identified with shades of red) reaches a depth of 0.016 inch (0.40 mm). This contrasts with the weld where the high hardness follows the fusion zone down into carbon steel and reaches a depth of roughly 0.083 inch (2.10 mm). A white dotted line was placed on each color map at a depth of 0.039 inch (1.00 mm) for reference among the three color maps. for Specimen 1, 2, and the bead-on-plate were 171.5, 179.8, and 195.5 HV 500 gf respectively. As expected, the brazing and SMAW bead-on-plate weld caused higher hardness in the weld HAZ, with the bead-on-plate specimen exhibiting the highest hardness. The peak hardness in the bead-on-plate specimen was 349 HV 500 gf while Specimen 2 had the highest pin brazement peak of 319 HV 500 gf. Lastly, the histograms in Figure 16 show the SMAW bead-on-plate had a larger percentage in the right tail correlating to larger areas of higher hardness. Therefore, the pin brazing process demonstrates a shallow and more localized region of increased microhardness when compared to an SMAW weld that is representative of the weld process typically used to attach a carbon steel tab. Figure 14: Pin braze Specimen 2 hardness map (HV 500 gf) Figure 13: Pin braze Specimen 1 hardness map (HV 500 gf) Descriptive statistics were performed for Specimens 1, 2, and the bead-on-plate with the results summarized in Table 3 and histograms with cumulative probability plots provided in Figure 16. The unaffected base metal was found to have an average microhardness of 136.7 HV 500 gf while the averages Figure 15: Bead-on-plate hardness map (HV 500 gf) 7 Downloaded From: https://proceedings.asmedigitalcollection.asme.org on 12/21/2018 TermsSuban of Use:(marjan.suban@gmail.com) http://www.asme.org/about-asme/terms-of-use Descargado por Marjan Copyright © 2018 ASME lOMoARcPSD|20905076 Table 3: Microhardness statistics Measure -ments Min . Max. Mean Median STD 10 129 144 136.7 135.5 5.2 Spec. 1 490 129 279 171.5 163 29.5 Spec. 2 525 132 319 179.8 166 38.7 BOP 850 136 349 195.5 169 46.3 Specimen Base Metal Robustness Testing of the Pin Brazing Process Robustness testing was conducted after completing the qualification testing using the same ASTM A-36 test plate. The objective of robustness testing was to determine how sensitive the pin brazing process was to a number of variables and when intentionally performed incorrectly. An initial test matrix was developed and can be seen in Figure 17. A builtin safety feature automatically ends the brazing cycle prematurely when a cable lug or a ceramic ferrule are not used together. Both conditions were validated and the cycle did not melt the pin capsule leaving those locations available for a second round of testing. The second round of testing included not depressing the trigger through the whole brazing cycle, and overriding the built-in safety feature so brazing would commence without a ceramic ferrule. Note that proper safety precautions were taken during testing without the ceramic ferrule to shield operator and spectators from molten filler and arc flash. The results from the robustness testing determined that overall the pin brazing process can produce acceptable brazements under most conditions. The off-angle pin brazing seen in Figure 18 was thought to be one of the most likely situations encountered in the field and had acceptable results. Pin brazing with lower downward pressure, over mild mill scale and soot, and with a shortened trigger depression all resulted in an acceptable brazement after bend tests. Attempting to pin braze without either a cable lug or a ceramic ferrule resulted in the fuse almost immediately being broken, ending the brazing process. In both cases, the safety feature engaged as expected with arc initiation noticed on the base metal for the test without the cable lug. Pictures of the tests without the ceramic ferrule or cable lug are found in Figure 19. When attempting to override the safety feature (attempting to trick the system into thinking that both a cable lug and ferrule are present) the process quickly blew a fuse as well leaving a small mark on the base metal. The last test condition was brazing over full mill scale which represents attempting to braze without cleaning the base metal. This condition also resulted in an obvious failure visually and the connection fell off when attempting to remove the capsule shank. Pictures of brazing over mild mill scale and soot, and full mill scale are found in Figure 20. The resultant test plate with all conditions identified via a text box and a summary table can be found in Figure 20 and Table 4 respectively. A green text box represents conditions that passed Case 2866 and draft N-882 code case acceptance criterion with a red text box indicating a failed condition. Hardness (HV 500 gf) # of Figure 16: Hardness histogram and cumulative probability of Specimen 1 (Top), Specimen 2 (middle), and Bead on Plate (bottom) 8 Downloaded From: https://proceedings.asmedigitalcollection.asme.org on 12/21/2018 TermsSuban of Use:(marjan.suban@gmail.com) http://www.asme.org/about-asme/terms-of-use Descargado por Marjan Copyright © 2018 ASME lOMoARcPSD|20905076 Figure 21: Results of robustness testing after bending approximately 45 degrees with green boxes representing test that passed qualification requirements and red boxes representing those that failed Figure 17: Initial test matrix for robustness testing Table 4: Summary of tests and results of robustness testing Figure 18: Off angle test before (left) and after brazing (right) Test Condition Description of Results Results Brazing gun held offangle Acceptable after bending Pass Brazing gun with low pressure applied Acceptable after bending Pass Pin braze without cable lug Safety feature engaged, fuse blown before brazing could begin Fail Pin braze without ferrule Safety feature engaged, fuse blown before brazing could begin Fail Pin braze without ferrule (Safety feature overridden) Brazing initiated but fuse was blown quickly after trigger (did not join) Fail Pin braze over mild scale and soot Braze was erratic with significantly more separation was observed Pass Pin braze over full scale Did not join to the plate and broke off easily Fail Pin braze with trigger depressed shorter than directed Acceptable after bending (more separation than typical pin brazement) Pass Pin Brazing with Water Backing A comment received on the ASME Standards Committee XI first consideration ballot of Case 2866 regarded the effectiveness of pin brazing for water backed applications. The commenter asked if the greater heat sink of a water backed component would have a deleterious effect on the process to join the connector. A water backed condition was considered bounded by the plate thickness was selected for pin brazement testing and since no preheat was applied. However, to evaluate a water back condition more directly remnant from robustness testing was used to perform pin brazing with water back conditions. The water backing was simulated using a pan filled with water that encroached up to approximately half of the plate thickness. Pictures of the test setup is shown in Figure 22. Three pin brazements were made after the test plate was positioned in the trough for approximately 15 minutes. Figure 19: Pin brazing without a cable lug (top), without a ceramic ferrule (bottom left), and the result of brazing without ceramic ferrule (bottom right) Figure 20: Pin brazing over full mill scale (left) and pin brazing over mild mill scale and soot from previous brazement (right) 9 Downloaded From: https://proceedings.asmedigitalcollection.asme.org on 12/21/2018 TermsSuban of Use:(marjan.suban@gmail.com) http://www.asme.org/about-asme/terms-of-use Descargado por Marjan Copyright © 2018 ASME lOMoARcPSD|20905076 Temperature readings of the water and plate were taken before and after brazing using a single digital thermometer. For the first test, the measurements for the water and plate were not taken at the same durations after the initial temperature readings. The water temperature was measured fairly quickly after pin brazing for Specimen 1-WB, but was found to have minimal increase. For the remaining two brazements the plate temperature was monitored more closely after completion of brazing. It was observed that temperature decreases rapidly after brazing had been completed. A table of temperature readings for all specimens are found in Table 5. Note that the digital thermometer appeared to perform better in the water due to a greater surface area of the probe being exposed to the media being measured whereas a smaller surface area could contact the plate. This is assumed to be the reason for the temperature differences between the initial water and plate temperatures. Water measurements were taken next to the plate near the brazement and plate measurements taken approximately a half inch next to the completed brazements. The completed brazements are seen in Figure 23. The three completed pin brazements were removed from water backing and bent approximately 45 degrees representing the requirements of Case 2866 and draft Case N882. All pin brazements were found to meet the acceptance requirements of both cases. They were then bent an additional 45 degrees to determine if there was good correlation between the water backed samples and those done during the qualification testing. Pictures of the initial 45 degrees bend and the 90 degrees bend are found in Figure 24. All bend test samples (with and without water backing) had similar results with minor amounts of separation that would be acceptable in accordance with the cases. In conclusion, testing shows there is good correlation between pin brazements made with and without water backing. Figure 22: Water backed testing setup (top and bottom left) and water level relative to test plate (top and bottom right) Figure 23: Pictures of the first pin brazement before brazing (top left), three completed pin brazement with capsule shanks still attached (top right), top view of pin brazements with capsule shanks removed (bottom left), and side view of pin brazements without shanks removed (bottom right) Table 5: Temperature readings taken during water backed pin brazing Specimen 1-WB 2-WB 3-WB Time (sec.) Water Temperature °F (°C) Plate Temperature °F (°C) Initial 5 15 25 Initial 5 15 25 Initial 5 15 30 70.7 (21.5) 74.5 (23.6) 70.7 (21.5) 71.9 (22.2) 71.4 (21.9) 71.2 (21.8) 73.0 (22.8) 93.5 (34.2) 85.5 (29.7) 74.8 (23.8) 125.0 (51.7) 90.0 (32.2) Figure 24: Pin brazements bent approximately 45 degrees (left) and pin brazements bent an additional 45 degrees (right) 78.9 (26.1) 130.0 (54.4) 105.0 (40.6) - STATUS OF CASE N-882 Standard Committee XI approved Code Case N-882 on March 29, 2018 by a vote of 28 approved, 0 disapproved, and 0 abstaining (Ballot 18-657). The case was approved for publication by the ASME Board of Nuclear Codes and Standards (BNCS) on April 18, 2018 (Ballot 18-987) [3]. 10 Downloaded From: https://proceedings.asmedigitalcollection.asme.org on 12/21/2018 TermsSuban of Use:(marjan.suban@gmail.com) http://www.asme.org/about-asme/terms-of-use Descargado por Marjan Copyright © 2018 ASME lOMoARcPSD|20905076 SUMMARY AND CONCLUSIONS The pin brazing process was found to produce multiple brazements all able to withstand aggressive bending while maintaining an acceptable bond. Ten pin brazements were evaluated and passed proposed qualification requirements of bending to 45 degrees with no visible separation greater than 50%. In fact, two pin brazements were bent an additional 45 degrees and only showed minor separation from the ASTM A-36 qualification plate. The pin brazing copper lug, shank, and filler metal composition were evaluated using EDS and found to be copper, brass alloy, and an Ag-Cu-Zn-Sn alloy respectively. Although the EDS analysis is not used for ascertaining definitive chemical composition, it could corroborate information found in BAC® technical datasheet. The pin brazing filler metal composition could not be definitively determined, but was found to align closely with BAg-36 filler metal. Note that both Case 2866 and N-882 require the same materials (connector and pin) that were used during the qualification process be used in production. The pin brazements were also examined via macrographs and found to contain some level of porosity and areas where there did not appear to be complete coalescence. This was not found to hamper the bond nor is it expected to lessen the effectiveness of the cathodic protection system. Copper penetration into the carbon steel was also found during macro examination in two specimens with the largest microcrack penetrating to 0.004 inch (0.10 mm). Most observed microcracks were on the order of 0.002 inch (0.05 mm) or smaller. Literature searches determined that copper penetration for carbon steel and for pin brazements is not uncommon with these material combinations. All microcracks were found to be contained under the pin brazement and due to the small size, limited amount, and intended function of the connectors (i.e. non-structural) they are expected to have no significance. The areas of higher hardness in the HAZ of pin brazements were determined to penetrate no more than 0.039 inch (1.0 mm) with the area of highest hardness contained centrally under the pin brazement. A weld bead-on-plate HAZ was used as comparison to the pin brazements and it was deeper penetrating and resulted in higher peak hardness. Thus, pin brazing can develop elevated hardness in the HAZ but it was found to be of smaller magnitude (depth and hardness) compared to a weld made using SMAW. The pin brazing process is purposely developed for installing cathodic protection connectors and does so quickly with reproducible results. Additionally, the process potentially has significant benefits to utilities in regards to time and cost savings by using a single step to attach cathodic protection connectors. The portability and reproducibility of pin brazing makes it ideal for applications such as buried piping which usually extend a great distance away from the plant. This evaluation of the pin brazing process found nothing to suggest the pin brazing process should not be used for cathodic protection applications. It is recommended that the pin brazing process be considered for attaching electrical connectors on carbon steels (P-No. 101 for brazing, limited to materials with a P-No. 1 for welding) via Code Case N-882 for Class 2 and 3 applications. Using the pin brazing process on base materials other than P-No. 101 would require further study. ACKNOWLEDGMENTS The authors would like to recognize Robert (Dana) Couch, EPRI Principal Technical Leader – Welding and Repair Technology Center, for his expertise, guidance during testing and development of Section IX case 2866 which much of the basis for the Section XI case is based upon. Dylan Cimock, EPRI Technical Leader – Plant Technology, for his expertise and input during testing and development of Section IX case 2866. Ben Sutton, EPRI Technical Leader – Welding and Repair Technology Center for his assistance with the EDS work associated with the Pin Brazing specimens. REFERENCES [1] Evaluation for Installing or Upgrading Cathodic Protection Systems: A Guide for Cathodic Protection for Buried Piping and Tanks. EPRI, Palo Alto, CA: 2015. 3002005067 [2] Case 2866, Pin Brazing, Approved September 30, 2016, ASME Record No.: 15-1762 [3] ASME Record No.: 17-1715, BPV SC-XI, Section XI Code Case N-882 for Pin Brazing [4] ASME Boiler and Pressure Vessel Code, ASME Section XI, Rules for Inservice Inspection of Nuclear Power Plant Components [5] Glenn Symington. “Pin Brazing- A metallurgically safe method of making electrical connections to pipelines and other metallic structures, which are to be cathodically protected or electrically earthed”, BAC Corrosion Control Ltd. [6] Website: http://www.pin-brazing.com/ [7] Website: http://www.stanleyhydraulics.com/produ cts/pin-brazing-safebonding [8] ASME Boiler and Pressure Vessel Code, Section II-C, Specifications for Welding Rods, Electrodes, and Filler Metals 2015 Edition, American Society of Mechanical Engineers, New York, NY. [9] W. F. Savage, E. F. Nippes, AND R. P. Stanton, “lntergranular Attack of Steel by Molten Copper”, American Welding Society Welding Journal, January 1978, pg 9-s to 16-s [10] M. Suban, S. Bozic, A. Zajec, R. Cvelbar, B. Bundara. “Crack Analysis in Thermite Welding of Cathodic Protection”, Nuclear Engineering and Design 246, 2012, pg. 123 -127 [11] BAC© Corrosion Control, “Pin Brazing – Easybond Unit”, Technical Datasheet 5.1-2 11 Downloaded From: https://proceedings.asmedigitalcollection.asme.org on 12/21/2018 TermsSuban of Use:(marjan.suban@gmail.com) http://www.asme.org/about-asme/terms-of-use Descargado por Marjan Copyright © 2018 ASME