Fundamental of Soil And Rock Mechanics University of Gondar Department of Geology Course Title: Fundamental of soil and rock mechanics Course Code: Geol. 3111 Credit hours: 3 credit or 5 ECTS Course Category: Core course Instructors: Azemeraw Wubalem (MSc) email: alubelw@gmail.com phone:0935452268 Office's 3rd floor room 28 11/17/2022 1 Chapter one: Introduction to soil mechanics Chapter one outline Objectives: students will able to • Introduction • Define soil and soil mechanics • Soil mechanics • Rock cycle and origin of soil • Soil type and profile • Evaluate how the soil is formed • Determine the profile of soil • Classify soils into different groups based on the texture 11/17/2022 2 Introduction to soil mechanics Introduction What is soil? ▪ The earth’s crust is composed of soil and rock. • In general sense of engineering, soil is defined as ▪ Rock can be defined as a natural aggregate of the unconsolidated aggregate (or granular material) of mineral grains and decayed organic matter along minerals that are connected by strong bounding or attractive forces. with the liquid and gas that occupy empty spaces between the solid particles. ▪ Soil may be defined as the unconsolidated • All man made structures, except those which float sediments and deposits of solid particles that or fly, are supported by natural soil or rock have resulted from the disintegration and deposited. decomposition of rocks. 11/17/2022 3 Introduction to soil mechanics What is soil mechanics? • Is the branch of science that deals with the physical properties of soil and behavior of soil • When loads are applied, on what rate does soil deform? • How much load can we apply to soil before it mass subjected to various type of forces. fails? • In other words, soil mechanics is the study of both solid and fluid mechanical characteristics of soils. • How does soil fail? ❖Fluid mechanics issues: ❖Solid mechanics issues: • How does water flow through soil? (how fast?) • How much soil will deform when it is loaded? • How can fluid flow through soil cause it to fail? 11/17/2022 4 Introduction to soil mechanics Why we study soil mechanics? • All branch of civil engineering require an • Knowledge of soil mechanics is essential to assure that the structures are properly supported. This can avert structural damage understanding of soil and how it behaves and failure, loss of life, and financial loss namely, etc. • Structural Engineering Transportation Engineering • Transportation Engineering • Roadbeds are often built of soil, and the • Environmental Engineering roadways themselves can often pass through • Hydraulic Engineering mountains, cuts, fills, etc. • Understanding SM can preclude problems Structural Engineering • All engineering structures are come in contact with soil via their foundations e.g. bridge, office, house etc. 11/17/2022 with pavement potholing and cracking, as well embankment and slope failures that can wipe out the entire roadways. 5 Introduction to soil mechanics Environmental Engineering Hydraulic Engineering • Landfilling of solid wastes, or liquid toxins or pollutants often spilled or • The design of earthen flow retention released inadvertently onto or into soil. • Therefore, important questions that need to be addressed are: structures such as dams, levees, dikes, storage ponds, etc. require a knowledge of how water is transported through soil. • Will the pollutants remain in place, or possibly • It also requires that to know how water be transported through soil? If so, on what rate? flowing through soil can cause failure by • Can anything be done to cleanup the pollution? mechanisms such as, boiling, piping, erosion, (like providing barriers and other remediation and scour. measures) 11/17/2022 6 Introduction to soil mechanics • In general, Behavior of the structure depends upon: Properties of soils on which the structure rests Properties of the soils from which they are derived (rocks) 11/17/2022 Properties of the rocks from which they are composed. 7 Introduction to soil mechanics • Engineering geologists or geotechnical • Before those, it is important to engineers must study the properties of revise about the classification of soils, such as its: rocks. • Origin, grain size distribution • Ability to drain water • Strength • Mechanical behavior of soil. • When they are sheared or compressed or when water flows through it. • The rocks that form the earth’s surface are classified as to origin as: • Igneous • Sedimentary, and • Metamorphic 11/17/2022 8 Introduction to soil mechanics Igneous rocks • Are formed when the molten state of magma or lava crystalized or solidified. • If the molten rock cools very slowly, the • When the solution of minerals is cooled more rapidly, tiny crystals of the minerals are formed in a vitreous matrix. different materials segregate into large crystals forming a coarse grained or • E.g. granular structures. For e.g. Granite (quartz and feldspar). • Based on silica content rocks are classified as acidic and mafic. 11/17/2022 rhyolite-extremely fine grained rocks • Basalt-when formed with ferromagnesian materials 9 Introduction to soil mechanics Sedimentary Rocks • Are formed from accumulated deposits of Metamorphic Rocks • Resulted when any type of existing soil particles or remains of certain organisms that have become hardened by pressure or cemented by minerals. rock is subject to metamorphism, the change brought about by combinations • Due to abundant availability of cementing of heat, pressure, and plastic flow so minerals such as silica, carbonates, and that the original rock structure and iron oxides. • For e.g., limestones, sandstone, shale, mineral composition are changed. e.g. Granite-Gnesis;sandstone-quartzite. conglomerate, and breccia. 11/17/2022 10 Rock cycle and Origin of soils • Origin of soil - is related to a complex combination of conditions and processes, and it is the result of continuous processes • It is associated to the rock cycle (weathering, transportation, deposition, compaction, then again disturbances and weathering etc.). • A basic understanding of soil forming relationships will aid the Engineering Geologist in evaluating soils and their uses. • Rock cycle 11/17/2022 11 Bowen’s Reaction Series and weathering for soil formation Bowen’s Reaction Series • The reaction series are similar to the weathering stability series • More stable higher weathering resistance • Weathering is more rapid for parent material composed of less stable minerals and it is faster at higher temperatures 11/17/2022 12 Weathering and formation of soils Climate- determines the amount of water and the Rocks (IR, SR and MR) •d temperature. • Arid: Minimal leaching, slow dissolution • Humid: Extensive leaching, rapid dissolution • Cool: Active physical weathering, slow chemical weathering. Weathering (physical/chemical/bio) • Warm: Strong chemical weathering Transported/in place Soil type Boulders, gravel, & sand, silt, & clay Coarse soil 11/17/2022 Fine soil 13 Weathering and formation of soils • Rocks whose chief mineral is quartz minerals with high silica content, decomposes to predominantly sandy or gravely soil with little clay Soil type • Soils can be grouped into two broad categories (depending on the method of deposition): 1. Residual – formed from the weathering rock • Basic rocks decomposed to the fine textured and remain at the location of their origin. Material which may possess little mineralogical silt and clay soils • The clays are not small fragments of the original resemblance to the parent rock materials that minerals that existed in the parent 2. Transported-those materials that have been rock) moved from their place of origin by gravity, results of primary rock minerals decomposing to form secondary minerals) water, glaciers, or man either singularly or in combination 11/17/2022 14 Origin of soil and type of soils • Transported soils are classified based on transported agency and methods of deposition such as: • Alluvial-transported by rivers • Glacial-by ice (glaciation-massive moving sheets of ice • Colluvial-deposited through action of landslide and slope wash. • Lacustrine-deposited in quiet lakes • Marine-deposited in sea water • Aeolian-transported by wind 11/17/2022 15 Soil profiles • A soil profile is a vertical cross-section of a soil • B-Horizon • The different soil layers are called soil horizons Enriched in clay, iron and aluminum (A-B-C horizons) and are differentiated on the oxides and hence red-brown in basis of color, structure, chemistry, texture, color. organic content, etc. • A-Horizon - Maximum biological activity with formation of A - Fine material leached from Ahorizon down reinforces the B- B Horizon to form a hardpan (or clay pan) humus C-Horizon: - Darker-colored than the lower layers - Zone of weathered parent material - Not suitable as a construction material or as a foundation 11/17/2022 C similar to the material from which the soil developed 16 Provide solutions, not problems I Will work Hard ,I Will Succeed 11/17/2022 Lecture 1 Come early, stay late you need to learn to only have fun after all of your work is done 17 End of chapter 1 36 •This is all what I have to say. •Thank you too much for your eyeful attention! 11/17/2022 18 Chapter Two: Soil aggregate relationship Chapter two outline Objectives: students will able to • Soil aggregate relationship • Define soil state • Soil state • Phase relationship • Relative density • State the soil phase condition and relationship • Identify soil grain shape and structure • Grain shape of soil • Clays and their behavior and soil structure 11/17/2022 • Differentiate the properties different clay minerals 19 of Soil Aggregate Relationship • Soil is a particulate material which Constituents of Soil Mass • The behavior of soil mass under stress is a function of material properties such as: means that a soil mass consists of accumulation of individual particles that are bonded together a) size and shape of grains, b) gradation, mechanical c) through not strongly as for rock. mineralogical composition, d) or attractive by means arrangements of grains, e) inter particle • Spaces in between solid particles is forces. • Material properties- f(constituents of the soil mass) 11/17/2022 called voids or pore spaces, which may fill by water or gas. • Therefore soil has soil particles, water, and air. 20 Soil Aggregate Relationship • Soil is inherently •d multiphase material which are solid, liquid and gaseous phases. • It can be two phases when it is completely dry or saturated 11/17/2022 21 Soil Aggregate Relationship Solid phase consists of : Liquid Phase • Primary rock forming minerals (size >2μm, poor reactivity, prone to Water disintegration) • Clay minerals (basic materials that form the soil mass, size< 2μm, high reactivity). • Cementing material (carbonates) • Organic matter (high Polluted Water Water soluble Water insoluble • Water soluble-chlorides, sulphates, bicarbonates (not capable of binding solid grains), more corrosive and acidic water • Water insoluble-carbonates (capable of binding solid absorption, compressible, unstable) 11/17/2022 Pure Water Dissolved salts grains) 22 Soil Aggregate Relationship Gaseous Phase Air Gasses Air Water Solids Solids 2-phase system: dry soil 11/17/2022 •n 2-phase system; saturated soil 23 Soil Aggregate Relationship Phase relationships • Volume relationship • Weight relationship • Inter other relationship 1. Volumetric relations • It is commonly used in soil and rock mechanics such as: • Void ratio e • Porosity n • Degree of saturation Sr • Air content ac • Air void ratio or percentage air voids na 11/17/2022 24 Soil Aggregate Relationship • Void ratio (e) is the ratio of volume of voids to the volume of solids e 𝑉𝑣 = 𝑉𝑠 • Volume of voids (Vv) refers to that portion of the volume of the soil not occupied by solid grains 11/17/2022 25 Soil Aggregate Relationship • In nature, even though the individual void spaces are larger in coarse grained soils, the void ratios of fine grained soils are generally higher than those of coarse grained soils. • The ratio of volume of voids to total volume V is defined as porosity (n). • n= • n= 𝑽𝒗 *100, 𝑽 𝒆 𝟏+𝒆 11/17/2022 but, V= 𝑽𝒗 + 𝑽𝒔 • n of soil cannot exceed 100%, which is in the range of 0<n<100 • It is the f(shape of grains, uniformity of grains size, and the condition of sedimentation). • n=25%-50% (natural sand) • n=30-60% (soft natural clays) 26 Soil Aggregate Relationship • Out of porosity n, void ratio is used frequently Natural water content of fine grained soils > in soil engineering because: e=Vv/Vs and coarse grained soils. No upper limit to w. n=Vv/V Degree of saturation Sr ❖Any change in V is a direct consequence of a similar change in Vv and while Vs remains the same. For partially saturated soil mass. (𝑉𝑣 −𝑉𝑎 ) 𝑆𝑟 = 𝑉𝑣 ∗ 100 = 𝑉𝑤 /𝑉𝑣 It is expressed in percentage, 0<Sr<100 Water content Sr=0 for completely dry soil • The water content w is given as Ww/Ws which expressed in percentage. Ww is weight of Sr=1 (100%) for completely saturated soil mass 0<Sr<100 for partially saturated soils. water, and Ws is weight of solids (dry conditions) 11/17/2022 27 Soil Aggregate Relationship Degree of saturation of sand in various states valid only sands • Fine or silty sands are moist, wet or saturated. • Clays are always completely or nearly saturated Condition of sand Sr % except in the layer of soil subjected to seasonal variation of temperature and moisture. Dry 0 Humid 1-25 Damp 26-50 Moist 5-75 Wet 76-99 Saturated 100 11/17/2022 • Air content 𝑎𝑐 = 𝑉𝑎 𝑉𝑣 =(𝑉𝑣 −𝑉𝑤 )/𝑉𝑣 = 1 − 𝑆𝑟 . • Ac=0 for saturated soil, but ac=1 for dry soil mass. • Air void ratio 𝑛𝑎 = 𝑉𝑎 𝑉 28 Soil Aggregate Relationship Weight Relationships • Unit weight Ƴ = 𝑊 𝑉 is the ratio of weight of soil to total volume of soil, which is the f(unit weight of solid constituents, n, and Sr) • Bulk unit weight (Ƴb) for a partially saturated soil mass • Ƴ𝑏 = 𝑊 𝑉 = (𝑊𝑤 + 𝑊𝑠 )/(𝑉𝑤 +𝑉𝑠 +𝑉𝑎 ) • Ƴ𝑠𝑎𝑡 =(𝑊𝑤 + 𝑊𝑠 )/(𝑉𝑤 +𝑉𝑠 ) • Dry unit weight • Ƴ𝑑 = 𝑊𝑠 =𝑊𝑠 /V 𝑉𝑠 +𝑉𝑎 = (𝑊 − 𝑊𝑤 )/V 𝑊 =( -𝑤𝑊𝑠 /V)=Ƴ𝑏 -wƳ𝑑 𝑉 Ƴ𝑑 =Ƴ𝑏 /(1+w), for dry soil mass, Vw=0. • Where Ƴ𝑠𝑎𝑡 is saturated unit weight of the soil 11/17/2022 29 Soil Aggregate Relationship Specific gravity • Is the ratio of the unit weight of a substance to the unit weight of water Yw at 4°c. • In soil mechanics, specific gravity generally refers to the specific gravity of solid particles Gs, and is defined as the unit weight of solid particles to the unit weight of water. 𝐺𝑠 = Ƴ𝑠 Ƴ𝑤 • 𝐺𝑠 =weight of soil solids/weight of water volume 𝑊𝑠 . 𝑉𝑠 Ƴ𝑤 = equivalent to that of water =(𝑊2 −𝑊1 )/ 𝑊4 − 𝑊1 − 𝑊𝑠 𝑉𝑠 • Unit weight of solid constituents Ƴ𝑠 = • Specific gravity can be determined from laboratory (𝑊3 − 𝑊2 )) ❖For most soils Gs ranges from 2.5-2.9. • Gs=2.65 for sands. 11/17/2022 30 Soil Aggregate Relationship Gs for a partially saturated soil: • Mass specific gravity 𝐺𝑚 = • 𝐺𝑚 (𝑑𝑟𝑦) = Ƴ𝑑 Ƴ𝑤 Ƴ𝑏 Ƴ𝑤 𝑓𝑜𝑟 𝑑𝑟𝑦 𝑠𝑜𝑖𝑙 • 𝐺𝑚 (𝑠𝑎𝑡𝑢𝑟𝑎𝑡𝑒𝑑) = Ƴ𝑠𝑎𝑡 Ƴ𝑤 𝑓𝑜𝑟 𝑠𝑎𝑡𝑢𝑟𝑎𝑡𝑒𝑑 𝑠𝑜𝑖𝑙 •= • = (𝑊𝑠 +𝑊𝑤 −𝑉Ƴ𝑤 )) V (𝑊𝑠 +𝑊𝑤 V 𝑉Ƴ𝑤 -treating whole soil mass as one unit −Ƴ𝑤 )) • = Ƴ𝑠𝑎𝑡 −Ƴ𝑤 • Gm (dry)-mass specific gravity (dry state) • Gm (sat)-mass specific gravity (saturated state) Submerged (Buoyant) unit weight Ƴ’= 𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝑠𝑜𝑖𝑙 𝑖𝑛𝑠𝑖𝑑𝑒 𝑡ℎ𝑒 𝑤𝑎𝑡𝑒𝑟 𝑡𝑜𝑡𝑎𝑙 𝑣𝑜𝑙𝑢𝑚𝑒 11/17/2022 31 Soil Aggregate Relationship Basic phase relationships 𝐺𝑠 = Two approaches: I. Specific volume approach (Vs=1) II. Unit volume approach (V=1) Ƴ𝑠 Ƴ𝑤 = 𝑊𝑠 , 𝑉𝑠 Ƴ𝑤 𝑊𝑠 =𝐺𝑠 Ƴ𝑤 , Ƴ𝑑 = 𝑊𝑠 /V=𝐺𝑠 Ƴ𝑤 /(1+e) Ƴ𝑑 = 𝐺𝑠 Ƴ𝑤 /(1+e) • Using specific volume approach, Vs is put as unit volume. • Specific volume V=1+e = 𝑉 𝑉𝑠 (which is nothing but total volume per unit volume of solids) Dry soil: from the definition of void ratio 𝑒 = 𝑉𝑣 / 𝑉𝑠 =𝑒 = 𝑉𝑣 , 𝑉𝑠 =1, 11/17/2022 32 Soil Aggregate Relationship • For fully saturated soil: • From the definition of water content 𝑊𝑤 𝑒Ƴ𝑤 w= = 𝑊𝑠 • From the definition of degree of saturation 𝐺𝑠 Ƴ𝑤 • e=𝑊𝐺𝑠 • Ƴ𝑠𝑎𝑡 = For partially saturated soil: 𝑆𝑟 = 𝑊 =(𝐺𝑠 Ƴ𝑤 +𝑒Ƴ𝑤 )/(1+e) 𝑉 • Ƴ𝑠𝑎𝑡 = Ƴ𝑤 (𝐺𝑠 +e) /(1+e) • Ƴ𝑑 = 𝑉𝑤 =w𝐺𝑠 /e, 𝑉𝑣 𝑊𝑠 𝑉 e=w𝐺𝑠 /𝑆𝑟 , 𝑆𝑟 =1, e=w𝐺𝑠 = 𝐺𝑠 Ƴ𝑤 /(1+w𝐺𝑠 /𝑆𝑟 ) 33 11/17/2022 Soil Aggregate Relationship Relationship between Yd, Gs, w, and na Unit volume approach (V=1): • 𝑉 = 𝑉𝑠 + 𝑉𝑤 + 𝑉𝑎 • In this approach total volume V is set as 1. • 1 = 𝑉𝑠 /𝑉 + 𝑉𝑤 /𝑉 + 𝑉𝑎 • This approach is used when no weights or • 1 − 𝑉𝑎 = 𝑉𝑠 /𝑉 + 𝑉𝑤 /𝑉 • Using 𝑊 Vs = 𝑠 , 𝑉𝑤 𝐺𝑠 Ƴ𝑤 = 𝑊𝑤 Ƴ𝑤 volumes are given in the problem statement. • Porosity n is used, • =Ƴ𝑑 /Ƴ𝑤 (w+1/𝐺𝑠 ) • Ƴ𝑑 =(1 − 𝑉𝑎 ) 𝐺𝑠 Ƴ𝑤 /(1+𝑤𝐺𝑠 ) • When soil becomes completely saturated 𝑉𝑎 =0 11/17/2022 34 Soil Aggregate Relationship • Unit volume approach (V=1) 𝑉𝑣 , 𝑤𝑖𝑡ℎ 𝑉 • N= 𝑉𝑣 𝑉𝑠 = 𝑛 1 𝑉 = 1, 𝑛 = 𝑉𝑣 , 𝑒 = = 𝑛, Ƴ𝑑 = 𝑊𝑠 𝑉 = 𝐺𝑠 Ƴ𝑤 (1 − 𝑛) • Ƴ𝑏𝑢𝑙𝑘 = 𝑊 𝑉 = (1 − 𝑛) 𝐺𝑠 Ƴ𝑤 +w𝐺𝑠 (1 − 𝑛)Ƴ𝑤 11/17/2022 35 Soil Aggregate Relationship For saturated soil: Ƴ𝑠𝑎𝑡 = 𝐺𝑠 1 − 𝑛 Ƴ𝑤 + 𝑛Ƴ𝑤 𝑤 = 𝑛Ƴ𝑤 /𝐺𝑠 1 − 𝑛 Ƴ𝑤 𝑤 = 𝑒/𝐺𝑠 , e= 𝑤𝐺𝑠 (𝑓𝑜𝑟 𝑆𝑟 = 1) 11/17/2022 • For a dry soil: • Ƴ𝑑 = 𝑀𝑠 𝑉 = (1 − 𝑛)𝐺𝑠 Ƴ𝑤 36 Soil Aggregate Relationship (Relative density) • The term relative density is commonly used to indicate the in situ denseness or looseness of granular soil. It is defined as • 𝐷𝑟 = 𝑒𝑚𝑎𝑥 −𝑒 *100 𝑒𝑚𝑎𝑥 −𝑒𝑚𝑖𝑛 • Where Dr is relative density, e is in situ • The relationships for relative density can also be defined in terms of porosity, where nmax and nmin porosity of the soil in the loosest and densest conditions void ratio of the soil, emax is void ratio of the soil in the loosest state, emin is void ratio of the soil in the densest state 11/17/2022 37 Soil Aggregate Relationship (Relative density) • The maximum and minimum void ratios for granular soils described in depend on several factors, such as • Grain size • Grain shape • Nature of the grain-size distribution curve • Fine contents, Fc (that is, fraction smaller than 0.075 mm) 11/17/2022 38 Grain shape of soil • The shape of soil grains is a useful General classification of grain shape soil grain property in the case of • Bulky grins coarse grained soils and it is • Flaky grains important • Needle shaped grains in influencing the engineering behavior of soils. • The shape of coarse grain soil can be examined with naked eyes, whereas fine grained soils require • Bulky Grains: where all dimensions of a grain are more or less the same. • These are characteristics of sand and gravel soils. microscopic examination. 11/17/2022 39 Grain shape of soil • Mechanical break down of parent rocks are source of bulky grains. • During their transportation by wind or water, the sharp edges of the grains may get worn out and the grains may become rounded. • E.g. the shape of river gravels and wind blown sands is rounded • Alluvial sands-sub-angular to sub-rounded • Soils containing particles with high angularity tend to resist displacement and hence possess higher shearing strength compared to those with less angular particles. 11/17/2022 40 Grain shape of soil • Flaky grains: plate shaped grains • Needle shaped grains: one dimension of are the ones in which one dimension of grain, normally its the grain is fully developed and is much larger than the other two dimensions. thickness bears no relationship with • Needle shaped grains are characteristic of the other two lateral dimensions the clay mineral Atapulgite. which are much bigger. • Submicroscopic crystals of clay minerals usually exhibit flaky grain shape. 11/17/2022 41 Clay minerals • Clay minerals: are complex aluminum silicates • n composed of two basic units: (1) silica tetrahedron and (2) alumina octahedron. • Each tetrahedron unit consists of four oxygen atoms surrounding a silicon atom. • Tetrahedron units linkup in hexagonal pattern and form tetrahedral layer which represented by silica sheet. • The other fundamental unit is octahedron which represented by aluminum sheet or gibbsa sheet. 11/17/2022 42 Clay minerals • Octahedron units linkup to form • Clay minerals: is the chemical weathering product octahedral layer. • If the anions of octahedral sheet are hydroxyls and 67% of the resulted in groups of crystalline particles of colloidal size less than 2μ. • The combination of silica sheet and gibbsite sheet can provide fundamental sheet structures. cation positions are filled with Al, then it is called Gibbsite sheet • Based on the structure, clay minerals are grouped into Kaolinite, Illite, and Montmorillonite 11/17/2022 43 Clay minerals I. Kaolinite: is common in sedimentary and • n Al residual soils. Si • It is a repeating layer of one silicate sheet and Al ➢ (OH)8Al4Si4O10 0.72 nm Si one gibbsite sheet or alumina sheet. Al • Forms strong hydrogen bonds between the Si hydroxyl of the gibbsite sheet and oxygen of Al the silicate sheet. Si joined by oxygen sharing • It has little tendency in the interlayer to allow water and to swell. 11/17/2022 44 Clay minerals II. Illite •n • It is repeated layers of gibbsite sheet sandwiched by two silicate sheet • Its similar with montmorillonite except its adjacent silica layers are bounded by potassium ions instead water • It is common in stiff clays and shales, post glacial marine and lacustrine soft clay and silt deposit • Swelling potential of illite>kaolinite<montmorillonite 11/17/2022 45 Clay minerals III. Montmorillonite • Is also called smectite clay mineral • It has bounded by weak bonds of weak Vander Waals forces • The amount of available water in the space can control the spacing between S-G-S. •n Si Al Si Si Al Si 0.96 nm Si Al Si • It is easily separated by water and has high tendency to water absorption and swell • Is dominate clay minerals in shales, residual soils derived from volcanic ash 11/17/2022 46 Formation of Clay minerals • Clay minerals are not stable, static Clay minerals occurrence Kaolinite Common in tropical and subtropical area. Highly weathered soils with good drainage. In older soils. Montmorillonite Weathering products of volcanic rocks or ash. Common in sediments of arid areas and often mixed with clay mica. E.g. bentonite Illite Weathering of sedimentary rock in arid regions. Found in slate and shale. Chlorite common in marine sediments and metamorphic rocks. Not dominantly found. entities in soils. • Since clay minerals are the products of chemical weathering of rocks, both the climate and parent rock, influence the type of minerals found. 11/17/2022 47 Identification of Clay minerals • No one method is satisfactory Three methods for identification because of • interference of minerals in a mixture and • Range of I. X-ray diffraction (XRD) II. Differential thermal analysis (DTA) III. Casagrande’s plasticity chart composition and crystal structure of clays from different sources. 11/17/2022 48 Clay Shapes and Surface Areas • Water adsorption= f(SSA) and SSA is Specific Surface Area (SSA) f(particle size) • Clay has flaky shape • SSA is defined as the total surface of the Lambe and Whitm (1969) Mineral SSA (m2/g) Water absorbed (%) Quartzite 0.03 1.5x10-4 Kaolinite 10 0.5 which is simply the total surface of the Illite 100 5 individual grains per dry mass of the grains, Montmori 1000 llonite individual grains per dry mass of the grains. • 𝑆𝑆𝐴 = 𝑠𝑢𝑟𝑓𝑎𝑐𝑒 𝑎𝑟𝑒𝑎 𝑣𝑜𝑙𝑢𝑚𝑒∗ρ • SSA is inversely proportional to the particle size • As the grain sizes decrease, the SSA of the soil increases exponentially. 11/17/2022 50 49 Surface Charge of Clay Particles • The surface of clays is generally Isomorphous substitution negatively charged, even though • It is the replacement of a cation in the mineral the resultant charge in a particle is structure by another cation of lower valence, neutral but of the same physical size • Due to: • For example, replacements of silicon ion in a • Isomorphous substitution tetrahedral unit by aluminum ion ( which could • Breakage of particles happen when Al ions are more readily available • Dissociation of hydroxyl (OH-) in water) radicals 11/17/2022 50 Clay Water Systems • In dry clay, the negative charge is balanced by •c exchangeable cations like Ca+2, Mg+2, Na+1, and K+1 surrounding the particles being held by electrostatic attraction. • When water is added to clay, these cations and a few anions float around the clay particles. • This configuration is referred to as a diffuse double layer. • The cation concentration decreases with the distance from the surface of the particle 11/17/2022 51 Interaction of Clay Particles • When many clay particles are mixed together in water, particles interact and their unit micelles overlap each other. • Several interactive forces (attractive or repulsive) exist between particles when those particles are brought closer. 11/17/2022 52 Clay minerals and cation exchange capacity (CEC) CEC • The ability of the a clay particle to adsorb ions on its surface or edges is called CEC • CEC, measured in milliequivalents per 100g of dry soil particles, is a measure of net –ve charge on the soil particles, resulting from isomorphs substitution and broken bonds at the boundary. • CEC=f(mineral structure of clay and size of particle) • CEC of montmorillonite=10(CEC) kaolinite 11/17/2022 Mineral type CEC (meq/100g of dry soil) Quartzite Very small (due to fine particles and broken bonds) kaolinite 3-8 Illite 40 Montmorillo 80 nite • Exchangeable cations are the +vely charged ions from the soils in the pore water which are attracted to the surface of clay particles to balance the –ve charge. 53 Clay minerals and cation exchange capacity (CEC) • The cations can be arranged in a series in terms of their affinity for attraction as follows: • Here Ca2+ ions replace Na1+ ions and reduces swelling of Na- • Al3+>Ca2+>Mg2+>NH4+>K+>H+>Na+>Li+ montmorillonite, because the adsorbed • This indicates that, Al3+ ion can replace Ca2+ water layer would become thinner and ions and Ca2+ can replace Na+ ions. undergoes a structural distortion. • This process is called cation exchange. Practical example for cation exchange • Stabilization of sodium based clay soil using lime, Naclay (montmorillonite based)+CaCl2+Caclay+NaCl 11/17/2022 54 Particle Force and Soil Structure Particle forces and behavior • Particle surface forces are of an electrical nature • The behavior of individual soil particles and their • They are caused by unsatisfied electrical charges in interaction with other particles is influenced by the the particle crystalline structure (net-ve charges). following forces: • Weight of the particle Fg • Surface forces Fs are directly proportional to the surface area and hence for equidimensional particles, • Particle surface forces Fs Fs α D 2 • Weight force of the particle is the result of the gravitational forces and is a function of the volume • of the particle • Thus, for larger particle sizes, which include soil • For equi-dimensional particles such as spheres of diameter D, the weight Fg is directly proportional to D3 or Fgα D3 11/17/2022 Fg/Fs α D, As D increase, Fg/Fs increase particles in the coarser fraction (>0.075mm) Fg is predominant over Fs 55 Particle Force and Soil Structure Particle forces and behavior Soil Structure: the geometric arrangement of soil • As the particle diameter decreases the ratio particles with respect to one another Fg/Fs decreases, that means surface forces • Structures of Cohesive less Soils • Single grained predominate. • Properties of soil mass = f(arrangement of • Honeycomb Structures of Cohesive Soils grains) • The system of discrete particles (grains), that • Flocculent/dispersed makeup soil are not strongly bonded together • Size, shape of grains and minerals from which the and hence are relatively free to move with grains are formed determine the formation of a respect to each other particular soil structure 11/17/2022 56 Structures of Cohesive less Soils Single grained structure •n • Each grain touches several of its neighbors in such a way that the aggregate is stable even if there are no forces of adhesion at the points of contact between the grains. • The arrangement may be dense or loose and the properties of aggregate are greatly influenced by the denseness or looseness ❖Loose state= high void ratio and low unit weight ❖Dense state= low void ratio and high unit weight 11/17/2022 57 Structures of Cohesive less Soils • For granular soils (sand and gravel) •n the range of void ratios generally encountered can be visualized by considering an ideal situation in which particles are spheres of equal size • The loosest and densest possible arrangements that we can obtain from these equal spheres are simple cubic and the pyramidal type of packing respectively. 11/17/2022 58 Structures of Cohesive less Soils • In the case of natural granular soils, • n particles are neither of equal size nor perfect spheres a) The small size particles may occupy void spaces between the larger ones, which will tend to reduce the void ratio of natural soils as compared to that for equal spheres b) On the other hand , the irregularity in the shape of the particles generally tends to increase void ratio of soil as compared to ideal spheres 11/17/2022 59 Structures of Cohesive less Soils Honeycomb structure-Single grained Soil • It is found in soil contains particle of size 0.02mm ❖The attraction of particles is due to cohesion between them, but this cohesion is just because of their size but however, these soils are not plastic to 0.002mm which are generally fine sands or silts. in nature. • When this type of soils is allowed to settle on the ground, the particles will attract each other and joins one with another and forms a bridge of ❖In fine sands, when water is added to dry fine sand bulking of sand occurs which is nothing but a structure of honeycomb. particles. • A large void is also formed between those bridges which makes the soil very loose in nature. 11/17/2022 60 Structure of clay soils (fine grained soils) • The final established structures from the of clay are balance of interactive forces and external forces applied to the clay assemblage Final clay structure with particles’ interactive and external forces • If two particles (platelet shape) approach each other in a suspension, the forces acting on them are: a) The Van der Waals force of attraction, and b) The repulsion between two +vely charged ionized adsorbed water layers. 11/17/2022 61 Particle Force and Soil Structure Dispersed clay structure • If the final interparticle forces are repulsive, the particles want to separate from each other when the boundary confinements are removed. • The net forces of repulsion are greatest in the case of particles approaching face to face • Lacustrine clays (deposited in fresh water lakes) generally have a dispersed structure. 11/17/2022 62 Particle Force and Soil Structure • In freshwater environments, more face-to-face Flocculated clay Structure • If the interparticle forces are attractive, then particles want to come together, making flocculated structures are formed due to negative charges at the edges flocculated clay. • In flocculated clays, surface and edge charges play an important role. • If the edge charges are positive, most likely the edges are attracted to the flat surfaces of other clay particles. • This makes a card-house structure of flocculated clay, most commonly in saltwater environments. 11/17/2022 63 Methods to identify soil structure Ordinary microscope SEM • It is valid for coarse grained soils only Scanning electron microscopy (SEM) • uses electrons rather than light to form an image. • This is ideally suited for clayey soils, as the resolution is sufficiently high and hence it is possible to go for higher magnifications (=1x105 times) 11/17/2022 64 End of chapter 2 36 •This is all what I have to say. •Thank you too much for your eyeful attention! 11/17/2022 65