College of Technology & Allied Sciences AS 1 GENERAL CHEMISTRY Bohol Island State University- Main Chapter 1: INTRODUCTION TO THE STUDY OF CHEMISTRY Chemistry is the study of matter and its properties, the changes that matter undergoes, and the energy associated with those changes (Silberberg, 3 rd ed., p. 3). Activity 1: Chemistry in the House Explore the objects in your house. Which among them do you think are related to chemistry? On a long bondpaper, list as many of these objects as you can. Beside the name of each object, write a phrase or sentence that explains why you say the object is related to chemistry. Present your answers using the table below. Object Relation to Chemistry Chemistry has a central role among the sciences. Paleontology Neurology Geology Medicine Physics Electronics Archaeology Ecology Meteorology CHEMISTRY Agriculture Metallurgy Botany Engineering Biology Toxicology Biochemistry Pharmacology Figure 1.1. Role of Chemistry Among Sciences Science is a unified whole. Common scientific laws apply everywhere and on all levels of organization. The various areas of science interact and support one another. Accordingly, chemistry not only is useful to itself but is also fundamental to other scientific disciplines. The application of chemical principles has revolutionized biology and medicine, has provided materials for powerful computers used in mathematics, and has profoundly influenced other fields such as psychology. The social goals of better health and more and better food, housing, and clothing are depended to the large extent on the knowledge and techniques in chemistry. Chemistry is indeed a central science. There is scarcely a single area of our daily lives that is not affected by chemistry. Activity 2: Contributions of Chemistry through Time Concentrate on your field/specialization. Make a timeline showing the contributions of chemistry in your major/ specialization (e.g. Food technology, electronics, etc.). You can either use cut-outs or computer graphics to present your timeline in chemistry. Show your creativity. Put in a long bondpaper. 1 College of Technology & Allied Sciences AS 1 GENERAL CHEMISTRY Bohol Island State University- Main Scientific Method – a process involving creative propositions & tests aimed at objective, verifiable discoveries. Hypothesis is revised if experimental results do not support it. Observations Natural phenomena and measured events Experiment Procedure to test hypothesis Hypothesis Tentative proposal that explains observations Further Experiment Tests predictions based on model Model (Theory) Set of conceptual assumptions that explains data from accumulated experiments Model is altered if predicted events do not support it. Figure 1.2. The Scientific Method Observations. These are facts our ideas must explain. Hypothesis. Whether derived from observation or from a “spark of intuition”, a hypothesis is a proposal made to explain an observation. A sound hypothesis need not to be correct, but it must be testable by experiment. Indeed, a hypothesis is often the reason for performing an experiment: if the results do not support it, the hypothesis must be revised or discarded. Hypotheses can be altered, but experimental results cannot. Experiment. A set of procedural steps that tests a hypothesis, an experiment often leads to revised hypothesis and new experiments to test it. Experimental results must be reproducible by others. Both skill and creativity play a part in experimental design. Model. Formulating conceptual models, or theories, based on experiments that test hypotheses about observations distinguishes scientific thinking from speculation. As hypotheses are revised according to experimental results, a model emerges to explain how the phenomenon occurs. A model is a simplified, not an exact, representation of some aspect of nature that we use to predict related phenomena. Ongoing experimentation refines the model to account for new facts. Classification of Matter Figure 1.3. Classification of Matter 2 College of Technology & Allied Sciences AS 1 GENERAL CHEMISTRY Bohol Island State University- Main Matter is anything that occupies space and has mass. Matter includes things we can see and touch (such as water, earth, and trees), as well as things we cannot (such as air). Thus, everything in the universe has a “chemical” connection. Mixture is a combination of two or more substances in which the substances retain their distinct identities. Some familiar examples are air, soft drinks, milk, and cement. Mixtures do not have constant composition. Therefore, samples of air collected in different cities would probably differ in composition because of differences in altitude, pollution, and so on. Mixtures are either homogeneous or heterogeneous. Homogeneous mixture (solutions) - no visible parts; composition of mixture is same throughout (e.g. coffee dissolved in water, air) Heterogeneous mixtures- with visible parts; composition of mixture not uniform (e.g. sand mixed with iron filings, halo-halo) ** Mixtures can be separated into pure substances by physical methods. Examples of these methods are: 1. Evaporation – used to separate components of a mixture with a dissolved solid in a liquid 2. Distillation – used to separate components of a liquid mixture by a process of heating and cooling, which exploits the differences in the volatility of each of the component (volatility is synonymous to how fast your substance evaporates) 3. Filtration - used to separate components of a mixture containing an undissolved solid in a liquid 4. Chromatography – used to separate mixtures of dissolved substances that have different colors Pure substance is a form of matter that has a definite (constant) composition and distinct properties. Examples are water, ammonia, table sugar (sucrose), gold, and oxygen. Substances differ from one another in composition and can be identified by their appearance, smell, taste, and other properties. Pure substances can be either elements or compounds. Compound- a substance composed of atoms of two or more elements chemically united in fixed proportions (e.g. water- H2O, table salt- NaCl) Element- is a substance that cannot be separated into simpler substances by chemical means (e.g. Hydrogen- H; gold-Au) ** Compounds can be separated into elements by chemical methods/ chemical reaction. Activity 3: Classification of Matter Chart Complete the Classification of Matter chart below. Matter Can it be separated by physical means? Yes No __________________ __________________ _ _ Is the composition uniform? Yes _____________ mixtures (salt solution) Can it be decomposed by ordinary chemical means? No _____________ mixtures (sand & gravel) Yes No _____________ _____________ (carbon dioxide) (carbon) 3 College of Technology & Allied Sciences AS 1 GENERAL CHEMISTRY Bohol Island State University- Main States of Matter Figure 1.4. States of Matter Solid- molecules are held close together in an orderly fashion with little freedom of motion; fixed shape Liquid- molecules are held close together but not rigidly in position & can move past one another Gas- molecules are separated by distances that are large; freely moving Table 1.1. Properties of Solid, Liquid and Gas Property Compressibility Density Volume Liquid Gas almost incompressible slightly compressible highly compressible high high very low definite volume; does not fill container assumes shape of container retains own volume Shape retains own shape Diffusion Expansion Solid fills the container assumes shape of container extremely slow; occurs only at surface slow rapid low expansion on heating low expansion on heating high expansion on heating The three states of matter can be interconverted without changing the composition of the substance as shown below: SOLID Vaporization LIQUID GAS Condensation Figure 1.5. Changes in the States of Matter Upon heating, a solid (for example, ice) will melt to form a liquid (water). (The temperature at which this transition occurs is called the melting point.) Further heating will convert the liquid into a gas. (This conversion takes place at the boiling point of the liquid.) On the other hand, cooling a gas will cause it to condense into a liquid. When the liquid is cooled further, it will freeze into the solid form. Figure 1.6. The three states of matter in water. A hot poker changes ice into water and steam. 4 College of Technology & Allied Sciences AS 1 GENERAL CHEMISTRY Bohol Island State University- Main Activity 4: What happens? What happens at the particle level in each of the following events? For each event, draw two particle pictures of the object to represent how it looks at the start and end of the vent described. Write a short explanation. 1. A crayon left on the sidewalk on a very hot sunny day. START END Explanation: 2. A woman places several mothballs in a resealable bag and seals the bag. One week later, she notices that the bag has become inflated and the mothballs are much smaller. END START Explanation: Properties of Matter Substances are identified by their properties as well as by their composition. Properties are characteristics that give each substance its unique identity. These can either be physical or chemical. Substance’s Properties Physical Properties - Characteristics a substance shows by itself, without changing into or interacting with another substance (e.g. color, melting point, boiling point) *For example, we can measure the melting point of ice by heating a block of ice and recording the temperature at which the ice is converted to water. Chemical Properties - Characteristics a substance shows as it changes into or interacts with another substance (e.g. flammability, toxicity, reactivity) *For example, the statement “Hydrogen gas burns in oxygen gas to form water” describes a chemical property of hydrogen, because to observe this property, we must carry out a chemical change, in this case burning. 5 College of Technology & Allied Sciences AS 1 GENERAL CHEMISTRY Physical Change - Occurs when a substance alters its physical properties, not its composition Ex. melting of wax, grinding solids to powders, sugar dissolves in coffee Bohol Island State University- Main Chemical Change/ Chemical Reaction - Substance is converted into different substance Ex. rusting of iron, burning, food being digested or cooked, rotting of banana All measurable properties Extensive Property - Depends on how much matter is being considered - Values of the same extensive property can be added together Intensive Property - Does not depend on how much matter is being considered - Values are not additive Ex. temperature, density Ex. mass, volume, heat Activity 5: Properties of an element Classify the following properties of an element X as physical or chemical property: a. Blue-gray color f. Denser than water b. Brittle g. Combines with oxygen c. Does not dissolve in water h. Does not oxidize d. Melts at 1410° C i. Pressure at 14 psi e. Reacts vigorously with fluorine j. Forms acid with hydrogen Classify the following changes as physical or chemical change: a. Shredding paper f. Breaking glass b. Mixing baking soda and vinegar g. Sublimation of dry ice c. Boiling water h. Milk going sour d. Baking a cake i. Leaves of trees becoming yellow e. Cooking an egg j. Vaporizing liquid nitrogen References: Chang, R. Chemistry. 10th Edition. New York: McGraw Hill 2010 Hill, J.W., McCreary, T.W., Kolb, D.K. Chemistry for Changing Times. 12 th Edition. Pearson Education, Inc. 2010 Ilao, L.V., Lontoc, B.M., Gayon, E.E. General Chemistry 1. Rex Bookstore 2016 Silberberg, M.S. Principles of General Chemistry. 3 rd Edition. New York: International Edition, McGraw Hill 2007 6