TABLE OF CONJUGATE ACID-BASE PAIRS Acid Base Ka (25 oC) HClO4 H2SO4 HCl HNO3 H3O+ H2CrO4 H2C2O4 (oxalic acid) [H2SO3] = SO2(aq) + H2O HSO4– H3PO4 Fe(H2O)63+ H2C8H4O4 (o–phthalic acid) H2C4H4O6 (tartaric acid) Hg(H2O)62+ Sn(H2O)32+ HCO2H (formic acid) Cr(H2O)63+ Hg2(H2O)22+ C6H5CO2H (benzoic acid) HC2O4– (hydrogen oxalate) HC4H4O6– (hydrogen tartrate) CH3CO2H (acetic acid) Al(H2O)63+ Be(H2O)42+ HC8H4O4– (hydrogen phthalate) Cd(H2O)62+ Cu(H2O)62+ H2CO3 HCrO4– H2S H2PO4– HSO3– HOCl Pb(H2O)32+ HOBr H3BO3 or B(OH)3 NH4+ Zn(H2O)42+ Ni(H2O)62+ HCO3– Co(H2O)62+ HOI Fe(H2O)62+ Mn(H2O)62+ Mg(H2O)62+ Ag(H2O)2+ HPO42– Al(H2O)3(OH)3(s) Ca(H2O)62+ Zn(H2O)4(OH)2(s) H2O HS– ClO4– HSO4– Cl– NO3– H2O HCrO4– HC2O4– HSO3– SO42– H2PO4– Fe(H2O)5OH2+ HC8H4O4– HC4H4O6– Hg(H2O)5OH+ Sn(H2O)2OH+ HCO2– Cr(H2O)5OH2+ Hg2(H2O)OH+ C6H5CO2– C2O42– C4H4O62– CH3CO2– Al(H2O)5OH2+ Be(H2O)3OH+ C8H4O42– Cd(H2O)5OH+ Cu(H2O)5OH+ HCO3– CrO42– HS– HPO42– SO32– OCl– Pb(H2O)2OH+ OBr– B(OH)4– NH3 Zn(H2O)3OH+ Ni(H2O)5OH+ CO32– Co(H2O)5OH+ OI– Fe(H2O)5OH+ Mn(H2O)5OH+ Mg(H2O)5OH+ Ag(H2O)OH(s) PO43– Al(H2O)2(OH)4– Ca(H2O)5OH+ Zn(H2O)3(OH)3– OH– S2– 1.8 x 10–1 5.90 x 10–2 1.71 x 10–2 1.20 x 10–2 7.52 x 10–3 1.84 x 10–3 1.30 x 10–3 1.04 x 10–3 2.6 x 10–4 ~2 x 10–4 1.9 x 10–4 1.6 x 10–4 ~1 x 10–4 6.46 x 10–5 6.40 x 10–5 4.55 x 10–5 1.76 x 10–5 1.4 x 10–5 ~1 x 10–5 3.1 x 10–6 8.32 x 10–7 ~5 x 10–7 4.3 x 10–7 3.20 x 10–7 1.2 x 10–7 6.23 x 10–8 6.0 x 10–8 2.8 x 10–8 1.3 x 10–8 2.06 x 10–9 5.8 x 10–10 5.65 x 10–10 2.5 x 10–10 ~6 x 10–11 5.61 x 10–11 ~4 x 10–11 2.3 x 10–11 ~1 x 10–11 ~6 x 10–12 ~4 x 10–12 ~7 x 10–13 4.5 x 10–13 ~4 x 10–13 3.2 x 10–13 (?) (1.0 x 10–14) ~1 x 10–19