Republic of the Philippines Central Mindanao University University Town, Musuan, 8710 Bukidnon Department of Mechanical Engineering Mechanical Engineering Laboratory 1 Plate No. 6 Determination of Density, Specific Gravity and Viscosity of Liquid Fuels Submitted by: Date Performed: DE LOS SANTOS, ANDREW JR. A. NOVEMBER 20, 2021 Schedule: Date Submitted: TTh 1:00 – 4:00 PM NOVEMBER 21, 2021 I. Objectives To learn what Liquid fuel is and its classifications. To learn what Density, Specific Gravity and Viscosity of Liquid Fuels are. To identify the instruments used to measure the Density, Specific Gravity and Viscosity of Liquid Fuels. II. Discussion LIQUID FUEL Liquid fuels are those combustible or energy-generating molecules that can be harnessed to create mechanical energy. Most liquid fuels, in widespread use, are or derived from fossil fuels such as gasoline, diesel, kerosene, alcohols, and hydrogen. Liquid fuels have lower ash contents and are easier to upgrade, because it removes unwanted impurities such as nitrogen and sulfur. Liquid fuel can be burned in pools or sprays and vaporizes in two modes. TYPES OF LIQUID FUELS PETROLEUM Petroleum is a naturally occurring liquid found beneath the earth’s surface that can be refined into fuel. Petroleum is used as fuel to power vehicles, heating units, and machines, as well as it can be converted into plastics and other materials. It’s been created by the decomposition of organic matter over millions of years. Petroleum is formed when large quantities of dead organisms, primarily underneath zooplankton sedimentary and rock algae, are subjected to intense heat and pressure. COAL TAR Coal tar is a complex mixture of hydrocarbons produced by the pyrolysis of coal. It is a dark viscous liquid primarily used in the manufacture of other chemicals. Coal tar constituents may be absorbed via inhalation, ingestion, or dermal contact. Coal tar is derived from coal. It is a byproduct of the production of coke, a solid fuel that contains mostly carbon, and coal gas. SHALE OIL Shale oil is the product of the thermal reaction and decomposition of kerogen present in oil shales. Shale oil is a highquality crude oil that lies between layers of shale rock, impermeable mudstone, or siltstone. ALCOHOL Alcohol, any of a class of organic compounds characterized by one or more hydroxyl groups attached to a carbon atom of an alkyl group (hydrocarbon chain). Alcohols may be considered as organic derivatives of water in which one of the hydrogen atoms has been replaced by an alkyl group, typically represented by R in organic structures. PROPERTIES OF LIQUID FUELS DENSITY Density is defined as the ratio of the mass of the fuel to the volume of the fuel at a reference temperature of 15°C. Density is measured by an instrument called a hydrometer. The knowledge of density is useful for quantitative calculations and assessing ignition qualities. The unit of density is kg/m3. SPECIFIC GRAVITY This is defined as the ratio of the weight of a given volume of oil to the weight of the same volume of water at a given temperature. The density of fuel, relative to water, is called specific gravity. The specific gravity of water is defined as one. Since specific gravity is a ratio, it has no units. The measurement of specific gravity is generally made by a hydrometer. Specific gravity is used in calculations involving weights and volumes. VISCOSITY The viscosity of a fluid is a measure of its internal resistance to flow. Viscosity depends on the temperature and decreases as the temperature increases. Any numerical value for viscosity has no meaning unless the temperature is also specified. Viscosity is measured in Stokes / Centistokes. . The measurement of viscosity is made with an instrument called a Viscometer. Viscosity is the most important characteristic in the storage and use of fuel oil. It influences the degree of pre-heating required for handling, storage and satisfactory atomization. INSTRUMENTS USE TO MEASURE THE PROPERTIES OF LIQUID FUELS HYDROMETER Hydrometer is a device for measuring some characteristics of a liquid, such as its density (weight per unit volume) or specific gravity (weight per unit volume compared with water). The device consists essentially of a weighted, sealed, long-necked glass bulb that is immersed in the liquid being measured; the depth of flotation gives an indication of liquid density, and the neck can be calibrated to read density, specific gravity, or some other related characteristic. VISCOMETER Viscometer, instrument for measuring the viscosity (resistance to internal flow) of a fluid. In one version, the time taken for a given volume of fluid to flow through an opening is recorded. In the capillary tube viscometer, the pressure needed to force the fluid to flow at a specified rate through a narrow tube is measured. III. Materials IV. PC/Laptop Formulas Density 𝑘𝑔 𝑔 𝑔 Unit: 𝑚3 , 𝑐𝑚3 , 𝑚𝐿 𝜌= 𝑚 𝑉 Specific Gravity 𝑆𝑝𝑒𝑐𝑖𝑓𝑖 𝐺𝑟𝑎𝑣𝑖𝑡𝑦 = 𝑑𝑒𝑛𝑠𝑖𝑡𝑦 𝑜𝑓 𝑜𝑏𝑗𝑒𝑐𝑡 𝜌𝑜𝑏𝑗𝑒𝑐𝑡 = 𝑑𝑒𝑛𝑠𝑖𝑡𝑦 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 𝜌𝐻2 𝑂 Viscosity Dynamic Viscosity – measures the ratio of the shear stress to the shear rate for a fluid. 𝜇= Units: 𝜏 𝛾 𝑑𝑦𝑛.𝑠 𝑘𝑔 𝑐𝑚 , 𝑚∙𝑠 , 𝑐𝑃, 𝑃(𝑝𝑜𝑖𝑠𝑒), 𝑃𝑎 ∙ 𝑠 Kinematic Viscosity – measures the ratio of the viscous force to the inertial force on the fluid. 𝜈= Units: V. 𝑐𝑚2 𝑠 , 𝑐𝑆𝑡(𝑐𝑒𝑛𝑡𝑖𝑠𝑡𝑜𝑘𝑒𝑠), 𝑓𝑡 2 𝑚2 𝑠 , 𝑠 𝜇 𝜌 , 𝑆𝑡(𝑠𝑡𝑜𝑘𝑒𝑠) Questions 1. The tool used to measure the mass of a substance or object is? BALANCE 2. What laboratory apparatus is used to measure the volume of a liquid? BURETTE 3. What is the unit for specific gravity? DIMENSIONLESS 4. It is necessary to mention the temperature at which specific gravity is calculated, because a. Rigidity of the substance changes with temperature b. Density of the substance changes with temperature c. Mass of the substance changes with temperature d. None of the mentioned 5. What is API gravity? It is to measure how heavy or light a petroleum liquid is compared to water. 6. API gravity is necessary for the calculation of specific gravity of petroleum products, because a. Potential energy of petroleum products changes with temperature b. Mass of petroleum products changes with temperature c. Volume of the petroleum products changes with temperature d. None of the above 7. What is viscosity and flow rate? Viscosity is the resistance of a fluid to a change in shape or movement. Flow rate is defined as the volume of fluid flowing through an area each second. 8. How is viscosity and density affected when a fluid is heated? a. Viscosity increases and density increases b. Viscosity decreases and density increases c. Viscosity decreases and density decreases d. Temperature has no effect on viscosity and density 9. Find the density of an unknown liquid in a beaker. The beaker's mass is 165 g when there is no liquid present. With the unknown liquid, the total mass is 309 g. The volume of the unknown liquid is 125 mL. Given: 𝑚𝑏 = 165 𝑔 𝑚𝑡𝑜𝑡 = 309 𝑔 𝑚𝑢𝑙 = ? 𝑝𝑢𝑙 = ? 𝑣𝑢𝑙 = 125 𝑚𝐿 Solution: 𝐹𝑜𝑟 𝑚𝑢𝑙 : 𝐹𝑜𝑟 𝑝𝑢𝑙 : 𝑚𝑢𝑙 𝑚𝑡𝑜𝑡 = 𝑚𝑏 + 𝑚𝑢𝑙 𝑝𝑢𝑙 = 𝑚𝑢𝑙 = 𝑚𝑡𝑜𝑡 − 𝑚𝑏 𝑝𝑢𝑙 = 125 𝑚𝐿 𝑚𝑢𝑙 = 309 𝑔 – 165 𝑔 𝑚𝑢𝑙 = 144 𝑔 𝑣𝑢𝑙 144 𝑔 𝑔 𝑝𝑢𝑙 = 1.152 𝑚𝐿 10. The density of gasoline is 736 kilograms per cubic meter. What is its specific gravity? Given: 𝑘𝑔 𝑝𝑔 = 736 𝑚3 𝑘𝑔 𝑝𝑤 = 1000 𝑚3 Solution: 𝑆. 𝐺 = 𝑆. 𝐺 = 𝑝𝑔 𝑝𝑤 736 𝑘𝑔/𝑚3 1000 𝑘𝑔/𝑚3 𝑆. 𝐺 = 0.736 VI. Conclusion Liquid fuels like furnace oil and LSHS (low sulphur heavy stock) are predominantly used in industrial applications. The various properties of liquid fuels like density, specific gravity, and viscosity can be measured by different measuring instruments like hydrometer and viscometer. Liquid fuels can also be classified as fossil fuel, therefore, some types of liquid fuels can be found naturally on ground or underneath the earth’s surface. VII. References https://www.researchgate.net/publication/293212846_Liquid_fuels_Types_proper ties_and_production https://www.sciencedirect.com/topics/earth-and-planetary-sciences/liquid-fuels https://www.investopedia.com/terms/p/petroleum https://www.sciencedirect.com/topics/neuroscience/coal-tar https://www.sciencedirect.com/topics/engineering/shale-oil https://www.britannica.com/science/alcohol http://ecoursesonline.iasri.res.in/mod/page/view.php?id=945 https://www.britannica.com/technology/hydrometer https://www.britannica.com/technology/viscometer