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00 Course Handout CRE-1 July Dec 2022

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Pandit Deendayal Petroleum University
Raisan, Gandhinagar – 382007, Gujarat, INDIA
School of Technology
Course Student Handout Evaluation from
Name of the Course with Course Code: CHEMICAL REACTION ENGINEERING – 1 (20CH302T)
Programme (B. Tech/M. Tech/M.Sc. /Ph.D. etc): B. TECH
Semester: 5
Branch: CHEMICAL ENGINEERING
Academic Year: 2021-22
Name of Course Coordinator: DR ASHISH UNNARKAT
Name of Subject Teachers: DR ASHISH UNNARKAT
Sr.
Item
No
1 Departmental Vision & Mission
Program educational objectives (PEOs) of
2
Department
3 Program Outcomes (POs)
4 Program Specific Outcomes (PSOs)
5 Academic Calendar
6 Class Time Table with office hours
Course Outcomes (COs), Course Syllabus, Pre
7
requisites for the course
8 Lesson Plan
Program Articulation Matrix and Course
9
Articulation Matrix
10 Evaluation Scheme and Rubrics
Tutorials, Assignments, Case Studies, Quiz,
11
Presentations etc.
Copy of Sessional Mid and End semester
12
Examination Question Papers
Course covered beyond syllabus and self-study
13
topics
Sign of subject teacher:
Dr. Ashish P. Unnarkat
Availability
(Yes / No)
YES
YES
Remarks
YES
YES
YES
YES
YES
YES
YES
YES
NA
YES
NA
Name and Sign of Reviewing officer
PANDIT DEENDAYAL ENERGY UNIVERSITY
PANDIT DEENDAYAL ENERGY UNIVERSITY
SCHOOL OF TECHNOLOGY
SCHOOL OF TECHNOLOGY
Department of Chemical Engineering
Department of Chemical Engineering
Program Education Objectives (PEOs)
VISION
 Acquire the fundamental principles of science and chemical engineering with modern
To impart quality education in an industry research driven modules to motivate the young
chemical engineers for creating knowledge wealth to help generate employability following
experimental and computational skills.
 Ability to handle problems of practical relevance of society while complying with
professional ethics and focus towards a sustainable environment and benefits to the
society.
economical, environmental, ethical, and safety factors.
 Demonstrate professional excellence, ethics, soft skills and leadership qualities with lifelong learning’s.
MISSION
 Graduates will be active members ready to serve the society locally and internationally.
 To facilitate the chemical engineering students with the state-of-the-art facilities with
focus on skill development, creativity, innovation and enhancing leadership qualities.
 To nurture creative minds thru’ mentoring, quality teaching & research for building a
value based sustainable society.
Program Specific Outcomes (PSOs)
1.
To analyse and tackle the complex and diverse engineering problems by appropriate
experimentation, simulation, data analysis and interpretation, and, provide probable
solutions by applying principles of chemical engineering in combination to the
 To work in unison with the national and international level academic and industrial
partners by venturing into collaborations to tackle problems of bigger interest to
society.
fundamental knowledge of basic sciences and mathematics.
2.
Competence to incorporate socio-economic considerations in engineering practices,
including the concept of sustainable development, into chemical engineering practice.
 To build an encouraging environment for the young faculties and staff by providing safe
work culture, transparency, professional ethics and accountability that will empower
them to lead the department in right spirit.
 To inculcate the culture of continuous learning among the faculties by encouraging
them to participate in a professional development programs and envisage to address
the social, economic and environmental problems.
3.
An ability to work together collaboratively in multidisciplinary teams to tackle
multifaceted problems and pursue a bright career in chemical engineering and allied
areas by demonstrating professional success at different platforms within industry,
governmental bodies or academia.
PANDIT DEENDAYAL ENERGY UNIVERSITY
SCHOOL OF TECHNOLOGY
6. The engineer and society: Apply reasoning informed by the contextual knowledge to
assess societal, health, safety, legal and cultural issues and the consequent
responsibilities relevant to professional engineering practices.
Department of Chemical Engineering
7. Environment and sustainability: Understand the impact of the professional
Program Outcomes
Engineering Graduates will be able to:
1. Engineering knowledge: Apply the knowledge of mathematics, science, engineering
fundamentals, and an engineering specialization to the solution of complex engineering
problems.
2. Problem analysis: Identify, formulate, review research literature, and analyze complex
engineering problems reaching substantiated conclusions using first principles of
mathematics, natural sciences, and engineering sciences.
3. Design/development of solutions: Design solutions for complex engineering
problems and design system components or processes that meet the specified need
with appropriate considerations for public health and safety, and the cultural, societal
and environmental considerations.
4. Conduct investigations of complex problems: Use research based knowledge and
research methods including design of experiments, analysis and interpretation of data,
and synthesis of the information to provide valid conclusions.
5. Modern tool usage: Create, select and apply appropriate techniques, resources, and
modern engineering and IT tools including prediction and modeling to complex
engineering activities with an understanding of the limitations.
engineering solutions in societal and environmental context, and demonstrate the
knowledge of, and need for sustainable development.
8. Ethics: Apply ethical practices and commit to professional ethics and responsibilities
and norms of the engineering practice.
9. Individual and team work: Function effectively as an individual, and as a member or
leader in diverse teams and in multidisciplinary settings.
10. Communication: Communicate effectively on complex engineering activities with the
engineering community and with society at large, such as, being able to comprehend
and write effective reports and design documentation, make effective presentations,
and give and receive clear instructions.
11. Project management and finance: Demonstrate knowledge and understanding of the
engineering and management principles and apply these to one′s own work, as a
member and leader in the team, to manage projects and in multidisciplinary
environments.
12. Life-long learning: Recognize the need for, and have the preparation and ability to
engage in independent and life-long learning of broadest context of technological
change.
ACADEMIC CALENDAR 2022-23 (ODD SEMESTER)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
JULY
2022
AUGUST
SEP
OCT
NOV
DEC
11
18
25
12
19
26
13
20
27
14
21
28
15
22
29
16
23
30
17
24
31
1
2
3
4
5
6
7
8
15
22
29
5
12
19
26
3
10
17
24
31
7
14
21
9
16
23
30
6
13
20
27
4
11
18
25
1
8
15
22
10
17
24
31
7
14
21
28
5
12
19
26
2
9
16
23
11
18
25
1
8
15
22
29
6
13
20
27
3
10
17
24
12
19
26
2
9
16
23
30
7
14
21
28
4
11
18
25
13
20
27
3
10
17
24
1
8
15
22
29
5
12
19
26
14
21
28
4
11
18
25
2
9
16
23
30
6
13
20
27
28
5
12
29
6
13
30
7
14
1
8
15
2
9
16
3
10
17
4
11
18
19
26
20
27
21
28
22
29
23
30
24
31
25
1
FACULTY DEVELOPMENT PROGRAMME WEEK
FACULTY DEVELOPMENT PROGRAMME WEEK
COMMENCEMENT OF ODD SEMESTER: July 25
RAKSHA BANDHAN
INDEPENDENCE DAY, JANMASHTAMI
SAMVATSSARI
MID-SEM EXAMINATIONS
COURSE FEEDBACK WEEK
DUSSHERA
DIWALI WEEK
GURU NANAK JAYANTI
COMPLETION OF ODD SEMESTER: Nov. 18
FOET Practical Exams : Nov.21 Onwards
FOLS Sem. End Examination : Nov. 21 Onwards
FOET Sem. End Examination : Nov.28 Onwards
Rural Internship for FOLS Students:
Dec. 17, 2022 to Jan. 10, 2023
 TOTAL WEEKS: 17
 Applicable to FOLS & FOET (Except B.Tech Sem.2 )
WINTER BREAK
ACADEMIC CALENDAR 2022-23 (EVEN SEMESTER)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
JAN
2023
3
4
5
6
7
8
9
16
23
30
6
13
20
27
6
13
20
27
3
10
17
24
10
17
24
31
7
14
21
28
7
14
21
28
4
11
18
25
11
18
25
1
8
15
22
1
8
15
22
29
5
12
19
26
12
19
26
2
9
16
23
2
9
16
23
30
6
13
20
27
13
20
27
3
10
17
24
3
10
17
24
31
7
14
21
28
14
21
28
4
11
18
25
4
11
18
25
1
8
15
22
29
15
22
29
5
12
19
26
5
12
19
26
2
9
16
23
30
1
2
3
4
5
6
7
FOET Practical Exams : May 1 Onwards
FOLS Sem. End Examination : May 1 Onwards
8
15
22
9
16
23
10
17
24
11
18
25
12
19
26
13
20
27
14
21
28
FOET Sem. End Examination : May 8 Onwards
JULY
29
5
12
19
26
30
6
13
20
27
31
7
14
21
28
1
8
15
22
29
2
9
16
23
30
3
10
17
24
1
4
11
18
25
2
AUGUST
3
10
17
24
31
4
11
18
25
1
5
12
19
26
2
6
13
20
27
3
7
14
21
28
4
8
15
22
29
5
9
16
23
30
6
FEB
MARCH
APRIL
MAY
1
2
3
4
5
COMMENCEMENT OF EVEN SEMESTER: Jan.2
2
JUNE
6
REPUBLIC DAY
MID-SEM EXAMINATIONS
HOLI
COURSE FEEDBACK WEEK
RAM NAVAMI
Dr.BABASAHEB AMBEDKAR JAYANTI
COMPLETION OF EVEN SEMESTER: April 28
Industrial Internship for FOET Students: May 22,2023 Onwards
(For B.Tech. Sem-VI and M.Tech. Sem-II)
Civic and Social Services Internship (CSSI) for FOET Students:
June 26, 2023 Onwards (For B. Tech. Sem-II)
FACULTY DEVELOPMENT PROGRAMME
FACULTY DEVELOPMENT PROGRAMME
COMMENCEMENT OF ODD SEMESTER: July 24, 2023
 TOTAL WEEKS: 17
SUMMER VACATION FOR FACULTY:
May 29, 2023 to July 7, 2023
(Faculty will resume office from July 10, 2023)
DR. ASHISH UNNARKAT - DEPARTMENT OF CHEMICAL ENGINEERING
Day
09:00-10:00
E1E2E3 (20CH302T)
E101, ASU-L
Friday
Saturday
12:00-13:00
E (20EEM501T)
E002, ASU-L
13:0014:00
14:00-15:00
15:00-16:00
E1E2E3 (20CH302T)
E101, ASU-L
16:00-17:00
E2 (20CH302P) E108, ASU-P
E (20EEM501T) E108,
ASU-L
E1E2E3 (20CH302T)
E005, ASU-L
Wednesday
Thursday
11:00-12:00
E4E5E6 (20CH302T)
E005, ASU-L
Monday
Tuesday
10:00-11:00
E4E5E6 (20CH302T)
E102, ASU-L
E3 (20CH302P) E108, ASU-P
E (20EEM501T)
E005, ASU-L
E1 (20CH302P) E108, ASU-P
E4E5E6 (20CH302T)
E101, ASU-L
17:00- 18:0018:00 19:00
Pandit Deendayal Energy University
School of Technology
20CH302T
Chemical Reaction Engineering 1
Teaching Scheme
Examination Scheme
Theory
L
3
T
0
P
0
C
Practical
MS
ES
IA
LW
LE/Viva
Total
Marks
25
50
25
--
--
100
Hrs/Week
0
3
COURSE OBJECTIVES




To provide understanding of basic principles and terminology in reaction kinetics
To acquaint students towards basic designing of ideal reactors
To allow students to analysis the rate data and thereby find the kinetics parameters of interest
To illustrate concept of reactor sequencing, and evaluate the performance of ideal reactors
UNIT 1 BASICS OF KINETICS
08 Hrs.
Mole balances, kinetics of homogeneous reactions – rate of reaction, type of reactions, reaction mechanism, temperature and
concentration dependent term of a rate equation, searching for a reaction mechanism, rate law and stoichiometry, approach to
reactor sizing and design.
UNIT 2 ANALYSIS OF RATE DATA
12 Hrs.
Collection and analysis of rate data, integral and differential method of analysis of data, batch reactor data, variable and constant
volume system, method of initial rates, method of half-life, differential reactors, least square analysis.
UNIT 3 ISOTHERMAL REACTOR DESIGN
10 Hrs.
Ideal reactors: batch reactors, semi-batch reactors, continuous-flow reactors, recycle reactors conversion and reactor sizing, design
equations, applications of the design equations for continuous-flow reactors, introduction to micro reactors, membrane reactors and
bioreactors
UNIT 4 REACTOR SEQUENCING
10 Hrs.
Reactors in series, reactors for parallel reactions, maximizing desired product in parallel reactions, maximizing desired product in
series reactions, temperature and pressure effect in single and multiple reactions, adiabatic reactor design.
Max. 40Hrs.
COURSE OUTCOMES
On completion of the course, student will be able to
CO1 – Relate to the basics of kinetics and basic theories to get the underlying mechanisms
CO2 – Interpret and evaluate the rate data and get the kinetics parameters
CO3 – Select proper design equations and perform reactor sizing for ideal reactors
CO4 – Examine the suitable combinations of ideal reactors for optimal performance
CO5 – Decide the reactor sequencing for single and multiple reactions towards desired products
CO6 – Design ideal reactor systems based on experimental data and optimize its performance
TEXT/REFERENCE BOOKS
1. H. S. Fogler, “Elements of Chemical Reaction Engineering”, 3rd Ed, New Delhi-Prentice Hall, 2001
2. O. Levenspiel,” Chemical Reaction Engineering” Willey Eastern, 3rd Ed., 2000
3. J. M. Smith, “Chemical Engineering Kinetics”, 3rd Ed., McGraw- Hill, 1988
END SEMESTER EXAMINATION QUESTION PAPER PATTERN
Max. Marks: 100
Part A/Question: Theoretical knowledge and understanding
Part B/Question: Problem Solving, Design and Analysis
Exam Duration: 3 Hrs
20-30 Marks
70-80 Marks
PANDIT DEENDAYAL ENERGY UNIVERISTY
Chemical Engineering Department
Lesson Planning - 5th Semester B Tech – July-Dec 2022
Chemical Reaction Engineering - 1 (20CH302T)
S/No
1
Topic Taught
Basics of Reaction Kinetics
Lectures
Required.
Lectures
Count
Remarks
8
8
Levenspiel
Mole balances, kinetics of homogeneous
reactions – rate of reaction, type of reactions,
reaction
mechanism,
temperature
and
concentration dependent term of a rate
equation, searching for a reaction mechanism,
rate law and stoichiometry, approach to reactor
sizing and design.
2
Analysis of Rate Data
Chapter 1 2
9-20
12
Collection and analysis of rate data, integral
and differential method of analysis of data,
batch reactor data, variable and constant
volume system, method of initial rates, method
of half-life, differential reactors, least square
analysis
3
Ideal Reactors and Sequencing
Chapter 3 4
21-32
12
Ideal reactors: batch reactors, semi-batch
reactors, continuous-flow reactors, recycle
reactors conversion and reactor sizing, design
equations, applications of the design equations
for continuous-flow reactors, introduction to
micro reactors, membrane reactors and
bioreactors
4
Reactors for Multiple Reactions
Levenspiel
Levenspiel
Chapter 5 6
33-40
8
Levenspiel
Reactors in series, reactors for parallel
reactions, maximizing desired product in
parallel reactions, maximizing desired product
in series reactions, temperature and pressure
effect in single and multiple reactions,
adiabatic reactor design.
5
Quiz + Tests
Chapter 7 9
2
42
Total
Mapping of Course Outcomes with Program Outcomes
Course and Program Articulation Matrix
COs↓
PO1
POs→
PO2
PO3
PO4
PO5
PO6
PO7
PO8
PO9
PO10 PO11 PO12
CO1
3
3
2
2
2
1
2
1
3
1
1
1
CO2
3
3
2
2
2
1
2
1
3
1
1
1
CO3
3
3
3
3
2
1
2
1
3
1
1
1
CO4
3
3
3
3
2
1
2
1
3
1
1
1
CO5
3
3
3
3
2
1
2
1
3
1
1
1
CO6
3
3
3
3
2
1
2
1
3
1
1
1
COs↓
POs→
PSO1
PSO2
PSO3
CO1
3
2
2
CO2
3
2
2
CO3
3
2
2
CO4
3
2
2
CO5
3
2
2
CO6
3
2
2
Evaluation Scheme and Rubrics
Assessment
Method
Direct
(Continuous
Assessment)
Direct
Direct
Assessment
Tool
Exam
Exam
Exam
Description
Internal Exam – Quiz,
Assignment, Tests
Mid Semester Exam
End Semester Exam
Marks
25
25
50
Mapping
with CO
Contribution
to CO’s
CO1 CO2
It contributes to
25% weightage
of Direct
Assessment to
CO
CO3 CO4
It contributes to
25% weightage
of Direct
Assessment to
CO
CO1-6
It contributes to
50% weightage
of Direct
Assessment to
CO attainment.
Roll No.:___________________
PANDIT DEENDAYAL PETROLEUM UNIVERSITY
School of Technology, Gandhinagar
Mid Semester Examination – September 2019
B. Tech. (Chemical Engineering)
Semester- V
Course: Chemical Reaction Engineering -1
Course Code: 16CH319T
Date: 25/09/2019
Max. Marks: 50
Instructions:
1. Assume suitable data wherever required and mention the same at appropriate place in the
solution.
2. Put the appropriate units after every numerical solution.
3. All questions are compulsory.
4. Do not write anything on the question paper other than roll no
1. The first-order reversible liquid reaction A↔R in a batch reactor. Equilibrium conversion is
70% while converts 30% in 10 minutes of time. Find the rate equation for this reaction. (08
marks)
2. Bitumen is cracked 1500oC, the rate is reduced by 4 times than the rate at 1100oC. Determine
the activation energy of cracking. (05 marks)
3. If the half-life of a radioactive material is 33 minutes. Determine the time for almost
complete decay if initial concentration if 15 mol/L. (05 marks)
4. After 8 minutes in a batch reactor, reactant (CA0 = 1 mol/L) is 80% converted; after 18
minutes, conversion is 90%. Find a rate equation to represent this reaction. (07 marks)
5. Derive an expression for reversible uni-molecular first order reaction (A↔ R) using an
integral method of analysis for rate data, k1, k2 being the forward and backward rate constant.
Show that first order irreversible is special case of reversible reaction. (10 marks)
6. Find the second order rate constant for the disappearance of A in the gas reaction 4A R if,
on holding the pressure constant, the volume of the reaction mixture, starting with 50%A,
decreases by 30% in 5min. Consider the initial molar concentration to be 2mol/L (10 marks)
7. Explain with example, (05 marks)
a. side by side and competitive reaction
b. elementary and non-elementary reaction
c. autocatalytic reaction
------------------------------------------------------ GOOD LUCK --------------------------------------------
Page | 1
Roll No.:___________________
PANDIT DEENDAYAL PETROLEUM UNIVERSITY
School of Technology, Gandhinagar
End Semester Examination – December 2019
B. Tech. (Chemical Engineering)
Semester- V
Course: Chemical Reaction Engineering -1
Course Code: 16CH319T
Date: 20/12/2019
Max. Marks: 100
Instructions:
1. Assume suitable data wherever required and mention the same at appropriate place in the
solution.
2. Put the appropriate units after every numerical solution.
3. All questions are compulsory.
4. Do not write anything on the question paper other than roll no
Section 01 (40 Marks)
1. The maximum allowable temperature for a reactor is 800K. At present our operating set point is 780
K, the 20K margin of safety to account for fluctuating feed, sluggish controls, etc. Now, with a more
sophisticated control system we would be able to raise our set point to 792K with the same margin of
safety that we now have. By how much can the reaction rate, hence, production rate, be raised by this
change if the reaction taking place in the reactor has an activation energy of 175 kJ/mol? (05 marks)
2. What are reactions of shifting order? Give brief. (03 Marks)
3. For the stoichiometry A+B  P. Find the reaction orders with respect to A and B (07 Marks)
CA
2
2
3
CB
125
32
32
-rA
25
16
32
4. Derive an expression for homogeneous catalyzed system (AR, and A+C R+C) using an integral
method of analysis for rate data. The reaction rate for a homogeneous catalyzed system is the sum of
rates of both the uncatalyzed and catalyzed reactions.
What if the reaction set is competitive reactions (AR and AS) Derive an expression using
integral method and show how the rate constants will be evaluated graphically. (15 marks)
5. Aqueous A at a concentration CA0 = 1 mol/L is introduced into a batch reactor where it reacts away to
form product R according to the reaction A  R. The concentration of A in the reactor is monitored
at various times, as shown below
t, min
0
100
200
300
400
CA, mol/m3
1000 500
333
250
200
Find the rate equation describing the data. Also, for CA0 = 500 mol/m3 find the conversion of reactant
after 5 hours in the batch reactor. (10 Marks)
Page | 1
Section 02 (30 Marks)
1. A specific enzyme acts as catalyst in the fermentation of reactant A. At a given enzyme concentration
in the aqueous feed stream (25 L/min) find the volume of plug flow reactor needed for 95%
conversion of reactant A (CA0 = 2 mol/L). The
kinetics of the fermentation at this enzyme
concentration is given on the right (10 Marks)
2. A gaseous feed of pure A (2 mol/L, 100 mol/min) decomposes to give a variety of products in a plug flow
reactor. The kinetics of the conversion is represented by A 2.5P, -rA = (10 min-1) CA. Find the expected
conversion in a 22 L reactor. (08 Marks)
3. A stream of pure gaseous reactant A (CA0 = 660 mmol/L) enters a plug flow reactor at a flow rate of FA0 =
540 mmol/min and polymerizes there by reaction given.
How large a reactor is needed to lower the concentration of
A in the exit stream to CAf = 330 mmol/L? Also, find the size
if it is CSTR. (08 Marks)
4. What are the different rules for arrangement for a given set of ideal reactors? (04 Marks)
Section 03 (30 Marks)
1. At present we have 90% conversion of a liquid feed (n = 1, CA0 = 10 mol/L) to our plug flow reactor with
recycle of product (R = 2). If we shut off the recycle stream, by how much will this change the processing
rate of our feed for the same 90% conversion? (08 Marks)
2. The kinetics of the aqueous-phase decomposition of A is investigated in two mixed flow reactors in series,
the second having twice the volume of the first reactor. At steady state with a feed concentration of 1.0
mol-A/L and mean residence time of 96 sec in the first reactor, the concentration in the first reactor is 0.5
mol-A/L and in the second is 0.25 mol-A/L. Find the kinetic equation for the decomposition. (08 Marks)
3. Substance A in the liquid phase produces R and S by the following reactions:
The feed (CA0 = 1.0, CR0 = 0, CS0 = 0.3) enters two mixed flow reactors in
series (τ1 = 2.5 min, τ2 = 10 min). Knowing the composition in the first
reactor (CA1 = 0.4, CR1 = 0.2, CS1 = 0.7), find the composition leaving the
second reactor. (10 Marks)
4. A+B R (Desired) and A+BS (Undesired) – with
𝑑𝐶𝑅
𝑑𝐶𝑆
𝑘
= 𝑘1 𝐶𝐴 −1.5𝐶𝐵 0.5
2
From the standpoint of favourable product distribution, order the contacting schemes (A High B High, A
Low B Low, A High B Low and A Low B High), from the most desirable to the least desirable. Draw the
contacting pattern in continuous flow operations. (04 Marks)
------------------------------------------------------ GOOD LUCK --------------------------------------------
Page | 2
Roll No.:___________________
PANDIT DEENDAYAL PETROLEUM UNIVERSITY
School of Technology, Gandhinagar
Re-End Semester Examination – December 2019
B. Tech. (Chemical Engineering)
Semester- V
Course: Chemical Reaction Kinetics
Course Code: CH320T
Date: 26/12/2019
Max. Marks: 100
Instructions:
1. Assume suitable data wherever required and mention the same at appropriate place in the
solution.
2. Put the appropriate units after every numerical solution.
3. All questions are compulsory.
4. Do not write anything on the question paper other than roll no
Section 01 (50 Marks)
1. Discuss elementary and non-elementary reactions with example. How molecularity and order
of reaction are related to each other? (07 Marks)
2. What is space time and space velocity? Give significance. (03 Marks)
3. Derive an expression for irreversible bimolecular second order reaction (2A  Products)
using an integral method of analysis for rate data. Extend the same to nth order reaction. (15
marks)
4. The pyrolysis of ethane proceeds with an activation energy of about 40 kJ/mol. How much
faster is the decomposition at 820°C than at 520oC? (05 Marks)
5. An ampoule of radioactive Kr-89 (half life = 76 minutes) is set aside for a day. What does
this do to the activity of the ampoule? Note that radioactive decay is a first-order process. (07
Marks)
6. For the reaction AR, second-order kinetics and CA0 = 1 mol/L, we get 50% conversion
after 1 hour in a batch reactor. What will be the conversion and concentration of A after 1
hour if CA0=10 mol/L? (08 Marks)
7. State whether True/False and Justify your answer (05 Marks)
PFR’s in series will behave as single PFR
CSTR’s in series will behave as single PFR
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Section 02 (50 Marks)
1. The homogeneous gas decomposition of phosphine proceeds at 649oC with first-order rate.
2.
3.
4.
5.
6.
What size of plug flow reactor operating at 649°C and 460 kPa can produce 80% conversion
of a feed consisting of 40 mol of pure phosphine per hour? (10 Marks)
In an isothermal batch reactor 70% of a liquid reactant is converted in 13 min. What spacetime and space-velocity are needed to effect this conversion in a plug flow reactor and in a
mixed flow reactor? (07 Marks)
An aqueous reactant stream (4 mol-A/L) passes through a mixed flow reactor followed by a
plug flow reactor. Find the concentration at the exit of the plug flow reactor if in the mixed
flow reactor CA = 1 mol/liter. The reaction is second-order with respect to A, and the volume
of the plug flow unit is three times that of the mixed flow unit. (10 Marks)
200 L/hr of radioactive fluid having a half-life of 40 hr is to be treated by passing it through
two ideal stirred tanks in series, V = 75 000 liters each. In passing through this system, how
much will the activity decay? (10 Marks)
Explain the following terms (03 Marks)
a. Instantaneous yield
b. Overall yield
c. Selectivity
For a given set of parallel reaction
with relative rates of R and S as
For different values of a1 and a2 (order of reaction) what concentration and what reactor
system will be used. (10 Marks)
------------------------------------------------------ GOOD LUCK --------------------------------------------
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