1.1 Introduction to the particulate nature of matter and chemical change Refresh: Monday, 14 November 202 Every lesson will begin with a refresher question from the previous class. Objectives: Keywords/ processes Grade 4 Grade 5 Grade 6 • Mixtures are either heterogeneous or homogenous • Use the correct state symbols (s), (l), (g) and (aq) in equations • Mixtures retain their individual properties as they contain more than one element and/or compound that are not chemically bonded together • Deduce chemical equations when the reactants and products are specified • Atoms of different elements combine in fixed ratios to form compounds Recall & remember Describe & explain Apply and evaluate Melting point Freezing point Boiling point Vaporization Condensation Sublimation Evaporation deposition Elements and Compounds ©Dr. Geoffrey Neuss thinkIB.net All pure substances are either made up of just one chemical element, eg. copper metal or oxygen gas, or are compounds made up of two or more elements, eg. water, carbon dioxide or glucose. A chemical element is a neutral substance that cannot be broken down into simpler substances using chemical methods. It consists only of atoms that contain the same number of protons and electrons, although the atoms can contain a different number of neutrons. There are 118 known chemical elements. A compound is a pure substance formed when two or more chemical elements are chemically bonded together. A compound has different properties from its component elements. For example, sodium is a reactive metal which melts at 98ºC and chlorine is a poisonous reactive gas whereas sodium chloride is a salt with a high melting point (801ºC) which dissolves in water. Objective: • Atoms of different elements combine in fixed ratios to form compounds Task 1 - Elements ©Dr. Geoffrey Neuss thinkIB.net Complete the following lists with the name or symbol for some common elements using Table 5 of the Chemistry Data Booklet 2016. Objective: • Atoms of different elements combine in fixed ratios to form compounds States of Matter There are three common states of matter: • Solid (s): occupy a fixed space and a fixed volume. Particles held closely together in a lattice. • Liquid (l): Fixed volume that takes up the shape of its container. Particles close together but moving with random motion. • Gas (g): Completely fills its container. Widely spaced particles moving with rapid, random motion. Objective: • Use the correct state symbols (s), (l), (g) and (aq) in equations ©Dr. Geoffrey Neuss thinkIB.net Task 2 – States of Matter ©Dr. Geoffrey Neuss thinkIB.net Explain the meaning of the following words with regards to changes in state: • melting • freezing • vaporization • evaporation • boiling • condensation • sublimation • deposition Objective: • Use the correct state symbols (s), (l), (g) and (aq) in equations Task 3 – Cooling Curves ©Dr. Geoffrey Neuss thinkIB.net The graph shows the temperature of a sample of naphthalene measured at one minute intervals as it cools from the liquid state of 90ºC. Explain the shape of the graph at the molecular level. Objective: • Use the correct state symbols (s), (l), (g) and (aq) in equations Pure Substances and Mixtures ©Dr. Geoffrey Neuss thinkIB.net A pure substance may either be an element or a compound and has a definite and constant composition. A mixture is a physical combination of pure substances. Mixtures have no definite or constant composition. A mixture can be separated into its pure components by physical means. Ways of separating mixtures into their pure components include filtration, distillation and different forms of chromatography. A mixture may be homogeneous – all the components are in the same phase or heterogeneous – the components are in different phases. There is a physical boundary between two phases so, for example, a mixture of oil and water is a heterogeneous mixture even though both the oil and the water are in the liquid state. Objective: • • Mixtures are either heterogeneous or homogenous Mixtures retain their individual properties as they contain more than one element and/or compound that are not chemically bonded together Task 4 – Pure Substances and Mixtures ©Dr. Geoffrey Neuss thinkIB.net Consider the following mixtures: • A solution of sodium chloride in water • An analgesic tablet containing paracetamol, caffeine and codeine • Unleaded gasoline (petrol) • Oil and vinegar 1. Identify which of the mixtures are homogeneous and which are heterogeneous. 2. Suggest how you could separate each of the mixtures into their individual components. Objective: • Mixtures are either heterogeneous or homogenous Task 5 - Assumptions ©Dr. Geoffrey Neuss thinkIB.net In the early nineteenth century John Dalton made the following assumptions: • Elements are made of extremely small particles called atoms. • Atoms of a given element are identical in size, mass, and other properties; atoms of different elements differ in size, mass, and other properties. • Atoms cannot be subdivided, created, or destroyed. • Atoms of different elements combine in simple whole-number ratios to form chemical compounds. • In chemical reactions, atoms are combined, separated, or rearranged. Discuss whether each of these five assumptions is still considered to be valid today. Objective: • Mixtures retain their individual properties as they contain more than one element and/or compound that are not chemically bonded together Chemical Equations ©Dr. Geoffrey Neuss thinkIB.net In a chemical equation reactants are written on the left-hand side and products on the right-hand side. The coefficient refers to the number in front of each reactant and product in the equation. The coefficients give information on the molar ratio. In a balanced chemical equation the amount (in moles) of each element must be the same on both sides as there is no overall change in mass during a chemical reaction. The states of the reactants and products are represented by (g), (l), (s) and (aq) where (aq) refers to ‘in aqueous solution.’ Reversible arrows are used to represent equilibrium reactions. CaCO3(s) + 2HCl(aq) CaCl2(aq) + CO2(g) + H2O(l) (single arrow as reaction goes to completion) N2(g) + 3H2(g) ⇌ 2NH3(g) (reversible arrows as reaction is in equilibrium) Objective: • • Use the correct state symbols (s), (l), (g) and (aq) in equations Deduce chemical equations when the reactants and products are specified Key Points • Physical and chemical properties depend on the ways in which different atoms combine. Objective: