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Absorption Cooling Theory

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Welcome to BROAD !
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© November 2005
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Warm-up Knowledge
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Absorption Cooling Theory
How Absorption Cooling Works
Why LiBr?
Energy efficiency
Advantages
Applications
Central A/C system
Standard
Energy
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Absorption Cooling Theory
making and keeping
cooling surrounding
special
surrounding
absorbing
heat
cooling
source
supply
chiller
ambient
surrounding
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Absorption Cooling Theory
condenser
throttling
device
refrigerant
cooling
source
1. Getting cooling
source
supply
evaporator
driving
device
chiller
refrigerant vapor
Refrigerant evaporation
Refrigerant make up
2.Maintaining
cooling source
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Keep vacuum
condition
Absorbing
refrigerant vapor
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Absorption Cooling Theory
In Evaporator:
Refrigerant water sprays on the extended surface copper tubes of
chilled water system
Evaporation takes away heat from surroundings
Water evaporates:
100 ℃ (212℉)
under normal atmospheric pressure
760mm Hg (29.9in Hg)
Water can also evaporate:
at low temperatures & under vacuum conditions
4℃ (39℉) 6mm Hg (0.24in Hg)
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Absorption Cooling Theory
6mmHg
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Absorption Cooling Theory
In Absorber:
• Lithium bromide has the ability to absorb water vapor
– 63% LiBr solution at 41℃ has a strong affinity for water.
Boiling point:1265℃
– Water is refrigerant
– LiBr which is the refrigerant absorbent absorbs water vapor
continuously and keeps the low pressure condition in the
evaporator/absorber vessel
– Refrigerant water is made up by condensation of the boiling
solution heated by external heat source.
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Absorption Cooling Theory
In Generator
• External heat source (gas, oil, steam, hot water…) heats the solution
– Concentrate it to ~63% (make up the refrigerant absorbent in
Absorber)
– Generate vapor (make up the refrigerant in Evaporator)
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Absorption Cooling Theory
Generator
Heat source
strong
solution
weak
solution
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Absorber
Water vapour
Evaporator
cooling
load
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Absorption Cooling Theory
Condenser
LTG
HTG
(57mmHg)
(57mmHg, 90℃)
(690mmHg, 155℃)
heating
source
63%, 90℃
63%, 155℃
HTHE
LTHE
41℃
38℃
42℃
Absorber
(6mmHg, 42℃)
Evaporator
(6mmHg, 4℃)
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57%, 38℃
38℃
 concentrated
solution
 diluted solution
 refrigerant vapor
 refrigerant water
 cooling water
 chilled water
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Absorption Cooling Theory
Water vapour
Generator
Heat source
Condenser
strong solution
Heat exchanger
Water vapour
weak
solution
cooling load
Absorber
Cooling water
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Evaporator
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How Absorption Cooling Works
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How Absorption Cooling Works
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Why LiBr?
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Why LiBr ?
LiBr Physic Characteristics
• LiBr: non-toxic, white crystal particles. Stable, odorless with
salty taste in room temperature.
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Its chemical characteristics are same as table salt (NaCI).
• degenerative, non-volatile and decomposable in the
atmosphere but soluble in water.
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molecular formula: LiBr
relative molecular quality:86.844
appearance: white crystal particle
density: 3464 kg/m3(25℃)
melting point: 549℃
boiling point: 1265℃
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Why LiBr ?
LiBr Solution’s Physic Characteristics
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Solubility: soluble weight in 1L water under certain temperature and
pressure. LiBr solubility: 111.2g at 20℃.
Saturated solution / balanced state
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Crystallization: crystal is to be separated out from saturated water
solution when solute is greater than solubility.
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Factors to cause crystallization:
- temperature
- concentration
- flow velocity
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Why LiBr ?
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Why LiBr ?
Additives
• Corrosion Inhibitor
- Lithium Chromate
- Lithium Molybdate
• Energy intensifier
• iso-octanol
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Energy Efficiency
Measurement of efficiency
- Coefficient of Performance (COP)
COP= energy out / energy input
Primary energy efficiency
- IPLV (Integrated Part Load Value)
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Advantages
BROAD Absorption cooling offers important advantages
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Possibility and effectiveness for heat recovery applications
Lower operating costs
Reliable and low maintenance cost, longer lifespan
Environmentally friendly
More functions (and smaller footprint than an electric chiller with boiler)
Sound primary energy efficiency
Energy safety
Safe, quite operation
Initial costs quickly offset by energy savings
National energy structure
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Energy Selection
Applications
Choosing an Energy Source for your Air Conditioning System
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Energy conservation is an issue increasingly catching the public's attention.
As larger portions of the globe race towards development, the strain on the
environment and its resources is increasing. The global community has to
make a greater effort to protect our future. Furthermore, using energy
economically is a smart move for national economies and with regards to
individual investments as well. Air conditioning systems are heavy consumers
of energy. In evaluating a building's operational costs, it is almost a certainty
that the energy used in the AC system covers a large percentage. The selection
of a more appropriate energy source and energy saving air conditioning
equipment can be key factors in reducing expenses for building
owners/tenants.
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BROAD recommends a series of proposals relating to energy source and air
conditioning equipment selection. These proposals have been implemented
numerous times, especially in the European and American markets. They are
cutting-edge, yet also very practical. The investment payback period is short,
and the system technologies are mature.
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Given a Heat Source, BROAD Can Provide Cooling
Primary Energy
Heat Equipment
Heat Input
Chiller Type
Function
Solar energy
Parabolic trough
solar collector
≥0.6MPa steam
≥160℃ hot water
Direct-fired & steam type
Direct-fired & hot water
type
CHW
Geothermal heat
(e.g. hot spring)
N/A
≥75℃ hot water
Single-stage hot water
type
C
Natural gas
Turbine
230-350℃ exhaust
Single-stage exhaust type
CH
≥400℃ exhaust
Two-stage exhaust type
Direct-fired & exhaust
CHW
Light oil
Internal combustion
engine
≥400℃ exhaust
≥90℃ jacket water
Two-stage exhaust type
Direct-fired & hot water &
exhaust type
CHW
NG
Town (coal) gas
Town bed gas
Coke-oven gas
Bio-gas
Light oil
Bio-energy
Fuel cell
Thermal power
station
Industrial furnace
Industrial boiler
≥400℃ exhaust
≥0.6MPa steam
Two-stage exhaust type
Two-stage steam type
Direct-fired & exhaust type
Direct-fired & steam type
CHW
Garbage
Small garbage
incinerator
≥400℃ exhaust
Two-stage exhaust type
CH
Garbage incinerator
& steam boiler
Steam turbine
≥0.6MPa steam
Two-stage steam type
C
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Examples of Various Types of Energy-saving Systems
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Examples of Various Types of Energy-saving Systems
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Examples of Various Types of Energy-saving Systems
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Examples of Various Types of Energy-saving Systems
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Examples of Various Types of Energy-saving Systems
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Examples of Various Types of Energy-saving Systems
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Examples of Various Types of Energy-saving Systems
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Brief Introduction to
Central Air Conditioning
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Central A/C System
Principle
heat transfer by
doors & windows
——Summer
heat transfer
by rooftop
Air Con
Sun Radiation
heat transfer
by floor
heat transfer
by wall
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Central A/C System
Principle
——Winter
heat transfer by
doors & windows
heat transfer
by rooftop
Air Con
heat transfer
by wall
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Central A/C System
Central Air Con System
Chiller
Terminal
System
Central Air
Conditioning
System
Water Pumps
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Cooling Tower
Others
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Central A/C System
air…
temperature/humidity/ flow…
chiller provides heat/cold water
Air-cooled
heat pump
Packaged Air
Conditioner
Absorption Chiller
Chiller
Screw
Centrifugal
Scroll
Fan Coil
air cools water…
heat rejection (& balance)
Open, Closed…
Round, Square…
Counterflow,
Transverse…
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AHU
Air Conditioner
(terminal)
A/C w. pump
Hot w. pump
Water pumps
Cooling
Tower
Cooling w. pump
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Central A/C System
Other Elements
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Water pipe (seamless, zinc-plated steel…)
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Air duct (zinc-plated steel, glass fibre reinforced plastic…)
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Water valve:regulate / cut off water flow
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Air (wind) valve: regulate / cut off air (wind) flow
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Water filter
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Air filter
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Insulation materials:
reduce heat loss / prevent surface dewing / avoid scalding
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Standards
Standards
• JIS B 8622
• ARI 560-2000
• Chinese National Standard
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Energy
Energy Sources
• Types: conventional/new; primary/secondary; renewable/nonrenewable; clean/not clean
• Measurements: kg,m3; kW, Btu, kcal; standard oil…
• Quality: temperature/heat value/enthalpy/intensity
Heating Value
Natural
Gas
m3
Diesel
kg
Coke
Oven Gas
m3
m3
kg
Power
kWh
kcal
8600
10400
4300
24600
12000
860
kWh
10
12
5
28.6
14
1
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LPG
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