Semiconductor Fundamentals
OUTLINE
• General material properties (Ch.1.1)
• Crystal structure (Ch.1.2)
• Crystallographic notation (Ch.1.2)
• Ch.1.3: reading assignment (optional)
Read: Chapter 1
What is a Semiconductor?
• Low resistivity => “conductor”
• High resistivity => “insulator”
• Intermediate resistivity => “semiconductor”
– conductivity lies between that of conductors and
insulators
– generally crystalline in structure for IC devices
• In recent years, however, non-crystalline semiconductors
have become commercially very important.
Fig. 1.1: polycrystalline amorphous crystalline
Prof. Changhwan Shin
Semiconductor Materials
Elemental:
Compound:
Alloy:
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From Hydrogen to Silicon
# of Electrons
1
2
3
Z Name 1s 2s 2p 3s 3p 3d
Notation
1
1H
1
1s
2 He
2
1s 2
3 Li
2
1
1s 2 2s 1
4 Be
2
2
1s 2 2s 2
5B
2
2
1
1s 2 2s 2 2p1
6C
2
2
2
1s 2 2s 2 2p2
7N
2
2
3
1s 2 2s 2 2p3
8O
2
2
4
1s 2 2s 2 2p4
9F
2
2
5
1s 2 2s 2 2p5
10 Ne
2
2
6
1s 2 2s 2 2p6
11 Na
2
2
6
1
1s 2 2s 2 2p6 3s 1
12 Mg
2
2
6
2
1s 2 2s 2 2p6 3s 2
13 Al
2
2
6
2
1
1s 2 2s 2 2p6 3s 2 3p1
14 Si
2
2
6
2
2
1s 2 2s 2 2p6 3s 2 3p2
15 P
2
2
6
2
3
1s 2 2s 2 2p6 3s 2 3p3
16 S
2
2
6
2
4
1s 2 2s 2 2p6 3s 2 3p4
17 Cl
2
2
6
2
5
1s 2 2s 2 2p6 3s 2 3p5
18 Ar
2
2
6
2
6
1s 2 2s 2 2p6 3s 2 3p6
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The Silicon Atom
• 14 electrons occupying the 1st 3 energy levels:
– 1s, 2s, 2p orbitals filled by 10 electrons
– 3s, 3p orbitals filled by 4 electrons
To minimize the overall energy, the 3s and 3p
orbitals hybridize to form 4 tetrahedral 3sp orbitals
Each has one electron and
is capable of forming a bond
with a neighboring atom
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The Si Crystal
• Each Si atom has 4
nearest neighbors
• lattice constant
= 5.431Å
• SC, BCC, FCC structures
vs. Diamond structure
“Diamond cubic” lattice
• Diamond vs. Zincblende
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How Many Silicon Atoms per cm-3?
• Number of atoms in a unit cell:
• 4 atoms completely inside cell
• Each of the 8 atoms on corners are shared among cells
à count as 1 atom inside cell
• Each of the 6 atoms on the faces are shared among 2
cells à count as 3 atoms inside cell
Þ Total number inside the cell = 4 + 1 + 3 = 8
• Cell volume:
(.543 nm)3 = 1.6 x 10-22 cm3
• Density of silicon atoms
= (8 atoms) / (cell volume) = 5 x 1022 atoms/cm3
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Compound Semiconductors
Ga
As
• “zincblende” structure
• III-V compound semiconductors: GaAs, GaP, GaN, etc.
ü important for optoelectronics and high-speed ICs
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Crystallographic Notation
Miller Indices:
Notation
(hkl)
Interpretation
{hkl}
[hkl]
equivalent planes
crystal direction
<hkl>
equivalent directions
crystal plane
h: inverse x-intercept of plane
k: inverse y-intercept of plane
l: inverse z-intercept of plane
(Intercept values are in multiples of the lattice constant;
h, k and l are reduced to 3 integers having the same ratio.)
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Crystallographic Planes and Si Wafers
Silicon wafers are usually cut
along a {100} plane with a flat
or notch to orient the wafer
during IC fabrication:
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Crystallographic Planes in Si
Unit cell:
View in <111> direction
View in <100> direction
View in <110> direction
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Summary
• Crystalline Si:
– 4 valence electrons per atom
– diamond lattice
• each atom has 4 nearest neighbors
– 5 x 1022 atoms/cm3
• Crystallographic notation
– Miller indices are used to designate planes
and directions within a crystalline lattice
Prof. Changhwan Shin