Microelectromechanical Systems (MEMS/NEMS) MEMS: A Technology from Lilliput An introduction "Innovation distinguishes between a leader and a follower." --Steve Jobs https://www.youtu be.com/watch?v= 0EokkhdppgE What are MEMS? (Micro-electromechanical Systems) • Fabricated using micromachining technology • Used for sensing, actuation or are passive micro-structures • Usually integrated with electronic circuitry for control and/or information processing Introduction, Continued Image Courtesy of Sandia National Laboratories, SUMMiTTM Technologies, www.mems.sandia.gov Figure 5.3: Spider mite with legs on a mirror drive assembly. Brief History 1962 1967 1967 1972 1979 1982 1982 1983 1983 1983 1985 1987 1993 1994 1999 Silicon Integrated piezo actuators BY O.N. Tufte et al. Anisotropic deep silicon etching H.A. Waggener The resonant gate transistor by H. Nathanson, et.al National Semiconductor - Pressure Sensor Thermal inkjet technology is invented at HP laboratories “Silicon as a Mechanical Material” K. Peterson Liga Process (KFIK, Germany) “Infinitesimal Machinery” R. Feynman Silicon Micromechanical devices – J.B.Angel etc. Integrated Pressure Sensor – Honeywell Airbag Crash Sensor Dr. Hornbeck Digital Micromirror Device or DMD (DLP by Texas Instruments) Later in 1990s micromachining begins leveraging microelectronics industry Accelerometer integrated with electronics Analog devices DRIE Etching (Bosch process is patented) Optical network switch - Lucent 3-D Micromachined Structures Linear Rack Gear Reduction Drive Triple-Piston Microsteam Engine Photos from Sandia National Lab. Website: http://mems.sandia.gov Applications: Passive Structures Inkjet Printer Nozzle https://www.youtube.com/watch?v=9yeZSaig Bj4&feature=youtu.be https://www.youtube.com/watch?v= qPwlgL91-Q4 On Chip Inductor A surface-micromachined parallel-plate variable capacitor Different implementations of a surface-micromachined parallel-plate variable capacitor: (a) perspective view of the basic concept showing a stationary plate and a moveable plate suspended by springs; (b) top view of a capacitor using straight beams as springs; (c) top view using Tshaped springs [8]; (d) top view using Lshaped springs [5]; and (e) top view with center anchor [7]. Applications: Sensors Pressure sensor: • Piezoresistive sensing • Capacitive sensing • Resonant sensing Application examples: • Manifold absolute pressure (MAP) sensor • Disposable blood pressure sensor (Novasensor) Piezoresistive Pressure Sensors Pressure Piezoresistive elements SiO2 p+ Si <100> Si substrate Piezoresistive Pressure Sensors Wheatstone Bridge configuration Illustration from “An Introduction to MEMS Engineering”, N. Maluf Applications: Sensors Inertial sensors • Acceleration – Air bag crash sensing – Seat belt tension – Automobile suspension control – Human activity for pacemaker control • Vibration – Engine management – Security devices – Monitoring of seismic activity • Angle of inclination – Vehicle stability and roll Accelerometers Accelerometer parameters • acceleration range (G) (1G=9.81 m/s2) • sensitivity (V/G) • resolution (G) • bandwidth (Hz) • cross axis sensitivity Application Range Bandwidth Air Bag Deployment ± 50 G ~ 1 kHz Engine vibration ±1G > 10 kHz Cardiac Pacemaker control ±2G < 50 Hz Comment resolve small accelerations (< 1 micro G) multiaxis, ultra-low power consumption https://www.youtube.com/watch?v=eqZgxR6eRjo&t=509s https://www.youtube.com/watch?v=4kfzqZpttTA https://www.youtube.com/watch?v=XsjvaYAFN1M Capacitive Accelerometers Anchor to substrate Spring Displacement Inertial Mass Stationary Polysilicon fingers Based on ADXL accelerometers, Analog Devices, Inc. Applications: Actuators Texas Instruments Digital Micromirror DeviceTM • Invented by Texas Instruments in 1986 • Array of up to 1.3 million mirrors • Each mirror is 16 mm on a side with a pitch of 17 mm • Resolutions: 800x600 pixels (SVGA) and 1280x1024 pixels (SXGA) For an animated demo of this device, go to http://www.dlp.com/dlp_technology/ Digital Micromirror Device From “An Introduction to Microelectromechanical Systems Engineering” by Nadim Maluf Digital Micromirror Device • Mirror is moved by electrostatic actuation (24 V applied to bias electrode) • Projection system consists of the DMD, electronics, light source and projection optics • Switching time: 16 µs (about 1000 times faster than the response time of the eye) => Acheive grey scale by adjusting the duration of pulse • Placing a filter wheel with the primary colors between light source and the micromirrors => Achieve full color by timing the reflected light to pass the wheel at the right color From “An Introduction to Microelectromechanical Systems Engineering” by Nadim Maluf Some future applications • Biological applications: – Microfluidics – Lab-on-a-Chip – Micropumps – Resonant microbalances – Micro Total Analysis systems • Mobile communications: – Micromechanical resonator for resonant circuits and filters • Optical communications: – Optical switching Microfluidics / DNA Analysis In the future, a complete DNA sequencing systems should include: •Amplification (PCR) •Detection (electrophoresis) •Fluid preparation and handling (pumps, valves, filters, mixing and rinsing) MEMS ! MEMS Fabrication “You can’t see it, but it’s everywhere you go.” —Bridget Booher, journalist, on silicon Materials for MEMS • If we view micromachining technology as a set of generic tools, then there is no reason to limit its use to one material. Indeed, micromachining has been demonstrated using silicon, glass, ceramics, polymers, and compound semiconductors made of group III and V elements, as well as a variety of metals including titanium and tungsten. • Silicon, however, remains the material of choice for microelectromechanical systems. Unquestionably, this popularity arises from the large momentum of the electronic integrated circuit industry and the derived economic benefits, not least of which is the extensive industrial infrastructure. Silicon-Compatible Material System • The silicon-compatible material system encompasses, in addition to silicon itself, a host of materials commonly used in the semiconductor integrated circuit industry. • Normally deposited as thin films, they include silicon oxides, silicon nitrides, and silicon carbides, metals such as aluminum, titanium, tungsten, and copper, and polymers such as photoresist and polyimide. Why Silicon • Silicon is one of very few materials that is economically manufactured in single crystal substrates. This crystalline nature provides significant electrical and mechanical advantages. • The precise modulation of silicon’s electrical conductivity using impurity doping lies at the very core of the operation of electronic semiconductor devices. • Mechanically, silicon is an elastic and robust material whose characteristics have been very well studied and documented. • The tremendous wealth of information accumulated on silicon and its compounds over the last few decades has made it possible to innovate and explore new areas of application. • It becomes evident that silicon is a suitable material platform on which electronic, mechanical, thermal, optical, and even fluid-flow functions can be integrated. • Ultrapure, electronic-grade silicon wafers available for the integrated circuit industry are common today in MEMS. • The relatively low cost of these substrates (approximately $10 for a 100mm-diameter wafer and $15 for a 150-mm wafer) makes them attractive for the fabrication of micromechanical components and systems. Forms of silicon • Silicon as an element exists with three different microstructures: • crystalline, polycrystalline, amorphous. • Polycrystalline, or simply “polysilicon,” and amorphous silicon are usually deposited as thin films with typical thicknesses below 5 µm. • Crystalline silicon substrates are commercially available as circular wafers with 100-mm (4-in) and 150-mm (6-in) diameters. Largerdiameter (200-mm and • 300-mm) wafers, used by the integrated circuit industry, are currently economically unjustified for MEMS. Standard 100-mm wafers are nominally 525 µm thick, and 150-mm wafers are typically 650 µm thick. • Double-side-polished wafers commonly used for micromachining on both sides of the wafer are approximately 100 µm thin-ner than standard thickness substrates. • Polysilicon is an important material in the integrated circuit industry and has been extensively studied. • Polysilicon is an equally important and attractive material for MEMS. • It has been successfully used to make micromechanical structures and to integrate electrical interconnects, thermocouples, p-n junction diodes, and many other electrical devices with micromechanical structures. • The most notable example is the acceleration sensor available from Analog Devices, Inc., of Norwood, Massachusetts, for automotive airbag safety systems. • The mechanical properties of polycrystalline and amorphous silicon vary with deposition conditions, but, by and large, they are similar to that of single crystal silicon. Both normally have relatively high levels of intrinsic stress (hundreds of MPa) after deposition, which requires annealing at elevated temperatures (>900ºC). • Beam structures made of polycrystalline or amorphous silicon that have not been subjected to a careful stress annealing step can curl under the effect of intrinsic stress. • Silicon is a very good thermal conductor with a thermal conductivity greater than that of many metals and approximately 100 times larger than that of glass. In complex integrated systems, the silicon substrate can be used as an efficient heat sink. • Unfortunately, silicon is not an active optical material—silicon-based lasers do not exist. Because of the particular interactions between the crystal atoms and the conduction electrons, silicon is effective only in detecting light; emission of light is very difficult to achieve. • The surface of silicon oxidizes immediately upon exposure to the oxygen in air (referred to as native oxide). The oxide thickness self-limits at a few nanometers at room temperature. As silicon dioxide is very inert, it acts as a protective layer that prevents chemical reactions with the underlying silicon. Silicon Oxide and Nitride • It is often argued that silicon is such a successful material because it has a stable oxide that is electrically insulating—unlike germanium, whose oxide is soluble in water, or gallium arsenide, whose oxide cannot be grown appreciably. • Various forms of silicon oxides (SiO2, SiOx, silicate glass) are widely used in micromachining due to their excellent electrical and thermal insulating properties. • They are also used as sacrificial layers in surface micromachining processes because they can be preferentially etched in hydrofluoric acid (HF) with high selectivity to silicon. • Silicon dioxide (SiO2) is thermally grown by oxidizing silicon at temperatures above 800°C, whereas the other forms of oxides and glass are deposited by chemical vapor deposition, sputtering, or even spin-on (the various deposition methods will be described in the next chapter). • Silicon oxides and glass layers are known to soften and flow when subjected to temperatures above 700°C. A drawback of silicon oxides is their relatively large intrinsic stresses, which are difficult to control. This has limited their use as materials for large suspended beams or membranes. • Silicon nitride (SixNy) is also a widely used insulating thin film and is effective as a barrier against mobile ion diffusion—in particular, sodium and potassium ions found in biological environments. Its Young’s modulus is higher than that of silicon and its intrinsic stress can be controlled by the specifics of the deposition process. • Silicon nitride is an effective masking material in many alkaline etch solutions. Thin Metal Film • The choice of a thin metal film depends greatly on the nature of the final application. • Thin metal films are normally deposited either by sputtering, evaporation, or chemical vapor deposition; gold, nickel, and Permalloy™ (NixFey), and a few other metals can also be electroplated. • For basic electrical interconnections, aluminum (usually with a few percent silicon and perhaps copper) is most common and is relatively easy to deposit by sputtering, but its operation is limited to noncorrosive environments and to temperatures below 300ºC. • For higher temperatures and harsher environments, gold, titanium, and tungsten are substitutes. • Aluminum tends to anneal over time and with temperature, causing changes in its intrinsic stresses. As a result, it is typically located away from stress- or strain-sensing elements. • Aluminum is a good light reflector in the visible, and gold excels in the infrared. Platinum and palladium are two very stable materials for electrochemistry, though their fabrication entails some added complexity. • Gold, platinum, and iridium are good choices for microelectrodes, used in electrochemistry and in sensing biopotentials. Silver is also useful in electrochemistry. • Chromium, titanium, and titanium-tungsten are frequently used as very thin (5–20 nm) adhesion layers for metals that have poor adhesion to silicon, silicon dioxide, and silicon nitride. • Metal bilayers consisting of an adhesion layer (e.g., chromium) and an intermediate nickel or platinum layer are normally used to solder with silver-tin or tin-lead alloys. For applications requiring transparent electrodes, such as liquid crystal displays, indium-tin-oxide (ITO) meets the requirements. • Finally, Permalloy™ has been explored as a material for thin magnetic cores. Polymers • Polymers, in the form of polyimides or photoresist, can be deposited with varying thicknesses from a few nanometers to hundreds of microns. • Spin-on organic polymers are generally limited in their application as a permanent part of MEMS devices because they shrink substantially as the solvent evaporates, and because they cannot sustain temperatures above 200°C. • Because of their unique absorption and adsorption properties, polymers have gained acceptance in the sensing of chemical gases and humidity [7]. Glass and Fused Quartz Substrates • Micromachining of glass and fused quartz (amorphous silicon dioxide) substrates is practical in special applications, such as when an optically transparent or an electrically insulating substrate is required. • Crystalline quartz (as opposed to fused quartz) also has the distinct property of being piezoelectric and is used for some MEMS devices. However, micromachining of glass or quartz is limited in scope relative to silicon. Etching in HF or ultrasonic drilling typically yields coarsely defined features with poor edge control. Thin metal films can be readily deposited on glass or quartz substrates and defined using standard lithographic techniques. • Channels microfabricated in glass substrates with thin metal microelectrodes have been useful in making capillaries for miniaturized biochemical analysis systems. Silicon Carbide and Diamond • Silicon carbide and diamond continue to captivate the imagination of many in the micromachining community. • Both materials offer significant advantages, in particular hardness, high stiffness (high Young’s modulus), resistance to harsh chemical environments, mechanical stability at high temperature, wide bandgap, and very high thermal conductivity. • An important feature of both silicon carbide and diamond is that they exhibit piezoresistive properties. • High temperature pressure sensors in silicon carbide substrates have been developed with stable operation up to about 500°C. What Is Micromachining? • Micromachining is the set of design and fabrication tools that precisely machine and form structures and elements at a scale well below the limits of our human perceptive faculties—the microscale. • Micromachining is the underlying foundation of MEMS fabrication; it is the toolbox of MEMS. Basic microfabrication technologies • Deposition – Chemical vapor deposition (CVD/PECVD/LPCVD) – Epitaxy – Oxidation – Evaporation – Sputtering – Spin-on methods • Etching – Wet chemical etching • Istropic • Anisotropic – Dry etching • Plasma etch • Reactive Ion etch (RIE, DRIE) • Patterning – Photolithography – X-ray lithography • Epitaxy, sputtering, evaporation, chemical-vapor deposition, and spin-on methods are common techniques used to deposit uniform layers of semiconductors, metals, insulators, and polymers. • Lithography is a photographic process for printing images onto a layer of photosensitive polymer (photoresist) that is subsequently used as a protective mask against etching. • Wet and dry etching, including deep reactive ion etching, form the essential process base to selectively remove material. Types: • Isotropic etchants etch uniformly in all directions, resulting in rounded cross sectional features. • Anisotropic etchants etch in some directions preferentially over others, resulting in trenches or cavities delineated by flat and well defined surfaces, which need not be perpendicular to the surface of the wafer. . The etch medium (wet versus dry) plays a role in selecting a suitable etch method. Wet etchants in aqueous solution offer the advantage of lowcost batch fabrication—25 to 50 100-mm-diameter wafers can be etched simultaneously—and can be either of the isotropic or anisotropic type. Dry etching involves the use of reactant gases, usually in a lowpressure plasma, but non plasma gas-phase etching is also used to a small degree. It can be isotropic or vertical. The equipment for dry etching is specialized and requires the plumbing of ultra-clean pipes to bring high purity reactant gases into the vacuum chamber Three Techniques of Micromachining • Surface Micromachining • Bulk Micromachining • LIGA Bulk micromachining Anisotropic etch of {100} Si 111 a 0.707a 54.74º Surface Micromachining substrate Important issues: • selectivity of structural, sacrificial and substrate materials • stress of structural material • stiction Surface Micromachining Most commonly used materials for surface micromachining: • substrate: silicon • sacrificial material: SiO2 or phosphosilicate glass (PSG) • structural material: polysilicon Alternative materials Substrates Sacrificial Structural Glass Plastic metals Polymer Metals silicon nitride Thin film silicon (a-Si:H, c-Si) silicon nitrides Silicon carbide Metals polymers bilayer composites LIGA – X-ray Lithography, Electroplating (Galvanoformung), Molding (Abformung) Remove mold Immerse in chemical bath and electroplate the metal Expose and develop photoresist Deposit photoresist Deposit plating base LIGA Photos from MCNC – MEMS group MEMS Resources Reference Books • Nadim Maluf, An Introduction to Microelectromechanical Engineering (Artech House, Boston,2000) • M. Elewenspoek and R. Wiegerink, Mechanical Microsensors (Springer-Verlag, 2001) • Héctor J. De Los Santos, Introduction to Microelectromechanical (MEM) Microwave Systems (Artech House, Boston, 1999) Websites • Sandia National Lab: http://mems.sandia.gov • Berkeley Sensors and Actuators Center: http://www-bsac.eecs.berkeley.edu • MEMS Clearinghouse: http://www.memsnet.org/ Some companies with MEMS products • Accelerometers – Analog Devices: http://www.analog.com/technology/mems/index.html • Digital Light Processing Projector- Texas Instruments: http://www.dlp.com • Micro-electrophoresis chip – Caliper Technologies: http://www.calipertech.com NEMS and Nanotechnology • Nanotechnology – manipulation of matter at the nanometer scale. • Nanomaterials – Started with carbon. – Behavior depends on morphology. Figure: Eight allotropes of carbon: Diamond, graphite, lonsdaleite, C60, C540, C70, amorphous carbon and carbon nanotube Micro and Nanotechnologies for Sensors Quantum dots are just as awesome as we’d hoped • • A new way to measure the efficiency of quantum dots could get them into things like solar cells and electronics faster. BY TAYLOR KUBOTA-STANFORD APR 11, 2019 Quantum Dots • Quantum dots—tiny, easy-to-produce particles—may soon take the place of more expensive single crystal semiconductors in advanced electronics found in solar panels, camera sensors, and medical imaging tools. • Although quantum dots have begun to break into the consumer market—in the form of quantum dot TVs—longstanding uncertainties about their quality have hampered their adoption. • “Traditional semiconductors are single crystals, grown in vacuum under special conditions. These we can make in large numbers, in flask, in a lab and we’ve shown they are as good as the best single crystals,” says co-lead author David Hanifi, a graduate student in chemistry at Stanford University. NEMS and Nanotechnology, Continued • Quantum dots • Nanowires • Quantum films https://www.youtu be.com/watch?v= 0EokkhdppgE Figure: Quantum Dots. ‘Giant leap’ • The measurement technique could lead to the development of new technologies and materials that require knowing the efficiency of our semiconductors to a painstaking degree, says Paul Alivisatos, professor of nanoscience and nanotechnology at the University of California, Berkeley. • “We want to measure emission efficiencies in the realm of 99.9 to 99.999 percent…” • “These materials are so efficient that existing measurements were not capable of quantifying just how good they are. This is a giant leap forward,” says Alivisatos. • “It may someday enable applications that require materials with luminescence efficiency well above 99 percent, most of which haven’t been invented yet.” Quantum dots from coal are a promising antioxidant • Quantum dots could make a great antioxidant to treat people who've had brain injuries, heart attacks, or strokes. Quantum dots from coal are a promising antioxidant • Graphene quantum dots drawn from common coal may be the basis for an effective antioxidant for treating traumatic brain injuries, strokes, or heart attacks. • Quantum dots are semiconducting materials small enough to exhibit quantum mechanical properties that only appear at the nanoscale. • The Tour lab first extracted quantum dots from coal in 2013 and reported on their potential for medical imaging, sensing, electronic, and photovoltaic applications. A subsequent study showed how they can be engineered for specific semiconducting properties.