THE PERIODIC TABLE AND THE ELEMENTS Mr. Broomfield Chemistry _ CSEC Cayman Academy THE PERIODIC TABLE AND THE ELEMENTS What is the periodic table ? What information is obtained from the table ? How can elemental properties be predicted base on the PT ? THE PERIODIC TABLE OF ELEMENTS A CHART THAT ORGANIZES THE ELEMENTS ACCORDING TO THEIR ATOMIC NUMBER DMITRI MENDELEEV (1869) In 1869 Mendeleev and Lothar Meyer (Germany) published periodic tables based on the similarity of properties and reactivities exhibited by certain elements. Later, Henri Moseley (England,1887-1915) established a periodic table based on atomic number. Mendeleev’s Published Periodic Table of Elements Why do you think there are question marks here? Image taken from: http://www.chemsoc.org/networks/learnnet/periodictable/post16/develop/mendeleev.htm Columns of elements What are columns of elements called? 1 2 groups 3 4 5 6 7 0 Rows of elements What are rows of elements called? periods 1 2 3 4 5 6 7 The Periodic Table Parts Groups 3 CLASSES OF ELEMENTS 1. Metals: to the left of the zig-zag line 2. Metalloids: border zig-zag 3. Non-metals: are to the right of zig-zag Non-metals Metalloids Metals Transition Metals METALS Location Found on the left of the zigzag line/staircase on the periodic table (exception Hydrogen) 79 Au 196.967 Chemical Properties Have few electrons in their outer energy level, thus lose electrons easily 11 Na 22.990 Physical Properties ductile, good conductors, malleable, shiny, most are solid @ room temperature What metal is not a solid @ room temperature? NON-METALS Location Most found to the right of the zigzag line/staircase on the periodic table 17 Cl 35.453 Chemical Properties Most have almost full outer energy levels, thus they tend to gain electrons; some have completely full outer level Image taken from: http://nobel.scas.bcit.ca/resource/ptable/cl.htm Physical Properties not ductile or malleable, not shiny, poor conductors, most are solid, but some are gas at room temperature 16 S 32.066 Image taken from: https://www.dmr.nd.gov/ndgs/rockandmineral/sulfur.asp METALLOIDS Location Border the zigzag line/staircase on the periodic table Chemical Properties Most atoms have ½ (≈) complete set of electrons in outer level Physical Properties have properties of both metals and non-metals 14 Si 28.086 Image taken from: http://library.thinkquest.org/C0113863/bios.shtml 5 B 10.811 Image taken from: http://library.thinkquest.org/C0113863/bios.shtml Metals Left of zig-zag Generally <3 e’s in outermost shell (except Sn,Pb,Bi) High m.p., b.p., density -Most are good conductors, ductile, malleable solid at room temp (except Hg) Metalloids Border zig-zag Outer shell about ½ full (3-6 e’s in outer shell) Non-Metals Right of zig-zag >5 e’s in outer shell (Carbon has 4) Low m.p., b.p.,density Properties of both Dull, brittle, poor metals and non- conductors metals More than ½ are gases at room temp, bromine is liquid Patterns: physical state Where are elements of different states grouped in the periodic table? solids on the left, in the centre and on the right liquids in the middle and on the right gases on the far right (except hydrogen) Only two elements are liquids at room temperature. What are they? bromine and mercury The Periodic Table Parts Elements in the same period have the same number of electron shells Groups Elements in the same group have the same number of valence electrons GROUPS – COLUMNS OF PT Elements in the same group have similar chemical and physical properties!! (Mendeleev did that on purpose.) Why?? • They have the same number of outer-shell (valence) electrons. • If the groups are numbered 1-8 (skip transition metals) the group number = # e’s in outer shell). Groups/Families of the Periodic Table Alkali Metals •Most Reactive Metals •Always found bonded with other elements Alkaline Earth Metals •Very Reactive •Always found bonded with other elements Groups/Families of the Periodic Table Carbon Family •Contains metals, non-metals and metalloids. •Carbon is found in all living things Groups/Families of the Periodic Table Nitrogen Family •Contains metals, non-metals and metalloids. •Nitrogen is found in the air Groups/Families of the Periodic Table Oxygen Family •Oxygen is very reactive •Animals breathe in oxygen Groups/Families of the Periodic Table Halogen Family •Very Reactive Always found combined with other element in nature . Groups/Families of the Periodic Table Nobel Gases •Very Stable and not reactive •All are found in the air PERIODIC TABLE: THE THREE BROAD CLASSES MAIN, TRANSITION, RARE EARTH Main (Representative), Transition metals, lanthanides and actinides (rare earth) Identifying an Element Given the Group and Period Number Name the element found in: group 4, period 3 1 2 1 2 group 0, period 1 group 2, period 4 Periods group 7, period 5 3 4 5 6 7 Groups 3 4 5 6 7 0 Exam-Style Questions Bronze: The element magnesium has 12 electrons. State magnesium’s group number and show o how you could prove your answer is correct. (2 marks). Group 2 Exam-Style Questions Silver: Part of Mendeleev’s periodic table is shown below. Group I Group ll Group lll Group IV Group V Group VI Group VII Li Be B C N O F Na Mg Al Si P S Cl Ti V Group VIII H i. Give the symbols of two elements that Mendeleev placed in group 2 which are not found in group 2 today.(2 marks) o K Ca Cu Rb Zn Sr Ag Cr As Y Zr Cd Nb Sn Mn Se Mo Sb In ii. Name these two elements. (2 marks) iii. Mendeleev left gaps in his periodic table. Explain why. (1 mark) iv. How are elements arranged in today’s periodic table? (1 mark) I Te Fe Co Ni Br Ru Rn Pd Q & A Exam-Style Questions Gold: The periodic table, as we know it today, is very different from theo early published periodic tables. Discuss how the periodic table has changed and, where possible, name the scientists involved. Your answer should be in chronological order. (4 marks) Students’ answers may vary. • 1817, Johann Dobereiner and his Law of Triads. Placed elements into groups of 3 based on appearance and similar reactions. • 1864, John Newlands and his Law of Octaves. Arranged elements in order of atomic mass and suggested that each element was similar to the element eight places further on. • 1869, Dmitri Mendeleev. Placed elements in order of atomic mass but left spaces for undiscovered elements. Mendeleev wasn’t afraid to switch elements around in the table.