School of Engineering and the Built Environment Honours Project (Engineering) MHH623549 Project Title: “The Use and Accuracy of the Arrhenius Equation in Electrical Plant Lifespan Predictions” Programme/Option: Electrical Power Engineering (Hons) Author: Lee Manson Student Number: S1631921 Supervisor(s): Dr Geraint Bevan Non-Disclosure Agreement: Yes / No. Except where explicitly stated all work in this report, including the appendices, is my own Signed: Date: 25/04/2019 ABSTRACT The Author was seeking to investigate the use and accuracy of the Arrhenius equation in estimating the remaining useful lifespan of electrical insulation. This is common industry practice, which is shown in the real-world application completed within, and it is used throughout international and national standards. To verify a relationship and check the accuracy of it, a practical experiment was attempted which accelerated the ageing of polyvinylchloride cable insulation to trend a practical lifespan focused on the effects of thermal stress only, which is deemed to be the dominant stress in electrical installations. Then a calculated Arrhenius estimation was completed for comparison to the practical experiment results. This proved to be inconclusive due to the main properties and changes seen in the ageing of polyvinylchloride insulation, which are mechanical rather than electrical, and due to the time and budget constraint’s to the investigation these mechanical/chemical changes were not tested or trended which led to a less than accurate practical estimation. The author concludes that whilst there is an observable and measurable change within the materials which appears to follow a linear pattern related to the temperature and time used, and in essence this describes the Arrhenius relationship, the experiment completed for this project has been unable to comprehensively prove this relationship and therefore has not checked the accuracy of using it in these estimations. The author then proceeds to highlight future work that is required to be done to complete the goal of this investigation. Page | i ACKNOWLEDGEMENTS I would like to take the opportunity to acknowledge help and support given to me during the completion of this report (and the degree) that marks a seven-year journey from college to university, and with that in mind I would like to thank all the lecturers and staff that have helped me get to this point, from Glasgow Kelvin College (Springburn) and GCU. A few people deserve special mention such as George McGuire who gave me a second chance after my biggest setback during my 1st HNC attempt, and from Springburn also -Fraser, Brian, Faris, Parky, Nirmal etc. who all went the extra mile in assisting me, from GCU I have received lots of help from Michelle McCourt in SEBE support particularly during my Industrial Placement with EDF Energy and Dr Geraint Bevan who has made this year achievable even though it has by far been the toughest yet, his calming influence helped talk me off a metaphorical ledge time and again. From EDF Energy I’d like to thank the Electrical Group Team who have all offered advice and help at some stage over the last year. A special mention goes to Dougie McIntosh, my Group/Branch Head who has been very understanding of my part time student requirements and helped me with my project topic and Sean O’Neill who has been a great source of advice whilst having to sit next to me and listen to all my gripes and moans. To all my friends, I appreciate the understanding and support you have all given me these last few years, in particular - Dave Mulholland and John Hodgson who was my boss all my time at college when I struggled with deadlines and the demand of full-time study and 20/30 hours of work a week. Thanks to my Mum, Brothers and Sisters who have been patient with me having had to listen to all of my moaning about the workload (see the pattern). To my friend and study partner for the last five years, Michael Gilfeather, thanks for keeping me going, especially during our 3rd year (which was a shock to the system coming to university from college). It’s been tough at times for both of us but now we are working in this field and starting to reap the benefits of all these choices we have made, I hope to continue this path and we can both see the rewards for finally eating that bloody elephant. Cheers Mate! To Keith and Chris who have been incredibly supportive during my studies, helping whenever possible especially with the girls, I want to say a big thanks. You do for family as we say but it’s always appreciated and hopefully reciprocated. Finally, the biggest thanks and recognition goes to my loving partner Sheena and my daughters Sophie, Hannah and Katie. Without you I would not have been able to accomplish any of this and you have all sacrificed for my choices over these years, so I hope I can repay that support and faith. I love you all so much and I promise no more academic study! Page | ii TABLE OF CONTENTS ABSTRACT ............................................................................................................................................... i ACKNOWLEDGEMENTS ...................................................................................................................... ii FIGURES .................................................................................................................................................. 4 TABLES ................................................................................................................................................... 5 ABBREVIATIONS ................................................................................................................................... 6 1 INTRODUCTION ..................................................................................................................... 7 2 SCOPE ....................................................................................................................................... 9 3 THE ARRHENIUS EQUATION AND REAL-LIFE ENGINEERING ................................... 9 3.1 LITERATURE REVIEW ...................................................................................................... 9 3.1.1 The Origins of the Arrhenius Equation .............................................................................. 9 3.1.2 Electrical Insulation & the Arrhenius Equation ............................................................... 10 3.1.3 Nuclear Qualification & Remaining Life Prediction ....................................................... 11 3.1.4 Rotating Machines & Stresses ......................................................................................... 12 3.1.5 Literature Review Summation ......................................................................................... 12 3.2 REAL WORLD ARRHENIUS APPLICATION ................................................................ 13 3.2.1 Arrhenius Equation Input Parameters (HNB 11kv Motor Stator Windings) ................... 15 3.2.2 Operational Data and Determination of Main Motor Winding Temperature Profiles ..... 17 3.2.3 Calculation Method For Thermal Life Expired Based on the Arrhenius Equation ......... 19 Page | 1 3.2.4 Calculated Thermal Life .................................................................................................. 20 3.2.5 Temperature Profile Charts .............................................................................................. 21 3.2.6 Operation in Normal Conditions ...................................................................................... 23 3.2.7 Operation in Outage Conditions at Elevated Temperatures ............................................. 24 3.2.8 Discussions of 11kV Motor Evaluation ........................................................................... 25 3.2.9 Recommendations of 11kV Motor Evaluation (Purss & Manson, 2018) ........................ 28 3.3 PRACTICAL EXPERIMENT ............................................................................................. 29 3.3.1 Cable Specifications......................................................................................................... 29 3.3.2 Methodology .................................................................................................................... 30 3.3.3 AGEING & TESTING .................................................................................................... 31 3.3.4 RESULTS ........................................................................................................................ 34 4 DISCUSSION .......................................................................................................................... 41 5 CONCLUSIONS AND FURTHER WORK............................................................................ 42 6 REFERENCES ........................................................................................................................ 44 7 BIBLIOGRAPHY .................................................................................................................... 46 8 APPENDICES ......................................................................................................................... 47 8.1 Appendix A – HYB/TOR 11kV motor stator ageing test programme and applicability of results to HNB/HPB 11kV motors. ...................................................................................... 47 8.2 Appendix B – Base Data from HYB/TOR 11kV Motor Lifetime R&D Project ................. 50 8.3 Appendix C – Data Analysis Results (valid August 2018) .................................................. 51 Page | 2 8.4 Appendix D - Case study STATOR 12 versus STATOR 12.2 ............................................ 52 8.5 Appendix E - % Thermal Life Expired Charts .................................................................... 54 8.6 Appendix F – 11kV Motor Stator Thermal Life Going Forward by Reactor Location ....... 73 8.7 Appendix G – Details from BS EN 60216-8:2013 Suggested Temperatures and durations for accelerated ageing tests. ................................................................................................. 74 8.8 Appendix H – Excel Data capture from Calculated Arrhenius Service Levels ................... 75 Page | 3 FIGURES Figure 1 - Cable Ageing Samples – 1m and 5 m coils ............................................................................ 32 Figure 2 - Electrical Test Circuit ............................................................................................................. 32 Figure 4 - Week 1 @ 120 degrees Celsius .............................................................................................. 35 Figure 3 - Week 2 @ 120 degrees Celsius .............................................................................................. 35 Figure 5 - Week 3 @ 120 degrees Celsius .............................................................................................. 35 Figure 6 - Week 5 @ 120 degrees Celsius .............................................................................................. 36 Figure 7 - Week 4 @ 120 degrees Celsius .............................................................................................. 36 Figure 8 - Week 6 @ 120 degrees Celsius .............................................................................................. 36 Figure 9 - Week 7 @ 120 degrees Celsius .............................................................................................. 37 Figure 10 - Thermal Capture of Sample from beginning to end (aged @ 120 degrees Celsius for 7 weeks). ..................................................................................................................................... 39 Figure 11 - Electrical Test Circuit and Thermal Capture ........................................................................ 39 Figure 12 - Arrhenius Equation Variation used to calculate service time @ rated temperatures ............ 41 Figure 13 - Service life @ Ea = 60 kj/mol .............................................................................................. 75 Figure 14 - Service life @ Ea = 130 kj/mol ............................................................................................ 75 Page | 4 TABLES Table 1 - Simplified Example ................................................................................................................. 19 Table 2 - Stators >70% Thermal Life Expired ........................................................................................ 20 Table 3 - Winding Temperature vs. % Thermal Life Expired................................................................. 23 Table 4 - R3 Outage 2015 / R4 Outage 2017 .......................................................................................... 25 Table 5 - Testing Temperatures & Approximate Lifespan of Insulation ................................................ 31 Table 6 - Tactile Inspection Notes .......................................................................................................... 34 Table 7 - Weight loss over 8-week period/two temperatures .................................................................. 38 Table 8 - Suggested exposure temperatures and times ............................................................................ 74 Page | 5 ABBREVIATIONS A AGR CO2 EDFE EPR eV GCU HNB HPB hrs HSE HV HYB IEEE IR K kj/mol kV kW m MΩ NDA OIP PLEX PVC RCD rpm SFE TOR XLPE Page | 6 Amperes Advanced Gas-cooled Reactor Carbon Dioxide EDF Energy Ethylene Propylene Rubber electron Volt Glasgow Caledonian University Hunterston B Power Station Hinkley Point B Power Station Hours Health & Safety Executive High Voltage Heysham 2 Power Station Institute of Electrical and Electronics Engineers Insulation Resistance Kelvins Kilo joules per mol kilo Volt kilo Watt Metres Mega Ohms Non-Disclosure Agreement Oil Impregnated Paper Insulation Plant Life Extension Polyvinylchloride Residual Current Device Revs per minute Super Fluid Extraction Torness Power Station Cross-Linked Polyethylene 1 INTRODUCTION Electrical Plant such as transformers, cables and motors all have electrical insulation within their construction. This insulation is used to protect the electrical circuit from leakage currents, to protect anyone working on or located near the circuit and it provides an element of mechanical protection. There are many different types of material used in the construction of electrical insulation but they all have one thing in common – they restrict the flow of current in an electrical circuit by having very high impedance. A perfect insulator would completely inhibit the flow of current but, due to minor imperfections and small amounts of charge carrying materials located within, a perfect insulator is impossible to manufacture therefore materials with a very high resistivity are used. From the UK government’s Health and Safety Executive the following information can be found, the home page for the HSE website states “Electricity is a familiar and necessary part of everyday life, but electricity can kill or severely injure people and cause damage to property.” From this statement, which features prominently within the advice given, the priority given on electrical safety is people first then property. As mentioned above electrical insulation is used to provide protection in both cases. Due to the physical laws of electricity, specifically Maxwell’s equations for magnetic force and Faradays equations for electric field theory, when you are dealing with large amounts of power, which consists of high levels of voltage and current, physically large electrical plant is required to handle the electrical and magnetic stress and this investment in plant is expensive, not to mention the large amounts of investment seen in the transportation of electrical power over large distances. Once an electrical system has been designed, considering that it needs to be safe and as efficient as is practicable, it is then put into service to generate, transport and deliver electrical power to the consumer or ‘load’. At this point manufacturers will have defined a maximum useful lifespan of the cable, generator or motor etc. before it is no longer capable of safely and efficiently delivering the power required and this time limit will be based on rigorous testing performed during its design. The lifespan given by the manufacturers after this testing will be on the cautious side such as the minimum lifespan seen from all the samples tested, this is to ensure safety when operating and to protect the manufacturers from any litigation based on figures given to customers being too generous. The data given is fine in a laboratory setting however in the real-world environment the plant usually does not see constant, continuous load. Often the service life of the plant item is dynamic, which is to say that it experiences cyclical or random levels of loads and ambient/ environmental conditions. To address this uncertainty and to take full commercial advantage of the investment in the plant there are a variety of maintenance plans adopted to ensure that the plant continues to be safe and efficient for as long as possible. The maintenance plans used in industry are routinely scheduled (planned maintenance), condition based (condition monitoring) or reliability centred maintenance (predictive maintenance) that seek to address any potential issues seen by the plant due to different types of stress in service and extend the lifespan whenever it is safe to do so. As with most engineering solutions each of these types of maintenance plans have pros and cons related to them which will not be discussed within the scope of this investigation. Page | 7 Generally, this report will focus on predictive maintenance plans as this is the most common trend adopted by engineers due to the relatively low amount of financial investment required to adhere to it. Specifically, the report will investigate a predictive calculation that is used in a variety of industries (and has been for decades) to provide an accurate lifespan for materials that encounter thermal stress during service whether normal or abnormal and seeks to explain the mechanical/chemical breakdown of these materials, this calculation is called the Arrhenius Equation after the engineer who brought it to prominence. The use of the Arrhenius equation in predictive maintenance has been chosen as the focus of this report as thermal breakdown has long been accepted as one of the dominant factors in ageing of electrical plant, whether that thermal stress comes from ambient (environmental) temperatures or from within the conductors (Ohmic heating or ‘Copper Losses’). How this report will investigate the Arrhenius Equation can be seen in Section 2. Page | 8 2 SCOPE This report will investigate the use and accuracy of the Arrhenius equation in electrical engineering. To achieve this it will investigate current literature regarding the subject matter and include the equations in use from inception until present day, there will be an example of a real-world engineering problem from a nuclear power plant that is utilising the Arrhenius equation, with details from the author’s employer EDF Energy (EDFE), and there will be a practical experiment on low voltage cables to check the accuracy of the Arrhenius equation which the report will critically analyse and present the results. Finally, there will be a conclusion on the use and accuracy of the Arrhenius equation which will provide an idea of how successful the investigation was and any future work that could be completed which would improve upon the investigation. 3 3.1 THE ARRHENIUS EQUATION AND REAL-LIFE ENGINEERING LITERATURE REVIEW 3.1.1 The Origins of the Arrhenius Equation A search using IEEE Xplore database provides the extensive list of journals, standards and reports that discuss the Arrhenius Equation in the context of engineering. These include the modelling of brain tissue heating caused by direct cortical stimulation and the estimation of maximum operating temperatures for copper wire bonds, this shows that the various uses of the Arrhenius equation are not necessarily involving the electrical aspect. Svante August Arrhenius whose name the equation bears was in fact a physicist who received the Nobel Prize for chemistry in 1903. The Arrhenius Equation has been used in the study of kinetic energy and chemical reactions since the mid nineteenth century. Arrhenius, and other scientists of the time such as (van't Hoff, M. J. H., 1884) and (Hood, 1885), realised that there was a noticeable dependence on temperature for chemical reaction rates. This is shown in (Logan, 1982) which states “…and in 1889 Arrhenius showed that temperature and rate constant could be correlated by one simple equation, which still bears his name…”. The most familiar form of that equation is: 𝐄 𝐤 = 𝐀. 𝐞−(𝐑.𝐓) Where, k = is the rate constant in units depending on the global order of reaction A= the pre-exponential factor, a constant for each chemical reaction E = the activation energy in kilo-joules per mol R = the universal gas constant in kilo-joules per kelvin per mol T = absolute temperature in kelvin e = Euler’s constant Page | 9 3.1.2 Electrical Insulation & the Arrhenius Equation From this earlier work up to modern times there is rarely a journal article, paper or standard surrounding thermal ageing or stress in electrical plant/machines that doesn’t directly or indirectly reference the Arrhenius equation. This shows just how important the work was and since the widespread inclusion of electricity into modern life, and the plant and machines that come with it, there have been investigations into ageing mechanisms for insulation materials. Operational experience shared amongst engineers during the early years of electrical power distribution showed a possible correlation between thermal stress and lifespan, but it was not really until 1930 when Montsinger established the 8-Degree Rule of Thumb, that industry noticed the benefits that could be achieved using the Arrhenius equation (or work based upon it). Paper (Montsinger, 1930) stated “It is shown by the use of the thermal laws that without increasing the maximum or hot spot temperature, transformers can be overloaded 1 per cent for each degree centigrade by which the ambient is below 30°C (air) for self-cooled transformers, 25°C (water) for water-cooled transformers.” Also quoted is the more common “These tests show that the rate of aging is roughly double for each 8°C increase in temperature.” Once this theory was established this became the industry standard for evaluating the remaining lifespan for electrical plant such as transformers, cables and motors to aid in the planning of maintenance and potential replacements and whilst not the only method available to engineers it is still widely in use for guidance in estimating plant lifespan. This theory developed further when in 1948 Thomas W. Dakin proposed the paper “Electrical Insulation Deterioration Treated as a Chemical Rate Phenomenon” (Dakin, 1948). In this paper Dakin examined changes in electrical/physical properties of electrical insulation and proposed a method of interpreting them during thermal ageing related stress. It also discussed the forms of deterioration within insulation such as slow oxidation, brittle hardening of insulation due to loss of plasticiser and excessive cross linking of polymer chains and a purely thermal or internally depolymerisation of plastic insulation. Dakin’s method assumed that the observed changes are resulting from internal reactions that obey theoretical laws and that is it possible to know the reason for electrical failure, i.e. a short circuit that is usually in the form of mechanical failure due to lower strength or flexibility. Dakin states in (Dakin, 1948) that “it is important to note that the absolute temperature scale is used, consequently the temperature intervals at higher temperatures have, percentagewise, less effect on a reaction than the same temperature intervals at a lower temperature. This fact is neglected in the commonly used rule of thumb, where the temperature interval for which a reaction rate doubles is used” As can be seen within more modern approaches, such as (Duran & Duarte, 2012) when attempting to assess the lifespan of electrical plant or machines there are a few steps to ensure the estimation is as accurate as practicable. Firstly, a list of the assets to be evaluated is collated Page | 10 then secondly, all the potential stresses that plant may see in normal and fault conditions are listed and finally the various methods for estimation are identified. Paper (Duran & Duarte, 2012) also states “In 1948 T. W. Dakin published some articles which raised a more precise mathematical expression to calculate the deterioration of the insulation from the Arrhenius equation.” The list of estimation methods investigated in (Duran & Duarte, 2012) are listed below; The Accelerated Ageing Factor (FAA) for thermally or non-thermally upgraded dielectric materials (British Standards Institute, 2018; IEEE, 2012) (based on the Arrhenius equation and Dakin’s proposition). Ageing due to number of operation cycles (Kam & Ledwich, 2009) which applies mainly to switching and protection equipment. The Delta-T criteria (Lindquist, Bertling & Eriksson, 2005), which evaluates the temperature increase in the contacts of electrical equipment by constant current flow. Two-parameter Weibull distribution to model dielectric materials ageing (Stone & Lawless, 1979) This work from (Dakin, 1948) and (Duran & Duarte, 2012) highlight the common use of the Arrhenius equation, and Dakin’s proposition based on it, in the estimation of the lifespan of electrical insulation when it is experiencing thermal stress. 3.1.3 Nuclear Qualification & Remaining Life Prediction As seen in (Robertson & Lamont, 2015) , The first commercial nuclear reactors were developed in the 1950’s which was the generation-1 reactors, and since the late 70’s- early 80’s the generation 2 reactors, advance gas-cooled reactors (AGRs) in the UK, have been connected to the grid generating electricity. There are many ageing mechanisms as previously discussed, and the same mechanisms apply to any nuclear power plant, but there is also the presence of ionising radiation in certain areas of the plant, within the reactor and any fuel storage or preparation area. As stated in (Banford & Fouracre, 1999) “it is of major importance to know how these materials will respond and how any resulting ageing phenomena can be monitored”. Insulation types that are most commonly found in cables used in nuclear power stations are Polyvinyl chloride (PVC), Cross-linked polyethylene (XLPE), ethylene propylene rubber (EPR) amongst others which are based on polymers. This is of interest as this type of accelerated ageing due to dose rate of ionising radiation influences electrical insulation, however due to the difficulty in obtaining radioactive material for testing purposes the effects of radiation have had to be excluded from this experiment, this will be mentioned in the further work section within the main body of the report. Page | 11 3.1.4 Rotating Machines & Stresses Paper (Brancato, 1978) states that the role of insulation is to withstand stress, separating the conductors from the outside environment and protecting the circuit, people and the system. This stress that can be seen is multifactor, as mentioned in Section 1, and one final type of aging mechanism or stress is vibration. Rotating machines by their very nature encounter vibration, this is due to the specific nature of motors, pumps or generators etc. which is to rotate at great speeds, for example 3000 revs per minute (rpm) for any electrical generator in the UK. This rotating causes vibration and whilst this investigation is focusing on thermal stress, the real-world application example will investigate 11kV induction motors, the reason for which will be discussed further in Section 3.2, therefore it is necessary to note that these motors experience a lot of stress due to the location and environment they are situated in. Vibration in electrical equipment can sometimes be tolerated, particularly in rotating machines however, large amounts of vibration can indicate that there are problems or deterioration of the equipment, electrical insulation in most modern machines comprises layers of oil impregnated paper or cast resin and when there are contaminants within the layers or poor manufacturing practices then the final product is imperfect. These imperfections can become worse brought about by constant vibration and the potential for resonance when the frequency of the vibration resonates with the materials and contributes to overall damage. 3.1.5 Literature Review Summation Paper (IEEE, 2014) section 4 discusses the various stressors seen by electrical plant, whether environmental or operational and that a typical concern is the potential for synergistic effects between temperature and radiation in some polymers, which is to say that the effects for thermal and radiation caused degradation can combine to be greater than the sum of the individual effects. Within the further work section of this project report these ageing mechanisms will be considered, but for the purposes of this investigation the main stresses experienced by the motors, and the possible detrimental effects caused by them, will be listed here: Mechanical (including vibration seen at full speed 3000rpm) – this can loosen fasteners on linkages causing loss of electrical contact integrity and possible heatrelated degradation from the poor connections, it also causes wear in moving parts due to misalignment. It can be mitigated for in the design stage and monitored for in a condition-based maintenance regime to trend Electrical (caused by the 11kV, 3 phase supply) – this is from the strength of the electrical field flowing through the conductors and insulation causing mechanical stress – again this can be mitigated in the design stage with conservative estimates, meaning the conductors and insulators have adequate electrical field strength. Page | 12 CO2 gas atmosphere (instead of air) – this hasn’t been fully investigated other than to assume that an air atmosphere at varying pressures is more onerous due to oxidation effects on the plant, therefore testing in air provides further conservatisms in the design stage which mitigates these effects. Doses of Ionising Radiation – in (Brancato, 1991), Brancato states “although radiation does tend to deteriorate insulation, in mild environments where the total dose absorbed during the lifetime of the equipment does not exceed 10,000 rads there appears to be no perceptible effects on the insulation lifetime expectancy.” It’s worth noting that in the context of Brancato’s report he was discussing plastics in general. Thermal (both from ambient heating and from Ohmic heating) - (Brancato, 1991) also states that “the electrical endurance qualities of insulation materials are affected by temperature and time. Relatively moderate temperatures can cause failure if applied for very long periods of time”. For example, if a cable had been poorly specified or the load connected is increased without thought to overloading, this increased current will cause more heat to be generated, without an insulation system sufficient enough to take this heat away it will deteriorate the insulation quicker than expected leading to spurious tripping of protection devices or even destructive faults such as a short circuit. Of these stresses, from experience over 40 years of service, EDF Energy has determined that the most onerous of these stresses are the Thermal stresses, High pressure differences and the ionising radiation from the reactor core. 3.2 REAL WORLD ARRHENIUS APPLICATION In the early 2000’s all of the Advanced Gas Cooled Reactors (AGRs) had their original designed generating life extended due to the condition of the plant and ancillary systems. Paper (Banford & Fouracre, 1999) states that “There is a general desire to continue operating the nuclear power stations for as long as possible. To do so, however, the utilities must convince the relevant regulatory authorities, as well as themselves, that continued operations are acceptably safe”. This work was completed to ensure plant life extension (PLEX) was not only safe but commercially viable. Now, nearing decommissioning, the same utility companies are looking at similar work to ensure that any major work that would be routinely completed can be deferred due to the plants closure date if it is safe to do so. Two power stations that are due to be decommissioned in 2023 are Hunterston B (HNB) and Hinkley Point B (HPB) power stations and each station have two AGRs onsite. The B moniker indicates that each site has had power stations on site before; these were the 1st generation Magnox stations Hunterston A and Hinkley Point A which are owned and operated by Magnox. As part of the design of the AGRs there were large 11kV electrical induction motors installed for safety use, to ensure that an NDA was not required the specific duty for these 11kV motors has intentionally been omitted however these motors are important to safe and efficient operation of the power station. Page | 13 To qualify an accurate life expectancy when the plant was being designed, and to test the thermal endurance of the motor insulation systems, test models of reduced sizes called ‘motorettes’ were designed using the same materials to scale. These motorettes could be exposed to accelerated ageing mechanisms for investigation giving a realistic approximation of the life sized motors ability and limits and this is discussed in (Brancato, 1978). These motors were rigorously tested using test rigs in the early 80’s and part of these tests were for the motor stator windings and the insulation used. Paper (EDF Energy, 1982) states that the motor stators were tested at an accelerated temperature, voltage and various depressurisation rates, to adequately qualify it for a temperature indices (TI) value of 155°C for 3000 hours, validating its class F rating and giving it a failure time of 20,000 hours at continuous hot spot loading. This equates to approximately 30 years for the motor stators as the average temperature rate is approximately 80°C. At HNB & HPB that 30-year period has since been surpassed due to PLEX and there has been work done to assess the stator windings, using the Arrhenius modelling and all the motor winding temperature data that has been accumulated, to provide a judgement that the motors do not require to be rewound as the 30 year lifespan prediction was for a constant temperature throughout the working life whereas in real-life the motors see a variety of temperatures which are usually much lower than the class F rated temperature. Each rewinding would cost approximately £600,000 and there are over 40 of these motors within the fleet so that would be a substantial outlay for the business so close to decommissioning with a lifespan of only 5 to 10 years required. The report calculated the expired thermal life as a proportion of the substantiated life, using an industry recognised method and took account of any operation at elevated winding temperatures. The thermal life expired profile for each winding is presented and the machines with the highest expired thermal life are identified. This investigation also presents recommendations for 11kV safety motors operation going-forward, including operation in low pressure CO2 and air. Report (Rollo, 2007) states that although the 11kV motors are not considered susceptible to simultaneous common mode failure while operating under normal conditions; abnormal conditions such as would be experienced during a severe depressurisation event would simultaneously expose all 11kV motor winding insulation systems to an increased mechanical stress as the CO2 tries to escape from the winding insulation layers. Under such circumstances common mode failure could occur if the 11kV motors were to be operated beyond their present level of substantiation and it was therefore concluded that the motors are vulnerable to a common mode failure if operated beyond 30 years. Report (Smyth, 2017) presents the results of a recent ageing test programme which extended the substantiated life of the HYB/TOR power station’s 11kV stator windings and in doing so, also extended the capability of the HNB 11kV stator windings as the test pieces and test conditions are considered representative for the HNB motor windings. Page | 14 As discussed previously when looking at conventional air-cooled motors the ageing of winding insulation materials is affected by many factors such as temperature, electrical and mechanical stresses, vibration, and contamination from moisture/dirt/chemicals. In modern insulation systems, high operating temperatures can cause an oxidation reaction (in air-cooled machines) resulting in the chemical bonds in the organic insulation compounds progressively breaking under the thermally induced vibration. When bond breakage occurs, oxygen often attaches to the broken bonds and the reduced bond strength leads to progressive delamination of composite insulation or embrittlement. In the 11kV motors (which normally operate submerged in 40bar Carbon Dioxide, CO2), the mechanisms which cause the insulation systems to age are complex. For example gas pressure cycling is considered to influence insulation delamination and the production of voids, however the windings operate in an oil vapour saturated environment, which results in oil penetrating and filling voids in the insulation (Kennedy, Sterling & Hains, 2008). Compared to conventional machines, it is recognised that 11kV safety motor operation in a non-oxidising CO2 atmosphere is less onerous than an air environment and will lessen the thermal aging affects (Schwarz, 1973). During operation in air, the HNB machines are known to operate with elevated winding temperatures. Although most of these elevated temperatures are below the thermal classification of the 11kV stator insulation system (Thermal Class 155 (F) in accordance with BS EN 60085) they have a considerable influence on thermal life as at high temperatures thermal life is used up at a significantly higher rate, challenging the original assumptions used to support the 30-year substantiated life. As mentioned previously the concept of the “10°C rule of thumb” for insulation thermal ageing calculations is a well-known industry approximation developed following early studies on the relationship between time and temperature and their effect on insulation. The “10°C rule” approximates that the thermal life of the insulation is reduced by one half for each 10°C increase in temperature and that for every 10°C reduction in temperature the insulation thermal life is approximately doubled. However, when material specific Activation Energy (E) values are known, the Arrhenius equation will provide a more accurate prediction of thermal life. The Arrhenius equation is adopted by international standards as the basis for evaluating the thermal performance of electrical insulation materials in air and is used within EDFE to calculate thermal ageing, where the material activation energy (E) is available. For the case where E is unknown, the “10°C rule” remains a useful conservative approximation for calculating thermal ageing. Several input parameters and the E for the HNB 11kV main motor winding insulation are used to calculate the service life (t2) for a range of service temperatures (T2). This, along with operational temperature data from the stations Ferranti Data Logging System allows the proportion of thermal life used to be calculated (expressed throughout this report as the ‘Percentage Thermal Life Expired’). 3.2.1 Arrhenius Equation Input Parameters (HNB 11kv Motor Stator Windings) Service Temperature (T2): Operational data gathered from a Ferranti Data Logging System provides a log of 11kV winding temperatures at a frequency of once per hour for Page | 15 each operational 11kV motor. The assessment and processing of the operational data for use in the thermal ageing calculations is discussed in detail within section 3.2.2 Activation Energy (E): All 11kV stator windings at HNB utilise a Novobond SX insulation system. Report (Rollo, 2016) has determined the E in air for Novobond SX as 1.20 eV. Theory and references indicate ageing in a non-oxidising environment is less onerous than in an air environment. Therefore, using the Arrhenius Equation and the above E value, derived from test conditions in air, to determine the thermal life expired whilst operating in CO2, provides an additional degree of conservatism for the proportion of the thermal life ageing attributed to CO2 operating conditions. This conservatism is not realised in the proportion of thermal ageing when operating in air. The Ageing Temperature (T1) and the Ageing Time (t1) : A test programme has been undertaken recently (Smyth, 2017) which included accelerated ageing of 11kV motorettes and end winding models for a prolonged period, to extend the winding substantiated life to support a 11kV motor winding life extension safety case for TOR and HYB Power Stations. The results detailed within (Smyth, 2017) have been used to provide an equivalent base Ageing Temperature (T1) of 160°C and base Ageing Time (t1) 1777.54hrs for the HNB Novobond SX insulation system, i.e. continuous operation of the insulation system at 160°C would result in its thermal life being 1777.54hrs. All winding thermal life calculations throughout the report used this base data to determine the percentage thermal life expired for each specific 11kV motor operational temperature profile. It should be noted that the accelerated ageing and tests were reported to be completed successfully and there was nothing in the final test and inspection results to suggest that the test pieces could not have undergone further ageing, giving a further extension to the thermal life capability. The calculations throughout this note use operational temperatures to determine a percentage thermal life expired for the HNB 11kVs motors. Assessing the expired (and hence remnant) thermal life in percentage terms is a move away from the current expression of substantiated life in terms of years. This change in emphasis means that the remaining life of the HNB 11kV main motor windings should not be thought of in terms of operational years, but as a percentage figure which will diminish at a variable rate determined by winding operational temperature profile. As such, the author has concluded that careful management of HNB 11kV winding temperatures can be used to prolong the remaining operational life. Page | 16 3.2.2 Operational Data and Determination of Main Motor Winding Temperature Profiles Operational data gathered from the Ferranti Data Logging System and other historical Station Records has been used to assess the percentage of thermal life expired for each of the main 11kV motors. The assessment of percentage thermal life expired for the pre-2001 (pre-Data loggers) operational period is discussed in detail in Section 3.2.3. The records and data provided by Hunterston are assumed to be accurate and correct. The Data Logging System provides a log of 11kV motor stator winding temperatures at a frequency of once per hour for each in service motor. This data has been assessed by the author, see Section 11.5 - Appendix E, looking at the temperatures for HNB Reactors R3 and R4 from June 2001 onwards. R3 Ferranti data analysed – 28/06/2001 to 22/08/2018 R4 Ferranti data analysed – 28/06/2001 to 22/08/2018 The stator winding temperatures logged by Ferranti utilise thermocouples, located between the stator winding conductors in the stator slot, which measure the temperature on the outer surface of the winding insulation. In low pressure CO2 and air at atmospheric conditions, the stator iron (core) losses have the greatest influence on stator winding temperatures. These losses along with the reduced mass coolant flow in low pressure conditions results in the highest stator winding temperatures occurring during operation in air. Under these conditions, at low current levels and therefore low resistance heating of the conductor, the measured temperature at the thermocouple position on the outer surface of the winding insulation closely represents the hot spot temperature as the primary heat source stator iron loss is external to the winding insulation. Operation with improved cooling at 40bar CO2 results in the motors running cooler even at the higher levels of conductor current heating. In this case the hot spot temperature is expected to occur at the centre of the coil cross-section due to the high winding currents rather than at the thermocouple location on the outer surface of the winding insulation. To account for the insulation thermal gradient a margin should be added to the measured temperatures when the machine is operating in 40bar CO2 conditions. Historically in winding life calculations a margin has been added to the peak measured temperature, however due to the relatively high temperatures experienced by the main motor windings at HNB when operating at low pressure CO2 or in air at atmospheric conditions, it is deemed overly conservative to use peak temperatures in this assessment. The Ferranti data has been processed by the author in excel, see Section 11.5 - Appendix E, to determine a temperature profile for each individual motor winding, applying the following rules: Page | 17 • Throughout the winding thermal life analysis detailed within this report, where the Ferranti logged winding temperatures are below 100°C (representative of 40bar CO2 operation) an additional 10% has been added to the measured temperature values to account for the hot spot temperature adjustment. Temperatures equal to and above 100°C are generally representative of operation in low pressure CO2 or air at atmospheric conditions, where the measured temperature closely represents the hot spot temperature and as such no margin has been added. This approach should ensure reasonable conservatism within the subsequent motor thermal life calculations, without being overly pessimistic. • Following the addition of 10% to Ferranti logged winding temperatures below 100°C, all low temperatures have been increased to a minimum value of 70°C. This ensures that for all percentage thermal life expired calculations detailed within this note a minimum Service Temperature (T2) of 70°C has been utilised adding further conservatism to the thermal life assessment. • The small number of stator winding temperatures recorded by Ferranti as 200°C are ‘full scale’ readings and are typically associated with conditions where the motor is not running and therefore not considered real, as such they have been given a nominal value of 70°C. The post-process temperature profiles for each individual motor stator winding are presented in the charts within Section 11.5 - Appendix E (Purss & Manson, 2018) and have been used for all percentage thermal life expired calculations within the report. Page | 18 3.2.3 Calculation Method For Thermal Life Expired Based on the Arrhenius Equation To assess the percentage thermal life expired of each motor stator winding, the service life (t2) (in hours) has been calculated using the Arrhenius equation and the parameters detailed in Section 3.2.1 above. The service life (t2) and the percentage of thermal life expired is calculated for each hour within the data period using the post-process temperature profiles, see Section 11.5 - Appendix E,(Purss & Manson, 2018) with the hourly temperature values rounded up to the next whole number. These hourly percentage thermal life expiry figures can then be summed to give a total percentage thermal life expired for the data period, and hence establish the remnant thermal life for each motor stator. Percentage thermal life expired for an hour = 100 / service life t2 applicable to the hour and temperature in question = 100/(1777.5/e(E/k*(1/(160 +273.15)-1/(winding temperature +273.15)))) cited from previous work within (Cowan & Potter, 2009) Motor stator winding temperature Calculated % thermal life expired per hour 120.5°C 0.0023367% @121°C 121.9°C 0.0025552% @122°C 122.1°C 0.0027930% @123°C If these three temperatures were experienced for a total of 5000hrs, 1000hrs and 3000hrs respectively, Total Percentage thermal life expired = (0.0023367x5,000) + (0.0025553x1,000) + (0.0027930x3,000) = 22.62% Therefore, Total Percentage remnant thermal life = 77.38% Table 1 - Simplified Example Pre-2001 Operational History During the production of Reference (Cowan & Potter, 2009), HNB quality plans and data records were used to establish the operational history of the motors. The total number of hours each motor was installed in a reactor location since the motors most recent stator rewind until start of the Ferranti logging period was established with worst case estimates being used where the motor reinstatement dates were not clear. The pre-2001 (pre-Ferranti) operational history established for Reference (Cowan & Potter, 2009) has been confirmed by station as correct and has been used in this report. In this report it is assumed that the motors experienced similar conditions in terms of main motor winding temperatures for the pre-2001 period (i.e. pre-Ferranti logged period) as during the Ferranti logged period. This leads to the assumption that the same thermal life expiry rate also applies to the pre-2001 period and as such a proportion of the calculated percentage thermal life expired for the Ferranti period has been added to represent the pre-2001 period. For example, if during the Ferranti logged period 50,000 service hours were calculated to use up Page | 19 10% of thermal life, then 150,000 service hours during the pre-2001 period would use a further 30% of thermal life and the total percentage thermal life expired would therefore be 40%. To make the percentage thermal life expired calculations more accurate, the station could consider reviewing the historical operating practice with the aim of determining appropriate winding temperature profiles for the pre-2001 period, however it is considered that the approach used in this report will be sufficiently representative and, due to the conservatisms introduced previously, a safe assumption that can be made. 3.2.4 Calculated Thermal Life The table in Section 11.3 - Appendix C (Purss & Manson, 2018) gives the results of the data analysis undertaken and details the calculated percentage thermal life expired for each motor stator winding. Observations: Eight stators are greater than 70% thermal life expired, see Table 2 below. Present Total % thermal life Service years since Location expired last rewind STATOR 12 Spare 137.18% 26.67 STATOR 20 4A2 95.93% 27.85 STATOR 3.2 3C2 92.34% 17.78 STATOR 02 3C1 87.30% 18.13 STATOR 08 Spare 84.93% 18.73 STATOR 18 4B2 77.04% 22.94 STATOR 12.2 3A2 74.52% 27.10 STATOR 05 3A1 72.08% 19.92 Table 2 - Stators >70% Thermal Life Expired Stator ID Note: Although STATOR 12.2 has over 27 years’ service (~235,000 service hours), it is only ~74% thermal life expired. This is attributed to relatively low winding temperatures during operation in CO2 from 2001 onwards. From station records, the earliest date of motor stator installation following the last stator rewind was 29/03/1982 for STATOR 20. Analysis of the data shows that STATOR 20 is calculated to be 95.93% thermal life expired. Several other stators have around 23 service years (~200,000 service hours) or greater namely STATOR 12.2, STATOR 12 (spare), STATOR 11, and STATOR 18, and the percentage thermal life expired calculated for these motor stator stators is 74.52%, 137.18%, 64.65% and 77.04% respectively. Page | 20 Spare STATOR 12 is more than 100% thermal life expired and should not be redeployed unless rewound. The average rate of thermal life expiry per service year is assessed to be highest for the following motor stators: o STATOR 21: 21.36% thermal life expired in 3.93 service years (average thermal life expiry rate = 5.43% per service year) o STATOR 03: 21.04% thermal life expired in 4.00 service years (average thermal life expiry rate = 5.26% per service year) o STATOR 07: 14.73% thermal life expired in 2.82 service years (average thermal life expiry rate = 5.22% per service year) o STATOR 03.2: 92.34% thermal life expired in 17.78 service years (average thermal life expiry rate = 5.19% per service year) The average thermal life expiry rates detailed above result in a total life capability far less than the original 30-year substantiated life stated for HNB machines in Reference (Rollo, 2007). The main reason for this is that the motor winding thermal life was originally based on operating at, or below, 80°C. Prolonged operation at the high temperatures experienced during low pressure operation has considerable influence on the thermal life. As shown in Section 11.3 Appendix C, stators with similar service hours can have significantly different calculated thermal life capability due to the varying stator winding temperature profiles. The case study within Section 11.4 - Appendix D compares STATOR 12.2 and STATOR 12 windings and clearly demonstrates the significant impact of operation at elevated temperatures. 3.2.5 Temperature Profile Charts The charts in Section 11.5 - Appendix E show the post-process stator winding temperature profile and percentage thermal life expired profile for each individual motor stator winding for the Ferranti data period. The charts are presented by motor machine ID rather than by reactor Location, so an individual chart could contain operational data from both reactors and/or multiple Locations. The charts present the post-process stator winding temperatures used within the percentage thermal life expiry calculations, rather than the actual Ferranti logged winding temperatures. As such and as per Section 3.2.4 above, the charts present the following temperature conservatisms: Page | 21 o An additional 10% has been added to Ferranti logged winding temperatures below 100°C to allow for the hot spot temperature. o Following the addition of 10% to the Ferranti logged winding temperatures, all low temperatures have been increased to a minimum of 70°C. o All temperature values have been rounded up to the next whole number i.e. 121.2°C is rounded up to 123°C. Where applicable this rounding occurs following the addition of 10% to the Ferranti Logged winding temperatures. o Stator winding temperatures logged at 200°C ‘full scale’ (refer earlier explanation) have been given a nominal value of 70°C. Observations: Typically, motor Ferranti logged winding temperatures range from 75°C to 100°C and are associated with normal running in 40bar CO2 (the temperature profile charts within Section 11.3 - Appendix E (Purss & Manson, 2018) show the post-process winding temperatures where 10% has been added to logged temperatures below 100°C to account for the hot spot temperature). Periods of high temperature operation (Ferranti logged winding temperatures >100°C) can generally be attributed to outages and motor operation at low pressure conditions. The majority of peak winding Ferranti logged winding temperatures are around 140°C, with a small number in the 140 - 150°C range. A maximum Ferranti logged winding temperature of 173°C was recorded on STATOR 02 in August 2006. The gradient of the percentage thermal life expired (red) line is equivalent to the thermal life expiry rate. During periods of high temperature operation, the gradient of the percentage thermal life expired line is steep, indicating that winding thermal life is being used up at a significantly higher rate. The starting point for the percentage thermal life expired profile is not always zero. This is to account for any service period prior to 2001 for which data is not available. As explained in Section 3.2.3 above, the assumption has been made that the same thermal life expiry rate applies to the pre-2001 period as the post-2001 Ferranti data period. As such a proportion of the calculated percentage thermal life expired for the Ferranti data period has been added to the starting point of the percentage thermal life expired profile to represent the pre-2001 period. Page | 22 For motors which have been rewound post 2001, the chart data starts at the post-rewind installation date and the percentage thermal life expired profile starts at zero. Significant data gaps within the charts can be attributed to time periods where the motor stator has not been installed in a reactor Location (i.e. is stored as a spare or is undergoing maintenance in the motor stator workshop). No stator winding temperature profile has been provided for STATOR 01 as this stator is currently a spare and is due to be rewound. 3.2.6 Operation in Normal Conditions Motor winding temperatures in 40bar CO2 are cooler and typically less variable, with Ferranti logged winding temperatures ranging from approximately 75°C to 100°C. These lower temperatures also have less impact on percentage thermal life expired as shown in Table 2 below, which illustrates the percentage of the entire substantiated thermal winding life used per day, month and year if operating continuously at the specified winding temperatures. Ferranti Logged Winding Temperature* 63.6°C Winding Hot Spot Temperature 70°C % Thermal Life Expired per Day 0.00029 % Thermal Life % Thermal Life Expired per Expired per Year Month 0.01 0.11 72.7°C 80°C 0.00093 0.03 0.34 81.8°C 90°C 0.00274 0.08 1.00 100°C 100°C 0.00767 0.23 2.80 110°C 110°C 0.02033 0.61 7.42 120°C 120°C 0.05126 1.54 18.71 130°C 130°C 0.12340 3.70 45.04 140°C 140°C 0.28470 8.54 103.92 150°C 150°C 0.63157 18.95 230.52 160°C 160°C 1.35050 40.52 492.93 Table 3 - Winding Temperature vs. % Thermal Life Expired *Where Ferranti logged winding temperatures are below 100°C (representative of 40bar CO2 operation) an additional 10% has been added to the measured temperature values to account for the hot spot temperature adjustment. Temperatures equal to and above 100°C are generally representative of operation in low pressure CO2 or air at atmospheric conditions, where the measured temperature closely represents the hot spot temperature and as such no margin has been added. Page | 23 From Table 3, if the HNB motors operated continuously at their original estimated operating temperature of 80°C (hot spot temperature 88°C), as given in Reference [28], the thermal life expiry rate per year is less than 1% and the motors have a winding thermal life capability of more than 100 years based on results from the latest HYB/TOR ageing test programme. Based on a revised representative Ferranti logged winding temperature of 100°C for normal running in 40bar CO2 and the results from the latest test programme, the thermal life expiry rate per year is 2.8% and the HNB motors have a winding thermal life capability of over 35 years, if run continuously at this temperature. 3.2.7 Operation in Outage Conditions at Elevated Temperatures To quantify ageing during outages when running at elevated temperatures, detailed assessments of two recent outages are presented in Table 4. This will also help with forecasting ageing during future outages. Table 4 show the motor stator winding percentage thermal life expired during the 2015 Reactor 3 and the 2017 Reactor 4 Statutory Outage periods. The temperature profile associated with each motor stator winding has been analysed for these outage periods and used to calculate the percentage thermal life expired for each individual motor winding during the outage period only. Only motor stators which remained in location throughout the outage periods are considered. Motor stator exchange locations are marked. Analysis shows that for normal ageing at a continuous Ferranti logged winding temperature of 100°C (judged representative of normal running in 40bar CO2), motor stator winding insulation thermally ages by approximately 2.8% (see Table 2) of its total substantiated thermal life over the period of a year. This contrasts with the figures provided for low pressure outage conditions in Tables 3 and 4 which, despite the shorter period, are significantly higher. Observations: During the R3 2015 outage period of 63 days, STATOR 03 winding in location 3C2 had the highest percentage thermal life expiry figure of 5.91% (>12 times the rate of normal ageing over the period). motor STATOR05 had the lowest percentage thermal life expiry figure of 2.55% during the Reactor 3 2015 outage (>5 times the rate of normal ageing over the period). During the R4 2017 outage period of 55 days, STATOR20 winding in location 4A1 had the highest percentage thermal life expiry figure of 6.93% (>16 times the rate of normal ageing). The lowest percentage thermal life expiry figure was 0.95% for STATOR21 during the R4 2017 outage (>2 times the rate of normal ageing). Page | 24 The average percentage thermal life expired during the 2015 R3 outage and 2017 R4 outages were 3.93% and 4.39% respectively (>8 and >10 times respectively the rate of normal ageing). The high temperatures experienced by the motor stators during operation in air at atmospheric conditions has resulted in a significant percentage of winding thermal life being used up in a relatively short period of time. In addition, the variability in motor stator outage operation and operating conditions, and hence their temperature profile, has resulted in variability in the percentage thermal life expired figures for both the R3 2015 and the R4 2017 outage periods. R3 Outage 2015 28/09/15 to 29/11/15 (63 days duration) % thermal life Location – Motor expired during Stator ID outage period 3A1 - STATOR 05 2.55% 3A2 - STATOR 12.2 2.97% 3B1 - STATOR 05.2 4.93% 3B2 - STATOR 11 5.47% 3C1 - STATOR 02 Exchanged 3C2 - STATOR 03 5.91% 3D1 - STATOR 04 4.51% 3D2 - STATOR 07 Exchanged Table 4 - R3 Outage 2015 / R4 Outage 2017 R4 outage 2017 08/09/17 to 31/10/17 (55 days duration) % thermal life Location - Motor expired during Stator ID outage period 4A1 - STATOR 03 Exchanged 4A2 - STATOR 20 6.93% 4B1 - STATOR 17 Exchanged 4B2 - STATOR 18 1.19% 4C1 - STATOR 21 0.95% 4C2 - STATOR 15 6.63% 4D1 - STATOR 06 3.96% 4D2 - STATOR 19 Exchanged Insulation systems can run at elevated temperatures without short term risk of failure; however, insulation ageing is accelerated. Careful consideration should be given to the motor stators’ future outage operating regime, specifically with respect to the duration of operation in low pressure CO2 or air at atmospheric conditions, as operation at higher temperatures greatly impacts thermal life. When the reactor is at low pressure, operation of motor stators with a calculated expired thermal life of greater than 90% (identified in Section 7.1) should be minimised and avoided entirely where possible. 3.2.8 • Discussions of 11kV Motor Evaluation A test programme has been undertaken recently, Reference (Smyth, 2017), which included accelerated ageing of 11kV motor stator motorettes and end winding models for a prolonged period, to extend the winding substantiated life to support a motor stator winding life extension safety case for TOR & HYB Power Stations. The results of this test programme have been used (Section 8.1 - Appendix A gives a justification for use) to provide an equivalent winding insulation qualified life of 1777.54hrs at 160°C for the HNB Novobond SX insulation system (see Section 8.2 - Appendix B). Page | 25 • The HYB/TOR ageing test programme has increased the substantiated thermal life for the HNB motor stator winding by approximately 75% for a given constant temperature (See Appendix B). Without this extension there would have been more machines near to, or exceeding, the 100% thermal life expired status than currently reported. • Assessing the expired (and hence remnant) thermal life in percentage terms is a move away from the current expression of substantiated life in terms of years. This change in emphasis means that the remaining life of the HNB 11kV main windings should not be thought of in terms of operational years, but as a percentage figure which will diminish at a variable rate determined by winding operational temperature profile. As such, careful management of HNB 11kV motor stator winding temperatures can be used to prolong the remaining operational life. It should be noted that calculating substantiated life in terms of years remains valid for machines where the spread of operational temperatures is small and therefore calculating thermal life based on a peak temperature would give a representative result, as is the case for HYB/TOR. • Typical motor winding temperatures logged by the Ferranti ranged from 75°C to 100°C and can be associated with normal running in 40bar CO2 (the temperature profile charts within Section 8.5 - Appendix E show the post-process winding temperatures where 10% has been added to Ferranti logged temperatures below 100°C to account for the hot spot temperature). • Periods of high temperature operation (Ferranti logged winding temperature >100°C) can generally be attributed to outages and moto operation within a low-pressure environment. Most peak winding temperatures are around 140°C, with a small number in the 140 to 150°C range. A maximum Ferranti logged winding temperature of 173°C was recorded on STATOR 02 in August 2006. • Stators with similar service years can have significantly different calculated thermal life expiry figures. This is due to the varying temperature profiles and the considerable influence prolonged operation at the high temperatures experienced during low pressure operation has on the thermal life. HNB 11kV motor stators with the highest percentage thermal life expiry figures: o STATOR 12 (spare), ~137% thermal life expired, ~26 service years o STATOR 20 (4A2), ~95% thermal life expired, ~27 service years o STATOR 03 (3C2), ~92% thermal life expired, ~17 service years o STATOR 02 (3C1), ~87% thermal life expired, ~18 service years Page | 26 o STATOR 08 (spare), ~84% thermal life expired, ~18 service years o STATOR 18 (4B2), ~77% thermal life expired, ~23 service years • The average thermal life expiry rates stated in this note, demonstrate that the total thermal life capability is far less than the 30-year substantiated thermal life the HNB machines are currently considered to have. The main reason for this is that the motor winding life was originally based on operating at, or below, 80°C. Prolonged operation at the high temperatures experienced during low pressure operation has considerable influence on the thermal life. • If the HNB 11kV motors operated continuously at their original estimated operating temperature of 80°C (hot spot temperature of 88°C), the motors would have a winding thermal life capability of more than 100 years based on results from the latest HYB/TOR ageing test programme. • Based on a revised representative Ferranti logged winding temperature of 100°C for normal running in 40bar CO2, the HNB 11kV motors have a winding thermal life capability of at least 35 years, if run continuously at this temperature. • The high temperatures experienced by the motor stators during outage operation in low pressure conditions can result in a significant percentage of winding thermal life being used up in a relatively short period of time: o Continual operation at a Ferranti logged winding temperature of 100°C would result in 2.80% of thermal life being used up per year. o Continual operation at a Ferranti logged winding temperature of 130°C would result in 45.04% of thermal life being used up per year. • Variability in motor stator outage operating conditions and hence their temperature profile has resulted in variability in the percentage thermal life expired figures for both the R3 2015 and the R4 2017 outage periods. The average percentage thermal life expired during the 2015 R3 outage and 2017 R4 outages were 3.93% and 4.39% respectively. • The variability and uncertainty over future outages make it difficult to predict thermal life expiry rates going forward. Page | 27 3.2.9 Recommendations of 11kV Motor Evaluation (Purss & Manson, 2018) • At date of issue, HNB Reactor 3 and Reactor 4 are off-line while work is completed to assess the graphite core and develop the longer-term safety case. Depending on the 11kV motor operating regime during this extended shutdown, the calculated thermal life expiry figures detailed within this investigation may now (at date of issue) be significantly higher. It is recommended that HNB provide up to date temperature data for both Reactor 3 and Reactor 4 such that the percentage thermal life expiry figures can be updated, and more accurate calculations of thermal life can be made. • STATOR 20 currently in location 3C1 is calculated to be >95% thermal life expired. HNB should provide up-to-date temperature data for this location as a priority. The stator winding temperatures of this stator should be closely monitored and managed. • Spare STATOR 12 is more than 100% thermal life expired and should not be redeployed unless rewound. • When the reactor is at low pressure, the number of 11kV motors operated should be minimised and the operation of any with a calculated expired thermal life of greater than 90% should be minimised and avoided entirely where possible. • Careful consideration should be given to future outage motor operating regime, specifically with respect to the duration of operation in low pressure conditions. • The stator winding temperatures of motor stators predicted to reach >90% thermal life expired before the end of station life should be closely monitored and managed, and should not exceed 155°C. To maximise remaining life, operation of these stators with the reactor at low pressure should be minimised and avoided entirely where possible. • Several motors stators are predicted to remain at <60% thermal life expired until the proposed end dates and where possible, these stators should be targeted for any required high temperature operation in air or low-pressure conditions. • The key points and recommendations identified within this investigation should be disseminated to relevant station personal to ensure the appropriate management of 11kV motor stator winding life. Page | 28 3.3 PRACTICAL EXPERIMENT The purpose of this practical element of the project is to provide a real-life example of a reaction rate in the insulation of electrical plant experienced linearly in time due to thermal stress. This is required as the real-world plant discussed in section 3.2 deals with 11kv motors which are important to safety and electricity generation, and due to this importance, there has never been a failure of these stators due to insulation faults or ageing/degradation. Therefore, to investigate how accurate lifespan estimation can be when using the Arrhenius equation data, a practical failure is required for investigation. To gather this data an experiment in accelerated ageing of electrical plant has been attempted, taking into consideration any limitations/restrictions in place such as the timescale of the project, the small budget and facilities available. As mentioned previously in Section 3.1.5 and within (Carfagno & Gibson, 1980) there are many factors of stress that cause ageing, Section 4 of (Carfagno & Gibson, 1980) discusses various theories of ageing and well-established models relating ageing to stress such as the Arrhenius model. Due to the limitations mentioned this practical experiment focused on thermal stress as this is considered one of the higher contributing factors and it is also relatively easy to work with. How this was completed is described in Section 3.3.2 – Methodology, but major steps are listed below to put the following sections into context: 3.3.1 To address the limited resources available to the author and to ensure the project stays within the timescale given a low voltage cable (see Section 3.3.1) was aged artificially until it couldn’t perform its duty. This was done using an oven located on site within a university lab. Several samples were aged to account for random failures or imperfections in manufacturing. To ensure no preconceptions are inherent in the results no targets or goals are being set, the (British Standards Institute, 2005b) was used and the outcomes recorded. The data from this was then compared to a calculated Arrhenius model for the same cable and the findings discussed. Cable Specifications The cable chosen for sampling is a Nexans Single Core, 1.5mm2, Solid conductor, nominal rating of 10A with a PVC conductor insulation. This cable was chosen due to the relatively low cost and accelerated ageing times required. To be more accurate to the electrical plant discussed in section 3.2 a different piece of plant would be used (discussed in Section 5 - further work), however this would require significantly longer for testing than the scope of this project allows. Page | 29 It has a 6491X cable code (H07V-U) – which is held to the following Standard (British Standards Institute, 2011) which relates to Class 1 – 1.5mm2 to 10mm2 with an Insulation type T1 as in Standard (British Standards Institute, 2006) which gives specifications for PVC insulating compounds that manufacturers are required to adhere to (Maximum temp rated for 70°C). 3.3.2 Methodology Using (British Standards Institute, 2005b) as a guide, the cable described in section 3.3.1 above was aged in an accelerated manner to simulate ageing caused by thermal stress. This standard (British Standards Institute, 2005b) states “although originally developed for use with electrical insulating materials and simple combinations of such materials, the procedures are considered to be of more general applicability and are widely used in the assessment of materials not intended for use as electrical insulation”. This shows the flexibility of the Arrhenius equation and accelerated ageing tests. Within (British Standards Institute, 2005b) there is a table of recommended temperatures and duration for baking when performing these ageing tests further details can be seen in Section 8.7 – Appendix G, the following procedures are recommended also: a. Prepare suitable specimens – for this practical experiment there will be five specimens of one metre in length and one specimen of five metres in length, all specimens will consist of three single cores taped together (this will enable insulation resistance testing between cores to be performed easily). This choice was made to accommodate the oven and space available to the author. b. Subject groups of specimens to ageing at several fixed levels of elevated temperature either continuously or cyclically – the first batch of specimens will be aged for 4 weeks at 110°C at which point the temperature will be increased at 10°C intervals and for a time relevant to temperature being used, see guide Table 5 and (British Standards Institute, 2005b) for reference. Then the second batch (five metres in length) will be aged at 120°C and then increase in 20°C intervals. This will continue until a point at which the specimens would fail in service for whatever reason (mechanical/electrical). c. Subject specimens to a diagnostic procedure in order to reveal the degree of ageing, diagnostic procedures may be destructive or non-destructive – for this experiment the diagnostic procedures chosen will be from (British Standards Institute, 2005a) with advice from (IEEE, 2014) – Visual/Tactile Test, DC resistance of conductor, weight of specimens to check polymer loss, insulation resistance (including Degree of Polymerisation and Dielectric Response Measurement), functional tests at near load current, thermography at load current. (Further details of each test will be in section 3.3.3) Page | 30 d. Extend the heat exposure until the specified end point – this end point will be for a period of at least 8 weeks to achieve the point where 60 years’ service would be approximated in ageing through thermal stress based on the temperatures being used, but until the cable cannot complete its service would be the defining end point. e. Report the test results, showing the kind of ageing procedure (continuous or cyclical) and diagnostic procedure – this will be in section 3.3.4 f. Evaluate these results numerically and present graphically - this will be in section 3.3.4 g. Express the complete information in abbreviated numerical form. By means of temperature index and halving interval - this will be in section 3.3.4 These procedures were followed, and the results shown in section 3.3.4 and a mathematical model of the same cable was created using the Arrhenius equation and the activation energy for PVC insulation which was compared with the practical experiment data. This should gave a good example of how accurate the Arrhenius equation method is and validated the findings for the real-world example in section 3.2. Rated temperature Gives approximate lifespan Gives approximate lifespan of (years) of (hours) >70°C 20+ 175200+ Using ‘10°K rule of thumb’. 71°C > 80°C 10 87600 81°C > 90°C 5 131040 91°C > 100°C 2.5 43800 101°C > 110°C 1.25 21900 111°C > 120°C 0.625 10950 121°C > 130°C 0.3125 5475 131°C > 140°C 0.15625 2737.5 141°C > 150°C 0.078125 1368.75 151°C > 160°C 0.0390625 684.375 161°C > 170°C 0.01953 342.1875 171°C > 180°C 0.009766 171.094 Table 5 - Testing Temperatures & Approximate Lifespan of Insulation 3.3.3 AGEING & TESTING To perform the ageing experiment the author made use of an oven within the university premises in one of the labs within the Charles Oakley building. The oven was available for continuous baking which allowed for a more comprehensive ageing test and in turn made the choice between cyclical or continuous. Page | 31 As discussed in the previous section batch one would contain five samples of one metre length, one of these specimens was wound around a one-inch pipe to create a coil. The purpose of this coil was to check the effect of bending on the insulations thermal strength and to check if the electrical degradation was different. Figure 1 below shows the specimens from batch one and two. Figure 1 - Cable Ageing Samples – 1m and 5 m coils To begin with the specimens were measured and taped together, then each specimen was weighed to allow any weight lost from the dielectric to be measured. To test the cables using the thermal camera (thermography) and for load current functional tests it was necessary to put the cables into an electrical circuit (see Figure 2). This circuit consisted of an electrical supply protected from overloads with a thermal trip. This was then connected to one end of a test specimen through a 13A fuse and that in turn was connected to a protected junction that has a residual current device (RCD) built in to prevent short circuits. Finally, a static resistive load was connected to the RCD junction through another 13A fuse. The load was an electric iron rated at 2kW which when supplied from 240V gives a constant load of 8.33A, this was sufficiently close enough to the maximum cable rating of 10A to provide a good test of its electrical capabilities during ageing. Protected Thermal CutOut Electrical Protective Residual Current Device for Load Aged Cable for Testing 13A Fused Plugs Fixed Electrical Load Figure 2 - Electrical Test Circuit Page | 32 The aim of the experiment is to test the condition of the cables before during and after the ageing process, this will enable a trending of the data to provide an expected end of life for the cables that can be compared with the Arrhenius modelling. As mentioned previously, tests will be conducted to monitor the cables condition, these were taken from (British Standards Institute, 2005a) with consideration from EDF Energy technical guidance note 099 – (summarised below for cables that have a PVC, XLPE or OIP dielectric and operate at less than 1kV). This guidance note recommends the following inspections for walkdowns and routine maintenance of the cables and to monitor its condition. a. Examine for mechanical damage, crushing or movement of any armour wires. b. Where cables are installed above ground all cable supports and cleats should be examined for corrosion, security and any fretting between cable and supports. c. PVC, PE cable sheaths should be examined for any crazing, cracking, etc. d. Cable terminations should be examined for evidence of corrosion or overheating at the bolted connections where accessible. e. Bonding leads and earth straps should be examined for corrosion, mechanical damage or overheating. f. The cable insulation resistance should be measured. Armoured cables should be measured phase to earth. Unarmoured cables should be measured between phases. NB: IR measurements can vary greatly with temperature, e.g. The resistivity of PVC drops by approximately 50% with a 10°C increase of temperature. It is recommended that repeat measurements are conducted at a similar time of day to minimise variations in environmental conditions. Ambient conditions at the time of measurement should be recorded to enable normalisation of the results if required. Where electrical testing has proved inconclusive non-destructive mechanical or chemical micro-sampling should be considered. From these sources the investigation will use the following combination of tests for trending: Visual/Tactile Test – the cables will be examined and any colour variation or damage to the surface spotted will be recorded. DC resistance of conductor – this will be tricky to get accurate due to the cable ends being exposed once tested and the conductor baked without insulation on it causing damage to the out layer of copper, possibility of a false reading. Weight of specimens – weighed at beginning, during and end of the ageing process to trend weight loss if present. Insulation Resistance – measured between cores of the specimens using a Fluke IR tester with a range up to 20MΩ at 500VDC test voltage, reading taken immediately, called the spot test. Polarisation Index – taking the IR value at 1 minute and 10mins, then putting the 10min/1min to give a ratio. Dielectric Absorption Ratio – taking the IR value at 30 secs then at60secs, then putting the 60secs/30secs to give a ratio. Page | 33 3.3.4 Functional tests at near load current – using circuit shown in Figure 2 to allow for testing of functional capability. Thermography at load current – using the circuit shown in Figure 2 to enable thermal images to be taken which will show any hotspots and potential degradation. RESULTS There are three processes in the ageing of PVC dielectric - oxidation, dehydrochlorination and plasticiser loss. It was observed within (Jakubowicz, Yarahmadi & Gevert, 1999) that the two main components of this chemical/mechanical change were the dehydrochlorination (discussed in the next section) and plasticiser loss (discussed in Section 3.3.4.3). 3.3.4.1 Visual/Tactile Examination Dehydrochlorination of the insulation causes discolouration (Ekelund, Edin & Gedde, 2007) therefore it can be possible to use the colour change to track ageing in an effective, albeit crude trending pattern. To attempt this the PVC insulation was photographed once per week during baking. This should show a trend in colour from new to aged corresponding to the temperature and time. During these intervals the specimens will be handled which will allow a tactile inspection to check on the flexibility of the samples, is there any noticeable cracking or variances in the surface etc. Week / Sample @ 120 Flexibility Cracking/Breaking degrees Celsius Week 1, Batch 1 – 1 metre Very flexible, as new None Very flexible, cores initially Week 2, Batch 1 – 1 metre None sticking together out of oven Still flexible but a noticeable difference since last week, Slight treeing appearing Week 3, Batch 1 – 1 metre cores sticking together more over bends on some samples and requiring pulling apart at times. Shiny coating on surface which cracks once bent, no Week 4, Batch 1 – 1 metre Much stiffer to bend apparent damage to insulation other than this Unable to bend fully, very If forced the insulation Week 5, Batch 1 – 1 metre stiff breaks Unable to bend fully, very If forced the insulation Week 6, Batch 1 – 1 metre stiff – brittle in places breaks Can be bent but is very brittle, exposed conductor at No real force required, ends are all coated in black insulation very brittle and Week 7, Batch 1 – 1 metre soot(?), conductor doesn’t cracks along bends every break but insulation very time fragile Table 6 - Tactile Inspection Notes Page | 34 The following images show the PVC insulation from week one until week seven, displaying the change in colour linked to dehydrochlorination and eventual mechanical failure of the insulation as seen in week seven. Figure 4 - Week 1 @ 120 degrees Celsius Figure 3 - Week 2 @ 120 degrees Celsius Figure 5 - Week 3 @ 120 degrees Celsius Page | 35 Figure 7 - Week 4 @ 120 degrees Celsius Figure 6 - Week 5 @ 120 degrees Celsius Figure 8 - Week 6 @ 120 degrees Celsius Page | 36 Figure 9 - Week 7 @ 120 degrees Celsius From the images above, when Dehydrochlorination occurs there is a marked difference within the cable’s appearance, including a darkening of the insulation colour to the point which gets darkest after approximately week 6 and at this point the insulation becomes very brittle when returned to ambient temperature from the oven. This could be a crude method to track ageing within the insulation, but chemical sampling would be able to make a hydrochlorination level against time curve possible giving a much more accurate trending tool. 3.3.4.2 Resistance of Conductor During the experiment it was considered that a measure of the conductor’s resistance during the ageing would be useful data to have, monitoring its electrical integrity before, during and after the process. However, it became apparent that the exposed ends of conductor were being aged also and becoming coated in something that gave false readings. To ensure accurate data it would be necessary to strip small amounts of insulation from the ends of the specimens and unfortunately this would also affect the weight – causing issues with recording plasticiser loss. Due to the importance of monitoring plasticiser loss it was decided to forego recording conductor resistance during the ageing process. 3.3.4.3 Weight of Specimens Pure PVC is rigid and brittle, therefore to be a practical insulator the addition of various plasticizers (phthalates and adipates) is required to make it malleable and workable. Weight loss tracking shows the amount of plasticiser loss caused by the ageing process (accelerated or otherwise) and this is linear with time when the rate is controlled by an evaporation process Page | 37 (Jakubowicz et al., 1999). Due to its increased mass, the 5-metre specimen was used for weight loss tracking. This ensured a noticeable change (in grams) over the ageing time – this is shown in the following images. To check the linearity of this weight loss the 5m samples were aged for 8 days at 140°C. Day / Specimen Weight (g) Day 1 @ 140 degrees, 5m sample 324 Day 2 @ 140 degrees, 5m sample 318.5 Day 3 @ 140 degrees, 5m sample 316 Day 4 @ 140 degrees, 5m sample 313 Day 5 @ 140 degrees, 5m sample 308 Day 6 @ 140 degrees, 5m sample 308 Day 7 @ 140 degrees, 5m sample 306 Day 8 @ 140 degrees, 5m sample 306 Table 7 - Weight loss over 8-week period/two temperatures Whilst this can be trended it is a crude method for evaluation of lifespan remaining. This is because to be as accurate as possible it requires chemical examination such as super fluid extraction SFE. This test was not conducted due to the restrictions on the project. Therefore, an estimation of lifespan based on the weight loss can be an indication but not an accurate trending tool. Table 7 shows that after 4 days @ 140°C weight loss plateaus around 308g to finally settle at 306g. It would be safe to assume from this that there is very little plasticiser left within the insulation to evaporate and hence the cable has reached its maximum lifespan, although in a real-world application this cable would be replaced closer to the time when it had reached lifespan and plasticiser loss equivalent to around day 5. It’s worth noting that with a ventilated fan oven for ageing, the activation energy required per molecule to begin the plasticiser losses and dehydrochlorination is less than in stagnant air, such as behind a wall and representative of an electrical installation, hence the timescales for service time will be much lower. This can be corrected for using a different activation energy level. 3.3.4.4 IR Spot Values, Dielectric Absorption Ratio, & Polarisation Index As discussed within Section 3.3.3. Insulation Resistance tests were going to be performed on the specimens to provide the main trending tool for comparison with the Arrhenius model for PVC cabling. However, it became apparent from lab tests and further research that the nature of PVC ageing causes mechanical degradation much sooner than electrical property changes. Due to the limitations of the project a Fluke tester with a maximum capability of 20MΩ readings was being used to trend IR values, but this range is much too low to observe electrical changes caused by ageing. For electrical changes to be observed a high voltage laboratory would be required with methods of measuring IR levels far more than the tester used in this experiment, see (Ekelund et al., 2007), and the ability to measure Partial Discharges or Leakage Current with a test voltage being greater than 3kV to enable partial discharges to be detectable. Page | 38 Due to the schedule there wasn’t enough time before the project deadline to complete these tasks within the HV lab at GCU. Therefore, for this report there have been no IR values or Ratios recorded. 3.3.4.5 Functional Tests and Thermography As previously discussed, a test circuit (see Figure 2 for more details) was used to perform a functional test at almost full rated load current and to allow for thermal images to be recorded, using the FLIR infra-red camera. Figures 6 and 7 below have confirmed that mechanical failure of the insulation has little effect on the electrical ability of the cables. There is no increase in temperature for the aged cable when handling the same electrical load even though at that point there was cracks forming in the insulation and bare conductor in places. Due to the condition of the insulation it would be unsuitable for use and would require changing so this would be considered at its end of useful life even with the electrical attributes being acceptable. Figure 11 - Electrical Test Circuit and Thermal Capture Figure 10 - Thermal Capture of Sample from beginning to end (aged @ 120 degrees Celsius for 7 weeks). Page | 39 3.3.4.6 Arrhenius Equation Model of PVC Cable Insulation Taking into consideration the fact that PVC cables have been used in industry since the 1980’s approximately there has been around 40 years of operating experience of these materials. There are varied suggestions of useful remaining lifespan within industry journals, papers and message boards, the variations are due to the fact that most PVC insulated cables have been oversized when being specified. This occurred due to electricians and engineers using British standards such as the wiring regulations BS7671 (currently on the 18th edition) which are more concerned with voltage drop and current carrying capability for safety reasons. This means that for a lighting circuit which is protected by a 6amp mini circuit breaker or residual current device and which typically only see operating current of 3 amps, specifying a minimum cable size of 1.5mm2 PVC cables which can cope with a maximum rating of 10amps (related to a constant temperature of 70°C) is considered highly over rated. Due to this most PVC cables within electrical installations (which are rarely over ambient temperature of 25/30°C – domestic or industrial) will have a lifespan well in excess of the 20,000 hours @ 89°C that they have been tested to. This means most cables will outlive the circuit/installation that they are part of. However, for completeness an attempt at specifying a service life for PVC insulated cables is included below using the Arrhenius Equation and an activation energy taken from (Linde & Gedde, 2014). For completeness both ventilated and stagnant air activation energies have been used, but to represent the fan oven the closest value would be the ventilated air (60 kj/mol), the service temperature chosen is the rating for the cables of a maximum of 70°C. Ventilated and Stagnant Air Conditions T1 = ageing temperature (K) = 413.15 K (140°C) T2 = service temperature (K) = 343.15 K (70°C) E1 = activation energy (eV), ventilated conditions = 0.622 eV (60 kj/mol) E2 = activation energy (eV), stagnant air conditions = 1.347 eV (130 kj/mol) t1 = ageing time @ T1 = 168 hours k = Boltzmann constant (eV/K) = 8.617 x 10-5 eV/K Page | 40 Figure 12 - Arrhenius Equation Variation used to calculate service time @ rated temperatures Using the equation in Figure 12, t2 (service lifespan) can be calculated for E1 & E2. (see Section 8.8 - Appendix H for the excel screenshots of data). (i) t2 for ventilated air = gives a service time of 0.68 years for a constant temperature of 70°C (ii) t2 for stagnant air = gives a service time of 43.19 years for a constant temperature of 70°C As can be seen from (ii) above, this would be an accurate estimation of a PVC insulated cable within a normal electrical installation. 4 DISCUSSION It was expected to be able to trend the electrical changes within the cables to provide an extrapolated natural lifespan at ambient temperature, but due to the nature of PVC ageing shown in paper (Ekelund et al., 2007) mechanical changes in the dielectric will be the limiting factors long before any electrical deterioration. Mechanical changes happen due to thermal induced ageing, such as compressor modulus, elongation at break and density changes. These mechanical changes are monitored using visual or tactile inspections, indenter modulus tools to measure surface hardness, tensile strength equipment, infrared spectroscopy to monitor the changes in the polymer and how much plasticiser has been lost, and other chemical observations. Of these only the visual and tactile inspections were completed due to the time and budget constraints, which means that the results are inconclusive and require more work to verify them or to provide more data which could be used to create a trend pattern. Page | 41 Due to the electrical bias and experience of the author these mechanical changes weren’t considered prior to conducting this experiment which has highlighted a latent error in which even using papers and standards as a guide to ensure no preconceived notions or ideas become prevalent, the unconscious awareness of the author discounted the mechanical aspects of the material and focused on the electrical service requirement for the cable to conduct the experiment. This error could be mitigated for future work by working in a small team of electrical and either mechanical or chemical engineers. Therefore, the equipment and measurements required to accurately predict lifespan using the practical experiment completed within this report have not been completed and these would need to be finished before any conclusive/comprehensive statement regarding the accuracy of the Arrhenius equation in predicting thermal stress ageing can be made. 5 CONCLUSIONS AND FURTHER WORK The work completed so far in this project has been inconclusive in corroborating the Arrhenius equations use in predictive maintenance. This is due to the choice of practical experimentation, the samples chosen and the test methods available to the author at this time and within the original time/financial constraints. There is an observable and measurable change within the materials when they are subjected to thermal stresses and this seems to follow a linear pattern related to the temperature and time used, which in essence is the description of the Arrhenius equation, but the experiment completed for this project has been unable to comprehensively prove this relationship. For example if using the colour changes and tactile response results from the practical experiment (@120°C) there was a big mechanical difference in the insulation, but as can be seen in the thermography and IR results, there was no discernible change in the cables electrical properties therefore as long as the cable wasn’t moved, by all accounts and purposes it would fulfil its duty. Also looking at the practical experiment for plasticiser loss (@140°C) the weight seemed to plateau after 4/5 days, this would suggest at that point the plasticiser has all but gone from the insulation, but again from IR and thermography tests the cable would complete its duty as long as the cable wasn’t moved. This proves an uncertainty and one that could only be cleared up with chemical examination and mechanical tests of the insulation in question. The author feels safe however in assuming that the discussions and recommendations made within the real-world Arrhenius investigation are still valid. This is due to the fact that Arrhenius has, and is still being used, within industry for ageing models and estimating lifespan of materials for the last 50+ years, also the British Standards Institute has included the estimation model using Arrhenius within its own cable, ageing and insulation standards (cited throughout this report) all of which have been revised within the last 3 years to remain relevant and valid. Page | 42 To achieve the goals of this project, this further work would need to be completed; A representative motorette sample (windings, insulation layers – epoxy resin, oil impregnated paper etc.) used in the ageing experiment to check the accuracy of the calculations within the real-world example. Mechanical tests added to the electrical tests performed in the practical experiment to provide a better trending of insulation deterioration. Chemical test added to trend the structure of the insulation throughout to increase estimations of lifespan. Utilising a HV test lab to also measure a more sensitive IR values, leakage current and partial discharge within the motorette sample for more accurate electrical data. A wider variety of samples tested; with a longer timescale required to test the materials, with test temperature as close to the service or rated temperature as practicable for accuracy. All of the trends collated and corrected to the one service life per service temp. This would allow for the most accurate real world estimation. Finally this accurate real-world estimation compared to a calculated one using Arrhenius. This would give an accuracy margin for the Arrhenius calculation and answer the question posed by this project with a high degree of confidence. Page | 43 6 REFERENCES BANFORD, H.M. & FOURACRE, R.A., 1999. Nuclear technology and ageing. IEEE Electrical Insulation Magazine. 15(5), pp.19-27. Available from: 10.1109/57.793826. BRANCATO, E.L., 1991. Life Expectancy of Motors. IEEE Electrical Insulation Magazine. 7(6), pp.14-22. BRANCATO, E.L., 1978. Insulation Aging - A Historical and Critical Review . IEEE Transactions on Electrical Insulation. (Vol EI-13, Vol 4), pp.308-317. BRITISH STANDARDS INSTITUTE., 2018. BS IEC 60076-7:2018 - Power transformers. Loading guide for mineral-oil-immersed power transformers. BRITISH STANDARDS INSTITUTE., 2011. BS EN 50525-2-31:2011 - Electric cables. Low voltage energy cables of rated voltages up to and including 450/750 V (U0/U). Cables for general applications. Single core non-sheathed cables with thermoplastic PVC insulation. BRITISH STANDARDS INSTITUTE., 2006. BS EN 50363-3:2005+A1:2011 - Insulating, sheathing and covering materials for low voltage energy cables. PVC insulating compounds. BRITISH STANDARDS INSTITUTE., 2005a. BS EN 50395:2005+A1:2011 - Electrical test methods for low voltage energy cables. BRITISH STANDARDS INSTITUTE BS EN 60216-2:2005: Electrical insulating materials. Thermal endurance properties. Determination of thermal endurance properties of electrical insulating materials. Choice of test criteria. , 2005b.British Standards Institute Available from: https://bsol.bsigroup.com/en/Bsol-Item-Detail-Page/?pid=000000000030077957. CARFAGNO, S.P. & GIBSON, R.J., 1980. Review of equipment aging theory and technology Final report. United States: Available from: http://inis.iaea.org/search/search.aspx?orig_q=RN:12582123. COWAN, D.K. & POTTER, J., 2009. Estimated Insulation Life on 11kV Motor Stator Windings . EDF Energy. DAKIN, T.W., 1948. Electrical Insulation Deterioration Treated as a Chemical Rate Phenomenon . AIEE Transactions. 67(1), pp.113-122. Available from: https://ieeexplore-ieeeorg.gcu.idm.oclc.org/document/5059649. DURAN, I.C.&O.G. DUARTE. , 2012.A survey of methods of estimating lifetime and aging of assets in substations In:Anonymous 9th IET International Conference on Advances in Power System Control, Operation and Management (APSCOM 2012), Stevenage, UK: IET, pp.107. EDF ENERGY., 1982. Plant Substantiation Document . NNC National Nuclear Corporation Limited. EKELUND, M., EDIN, H. & GEDDE, U.W., 2007. Long-term performance of poly(vinyl chloride) cables. Part 1: Mechanical and electrical performances. Polymer Degradation and Page | 44 Stability; Polymer Degradation and Stability. 92(4), pp.617-629. Available from: 10.1016/j.polymdegradstab.2007.01.005. HOOD, J.J., 1885. LIII. On retardation of chemical change. The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science. 20(126), pp.444-456. Available from: 10.1080/14786448508627784. IEEE., 2014. IEEE Guide for Assessing, Monitoring, and Mitigating Aging Effects on Electrical Equipment Used in Nuclear Power Generating Stations and Other Nuclear Facilities (1205-2014). USA: IEEE. IEEE., 2012. IEEE Guide for Loading Mineral-Oil-Immersed Transformers and Step-Voltage Regulators - Redline (C57.91-2011). Piscataway, USA: IEEE. JAKUBOWICZ, I., YARAHMADI, N. & GEVERT, T., 1999. Effects of accelerated and natural ageing on plasticized polyvinyl chloride (PVC). Polymer Degradation and Stability. 66(3), pp.415-421. Available from: 10.1016/S0141-3910(99)00094-4. KAM, S.-. & LEDWICH, G. A database Alternative Transient Program simulated waveforms of shunt reactor switching cases with vacuum breakers on motor circuits. , 2009.Australian Journal of Electrical and Electronics Engineering. KENNEDY, A., STERLING, R.&HAINS, A., 2008. Justification and Application of 11kV Motor Stator Moisture Withstand Limits including Interpretation of Spraywater test results . EDF Energy. LINDE, E. & GEDDE, U.W., 2014. Plasticizer migration from PVC cable insulation – The challenges of extrapolation methods. Polymer Degradation and Stability. 101(1), pp.24-31. Available from: 10.1016/j.polymdegradstab.2014.01.021. LINDQUIST, T.M., BERTLING, L. & ERIKSSON, R. Estimation of disconnector contact condition for modelling the effect of maintenance and ageing. , 2005.IEEEAvailable from: 10.1109/PTC.2005.4524406. LOGAN, S.R., 1982. The origin and status of the Arrhenius equation. Journal of Chemical Education. 59(4), pp.279. Available from: 10.1021/ed059p279. MONTSINGER, V.M., 1930. Loading Transformers By Temperature. AIEE Transactions. 49(2), pp.776-790. Available from: https://ieeexplore.ieee.org/document/5055572. PURSS, J. & MANSON, L., 2018. Assessment of Thermal Life of the 11kV Motor Stator Windings . EDF Energy. ROBERTSON, L.K.&L.A. LAMONT. , 2015.An overview of nuclear power In:Anonymous 2015 5th International Youth Conference on Energy (IYCE), Iyce, 2015.IEEE, pp.1-6. ROLLO, J., 2016. Justification for the Thermal Ageing Calculations used to assess 11Kv Motor Stators Substantiated Lifespan . EDF Energy. Page | 45 ROLLO, J., 2007. Review the requirement to introduce a 11kV motor rewind program at HNB . EDF Energy. SCHWARZ, K.K., 1973. SUBMERGED GAS-CIRCULATOR MOTORS FOR ADVANCED GAS-COOLED REACTORS. Proceedings of the Institution of Electrical Engineers. 120(7), pp.777-785. Available from: 10.1049/piee.1973.0168. SMYTH, T.P., 2017. HYB and TOR - 11kV Motor Insulation Tests: Phase 3 . EDF Energy. STONE, G.C. & LAWLESS, J.F., 1979. The Application of Weibull Statistics to Insulation Aging Tests. IEEE Transactions on Electrical Insulation. EI-14(5), pp.233-239. Available from: 10.1109/TEI.1979.298226. VAN'T HOFF, M. J. H., 1884. Etudes de dynamique chimique. Recueil Des Travaux Chimiques Des Pays-Bas. 3(10), pp.333-336. Available from: 10.1002/recl.18840031003. 7 BIBLIOGRAPHY E. L. Brancato, "Insulation Aging - A Historical and Critical Review", IEEE Transactions on Electrical Insulation, (Vol EI-13, Vol 4), pp. 308-317, Aug 1, 1978. EDF Energy Documents have been included as references and hard copies can be supplied at request whenever protective markings allow. The data within this report has been altered to be less specific to avoid the need for a non-disclosure agreement. Page | 46 8 APPENDICES DATA from EDF Energy regarding the real-world Arrhenius equation example. This has been copied from the original report, (Purss & Manson, 2018), for information purposes only. As before, a hard copy of the reference is available on demand. 8.1 Appendix A – HYB/TOR 11kV motor stator ageing test programme and applicability of results to HNB/HPB 11kV motors. This Appendix contains a summary review of the recent ageing test programme (Reference A2), which extended the qualified life of the HYB/TOR 11kV motor windings. The assessment considers the applicability of the test models and conditions such that the results may be used in the calculation of HNB (and HPB) 11kV motor winding thermal life. Test models v HNB 11kV motor windings The motorettes and end winding models were manufactured by the motor OEM, ATB Laurence Scott, to an essentially similar insulation specification (N257F7) as the present HNB motor windings. The HNB motors have been rewound (at least once) by Laurence Scott to the same specification since the machines were originally supplied. The ground wall insulation is glass backed mica paper referred to as Novobond SX. ‘SX’ refers to the insulation tape resin Epoxy Novolac SX and it is thermal ageing of this resin which is important because it plays a significant role in maintaining the mechanical integrity of the conductor insulation to resist the effects of pressurised CO2 / pressure cycling and therefore withstanding a rapid depressurisation fault. The final coating resin on the test programme models is Epoxylite 235SG, which is a 2part epoxy chosen to replace the original Sterling 006 1073 because it is obsolete. Epoxylite 235SG was deemed to be equivalent to 006 1073. The HNB (and HPB) motor windings are coated with Sterling 003 1010 isophthalate polyester varnish. The difference in final coating material is much less important for thermal ageing and resistance to CO2 effects as it does not play a significant role in the electric or mechanical strength capability of the insulation system. It is known that early in the life of the resin coating, cracks appear in the resin on the endwindings due to the pressure cycling and this is the case with both types of final coating material. During ageing the test models are subjected to a high-pressure atmosphere saturated with oil to simulate the presence of bearing oil in the real motor compartment due to leaks from the bearings. The resin cracks are a potential penetration route for water, but the high moisture cycle and water spray tests gave no failures. This is in part due to the waterproofing action of the oil which has been forced into the insulation layers under action of pressurised CO2 and this is common to the test models and actual machines. It is worthy of note that part of the Project mitigations, for the HYB/TOR ageing programme not delivering an extended winding life, was a study to assess the feasibility of rewinding HYB/TOR stators at the HPB rewind facility. ATB Laurence Scott concluded (Reference A1) that isophthalate polyester varnish was a proven system with ATB LS referring to the rewinds Page | 47 on HPB/HNB motors through both in service experience and simulated boiler tube leak water spray testing for HPB/HNB (see mention below of the HPB/HNB water spray testing). Ageing test conditions (Reference A2) Test models underwent accelerated ageing at elevated temperature in pressurised CO2, normal moisture levels and were subjected to regular pressure cycles representative of normal reactor pressurising and depressurising rates. Also included were several rapid depressurisations. Testing Environment - The accelerated ageing was completed in a pressurised CO2 environment. No ageing testing was conducted in an air environment; however, the test results are considered applicable to the HNB winding thermal life calculations for periods of operation in an air environment on the following basis. The thermal classification of the HNB 11kV motor stator insulation system is Thermal Class 155 (F) in accordance with BS EN 60085, meaning that the insulation should have an average life of 20,000 hours when operating at 155°C (Reference A5). The test results from the accelerated ageing in CO2 provide a qualified life base ageing temperature and duration for the winding thermal life calculations detailed within this report (Section XX - Appendix B) and it has been used to determine an equivalent thermal life capability of 2,587hours at 155°C. The thermal life capability derived from the test results is much more conservative than the 20,000hours and therefore bounds motor operation in an air environment. It should be noted that the accelerated ageing and tests were completed successfully and there was nothing in the final diagnostic test and inspection results to suggest that the test pieces could not have undergone further ageing, giving a further extension to the thermal life capability. Rapid Depressurisation Rate reproduced the pressure profile for a HNB major breach curve as closely as reasonably practicable and was chosen as depressurisation at HNB would occur more rapidly than at HYB/TOR (Figure 3 Reference A2). The test profile was 4.8 bar/min to 20.69 barg, followed by 1.8 barg/min to 6.9 barg, then 0.5 bar/min until depressurised. Test voltages during ageing and water spray testing - The test models were subjected to test voltages based on the motor rated voltage 11 kV so equally applicable to HNB. Moisture concentration levels - For normal ageing in pressurised CO2, the moisture level was based on the maximum of the normal concentration range specified in Reference A3 for HYB/TOR i.e. 194 wppm and was finally chosen to be 205 wppm on average over a test dwell period. The maximum level specified in Reference A3 for HNB is 124 wppm (HPB 112 wppm) so the test moisture level bounds the HNB operation. For a test cycle with high moisture level cycle followed by rapid depressurisation, (to simulate water ingress conditions following a boiler tube failure) the test simulated water saturated conditions so it is equally applicable to HNB. Voltage Endurance and Spray Testing (VEST) o All test pieces endured 2off VESTs after they reached an equivalent of 42+ yrs. – one to simulate 3.3 kV VSD/VFC operation and one for 11 kV. o Page | 48 VEST consists of enduring the appropriate voltage for 26.4 (24+10%) hrs dry plus 26.4hrs fully wetted (spray on) plus 26.4 hrs of “wet” (left wet following the spray on period but spray is turned off). o The four oldest motorettes endured another 2off VESTs (based on 3.3 kV and 11 kV) at their final 54+ yr. ages. There is no reason to suggest that the next two oldest (~50 years old) motorettes wouldn’t have been able to endure similar additional VESTs but project time constraints prevented additional testing. Water spray testing carried out several years ago for HPB/HNB for the Boiler Tube Leak safety case development (see Reference A4 which quotes HINB/R/MSR/PLEX/002) established a safety case claim of: Short term spray rate: 0.1kg/s per motor for up to 30 minutes, Longer term spray rate: 0.03kg/s per motor for up to 6 hours. Cumulative durations achieved under wetted conditions were 16 hrs, 18.5 hrs, 25 hrs for different test samples/configurations. In this case HNB withstand against water ingress is bounded by the HYB/TOR test programme. Conclusion - The recent test programme to extend the winding substantiated life to support a motor winding life extension safety case for TOR and HYB Power Stations included accelerated ageing of motorettes and end winding models. The test pieces and test conditions are considered representative for the HNB (and HPB) 11kV motor windings and the test results are appropriate for use in the HNB winding thermal life calculations in this report. Appendix A References: A1. ATB LS.2016.1624W04.01 (CDMS Records) Stator Impregnation system design study, September 2016. A2. 201424-TR-000037 (HYB CDMS Controlled Documents), Heysham 2 & Torness Power Stations. Motor Insulation Tests: Review of Phase 3 Test Conditions, Issue 01, 19 February 2016. A3. BEG/SPEC/ENG/BEOM/211 Control of AGR Coolant Composition. A4. DAO/REP/JICC/018/AGR/08, Hunterston B and Hinkley Point B, Justification and Application of 11kV Motor Moisture Withstand Limits including Interpretation of Spray water Test Results, August 2008. A5. Electrical Insulation for Rotating Machines: Design, Evaluation, Aging, Testing and Repair, Greg C. Stone / Edward A. Boulter / Ian Culbert / Hussein Dhirani, 2004. Page | 49 8.2 Appendix B – Base Data from HYB/TOR 11kV Motor Lifetime R&D Project Test results are detailed within table 6-5 ‘Summary of Test Piece Ages’ of report Reference [18] and are used to provide a qualified life base ageing temperature and duration for the winding thermal life calculations detailed within this report. It should be noted that the accelerated ageing and tests were completed successfully and there was nothing in the final diagnostic test and inspection results to suggest that the test pieces could not have undergone further ageing, giving a further extension to the thermal life capability. Heysham 2 and Torness motor stators have a mix of Novobond S motors and SX motors. The test pieces, subject of Reference [18], were made from SX, the S material being no longer available. It was considered appropriate by the project to simulate the slightly more inferior S material by basing the test durations on the S activation energy. For the purposes of calculating the winding thermal life for HNB motor stators which only contain SX material, it is necessary to derive a base ageing test duration which can then be used to calculate service life based on the SX activation energy. Service Temperature: 92.4°C (365.55 K) - Section 2.2 of Reference [18] Average Claimed Service Age: 54.8years (480,048 hours) Novobond S Activation Energy E = 1.13eV Novobond SX Activation Energy E = 1.2eV Solving the Arrhenius Equation for t1 assuming an ageing test temperature of 160°C (433.15 K) and E of 1.13eV, gives an ageing test duration of 1777.54 hours. Therefore, the winding insulation has a qualified thermal life of 1777.54 hrs at 160°C. All winding thermal life calculations throughout this note use this base test temperature and duration to determine the equivalent insulation thermal life capability (in hours) for the HNB insulation material Novobond SX. For example, if a HNB motor stator ran continuously at 121°C, the insulation (Novobond SX) thermal life capability is calculated using the Arrhenius Equation as follows: Novobond SX Activation Energy (E) = 1.2eV T1base = (273.15 + 160) K T2 = (273.15 + 121) K t1base (the ageing time at T1base) = 1,777.54hrs k (the Boltzmann constant) = 8.617x10-5eVK-1 Solving the Arrhenius Equation for t2 results in a thermal service life capability = 42,795 hours. It should be noted that the qualified life of 1777.54 hrs at 160°C is equivalent to ~3800 hrs life at 150°C. This can be compared against the original Torness and Heysham 2 winding substantiation test programme in the 1980s which maintained the test motorette coils at 150°C for 2160 hrs (5 days in every 7 of the 3,000-hour programme) Reference [21]. Therefore, the recent ageing test programme increased the substantiated thermal life capability of the HNB stator winding by approximately 75% for a given constant temperature. Page | 50 Gas circ stator ID Present Berth STATOR Hunt 05 3A1 Date of rewind 28/08/1993 Installation date Data start date Data hours (Ferranti data period) Data years (Ferranti data period) Hours pre-2001 (pre-Ferranti) 29/08/1993 05/07/2002 STATOR Hink 12 STATOR Hink 05 STATOR Hunt 11 3B2 STATOR Hunt 02 3C1 16/09/1999 Complete 2015 17/09/1999 28/06/2001 30/09/2012 30/09/2012 29/10/2015 29/10/2015 112356 139008 51694 24694 11.97 12.83 15.87 5.90 2.82 0 125892 46451 16715 0 0 11.27 0.00 14.37 5.30 1.91 0.00 0.00 19.92 27.10 5.90 26.35 18.13 17.78 5.90 2.82 53.91 43.53 13.54 29.38 61.77 82.43 22.89 14.73 18.17 30.99 0 35.27 25.53 9.91 0 0 22/06/1989 3B1 prior to R3 stat 2012 20/01/1984 27/06/1996 23/06/1989 28/06/2001 30/09/2012 30/09/2012 20/01/1984 05/07/2003 28/06/1996 28/06/2001 130484 138681 51694 104893 14.90 15.83 5.90 43989 98723 Years pre-2001 (pre-Ferranti) 5.02 Total service years since rewind % thermal life expired during Ferranti data period % thermal life expired pre-2001 (pre-Ferranti) Total % thermal life expired Gas circ stator ID Present Berth Date of rewind Installation date Data start date Data hours (Ferranti data period) Data years (Ferranti data period) Hours pre-2001 (pre-Ferranti) Years pre-2001 (pre-Ferranti) Total service years since rewind % thermal life expired during Ferranti data period % thermal life expired pre-2001 (pre-Ferranti) Total % thermal life expired 72.08 STATOR Hunt 03 4A1 prior to R4 stat 2011 02/08/2011 02/08/2011 74.52 STATOR Hunt 20 4A2 13.54 STATOR Hunt 17 4B1 64.65 STATOR Hunt 18 4B2 28/03/1982 29/03/1982 06/07/2001 completed 2015 12/10/2017 12/10/2017 07/11/1987 08/11/1987 28/06/2001 35061 121388 7550 96432 4.00 13.86 0.86 0 122584 0.00 92.34 STATOR Hunt 15 4C2 STATOR Hunt 22.89 STATOR Hunt 06 4D1 STATOR Hunt 07 3D2 14.73 STATOR Hunt 19 4D2 21/06/2000 21/06/2000 06/07/2001 completed 2016 22/10/2017 22/10/2017 34399 134372 133217 7309 11.01 3.93 15.34 15.21 0.83 0 104540 0 8355 9276 0 13.99 0.00 11.93 0.00 0.95 1.06 0.00 4.00 27.85 0.86 22.94 3.93 16.29 16.27 0.83 21.04 47.73 5.26 36.97 21.36 62.86 47.19 2.97 0 21.04 48.2 95.93 0 5.26 40.07 77.04 0 21.36 3.91 66.77 3.28 50.47 0 2.97 SPARE SPARE SPARE SPARE Date of rewind 01/08/1994 01/06/2003 11/09/1986 planned 2018 Installation date Data start date Data hours (Ferranti data period) Data years (Ferranti data period) Hours pre-2001 (pre-Ferranti) 01/08/1994 06/07/2001 01/06/2003 01/06/2003 11/09/1986 06/07/2001 0 0 113505 116150 132735 0 12.96 13.26 15.15 0.00 STATOR Hunt 10 STATOR Hunt 12 Hunt 01 STATOR 50579 0 100907 0 Years pre-2001 (pre-Ferranti) 5.77 0.00 11.52 0 Total service years since rewind 18.73 13.26 26.67 0.00 58.75 66.53 78 0 26.18 0 59.18 0 84.93 66.53 137.18 0.00 Page | 51 3C2 08/07/2000 08/07/2000 06/07/2001 STATOR Hunt 08 Total % thermal life expired 87.30 STATOR Hunt 21 4C1 prior to R4 stat 2014 20/09/2014 20/09/2014 Gas circ stator ID Present Berth % thermal life expired during Ferranti data period % thermal life expired pre-2001 (pre-Ferranti) STATOR Hink 03 04 3D1 prior to R3 stat 2012 3A2 8.3 Appendix C – Data Analysis Results (valid August 2018) 8.4 Appendix D - Case study STATOR 12 versus STATOR 12.2 11kV motor stators STATOR 12.2 and STATOR 12 have a similar number of service years but a significant difference has been calculated in their percentage thermal life expired. Comparing these two machines clearly demonstrates the effect that service temperature has on the thermal life of the stator windings. Stators STATOR 12.2 and STATOR 12 were both deployed following rewind in the late 1980’s. Prior to the Ferranti data period each machine had approx. 11.5 years of service. Approximately 135,000 hours’ worth of logged Ferranti data has been analysed for each stator winding, with both machines having approximately 27 years total service. STATOR 12 was withdrawn from Reactor 4 in October 2017, whereas STATOR 12.2 is currently installed in Reactor 3 location 3A2. Table C1 – STATOR 12 vs. STATOR12 Stator ID STATOR 12.2 STATOR 12 Present location 3A2 SPARE Installation date 23/06/1989 11/09/1986 Data start date 28/06/2001 06/07/2001 Data years (Ferranti data period) 15.83 15.15 Years pre-2001 (pre-Ferranti) 11.27 11.52 Total service years (since rewind) 27.10 26.67 % thermal life expired during Ferranti data period 43.53 78.00 % thermal life expired pre-2001 (pre-Ferranti) 30.98 59.18 Total % thermal life expired 74.52 137.18 Page | 52 The temperature profiles for STATOR 12.2 and STATOR 12 are included in Section 11.5 Appendix E. Since 2001, both machines have continuously been deployed into a reactor location, other than a period of approximately a year for each, where the machine was withdrawn for maintenance. At first glance the temperature profiles for each machine look similar, with STATOR 12 service temperatures generally only slightly higher than those of STATOR 12.2. Further data analysis supports this, as the average Ferranti logged temperature of the STATOR 12.2 winding is 88°C compared with a modestly higher 93°C average temperature for the STATOR 12 winding. However close examination of the two charts shows that the extended/additional periods at elevated temperatures (>140°C) experienced by STATOR 12 significantly impacts the percentage thermal life expiry rate (gradient of the red line). Again, further data analysis supports this, with STATOR 12.2 winding temperatures >140°C for only 5 hours accounting for 0.06% of expired thermal life, and STATOR 12 winding temperatures >140°C for 1,302 hours, accounting for 25% of expired thermal life. In conclusion, although stators STATOR 12.2 and STATOR 12 have a similar number of service years, the periods of elevated temperatures experienced by STATOR 12 have resulted in its percentage thermal life expired being nearly double that of STATOR 12.2. Page | 53 8.5 Appendix E - % Thermal Life Expired Charts STATOR 05 in HNB location 3A1 as of August 2018 STATOR Page | 54 STATOR 12.2 in HNB location 3A2 as of August 2018 STATOR Page | 55 STATOR 05.2 in HNB location 3B1 as of August 2018 STATOR Page | 56 STATOR 11 in HNB location 3B2 as of August 2018 STATOR Page | 57 STATOR 02 in HNB location 3C1 as of August 2018 STATOR Page | 58 STATOR 03.2 in HNB location 3C2 as of August 2018 STATOR Page | 59 STATOR 04 in HNB location 3D1 as of August 2018 STATOR Page | 60 STATOR 07 in HNB location 3D2 as of August 2018 STATOR Page | 61 STATOR 03 in HNB location 4A1 as of August 2018 STATOR Page | 62 STATOR 20 in HNB location 4A2 as of August 2018 STATOR Page | 63 STATOR 17 in HNB location 4B1 as of August 2018 STATOR Page | 64 STATOR 18 in HNB location 4B2 as of August 2018 STATOR Page | 65 STATOR 21 in HNB location 4C1 as of August 2018 STATOR Page | 66 STATOR 15 in HNB location 4C2 as of August 2018 STATOR Page | 67 STATOR 06 in HNB location 4D1 as of August 2018 STATOR Page | 68 STATOR 19 in HNB location 4D2 as of August 2018 STATOR Page | 69 STATOR 08 Spare as of August 2018 STATOR Page | 70 STATOR 10 Spare as of August 2018 STATOR Page | 71 STATOR 12 Spare as of August 2018 STATOR Page | 72 8.6 Appendix F – 11kV Motor Stator Thermal Life Going Forward by Reactor Location R3 Berth % life expired at August 2018 3A1 STATOR HUNT 05 3A2 72.08% HINK 12 STATOR 3B1 74.52% STATOR HINK 05 13.54%STATOR HUNT 11 3B2 Planned deployment of HUNT 10 STATOR R3 2019 Stat Outage 3C2 HINK 03 STATOR 22.64% 75.63% 83.98% 88.94% 11.90% 21.00% 25.44% 34.54% 78.43% 87.53% 99.20% 108.30% Planned deployment of HINK 12 STATOR 2022 91.74% 23.80% 37.34% 90.33% 2023 94.54% 26.60% 40.14% 93.13% 2024 2025 97.34% 100.14% 29.40% 32.20% 42.94% 45.74% 95.93% 98.73% Planned deployment of HUNT 18 R4 Berth 4A1 % life expired STATOR HUNT 03 at August 2018 2019 R4 2020 Stat Outage 2021 2022 2023 2024 2026 4A2 21.04%STATOR HUNT 20 23.84% 32.94% Planned deployment of HUNT 08 35.74% 38.54% 41.34% 44.14% 46.94% SPARE SPARE % life expired STATOR HUNT 12 137.18%STATOR HUNT 01 at August 2018 4B1 95.93%STATOR HUNT 17 5.26%STATOR HUNT 18 98.73% 94.03% 96.83% 99.63% 102.43% 105.23% 108.03% 4B2 8.06% 17.16% Planned deployment STATOR of HUNT 11 19.96% 22.76% 25.56% 28.36% 31.16% SPARE SPARE 0.00%STATOR HUNT 08 84.93%STATOR HUNT 10 3D1 3D2 92.34% STATOR HUNT 04 22.89% STATOR HUNT 07 14.73% 66.53% 9.10% 2020 R3 2021 Stat Outage 81.18% Planned deployment of HUNT 01 3C1 64.65%STATOR HUNT 02 87.30% 96.40% 101.44% 31.99% 23.83% 104.24% 83.62% 34.79% 43.89% 26.63% 35.73% 111.10% 86.42% 46.69% 38.53% 113.90% 89.22% 49.49% 41.33% 116.70% 119.50% 92.02% 94.82% 52.29% 55.09% 44.13% 46.93% 4C1 4C2 77.04%STATOR HUNT 21 21.36%STATOR HUNT 15 4D1 4D2 66.77%STATOR HUNT 06 50.47%STATOR HUNT 19 2.97% 79.84% 73.75% 24.16% 33.26% 69.57% 78.67% 53.27% 62.37% 5.77% 14.87% 76.55% 79.35% 82.15% 84.95% 87.75% 36.06% 38.86% 41.66% 44.46% 47.26% 81.47% 84.27% 87.07% 89.87% 92.67% 65.17% 67.97% 70.77% 73.57% 76.37% 17.67% 20.47% 23.27% 26.07% 28.87% 66.53% Predicted % life used per non-outage year 2.8% This figure is based a years continual operation with winding temperatures at 100°C Predicted % life used per outage year This figure is based on an outage of 55 days duration with winding temperatures continuously at 130°C and the remainder of the 9.1% year with winding temperatures continuously at 100°C. Page | 73 8.7 Appendix G – Details from BS EN 60216-8:2013 Suggested Temperatures and durations for accelerated ageing tests. Table 8 - Suggested exposure temperatures and times Page | 74 8.8 T1 = T2 = t1 = k= Ea = Appendix H – Excel Data capture from Calculated Arrhenius Service Levels 413.15 343.15 168 8.62E-05 0.622 K K hours eV/K eV Ventilated Air = Ea = 60 kj/mol t2 = 23.1657 hours t2 = 46.3314 hours t2 = 92.66279 hours t2 = 185.3256 hours t2 = 370.6512 hours t2 = 741.3023 hours t2 = 1482.605 hours t2 = 2965.209 hours t2 = 5930.419 hours t2 = 11860.84 hours t2 = 23721.68 hours t2 = 47443.35 hours t2 = 94886.7 hours t2 = 189773.4 hours 0.965237 1.930475 3.86095 7.721899 15.4438 30.8876 61.7752 123.5504 247.1008 494.2016 988.4031 1976.806 3953.613 7907.225 days days days days days days days days days days days days days days 0.002644 0.005289 0.010578 0.021156 0.042312 0.084624 0.169247 0.338494 0.676988 1.353977 2.707954 5.415908 10.83182 21.66363 years years years years years years years years years years years years years years 150 degrees Celsius 140 degrees Celsius 130 degrees Celsius 120 degrees Celsius 110 degrees Celsius 100 degrees Celsius 90 degrees Celsius 80 degrees Celsius 70 degrees Celsius 60 degrees Celsius 50 degrees Celsius 40 degrees Celsius 30 degrees Celsius 20 degrees Celsius Figure 13 - Service life @ Ea = 60 kj/mol T1 = T2 = t1 = k= Ea = 413.15 343.15 168 8.62E-05 1.347 K K hours eV/K eV Stagnant Air = Ea = 130 kj/mol t2 = 1475.452 hours t2 = 2950.905 hours t2 = 5901.81 hours t2 = 11803.62 hours t2 = 23607.24 hours t2 = 47214.48 hours t2 = 94428.96 hours t2 = 188857.9 hours t2 = 377715.8 hours t2 = 755431.7 hours t2 = 1510863 hours t2 = 3021727 hours t2 = 6043453 hours t2 = 12086907 hours Figure 14 - Service life @ Ea = 130 kj/mol Page | 75 61.47719 122.9544 245.9087 491.8175 983.635 1967.27 3934.54 7869.08 15738.16 31476.32 62952.64 125905.3 251810.6 503621.1 days days days days days days days days days days days days days days 0.168431 0.336861 0.673723 1.347445 2.69489 5.389781 10.77956 21.55912 43.11825 86.23649 172.473 344.946 689.8919 1379.784 years years years years years years years years years years years years years years 150 degrees Celsius 140 degrees Celsius 130 degrees Celsius 120 degrees Celsius 110 degrees Celsius 100 degrees Celsius 90 degrees Celsius 80 degrees Celsius 70 degrees Celsius 60 degrees Celsius 50 degrees Celsius 40 degrees Celsius 30 degrees Celsius 20 degrees Celsius