CHEM 102 Organic Chemistry Tutorial Three 1. Attempt the following before the tutorial session. 2. Bring your notes and textbook to the tutorial. 1. Show a detailed Free-Radical chain mechanism of monobromination of ethane in the presence of light. 2. Give the mechanism for the electrophilic hydrohalogenation of 2-methyl-1butene using HCl. Indicate the major and minor product. 3. Indicate whether each of the following carbocations is 1o, 2o or 3o. a) + b) + + c) 4. What is the molecular formula and name of an alkyne with 10 carbon atoms? 5. Give the IUPAC names of the following compounds, a) b) Br c) d) 1 6. Draw the bond line structural formulae of the following molecules a) 3,3-dibromo-1-butyne b) 6,6-dipropyl-4-nonyne 7. Give the structure of the major product in the following reaction, 2HBr 8. Outline all structural criteria that must be satisfied for a compound to be aromatic. 9. Which of the following is aromatic? d) c) a) b) e) f) g) h) i) 2 10. Give the IUPAC names of the following compounds. Br c) b) a) Cl Cl d) e) f) 3 10. Provide the products for the following reactions + Br2 a) + Br2 + Cl2 FeBr3 b) FeCl3 c) 4