Chemistry 20: Module 1: Lesson 2 1 Assignment MODULE 1: LESSON 2 ASSIGNMENT This Module 1: Lesson 2 Assignment is worth 60 marks. The value of each assignment and each question is stated in the left margin. (60 Marks) Lesson 2 Assignment: Elements and Ions (4 marks) 1. Write the symbol corresponding to each of the following theoretical descriptions. a. 8 protons and 10 electrons b. 18 electrons and a net charge of 3+ c. 2 electrons and 2 protons d. 33 protons and 3 extra electrons (1 mark) 2. Cesium, mercury, and radium are examples of A. B. C. D. metals non-metals semi-metals compounds Answer: (1 mark) 3. Neon, argon, and krypton are part of a group of elements called A. B. C. D. alkali metals noble gases halogens alkaline-earth metals Answer: Chemistry 20: Module 1: Lesson 2 2 Assignment Use the following diagram to answer questions 5 to 7. (1 mark) 5. What is the atomic number of the element? A. B. C. D. 17 18 35 36 Answer: (1 mark) 6. What is the atomic mass of the element? Express your answer to two decimal places. Answer: (1 mark) 7. Which element is it? A. B. C. D. argon bromine chlorine magnesium Answer: Chemistry 20: Module 1: Lesson 2 (6 marks) (16 marks) 8. 9. 3 Assignment Draw condensed versions of the following ions. a. fluoride ion b. calcium ion c. nitride ion Complete the following table. Atom or Ion Name Symbol Number of Protons Number of Electrons 56 54 Charge Cs+ lost 1 34 cadmium ion Number of Electrons Lost or Gained 2– 46 Chemistry 20: Module 1: Lesson 2 4 Assignment MODULE 1: LESSON 3 ASSIGNMENT This Module 1: Lesson 3 Assignment is worth 50 marks. The value of each assignment and each question is stated in the left margin. (22 Marks) Lesson 3 Assignment: Ionic Compounds (10 marks) 1. Fill in the table with the required information. The first one is done for you. Atoms Combined Formula of Ions Involved Chemical Formula Name of Compound Na and Cl Na+ and Cl– NaCl sodium chloride Ca and Cl K and Br Fe3+ and OH– aluminium sulfide Nickel (II) cyanide Ga2(SO4)3 • 18H2O Cu3N2 Mg2+ and O2– Al and O AuBO3 (12 marks) 2. Complete the following table. Element Electronegativity Group Number 1.3 Number of Valence Electrons Number of Bonding Electrons 2 3.2 1.6 13 0.9 1 1.9 2.2 4 1 Number of Lone Pairs of Electrons Chemistry 20: Module 1: Lesson 2 5 Assignment MODULE 1: LESSON 4 ASSIGNMENT This Module 1: Lesson 4 Assignment is worth 22 marks. The value of each assignment and each question is stated in the left margin. (22 Marks) Lesson 4 Assignment: Molecular Elements and Compounds (6 marks) 1. Provide the name for each of the following compounds. a. CO2(g) b. NH3(g) c. P4O6(s) d. Cl2(g) e. H2O2(l) f. (6 marks) 2. NI3(s) Provide the correct chemical formula for each of the following compounds. a. bromine b. sulfur trioxide c. sulfur d. methanol e. phosphorus f. (10 marks) 3. sucrose Use the periodic table to calculate the electronegativity difference for each pair of elements. Determine whether each compound is non-polar covalent, polar covalent, or ionic. a. the bond between Mg and F atoms in MgF2 b. the bond between H and S atoms in H2S c. the bond between Al and O atoms in Al2O3 d. the bond between Br atoms in Br2 e. the bond between N and H atoms in NH3 Chemistry 20: Module 1: Lesson 2 6 Assignment MODULE 2: LESSON 1 ASSIGNMENT Lesson 1 Assignment: Bonding Theory and Lewis Formulas 1. Draw the Lewis symbols for the first three elements of group 2 on the periodic table. How are these elements similar? Answer: 2. Draw the Lewis symbols for the first three elements of group 17 on the periodic table. How are these elements similar? Answer: 3. Draw the Lewis formula and structural diagram for the following molecular elements. a. Iodine (I2) Answer: b. Nitrogen (N2) Answer: Chemistry 20: Module 1: Lesson 2 4. 7 Assignment Draw the Lewis formula and structural diagram for the following molecular compounds. a. hydrogen sulfide, H2S Answer: b. hydrogen cyanide, HCN Answer: c. methanol, CH3OH Answer: 5. Identify the central atoms for each of the compounds drawn in question 4 above. Answer: Chemistry 20: Module 1: Lesson 2 8 Assignment MODULE 2: LESSON 2 ASSIGNMENT Lesson 2 Assignment: Molecular Shapes and VSEPR Theory 1. For each compound, draw the Lewis formula and stereochemical formula. Identify its VSEPR geometry. a. BeCl2 Answer: b. PF3 Answer: c. BBr3 Answer: f. CH2O Answer: g. CS2 Answer: Chemistry 20: Module 1: Lesson 2 9 Assignment LESSON 2— MOLECULAR SHAPES AND VSEPR THEORY Representing Atoms Using Models When using models to represent atoms, lone pairs of electrons tend not to be represented. In molecular model kits the location of bonding electrons is indicated by holes. Since bonding electrons (bond pairs) are used to form covalent bonds between atoms, their location is identified by the connections between atoms. Using the information below, you will be able to identify where bond pairs can develop for a variety of non-metallic elements. Element Lewis Formula Lone Pairs Bonding Attachment Location of Attachment Points Electrons Points Hydrogen 0 1 1 Beryllium 0 2 2 Boron 0 3 3 Carbon 0 4 4 Chemistry 20: Module 1: Lesson 2 10 Assignment Nitrogen 1 3 3 Oxygen 2 2 2 Halogen (fluorine, chlorine, iodine, bromine) 3 1 1 Chemistry 20: Module 1: Lesson 2 11 Assignment LESSON 2 — MOLECULAR SHAPES AND VSEPR THEORY Try This: Using VSEPR Theory to Predict Molecular Shape In Chemistry 20 molecule shape focuses on the arrangement of atoms around central atoms. As you will learn in this activity, the presence of bond pairs as well as lone pairs of electrons influences a molecule’s shape. To complete this activity you will need to be familiar with the following electron pair arrangements and the shapes that result. Trigonal Linear Angular Tetrahedral Trigonal Planar Pyramidal Complete the following table as you work through the activity. Molecule beryllium dihydride, BeH2 boron trihydride, BH3 methane, CH4 ammonia, NH3 water, H2O Lewis Formula Bond Pairs Lone Pairs Total Pairs Electron Pair Arrangement (shape) Stereochemical Formula (3-D representation) Chemistry 20: Module 1: Lesson 2 hydrogen chloride, HCl oxygen, O2 nitrogen, N2 carbon dioxide, CO2 12 Assignment Chemistry 20: Module 1: Lesson 2 13 Assignment MODULE 2: LESSON 3 ASSIGNMENT Lesson 3 Assignment: Molecular Polarity Lab: Evidence for Polar Molecules Part 1: Pre-Lab 1. Draw stereochemical formulas for the following molecules. (6 marks) Substance Water Pentane Ethanol Chemical Formula H2O C5H12 C2H5OH Methanol Don’t do CH3OH Don’t do Structural Formula Don’t do Stereochemical Formula DO NOT DO DO NOT DO 2. Complete a hypothesis to predict which substances are polar. Justify your selections. (4 marks) Answer: Chemistry 20: Module 1: Lesson 2 14 Assignment MODULE 2: LESSON 4 ASSIGNMENT Lesson 4 Assignment: Intermolecular Forces Part 2 2. Complete Lab Exercise 3. A, "Boiling Points and Intermolecular Forces," on page 110 of your textbook. a. Place a copy of your graph here. (10 marks) Chemistry 20: Module 1: Lesson 2 15 Assignment b. Which compounds do not fit the pattern for the rest in their group? Why? (3 marks) Answer: (10 marks) 4. Complete the following table. The first row has been done for you. Molecule HBr Structural Shape Polarity Types of Intermolecular linear polar dipole-dipole NF3 GeH4 NI3 CF4 HF 6. Given the gases methane, CH4(g), and sulfur dioxide, SO2(g), predict which of the two will be more soluble in water. Explain your answer. (2 marks) Answer: Chemistry 20: Module 1: Lesson 2 16 Assignment Unit 1 Review Assignment: (133) Please submit all your work when you have completed this assignment. Show all work wherever necessary. 1. Complete energy level diagrams and the table for the following elements: (10 marks) Name Magnesium Oxygen Phosphorus Calcium Hydrogen Energy Level Diagram Number of protons Number of electrons Number of valence electrons Number of neutrons Chemistry 20: Module 1: Lesson 2 17 Assignment 2. Complete energy level diagrams and the table for the following ions: (8 marks) Name Energy Level Diagram Number of protons Number of electrons Number of valence electrons Number of neutrons Hydrogen ion Oxide Chlorine ion Potassium ion 3. What is the atomic number equal to for elements? (1 mark) 4. What subatomic particle can you find the quantity of using atomic mass? (1 mark) 5. In an element, the number of protons equals the number of electrons which allows it to have no net charge. In a cation, there are __________(more/less) electrons than protons, giving it a ___________(positive/negative) charge. These are most likely ___________ (metals/nonmetals) on your periodic table. In a anion, there are __________(more/less) electrons than protons, giving it a ___________(positive/negative) charge. These are most likely ___________ (metals/nonmetals) on your periodic table. (6 marks) Chemistry 20: Module 1: Lesson 2 18 Assignment 6. Complete the following table for ionic compounds, molecular compounds and elements. (18) Ionic/ Molecular/ Element Ionic Name Formula IF Ionic, state if soluble in water. Sodium Chloride NaCl aq Carbon monoxide H2SO4 Iron(III)oxide CuSO4 Sulphur Methane Methanol Mg(OH)2 KMnO4 If you still require extra practice on naming, review chapter 1 in your Nelson textbook or contact your teacher for additional resources. 7. Complete the following table: (4) Ionic, Molecular, Or Acid (I,M,A) Name Chemical Formula Potassium iodide C3H8(g) KMnO4(s) Copper(II)sulfate pentahydrate Na2CO3(s) Fe2O3(s) Ammonium sulfate C2H5OH(l) Nitrogen tribromide HF(aq) Johnny was a chemist’s son, But Johnny is no more… What Johnny thought was H2O, Was H2SO4. Chemistry 20: Module 1: Lesson 2 19 8. Briefly describe the Kinetic Molecular Theory (2 marks) 9. Balance these equations! (15 marks) 1) ____ AlBr3 + ____ K ____ KBr + ____ Al 2) ____ FeO + ____ PdF2 ____ FeF2 + ____ PdO 3) ____ P4 + ____ Br2 ____ PBr3 4) ____ LiCl + ____ Br2 ____ LiBr + ____ Cl2 5) ____ PbBr2 + ____ HCl ____ HBr + ____ PbCl2 6) ____ CoBr3 + ____ CaSO4 ____ CaBr2 + ____ Co2(SO4)3 7) ____ Na3P + ____ CaF2 ____ NaF + ____ Ca3P2 8) ____ Mn + ____ HI ____ H2 + ____ MnI3 9) ____ Li3PO4 + ____ NaBr ____ Na3PO4 + ____ LiBr 10) ____ CaF2 + ____ Li2SO4 ____ CaSO4 + ____ LiF 11) ____ HBr + ____ Mg(OH)2 ____ MgBr2 + ____ H2O 12) ____ LiNO3 + ____ CaBr2 ____ Ca(NO3)2 + ____ LiBr 13) ____ AgNO3 + ____ Li ____ LiNO3 + ____ Ag 14) ____ Si(OH)4 + ____ NaBr ____ SiBr4 + ____ NaOH 15) ____ NaCN + ____ CuCO3 ____ Na2CO3 + ____ Cu(CN)2 Assignment Chemistry 20: Module 1: Lesson 2 20 Assignment 10. Fill in the following table (18) Chemical Formula Lewis Structure Stereochemical And VSPER shape Intramolecular forces Intermolecular Forces Solubility in Water (Y/N) CH2O BBr3 OF2 SiH4 HCN HNO 11. When the energy from temperature is reduced (temperature is reduced), what causes carbon monoxide to go from a gas to a liquid? – 2 marks Chemistry 20: Module 1: Lesson 2 21 Assignment 12. Which of the following hydrocarbons would have the higher boiling point (explain): CH 3OH or C2H5OH? -2 marks 13. Identify the type of substance that is material X from the following properties and justify your answer. – 2 marks Melting Point Boiling Point Conductivity Solubility in water Material X 750oC 2250oC No No 14. Identify the following bonds within (intramolecular) the molecule or compound as: a. non polar covalent b. polar covalent c. ionic 1. C3H8 2. LiF 3. CO2 15. Which statement below is true for the Aluminum atom: a. aluminum has one bonding pair of electrons b. aluminum has three bonding pairs of electrons and one lone pair c. aluminum has only three bonding electrons d. aluminum has one lone pair and three bonding electrons Chemistry 20: Module 1: Lesson 2 22 Assignment 16. Which statement below is false for the Phosphorus atom: a. Phosphorus has one lone pair. b. Phosphorus has 5 valence electrons. c. Phosphorus bonds with three others to form its basic molecular compound. d. Phosphorus has three bonding pairs. 17. Which statement is true for the nitrogen molecule: a. It has 3 bond pairs b. It has 1 lone pair c. It has 3 bonding electrons d. It has 1 lone pair and 3 bonding electrons 18. Which statement is true for phosphorus trichloride: a. It forms 3 weak bonds. b. It does not dissolve in water. c. It creates 3 covalent bonds. d. It is ionic. 19. How many electrons are in the valence level of P? a. 2 b. 3 c. 4 d. 5 20. How do the electronegativities compare on the periodic table within a period? a. Electronegativities go up the further right you go. b. Electronegativities go up the further left you go. c. Electronegativities go down the further down you go. d. Electronegativities go down the further up you go. 21. Which does NOT follow according to VSEPR theory: a. Valence electrons are paired in a molecule or polyatomic ion. b. Valence pairs repel each other electrostatically. c. Atoms with greater electronegativity will have a stronger pull towards bonded pairs of electrons. d. The molecular shape is determined by the positions of the electron pairs when they are a maximum distance apart. Chemistry 20: Module 1: Lesson 2 23 Assignment For questions 22-26 identify the correct electron pair arrangement according to the VSEPR theory. Use the following data to solve these questions. Electron pair arrangements i. Linear ii. Trigonal Planar iii. V – Shaped iv. Trigonal Pyramidal v. Tetrahydral 22. CO2 23. NH3 24. BCl3 25. SiCl4 26. OCl2 27. Which type of bond has the most electronegative difference: a. Hydrogen Bond b. Polar Covalent Bond c. Non-Polar Covalent Bond d. Ionic Bond 28. Circle ALL the Intermolecular forces that are found within distilled water. a. Hydrogen bonding b. Dipole- Dipole c. London Forces d. Ionic Bonding e. All of the above 29. “Doping” is the process of adding a tiny quantity (5 ppm) of a group 13 or 15 element to: a. Make an ionic crystal conductive b. Make a covalent network crystal conductive c. Strengthen bonds within a crystal lattice d. Increase melting point of a crystal Chemistry 20: Module 1: Lesson 2 24 Assignment Please be specific and use theories and scientific concepts discussed in class whenever possible to support your answer. 30. Which element has: 2 bonding electrons, 2 lone pairs and 3 energy levels? (1) 31. Name and draw (using LDD) a compound with 3 bond pairs and 1 lone pair of electrons. (2) 32. What kind of bond forms between oxygen atoms in an oxygen molecule (O2)? Be specific. (1) For questions 33-36, use Lewis Diagrams to draw the following. (4 marks) 33. [NH4]+ 34. CH2O 35. CH3SH 36. HCN 37. Explain a process to determine whether an unknown liquid is polar or non polar? (2) Chemistry 20: Module 1: Lesson 2 25 Assignment 38. Mechanics in a shop spill oil on a regular basis. Describe an environmentally safe method of cleaning these spills and justify with your reasoning. (4) 39. Explain why chlorine gas (Cl2(g)) will not dissolve in water but would in hexane (C6H14(l)). (3) 40. Explain the boiling points of the following hydrogen compounds with relation to each other. Describe the similar forces and the difference in boiling points. (3) Compound (at SATP) CH4(g) SiH4(g) Electrons 10 18 Boiling Point (oC) -164 -112 41. Describe the physical property that allows an insect to walk on top of water? (2) Chemistry 20: Module 1: Lesson 2 26 Assignment Use the table to answer questions 42 Unknown Chloride Melting Point (oC) Boiling Point (oC) Solubility in water Solubility in C6H6(l) XCla -75 53 very low high XClb 850 1480 high very low 42. What type of bonding would be in each chloride listed (justify your answer)? (4)