ENVIRONMENTAL SCIENCES An Interdisciplinary Monograph Series Third Edition air ~iSll tió~ VOLUME II The Effects of Air Pollution edited by Arthur C. Stern ACADEMIC PRESS, INC. A Subsidiary of Harcourt Brace Jovanovich, Publishers AIR POLLUTION THIRD EDITION VOLUME II The Effects of Air Pollution Edited by Arthur C. Stern Department of Environmental Sciences and Engineering School of Public Health University of North Carolina at Chapel Hill Chapel Hill, North Carolina ACADEMIC PRESS New York San Francisco London 1977 A Subsidiary of Harcourt Brace Jovanovich, Publishers E . rJt2.0 IT c' natura BIBLIOTECA ®EATAO i1AI1O 4 Ab «TUGU= 0 6. 0 8 112 COPYRIGHT © 1977, BY ACADEMIC PRESS, INC. ALL RIGHTS RESERVED. NO PART OF THIS PUBLICATION MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM OR BY ANY MEANS, ELECTRONIC OR MECHANICAL, INCLUDING PHOTOCOPY, RECORDING, OR ANY INFORMATION STORAGE AND RETRIEVAL SYSTEM, WITHOUT PERMISSION IN WRITING FROM THE PUBLISHER. ACADEMIC PRESS, INC. 111 Fifth Avenue, New York, New York 10003 United Kingdom Edition published by ACADEMIC PRESS, INC. (LONDON) LTD. 24/28 Oval Road, London NW1 Library of Congress Cataloging in Publication Data Stern, Arthur Cecil. The effects of air pollution. (His Air pollution, third edition ; v. 2) (Environmental sciences) Bibliography: p. Includes index. Air—Pollution. 2. Air—Pollution—Physiologi1. cal effect. Title. I. II. Series: Environmental sciences. TD883.S83 1976 voL 2 363.6 77-7189 ISBN 0-12-666602-4 PRINTED IN THE UNITED STATES OF AMERICA Contents Lint of Contributors Preface Contents of Other Volumes xi xiii xv Park A EFFECTS ON PHYSICAL AND ECONOMIC SYSTEMS L Effects on the Physical Properties of the Atmosphere Elmer Robinson 1 I. Introduction 3 II. Mathematical Concepts of Visibility 27 III. Meteorological Aspects of Visibility IV. Air Pollution Effects on Weather and Atmospheric Conditions 37 60 V. Conclusions 61 References 2. Effects on Economic Materials and Structures John E. Yocom and James B. Upham I. Introduction II. Mechanisms of Deterioration in Polluted Atmospheres III. Factors that Influence Atmospheric Deterioration . . IV. Methods of Measuring Atmospheric Deterioration . V. Materials Damage VI. Economics of Air Pollution Effects References 65 • 66 • 67 • 69 74 108 112 vii viii CONTENTS 3. Effects on Indoor Air Quality John E. Yocom, William A. Coté, and Ferris B. Benson 117 I. Introduction 118 II. Factors Influencing Indoor Air Quality 120 III. Indoor-Outdoor Air Quality Relationships IV. Effects of Indoor Generation of Pollutants and Other Factors 132 on Indoor Air Quality 153 References PART B EFFECTS ON BIOLOGICAL SYSTEMS 4. Effects on Vegetation: Native, Crops, Forests Walter W. Heck and C. Stafford Brandt I. Introduction II. Air Pollution Effects on Vegetation III. Factors Affecting the Response of Vegetation to Air Pollutants IV. Effects of Air Pollutants on Biomass and Yield . . V. Dose—Response of Vegetation to Air Pollutants . . VI. Vegetation as a Biological Monitor for Air Pollutants . VII. Economic Evaluation of Response VIII. Vegetation as a Sink for Air Pollutants—Greenbelts . IX. Reduction of Air Pollution Injury to Vegetation . . References 158 161 176 185 184 203 212 215 218 220 5. Biological Effects of Air Pollutants David L. Coffin and Herbert E. Stokinger I. Photochemical Oxidants II. Ozone III. Nitrogen Dioxide IV. Sulfur Oxides V. Carbon Monoxide VI. Particulate Material VII. Interaction of Air Pollutants and Biological Agents VIII. Real and Synthetic Atmospheres IX. Air Pollution and Domestic Animals References 232 233 264 289 305 312 324 336 341 345 6. Organic Particulate Pollutants—Chemical Analysis and Bioassays for Carcinogenicity Dietrich Hoffmann and Ernst L. Wynder I. Introduction II. Standard Laboratory Conditions 362 364 CL I.11, jv:.j¿iUL 1.iiii1GQNLl'P ix CONTENTS III. Fractionation IV. Neutral Fraction V. Acidic Fraction VI. Basic Fraction VII. Bioassay VIII. Outlook References 365 368 414 418 423 445 445 7. Effects of Air Pollution on Human Health John R. Goldsmith and Lars T. Friberg I. Introduction II. Acute Air Pollution Effects and Their Detection . . . III. Combined Effects of Sulfur Oxides and Black Suspended Matter IV. Effects of Gaseous Pollutants V. Particulate Pollutants and Their Effects VI. Air Pollution as a Causal Factor in Chronic Disease References 458 469 483 493 531 553 590 PART C AIR POLLUTION LITERATURE RESOURCES 8. Literature Resources Peter Halpin I. State of the Literature II. Primary Resources III. Secondary Resources IV. Tertiary Resources V. Newsletters VI. Translations VII. Audiovisual Materials VIII. The Information Network IX. Bibliographies, Directories, and Guides References S & ct Index 612 613 649 657 659 659 660 661 661 662 681 Third Edition AIR POLLUTION Edited by ARTHUR C. STERN Volumes in the ENVIRONMENTAL SCIENCES Series FROM REVIEWS OF THE SECOND EDITION: "The American literature-in fact, the whole field of air pollution and its control is indeed fortunate to be in possession of this encyclopedic treatise. Without question, it is the most complete work in existence at this time .... No worker really interested in air pollution and its control should be Leonard Greenburg in AMERICAN JOURNAL OF PUBLIC HEALTH withouta Copy.. ""Amply meets its stated objective, to be the most comprehensive analysis of air pollution available."" • Byron A Berg in JOURNAL OF OCCUPATIONAL MEDICINE " will be of great service to all who are concerned with the many aspects and problems or -A. Parker in NATURE mitigation of air pollution. - Volume I/Air Pollutants, Their Transformation and Transport 1976, 752 pp. / ISBN 0-12-666601-6 THE POLLUTANTS Leslie A. Chambers, Classification and Extent of Air Pollution Problems. Paul Urone, The Primary Air Pollutants-Gaseous: Their Occurrence, Sources, and Effects. Morton Corn, Aerosols and the Primary Air Pollutants--Nonviable Particles: Their Occurrence, Properties, and Effects. Alvin R. Jacobson and Samuel C. Mor ris, The Primary Air Pollutants--Viable Particulates Their Occurrence, Sources, and Effects Merril Eisenbud, The Primary Air Pollutants-Radioactive: Their Occurrence, Sources, and Effects. THE TRANSFORMATION OF AIR POLLUTANTS A. J. Haagen•Smit and Lowell G. Wayne, Atmospheric Reactions and Scavenging Processes. D. M. Whelpdale and R. E. Munn, Global Sources, Sinks, and Transport of Air Pollution. THE TRANSPORT OF AIR POLLUTANTS Raymond C. Wanta and William P. Lowry, The Meteorological Setting for Dispersal of Air Pollutants. Gordon H. Strom, Transport and Diffusion of Stack Effluents. Warren B. Johnson, Ralph C. Sklarew, and D. Bruce Turner, Urban Air Quality Simulation Modeling. E. Wendell Hewson, Meteorological Measurements. Robert A. McCormick and George C. Holzworth, Air Pollution Climatology. Volume III/Measuring, Monitoring, and Surveillance of Air Pollution 1976, 824 pp. / ISBN 0-12-666603- 2 SAMPLING AND ANALYSIS Paul M. Glover, Particulate Matter Sampling and Sizing. Philip W. West, Analysis of Inorganic Particulates Walter C. McCrone, Microscopy and Pollution Analysis. H,+rman D. Axelrod and James P. Lodge, Jr., Sampling and Calibration of Gaseous Pollutants. Aubrey Paul Altschuller, Hydrocarbons and Carbon Oxides Donald F. Adams, Sulfur Compounds Morris Katz, Nitrogen Compounds and Oxidants. Austin H. Phelps, Odors. AMBIENT AIR SURVEILLANCE Robert J. Bryan, Ambient Air Quality Surveillance. Charles W. Gruber and George Jutze, Air Pollution Effects Surveillance, Harry F. Schulte, Radionuclide Surveillance. Charles E. Zimmer, Air Quality Data Handling and Analysis Richard D. Cadle, Global Monitoring and Surveillance of Air Pollution. SOURCE SURVEILLANCE Harold J. Paulus and Raymond W. Thron, Stack Sampling. John S. Nader, Source Monitoring. William F. Biller and John Harkins, Measurement, Testing, and Surveillance of Air Pollution from Mobile Sources James R. Hammerle, Emission Inventory. Academic Press NEW YORK SAN FRANCISCO LONDON A Subsidia,y of Ha,cUUrt Brace Ju Va'iov.cP Publsile/, Academic Press. Inc. 111 FIFTH AVENUE NEW YORK NEW YORK 10003 Academk: Press, Inc. (London) Ltd. taro , ,r...,„t• t r ,•14,•,•<1 ,•••15., 5995i4 , 24.28 OVAL ROAD LONDON NW' 7DX L... Harcourt 300 NORTH Group (Australia) T R Ltd. PO BOX 300 NORTH RUDE NSW 2113 AUSTRALIA AUSTRALIA ISBN 0-12-666602-4