Nuclear physics Chapter 12.2 Exercises Exercises Chapter 12 Unit 12.2 Unit 12.2 Exercises 1 / 28 Outline I Q1 Q2 Q3 Q4 Q5 Q6 Q7 Q8 Q9 Q10 Q11 Q12 Q13 Q14 Q15 Q16 Q17 Unit 12.2 Exercises 2 / 28 Q1 An alpha particle is fired head-on at a stationary gold nucleus from far away. Calculate the initial speed of the particle so that the distance of closest approach is 8.5 × 10−15 m. (Take the mass of the alpha particle to be 6.64 × 10−27 kg.) Unit 12.2 Exercises 3 / 28 Q1 An alpha particle is fired head-on at a stationary gold nucleus from far away. Calculate the initial speed of the particle so that the distance of closest approach is 8.5 × 10−15 m. (Take the mass of the alpha particle to be 6.64 × 10−27 kg.) By conservation of energy 1 2 k(2e)(79e) mv = 2 r d 2k(2e)(79e) v= md s = (2)(8.99 × 109 )(2)(1.6 × 10−19 )(79)(1.6 × 10−19 ) (6.64 × 10−27 )(8.5 × 10−15 ) = 3.7 × 107 m s−1 Unit 12.2 Exercises 3 / 28 Q2 A particle of mass m and charge e is directed from very far away toward a massive (M >> m) object of charge +Ze with a velocity v , as shown in the diagram. The distance of closest approach is d. Sketch (on the same axes) a graph to show the variation with separation of: a. the particle’s kinetic energy b. the particle’s electric potential energy. v d Ze Unit 12.2 Exercises 4 / 28 Q2 The idea is that since the nucleus is very massive will not A particle of mass m and charge e is directed from very faritaway toward a massive (M >> m)atobject of charge +Ze with a velocity as shown in recoil. Then the point of closest separation thev ,kinetic the diagram. Thebe distance of closest is d. as Sketch (on the same energy will a minimum andapproach will increase the separation axes)increases. a graph to The showpotential the variation withis separation energy given by of: a. the particle’s kinetic energy kZe 2 b. the particle’s electric potential energy. E = P r and so will be a maximum at the point of closet separation and will tend to zero as the separation increases. v d Ze Unit 12.2 Exercises 4 / 28 Q2 A particle of mass m and charge e is directed from very far away toward a massive (M >> m) object of charge +Ze with a velocity v , as shown in the diagram. The distance of closest approach is d. Sketch (on the same axes) a graph to show the variation with separation of: a. the particle’s kinetic energy b. the particle’s electric potential energy. v d Ze Unit 12.2 Exercises 4 / 28 Q2 A particle of mass m and charge eEnergy/J is directed from very far away toward a massive (M >> m) object of charge +Ze with a velocity v , as shown in the diagram. The distance of closest approach is d. Sketch (on the same axes) a graph to show the variation with separation of: a. the particle’s kinetic energy b. the particle’s electric potential energy. v Seperation (to left) Minimum Seperation d Seperation (to right) Ze Unit 12.2 Exercises 4 / 28 Q2 A particle of mass m and charge eEnergy/J is directed from very far away toward a massive (M >> m)KE object of charge +Ze with a velocity v , as shown in the diagram. The distance of closest approach is d. Sketch (on the same axes) a graph to show the variation with separation of: a. the particle’s kinetic energy b. the particle’s electric potential energy. v Seperation (to left) Minimum Seperation d Seperation (to right) Ze Unit 12.2 Exercises 4 / 28 Q2 A particle of mass m and charge e is directed from very far away toward a massive (M >> m) object of charge +Ze with a velocity v , as shown in the diagram. The distance of closest approach is d. Sketch (on the same axes) a graph to show the variation with separation of: a. the particle’s kinetic energy b. the particle’s electric potential energy. v d Ze Unit 12.2 Exercises 4 / 28 Q2 A particle of mass m and charge eEnergy/J is directed from very far away toward a massive (M >> m)KE object of charge +Ze with a velocity v , as shown in the diagram. The distance of closest approach is d. Sketch (on the same axes) a graph to show the variation with separation of: a. the particle’s kinetic energy b. the particle’s electric potential energy. v Seperation (to left) Minimum Seperation d Seperation (to right) Ze Unit 12.2 Exercises 4 / 28 Q2 A particle of mass m and charge eEnergy/J is directed from very far away toward a massive (M >> m)KE object of charge +Ze with a velocity v , as shown in the diagram. The distance of closest approach is d. Sketch (on the same axes) a graph to show the variation with separation of: a. the particle’s kinetic energy b. the particle’s electric potential energy. PE v Seperation (to left) Minimum Seperation d Seperation (to right) Ze Unit 12.2 Exercises 4 / 28 Q3 a. Deviations from Rutherford scattering are expected when the alpha particles reach large energies. Suggest an explanation for this observation. b. Some alpha particles are directed at a thin foil of gold (Z = 79) and some others at a thin foil of aluminium (Z = 13). Initially, all alpha particles have the same energy. This energy is gradually increased. Predict in which case deviations from Rutherford scattering will first be observed. Unit 12.2 Exercises 5 / 28 Q3 a. Deviations from Rutherford scattering are expected when the alpha particles reach large energies. Suggest an explanation for this observation. Unit 12.2 Exercises 6 / 28 Q3 a. Deviations from Rutherford scattering are expected when the alpha particles reach large energies. Suggest an explanation for this observation. As the energy increases the alpha particle can approach closer and closer to the nucleus. Eventually it will be within the range of the strong nuclear force and some alphas will be absorbed by the nucleus and will not scatter. Unit 12.2 Exercises 6 / 28 Q3 b. Some alpha particles are directed at a thin foil of gold (Z = 79) and some others at a thin foil of aluminium (Z = 13). Initially, all alpha particles have the same energy. This energy is gradually increased. Predict in which case deviations from Rutherford scattering will first be observed. Unit 12.2 Exercises 6 / 28 Q3 b. Some alpha particles are directed at a thin foil of gold (Z = 79) and some others at a thin foil of aluminium (Z = 13). Initially, all alpha particles have the same energy. This energy is gradually increased. Predict in which case deviations from Rutherford scattering will first be observed. Since the nuclear charge of aluminium is smaller than that of gold the alphas will get closer to aluminium and so will experience the nuclear force first. Hence deviations will first be seen for aluminium. Unit 12.2 Exercises 6 / 28 Q4 Show that the nuclear density is the same for all nuclei. (Take the masses of the proton and neutron to be the same.) Unit 12.2 Exercises 7 / 28 Q4 Show that the nuclear density is the same for all nuclei. (Take the masses of the proton and neutron to be the same.) The radius of a nucleus of mass number A is 1 R = 1.2 × A 3 × 10−15 m and its mass is M = Amn (where mn is the mass of a nucleon) The density is therefore ρ= M 4 3 3 πR = Amn 4 3 π(1.2 ×A 1 ×10−15 3 )3 = 4 3 π(1.2 mn × 10−15 )3 and so is independent of A. An estimate of this density is Unit 12.2 Exercises 7 / 28 Q4 Show that the nuclear density is the same for all nuclei. (Take the masses of the proton and neutron to be the same.) An estimate of this density is ρ= Unit 12.2 1.67 × 10−27 ≈ 1017 kg m−3 −15 3 × 10 ) 4 3 π(1.2 Exercises 7 / 28 Q5 a. State the evidence in support of nuclear energy levels. Radium’s first excited nuclear level is 0.0678 MeV above the ground state. b. Write down the reaction that takes place when radium decays from the first excited state to the ground state. c. Find the wavelength of the photon emitted. Unit 12.2 Exercises 8 / 28 Q5 a. State the evidence in support of nuclear energy levels. Unit 12.2 Exercises 9 / 28 Q5 a. State the evidence in support of nuclear energy levels. The main evidence is the discrete energies of alpha particles and gamma particles in alpha and gamma decay. Unit 12.2 Exercises 9 / 28 Q5 Radium’s first excited nuclear level is 0.0678 MeV above the ground state. b. Write down the reaction that takes place when radium decays from the first excited state to the ground state. Unit 12.2 Exercises 9 / 28 Q5 Radium’s first excited nuclear level is 0.0678 MeV above the ground state. b. Write down the reaction that takes place when radium decays from the first excited state to the ground state. 226 88 Unit 12.2 0 Ra →226 88 Ra +0 γ Exercises 9 / 28 Q5 Radium’s first excited nuclear level is 0.0678 MeV above the ground state. c. Find the wavelength of the photon emitted. Unit 12.2 Exercises 9 / 28 Q5 Radium’s first excited nuclear level is 0.0678 MeV above the ground state. c. Find the wavelength of the photon emitted. hf = hc = ∆E λ hc λ= ∆E (6.63 × 10−34 )(3.0 × 108 )) = (0.0678 × 106 )(1.6 × 10−19 ) = 1.83 × 10−11 m Unit 12.2 Exercises 9 / 28 Q6 238 Plutonium (242 94 Pu) decays into uranium ( 92 U) by alpha decay. The energy of the alpha particles takes four distinct values: 4.90 MeV, 4.86 MeV, 4.76 MeV and 4.60 MeV. In all cases a gamma ray photon is also emitted except when the alpha energy is 4.90 MeV. Use this information to suggest a possible nuclear energy level diagram for uranium. Unit 12.2 Exercises 10 / 28 Q6 238 Plutonium (242 94 Pu) decays into uranium ( 92 U) by alpha decay. The energy of the alpha particles takes four distinct values: 4.90 MeV, 4.86 MeV, 4.76 MeV and 4.60 MeV. In all cases a gamma ray photon is also emitted except when the alpha energy is 4.90 MeV. Use this information to suggest a possible nuclear energy level diagram for uranium. We are told that no photon is emitted when the alpha particle has an energy of 4.9 MeV, so the difference between the plutonium and uranium ground state energies must be ∆E = 4.9 MeV. If the alpha energy is less than 4.9 MeV and a photon is emitted that means there must be an excited state of the uranium nucleus, and the difference between the alpha energy and 4.9 MeV tells you the energy of the excited state. Unit 12.2 Exercises 10 / 28 Q6 238 Plutonium (242 94 Pu) decays into uranium ( 92 U) by alpha decay. The energy of the alpha particles takes four distinct values: 4.90 MeV, 4.86 MeV, 4.76 MeV and 4.60 MeV. In all cases a gamma ray photon is also emitted except when the alpha energy is 4.90 MeV. Use this information to suggest a possible nuclear energy level diagram for uranium. You have a two step process: 1. the plutonium nucleus emits an alpha particle and forms a uranium nucleus 2. the uranium nucleus may be formed in an excited state - if so it will relax to the ground state by emitting a gamma ray photon Unit 12.2 Exercises 10 / 28 Q6 242 Pu 94 α emmision < 4.9 MeV ∆E = 4.9 MeV α emmision = 4.9 Mev γ emmsion 238 U 92 Unit 12.2 Eα < 4.9 MeV Exercises Excited State Eγ Ground State 11 / 28 Q7 The diagram shows a few nuclear energy levels for 40 Ar, 40 K 18 19 and 40 Ca. 20 40 K 19 II III I 40 Ca 20 IV 40 A 18 Identify the four indicated transitions. Unit 12.2 Exercises 12 / 28 Q7 The diagram shows a few nuclear energy levels for 40 Ar, 40 K 18 19 and 40 Ca. 20 40 K 19 II III I 40 Ca 20 IV 40 A 18 Identify the four indicated transitions. I Unit 12.2 Exercises 12 / 28 Q7 The diagram shows a few nuclear energy levels for 40 Ar, 40 K 18 19 and 40 Ca. 20 40 K 19 II III I 40 Ca 20 IV 40 A 18 Identify the four indicated transitions. I Unit 12.2 40 19 K + →40 18 Ar + e + v (beta plus decay) Exercises 12 / 28 Q7 The diagram shows a few nuclear energy levels for 40 Ar, 40 K 18 19 and 40 Ca. 20 40 K 19 II III I 40 Ca 20 IV 40 A 18 Identify the four indicated transitions. II Unit 12.2 Exercises 12 / 28 Q7 The diagram shows a few nuclear energy levels for 40 Ar, 40 K 18 19 and 40 Ca. 20 40 K 19 II III I 40 Ca 20 IV 40 A 18 Identify the four indicated transitions. II Unit 12.2 40 19 K →40 19 K + γ(gamma decay) Exercises 12 / 28 Q7 The diagram shows a few nuclear energy levels for 40 Ar, 40 K 18 19 and 40 Ca. 20 40 K 19 II III I 40 Ca 20 IV 40 A 18 Identify the four indicated transitions. III Unit 12.2 Exercises 12 / 28 Q7 The diagram shows a few nuclear energy levels for 40 Ar, 40 K 18 19 and 40 Ca. 20 40 K 19 II III I 40 Ca 20 IV 40 A 18 Identify the four indicated transitions. III Unit 12.2 40 19 K − →40 20 Ca+e +v (beta minus decay) Exercises 12 / 28 Q7 The diagram shows a few nuclear energy levels for 40 Ar, 40 K 18 19 and 40 Ca. 20 40 K 19 II III I 40 Ca 20 IV 40 A 18 Identify the four indicated transitions. IV Unit 12.2 Exercises 12 / 28 Q7 The diagram shows a few nuclear energy levels for 40 Ar, 40 K 18 19 and 40 Ca. 20 40 K 19 II III I 40 Ca 20 IV 40 A 18 Identify the four indicated transitions. IV Unit 12.2 40 19 K + →40 18 Ar + e + v (beta plus decay) Exercises 12 / 28 Q8 a. Find the decay constant for krypton-92, whose half-life is 3.00 s. 1 b. Suppose that you start with 100 mol of krypton. Estimate how many undecayed atoms of krypton there are after i. 1 s ii. 2 s iii. 3 s Unit 12.2 Exercises 13 / 28 Q8 a. Find the decay constant for krypton-92, whose half-life is 3.00 s. λ= ln 2 ln 2 = = 0.231 s−1 T1 3.00 2 1 mol of krypton. Estimate how many b. Suppose that you start with 100 undecayed atoms of krypton there are after i. 1 s ii. 2 s iii. 3 s Unit 12.2 Exercises 13 / 28 Q8 a. Find the decay constant for krypton-92, whose half-life is 3.00 s. λ= ln 2 ln 2 = = 0.231 s−1 T1 3.00 2 1 mol of krypton. Estimate how many b. Suppose that you start with 100 undecayed atoms of krypton there are after i. 1 s ii. 2 s iii. 3 s We start with 1 × 6.02 × 1023 = 6.02 × 1021 100 nuclei and so: Unit 12.2 Exercises 13 / 28 Q8 a. Find the decay constant for krypton-92, whose half-life is 3.00 s. λ= ln 2 ln 2 = = 0.231 s−1 T1 3.00 2 1 mol of krypton. Estimate how many b. Suppose that you start with 100 undecayed atoms of krypton there are after i. 1 s, N = 6.02 × 1021 × e (−0.231)(1) = 4.78 × 1021 ii. 2 s iii. 3 s We start with 1 × 6.02 × 1023 = 6.02 × 1021 100 nuclei and so: Unit 12.2 Exercises 13 / 28 Q8 a. Find the decay constant for krypton-92, whose half-life is 3.00 s. λ= ln 2 ln 2 = = 0.231 s−1 T1 3.00 2 1 mol of krypton. Estimate how many b. Suppose that you start with 100 undecayed atoms of krypton there are after i. 1 s, N = 6.02 × 1021 × e (−0.231)(1) = 4.78 × 1021 ii. 2 s iii. 3 s We start with 1 × 6.02 × 1023 = 6.02 × 1021 100 nuclei and so: Unit 12.2 Exercises 13 / 28 Q8 a. Find the decay constant for krypton-92, whose half-life is 3.00 s. λ= ln 2 ln 2 = = 0.231 s−1 T1 3.00 2 1 mol of krypton. Estimate how many b. Suppose that you start with 100 undecayed atoms of krypton there are after i. 1 s, N = 6.02 × 1021 × e (−0.231)(1) = 4.78 × 1021 ii. 2 s, N = 6.02 × 1021 × e (−0.231)(2) = 3.79 × 1021 iii. 3 s We start with 1 × 6.02 × 1023 = 6.02 × 1021 100 nuclei and so: Unit 12.2 Exercises 13 / 28 Q8 a. Find the decay constant for krypton-92, whose half-life is 3.00 s. λ= ln 2 ln 2 = = 0.231 s−1 T1 3.00 2 1 mol of krypton. Estimate how many b. Suppose that you start with 100 undecayed atoms of krypton there are after i. 1 s, N = 6.02 × 1021 × e (−0.231)(1) = 4.78 × 1021 ii. 2 s, N = 6.02 × 1021 × e (−0.231)(2) = 3.79 × 1021 iii. 3 s We start with 1 × 6.02 × 1023 = 6.02 × 1021 100 nuclei and so: Unit 12.2 Exercises 13 / 28 Q8 a. Find the decay constant for krypton-92, whose half-life is 3.00 s. λ= ln 2 ln 2 = = 0.231 s−1 T1 3.00 2 1 mol of krypton. Estimate how many b. Suppose that you start with 100 undecayed atoms of krypton there are after i. 1 s, N = 6.02 × 1021 × e (−0.231)(1) = 4.78 × 1021 ii. 2 s, N = 6.02 × 1021 × e (−0.231)(2) = 3.79 × 1021 iii. 3 s, N = 6.02 × 1021 × e (−0.231)(3) = 3.01 × 1021 Unit 12.2 Exercises 13 / 28 Q9 a. State the probability that a radioactive nucleus will decay during a time interval equal to a half-life. b. Calculate the probability that it will have decayed after the passage of three half-lives. c. A nucleus has not decayed after the passage of four half-lives. State the probability it will decay during the next half-life. Unit 12.2 Exercises 14 / 28 Q9 a. State the probability that a radioactive nucleus will decay during a time interval equal to a half-life. Unit 12.2 Exercises 15 / 28 Q9 a. State the probability that a radioactive nucleus will decay during a time interval equal to a half-life. The probability of decay within a half-life is always 12 . Unit 12.2 Exercises 15 / 28 Q9 b. Calculate the probability that it will have decayed after the passage of three half-lives. Unit 12.2 Exercises 15 / 28 Q9 b. Calculate the probability that it will have decayed after the passage of three half-lives. The probability that the nucleus will not decay after the passage of three half – lives is 1 2 × no decay 1 2 × no decay 1 2 no decay = 1 8 Hence the probability that the nucleus will decay some time within three half – lives is 1− Unit 12.2 7 1 = = 0.875 8 8 Exercises 15 / 28 Q9 c. A nucleus has not decayed after the passage of four half-lives. State the probability it will decay during the next half-life. Unit 12.2 Exercises 15 / 28 Q9 c. A nucleus has not decayed after the passage of four half-lives. State the probability it will decay during the next half-life. The probability of decay in any one half – life interval is 0.5. More mathematically, we want to find P(D|N) where we use the notation of conditional probability and the events D = decay in the next half-life N = no decay in the first 4 half lives. Then P(D|N) = Unit 12.2 P(D ∩ N) P(N) Exercises 15 / 28 Q9 c. A nucleus has not decayed after the passage of four half-lives. State the probability it will decay during the next half-life. Now P(N) = 1 1 = 4 2 16 and P(D ∩ N) = 1 32 Hence P(D|N) = Unit 12.2 1 16 1 × = 32 1 2 Exercises 15 / 28 Q10 Estimate the activity of 1.0 g of radium-226 (molar mass = 226.025 g mol–1 ). The half-life of radium-226 is 1600 yr. Unit 12.2 Exercises 16 / 28 Q10 Estimate the activity of 1.0 g of radium-226 (molar mass = 226.025 g mol–1 ). The half-life of radium-226 is 1600 yr. The half-life is so long so that what we are really asked to find is the initial activity of 1.0 g of pure radium. We have that A = λN0 e −kt so that the initial activity is λN0 . A mass of 1.0 g of radium corresponds to 1 = 0.0044243 moles 226.025 and hence N0 = (0.0044243)(6.02 × 1023) = 2.6634 × 1021 nuclei Since λ= ln 2 ln 2 = = 1.3737 × 10−11 s−1 T1 (1600)(365)(24)(60)(60) 2 Unit 12.2 Exercises 16 / 28 Q10 Estimate the activity of 1.0 g of radium-226 (molar mass = 226.025 g mol–1 ). The half-life of radium-226 is 1600 yr. We find an activity of A = −λN −11 21 (2.6634 × 10 )(1.3737 × 10 Unit 12.2 Exercises ) = 3.66 × 1010 Bq 16 / 28 Q11 The half-life of an unstable element is 12 days. Find the activity of a given sample of this element after 20 days, given that the initial activity was 3.5 MBq. Unit 12.2 Exercises 17 / 28 Q11 The half-life of an unstable element is 12 days. Find the activity of a given sample of this element after 20 days, given that the initial activity was 3.5 MBq. The decay constant is λ= ln 2 ln 2 = 0.0578 day−1 = T1 12 2 and so A = λN0 e −kt = 3.5e (−0.0578)(20) = 1.1 MBq Unit 12.2 Exercises 17 / 28 Q12 A radioactive isotope of half-life 6.0 days used in medicine is prepared 24 h prior to being administered to a patient. The activity must be 0.50 MBq when the patient receives the isotope. Estimate the number of atoms of the isotope that should be prepared. Unit 12.2 Exercises 18 / 28 Q12 A radioactive isotope of half-life 6.0 days used in medicine is prepared 24 h prior to being administered to a patient. The activity must be 0.50 MBq when the patient receives the isotope. Estimate the number of atoms of the isotope that should be prepared. The decay constant is λ= ln 2 ln 2 = 1.34 × 10−6 s−1 = T1 (6)(24)(60)(60) 2 From A = λN0 e −λt −6 )(24)(60)(60) 0.50 × 106 = 1.34 × 10−6 × N0 e (−1.34×10 N0 = 4.2 × 1011 Unit 12.2 Exercises 18 / 28 Q13 The age of very old rocks can be found from uranium dating. Uranium is suitable because of its very long half-life: 4.5 × 109 yr. The final stable product in the decay series of uranium-238 is lead-206. Find the age of rocks that are measured to have a ratio of lead to uranium atoms of 0.80. You must assume that no lead was present in the rocks other than that due to uranium decaying. Unit 12.2 Exercises 19 / 28 Q13 The age of very old rocks can be found from uranium dating. Uranium is suitable because of its very long half-life: 4.5 × 109 yr. The final stable product in the decay series of uranium-238 is lead-206. Find the age of rocks that are measured to have a ratio of lead to uranium atoms of 0.80. You must assume that no lead was present in the rocks other than that due to uranium decaying. After time t the number of uranium atoms remaining in the rocks is N = N0 e −λt and so the number that decayed (and hence eventually became lead) is N − N0 = N0 (1 − e −λt ) Hence we have that N0 (1 − e −kt ) = 0.80 N0 e −λt Unit 12.2 Exercises 19 / 28 Q13 The age of very old rocks can be found from uranium dating. Uranium is suitable because of its very long half-life: 4.5 × 109 yr. The final stable product in the decay series of uranium-238 is lead-206. Find the age of rocks that are measured to have a ratio of lead to uranium atoms of 0.80. You must assume that no lead was present in the rocks other than that due to uranium decaying. This means that 1 − e −λt = 0.80e −λt 1 = 1.80e −λt e −λt = 1.8 Hence λt = ln(1.80) = 0.5878 Unit 12.2 Exercises 19 / 28 Q13 The age of very old rocks can be found from uranium dating. Uranium is suitable because of its very long half-life: 4.5 × 109 yr. The final stable product in the decay series of uranium-238 is lead-206. Find the age of rocks that are measured to have a ratio of lead to uranium atoms of 0.80. You must assume that no lead was present in the rocks other than that due to uranium decaying. Since λ= ln 2 ln 2 = = 1.54 × 10−10 yr−1 T1 4.5 × 109 2 t= Unit 12.2 0.5858 = 3.8 × 109 yr 1.54 × 10−10 Exercises 19 / 28 Q14 9 The isotope 40 19 K of potassium is unstable, with a half-life of 1.37 × 10 yr. 40 It decays into the stable isotope 18 Ar. Moon rocks were found to contain a ratio of potassium to argon atoms of 1 : 7. Find the age of the Moon rocks. Unit 12.2 Exercises 20 / 28 Q14 9 The isotope 40 19 K of potassium is unstable, with a half-life of 1.37 × 10 yr. 40 It decays into the stable isotope 18 Ar. Moon rocks were found to contain a ratio of potassium to argon atoms of 1 : 7. Find the age of the Moon rocks. One half life gives a ratio of 1 2 parent to 1 2 daughter or 1:1. Two half lives halve the parent again so we have a ratio of daughter or 1:3. Three half lives means 1 8 parent, and 7 8 1 4 parent to 3 4 daughter, or 1:7. So a ratio of 1 : 7 corresponds to three half-lives. The age is therefore about t = 3 × 1.37 × 109 = 4.1 × 109 yr Unit 12.2 Exercises 20 / 28 Q15 Two unstable isotopes are present in equal numbers (initially). Isotope A has a half-life of 4 min and isotope B has a half-life of 3 min. Calculate the ratio of the activity of A to that of B after: a. 0 min b. 4 min c. 12 min Unit 12.2 Exercises 21 / 28 Q15 Two unstable isotopes are present in equal numbers (initially). Isotope A has a half-life of 4 min and isotope B has a half-life of 3 min. Calculate the ratio of the activity of A to that of B after: a. 0 min Unit 12.2 Exercises 22 / 28 Q15 Two unstable isotopes are present in equal numbers (initially). Isotope A has a half-life of 4 min and isotope B has a half-life of 3 min. Calculate the ratio of the activity of A to that of B after: a. 0 min The activity is given by A = λN = λN0 e −λt where λ = ln 2 T1 is the 2 decay constant. AA λA N0A 3 3 = = × 1 = = 0.75 AB λB N0b 4 4 Unit 12.2 Exercises 22 / 28 Q15 Two unstable isotopes are present in equal numbers (initially). Isotope A has a half-life of 4 min and isotope B has a half-life of 3 min. Calculate the ratio of the activity of A to that of B after: b. 4 min Unit 12.2 Exercises 22 / 28 Q15 Two unstable isotopes are present in equal numbers (initially). Isotope A has a half-life of 4 min and isotope B has a half-life of 3 min. Calculate the ratio of the activity of A to that of B after: b. 4 min The activity is given by A = λN = λN0 e −λt where λ = ln 2 T1 is the 2 decay constant. ln 2 λA N0A e −λA ×4 3 e − 4 ×4 AA = = × = 0.95 AB 4 e − ln32 ×4 λB N0B e −λB ×4 Unit 12.2 Exercises 22 / 28 Q15 Two unstable isotopes are present in equal numbers (initially). Isotope A has a half-life of 4 min and isotope B has a half-life of 3 min. Calculate the ratio of the activity of A to that of B after: c. 12 min Unit 12.2 Exercises 22 / 28 Q15 Two unstable isotopes are present in equal numbers (initially). Isotope A has a half-life of 4 min and isotope B has a half-life of 3 min. Calculate the ratio of the activity of A to that of B after: c. 12 min The activity is given by A = λN = λN0 e −λt where λ = ln 2 T1 is the 2 decay constant. ln 2 λA N0A e −λA ×12 3 e − 4 ×12 AA = = × = 1.5 AB 4 e − ln32 ×12 λB N0B e −λB ×12 Unit 12.2 Exercises 22 / 28 Q16 A sample contains two unstable isotopes. A counter placed near it is used to record the decays. Discuss how you would determine each of the half-lives of the isotopes from the data. Unit 12.2 Exercises 23 / 28 Q16 A sample contains two unstable isotopes. A counter placed near it is used to record the decays. Discuss how you would determine each of the half-lives of the isotopes from the data. This is a very diffcult question and many different possibilities must be considered. Essentially we must be able to determine form a graph of activity versus time the initial activities of the two isotopes and their respective half – lives. Unit 12.2 Exercises 23 / 28 Q16 One possibility is represented by the following graph in which a short (S) and a long (L) half – life isotopes are present. The shape of the curve is not a pure exponential. A × 1010 Bq 2 1.5 1 0.5 0 1 Unit 12.2 2 Exercises 3 4 t/min 24 / 28 Q16 A × 1010 Bq 2 1.5 1 0.5 0 1 2 3 4 t/min We see that after about 1 minute we have a smooth exponential curve which implies that one of the isotopes has essentially decayed away, leaving behind just one isotope. This is justified by estimating a half-life for times greater than 1 minute. We get consistently a half-life of 1 minute for the long half – life isotope. Extending smoothly the exponential curve backwards, we intercept the vertical axis at about 1 × 1010 Bq. Unit 12.2 Exercises 25 / 28 Q16 A × 1010 Bq 2 1.5 1 0.5 0 1 2 3 4 t/min t Thus the activity of isotope L is given by AL = 1 × 1010 × 0.5 1 . This means that the initial activity of the short lifetime isotope S is also 1 × 1010 Bq. Unit 12.2 Exercises 25 / 28 Q16 Subtracting from the data points of the given graph the activity of this isotope we get the following graph. A × 1010 Bq 1 0.8 0.6 0.4 0.2 0 0 0.2 0.4 0.6 0.8 1 t/min This represents the decay of just isotope S. From this graph we find a half-life of about 0.1 minute. Obviously, this analysis gets more complicated when the half-lives are not so different or when the initial activities are very different. Unit 12.2 Exercises 26 / 28 Q17 The half-life of an isotope with a very long half-life cannot be measured by observing its activity as a function of time, since the variation in activity over any reasonable time interval would be too small to be observed. Let m be the mass in grams of a given isotope of long half-life. a. Show that the number of nuclei present in this quantity is N0 = m µ NA –1 where µ is the molar mass of the isotope in g mol and NA is the Avogadro constant. −λt , how that the initial activity is b. From A = − dN dt = N0 eλe mNA A0 = µ λ and hence that the half-life can be determined by measuring the initial activity (in Bq) and the mass of the sample (in grams). Unit 12.2 Exercises 27 / 28 Q17 The half-life of an isotope with a very long half-life cannot be measured by observing its activity as a function of time, since the variation in activity over any reasonable time interval would be too small to be observed. Let m be the mass in grams of a given isotope of long half-life. a. Show that the number of nuclei present in this quantity is N0 = m µ NA –1 where µ is the molar mass of the isotope in g mol and NA is the Avogadro constant. Unit 12.2 Exercises 28 / 28 Q17 The half-life of an isotope with a very long half-life cannot be measured by observing its activity as a function of time, since the variation in activity over any reasonable time interval would be too small to be observed. Let m be the mass in grams of a given isotope of long half-life. a. Show that the number of nuclei present in this quantity is N0 = m µ NA –1 where µ is the molar mass of the isotope in g mol and NA is the Avogadro constant. If the mass (in grams) is m and the molar mass is µ, the number of moles of the radioactive isotope is m µ . The initial number of nuclei is then N0 = m × NA µ since one mole contains Avogadro’s number of molecules. Unit 12.2 Exercises 28 / 28 Q17 The half-life of an isotope with a very long half-life cannot be measured by observing its activity as a function of time, since the variation in activity over any reasonable time interval would be too small to be observed. Let m be the mass in grams of a given isotope of long half-life. −λt , how that the initial activity is b. From A = − dN dt = N0 eλe A A0 = mN µ λ and hence that the half-life can be determined by measuring the initial activity (in Bq) and the mass of the sample (in grams). Unit 12.2 Exercises 28 / 28 Q17 The half-life of an isotope with a very long half-life cannot be measured by observing its activity as a function of time, since the variation in activity over any reasonable time interval would be too small to be observed. Let m be the mass in grams of a given isotope of long half-life. −λt , how that the initial activity is b. From A = − dN dt = N0 eλe mNA A0 = µ λ and hence that the half-life can be determined by measuring the initial activity (in Bq) and the mass of the sample (in grams). The activity is A = λN = λN0 e −λt = λ m NA e −λt µ and the initial activity is thus A0 = λ Unit 12.2 m NA x µ Exercises 28 / 28 Q17 The half-life of an isotope with a very long half-life cannot be measured by observing its activity as a function of time, since the variation in activity over any reasonable time interval would be too small to be observed. Let m be the mass in grams of a given isotope of long half-life. −λt , how that the initial activity is b. From A = − dN dt = N0 eλe A A0 = mN µ λ and hence that the half-life can be determined by measuring the initial activity (in Bq) and the mass of the sample (in grams). Measuring the initial activity then allows determination of 2 the decay constant and hence the half-life from λ = ln T1 2 Unit 12.2 Exercises 28 / 28