PET312 BASIC PETROLEUM GEOLOGY Units: 3 1 Brief overview of Course The course basically is meant to introduce students to petroleum geology with particular interest in the origin of petroleum, migration and eventual accumulation due to geologic traps 2 Course Objectives/Goals At the end of the course, students should be able to: 1. Know what minerals and rocks are, sedimentary processes that supports petroleum occurrence. 2. Know the origin of petroleum 3. Understand the concept of migration of hydrocarbon from source rocks to reservoir rocks 4. Understand how the various hydrocarbon traps lead to accumulation of petroleum 3 Course Outline 1. Weathering, Erosion and Deposition Geological cycles Sedimentary processes Sediment transport and deposition 2. Diagenesis 3. Reservoirs 4. Structural Geology and Petroleum 5. Origin, Migration and Accumulation of Petroleum 6. Sedimentary Basins Basins in Nigeria – 4 Recommended Reading/Text 1. Rocks and minerals – by Chris Pellant 2. An introduction to the study of mineralogy – by Bakewell, J.R 3. Elements of petroleum Geology – by Richard C. Selley 4. Introduction to physical geology – Plummer et. al. 5 Weathering, Erosion and Deposition This section explains that part of the rock cycle that operates at, or near, the Earth's surface. Such processes are responsible for the formation of hydrocarbon source rocks, most reservoir units, and seals. 6 1.2 Physical and chemical weathering of rocks Two distinct types of weathering are distinguished: physical weathering (or mechanical disaggregation) and chemical weathering (or chemical decomposition). Both processes, either separately or together, lead to the formation of a wide range of sedimentary rocks. frost shattering: Such shattering of rocks into smaller fragments exposes a much larger surface area to rainwater run-off, and so that they undergo chemical weathering. 7 Bowen reaction series 2 8 Bowen reaction series 1 9 The products of chemical weathering Three products result from chemical weathering. 1) Leaching away of minerals 2) New minerals are formed thru leaching of existing minerals. An example of this process is the formation of clay minerals through the weathering of feldspar and micas in granite. 3) Resistant minerals, such as quartz, are not chemically attacked at all. Remaining minerals are known as residual minerals. 10 The transport of weathered material This points to the removal of residual products of weathering various transporting media. (Wind, water, glacial, human) loads (bedload and suspended) sorting Energy of transportation (sorting, roundedness and angularity) distance of transportation nature of sediment in motion (i.e. Grain size) The transport and erosion of sediment by wind and ice: Consequence is well sorted sediment aggregate. Sediments end up with more rounded corners and edges worn down much more rapidly due to the cushioning effect of water that is absent. On the converse, because sediments are embedded in ice and unable to move they tend to retain their characteristic and consequently, true glacial sediments are very poorly sorted and the fragments are characteristically angular. This means that glacial sediments are not characterized by diagnostic grain shapes or degrees of sorting. 11 The transport and deposition of the soluble products of chemical weathering: Two major ways in which dissolved salts are removed are (i) by the action of marine organisms and (ii) by direct chemical precipitation. a.) Many marine animals build shells composed of calcium carbonate by extracting both Ca2+ and HCO3 from seawater to form the mineral calcite (CaCO3). Typical of this is the formation of limestone Formation of calcareous sediments in the deeper ocean basins from the accumulation of calcareous microfossils that are far too small to be seen with the naked eye (calcareous oozes). This accounts for the formation of fine-grained chalky limestones. Once exposed at the Earth's surface, limestones are very susceptible to chemical weathering because they dissolve easily in rainwater that has been acidified by atmospheric carbon dioxide. 12 b.) Sediments formed from soluble cations by direct precipitation are comparatively rare, but some are of great economic importance. The best known are salt deposits, or evaporites, which form in isolated inland seas or in narrow, newly formed ocean basins where circulation with the other masses of sea-water does not take place. The water becomes saturated with respect to ions such as Na+, K+, M2+, Ca2+, CI-, (SO4)2- and (HCO3), and salts of these, such as halite (NaCl), gypsum (CaSO4.2H2O) and, of course, calcite (CaCO3), crystallize out. High evaporative rates are common in arid climates; thus, evaporites in rock sequences are a good indicator of ancient arid climates. A few limestones are precipitated directly from seawater but they are relatively rare. They require warm shallow waters (CaCO3 is less soluble in warm water than cold water) that are well agitated by waves or currents, and particles such as sand grains or shell fragments act as nuclei for the precipitated CaCO3 to grow around. The resulting calcareous grains are slightly well rounded and are termed ooids. 13 EROSION AND MASS WASTING These processes of wearing away and removal (or transport) of debris are known collectively as erosion, a very apt term derived from two Latin words: ‘e' meaning ‘from' and ‘rodere' meaning ‘to gnaw'. Thus erosion is the ‘gnawing away from' the land surfaces, which implies a slow but very persistent process. Name some agents of erosion that you know? Mass movement The causes of mass movement: Weathered debris is usually stable on a slope until the friction between the debris and the slope is overcome. In theory friction alone can hold weathered debris on slopes up to 45°, but in practice movement may occur on slopes as little as 1°, and so there must be other factors that act to overcome the friction. Triggering mechanisms can be tectonic activity as, for example, in regions subjected to frequent earthquakes. The types of mass movement “The importance of mass movement is that it is the means whereby weathered debris can be moved from hillsides and cliffs into a river, onto a glacier, or into the sea to begin a more substantial phase of transport.” 14 Facts When velocities are low, flow are laminar, and only fine sands, silts, and clays can be moved; they are carried within the moving water that is in suspension and form the suspension load. Fine-grained sediments carried in suspension by laminar flows form suspension deposits when the current velocity falls. When flow is turbulent, coarse sand grains and even pebbles can be transported, but these are moved initially along a riverbed, and not in suspension. This coarser sediment forms the traction or bed load of the moving water. A very much higher velocity of water movement is needed to lift the bed load into suspension. 15 The erosion of sediments by moving fluids A noticeably higher velocity is required to begin moving a grain than that at which the grain was deposited. This is because the friction between the grain and the riverbed must be overcome first. Where wind transport is concerned, wind speeds of the order of thirty times greater than those of water are required to set grains of a given size in motion. Finer silts and clays show a cohesive strength, which is due to surface tension created by films of water between the particles. These are called cohesive sediments, and cohesion between the particles is increased by compaction of the sediment. Thus, once clay sediments are deposited, they are less likely to suffer reworking than sandy sediments. Sand-sized sediments are more likely therefore to be preserved if they are buried by a layer of clay. 16 Sediments and sedimentary bed forms resulting from deposition in flowing water The evidence of this is that, suspension and traction deposits each lead to characteristic types of layering in sediments, which are then preserved in sedimentary rocks. The nature of such layering will influence the vertical and horizontal characteristics of reservoir units. When the discrete layers are only a few millimetres thick, they are termed laminae and the sediments or rocks are described as laminated. On the other hand, layers equal to or greater than 0.5cm are called beds. Horizontal or planar laminae like these are characteristic of suspension deposits. However, coarser horizontal layering, known as planar bedding, occurs in some traction deposits. Slow-moving water currents deposits coarse sands, while at higher current velocities, the traction deposits are built into a series of mounds on the bed beneath the current. 17 Fig. The movement and deposition of sediment on a ripple. Solid arrows represent transport in and deposition from the bed load. Broken arrows represent transport in and deposition from the suspended load. Aqueous dune and sand wave forms are produced by a similar pattern of sediment movement. Bedform configurations cross-stratification cross-lamination cross-bedding. 18 Flow Bedforms regimes Lower flow Ripples, low regime planar beds, sand waves and sand dunes Upper flow Upper planar regime beds, antidunes 19 20 Two important points that are very relevant to the interpretation of sequences of sedimentary rocks. First, we can use cross-lamination or cross-bedding preserved in sedimentary rocks to tell us which way the current was flowing when the original sediments were deposited. This is referred to as a palaeocurrent direction. Such information can be obtained from the subsurface if oriented cores are recovered, or, for cross bedding, from dip-meter data. Knowledge of the palaeocurrent direction is likely to aid prediction of the direction of elongation of reservoir sand bodies. Second, we can make estimates about how flow conditions may have varied with time from the range of bed forms present in a sequence of sediments. Failure to recognize whether or not cross-stratification represents a cross-section of a bed form parallel to the flow direction can lead to the miscalculation of palaeocurrent directions. 21 Sedimentary bed forms resulting from oscillatory water movements 22 Fig. Patterns of cross-stratification produced by tidal currents. The arrows are proportional in length to the strength of opposing currents. (a) herring-bone cross-stratification: the currents have approximately equal strengths. This form of crossstratification is produced only by larger bed forms and not produced by ripples. (b) Reactivation surfaces within cross-stratification caused by opposing tidal currents: in this 23 illustration, the flood tide is stronger than the opposing ebb tide. Fig. The movement of sediment and water within a turbidity current. In the head, the sediment and water are swept up and round, whereas turbulent eddies develop in the body. Turbidite sequence Although the initial velocity of the current is a function of the density contrasts between current and seawater and of the thickness of the flow, the decrease in gradient towards the base of the continental slope leads to a rapid decrease in velocity so that deposition occurs. The resultant 24 deposit is known as a turbidite. Fig. The ideal Bouma turbidite sequence. Units A to E were deposited in different flow conditions within a turbidity current. Note that the width of the sediment column is proportional to the grain size. 25