Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Trade name PRODUCT CODE CHEMICAL FAMILY : : : TEGO AIREX 940 206985 Solution of polymeric substances Information on manufacturer/supplier : Evonik Industries AG Werk Tego Goldschmidtstr. 100 Essen, 05 45127 Emergency telephone number (24h) : Telephone: CHEMTREC CANUTEC Non-Emergency Phone Number: (800) 424-9300 (613) 996-6666 (800) 732-5616 2. COMPOSITION/INFORMATION ON INGREDIENTS Components Benzene, 1,3,5-trimethylBenzene, dimethylBenzene, 1,2,4-trimethyl 4-Heptanone, 2,6-dimethylNaphtha (petroleum), hydrodesulfurized heavy Diisobutylcarbinol CAS-No. 108-67-8 1330-20-7 95-63-6 108-83-8 64742-82-1 108-82-7 Concentration [%] >= 0.1 - < 0.5 < 0.5 >= 1 - < 2.5 >= 25 - < 50 >= 25 - < 50 >= 25 - < 50 3. HAZARDS IDENTIFICATION Emergency Overview Physical Appearance Form Colour Odour Water solubility : : : : pH : Liquid colourless to brown mild insoluble not measured 206985 Page 1/12 Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 Potential health effects Immediate concerns : Flammable. Irritating to respiratory system. Toxic for aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Vapours may cause drowsiness and dizziness Eyes : No harmful effects have been reported upon contact with the eyes. Skin : Can cause irritation which may be severe on prolonged contact. Repeated contact can cause defatting, cracking and dermatitis. Ingestion : Aspiration can lead to respiratory tract or lung damage. Inhalation : Irritating to respiratory system. Primary routes of entry : Eyes, Skin, Inhalation, Ingestion Target organs : Eyes, Skin, Respiratory Tract Carcinogenicity : Not listed by NTP, IARC, ACGIH, or OSHA as a carcinogen. Eyes : In case of contact with eyes rinse thoroughly with plenty of water. If symptoms persist, seek medical advice. Skin : In case of contact with skin wash off with soap and water. Consult a doctor if skin irritation persists. Ingestion : drink large quantities of water; do not induce vomiting. consult a physician immediately. Inhalation : Ensure supply of fresh air. In the event of symptoms seek medical advice. 4. FIRST AID MEASURES 206985 Page 2/12 Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 Notes to physician Symptoms : Depending on the dose inhalation and/or ingestion may cause: headache, inebriation, unconsciousness. Prolonged skin contact may cause skin irritation and/or dermatitis. Treatment : If swallowed, in the event of vomiting, risk of product entering the lungs. General advice : Remove soiled or soaked clothing immediately 5. FIRE-FIGHTING MEASURES Flash point : 115 °F Autoignition temperature : not measured Upper Explosion limits : not measured Lower explosion limit : not measured Suitable extinguishing media : foam, carbon dioxide, dry powder, water spray. Extinguishing media which must not be used for safety reasons : Full water jet Products in case of fire : In the event of fire the following can be released: - carbon dioxide, carbon monoxide Under certain conditions of combustion traces of other toxic substances cannot be excluded Further information : Collect contaminated firefighting water separately, must not be discharged into the drains. Special protective equipment for fire-fighters : Do not inhale explosion and/or combustion gases Use self-contained breathing apparatus Hazardous decomposition products : None with proper storage and handling. OSHA flammable class : Combustible Liquid, Class II 206985 Page 3/12 Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up / taking up : Small spills : Take up with absorbent material (Sand, Universal Binder). Take up absorbent material. When absorbed, sweep or otherwise collect and dispose of properly. Release Notes : US regulations require reporting spills of this material that could reach any surface waters In case of accident or road spill notify : Telephone: (800) 424-9300 CHEMTREC USA (613) 996-6666 CANUTEC Canada CHEMTREC (other countries) (International code)+1-202-483-7616 7. HANDLING AND STORAGE General Procedures Handling Advice on safe handling : Provide good ventilation of working area (local exhaust ventilation if necessary). Advice on protection against fire and explosion : Keep away from sources of ignition Take precautionary measures against electrostatic loading. Cool endangered containers by water spray Vapours may form explosive mixtures with air : Keep container tightly closed in a cool, well-ventilated place Storage Further information 206985 Page 4/12 Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 8. EXPOSURE CONTROLS / PERSONAL PROTECTION OSHA hazardous components (29 CFR 1910.1200) Components CAS-No. Base Type Value Note Naphtha (petroleum), hydrodesulfurized heavy 64742-82-1 US. ACGIH Threshold Limit Values Time Weighted 100 ppm Average (TWA): Benzene, dimethyl- 1330-20-7 US. ACGIH Threshold Limit Values Time Weighted 100 ppm Average (TWA): Benzene, dimethyl- 1330-20-7 US. ACGIH Threshold Limit Values Short Term 150 ppm Exposure Limit (STEL): Benzene, 1,2,4trimethyl 95-63-6 US. ACGIH Threshold Limit Values Time Weighted 25 ppm Average (TWA): 4-Heptanone, 2,6dimethyl- 108-83-8 US. ACGIH Threshold Limit Values Time Weighted 25 ppm Average (TWA): Benzene, 1,3,5trimethyl- 108-67-8 US. ACGIH Threshold Limit Values Time Weighted 25 ppm Average (TWA): Naphtha (petroleum), hydrodesulfurized heavy 64742-82-1 US. NIOSH: Pocket Guide to Chemical Hazards Recommended exposure limit (REL): 350 mg/m3 Naphtha (petroleum), hydrodesulfurized heavy 64742-82-1 US. NIOSH: Pocket Guide to Chemical Hazards Benzene, dimethyl- 1330-20-7 US. NIOSH: Pocket Guide to Chemical Hazards Ceiling Limit Value and Time Period (if 1,800 mg/m3 specified): Recommended 100 ppm exposure limit (REL): 435 mg/m3 Benzene, dimethyl- 1330-20-7 US. NIOSH: Pocket Guide to Chemical Hazards Short Term 150 ppm Exposure Limit 655 mg/m3 (STEL): Benzene, dimethyl- 1330-20-7 US. NIOSH: Pocket Guide to Chemical Recommended 100 ppm exposure limit 206985 Page 5/12 Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 Hazards (REL): 435 mg/m3 Benzene, dimethyl- 1330-20-7 US. NIOSH: Pocket Guide to Chemical Hazards Short Term 150 ppm Exposure Limit (STEL): 655 mg/m3 Benzene, dimethyl- 1330-20-7 US. NIOSH: Pocket Guide to Chemical Hazards Recommended 100 ppm exposure limit 435 mg/m3 (REL): Benzene, dimethyl- 1330-20-7 US. NIOSH: Pocket Guide to Chemical Hazards Short Term 150 ppm Exposure Limit (STEL): 655 mg/m3 Benzene, 1,2,4trimethyl 95-63-6 US. NIOSH: Pocket Guide to Chemical Hazards Recommended 25 ppm exposure limit 125 mg/m3 (REL): 4-Heptanone, 2,6dimethyl- 108-83-8 US. NIOSH: Pocket Guide to Chemical Hazards Recommended 25 ppm exposure limit 150 mg/m3 (REL): Benzene, 1,3,5trimethyl- 108-67-8 US. NIOSH: Pocket Guide to Chemical Hazards Recommended 25 ppm exposure limit 125 mg/m3 (REL): Naphtha (petroleum), hydrodesulfurized heavy 64742-82-1 PEL: Benzene, dimethyl- 1330-20-7 US. OSHA Table Z1 Limits for Air Contaminants (29 CFR 1910.1000) US. OSHA Table Z1 Limits for Air Contaminants (29 CFR 1910.1000) US. OSHA Table Z1 Limits for Air Contaminants (29 CFR 1910.1000) 4-Heptanone, 2,6dimethyl- 108-83-8 500 ppm 2,900 mg/m3 PEL: 100 ppm 435 mg/m3 PEL: 50 ppm 290 mg/m3 Personal protective equipment General protective measures 206985 : Do not inhale gases/vapours/aerosols. Avoid contact with eyes and skin Page 6/12 Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 Hygiene measures : Do not eat, drink or smoke when working. Remove soiled or soaked clothing immediately. Wash hands before breaks and after work. Use barrier skin cream. Respiratory protection : in case of formation of vapours/aerosols: Short term: filter apparatus, Filter A-P2 Hand protection : protective gloves made of fluorinated rubber (FKM, e.g. Viton) Eye protection : safety glasses Protective clothing : protective clothing 9. PHYSICAL AND CHEMICAL PROPERTIES Form Colour Odour State of aggregation : : : : Liquid colourless to brown mild Liquid Melting temperature : not measured Boiling temperature : not measured Vapour pressure : not measured Density : 0.811 g/cm3 Water solubility : insoluble pH : not measured Viscosity, kinematic : < 7 mm2/s Volatile organic compound : 689.56 g/l 5.75 Lb/Gal percentage volatile: 85.14 % Percent Water:0.16 % percent non-volatile: 14.86 % 10. STABILITY AND REACTIVITY 206985 Page 7/12 Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 Thermal decomposition : Not measured Hazardous reactions : Reactions with oxidizing agents. Hazardous decomposition products : None with proper storage and handling. 11. TOXICOLOGICAL INFORMATION Acute inhalation toxicity : The results based on calculation as per chapter 3.1.3.6 Directive 1272/2008/EC are above the classification limits. Note : Irritating to respiratory system Aspiration can lead to respiratory tract or lung damage Vapours may cause drowsiness and dizziness. Due to the composition of the product it cannot be excluded: Repeated exposure may cause skin dryness or cracking. 12. ECOLOGICAL INFORMATION Further ecological information Ecological notes : Do not allow to enter soil, waterways or waste water canal. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local, state, and federal regulations. Product disposal and disposal requirements : In accordance with local authority regulations, take to special waste incineration plant Contaminated packaging : If empty contaminated containers are recycled or disposed of, the receiver must be informed about possible hazards. 14. TRANSPORT INFORMATION Sea transport IMDG: Class UN-No 206985 : : 3 1993 Page 8/12 Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 PG MFAG EmS Proper shipping name Hazard release Label : : : : : : III F-E S-E FLAMMABLE LIQUID, N.O.S. petroleum distillates Diisobutyl ketone 3 Marine pollutant Air transport ICAO/IATA: Class UN-No PG Proper shipping name Hazard release Label : : : : : : 3 1993 III Flammable liquid, n.o.s. petroleum distillates Diisobutyl ketone 3 DOT (Department of Transportation) CFR Road: Class UN-No PG Proper shipping name Correct technical name Label : : : : : : 3 1993 III Flammable liquids, n.o.s. petroleum distillates Diisobutyl ketone 3 Marine pollutant CFR Rail: Class UN-No PG Proper shipping name Correct technical name Label : : : : : : 3 1993 III Flammable liquids, n.o.s. petroleum distillates Diisobutyl ketone 3 Marine pollutant CANADA Transport of Dangerous goods TDG Road: Class UN-No PG Proper shipping name Correct technical name Label 206985 : : : : : : 3 1993 III FLAMMABLE LIQUID, N.O.S. petroleum distillates Diisobutyl ketone 3 Marine pollutant Page 9/12 Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 TDG Rail: Class UN-No PG Proper shipping name Correct technical name Label 206985 : : : : : : 3 1993 III FLAMMABLE LIQUID, N.O.S. petroleum distillates Diisobutyl ketone 3 Marine pollutant Page 10/12 Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 15. REGULATORY INFORMATION United States SARA Section 311/312 : Fire: Yes Pressure generating: No Reactivity: No Acute: Yes Chronic: No SARA Sections : SECTION 313 Notification : No This product contains no SARA Title III, Section 313 listed chemicals. Notification Status : TSCA Notification : Yes All intentional ingredients are listed in the TSCA Inventory or comply with TSCA Polymer Exemption critieria per 40 CFR 723. State regulations : MASS. RIGHT TO KNOW Notification : Yes RHODE ISLAND RTK Notification : Yes NEW JERSEY RTK Notification : Yes PENNSYLVANIA RTK Notification : Yes California Proposition 65 Statement 206985 : Notification : No This product does not contain any substance(s) which are defined by the state of California to cause cancer, birth defects, or other reproductive effects. Page 11/12 Material Safety Data Sheet Version: Revision Date Date Issued 3.0 : : 04/03/2012 08/22/2013 TEGO AIREX 940 Canada : WHMIS CLASSIFICATION Class B, Division 3, Combustible Liquid Class D, Division 2, Subdivision B This product contains component(s) that are listed on the WHMIS Ingredient Disclosure List. Components Naphtha (petroleum), hydrodesulfurized heavy Benzene, dimethylBenzene, 1,2,4-trimethyl 4-Heptanone, 2,6-dimethylBenzene, 1,3,5-trimethyl- Notification Status CAS-No. 64742-82-1 1330-20-7 95-63-6 108-83-8 108-67-8 : Canadian Environmental Protection Act DSL Notification : Yes All intentional ingredients are listed on the DSL (Domestic Substance List) or have been notified pursuant to the NSN regulations. : Fire : 2 Health : 2 Physical Hazard : 0 Protection : X 16. OTHER INFORMATION HMIS Codes Other information : Comply with national laws regulating employee instruction. Manufacturer disclaimer : While the information and recommendations contained herein are believed to be accurate, we make no warranty with respect hereto and disclaim all liability from reliance thereon END OF MSDS 206985 Page 12/12