GENERAL CHEMISTRY 2 CHEM-2122 Grade 12 AMA30K How many grams of AgNO3 (MM=169.87) are needed to prepare 0.125M solution in 250mL of water? Answer: 5.3g How many mL of 10.8M HCl are required to make 100.0mL of 3.00M acid? Answer: 27.8mL True or False? The higher the concentration of a solution the less solutes it has in it. Answer: False How many moles of NaCl are present in a solution with a molarity of 8.59M and a volume of 125mL? Answer: 1.07mol What volume of 1.50 M KBr can be made from 15.6mL of concentrated KBr with a molarity of 9.65M? Answer: 100mL Calculate the molarity of the following solution: 1.0 mole of KCl in 750.0mL of solution. Answer: 1.3M Which of the following has the most NaCl (MM=58.44)? Answer: 1mole Find the molarity of 186.55 g of sucrose, C12H22011 (MM=342) in 250mL of water. Answer: 2.18M How many moles are needed to make 2.5L of a 3.8M solution? Answer: 9.5mol What is the molarity of 4 g of NaCl (MM=58.45) in 3,800mL of solution? Answer: 0.018 M How many liters would you need to make 1M solution if you have 6mol of sodium hydroxide? Answer: 6 How many grams of solute are dissolved in 125.0mL of 5.00M NaCl (MM=58.45)? Answer: 36.5g NaCl What is the molarity of a solution made by diluting 26.5 mL of 6.00M HNO3 to a volume of 250 mL? Answer: 0.636M Which sweet tea would you expect to taste the sweetest? Answer: 3.1M What is the molarity of a solution made by adding 1.565 moles of PbNO3 to 500 mL? Answer: 3.13M Which of these molecules could have dipole-dipole attraction? Answer: PCl3 London forces are stronger in heavier atoms or molecules, and weaker in lighter atoms or molecules. Which of these has the strongest London forces? Answer: I2 Van der Waals forces include Answer: Both London and dipole-dipole attractions Does NH3 have hydrogen bonding? Answer: No Does HF have hydrogen bonding? Answer: Yes Which is the second strongest intermolecular force, after hydrogen bonding? Answer: Dipole-dipole attraction Which kind of intermolecular force is strongest? Answer: Hydrogen bonding Does CH4 have hydrogen bonding? Answer: No Hydrogen bonding occurs when hydrogen is bonded to N, O , or F. Which of the following has hydrogen bonding? Answer: NH3 Does HCl have hydrogen bonding? Answer: No Which is stronger? Answer: Intermolecular forces Dipole-dipole attraction occurs when molecules are polar. Which of these molecules contains a polar bond Answer: HCl All molecules have London forces between them, but dipole-dipole and hydrogen bonding are so much stronger that when they are present we can ignore London forces. Which of these has ONLY London forces? Answer: I2 Which of the following is NOT a kind of intermolecular force? Answer: Covalent bond Does NO2 have hydrogen bonding? Answer: No Does H2S have hydrogen bonding? Answer: No A substance capable of hydrogen bonding has a ____________ boiling point than a similar substance that doesn’t hydrogen bond. Answer: Higher Does H2O have hydrogen bonding? Answer: Yes Which kinds of substances are held together by intermolecular forces? Answer: Molecules (covalent) in solid and liquid phases Which of these molecules could have dipole-dipole attractions? Answer: HCl (electronegativity difference = 1.1) What is the measuring unit for mass? Answer: Grams Fluids with very low viscosity very __________. Answer: Fast A block has a mass of 54g and a volume of 20cm3. What is the density of the block? Answer: 2.7g/cm3 Which unit of measurement is used for volume? Answer: Milliliter Which lab tool might you use to measure the volume of a liquid? Answer: Graduated cylinder What units are used to measure Density? Answer: g/cm3 What is viscosity? Answer: A liquid’s resistance to flow Why do some substances float on water? Answer: They are less dense than water A brick sinks in water while a wooden block of the same size floats. This is because the brick has a ___________. Answer: Higher density than the wooden block Which box has a higher density? Answer: Box A A piece of copper has a mass of 89g and a volume of 10cm3. What would be the density of the copper? Answer: 8.9g/cm3 The following liquids are poured in a beaker: alcohol (density=0.79), corn syrup (density=1.38), water (density=1.0), and cooking oil (density= 0.93). which of theses liquids will sink to the bottom of the beaker? Answer: Corn syrup What is the mass if the volume of the object is 75 cm3 and the density is 1.56g/cm3? Answer: 117 grams Put the liquids in order from most dense to least dense? Answer: 4,3,2,1 Which property of matter is determined by dividing its mass by its volume? Answer: Density The piece of copper has a mass of 89g and a volume of 10cm3. What would be the density of the copper? Answer: 8.9g/cm3 Define the term “mass” Answer: The amount of matter in an object Fluids with very high viscosity flow very ___________. Answer: Slow As temperature increases viscosity __________. Answer: Decreases It is an indication of the escape of molecules from the surface of the liquid. Answer: Evaporation Surface tension is the property of water in which Answer: Water molecules at the surface tend to stick together Surface tension of water can be reduced by Answer: Heating Because of surface tension, you can put things into a full of water and Answer: The water will never spill Water beads up on the surface of a penny because of this property Answer: High surface tension Force of attraction between similar molecules is called Answer: Cohesive Force What is adhesion? Answer: Water’s ability to stick to other substances Water’s ability to stick to glass is Answer: Adhesion Rain drops are spherical in shape because of Answer: Surface tension Describe COHESION Answer: Water molecules attracted to other water molecules What word describes when water is attracted to other substances? Answer: Adhesion Refer to the picture of water sticking to a leaf, this is occurring because of Answer: Adhesion Tendency of molecules of the same kind to stick to one another Answer: Cohesion Water droplets take a spherical shape (as pictured) because of Answer: Cohesion Which characteristic of water will allow a paperclip to remain floating on water when the paperclip is gently placed on top of the water? Answer: Solvent properties Water droplets take a spherical shape (as pictured) because of Answer: Cohesion What is the basis of a metallic bond? Answer: The attraction between positive metal ions and free-floating electrons. Which substance would have the weakest intermolecular forces of attraction? Answer: CH4 The model used to describe and explain the bonding and arrangement of atoms in a solid metal is the Answer: Electron sea model Intermolecular forces for: CO2 Answer: Dispersion Force Determine the type of intermolecular force present in SiO2. Answer: Covalent network This picture most likely depicts the arrangement of atoms in a __________. Answer: Metal Intermolecular force present HCl? Answer: Dipole dipole Does HCl have hydrogen bonding? (LQ#1) Answer: Yes Intermolecular forces for NH3 Answer: Hydrogen bonding ________________________________ have the strongest intermolecular forces of attraction. Answer: Hydrogen bonds Does CH4 have hudrogen bonding? Answer: No Ionic Bonding involves… Answer: The transfer of electrons Which is the strongest intermolecular force below? Answer: Ionic What explains the very high melting and boiling point of water. Answer: Strong hydrogen bonds between water molecules Which of the following solutions has the highest boiling point? Assume that all solutes in solution are nonvolatile. Answer: 1m magnesium chloride Colligative properties are dependent only on the number of particles in a solution, and not their identity. (select all that apply) Answer: Lowering of vapor pressure, Depression of freezing point, Elevation of boiling point, Osmotic pressure Molality, also called molal concentration, is a measure of the concentration of a solute, in a solution in terms of amount of substance in a specified amount of mass of the solvent. Answer: True Osmotic pressure is the minimum pressure which needs to be applied to a solution to prevent the inward flow of its pure solvent across a semipermeable membrane Answer: True If 4.27 g sucrose (C12H22O11) are dissolved in 15.2 g water, what is the boiling point of the resulting solution? Kb for water= 0.51℃/m. ΔTb= I x Kb x m. Answer: 10.42℃ Which of the following colligative properties is associated with a semipermeable membrane? Answer: Osmotic pressure The change in the vapor pressure that occurs when a solute is added to a solvent is therefore a colligative property. Answer: True The basic law governing the colligative properties of solutions is Raoult’s law. Raoult’s law explains the relationship between the vapor pressure of the solution, mole fraction, and vapour pressure of the solvent. This can be given as: Answer: P1= x1p1° What is the name for a substance that dissolves in water but does not form ions or conduct an electric current? Answer: Nonelectrolyte Colligative properties are dependent only on the number of particles in a solution, and not their identity. Answer: True What is the boiling point of a solution created when four moles of glucose are dissolved in two kg of water? Assume that glucose isa nonvolatile solute. Kb water= 0.515℃.kg/mol Answer: 101.03℃ Examples of colligative properties include vapor pressure lowering, freezing point depression, osmotic pressure, molarity, molality and boiling point elevation. Answer: False What is the osmotic pressure (atm) of a 0.30 M solution of glucose in water that is used for intravenous infusion at body temperature, 37℃? R=0.082 L.atm/mol.k Answer: 0.76 atm Colligative properties are not dependent only on the number of particles in a solution, and their identity. Answer: False Antifreeze works because the freezing and boiling points of liquids are “colligative” properties. This means they depend on the concentrations of “solutes”, or dissolved substances, in the solution. Answer: True Is the combustion of gasoline endothermic or exothermic? Answer: Exothermic As someone is running on the track they begin to perspire. If the runner is our system, are they endothermic or exothermic? Answer: Exothermic process A reaction is performed in a beaker with a temperature probe recording the temperature changes of the reaction. If the temperature began at 15.0 degrees Celsius and ended at 27.5 degrees Celsius. If the reaction is our system, is the system endothermic or exothermic? Answer: Endothermic Refer the following question: 2n2 + 3H2 → 2NH3 +46 kJ. How much energy would be produced if only 1 mol of nitrogen was reacted? Answer: 23kJ How much energy must be used to produce 4.75 mol of gaseous water?: H20 (l) + 44.0 kJ - → H2O (g) Answer: 207kJ What mass of P4 must be reacted to produce 5905 kJ of energy?: P4 + 6Cl2 - → 4PCl3 + 2439 kJ Answer: 300.0g Do reactants in an endothermic reaction have a higher or lower energy than the products? Answer: Lower Do the reactants in an exothermic reaction have a higher or lower energy than the products? Answer: Higher In an exothermic process the surrounding loses heat Answer: False In an endothermic reaction the system is releasing energy. Answer: False How does a catalyst work in speeding up a reaction? Answer: By lowering the activation energy or reaction Why does a higher concentration increase the rate of reaction? Answer: It increases the frequency of particle collisions Why does a higher temperature increase the rate of a reaction? Answer: It only increases the frequency of particle collisions What factors can affect the value of the activation energy of a reaction? Answer: The presence of a catalyst Catalysts are thought to increase the rate of a chemical reaction by Answer: Providing an alternative reaction pathway with a lower activation energy Increasing the temperature of a chemical reaction Answer: Increases the energy of the reactant and product particles What is the rate of reaction? Answer: How fast a reaction is Grinding a effervescent tablet into powder increases the rate of reaction due to increased Answer: Surface area The ___________ is required to break the bonds of the reactants. Answer: Activation energy List four factors that affects the rate of a reaction Answer: Temperature, Surface area, Catalyst, Concentration Olive oil Answer: Homogenous mixture mix In general, substances with stronger intermolecular forces have _____ boiling points than those with weaker forces Answer: Higher Which of the following geometries could be nonpolar? Answer: Tetrahedral Which of the following is a polar molecule? Answer: H2O Kool-Aid – Powder, sugar, and water. Identify the solvent Answer: Water Which is an example of a solution? Answer: Juice When materials combine to form a mixture, they Answer: Keep their original properties. What type of solution is shown in the picture? 30% Solute 60% H2O Answer: Hypertonic When a certain amount of solvent cannot hold any more solute it is called a _____ solution Answer: Saturated How will the following molecule bond with itself? Answer: Dipole Solubility refers to the ___ of solute that can dissolve in a certain volume or mass of solvent, at a certain temperature Answer: Amount Which of the following molecules, based on the elements present, would be most polar? Answer: HF How does a solution become supersaturated? Answer: Dissolve more solute than you should be able to A 3 M solution has how many moles per liter? Answer: 3 Which is the strongest intermolecular force below” Answer: Hydrogen bonding What type of solution is shown in the picture? 10% Solute 90% H2O Answer: Hypotonic Type of intermolecular force present in HF Answer: H-bond Diluting a solution reduces the total number of moles per liter of solution Answer: False Which of these is not an intermolecular force? Answer: Covalent bonding Intermolecular forces are the forces Answer: between molecules What type of solution is shown in the picture? 1% Solute 99% H2O Answer: Hypertonic Another name for a homogenous mixture is Answer: a solution Intermolecular force present in CHF3 Answer: dipole dipole Moles of solute= Molarity x Volume Answer: True How does a solution become supersaturated? Answer: dissolve more solute than you should be able to This is the part of a solution that dissolves Answer: Solute What does it mean to dilute a solution? Answer: lower the concentration of solute per solvent What explains the very high melting and boiling point of water? Answer: Hydrogen bonds between water molecules Contains the maximum amount of dissolved solute Answer: saturated solution Which of the following is NOT TRUE about Heterogeneous Mixtures? Answer: Solutions are a type of heterogenous mixture The image shown is an example of a Answer: Solution Does NH3 have hydrogen bonding? Answer: yes What is a substance that is dissolved in another substance? Answer: solute Intermolecular force present in Cl2? Answer: dispersion What is the difference between concentration and saturation? Answer: concentration is a fixed % and saturation refers to amount of solute dissolved Which of the following has the highest boiling point? Answer: NH3 This solution would be considered Answer: Saturated Which of the following would have molecule(dipole)-ion attractions? Answer: NaCl(aq) Which noble gas has the highest boiling point? Answer: Xe How do you calculate the molarity of a solution? Answer: Dividing the moles of solute by the L of solution Salt water is a Answer: solution In this mixture, which of the following will be the solute? Answer: The powder on the spoon This type of mixture contains two or more substances that are visibly distinguishable Answer: heterogeneous Determine the type of intermolecular force present in sand, SiO2 Answer: covalent network Intermolecular force present in HCl? Dipole dipole Answer: Dispersion Type of intermolecular force present in l2, Br2, and Cl2 Answer: Dispersion A molecule containing polar covalent bonds is always polar Answer: False What is a solvent? Answer: The substance that does the dissolving in a solution Which is an example of a solution? The correct answer is: Juice A molecule containing polar covalent bonds is always polar. The correct answer is 'False'. What is a substance that is dissolved in another substance? The correct answer is: solute Olive Oil The correct answer is: Homogeneous mixture The image shown is an example of a ___________. (Kool-Aid) The correct answer is: solution This type of mixture contains two or more substances that are visibly distinguishable. The correct answer is: heterogeneous What does it mean to dilute a solution? The correct answer is: lower the concentration of solute per solvent A 3 M solution has how many moles per liter? The correct answer is: 3 Diluting a solution reduces the total number of moles per liter of solution. The correct answer is 'False'. What type of solution is shown in the picture? 1% - Solute 99% - Water The correct answer is: Hypotonic Does NH3 have hydrogen bonding? The correct answer is: yes Contains the maximum amount of dissolved solute The correct answer is: saturated solution What is the difference between concentration and saturation? The correct answer is: concentration is a fixed % and saturation refers to amount of solute dissolved Which of the following is a polar molecule? The correct answer is: H2O Intermolecular force present in HCl? dipole dipole The correct answer is: Dispersion How does a solution become supersaturated? The correct answer is: dissolve more solute than you should be able to. Type of intermolecular force present in I2, Br2, and Cl2. The correct answer is: Dispersion Which of the following would have molecule(dipole)-ion attractions? The correct answer is: NaCl(aq) Moles of solute= Molarity x Volume. The correct answer is 'True'. Which of the following is NOT TRUE about Heterogeneous Mixtures? The correct answer is: Solutions are a type of heterogenous mixture What is a solvent? The correct answer is: The substance that does the dissolving in a solution. This solution would be considered The correct answer is: Saturated Which of the following has the highest boiling point? The correct answer is: NH3 What type of solution is shown in the picture? 60% Solute 40% Water The correct answer is: Hypertonic When a certain amount of solvent cannot hold any more solute it is called a ________ solution. The correct answer is: Saturated Kool-Aid - Powder, sugar, and water. Identify the solvent The correct answer is: water Intermolecular force present in Cl2? The correct answer is: dispersion In this mixture, which of the following will be the solute? Glass, spoon, powder, and water The correct answer is: The powder on the spoon Which is the strongest intermolecular force below" The correct answer is: Hydrogen bonding Intermolecular forces are the forces The correct answer is: between molecules Which of these is not an intermolecular force? The correct answer is: covalent bonding Which noble gas has the highest boiling point? The correct answer is: Xe Salt water is a The correct answer is: solution How does a solution become supersaturated? The correct answer is: dissolve more solute than you should be able to. How do you calculate the molarity of a solution? The correct answer is: Dividing the moles of solute by the L of solution Hydrogen bonding occurs when hydrogen is bonded to N, O, or F. Which of the following would have hydrogen bonding with water molecules? NO2, . H2S Which of the following molecules, based on the elements present, would be most polar? The correct answer is: HF Type of intermolecular force present in HF. The correct answer is: H-bond Intermolecular force present in CHF3 The correct answer is: dipole dipole Which of the following geometries could be nonpolar? The correct answer is: tetrahedral What type of solution is shown in the picture? 10% solute 90% water The correct answer is: Hypertonic What explains the very high melting and boiling point of water? The correct answer is: Hydrogen bonds between water molecules Which formula represents a nonpolar molecule? HBr c. CBr4 d. H2S Solubility refers to the ____ of solute that can dissolve in a certain volume or mass of solvent, at a certain temperature. The correct answer is: Amount Determine the type of intermolecular force present in sand, SiO2. The correct answer is: covalent network This is the part of a solution that dissolves The correct answer is: Solute When materials combine to form a mixture, they The correct answer is: a. keep their original properties. In general, substances with stronger intermolecular forces have ________ boiling points than those with weaker forces The correct answer is: Higher Another name for a homogeneous mixture is The correct answer is: a solution. How will the following molecule bond with itself? The correct answer is: Dipole