GENERAL CHEMISTRY I DARYLL T. CAGOYONG Instructor How did people in ancient times know what to use for soap, perfumes, metal refining, medicines and etc.? Describe the approaches used by the ancient Greek philosophers to understand the world around them. Define deductive and inductive reasoning. Name key individuals and groups who contributed to the science of chemistry. Describe the scientific method. Describe the rise and fall of phlogiston theory. • Developed some powerful methods of acquiring knowledge. • Known for their love of wisdom “PHILOSOPHY” • Was the approach answering questions the world. basic in about • Was the best way to answer fundamental questions. THALES of Miletus (625-545 BC) – believed that water was the fundamental unit of matter. Anaximenes (585 – 525 BC) – felt that air was the basic unit of matter. Empedocles (490-430 BC) – argued for the idea that matter was composed of earth, air, fire, and water. • Ideas of matter were put forth but could not be proven or disproven. Assumed four fundamental substances of matter : air, water, fire, and earth. First major philosopher to gather data thru observation. Could potentially be considered the first “real” scientist because of his systematic observations of nature before trying to understand what he was seeing. Recorded many observations in the field of astronomy, meteorology, biology, and optics. Was refuted by Leucippus and Democritus of his proposed theories about matter. • Deductive & Inductive Reasoning • Hypothesis, Theories, & Laws INDUCTIVE REASONING DEDUCTIVE REASONING From specific to general. From general to specific. E.g. E.g. "The coin I pulled from the bag is a penny. That coin is a penny. A third coin from the bag is a penny. Therefore, all the coins in the bag are pennies." "All men are mortal. Picolo is a man. Therefore, Picolo is mortal." • Wild/genius guess. • a supposition or proposed explanation made on the basis of limited evidence as a starting point for further investigation. • Tentative explanation of the natural law. • a model or way of looking at nature that can be used to explain natural laws and make further predictions about natural phenomena. When differing or conflicting theories are proposed, the one that is most successful in its predictions is generally chosen. Also, the theory that involves the smallest number of assumptions— the simplest theory—is preferred. • Answers to “why’s” • Phlogiston Theory suggested that flammable materials tended to weigh less after being burned. • Phlogiston – substance that is lost from a material when it is burned; burning up. Put forth in 1667 SUPPORTS Burning of wood—ashes remains weigh less than the original wood sample. (dephlogisticated- the remains) CONTRADICTS Mercury experiment of Lavoisier— when mercury was heated it would become mercuric oxide and would gain weight. When mercuric oxide was heated, it returned to mercury and released gas he identified as oxygen. Later the theory was replaced by the oxygen-based combustion. • A concise statement—always true, often in mathematical form, about natural phenomena. • combination of observation, experimentation, and the formulation of laws, hypotheses, and theories. • Developed by Francis Bacon but was later modified. 1. Ask a question. 2. Do background research. 3. Form a hypothesis. 4. Test the hypothesis. 5. Collect, Organize and Analyze the Data. 6. Draw Conclusions. 7. Communicate the results. STEP 1: ASK A QUESTION / OBSERVATIONS Observations based on senses or tools Sight, Smell, Touch etc. Observations of natural events usually raise a question Why did the water rise when the candle went out? Research is usually done to help find out more about the question raised The scientific method starts when you ask a question about something that you observe: How, What, When, Who, Which, Why, or Where? Rather than starting from scratch in putting together a plan for answering your question, you want to be a savvy scientist using library and Internet research to help you find the best way to do things and ensure that you don't repeat mistakes from the past. For a help in this step, use these sources: Background Research Plan Finding Information Bibliography Research Pape Based on your observation a Hypothesis is formed that tries to explain your observation or answer your question A hypothesis tries to predict or determine the outcome of your experiment even before the experiment is done Predictions usually stated in an “if ….. Then” statement. Ex: If I drop a rock then it will fall down toward the ground HYPOTHESIS MUST BE TESTABLE! Controlled Experiments are used to test a hypothesis A controlled experiment is an experiment that tests only one factor at a time by a control group is compared with an experimental group. Variables are not changed in the Control Group. Control groups allows you to see if a change in a variable creates an observed outcome by comparing the control group with the exp. grp A variable is a factor that changes in a controlled experiment. Variables are changed in the Exp. Group AND SERVE AS THE FACTOR TESTED. INDEPENDENT The variable being changed in the experiment DEPENDENT The variable that responds to the changed independent variable The variable being measured EX: growing plants with different amounts of fertilizer Scientists try to design experiments that will clearly show whether a particular VARIABLE caused an observed outcome. IF IT CANNOT BE OBSERVED THEN IT CANNOT BE TESTED!!! Can we test if a comet impact kill the dinosaurs? Why or Why Not? Sometimes models are used to represent a real object Used when it is difficult to control all of the variables or not possible to test “the real thing” Variables are not Changed in C.G. One Variable Changed in Each Exp. Group Data collected from experiments Data is defined as: recorded observations or measurements (qualitative = description, quantitative = number data) Based on observations Utilize tools or senses: sight, smell, temperature change etc. Data is organized in tables, charts and graphs so that it can be more easily analyzed Scientists decide whether the results of the experiment support a hypothesis. When the hypothesis is not supported by the tests the scientist must find another explanation for what they have observed NO EXPERIMENT IS A FAILURE: All experiments are observations of real events Results must be communicated in the form of a written paper or presentation Communication helps other scientists performing the same experiments to see if the results of your experiment are the same as their results Helps people see if results are repeatable! Get a paper and make a scientific method you’ve done in your life.