Second International Conference on Coastal Zone Engineering and Management (Arabian Coast 2010), November 1-3, 2010, Muscat, Oman ISSN: 2219-3596 A CORMIX Model Study of an Effluent Plume from a Marine Oufall at Minal Al Fahal, Oman Anton Purnama* Department of Mathematics and Statistics, Sultan Qaboos University, Sultanate of Oman MS Baawain Department of Civil and Architectural Engineering, Sultan Qaboos University, Sultanate of Oman YVB Sarma Department of Marine Sciences and Fisheries, Sultan Qaboos University, Sultanate of Oman Abstract: A submerged marine outfall at a distance of 150 m from the beach has recently been installed for discharging the drained water from crude oil tanks at the effluent treatment facility at Minal Al Fahal terminal. In order to meet the marine disposal limits of Oman, CORMIX was applied to simulate effluent plumes to predict, within a circular mixing zone with a radius of 150 m from the outfall, the concentration levels of certain components such as biochemical oxygen demand, chemical oxygen demand, dissolved oxygen, mercury, pH, phenol, total petroleum hydrocarbon, temperature and salinity. The effluent discharge density is greater than the surrounding ambient water density, and thus the effluent plume is negatively buoyant and will tend to sink towards the seabed. The potential benthic impact due to a concentrated effluent plume should be considered. Due to uncertainty in the input data, CORMIX simulations were carried out by varying the ambient current velocity, the effluent discharge density, and the effluent flow rate. The results showed that the permissible concentration levels are met within the regulatory mixing zone, except phenol. Hence, further treatment of effluent at the terminal is still needed in order to meet the marine discharge limits. Key words: CORMIX, effluent discharges, marine outfall, Minal Al Fahal, Oman. * Corresponding author. Email: antonp@squ.edu.om PDO has modified its marine discharge of treated effluents at MAF outfall system from an open gutter over the beach to a submerged outlet system, at a distance of 150 m from the beach (Baawain et al., 2009). The effluents are heterogenous and contain a wide range of pollutants, mainly oil and heavy metals in a matrix of highly saline wastewater. Therefore the impact of components of the effluent, such as biochemical oxygen demand (BOD), dissolved oxygen (DO), phenol, total petroleum hydrocarbon (TPH, also referred to as oil and grease), chemical oxygen demand (COD) and (heavy metal) mercury, should be studied. 1. Introduction Mina Al Fahal (MAF), an open sandy bay within the capital area, Muscat, is the site of Petroleum Development Oman's (PDO) oil storage facility (tank farm), tanker loading operations and the Oman Refinery Company (Jupp, 1998). Contaminated oily water, which is allowed to settle out and is drained from the crude storage tanks, is then treated in an effluent treatment plant (ETP). The plant is designed to remove the saline production water by the dehydration of settled oily water and then dispose of this treated water as an effluent into MAF, and also to recover any skimmed off oil in this process. The bathymetry of MAF bay shows a relatively flat bottom to the 30 m contour then a gentle slope towards the 1 60 m contour in the north-east. Tides in the Gulf of Oman have a strong diurnal component with a spring-tide range of 2.6 m or more (National Hydrographic Office, 2008). Other reported data and other observations (Jupp, 1998) showed that the nearshore currents in and around MAF are generally weak of up to 0.1 m/s with the predominant current running to the north-west (2700-3150) for 40-50% of the time and in the opposite direction (90 0-1350) for 1520% of the time. High but variable current speeds occur further offshore with maxima at spring tides of up to 0.8 m/s. The overall conclusion would appear to be that MAF experiences strong horizontal and mainly westerly water movements. point. The legislation also defines acceptable limits of the effluent release for various parameters, and the near-field dispersion modelling will show whether the outfall discharges are sufficient to achieve these standards. The design of the outfall is an important component to predict the fate of an effluent in the immediate vicinity of the outfall, and this will provide the starting point for the farfield (up to 1000 m) modelling for different ambient conditions of the various release scenarios. 3. CORMIX v6.0 Base Simulations The marine outfall at MAF is located at 150 m offshore on the uniformly sloping beach, and 3.5 m below the sea surface. Since the height of the port is 0.5 m above the seabed, CORMIX classifies the outfall as a deeply submerged discharge. The effluent density 1034.54 kg/m3 (typically of salinity 52 ppt and temperature 30 0C) is greater than the surrounding ambient density 1022.72 kg/m3. Therefore, this brine type of effluent plume is negatively buoyant and will tend to sink at the seabed. The base simulations with brine concentration (above ambient) set as 100% at the discharge point will be terminated when the boundary limits as specified by the regulatory mixing zone (RMZ) at 150 m radius from the discharge point or the region of interest (ROI) at 1000 m downstream are met. The input data are summarized in Table 1. A numerical modeling is required by Omani law to study the impacts of the MAF effluent disposal in the sea. The model should be applied to the worst initial mitigation conditions, i.e. the lowest wind speed concurrent with the diminishing high and low tides, the lowest recorded current speed in the location and the tidal reflection in view of such conditions. It should also be applied to the effluent discharge conditions of normal flow rate at 800 m3/day and peak flow at 1950 m3/day. 2. Cornell Mixing Zone Model Expert (CORMIX) System CORMIX is a U.S. EPA approved software system for the analysis, prediction, and design of outfall mixing zones resulting from the discharge of aqueous pollutants into diverse water bodies (Akar and Jirka, 1991; Del Bene et al., 1994; Jones et al., 1996). It employs a rule-based expert system to screen input data and select the appropriate hydrodynamic simulation model to simulate the physical mixing processes contained within a given dischargeenvironment interaction, ranging from internally trapped plumes, buoyant plumes in uniform density layers, and sinking of negatively-buoyant plumes. Boundary interaction, upstream intrusion, buoyant spreading, and passive diffusion in the far field are also considered. Table 1. Input data for the CORMIX base simulations Parameter Base value Ambient (unbounded coastal environment) Velocity of the currents 1.0 Depth at discharge 3.5 Bottom slope 1.34 Wind speed 1.0 Average Density 1022.72 Temperature 27 (Single port) Discharge Distance to nearest bank 150.0 Port diameter 0.1 Port height above bottom 0.5 Theta = Vertical angle -22.5 Sigma = Horizontal angle 90 Effluent flow rate 0.01 Salinity (above ambient) 17.0 Temperature (above ambient) 3.0 Average Density 1034.54 Mixing zone RMZ = Regulatory mixing zone 150 ROI = Region of interest 1000 Discharge type Single Port CORMIX has been successfully applied by regulators, engineers, and environmental scientists worldwide to the design and monitoring of wastewater disposal systems in oceans, rivers, lakes, and estuaries, and it is also recognized by regulatory authorities in all continents for environmental impact assessment (US EPA, 1999). Extensive comparison with field and laboratory data has shown that the CORMIX predictions on dilutions and concentrations (with associated plume geometries) are reliable for the majority of cases (Roberts and Tian, 2004). CORMIX results include contemporary three dimensional plume and diffuser visualizations, design recommendations, flow class descriptions and reporting oriented on discharge zone analysis (Doneker and Jirka, 2001). According to the Omani regulation for mixing zones, the modelling process will be limited to a domain of approximately 300 m in diameter centred on the outfall 2 Unit m/s m o m/s kg/m3 °C m m m o o m3/s mg/l °C kg/m3 m m - Table 2. The regulatory mixing zone characteristics The dynamic of MAF brine effluent plume motion is classified as (CORMIX flow class NH4) the near bottom, negatively buoyant flows in a uniform density layer. As the concentrated brine effluent is released from the outfall, the jet plume becomes strongly deflected by the ambient current. The deflected plume slowly descends toward the bottom and once it reaches the seabed within 8 m downstream, the plume will remain at the seabed due to its negative buoyancy. The height of the top part of the plume slowly rises and reaches its maximum within 200 m downstream, and the concentration distribution becomes relatively uniform across the plume width and thickness (Figure 1). After the concentrated plume is attached to the seabed, it continues to spread laterally due to bottom density current while it is being advected by the ambient current. In the absence of ambient stratification, the concentrated plume will proceed down the slope until it reaches the ROI. Therefore, the potential benthic impact can no longer be ruled out. Concentration at the edge of RMZ Dilution at the edge of RMZ RMZ location (centerline coordinates) RMZ plume dimensions Cumulative travel time 0.28 % 357 X=150 m Y=1.30 m Z= -3.53 m Half-width= 2.30 m Thickness= 1.11 m 127.53 sec The plume conditions at the boundary of the RMZ are presented in Table 2. The concentrated plume dilution, defined as the ratio of the initial concentration (above ambient) at the discharge point to that at a given location, is given in Figure 3. A plume dilution value of 562 is obtained at the ROI. Figure 1. Side view of the negatively buoyant plume of MAF effluent The three dimensional view of the concentrated effluent plume within the RMZ is shown in Figure 2. The origin is located at the sea surface directly above the submerged outfall, and 150 m offshore. The x-axis points downstream, the y-axis points to the left (in the flow direction), and the z-axis points upward. The CORMIX base simulation results show that the overall concentration increase is less than 0.3% at the edge of the RMZ. Figure 3. The MAF effluent plume dilution within RMZ Other CORMIX base simulations were carried out for other components of the MAF effluent, and the results at the boundary of the RMZ are summarized in Table 3, together with the maximum permissible limits (or Water Quality Standard=WQS) set by the Oman government (MD 159/2005) that should be met within the RMZ. The results show that WQS for all components are met for the normal flow rate for the effluent discharge conditions of 0.01 m3/s. 4. CORMIX Sensitivity Study CorSens is the CORMIX sensitivity analysis tool that generates a sensitivity study case to address model performance due to inherent uncertainty in the input data (Alameddine and El-Fadel, 2007). Therefore, instead of the tedious repetition of manual data entry, it automatically Figure 2. The negatively buoyant plume of MAF effluent 3 Table 3. Summary of MAF outfall effluents Effluent MAF Outfall RMZ DO (mg/l) 0.71 5.985 pH 6.8 7.997 Salinity (ppt) 52 35.05 Temperature (oC) 30 27.01 BOD (mg/l) COD (mg/l) Mercury (mg/l) Phenol (mg/l) TPH (mg/l) 155 1400 0.004 0.7 90 0.434 3.919 0.0001 0.002 0.252 Table 4. The CorSens results summary on the ambient velocity RMZ centerline (in m) X Y Z 150.0 1.30 -3.53 150.0 1.42 -3.53 150.0 1.61 -3.54 150.0 1.89 -3.54 150.0 2.35 -3.56 150.0 3.11 -3.57 150.0 4.57 -3.61 150.0 8.57 -3.70 150.0 18.78 -3.94 150.0 65.68 -5.02 Dilution S 357 310 263 218 181 153 116 64 27 15 Dilution Ambient 10.6 6.0 6 8.0 8.5 35.0 3.0 27.0 7.75 7 4 350 6 0 0 0 0 0 of the RMZ, the elongated effluent plume grows and becomes wider in the y-axis. The RMZ half-width plume dimensions at velocity 0.2 m/s equals to 7.11 m. The uncertainty in sea conditions has big effects on effluent plume dilution (or concentration at the edge of RMZ), and thus the potential benthic impact of a concentrated plume should be considered. It is found that the plume dilution value at ambient velocity 0.2 m/s is 13 times smaller than that at 1.0 m/s. increments data to analyze mixing zone conditions. Sensitivity studies are also motivated by the fact that there are no user-adjustable model “tuning” coefficients within CORMIX. The basis for this restriction is that normal variation in ambient conditions are likely to have greater influence over mixing zone behavior than “tuning” a model parameter to obtain a “desired” result. Velocity (m/s) 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 WQS Concentration 5.5 (0.5 below ambient) 7.8 (0.2 below ambient) 37.0 (2 above ambient) 28.0 (1 above ambient) 20.0 200.0 0.001 0.002 15.0 Table 5. The CorSens results summary on the discharge density % C 0.28 0.323 0.38 0.459 0.551 0.655 0.866 1.56 3.70 6.68 Density (kg/m3) 1034.54 1032.54 1030.54 1028.54 1026.54 1024.54 RMZ centerline (in m) X Y Z 150.0 1.30 -3.53 150.0 1.30 -3.53 150.0 1.30 -3.53 150.0 1.31 -3.53 150.0 1.32 -3.53 150.0 1.35 -3.53 Dilution S 357 369 383 399 419 451 % C 0.28 0.271 0.261 0.251 0.239 0.222 Next, further simulations were also carried out by varying the discharge density (an effluent parameter), which reflect the uncertainty on the MAF effluent property, and the results summary of reducing discharge density from 1038.54 kg/m3 to 1024.54 kg/m3 are presented in Table 5. The density variations represent the base effluent with a temperature rise up to 50 0C, and a salinity decrease down to 39 ppt. Since the plume dilution values are all bigger than the base dilution, reducing the discharge density improves the effluent plume characteristics at the edge of the RMZ. First, the CorSens simulations were carried out by varying the ambient current velocity (a coastal environment parameter), which reflect the uncertainty in the sea conditions, while holding the other input parameters the same as the base simulation given in Table 1, and the results summary of reducing the ambient velocity from 1.0 m/s to 0.1 m/s are presented in Table 4. For calm sea conditions (i.e. when the ambient velocity is less than 0.2 m/s), also perhaps due to its negative buoyancy, the concentrated brine plume becomes immediately attached to the seabed as it leaves the outfall, and then spreads due to bottom density current. At the edge Lastly, the simulations were carried out by varying the effluent flow rate (a discharge parameter), which reflect the uncertainty on the effluent treatment plant's operation, and 4 the results summary of increasing effluent discharge rate from 0.01 m3/s to 0.025 m3/s are presented in Table 6. The normal flow rate for the effluent discharge conditions at MAF outfall are 800 m3/day which is equivalent to 0.01 m3/s, and the peak flow rate conditions are 1950 m3/day or about 0.023 m3/s. At the edge of RMZ, the effluent plume dilution values decrease but they are still much higher than the base plume dilution, except for phenol. ambient velocity reduces from 1.0 m/s to 0.2 m/s. Although all the concentration values are increasing, they are still below the WQS values, with the only exception being phenol, where all values are higher than the maximum permissible limit of 0.002 mg/l. 5. Conclusions CORMIX base simulation results showed that the permissible concentration levels are met within the regulatory mixing zone. However, phenol concentration levels are found to be higher than the permissible limits under the calm sea conditions and when the effluent discharge rate is bigger than the normal flow rate for the effluent discharge conditions of 800 m3/day. Hence, further reduction of phenol concentration at the discharge point is required by upgrading the treatment plant. In order to reduce the plume dilution to below 50 for the calm sea conditions, the concentration of phenol at MAF outfall should be less than 0.1 mg/l. Table 6. The CorSens results summary on the effluent flow rate Flow rate (m3/s) 0.01 0.0125 0.015 0.0175 0.02 0.0225 0.025 RMZ centerline (in m) X Y Z 150.0 1.30 -3.53 150.0 1.58 -3.54 150.0 1.90 -3.54 150.0 2.25 -3.55 150.0 2.63 -3.56 150.0 3.05 -3.57 150.0 3.51 -3.58 Dilution S 357 292 251 230 221 208 195 % C 0.28 0.343 0.399 0.434 0.453 0.481 0.512 As the concentrated effluent plume is attached to the seabed and spreads due to bottom density current, the potential benthic impact should also be considered. The predicted concentration values of MAF effluent plumes at the edge of RMZ are given in Table 7 as the Table 7. Summary of the MAF effluents plume at RMZ on the ambient velocity 1.0 0.8 0.6 Effluent WQS Dilution 357 263 181 DO (mg/l) pH Salinity (ppt) Temperature (oC) BOD (mg/l) COD (mg/l) Mercury (mg/l) Phenol (mg/l) TPH (mg/l) 5.5 7.796 37.0 28.0 20.0 200.0 0.001 0.002 15.0 10.6 5.9 8.5 3.0 7.75 7 4 350 6 5.985 7.997 35.048 27.008 0.434 3.922 0.0001 0.002 0.252 5.980 7.995 35.065 27.011 0.589 5.323 0.0002 0.0027 0.342 5.971 7.993 35.094 27.017 0.856 7.735 0.0002 0.0039 0.497 0.4 0.2 116 27 5.954 7.990 35.147 27.026 1.336 12.069 0.0003 0.006 0.776 5.804 7.956 35.630 27.111 5.741 51.852 0.0015 0.0259 3.333 Alameddine, I. and El-Fadel, M. 2007. “Brine discharge from desalination plants: a modelling approach to an optimized outfall design”, Desalination, 214, 241-260. Acknowledgments The funding of this study was provided by Sultan Qaboos University and PDO under the support service agreement AS/ENG/CIVL/09/02. 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