Original Author: Prof. Niall Tait Modified by Prof. Ravi Prakash Updated for ELEC 4703 Winter 2022 by Robert Gauthier ELEC 4703 LAB 4 SOLAR CELL TESTING: PART 1 OVERVIEW In this lab we will begin testing the solar cells designed by the current 4703 class. The cell characteristics will be measured using an HP4145 Semiconductor Parameter Analyzer. CONNECTION TO THE REMOTE SERVER I. Start by connecting to the Carleton VPN as done in Labs 1, 2 and 3. For detailed instructions II. please refer to the Lab 1, 2 or 3 tabs in Brightspace III. Once connected to the Carleton VPN, open labstats on your browser using the link: https://remoteaccess.labstats.com/Carleton-University-Electronics-Engineering-me4135. Under the heading ME4135, all the available lab stations are shown. For the 8 lab groups, we have set up stations (7-14) and below is the breakdown of groups and their corresponding stations. Lab group Station number 7 7 8 8 9 6 10 1 11 2 12 3 13 4 14 5 IV. V. Find your above assigned lab station and click on the connect button. Only one user will connect to the lab station using the procedure above; the other group members will participate in all lab activities interactively through group discussion and multiple user screenshare features on BBB. Once you click the connect button, you will be asked to download a file, click on the download button. If your lab station is not shown, it means that the lab station is currently in use already or the previous user did not sign out correctly. If this is the case, alert the TA in the lab and they will reset the station for you. 1 VI. Open the downloaded file, which will be named the same as the assigned lab station number. You will be shown the following screen, click on connect. You will then be asked to enter your credentials. You must enter “VLSI\” before your username (same as your MC1 username) and the password is “pW” followed by your student number. Click on OK. You will be asked to confirm that you would like to connect. Click on “Yes” and you will connect to the lab station. 2 VII. Getting started with IntuiLink Data Capture: Perform a quick search by typing IntuiLink in the Windows search bar. VIII. Click the instruments tab from the top menu and select 4145A/B. 3 IX. To log into the instrument, you should ensure that the instrument addresses is selected as: GPIB 17. Make sure to save all work on your H: drive to avoid any data loss. Before starting the lab, read through the rest of this instruction manual. 4 INTRODUCTION TO THE SOLAR TEST PROBE STATIONS Before you begin testing anything, please familiarize yourself again with the probe stations (Figure 1). These stations include an incandescent lamp with a high temperature tungsten-halogen bulb intended to simulate sunlight, and a temperature-controlled chuck. The lamp is pre- calibrated for you so that the input spectral power density to the cell would be (Hin) 100 mW/cm2. We will see that temperature control is essential to obtain an accurate measurement of Voc. The middle and bottom gray/black buttons on the temperature controller respectively raise and lower the set-point temperature. Stage cooler power supply Lamp Temperature controller Vacuum Pump Chuck/Stage SMU Cables Probe positioner/ Micromanipulator Figure 1: Carleton solar cell probe station CELL TESTING In order to test a cell, we need to create electrical contacts with the front metal grid and the back contact. The polished chuck acts as the back contact. The front contact is achieved by positioning a fine tip micro-positioner probe onto the busbar contact pad. Figure 2 shows a closer look at the micromanipulator and probe. For all experiments, a TA will setup the front and back contact of each cell. 5 Figure 2. Closer view of the SMU connection and the micromanipulator. GETTING STARTED Our Lab TA would have pre-loaded the program solar1 on the HP4145. This program will produce a simple solar cell I-V curve, with the emitter bias on (SMU 1) set to sweep from 0 to -0.7V. SMU 2 is set as common and is connected to the chuck (base). Click the camera icon to access the webcam feed to step through the menus until the graphics data display page appears. The TAs will essentially setup all manual data capture steps, which you can observe through the camera feed. Cell setup: One of the TAs will place a wafer piece that we want to test and locate your group’s cell. Using tweezers, they will center the piece on the chuck and turn on the backside vacuum. The chuck temperature controller will be turned on and set to 25°C. Under Solar 1 configuration, SMU1 sources voltage VEE and reads current IEE. The chuck to SMU2, which applies a common ground reference voltage to the base. The lamp is set on to the brightest setting (“II”) and calibrated to give an incident light power density of approximately 100 mW/cm2 at the chuck surface, equivalent to the light power density of AM1.5 sunlight. 1. ILLUMINATED I-V CHARACTERISTICS Using the HP4145 record the illuminated I-V curve (IEE versus VEE) for your AR-coated cell. Capture the curve with IntuiLink Data Capture and include it in your final report. The assisting TA will turn on the cursor/marker function in the 4145, to accurately identify values of Voc, Isc, Vmp and Imp, and label these on your graph. Compute FF and Jsc. Compute the energy conversion efficiency η. 2. EFFECT OF ANTIREFLECTION COATING At this point, the setup will switch to a cell of your design without AR coating. Use a quarter from the same wafer tested in Part 1. Record the IEE-VEE curve IntuiLink Data Capture and include it in your final report. Determine Voc, Isc and Jsc and η. What percentage improvement in Jsc is provided by the antireflection coating? How does this compare to the predictions of Lab 3 section 3? Looking at it from the webcam, what color does the AR coated cell appear? Why does it appear to 6 have that color? Hint: Think constructive interference for reflected wavelengths. 3. THE SUPERPOSITION PRINCIPLE The Superposition Principle states that the current IL flowing in an illuminated solar cell at a bias voltage V is given by: IL(V) = ID(V) + Isc (1) where ID is the dark current and Isc is the short circuit photocurrent. To verify this, we will switch back the test cell to your group’s AR coated cell. Once the setup is ready, record the IEE–VEE curve under illumination. and store the curve (This will be done by pressing the grey soft key > Store). Write down the value of Isc. Next completely cover the cell with a black cloth. Program the HP4145 to compute ISUP = IEE + Isc. Record the ISUP versus VEE curve. Using the recall feature, compare the ISUP-VEE curve with the actual illuminated I-V curve. Include the superposed curves in your report. Comment on the accuracy of the superposition principle. Suggest a reason for any measurable deviation from Equation (1). Does Equation (1) over or underestimate the energy conversion efficiency of your cell? 4. TEMPERATURE EFFECTS To observe the effect of temperature on solar cell, you will test your solar cell and record the illuminated IEE-VEE curve at 20°C and at 40°C. Using the append feature of the HP4145, a graph with the two curves overlapping can be captured. Include the comparison plot in your final report. Discuss the effect of temperature on the cell characteristics and efficiency. Briefly explain your observations in terms of the temperature dependence of the dark current. When finished, we will return the chuck temperature to room temperature, 25°C. 5. RED AND YELLOW RESPONSE A yellow light filter will be placed in front of the light source by a TA. Record the IEE-VEE curve and note the value obtained for Isc. Repeat this measurement again with a red-light filter placed between the light source and the cell. Can you explain the difference in values of Isc obtained if any for the unfiltered light vs the yellow light filter vs the red-light filter setup? DATA REPORTING A report is not required for Lab 4 since all the testing and characterization data is part of a final project report on solar cell design, fabrication and testing. For this purpose, at the end of the lab you are required to prepare a table summarizing all of your results obtained. This table should include the wafer name, substrate resistivity, emitter sheet resistance, Jsc, Voc, FF and η. Ensure to distinguish between uncoated and AR coated cells and any cells tested with the red and yellow filters. TAs will verify this table during Lab check-out. 7