Charge transport in semiconductors: electrons and holes Intrinsic semiconductor Electron in a semiconductor crystal can absorb energy became free leaving a positively charged vacancy – “hole” . n-type material: electrical current is a flow of the negatively charged electrons As is a donor dopant or donor impurity for Si p-type material: electrical current is a flow of the positively charged vacancies – “holes” Al is an acceptor dopant or acceptor impurity for Si The law of mass action: intrinsic semiconductor Intrinsic carrier concentration Data from “Semiconductor devices:basic principles” by J. Singh, Jon Wiley&Sons. Inc. Fermi level position: summary Light absorption in semiconductors Reduced density of states