10 L A S _ S ci Science Activity Sheet Quarter 4 – MELC 1 Weeks 1-2 Gas Laws REGION VI – WESTERN VISAYAS Science 10 Activity Sheet No. 1: Gas Laws First Edition, 2021 Published in the Philippines By the Department of Education Region 6 – Western Visayas Republic Act 8293, section 176 states that: No copyright shall subsist in any work of the Government of the Philippines. However, prior approval of the government agency of office wherein the work is created shall be necessary for exploitation of such work for profit. Such agency or office may, among other things, impose as a condition the payment of royalties. This Learning Activity Sheet was developed by DepEd Region 6 – Western Visayas. ALL RIGHTS RESERVED. No part of this learning resources may be reproduced or transmitted in any form or by any means electronic or mechanical without written permission from the DepEd Regional Office 6 – Western Visayas. Development Elena P. Gonzaga,Team of Science Activity Sheet Donald T. Writer: Melvin B. Medina Genine Rovel T. Pastias R. Editors: Rochelle , Ma. Concepcion G. Pagcaliwagan Salcedo, Illustrator: Moonyeen Melvin B. C. Medina Rivera, Anita S. Grande Layout Artist: Jennie H. Gubalane, Minda L. School Division Quality Assurance Team Soldevilla, Rochelle T. Pastias Daisy L. Lopez, Ma. Concepcion G. Pagcaliwagan Fatima A. Cordero Grace B. Jungco Ana Lee C. Bartolo Division of La Carlota City Management Team Neri Anne M. Alibuyog, Melgar B. Coronel Ana Lee C. Bartolo Ma. Concepcion G. Pagcaliwagan Leopoldo F. Sichon Gilda C. Lastimosa Regional Management Team Ramir B. Uytico, Elena P. Gonzaga Rovel R. Salcedo Pedro T. Escobarte, Jr. Donald T. Genine Anita S. Gubalane Moonyeen C. Rivera, Minda L. Soldevilla Joseph M. Pagalaran Daisy L. Lopez Introductory Message Welcome to Science 10! This Learning Activity Sheet is a product of the collaborative efforts of the Schools Division Office of La Carlota City and DepEd Regional Office VI – Western Visayas through the Curriculum and Learning Management Division (CLMD). This was developed to guide the learning facilitators (teachers, parents and responsible adults) in helping the learners meet the standards set by the K to 12 Basic Education Curriculum. This Learning Activity Sheet is a self-directed instructional material aimed to guide the learners in accomplishing activities at their own pace and time using the contextualized resources in the community. This will also assist the learners in acquiring the lifelong learning skills, knowledge and attitudes for productivity and employment. For the learning facilitator: This Science 10 Activity Sheet will help you facilitate the teaching-learning activities for the specified Most Essential Learning Competency (MELC) with minimal or no face-to-face encounter between the teacher and the learner. This is made available to the learners with the references/links to ease independent learning. For the learner: This Science 10 Activity Sheet was developed to help you continue learning even if you are not in school. This learning material provides you with meaningful and engaging activities for independent learning. Being an active learner, carefully read and understand the instructions then perform the activities and answer the assessments. This will be returned to your school and teacher on the agreed schedule. Name of Learner: _________________________________________________________ Grade and Section: _____________________________ Date: ____________________ SCIENCE 10 ACTIVITY SHEET No. 1 Gas Laws I. Learning Competency with Code Investigate the relationship between volume and pressure at constant temperature of a gas; volume and temperature at constant pressure of a gas and explains these relationships using the kinetic molecular theory (S10MTIV-a-b-21). II. Background Information for Learners This learning activity offers interesting discussion about gases. You are given the chance to get to know important concepts and ideas that will make you appreciate the properties and the behavior of gases. Most gases are invisible to your naked eye. You can name as many solids and liquids that you can see around but not gases. You can only name a very few colored ones like the black smoke produced by vehicles or the ones you see in your kitchen when you cook with firewood or charcoal. Invisible gases are present everywhere. They are in a clear bottle that seems to be empty, in the production of food by the plants during photosynthesis, and even in playing your favorite sports. Can you ride your bicycle if its wheels are not sufficiently filled with air or gas? Your very existence requires the presence of invisible gases. You inhale oxygen and exhale carbon dioxide during the process of respiration. Can you survive here on earth without these gases? In this learning activity, you will learn the different properties of gases and how these properties are related to one another. Furthermore, after going through the activities provided, you will explain the relationships that exist between the properties of gases in terms of the Kinetic Molecular Theory. III. Accompanying DepEd Textbook Department of Education. (2015). K-12 Basic Education Curriculum, Science 10 Learner’s Material (pp 171-182). Pasig City, Philippines Department of Education. (2015). K-12 Basic Education Curriculum, Science 10 Teacher’s Guide (pp 48). Pasig City, Philippines IV. Activity Proper ACTIVITY 1 Properties of Gases Study the situations below and answer the questions that follow. Write the answer on your answer sheet. Situation 1. The mass of a deflated balloon was measured using a digital balance. Such balloon was later inflated and place again on the digital balance to determine its mass. Data were gathered and indicated in the table below. Study the table and answer the questions that follow. Table 1. Comparison of the mass of inflated and deflated balloon. Trial Mass of the deflated Mass of the inflated balloon in grams balloon in grams 1 3.46 13.21 2 3.48 13.76 3 3.49 15.01 Questions. 1. Which is heavier, the deflated or inflated balloon? Why? ___________________________________________________________________________ 2. What can you infer from the data presented in the table? __________________________________________________________________________ Situation 2. An approximately 40 mL of water was placed in a graduated cylinder. It was then added with cooking oil up to 60 mL. After a while the oil float on top of the water. Later, the tip of syringe (with its plunger pulled up) was dipped in the mixture until it reaches the water portion. The plunger was pushed down, and the volume of the mixture was again recoded as shown in Table 2. Table 2. Trial Volume of water plus Total volume when air oil was introduced 1 2 3 60 mL 60 mL 60 mL 87 mL 90 mL 91 mL Questions. 1. What happens to the volume of water and oil mixture when air was introduced? ________________________________________________________________________ 2. What does it indicate? _____________________________________________________________________ Situation 3. A 150 mL water was placed in a beaker. Using a thermometer, the initial temperature of the air above the water was determined. The beaker is then filled with ice cubes and after 5 minutes, the temperature of the air above it was measured and recorded. Finally, the beaker was placed on a tripod over an alcohol lamp. It was heated until it boils, then the temperature of air just above the water was measured. The data gathered in this activity are indicated in the Table 3 below. Table 3. Temperature of air Trial Initial temperature air 1 23°C 2 23°C 3 23°C Temperature of Temperature of of air above iced air above the water boiling water 14°C 85°C 15°C 88°C 14°C 92°C Question. 1. Is there a difference in the temperature of air in the three set-ups? If yes, explain what cause/s the difference. ______________________________________________________________________ Situation 4. An inflated balloon was placed in the mouth of an Erlenmeyer flask with hot water. After a few minutes, the balloon inflated. In another case, a deflated balloon was placed in the mouth of an Erlenmeyer flask with water. The flask was heated over an alcohol lamp. After a while, the balloon starts to inflate and changes its size and shape. Questions. 1. What cause/s the changes in the size and shape of inflated balloon when place in an Erlenmeyer flask with hot water? ________________________________________________________________________ 2. What cause/s the balloon in the Erlenmeyer with water to inflate and changed its size and shape when the flask was heated? ________________________________________________________________________ After knowing that gases have mass, volume, temperature, and pressure, it’s a must for you to familiarize with the units being used to express these measurable properties of gases. The table below shows the common units and some of their interconversions. Table 1: Common Units for Variable SI Unit Volume cubic meter (m3) cubic decimeter(m3) cubic centimeter(m3) Pressure Pascal (Pa) Pressure and Volume Metric Unit English Unit liter (L) Quart (qt) milliliter (mL) Gallon (gal) atmosphere torr (atm) lb/in2 psi millimeters of mercury (mm Hg) centimeters of mercury (cm Hg) Volume units and their equivalents: 1 mL = 1 cm3; 1 L = 1 dm3 ;1 m3 = 1000 L Pressure units and their equivalents: 1 atm = 760 mm Hg = 76 cm Hg = 760 torr = 101325 Pa = 14.6956 psi = 9.81 N/cm2 Temperature units and their equivalents: 0˚C = 273.15 K; 0˚C = 32˚F These units of measure will be utilized as you go along with the discussions on gases. The measurable properties of gases are interrelated and can be modeled mathematically. Now, you will investigate the relationship between the volume and pressure of a confined gas at constant pressure. ACTIVITY 2 Volume-Pressure Relationship in Gases Have you observed how the balloon expands and gets hard when you blow air on it? Have you also observed what happens when you squeezed an inflated balloon? This activity gives a quantitative treatment of the relationship between volume and pressure in gases. What you need Plastic or syringe Graphing paper What you have to do A. Qualitative Treatment of Volume-Pressure Relationship 1. Observe the qualitative relationship between gas volume and pressure at constant temperature. Follow these steps: a. Fill a syringe with air by pulling the plunger up. b. Press your finger against the end of the tip of the syringe in order to trap the air. c. Push the plunger in. Try again but press harder this time. Directions. Answer the following questions. Write the answer on your answer sheet. 1. What have you observed? ___________________________________________________________________________ 2. Is the trapped air in the syringe affected by the added pressure as you press down the plunger with minimal force? ___________________________________________________________________________ 3. How do you relate the pressure (ex., applied force) to the volume or compressibility of air in the syringe? ___________________________________________________________________________ B. Quantitative Treatment of Volume-Pressure Relationship A syringe having a diameter of 1.5 cm was filled with a volume of air as shown in Column A in the table below. A force that acts on the volume of air was also determined and are indicated in Column B. Directions: Copy and complete the data Table 1.1. Compute for Pressure (Column C) Total Pressure (Column D) P x V (Column E) Pt x V (Column F) and P/V (Column G). Item number 1 is done for you. Write the answer on your answer sheet. Table 1.1 Data for deriving pressure-volume relationship Volume (V) of air in syringe (cm3) Pressure (P) (force/area of plunger) (N/cm2) (A) Force (F) (weight of plunger) + weight added to plunger, (N) (B) 4.9 0.6 0.34 4.4 4.0 3.6 3.4 2.6 4.6 6.8 8.8 (C= B/1.77) Total pressure (Pt) (Pt =P+) atmospheric pressure ) (N/cm2) (D= 10 +C) 10+0.34= 10.34 PxV Pt x V P/V (E=AxC) (F=AxD) (G=C/A) 1.67 50.47 0.06 Since the inside diameter (d) of the syringe is given, you can compute the area of the plunger circular cross section. The formula for finding the area of a circle is A= πr2, where r is radius Since d = 1.5 cm and d= 2r, A = π (d/2)2. Upon substitution to the equation, you can obtain A = 1.77 cm2 Step 1 Compute the pressure (P) using the equation P = F/A. Record your answers in the Column C of Table 1.1. For the given set of data in the table, pressure is computed a: P = 0.6N/1.77 cm2 = 0.34 N/ cm2. Step 2: The atmosphere also exerts pressure on the plunger. The total pressure (Column C) on the air in the syringe is the sum of the atmospheric pressure, which is 10 N/cm2 at sea level and the pressure due to force (F) applied. In the first set of data, the total pressure is computed as Pt = 0.34 N/cm2 + 10 N/cm2 = 10.34 N/cm2 Step 3 Plot a graph with the pressure at the y axis and volume at the x axis. Do this in your answer sheet. Directions. Answer the following. Write the answer on your answer sheet. 1. What happened to the volume of the syringe as the set of weights is added on top of it? ___________________________________________________________________________ 2. What happened to the pressure on the syringe when the set of weights is added? ___________________________________________________________________________ 3. Describe the graph. ___________________________________________________________________________ 4. What is the relationship between volume and pressure of gases as indicated in the graph? ___________________________________________________________________________ The relationship between the volume and pressure of gases at constant temperature is known as Boyle’s law. The law states that the volume V of a sample of gas changes inversely with the pressure P of the gas as long as the temperature T and the amount of gas n remain constant. This means that if the volume is doubled, the pressure will be reduced by one-half. Boyle’s law equation can be expressed as: Vα 1 at constant T and n P Where: V = volume, P = pressure, T = temperature and n = amount of the gas. The volume of a gas is inversely proportional to its pressure, if temperature and amount of a gas are held constant. Take a look at the equation again and try to change the proportionality sign (α) with the equal sign (=). 1 Vα at constant (k) P V= k Thus, k = VP P P1V1 = P2V2 (Boyle’s Law Equation) Sample Problem The inflated balloon that slipped from the hand of Renn has a volume of 0.50 L at sea level (1.0 atm) and it reached a height of approximately 8 km where the atmospheric pressure is approximately 0.33 atm. Assuming that the temperature is constant, compute for the final volume of the balloon. Initial Conditions V1= 0.50 L P1= 1.00 atm Equation: P1V1 V2 = P2 Solution: P1V1 V2 = P2 (1.0 atm) (0.50 L) V2 = 0.33 atm 0.5 L V2 = = 1.5 L 0.33 Final Conditions V2=? P2= 0.33 atm ACTIVITY 3 Boyle’s Law Problem Directions: Read and understand each problem. Use Boyle’s law to solve the problem by writing the given, equation and solution. Box your final answer. Write the answer on your answer sheet. 1. A scuba diver needs a diving tank in order to provide breathing gas while he is underwater. How much pressure is needed for 6.00 liters of gas at 1.01 atmospheric pressure to be compressed in a 3.00-liter cylinder? ACTIVITY 4 Volume-Temperature at Constant Pressure What relationship exists between the volume and temperature of gas? What you need 1 rubber balloon 1 small basin tape measure tap water hot water ice What you have to do 1. Prepare 1 small basin. 2. Inflate a balloon. 3. Measure the circumference of the balloon using a tape measure. 4. Fill half of the basin with 1 L hot water. 5. Submerged the inflated balloon in hot water for 5 minutes by pushing down with your hands. Then measure again its circumference. Record your data. Do the same for second and third trial. Warning: Exercise caution when performing this activity. 6. Repeat procedures 2-5 using tap water and cold water. 7. Record the results in table 1.2 Table 1.2 Data on Determining the Size of the Balloon at Different Temperatures Set-up Temperature Average Circumference of the Balloon (cm) Description Trial 1 Trial 2 Trial 3 Hot water hot Tap water warm Cold water cold Directions. Answer the following questions. Write the answer on your answer sheet. 1. What happens to the size of the balloon as the temperature decreases? ___________________________________________________________________________ 2. How does the change in the temperature relate to the volume of gas in the balloon? ___________________________________________________________________________ The volume - temperature relationship in gases (k = V/T) was determined by and named after Jacques Charles. Charles’ Law states that at constant pressure, the volume of a fixed amount of gas is directly proportional to the Kelvin (K) temperature. Mathematically, Charles’ Law can be expressed as: V α T at constant P Where: V = volume and T = temperature expressed in Kelvin Kelvin is the basic unit for measuring temperature in the International System (SI). “It denotes the absolute temperature scale whereby 0K or absolute zero is defined as the temperature when molecules will have the lowest energy. Removing the proportionality symbol (α) and using the equality sign (=) the equation will be as follows: 𝐕 V = k T or 𝒌= 𝐓 Whereas, V1 is the initial volume and V2 is the final volume T1 is the initial temperature and T2 is the final temperature. If the volumetemperature ratios are the same in the initial and final conditions, then you will arrive at this equation: V1 = T1 V2 (Charles’ Law Equation) T2 Directions: Copy and complete the table with the necessary information on your answer sheet. Then, plot the data from Table 1.3 in a graph by placing the volume in the y axis and temperature at Kelvin scale in the x axis. Trial 1 2 3 4 Table 1.3 Data on Volume-Temperature Relationship Volume Reading (ml) Temperature (oC) Temperature (K) 25 30 35 40 2 57 102 152 Note: To convert °C to K, use this formula: K = °C + 273.15 Example: 5 °C = K, K = °C + 273.15, K = 5+ 273.15 = 278.15 K Directions. Answer the following questions. Write the answer on your answer sheet. 1. What happens to the temperature when the volume increases? ___________________________________________________________________________ 2. Describe the graph. ___________________________________________________________________________ 3. What is the relationship between volume and temperature of gases at constant pressure? ___________________________________________________________________________ Apply Charles’ Law in solving problems related to volume- temperature relationship in gases. Sample Problem: An inflated balloon with a volume of 0.75 L at 30°C was placed inside the freezer where the temperature is -10°C. Find out what will happen to the volume of the balloon if the pressure remains constant. Support your answer with computation. Initial Conditions V1= 0.75L T1= 30 0C =303K Final Conditions V2=? T2= -10 0C =263 K Equation: V2 = V1T2 T1 Solution: V2 = V2 = V1T2 T1 (0.75 L) (263. K) L) V2 = 303. K 197.25 L 303 = 0.65 L Activity 5 Solving Charles Law Problem Directions: Read and understand each problem. Use Charles law to solve the problem by writing the given, equation and solution. Box your final answer. Write the answer on your answer sheet. 1. A cylinder with a movable piston contains 250 cm3 air at 10°C. If the pressure is kept constant, at what temperature would you expect the volume to be 150 cm3? Activity 6 Kinetic Molecular Theory The Kinetic Molecular Theory (KMT) explains the properties of gases and describes the behavior of gases. It states that: 1. Gases are composed of molecules. The distances from one molecule to another molecule are far greater than the molecules’ dimensions. These molecules can be considered as spherical bodies which possess negligible mass and volume. Figure 1. Molecules of Gases 2. Gas molecules are always in constant random motion and they frequently collide with one another and with the walls of the container. Collision among molecules are perfectly elastic, that is, energy may transfer from molecule to molecule as the result of collision but the total energy of all the molecules in the system remains the same/constant. 3. There is a neither attractive nor repulsive force between or among gas molecules. 4. Movement of gas molecules is affected by Figure 2. Molecules of Gases in Random Motion temperature. The molecules move faster as the Images are taken from Science10 temperature increases. This is due to heat that is Learner’s Module converted to KE energy of molecules. As the molecules absorb more KE, they move faster and bump the walls of the container causing it to expand, the material is elastic. Activity 7 Directions. Answer the following questions on your answer sheet. 1. How do you explain the relationship of volume and pressure using the Kinetic Molecular Theory? _____________________________________________________________________ 2. How do you explain the relationship of volume and temperature using the Kinetic Molecular Theory? ____________________________________________________________________ Activity 2 A 1. The plunger does not move downward if the other end is closed. 2. No, a minimal force seems to have a very small effect on the plunger as it is being pressed down. 3. The volume of air decreases as pressure increases. B Table 1.1 Data for deriving pressure-volume relationship PxV Pt x V Pressure (P) Total pressure (Pt) 10.3 1.47 50 11.5 6.6 50 12.6 10.4 50 13.8 13.7 50 15.0 17.0 50 0.3 1.5 2.6 3.8 5.0 P/V 2.10 2.6 3.15 3.83 4.4 1. The volume decreases. 2. The pressure increases. 3. The recorded volume must be decreasing while the recorded pressure must be increasing. Therefore, when a line graph of gas’ volume vs. its pressure is plotted, with the pressure on the y axis and the volume on the x axis. 4. Inversely proportional. Activity 1 Situation 1 1. Inflated balloon is heavier. The difference in the mass is due to the addition of gas, 2. Gases like solids and liquids have mass too. Situation 2 1. The volume increases 2. Gases have volume too. Situation 3 1. Yes, Heat flows from the surroundings or vice versa. If the water is cooled, the surrounding air also gets cooled. Conversely, if the water is hot, the surrounding air also get hot. Situation 4. 1. Heat flows. The heat from water is transferred to the air above it. As the air gets heated, its molecules become excited and push the walls of the balloon making changes in the size and shape. 2. As the water is heated until it boils, water vapors are produced. The water vapors are warm and warm air goes up. In the setup the war air goes to the balloon making it inflated. The more water vapor is produced, the bigger the size of the balloon. VI. Answer Key 1. What are some of the daily situations and activities observed at home and the community that involves the properties of gases? Cite examples. V. Reflection Activity 4 Table 1.2 Data on Determining the Size of the Balloon Answers may vary. 1. The size of the balloon decreases. 2. As temperature decreases, the volume of the gas decreases. Table 1.3 Data on Volume-Temperature Relationship 1. 275 K 2. 330 K 3. 375 K 4. 425 K 1. The temperature increases when the volume increases. 2. The graph is increasing. 3. Directly proportional. Activity 5 1. Final temperature = 169.8K Activity 6. 1. Attraction between gas particles. 2. The particles of a gas move rapidly. 3. Gas particles move at random motion with no attractive forces between them. Activity 7 1. According to Kinetic molecular theory, the molecules of gas are in continuous motion. When the volume is less, collision is greater and pressure between molecules increases. 2. According to Kinetic Molecular Theory, an increase in temperature will increase the average kinetic energy of the molecules. At a higher temperature, the pressure of a container is increased due to the increase in the number of times gas molecules strike the container walls. Graph Activity 3 1. Final Pressure = 2.02 atmosphere