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PERRY TABBINGS

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2
VP (Organic
Compounds)
UNITS &
SYMBOLS
Physical
Constant
VAPOR
PRESSURES
VP (Water)
Chemical
Family
Formula
Index
VP (Inorg &
Org Liquids)
VP (Inorg
Cmpds)
H2O/HCl
Solutions
H2O/H2SO4
Solutions
SO2/Water
HNO3,H2O/
HNO3 Sol’ns
CH3COOH
Solutions
H2O/NH3
Solutions
H2O/Na2CO3
Sol’ns
SOLUBILITIES
Inorganic
Compounds
Henry’s
Constant
DENSITIES
Saturated
Liquid H2O
ρ (Inorg &
ρ (Aqueous
Org Liquids) Inorg Sol’ns)
LATENT HEATS
Heat of
Vaporization
ΔHfus (Org
Cmpds)
ΔHv (Inorg &
Org Liquids)
SPECIFIC
HEATS
Cp (Elem &
Cp (Inorg &
Inorg Cmpds) Org Liquids)
Cp/Cv
Cp (Aqueous
Sol’ns)
Cp (Misc
Materials)
FORMATION &
COMBUSTION
ΔH & ΔF
(Inorg C.)
Enthalpy /
ΔG / Entropy
Inorganic
Organic
Compounds Compounds
THERMAL
EXPANSION
Linear
Expansion
Volume
Expansion
JouleThompson
Elements &
Organic
Inorg Cmpds Compounds
PARTIAL
PRESSURES
H2O,CH3OH/ H2O/NaOH
CH3OH Sol’ns Solutions
ρ (Aqueous
Org Sol’ns)
Ideal Gas
Constant, R
CONVERSION
FACTORS
ρ (Misc
Materials)
Cp (Organic
Cp
Cp
Solids)
(Polynomial) (Hyperbolic)
Enthalpy
(Combust)
Entropy
(Combust)
HEATS OF
SOLUTION
Critical
Constants
COMPRESSIBILITY, Z
THERMODYNAMIC P.
Air
Ammonia
Carbon
Dioxide
Carbon
Monoxide
Ethanol
Hydrogen
Methane
Methanol
Nitrogen
Oxygen
R-22
(CCl2F2)
R-32
(CH2F2)
R-125
(C2HF5)
R-134a
(CH2FCF3)
R-143a
(C2H3F3)
R-404A
R-407C
R-410A
OpteonTM YF
(R-1234yf)
Water
TRANSPORT
PROPERTIES
Surface
Tension σ
Viscosity
(Inorg & Org)
Viscosity
(Liquids)
Diffusivities
(Gas & Vap)
Diffusivities
(Liquids)
Cognomen
Critical
Properties
Normal
Melting Pt.
Normal
Boiling Pt.
Acentric
Factor
Radius of
Gyration
Dipole
Moment
Refractive
Index
Dielectric
Constant
Vapor
Pressure
Thermal
Properties
Enthalpy of
Formation
Entropy
Latent
Enthalpy
Enthalpy of
Vaporization
Enthalpy of
Fusion
Enthalpy of
Sublimation
Heat
Capacity
Density
Viscosity
Thermal
Conductivity
Surface
Tension
Flammability
Properties
Flash Point
3
MATHEMATICS
Constants & MENSURATION ELEMENTARY
Formulas
FORMULAS
ALGEBRA
ANALYTIC
ALGEBRA
INFINITE
SERIES
COMPLEX
VARIABLES
DIFFERENTIAL
EQUATIONS
4
Thermodynamic Laws
Variables &
Definitions
Cpig – T
Equations
Steady state
(Definition)
GENERAL
BALANCES
Clapeyron
Equation
Antoine
Equation
Energy
Balance
Entropy
Balance
Irreversibility
Poynting
Correction
Virial EOS
PengLorentzRobinson (PR) Berthelot rule
Change of
Mixing
GE Models
Vapor/Liquid Equilibrium
Equilibrium
Ratio
Dew
Bubble, Dew
Calculation Sample Prob
5
Prandtl
Thermal
ThermoFlammability
Flash Points
Number (Air) Conductivity physical Prop
Limits
Ostwald
coefficient
CONDUCTION Fourier’s Law
Autoignition PREDICTION &
CORRELATION
Temp
Flammability Autoignition
Limit
Temp
DIFFERENTIAL
CALCULUS
INTEGRAL
CALCULUS
Continuity
Equations
PFD (DME
Synthesis)
Ideal Gas
Carnot
Efficiency
Flow
Processes
EQUATIONS
OF STATE
Fugacity
Chemical
Potential
GibbsDuhem Eqn
LewisRandall Rule
Phase Rule
Excess
Property
Duhem’s
Theorem
RachfordModified
Bubble
Raoult’s Law
Rice Method
Raoult’s Law Calculation
LAPLACE
INITIAL-VALUE
OPTIMIZATION
TRANSFORM
PROBLEMS
PLANE
TRIGO
STATISTICS
Bunsen
coefficient
Std. Property
Change
Steady
rate of Q
b, measure
of curvature
Biot
Number, Bi
CONVECTION
Nusselt
Natural
Number, NuD Convection
Rayleigh
Number, Rax
Prandtl
Number, Pr
Forced
Convection
Condensation
Falling Film
Jakob
Number, Jal
Pool Boiling
Planck’s Law
Wien
Equation
Emittance &
Absorptance
Kirchoff’s
Law
Yamauiti
Principle
MASS
TRANSFER
Fick’s
First Law
Diffusivities
(Dilute Liq.)
Diffusivities
(Conc’d Liq)
Diffusivity
Estimation
Diffusivities
(Solids)
HTU
NTU
Film Theory
Penetration
Theory
Danckwerts
Theory
RADIATION
Blackbody
Radiation
Mass Transfer Diffusivities
Coefficient
(Gases)
Sherwood
Schmidt
Stanton
Number, NSh Number, NSc Number, NSt
6
FLUID
DYNAMICS
Fluid Types
Bernoulli
Equation
Cauchy
Momentum
NavierStokes Eqn
Fanning
factor, ƒ
HagenPoiseuille
Knudsen
Number, Kn
Frictional
Losses
Dean
Number, De
Mach
Number, M
Flow Pattern
Transport
Velocity
Durand
Equation
Impeller Re
(ReI)
Power
Number, NP
Ergun
Equation
Porous
Media
Darcy’s Law
Strouhal
Number, Sr
Kolmogorov Dimensioneddy
less Numbers
PARTICLE
DYNAMICS
Drag
Coefficient
Terminal
Velocity
Stoke’s Law
Intermediate
Law
Newton’s
Law
Hindered
Settling
Weber
Best
Number, We Number, ND
Wall Corr.
Factor, kw
7
Reaction
Rate
Heat of
Chemical
Reaction, ΔHr Equilibrium
Limiting
Reactant
Extent of
Reaction, ξ
Selectivity, S
Yield. Y
1st-Order
Reactions
HOMOGENEOUS RXNS
Reaction
Law of Mass
Classification
Action
Catalysis
IDEAL
REACTORS
Arrhenius
Equation
Batch
CSTR
PFR
Chain
Reactions
Phosgene
Synthesis
O3-O2
Conversion
HBr
Synthesis
FLUID-SOLID
CATAL. RXNS
Ely-Rideal
Kinetics
Biocatalysis
Monod
Kinetics
Chain
Polymeriz’n
Biochemical Biological Vs. Electrochem
Reactions
Chemical
Reactions
Butene-1
Isomeriz’n
Enzyme
Kinetics
Exponential Langmuir- External Mass Intraparticle
growth
Hinshelwood
Transfer
Diffusion
Catalyst
G-S Noncatal GAS-LIQUID Reaction-Diff.
Hatta
REACTIONS
Deactivation Reactions
Regime
Number, Ha
Polydispersity
Homo.
Catalysis
Faraday’s
Law
Feedforward Open- vs.
Control
Closed-Loop
Autocatalysis
Thiele
Modulus
G-L-S
REACTIONS
Catalytic
Reactions
Polymeriz’n
Reactions
MW
Distribution
Current
Efficiency
Laboratory
Reactors
Kinetic
Parameters
Half-Life
Method
Laplace
Transform
SISO
Systems
Feedback
Control
On/Off
Control
8
Control
System
Feedback
Control
Proportional
Control
PI Control
PID Control
Controller
Tuning
ADVANCED
CTRL SYSTEM
FB-FF
Pros & Cons
Cascade
Control
Selective &
Override
Split-Range
Control
Adaptive
Control
UNIT OPS
CTRL SYSTEM
P&I
Diagrams
Heat E.
Control
Distillation C.
Control
Chemical
Reactors
Drying
Operations
Compressor
Control
Plantwide
Control
BIOPROCESS
PROCESS
Temperature
CONTROL MEASUREMENT
Pressure
Flow
Control
Valves
Speed
Pumps
Regulators
PLANT SAFETY
Pressure
Measure
Static
Pressure
Velocity
Measure
Flowmeters
HDA Process
Batch vs
BATCH
Flowsheet PROCESS CTRL Continuous
Batch
Reactor Ctrl
Level
Physical
Property
Electroanalytical
9
TERMS
10
MEASURE OF
FLOW
Behavior
of Fluids
Velocity
Meters
PUMPS
Centrifugal
Pumps
Propeller &
Turbine P.
Jet Pumps
COMPRESSOR
Cont.-Flow
Compressor
Ejectors
Seals
Bearings
Compressor
Problems
Rotor
Dynamics
Metallic
Piping
Properties of
Steel Pipe
Flanged
Joints
Mechanical
Joints
Valves
11
THERMAL
DESIGN
Mean Temp
Difference
LMTD
Temperature
Profiles
Tank Coils
Fouling &
Scaling
Chemical
Composition
EVAPORATOR
Total
Dry- & WetTemperature Bulb Temp
Heat-Transfer
Solids
Coefficients Processing
Shell-side
Baffles &
DOUBLE-PIPE
HE
Construction Tube Bundles
Moisture
Emissivity
Compression Theory of
of Gases Compression
Vibration
Monitoring
Thermal
Modulus
Coeff (Metal) of Elasticity
LMTD Corr.
Factors
Condensers
PROCESS
PLANT PIPING
Selection
of Pipes
Storage
of Gases
Pressure
Vessels
Reboilers
Evaporators
Types of
Tube-side
SHELL-AND- HT Equipment
TUBE HE
& Functions Construction Construction
THERMAL
INSULATION
AIRCONDITION
Types &
Boiling-Point Vapor-Liquid
Arrangement Calculations Accessories
Applications
Rise
Separation
Operation
AIR-COOLED COMPACT &
HE
NONTUBULAR
Fans &
Blowers
HE FOR
SOLIDS
REFRIGERATION
12
PSYCHROMETRY
Terminology
Formulas
Psychro-M
Charts
Sample
Problems
Psychro-M
Calculations
Worked
Examples
Measure of
Humidity
EVAPORATIVE
COOLING
Cooling
Towers
Makeup
Water
Wet Surface
Air Coolers
SOLIDSDRYING
Terminology
Moisture
Transport
Drying
Kinetics
Dryer Types
Tray Dryers
Tunnel
Dryers
Agitated &
Rotary Dryers
FluidizedBed
13
DISTILLATION
Phase
Equilibria
K Value
Raoult’s Law
No. of Stages
FLASH
BINARY
CALCULATION DISTILLATION
K Value
Correlations
Required
Material
Balances
Operating
Line
Murphree
Efficiency
MULTI-COMP
DISTILLATION
Fenske’s
Equation
Underwood
Equation
Gilliland
Equation
MaxwellStefan
Azeotropy
Azeotropic
Distillation
Extractive
Distillation
Reactive
Distillation
PETROLEUM
DISTILLATION
BATCH
DISTILLATION
Tray-Tower
Design
Heat Effects
in Gas Ab
Multicomponent
14
PackedGAS
ABSORPTION Tower Design
TRAY
COLUMNS
Tray Types
Flooding
Entrainment
Pressure
Drop
Hydraulic
Limits
Structured
Packings
Packing
Efficiency
Wetted-Wall
Columns
PHASE
DISPERSION
Bubble Size
PHASE
SEPARATION
McCabeThiele
Kremser
Equation
Equil Stage
Equations
Absorp w/
Chem’l Rxn
Conc’n
Profile
Hatta
Number, NHa
Tray
Efficiency
PACKED
COLUMNS
Random
Packings
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