Notes by 0625 syllabus content PHYSICS NOTES SIMPLE KINETIC MOLECULAR MODEL OF MATTER State the distinguishing properties of solids, liquids and gases Describe qualitatively the molecular structure of solids, liquids and gases in terms of the arrangement, separation and motion of the molecules Relate the properties of solids, liquids and gases to the forces and distances between molecules and to the motion of the molecules STATE ARRANGEMENT MOTION Solid The particles are closely packed in a regular pattern and held in place by strong intermolecular forces. This is also the reason to why solids retain their shape The particles vibrate about a fixed position within the structure. This is because each particle is in close contact with all the neighbouring particles due to the strong forces therefore leaving no relative space to move around Liquid The particles are packed slightly less close together compared to a solid and in an irregular pattern (more jumbled and disorderly). The intermolecular forces are also weak. This is also the reason to why liquids take up the shape of their container The particles slide over each other in a random manner. This is because the particles less tightly packed due to the weak forces hence leaving room to move around. Gas The particles are widely spaced and separated from each other, no longer in contact unless on collision. The forces between the molecules are negligible. This is why gases fill their container. The particles are in random motion, faster than the other states, bouncing off one another and off the inner surfaces of their container. Interpret the temperature of matter in terms of the motion of its molecules When matter is heated, energy is given to the molecules. Generally, the molecules gain kinetic energy. In a solid they vibrate faster and, in a liquid, or gas they move faster. Not all molecules move at the same speed or in the same direction. The average kinetic energy of the molecules is a measure of the temperature of the material – the higher the average kinetic energy of the molecules, the higher the temperature. Describe qualitatively the pressure of a gas in terms of the motion of its molecules Explain pressure in terms of the change of momentum of the particles striking the walls creating a force A gas is stored in a container. The gas molecules move at random and collide with each other and the container walls and bounce off. Each time the wall is hit there is a small force on the wall. There are billions of collisions with the wall each second, and the overall effect of these forces is to produce a pressure on the wall because force is directly proportional to pressure: 𝑃 = 𝐹 𝐴 If the gas is heated, the molecules move faster. Therefore, they collide with each other and the walls more frequently and each collision is harder. This means more force and because 𝑃 = 𝐹 𝐴 ,the result is that the pressure increases when the temperature increases. Describe evaporation in terms of the escape of more-energetic molecules from the surface of a liquid Demonstrate an understanding of how temperature, surface area and draught over a surface influence evaporation Relate evaporation to the consequent cooling of the liquid By Eng. Trish Sakarombe Explain the cooling of a body in contact with an evaporating liquid Distinguish between boiling and evaporation Evaporation is when a liquid changes to a gas at a temperature below its boiling point. For example, on a sunny day, a puddle of water will slowly disappear. The liquid water has turned into vapour. Clearly the water has not boiled, it has evaporated. Evaporation occurs when the most energetic molecules leave the surface of a liquid. This results in the average kinetic energy of the remaining molecules being reduced. Consequently, the temperature of the remaining liquid falls. Evaporation increases when: 1. 2. 3. The temperature increases The surface area of the liquid is increased There is a breeze (draught) across the surface of the liquid Clothes left crumpled up take a long time to dry because the surface area exposed to air is reduced. A sunny, windy day is best for drying clothes. The raised temperature means that more molecules have sufficient energy to escape and the wind blows away those molecules which have already escaped, so they cannot go back into the liquid or bounce other molecules back into it. Evaporation vs Boiling Evaporation Surface effect Boiling Occurs throughout the liquid with bubbles of vapour forming in the liquid Occurs only at a boiling point Vigorous process Occurs at all temperatures Quiet process Describe qualitatively, in terms of molecules, the effect on the pressure of a gas of: – a change of temperature at constant volume – a change of volume at constant temperature Recall and use the equation 𝒑𝑽 = 𝒄𝒐𝒏𝒔𝒕𝒂𝒏𝒕 for a fixed mass of gas at constant temperature At constant volume, if the temperature of a gas is increased, the molecules gain kinetic energy and begin to move faster. This increases the chances of collisions between the gas molecules and the walls of the container, creating a force. The higher the force, the higher the pressure. The opposite is true. At constant temperature, if the volume of a gas is increased, the molecules will have more space to move around in. This decreases the chances of collisions between the gas molecules and the walls of the container, resulting in less force created. The lower the force, the lower the pressure. If the volume is decreased (compressing a gas), the molecules will have less space to move around in. This increases the chances of collisions between the gas molecules and the walls of the container, resulting in a higher force. The greater the force, the greater the pressure. **Note** ONLY MENTION KINETIC ENERGY WHEN THERE IS A CHANGE OF TEMPERATURE NOT WHEN TEMPERATURE IS KEPT CONSTANT. 𝐵𝑜𝑦𝑙𝑒 ′ 𝑠 𝐿𝑎𝑤 ∶ 𝑝𝑉 = 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡 Where 𝑝 = pressure And 𝑉 = volume By Eng. Trish Sakarombe 𝑝∝ 1 𝑉 𝑉= 1 𝑝 Boyle’s law states that the volume of a fixed mass of gas is inversely proportional to its pressure, provided its temperature remains constant. Similarly, we can make calculations using: 𝑝1 𝑉1 = 𝑝2 𝑉2 Where, 𝑝1 = initial pressure 𝑝2 = final pressure 𝑉1 = initial volume 𝑉2 = final volume By Eng. Trish Sakarombe