Study of rate of evaporation of different liquids INDEX I. OBJECTIVE II. THEORY III. MATERIALS RECQUIRED IV. PROCEDURE V. OBSERVATION VI. CONCLUSION VII. BIBLIOGRAPHY This project would not have been possible without the kind support and help of many individuals. I would like to thank our principal, Mr.M.Pradeesh Kumar for his priceless motivation. I would also like to thank our subject teacher; Mrs.Anita and Mrs.Raghendu whose valuable guidance helped me patch this project. I would like to thank my parents for their heartfelt support and encouragement. My thanks to my fellow classmates in developing the project. Rate of Evaporation of Different Liquids Objective of Project In this project, we shall investigate various factors such as nature of liquid, surface of liquid and temperature and find their correlation with the rate of evaporation of different liquids. THEORY Factors influencing rate ofEvaporation:1. Concentration of the substance evaporating in the air. If the air already has a high concentration of the substance evaporating, then the givensubstance will evaporate more slowly. 2. Concentration of other substances in the air. If the air is already saturated with other substances, it can have a lower capacity forth substance evaporating. 3. Temperature of the substance. If the substance is hotter, then evaporation will be faster. 4. Flow rate of air. This is in part related to the concentration points above. If fresh air moves over the substance all the time, then the concentration of thesubstance in the air is less likely to go up with time, thus encouraging faster evaporation. In addition, molecules in motion have more energy than those at rest, and so the stronger the flow of air, the greater the evaporating power of the airmolecules. 5. Inter-molecular forces. The stronger the forces keeping the molecules together in the liquid or solid state the more energy that must be input in order to evaporate them. 6. Surface area and temperature. The rate of evaporation of liquids varies directly with temperature. With the increase in the temperature, fraction of molecules having sufficient kinetic energy to escape out from the surface alsoincreases. Thus with the increase in temperature rate of evaporation also increases. Molecules that escape the surface of the liquids constitute the evaporation.Therefore larger surface area contributes accelerating evaporation. 7. Nature of Liquids The magnitude of inter-molecular forces of attraction in liquid determines the speed of evaporation. Weaker the intermolecular forces of attraction larger are the extent of evaporation. 8. Density The higher the density, the slower a liquid evaporates. 9. Pressure In an area of less pressure, evaporation happens faster because there is less exertion on the surface keeping the molecules from launching themselves. MATERIALS REQUIRED APPARATUS: Three petridishes of diameter 10 cm with covers. 10 ml pipette. Stop watch. CHEMICALS: Acetone Benzene Chloroform Fig 0.1: Petridish used for experiment Experiment no. 1 Aim: To compare the rates of evaporation of acetone, benzene and chloroform. Requirement: Three same size Petri dishes of diameter 10 cm, 10 ml. pipettes, stop watch, acetone benzene and chloroform. Procedure: Clean and dry all Petri dishes and identify them as A, B and C. Pipette out of 10 ml. acetone in Petri dish "A" with stopper similarly pipette out of 10 ml. of benzene and chloroform in each of Petri "B" and "C". Remove the cover plates from all Petri dishes and start the stop watch. Let the Petri dishes remain exposed for 10 minute. Now cover each of the petridish and note the volume of remaining material in them. Observation: Time: 10 min = 600 Sec. Liquid Vol. Petri Volume Taken Evap. dishes remaining Rate (V/T) ml./s (V1) V=V1– Marked (V2) ml. ml. V2 A B C 10 10 10 2 3 4 8 7 6 8/600=0.0133 7/600=0.0116 6/600=0.010 Results: Rate of evaporation of Acetone is 0.0133 ml/s. Rate of evaporation of Benzene is 0.0166 ml/s. Rate of evaporation of Chloroform is 0.010 ml/s. Conclusion: The intermolecular forces of acetone, benzene and chloroform are in order. Chloroform > Benzene > Acetone. Fig1.1 Intermolecular forces Experiment no. 2 Aim: To study the effect of surface area on the rate of evaporation of diethyl ether. Requirement: Three petri dishes of diameter 2.5 cm, 5cm, 7.5 cm with cover, 10 ml of pipette and stop watch. Procedure: Clean and dry all petridishes and mark them as A, B and C. Pipette out 10 ml of diethyl ether in each of the petridish A, B and C and cover them immediately. Uncover all the 3 petridish and start the stopwatch. Note the remaining volume after 10 minutes. Observation: Time: 10 minutes = 600 seconds. Petri Diameter of Volume Taken Remaining Evaporated dishes P.T.Ds. (ml.) Vol. (ml.) volume Marked A B C 2.5 5.0 7.5 10 10 10 4 2 0 6 8 10 Result: The order of evaporation of acetone in three petridish are as 7.5 > 5.0 > 2.5. Conclusion: Larger the surface area, greater the evaporation. Fig 2.1 Different petridishes with different surface areas. Experiment 3 Aim: To study the effect of temperature on rate of evaporation of acetone. Requirement: Two petridish of 5 cm diameter, stop watch, 10 ml pipette, thermometer, thermostat. Procedure: Wash, clean, dry the petridish and mark them as A,B Pipette out 10 ml of acetone in each of the petridish and cover them. Put one at room temperature and heat the other. Note the reading. Observation: Time taken 10 minutes = 600 seconds. Petri Evaporated Time Temperature Volume Taken dishes volume (Sec.) (0C) (ml.) Marked (ml.) A B 10 20 30 40 10 10 10 10 Result: Evaporation during heating is greater than evaporation at room temperature. Conclusion: Evaporation increases with increase in temperature. Fig 3.1: Heating a petridish. CONCLUSION Rate of evaporation of the given three liquids is in the order: Chloroform=0.0133 ml./s Benzene=0.0116ml./s Acetone=0.010ml./s Chloroform > Benzene > Acetone The intermolecular forces of acetone, benzene and chloroform are in order. Chloroform > Benzene > Acetone. Larger the surface area, greater the evaporation. Evaporation increases with increase in temperature. BIBLIOGRAPHY WWW.WIKIPEDIA.ORG WWW.CHEMWORLD.COM WWW.QUORA.COM WWW.ICBSE.COM