Chapter 3 Features, advantages and applicability of CCTs (Coal-Based Power Generating Technologies) 3.1. Coal-fired power plants Fig.3.1.1 shows a schematic overview of a typical and current coal fired power plant constructed in Japan. Low NOx burner, De-NOx, De-SOx and Electrostatic Precipitator (ESP) are essential. Gas-gas heater (GGH) is equipped to avoid white smoke from the stack by the warming-up of the flue gas exhausted from wet type De-sulfurization equipment. Ancillary equipment are introduced in chapter 4. Reheat steam Main steam Figure 3.1.1 Schematic overview of a typical coal fired power plant installed in Japan Source: Japan Coal Energy Center 3.2 History of steam conditions for coal-fired power plants (1) Improvement of steam condition Development history of steam conditions for power plant in Japan is shown in Figure 3.2.1. The steam pressure and temperature have been intended to increase for the improvement of power generation efficiency. Supercritical power plant started in 1967 with oil and gas fired boiler (Steam pressure in 24.1MPa, main steam temperature in 538 degrees C and re-heater steam temperature in 566 degrees). Coal fired supercritical power boiler started in 1983 with 24.1 MPa and 538 degrees C steam (both superheated and reheated steam). Ultra supercritical power unit started in 1993 at 24.1 MPa and 538 degrees C of main steam and 593 degrees C of re-heater steam. As of 2014, the latest coal fired power plant designed at 25MPa and 600 degrees C main steam and 620 degrees C reheated steam started in2009. Figure 3.2.1 Development of steam temperature and pressure. Source: Japan Coal Energy Center (2) Comparison of Subcritical unit and supercritical unit Table 3.2.1 shows the main comparative features of boiler designed by new technology to old one. type Table 3. 2. 1 Comparison of new designed boiler to old one. Subcritical unit Supercritical and Ultra-supercritical units (Drum type boiler) (Once-through type boiler) To Turbine Super-heater Water circulation Riser pipes Furnace Wall tube (Water-cooled) To Turbine Economizer ρ2 Feed-water ρ1 Down-comers Densityρ1>ρ2 Burners Features Drum Super-heater Boiler water circulation Furnace Wall tube (Water-cooled) Furnace Wall tube (Water-cooled) Burners Economizer Feed-water ・Boiler-water is fed to drum through the economizer. ・ Fluid (feed-water) at supercritical pressure experiences a ・Boiler-water is supplied to furnace wall through down-comer and heated up continuous transition from water-like to steam-like in the furnace. Heat addition generates a steam-water mixture and returns to characteristics. The fluid passed through the economizer in drum. In the drum, the steam is separated from boiler water and supplied to liquid phase flows to the furnace wall tubes and is heated-up in super-heater. Superheated steam is supplied to turbine for power generation. the furnace and changed to vapor (steam) phase and connected ・In circulation, gravity acting on the density difference between the sub-cooled to super-heater. Superheated steam is supplied to turbine for water in the down-comer and steam water mixture in the heating tube circuit power generation. produces the driving force for circulation. ・No two phases state occurs in the furnace and drum is not ・Maximum capacity of the plant is limited up to about 600MW due to the required. limitation of the drum sizing. Steam Conditions Subcritical Supercritical Ultra-supercritical 16.6 24.1 24.1 538 - 566 538 - 566 593 - 620 Drum Once-through Once-through Generating Efficiency low high highest Fuel/ Exhaust gas more less Least *1 Water quality control easy severe*2 more severe *2 Steam temperature control easy severe Load changing rate low high Start-stop time long quick Pressure MPa (Typical) Temperature ℃ (Typical) Boiler type Operation relatively easy (base) Quick responding action required *3 Maintenance relatively easy (base) Establishment of maintenance procedure is required *4 Main tube material low alloy Low/ high alloy Ferritic stainless *5 Remarks *1. Less exhaust gas contributes to less amount of NOx, SOx, Particulate matter and CO 2 emission. *2. Impurities are entrained to turbine or accumulated in boiler tubes. *3. Rapid steam pressure and temperature control is required due to less holding amount of boiler water. *4. Considering characteristics of new materials for high temperature use, maintenance procedure is required to republish. *5. Austenitic stainless steel tubes is used for high temperature steam condition. *6. Typical side view of Subcritical Boiler *7. Typical side view of Supercritical Boiler Source: Japan Coal Energy Center Figure 3.2.2 Typical side view of Subcritical Boiler*6 Source: The Institute of Electrical Engineers of Japan Pendant Super-heater Pendant Re-heater Horizontal Re-heater Horizontal Super-heater Evaporator Economizer Coal Banker DeNOx Burner Air-heater Pulverizer Figure 3.2.3 Typical side view of Supercritical Boiler*7 Source: The Institute of Electrical Engineers of Japan 3.3 Ultra-supercritical coal-fired power plants In the 90th, National project was started to develop 600 degrees C class coal fired power plants to improve the thermal efficiency. First USC (≥24.1 MPa and 593 ℃) in Japan was built in 1993 whose capacity was 700MW. Since then the steam conditions in USC for all coal fired power plants have been adopted in Japanese power station. Furthermore the development for the application of higher steam temperature has been proceeded and as of 2014, the highest super-heater and re-heater steam temperatures are in 600 ℃ and 620 ℃ respectively. . All of them have been operating with a high efficiency and high availability. Fig.3.3.1 shows power generation efficiency and CO2 reduction rates for various steam conditions of SC/USC units. Efficiency improve from 538 degree C class to 625 degree C is relatively +5% and CO2 reduction is -4.5%. Fig.3.3.2 is a view of Isogo Power Station. Figure 3.3.1 Efficiency and CO2 reduction rate Source: Japan Coal Energy Center Figure 3.3.2 Up-to-date USC, Isogo No.1 and No.2 Units (600MW respectively, From J-POWER Homepage) Fig 3.3.3 Boiler side view of Ultra-supercritical unit (Isogo Unit No.1; 600MW) For the next step, the study for a 700 degree C class USC power plant started in 1998. It is called as A-USC (Advanced USC) whose targeted net efficiency is around 50% (LHV basis). 3.4 Integrated Coal Gasification Combined Cycle (IGCC) (1) General Coal fired power plants play an important role in providing energy at low prices because coal is abundant, efficient and less expensive than most other energy options and will remain an important part of energy future in the world. However coal fired power plants emit considerable quantity of carbon dioxide (CO 2 ), a greenhouse gas (GHG), into atmosphere compared to other power generation plants and required to be improved in environmental performance. IGCC has been developed to improve the power generation efficiency using gasifier technology to turn coal into synthesis gas (syngas) for gas turbine power generation. The plant is called integrated because the syngas produced in the gasification section is used as fuel for the gas turbine in the combined cycle and steam produced by syngas cooler in the gasification section and heat recovery steam generator (HRSG) installed gas turbine exhaust section is used by steam turbine in combined cycle. Figure 3.4-1 shows outline of IGCC. Figure3.4.1 Outline of IGCC Source: Joban Joint Power., Ltd. Figure3.4.2 shows thermal efficiency of typical power generation plant. Figure3.4.2 Thermal efficiency of typical power generation plant Source: Japan Coal Energy Center (2) Demonstration Plant Figure3.4-3 shows 250MW demonstration plant installed at Nakoso power station of Joban Joint Power Co., in Japan supplied by Mitsubishi Heavy Industries, Ltd.. The plant had successfully completed its demonstration operation under Clean Coal Power R&D Co., Ltd. and has started its commercial operation since April of 2013 under Joban Joint Power Co., the new owner of 250MW Nakoso IGCC plant. Gasifier HRSG GT / ST Gas Clean-Up Figure 3.4.3 250 MW IGCC Demonstration Plant Source: Joban Joint Power., Ltd. (3) Beneficial features IGCC system has following features compared with conventional coal fired power generation systems. 1) High plant efficiency 2) Low pollution in NOx, SOx, CO2 and dust emission 3) Reduction of ash volume and protection from heavy-metals elution after landfill by melting of ash in gasifier and exhausted as vitric slag. 4) Coal with low ash melting temperature, ill-suited for pulverized coal fired boiler, can be used. 3.5 Japan’s Typical Coal-Fired Power Plants (1) Tokyo Electric Power Co., Inc. 1) Hirono Coal-fired Power Plant (Space: 1,320,000M2) 1 a) Unit Specification No. Nominal Output(MW) Steam condition Temp. COD Pressure #5 600 600/600℃ 24.5MPa June/2004 #6 600 600/600℃ 24.5MPa Dec./2014 Unit1,2,3,4 are oil-fired Units. b) Overview of TPS 1 Reference: Tokyo Electric Power HP http://www.tepco.co.jp/cc/press/betu13_j/images/131203j0101.pdf , Jcoal Coal Data Bank c) Layout of TPS 2) Hitachinaka Coal-fired Power Plant (Space:1,410,000M2) 2 a) Unit Specification No. Nominal Steam condition COD Output(MW) Temp. Pressure #1 1000 600/600℃ 24.5MPa June/2003 #2 1000 600/600℃ 24.5MPa Dec./2013 b) Overview of TPS Reference: Tokyo Electric Power HP http://www.tepco.co.jp/cc/press/betu13_j/images/131218j0101.pdf,Jcoal ,Coal Data Bank 2 c) Layout of TPS (2) CHUBU Electric Power Co., Inc. Hekinan Coal - Fired Power Plant (Space: 1,600,000M2) 3 a) Unit Specification No. 3 Nominal Steam condition COD Output(MW) Temp. Pressure #1 700 538/566℃ 24.1 MPa Oct./1991 #2 700 538/566℃ 24.1 MPa June/1992 #3 700 538/593℃ 24.1 MPa Apr./1993 #4 1000 566/593℃ 24.1 MPa Nov./2001 #5 1000 566/593℃ 24.1 MPa Nov./2002 Reference: Material was supplied by CHUBU Electric Power Co.,Inc. b) Overview of TPS c) Layout of TPS (3) Electric Power Development Co., Ltd Isogo Coal-fired Power Plant (Space: 120,000M2) 4 a) Unit Specification No. Nominal Steam condition COD Output(MW) Temp. Pressure #1 600 600/610℃ 25MPa Apr./2002 #2 600 600/620℃ 25MPa July/2009 b) Unit Specification No. Nominal Steam condition Output(MW) Temp. Pressure #1 600 600/610℃ 25MPa Apr./2002 #2 600 600/620℃ 25MPa July/2009 c) Overview 4 COD of TPS Reference: Guidebook of Isogo Thermal Power Station Published by Electric Power Development Co.,Ltd d) Layout of TPS