Safety data sheet
Page: 1/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
1. Identification of the substance/mixture and of the company/undertaking
Product identifier
Agnique® BL 7054
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: formulation auxiliary for the chemical industry
Details of the supplier of the safety data sheet
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Care Chemicals
Telephone: +49 621 60-44676
E-mail address: emd-ems-ehs-masterdata@basf.com
Emergency telephone number
International emergency number:
Telephone: +49 180 2273-112
2. Hazards Identification
Label elements
Globally Harmonized System, EU (GHS)
Pictogram:
Page: 2/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
Signal Word:
Danger
Hazard Statement:
H318
H412
Causes serious eye damage.
Harmful to aquatic life with long lasting effects.
Precautionary Statements (Prevention):
P280d
Wear eye/face protection.
P273
Avoid release to the environment.
Precautionary Statements (Response):
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310
Immediately call a POISON CENTER or doctor/physician.
Precautionary Statements (Disposal):
P501
Dispose of contents/container to hazardous or special waste collection
point.
According to Regulation (EC) No 1272/2008 [CLP]
Hazard determining component(s) for labelling: D-Glucopyranose, oligomers, decyl octyl glycoside
According to Directive 67/548/EEC or 1999/45/EC
Directive 1999/45/EC ('Preparation Directive')
Hazard symbol(s)
Xi
Irritant.
R-phrase(s)
R41
S-phrase(s)
S26
S39
Risk of serious damage to eyes.
In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
Wear eye/face protection.
Hazard determining component(s) for labelling: D-Glucopyranose, oligomers, decyl octyl glycoside
Classification of the substance or mixture
According to Regulation (EC) No 1272/2008 [CLP]
Eye Dam./Irrit. 1
Aquatic Chronic 3
According to Directive 67/548/EEC or 1999/45/EC
Page: 3/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
Possible Hazards:
Risk of serious damage to eyes.
For the classifications not written out in full in this section the full text can be found in section 16.
Other hazards
According to Regulation (EC) No 1272/2008 [CLP]
No specific dangers known, if the regulations/notes for storage and handling are considered.
3. Composition/Information on Ingredients
Mixtures
Chemical nature
Aqueous solution based on: Alkylpolyglucoside
Hazardous ingredients (GHS)
according to Regulation (EC) No. 1272/2008
D-Glucopyranose, oligomers, decyl octyl glycoside
Content (W/W): >= 25 % - < 50 % Eye Dam./Irrit. 1
CAS Number: 68515-73-1
Aquatic Chronic 3
EC-Number: 500-220-1
H318, H412
REACH registration number: 012119488530-36
ammonia...%
Content (W/W): >= 0.3 % - < 1 %
CAS Number: 1336-21-6
EC-Number: 215-647-6
REACH registration number: 012119488876-14
INDEX-Number: 007-001-01-2
Skin Corr./Irrit. 1B
Eye Dam./Irrit. 1
STOT SE 3 (irr. to respiratory syst.)
Aquatic Acute 1
H400, H335, H314
Hazardous ingredients
according to Directive 1999/45/EC
D-Glucopyranose, oligomers, decyl octyl glycoside
Content (W/W): >= 25 % - < 50 %
CAS Number: 68515-73-1
EC-Number: 500-220-1
REACH registration number: 01-2119488530-36
Hazard symbol(s): Xi
Page: 4/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
R-phrase(s): 41
ammonia...%
Content (W/W): >= 0.3 % - < 1 %
CAS Number: 1336-21-6
EC-Number: 215-647-6
REACH registration number: 01-2119488876-14
INDEX-Number: 007-001-01-2
Hazard symbol(s): C, N
R-phrase(s): 34, 50
For the classifications not written out in full in this section, including the indication of danger, the
hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.
4. First-Aid Measures
Description of first aid measures
Remove contaminated clothing.
If inhaled:
Immediately inhale corticosteroid dose aerosol.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further important symptoms and effects are so far not known.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam
Special hazards arising from the substance or mixture
harmful vapours
Page: 5/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.
Advice for fire-fighters
Further information:
Contaminated extinguishing water must be disposed of in accordance with official regulations.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Information regarding personal protective measures see, section 8.
Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
Methods and material for containment and cleaning up
For large amounts: Dike spillage. Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance
with regulations.
Dispose of absorbed material in accordance with regulations.
Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.
7. Handling and Storage
Precautions for safe handling
No special measures necessary provided product is used correctly.
Protection against fire and explosion:
No special precautions necessary.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed and in a cool place.
Protect from temperatures below: 0 °C
Characteristics of the product are reversibly changed when falling below the limit temperature.
Protect from temperatures above: 45 °C
The packed product will not be damaged by high temperatures.
Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.
Page: 6/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
8. Exposure Controls/Personal Protection
Control parameters
Components with workplace control parameters
56-81-5: Glycerol
1336-21-6: ammonia...%
TWA value 14 mg/m3 ; 20 ppm (OEL (EU))
indicative
STEL value 36 mg/m3 ; 50 ppm (OEL (EU))
indicative
Exposure controls
Personal protective equipment
Respiratory protection:
Suitable respiratory protection for lower concentrations or short-term effect: Gas filter for
gases/vapours of organic compounds (boiling point <65 °C, f.e. EN 14387 Type AX)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is recommended.
9. Physical and Chemical Properties
Information on basic physical and chemical properties
Form:
Colour:
Odour:
Odour threshold:
pH value:
liquid
yellowish
amine-like
not determined
7.0 - 8.0
(1 %(m))
(ISO 4316)
Page: 7/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
solidification temperature:
not determined
Boiling point:
> 100 °C
Flash point:
> 150 °C
Evaporation rate:
not determined
Flammability:
does not ignite
Lower explosion limit:
For liquids not relevant for
classification and labelling.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature:
Based on the water content the
product does not ignite.
Vapour pressure:
not determined
Density:
1.11 g/cm3
(ASTM D4052)
(20 °C)
Relative density:
1.11
(20 °C)
Relative vapour density (air):
not determined
Solubility in water:
contains water
Solubility (qualitative) :
not available
Partitioning coefficient n-octanol/water (log Kow):
not applicable
Self ignition:
not self-igniting
Viscosity, dynamic:
16 mPa.s
(23 °C)
Explosion hazard:
not explosive
Fire promoting properties: not fire-propagating
(DIN EN ISO 2555)
Other information
Self heating ability:
It is not a substance capable of
spontaneous heating.
Radioactivity:
not radioactive for transport
purposes
Hygroscopy:
hygroscopic
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.
10. Stability and Reactivity
Reactivity
Page: 8/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Peroxides:
The product does not contain peroxides. The product/the substance does
not incline for the formation of peroxide.
Possibility of hazardous reactions
No hazardous reactions when stored and handled according to instructions.
Conditions to avoid
See MSDS section 7 - Handling and storage.
Incompatible materials
Substances to avoid:
acids, Alkalines, caustics, halogens, reactive chemicals
Hazardous decomposition products
No hazardous decomposition products if stored and handled as prescribed/indicated.
11. Toxicological Information
Information on toxicological effects
Acute toxicity
Experimental/calculated data:
LD50 rat (oral): > 5,000 mg/kg
Irritation
Experimental/calculated data:
Skin corrosion/irritation: non-irritant
Serious eye damage/irritation rabbit: irreversible damage (OECD Guideline 405)
Other relevant toxicity information
The product has not been tested. The statements on toxicology have been derived from the
properties of the individual components.
Page: 9/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
12. Ecological Information
Toxicity
Assessment of aquatic toxicity:
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Information on: D-Glucopyranose, oligomers, decyl octyl glycoside
Toxicity to fish:
LC50 (96 h) 126 mg/L a.i., Brachydanio rerio (OECD 203; ISO 7346; 84/449/EEC, C.1, semistatic)
Nominal concentration.
---------------------------------Information on: D-Glucopyranose, oligomers, decyl octyl glycoside
Aquatic invertebrates:
EC50 (48 h) > 100 mg/l, Daphnia magna (Directive 92/69/EEC, C.2, static)
Nominal concentration.
LC50 (10 d) 3318 mg a.i./kg dw, Corophium volutator (, static)
Nominal concentration.
---------------------------------Information on: D-Glucopyranose, oligomers, decyl octyl glycoside
Aquatic plants:
EC50 (72 h) 27,2 mg/L a.i. (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static)
Nominal concentration.
----------------------------------
Persistence and degradability
Information on: D-Glucopyranose, oligomers, decyl octyl glycoside
Elimination information:
100 % DOC reduction (28 d) (OECD 301E/92/69/EEC, C.4-B) (aerobic, activated sludge, nonadapted)
----------------------------------
Bioaccumulative potential
Assessment bioaccumulation potential:
Accumulation in organisms is not to be expected.
Mobility in soil (and other compartments if available)
Assessment transport between environmental compartments:
The substance will not evaporate into the atmosphere from the water surface.
Adsorption to solid soil phase is possible.
Results of PBT and vPvB assessment
Page: 10/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vPvB (very
persistent/very bioaccumulative).
Additional information
Other ecotoxicological advice:
The product has not been tested. The statements on ecotoxicology have been derived from the
properties of the individual components. Do not allow to enter soil, waterways or waste water
channels.
13. Disposal Considerations
Waste treatment methods
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
14. Transport Information
Land transport
ADR
UN number:
UN proper shipping name:
Transport hazard class(es):
Packing group:
Environmental hazards:
Special precautions for
user
Not classified as a dangerous good under transport regulations
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
None known
RID
UN number:
UN proper shipping name:
Transport hazard class(es):
Packing group:
Environmental hazards:
Special precautions for
user
Inland waterway transport
ADN
Not classified as a dangerous good under transport regulations
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
None known
Page: 11/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
Not classified as a dangerous good under transport regulations
UN number:
Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group:
Not applicable
Environmental hazards:
Not applicable
Special precautions for
None known
user
Transport in inland
Not evaluated
waterway vessel:
Sea transport
IMDG
UN number:
UN proper shipping name:
Transport hazard class(es):
Packing group:
Environmental hazards:
Special precautions for
user
Not classified as a dangerous good under transport regulations
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
None known
Air transport
IATA/ICAO
UN number:
UN proper shipping name:
Transport hazard class(es):
Packing group:
Environmental hazards:
Special precautions for
user
Not classified as a dangerous good under transport regulations
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
None known
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Regulation:
Shipment approved:
Pollution name:
Pollution category:
Ship Type:
Not evaluated
Not evaluated
Not evaluated
Not evaluated
Not evaluated
Page: 12/12
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 14.09.2012
Version: 1.0
Product: Agnique® BL 7054
(ID no. 30575438/SDS_GEN_EU/EN)
Date of print 15.09.2012
15. Regulatory Information
Safety, health and environmental regulations/legislation specific for the substance or
mixture
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.
16. Other Information
Information on intended use: This product is of industrial quality and unless otherwise specified or
agreed intended exclusively for industrial use. This includes the mentioned and recommended
usage. Any other intended applications should be discussed with the manufacturer. In particular this
concerns the application for products that are the object of special standards and regulations.
Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases,
and the hazard statements, if mentioned in section 2 or 3:
Xi
Irritant.
C
Corrosive.
N
Dangerous for the environment.
41
Risk of serious damage to eyes.
34
Causes burns.
50
Very toxic to aquatic organisms.
Eye Dam./Irrit.
Serious eye damage/eye irritation
Aquatic Chronic
Hazardous to the aquatic environment - chronic
Skin Corr./Irrit.
Skin corrosion/irritation
STOT SE
Specific target organ toxicity — single exposure
Aquatic Acute
Hazardous to the aquatic environment - acute
H318
Causes serious eye damage.
H412
Harmful to aquatic life with long lasting effects.
H400
Very toxic to aquatic life.
H335
May cause respiratory irritation.
H314
Causes severe skin burns and eye damage.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.